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Abstract
The alarming increase of incidence of skin cancer has hastened development of ultraviolet (UV) protective clothing and
research on UV protection of apparel. Although various fabric parameters that affect ultraviolet radiation (UVR) transmission were studied by researches, most of them focused on woven fabrics and chemical approach in enhancing UV
protection. There were few studies concerning knitted fabrics, in particular the influence of fabric constructions on
ultraviolet protection factor (UPF) and structural properties. The magnitude of transmission and scattering of UVR
through a fabric is decided by fabric construction or knit structure, which is classified by geometrical arrangement of
yarns and fibers of the fabric. This paper aimed at studying the influence of different knit structures upon the UPF with
the three main knit stitches incorporated in the knitted fabric constructions, namely the knit, tuck and miss stitches. The
UPF and structural characteristics, including thickness, weight, stitch density and porosity of greige and bleached knitted
fabrics with different knit structures, are compared by adopting factorial analysis of variance. The results show that
fabrics with miss stitches possess a higher UPF than fabrics with tuck stitches. The double-knitted fabrics have better UV
protection than the single-knitted fabrics overall, but bleaching has different impacts on the UPF of single- and doubleknitted fabrics. The study reveals that fabric thickness or weight cannot be used solely in explaining the UV protective
performance of knitted fabrics. However, fabric porosity can be a good indicator for UV protection when comparing
fabrics with similar fabric weight and thickness but different structures or fiber contents.
Keywords
Ultraviolet protection factor, knit structures, weight, thickness, stitch density, porosity
Evidences were found globally that there is an increasing number of people dying from skin cancer each year
and it is apparent that over-exposure to ultraviolet radiation (UVR) is deemed to be one of the main reasons.1
Skin cancers are very common in the UK, with more
than 70,000 new cases diagnosed each year.2 In the US,
skin cancer is the most common cancer, which accounts
for nearly half of all cancer types with more than
2 million cases found each year.3 Skin cancer is also
the most common cancer type in Canada, which
accounts for an estimated one-third of all new cases
of cancer and its incidence rate continues to rise.4
Australia has the highest incidences of skin cancer in
the world which is almost four times the rates in the
UK, the US and Canada. Skin cancers account for 80%
of all newly diagnosed cancers in Australia and two in
1
Institute of Textiles and Clothing, The Hong Kong Polytechnic
University, Hong Kong
2
School of Chemistry, University of New South Wales, Australia
Corresponding author:
Jimmy Kwok-Cheong Lam, Institute of Textiles and Clothing, The
Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong.
Email: tclamj@inet.polyu.edu.hk
684
Experimental details
Materials
In this study, 10 fabric constructions were examined
wherein four structures are single-knitted fabrics and
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Figure 1. Basic knit stitches viewed from the fabric face: (a) knit stitch; (b) tuck stitch; (c) miss stitch.
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Test methods
Assessment of ultraviolet protection factor
The UV protective ability of fabrics is commonly
expressed in terms of UPF. The UPF of fabric specimens was measured using a Cary 300 Conc ultravioletvisible (UV-Vis) spectrophotometer equipped with an
integrating sphere and a Schott UG lter for minimizing any measurement error caused by uorescence.
UPF measurement was conducted corresponding to
the Australian/New Zealand Standard AS/NZS
4399:1996.35 Fabric specimens were evaluated in a
dry, at and tensionless state with measurements
taken in both machine and cross-machine directions
of the fabric. All fabric specimens were conditioned
under standard environment for 24 hours prior to
assessment.36 The transmittance over a wavelength
range of 290400 nm with 5 nm intervals was measured
using the spectrophotometer for calculating the UPF of
fabric specimens using Equation (1):37,38
P400 nm
Eeff
nm E S
UPF 0 P400 290
nm
E
290 nm E S T
Porosity
Previous studies found that porosity is an important
indicator for UV protection performance of a
fabric.8,4145 When UVR strikes the fabric, it can be
reected, absorbed by ber, scattered within the
fabric layer and transmitted through bers and fabric
pores.18 The incident radiation passing through fabric
is largely dependent on the percentage of volume within
a fabric in which there is no ber in that volume from
the fabric face to back.46 Therefore, the threedimensional nature of fabrics with various knit structures can be investigated by considering the fabric porosity instead of either fabric thickness or fabric weight
only. The more porous structure of the fabric will result
in a higher porosity, while a tighter structure gives a
lower porosity. Knitted fabrics usually have a higher
porosity than woven fabrics.47 Various methods of
determining the porosity of porous materials were
rstly developed in the eld of petroleum technology,
wherein the gravimetric method has been applied to
fabrics.44 Porosity can be dened as the proportion of
void space within the boundaries of a solid material,
compared to its total volume; in other words, it is the
fraction of void space in a porous medium.4749
Porosity is usually expressed in percentage (%); the calculation is shown in Equation (2):
t
Porosity 100 1
m
t
M
V
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687
The volume of the unit area of fabric is simply equivalent to the geometrical fabric thickness, t, and therefore
calculation of bulk density can be summarized as
Equation (4):51
Bulk Density g=cm3
Mg=cm2
tcm
Analysis
In order to systematically study the impact of knit
structures and bleaching on the UV protective
Figure 3. Micrographs of greige and bleached single-knitted cotton fabrics at gauge length 14 G: (a) all knit; (b) knit & tuck; (c) knit &
miss (25%); (d) knit & miss (50%).
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Figure 4. Micrographs of greige and bleached double-knitted cotton fabrics at gauge length 14 G: (a) 1 1 rib; (b) half cardigan;
(c) full cardigan; (d) half Milano; (e) full Milano; (f) interlock.
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Figure 5. Ultraviolet protection factor (UPF) of greige and bleached, single- and double-knitted cotton fabrics at gauge length 14 G
(with error bars): (a) UPF of single-knitted fabrics; (b) UPF of double-knitted fabrics.
Figure 6. Thickness of greige and bleached, single- and double-knitted cotton fabrics at gauge length 14 G (with error bars):
(a) thickness of single-knitted fabrics; (b) thickness of double-knitted fabrics.
miss (50%) has more miss stitches than the knit & miss
(25%) as well as higher UPF. The micrographs shown
in Figure 3(c) and (d) provide a comparison between
these two structures with a higher number of wales per
unit length in the knit & miss (50%) than that in the
knit & miss (25%) for both greige and bleached stages.
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691
Figure 7. Fabric weight of greige and bleached, single- and double-knitted cotton fabrics at gauge length 14 G (with error bars):
(a) fabric weight of single-knitted fabrics; (b) fabric weight of double-knitted fabrics.
Figure 8. Fabric stitch density of greige and bleached, single- and double-knitted cotton fabrics at gauge length 14 G (with error
bars): (a) stitch density of single-knitted fabrics; (b) stitch density of double-knitted fabrics.
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Figure 9. Porosity of greige and bleached, single- and double-knitted cotton fabrics at gauge length 14G (with error bars):
(a) porosity of single-knitted fabrics; (b) porosity of double-knitted fabrics.
Table 1. Summarized results of the two-way between-groups analysis of variance (ANOVA) for ultraviolet protection factor (UPF)
and structural parameters of fabric specimens
Single-knitted fabrics
Dependent variables
UPF
Fabric thickness
Fabric weight
Stitch density
Calculated Porosity
Double-knitted fabrics
Independent
variables
F test
p-value
Partial eta
square
F test
p-value
Partial
eta square
Structures
Bleaching
Interaction
Structures
Bleaching
Interaction
Structures
Bleaching
Interaction
Structures
Bleaching
Interaction
Structures
Bleaching
Interaction
F3,16 79.824
F1,16 51.705
F3,16 23.346
F3,16 173.333
F1,16 3640.474
F3,16 26.298
F3,16 128.228
F1,16 2701.279
F3,16 15.053
F3,16 308.314
F1,16 425.658
F3,16 9.747
F3,16 45.958
F1,16 0.292
F3,16 7.423
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.000
0.596
0.002
0.937
0.764
0.814
0.970
0.996
0.831
0.960
0.994
0.738
0.983
0.964
0.646
0.896
0.018
0.582
F5,24 5.348
F1,24 516.202
F5,24 21.325
F5,24 76.091
F1,24 1464.266
F5,24 32.596
F5,24 473.943
F1,24 1225.925
F5,24 269.254
F5,24 448.017
F1,24 77.63
F5,24 14.214
F5,24 91.179
F1,24 87.908
F5,24 24.843
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.527
0.956
0.816
0.941
0.984
0.872
0.990
0.981
0.982
0.989
0.764
0.748
0.950
0.786
0.838
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Table 2. Pearson correlation coefficients (r) between the ultraviolet protection factor (UPF) and the structural
parameters of fabric specimens
Single-knitted fabrics
Structural parameters
Fabric thickness
Fabric weight
Stitch density
Calculated Porosity
Greige
Double-knitted fabrics
Bleached
NS
0.298
0.702a
0.813a
0.896a
0.821
0.949a
0.142NS
0.246NS
The correlation with the UPF is significant at the 0.05 confidence level.
The correlation with the UPF is not significant at the 0.05 confidence level.
NS
Greige
Bleached
NS
0.416
0.242NS
0.044NS
0.546a
0.600a
0.958a
0.713a
0.812a
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fabrics, although there is an interaction between bleaching and the single-knit structure (F3,16 7.423,
p 0.05). The eect size of knit structure (partial eta
squared 0.896) is greater than that of bleaching (partial eta squared 0.018) and also the interaction
between knit structures and bleaching (partial eta
squared 0.582). There are insignicant increases in
porosity for the single-knitted fabrics after bleaching
that are contrary to the previous structural parameters
studied (t11 0.34, p 0.737, two-tailed), as shown in
Figure 9(a). Although there are signicant changes in
fabric thickness and fabric weight for the single-knitted
fabrics, porosity has less variation after bleaching
because the shrinkage of fabrics in scouring and bleaching caused increase in fabric weight and thickness
simultaneously.
The results of the post-hoc test indicate that the greige
knit & tuck (Mean 89.35, SD 0.11) and greige knit &
miss (25%) (Mean 86.97, SD 0.32) have the largest
dierence in porosity, as well as the bleached knit & tuck
(Mean 88.42, SD 0.12) and bleached knit & miss
(25%) (Mean 87.29, SD 0.30). The porosities
among the other three structures, all knit, knit & miss
(25%) and knit & miss (50%), are not signicantly different from each other in both greige and bleached
stages. The bleached and greige knit & tuck have
higher porosities than the other three single-knit structures because the presence of tuck stitches increases the
porosity of fabric due to the unique formation of a tuck
loop. Since a tuck stitch is formed when a needle takes a
new loop without clearing the previously formed loop
(held loop), the held loop together with the loop that
joins (tuck loop) are accumulated on the needles and
eventually give a bulkier structure to fabrics with more
void space within the fabric layer. Although the four
single-knit structures have quite similar fabric thickness
and weight, they dier in stitch density and porosity
because of their distinct fabric structures. A fabric with
higher porosity represents its fabric structure, encompassing more void spaces or fabric pores; in other
words, it is a rather porous structure. The knit & tuck
structure is obviously more porous than the other three
single-knit structures, as shown in Figure 4, and also
reects the result of lower stitch density, even resembling
the fabric weight and thickness. Fabric porosity is a key
factor for UVR transmission, as the incident light can
pass through the fabric pore directly.42 Therefore, the
knit & tuck fabric provides more void spaces for the
transmission of UVR through the fabric, resulting in a
lower UPF than other single-knit structures.
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Conclusions
The UPFs are statistically dierent among various
fabric constructions with knit, tuck and miss stitches.
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Acknowledgement
The authors would like to thank Prof. Ron Postle of the
University of New South Wales for his help and advice on
this research.
References
1. Ultraviolet radiation and human health. http://
www.who.int/mediacentre/factsheets/fs305/en/index.html
(2009, accessed 10 May 2011).
2. Malignant Melanoma UK report. http://publications.cancerresearchuk.org/downloads/product/
cs_pdf_melanoma_jan_2006.pdf (2006, accessed 21 July
2011).
3. Skin Cancer Facts. http://www.cancer.org/Cancer/
CancerCauses/SunandUVExposure/skin-cancer-facts
(2010, accessed 20 June 2011).
4. Skin Cancer-Sunlight and Exposure. http://www.hcsc.gc.ca/hl-vs/sun-sol/expos/skin-cancer-peau-eng.php
(2009, accessed 21 July 2011).
5. Skin cancer facts and figures. http://www.cancer.org.au/
cancersmartlifestyle/SunSmart/Skincancerfactsandfigures.
htm (2011, accessed 13 May 2011).
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