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Abstract
Low salinity waterflooding (LSWF), versus high salinity waterflooding (HSWF) has been the focus of
significant research at various centres around the world, yet there is still considerable debate over the exact
mechanism that provides incremental oil recovery. The use of the LSWF technique is not widespread in
the United Kingdom continental shelf (UKCS). However, it has been announced that the Clair Ridge
development will deploy low salinity waterflooding (LSWF) in secondary mode from the start of field life,
and a number of companies are currently assessing the applicability of the technique through high level
screening and core flooding. Forecasting the potential oil recovery under LSWF is heavily influenced by
the simulation technique that is used. Presently the most widely discussed approach is the use of a
weighting table with relative permeabilities representing the high and low salinity cases. As the grid block
falls below threshold salinity, the simulator utilises the weighting table to assign an interpolated value of
salinity. This value of salinity is utilised to represent a change in wettability. While this approach
approximates the net effect of LSWF, it does not capture the oil/rock/brine interaction. This study
examines the modelling approach to LSWF utilising an in-house generic Forties Palaeocene model in
CMGs STARS simulator. The conventional approach of modelling LSWF using high and low salinity
relative permeabilities is compared to the latest Multi-component Ion Exchange (MIE) methods by
numerical simulation to assess the impact on incremental oil recovery. A sensitivity analysis is then
carried out on the effects of specific parameters on incremental oil recovery, utilising published data from
fields in the Forties Palaeocene fan system. A discussion is provided. The impact on secondary recovery
was accessed with respect to wettability alteration; injection salinity (LSWF versus HSWF); oil viscosity
and aquifer influx. The application of LSWF in secondary mode to the Forties Palaeocene Sandstones was
found to be favourable for the case of mixed-wet reservoirs.
Introduction
Low salinity waterflooding (LSWF) is an enhanced oil recovery (EOR) technique which is of growing
interest, as it represents a low cost and flexible form of EOR. The technique involves the injection of water
at of a significantly lower salinity, compared to the natural salinity of the reservoir connate water. Until
recently, although it was known that the ionic composition of a fluid flowing in a porous medium does
influence the measured permeability (Schleidegger 1974), the manipulation of this effect to improve oil
SPE-170725-MS
recovery by injecting water of a different salinity and ionic composition to that of the natural formation
water, had not been considered. As compared to the normal method of injecting seawater (HSWF), LSWF
is seen as a viable EOR technique. Further, LSWF offers the potential to increase recoverable oil without
the need for re-engineering of the field, as it can use the existing infrastructure and wells, provided that
facilities space exists topsides for installation of a reverse osmosis plant.
The application of the technique in secondary mode is considered to offer a higher potential gain than
in tertiary mode (Jerauld et al 2008). LSWF in secondary mode is considered to be economic for new
fields, with published field studies in other parts of the world suggesting the technique has been successful
(Vledder et al 2010, Mahani et al 2011). To date in the North Sea, no secondary or tertiary offshore
implementation of low salinity EOR has yet been performed, though plans for the Clair Ridge Phase 2
development, using LSWF in secondary mode, are well advanced.
The merits of applying the LSWF technique in tertiary mode are uncertain. Variable recoveries have
been observed in coreflood results and only one limited field trial in the Endicott field has taken place to
date. Given the uncertainty surrounding incremental oil recovery from tertiary mode, combined with the
cost associated with upgrading older platforms and infrastructure, low salinity EOR in tertiary mode has
not yet been piloted in the UKCS.
The simulation work described in this paper is performed on a generic proprietary Senergy model of
the Forties Sandstone loosely based upon the Arbroath field. The main hydrocarbon bearing reservoir is
the Palaeocene Forties sandstone member which is characterised by laterally extensive submarine
low-stand fan deposits. The facies in the static model have been simplified to consist of channel and
over-bank deposits.
The CMG STARS reservoir simulator was chosed for the modeling work, as in addition to relative
permeability interpolation, it has an Ion Exchange model (MIE) to model the ion exchange between
cations in the aqueous phased and those sorbed on the surface of the reservoir rocks. At this time, it was
chosen to perform the work in isothermal mode.
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exchange as the fundamental mechanism resulting from a LSWF. Ionic exchange between the injected
brine and the formation water, leads to the adsorption of divalent ions, promotes mineral dissolution and
changes the ionic composition of the formation water and the state of wettability.
Thus, although it cannot be specifically argued that one single mechanism is responsible for the
increased oil recovery seen subsequent to a LSWF, what is widely agreed is that the result of the
mechanism(s) is an alteration in the wettability of the reservoir towards increased water wetness, leading
to a reduction in Sor, and thus the production of more oil.
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Elsewhere in the North Sea, based on laboratory work and SWCTTs carried out over the last few years,
other fields are now being proposed for LSWF. Statoil have suggested that the Heidrun, Snorre and
Gullfaks fields are all being considered for low salinity pilots (Spangenberg 2008). More recently, the
Varg Field, operated by Talisman (RezaeiDoust, 2010), and the Fry Field, operated by DetNorskOljeselskap (Hadia 2011), have been evaluated for their low salinity potential.
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Table 1High level screening criteria utilised for Forties Palaeocene Sandstone based on Prudhoe Bay/Endicott field
Suitability Indicator
Endicott/Prudhoe Bay
Reference
Forties Formation
Reference
Mixed-wet
Jerauld et al (1997)
Mixed-wet to water-wet
Hughes et al (1990)
Turran et al (2002)
Hughes et al (1990)
Davis et al (2009)
Almond et al (1990)
McGuire et al (2005)
Presence of polar
compounds in the
oil
pH of formation water
less than 7
Presence of soluble
minerals in
formation
Moderate Formation
Salinity
Buckley (1998)
169F
205F
0.09mg KOH/g
Brand et al (1996)
Hughes et al (1990)
Chevron (2013)
BP (2013b)
7 to 8
McGuire et al (2005)
5.6
Mitchell et al (1980)
McGuire et al (2005)
Mitchell et al (1980)
McGuire et al (2005)
55,000ppm (55kg/m3)
Carter et al (2003)
control the wettability shift, neglected the more complex oil/brine/rock reactions. Subsequent studies by
Sorbie and Collins (2010), Wu et al (2009), Omekeh et al (2012) and, most recently, Dang et al (2013),
sought to address the complex geochemical processes in the reservoir.
Dang et al (2013) modelled LSWF behaviour by developing a comprehensive ion exchange model with
geochemical processes including intra-aqueous and mineral reactions, which they coupled to the multiphase, multi-component flow equations in the equation-of-state compositional simulator GEM. They
demonstrated that the new model was able to capture most of the important physical and chemical
phenomena that ensue during a LSWF, in particular, intra-aqueous reactions, mineral dissolution /
precipitation, and wettability alteration. The use of the Ca equivalent fraction as the interpolant was
found to be sufficient to match the experimental coreflood data. The GEM model was validated against
the ion-exchange model of the geochemistry software PHREEQC, and showed strong agreement in ion
evolution. Additional validation was undertaken using the results of low salinity coreflood studies on a
North Sea reservoir, Fjelde et al (2012), and a Texas reservoir (Rivet 2009). In both cases, the new model
was able to generate excellent matches to the effluent ion concentrations, and effluent pH and oil recovery
as measured in the laboratory. From these results, it was deduced that the new model was accurately
capturing the main mechanisms of LSW, providing a robust tool for LSW design and process performance
interpretation in the field.
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Table 2Depth, Initial Pressure, Temperature and Static Properties of the Forties Sandstone Fields (Kunka et al 2003, Hogg 2003, Carter et al
2003)
Field Name
Depth
to
Crest
(feet)
Initial
Pressure
(psia)
Arbroath
Arkwright
Forties
Gannet South
Montrose
Nelson
8030
8500
6660
5,550
8040
7192
3700
3700
3215
2,640
3744
3322
Formation
Age
Porosity
(%)
Palaeocene
Palaeocene
Palaeocene
Palaeocene
Palaeocene
Palaeocene
Permeability
(mD)
Net to
Gross
1 to 4,000
20 to 50
700 to 4,000
200 to 2,400
80 to 2,000
7 to 1,610
0.50
0.78
0.65
0.70
0.50
0.7
24
19
0.27
28
24
23
Table 3Reservoir fluid properties of the Forties Sandstone Fields (from Kunka et al 2003, Hogg 2003, Carter et al 2003)
Field
Name
Arbroath
Arkwright
Forties
Gannet
South
Montrose
Nelson
Petroleum
Saturation
(%)
Oil
Gravity
( API)
Oil Viscosity
(cP)
55
51
85
unknown
38-42
38-42
37
19.6
0.4
0.43
0.76
15.3
55
unknown
40
40.6
0.32
unknown
Gas to
Oil Ratio
(scf/stb)
Oil FVF
(rb/stb)
Formation Water
Salinity (ppm)
1991
2670
1142-1390
1,142
490
700
300
114
1.327
1.456
1.22
1.085
135,000
55,000
55,000
unknown
2348
1550-1699
600
555
1.467
1.357
111,000
84,000
Bubble
Point
(psia)
temperature and static properties for the fields (Table 2). The reservoir fluid properties are similar in terms
of API gravity (Table 3), but vary in terms of other parameters, in particular oil density, oil viscosity, and
formation water salinity.
Wettability
Ion exchange facilitates adsorption/desorption of surface active components, encourages mineral dissolution and leads to an increase in the pH of the formation water, all of which promote a shift in the
SPE-170725-MS
wettability of the rock/water interface. In STARS, the resulting change in the shape and end points of the
relative permeability curves can be modelled using ion exchange as the mechanistic effect. This is
accomplished by combining the relative permeability interpolation keyword, with a sub-keyword which
links the rock-fluid interpolating parameter to variation in a specific component. In this context, the effect
of wettability alteration is modelled by shifting the relative permeability curves from a less water wet to
a more water wet scenario. Multiple relative permeability tables can be defined for a reservoir rock type,
where each table corresponds to one value of a specified interpolant. Typically, two sets of relative
permeability curves representing low salinity and high salinity conditions are considered and an interpolation between these two curves is performed. The interpolation parameter can be the aqueous ion
concentration, the adsorbed ion concentration, the surface active acid component concentration in the oil
phase, or the adsorbed species concentration. Further adjustment to the shape of the curves may be
implemented by use of curvature interpolation parameters which can be defined to correspond to
laboratory results as required by the user.
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Figure 1Location of the fields within the Forties Sandstone of the UKCS (From Hogg et al 2003)
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Figure 2Laterally extensive mudstones (red) represented in the Forties generic reservoir model
10
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Figure 4 Comparison of oil recovery observed for LSWF modeling approach and injection salinity
no maximum flowrate constraint. The Injection wells are set to voidage to balance the production well
withdrawal rates. Although ion exchange properties for the Forties sandstone vary across the fan system
published, constant values for sandstone are utilized in the absence of measured coreflood data.
Modelling approach: comparison of the effect of incorporating ion exchange between the rock
surface and aqueous phase, versus standard relative permeability interpolation on salinity.
Salinity Injection response: benchmark the recovery under low salinity waterflood compared to the
high salinity case.
Oil Viscosity: the oil viscosity is known to effect mobility and therefore recovery under both high
and low salinity waterflood. A comparison for the range of oil viscosities in the Forties sandstone
reservoirs was run.
Aquifer input: the forties sandstone reservoirs are pressure supported by both basal and edge
aquifers. Aquifer influx effects were modelled for cases of both basal and edge scenarios to assess
the impact on LSWF.
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11
Figure 5Comparison of Oil recovery for HSWF and LSWF in the sector model for different oil viscosities
exchange in sandstones were used to run sensitivities to assess the influence on oil recovery (Figure 4).
The difference between the traditional relative permeability interpolation and the use of an ion exchange
model for this case appears relatively small. The difference of 4.8% in recovery factor for the LSWF case
with and without MIE does however confirm that when conducting this type of analysis, the oil/rock/brine
reactions should be considered. The presence of clay will influence the ion exchange capacity of the rock
and should be obtained from laboratory testing. It should be noted that core taken for use in testing may
not be fully representative of the reservoir as a whole.
12
SPE-170725-MS
Figure 6 Comparison of Watercut development for HSWF and LSWF in the sector model for different oil viscosities
facies will limit the potential for oil/brine/rock reactions and specific properties should be utilised when
assessing the actual Forties type field specific potential for LSWF. In this context, the incremental
recovery due to LSWF of 8.1 % in this study is considered low.
Oil Viscosity
Oil viscosity is a key parameter in assessing the potential recovery of a reservoir. The literature of the
Forties sandstone fields (Table 3) identifies the viscosity in the fields as varying in the range of 0.32 cP
to 15.3 cP. The influence of viscosity on the oil recovery is assessed for values of viscosity of 0.32cP,
0.76cP and 15.3cP (Figure 5). As would be expected, it is observed that under HSWF by increasing the
viscosity of oil the oil recovery is reduced. This is to be expected since higher viscosity oil tends to have
a less favourable mobility ratio. The introduction of low salinity water into the reservoir is observed to
increase recovery for all values of viscosity. The change in relative permeability endpoints between
HSWF and LSWF combined with the different oil viscosities leads to different mobility ratios. The
recovery is a function of the relative permeability end points since the viscosity of water is held constant
regardless of salinity. The incremental oil due to LSWF was found to be in the range of 4.2 %, 3.5 % and
2.3 % OOIP for oil viscosities of 0.32 cP, 0.76 cP and 15 cP. The influence of LSWF on watercut behavior
(Figure 6) suggests that utilsing LSWF can reduce the degree of water breakthrough in secondary mode.
The stepped nature of the plot is influenced by the facies in the Forties sandstone model. Initially, the
channel facies water out for the HSWF cases with later contributions to flow coming from the overbank
deposits. When LSWF is utilised in secondary mode the injected fluid enters the reservoir displacing the
oil and connate water bank ahead of the LSWF. The effect of the LSWF is to create a net wettability shift
which reduces residual oil saturation which leads to a slower development of watercut as more oil is
mobilised towards the producer.
SPE-170725-MS
13
Aquifer Influx
The Forties sandstone reservoirs are pressure supported from a large regional aquifer for which the influx
terms will vary according to the specific field, as the fields within the Forties fan system are supported
by different aquifer configurations. The Forties (Wills et al. 1991) and Nelson fields (Kunka et al. 2003)
are supported by basal aquifers. The Arbroath field contains oil bearing sandstones which have a
mudstone layer at their base (Crawford et al 1991) and can be considered to be edge aquifer supported.
Sensitivities were run to assess the effect of edge and basal water drives on oil recovery. Scenarios
representing a basal aquifer plus LSWF and an edge aquifer plus LSWF, were compared to the base case
LSWF.
There is a positive response in oil recovery, ( 4% incremental recovery), to the presence of the
aquifer, but the results are inconclusive, with both edge and basal aquifer support resulting in similar
recoveries. Potential dilution effects on the LSWF due to the higher salinity aquifer influx are masked.
Possible reasons for this include the small sector scale of the model, in which the injectors are located
close to the OWC, and both producers and injectors are preferentially located in the channelized facies,
which limits the ability of the aquifer to dilute the LSWF significantly and thus adversely impact oil
recovery. Further work is required in this area.
Conclusions
It has been demonstrated that the incorporation of ionic exchange into the modeling process, versus
relative permeability interpolation on salinity alone, impacts the modeled oil recovery. It is concluded that
this is a more physical representation of the reservoir processes during a LSWF.
Based upon this modeling technique, the following conclusions could be drawn from this high level
screening and simulation study of the Forties Generic Sandstone Reservoir Model:
The properties of the Forties sandstone reservoirs are analogous to the Endicott/Prudhoe bay
reservoirs in terms of initial wettability, Kaolinite clay content, reservoir temperature, acid number
14
SPE-170725-MS
and the presence of soluble minerals in the formation. As such, the Forties reservoirs could be well
suited for low salinity waterflooding.
A generic model of the Forties sandstone based on the geology of the fan system consisting of
channels and overbanks was utilised. Conservative relative permeability data was assigned to both
the channels and overbanks to represent the differences in facies response. The relative permeability curves influenced the recoverable oil from both the HSWF and LSWF cases. In the absence
of measured ion exchange data for the Forties sandstone reservoirs, generic values were assigned
in STARS. The ion exchange capacity influences the oil/rock/brine reactions in the reservoir and
as such the low increase in incremental recovery is attributed to the parameters selected., The ion
exchange reactions will be specific to the sandstones of specific reservoirs within the Forties
Sandstone and should be sought before simulating the effects.
The oil recovery was found to be dependent upon viscosity which is consistent with expected
behaviour under high salinity waterflooding (HSWF). The LSWF application was found to be
beneficial in all cases with an incremental increase in recovery of 4.2 to 2.3 % for oil viscosities
of 0.32 cP to 15.3 cP.
The effect of aquifer influx was assessed to compare basal and edge aquifer effects. For the
specific case of the Drumoak model in STARS the type of aquifer was found to have a small effect.
The placement of the injection wells at the OWC, and the location of the injection/production wells
in the channel facies is thought to limit the potential aquifer influx.
the Forties sandstone reservoirs to assess the differences in recovery when modeling
utilising the ion exchange and relative permeability options.
The effect of aquifer influx should be to reduce the dilution effect of the low salinity
waterflooding. The degree of dilution will be affected by model size, aquifer influx
and the salinity of the reservoir initially. Further study should be undertaken to
consider these parameters at a larger scale.
Additional low salinity functionality associated with geochemical processes such as
intra-aqueous and mineral reactions, should be accessed using a simulator with a
full Geochemical reaction model as well as Ion Exchange Model, such as the CMG
GEM simulator.
The existing work was performed under isothermal conditions. It is recommended
that further work should look at the impact of temperature dependency on the LSWF
process.
Acknowledgements
The authors wish to acknowledge the assistance given by both LR Senergy and CMG in assisting in the
preparation of this paper.
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