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EJERCICIOS
PROPUESTOS
1. A natural gas mixture consists of three components, C1, C2, and C3. Their
mole fractions and viscosities at a particular temperature are indicated
below:
Componen Mole
Mi Viscosity(i),
t
Fraction Yi
cP
C1
0,900
16 0,0130
C2
0,080
30 0,0112
C3
0,020
44 0,0098
Total
Calculate the viscosity of the gas mixture.
YiMi 1/2
iYiMi 1/2
3,600
0,438
0,133
4,171
0,0468
0,0049
0,0013
0,0530
( i y i M i )
( yi M i )
Entonces,
=
0,0530 cp
=0,0127 cP
4,171
2. At 100 psig and 75F, a gas has a volume of 800 ft 3. If the volume is kept
constant and the gas temperature increases to 100F, what is the final
pressure of the gas? Keeping the pressure constant at 100 psig, if the
temperature increases to 100F, what is the final volume? Use 14.73 psi for
base pressure.
RTA/
Condiciones iniciales:
P1= 100 psig + 14,73 psi = 114, 73 psia
Entonces,
V 2=
800( ft )560 R
3
=837,38(ft )
535 R
3. Calculate the apparent molecular weight of a natural gas mixture that has
89% methane, 8% ethane, 2% propane, and 1% normal butane as shown
below.
RTA/
M GAS= M iY i
i=1
Dnde:
Mi es la masa molar de cada componente
Yi la fraccin molar de cada componente
Componente
%
Molar
89
8
2
1
100
CH4
C2H6
C3H8
C4H10
total
M GAS =18,1
Yi
Mi (lb-m/lb-mol)
0,89
0,08
0,02
0,01
1
16
30
44
58
MiYi (lb-m/lbmol)
14,24
2,40
0,88
0,58
18,1
Lbm
Lbmol
i=1
i=1
T pc = Y iT C P pc = Y iPC
Dnde:
Tc y Pc son la temperatura y presin crticas
Tpc, Ppc, la temperatura y presin pseudocriticas
Yi la fraccin molar
Componen
t
CH4
C2H6
C3H8
Total
% Molar
Yi
Tc ( R )
Pc (Psia)
Yi Tc ( R )
89
8
3
100
O,89
0,08
0,03
1
343
550
666
667
708
615
305,27
44,00
19,98
369,25
Yi Pc
(Psia)
593,63
56,64
18,45
668,72
T pc =369,25 R
P pc =668,72 Psia
5. If the temperature of the gas in the previous example is 80F and the
average gas pressure is 1000 psig, what are the pseudo-reduced
temperature and pseudoreduced pressure of this gas? Use 14.7 psia for
base pressure.
RTA/
Sabiendo que para la mezcla de gases tenemos,
P pc =668,72 Psia
T pc =369,25 R
T =80 F=540 R
P=1000 psig+ 14,4 psi a=1014,7 psia
Entonces,
T
540 R
T pr =
=
=1,46
T pc 369,25 R
P pr=
P 1014,7 PSIa
=
=1,52
P pc 668,67 PSIa
%
Molar
84
10
6
100
Yi
Mi (lb-m/lb-mol)
0,84
0,10
0,06
1
16
30
44
MiYi (lb-m/lbmol)
13,44
3
2,64
19,08
M GAS 19,08
=
=0,66
M AIR
29
%
12
22
T pc =T pc
P pc =
P pcT pc
T pc + B(1B)
P pc =
675348,9
=611,17 psia
380+0,22 ( 10,22 )31,1
P 1014.7 [ psia ]
=
=1.5637
PPc 648.9 [ psia ]
T pr =
T
539.6 R
=
=1.4699
T Pc 367.38 R
Compone
nt
C1
C2
C3
N2
CO2
H2S
Mole
Fraction Yi
0,850
0,004
0,002
0,014
0,010
0,120
(a) Calculate the apparent molecular weight of the gas, gravity, and the
pseudocritical, temperature and pseudo-critical pressure.
(b) Calculate the compressibility factor of the gas at 100F and 1400 psia.
RTA/
Component
Yi
Mi
Tc(R)
Pc(psia)
YiTc (R)
C1
C2
C3
N2
CO2
H2S
Total
0,850
0,004
0,002
0,014
0,010
0,120
12
24
36
28
44
34
343
550
666
227,07
547,54
671,67
667
708
615
491.6
1071
1306
291,55
2,2
1,332
3,179
5,475
80,6
384,336
T pc = Y iT C =384,336 R
i=1
G=
M GAS 15,278
=
=0,527
M AIR
29
(b)
T =100 F=560,67[ R] P=1400 [ psia ]
YiPc
(psia)
566,95
2,832
1,23
6,882
10,71
156
744,604
YiMi
10,2
0,096
0,07
0,392
0,44
4,08
15,278
P pr=
P
1400
T
560,67
=
=1,88T pr =
=
=1,459
PPc 744,6
T Pc 384,34
Z =0.81
10. The gravity of a natural gas mixture is 0.62. Calculate the compressibility
factor of this gas at 1400 psig and a temperature of 80F, using the CNGA
method.
T f =540 R
Usando el mtodo de la CNGA
Z=
[(
1+
3,825
)]
1,7850,62
1400344 400(10)
1
=1+
Z
5403,825
Z =0,821
=1,218