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UNIT I
PN JUNCTION DEVICES

1. PN JUNCTION DIODE STRUCTURE


Classification of Materials:
Materials are classified into conductors, semiconductors, and insulators, which are
categorized as such by using energy band concept. It is the width of the forbidden
band (as shown in the figure below) that determines whether a material is an
insulator, a semiconductor or a conductor.
A conductor has no forbidden band or energy gap(It is equal to the difference of
energy levels between the conduction band & valence band) and the valence and
conduction bands overlap (e.g., copper, aluminium).
A semiconductor has a medium width forbidden band (e.g., germanium, silicon).
An
insulator
has a wide forbidden (e.g.,
plastic,
carbon).

Semiconductors are mainly classified into two categories: Intrinsic and Extrinsic.
Intrinsic semiconductor:
An intrinsic semiconductor material is chemically very pure and possesses poor
conductivity. It has equal numbers of negative carriers (electrons) and positive carriers
(holes).
Extrinsic semiconductor:
Intrinsic (or purity) semiconductor by itself is of little significance as it has little current
conduction capability at ordinary room temperature. However, the electrical conductivity
of intrinsic semiconductor can be increased many times by adding very small amount of
impurity (of the order of ne atom per million atoms of the pure semiconductor) to it in
the process of crystallization. This process is called doping and the doped material is
called the extrinsic semiconductor.
Germanium and silicon are tetravalent. So the impurity may be either pentavalent
(antimony, arsenic, phosphorous) or trivalent (boron, aluminium, gallium). Accordingly
the impurity introduced may be of two types viz (i) donor type (pentavalent) or n-type
and (ii) acceptor type (trivalent) or p-type.
Depending on the type of impurity added, the extrinsic conductors can be divided into
two classes namely,
(i) n-type semiconductors (electrons are majority carriers) and
(ii) p-type semiconductors (holes are majority carriers)
N-Type Semiconductor

Germanium (Ge) has 4 valence electrons and antimony (Sb) has 5 valence electrons as
shown in fig(a). Each antimony atom forms covalent bond with surrounding 4
germanium atoms.
Thus four valence electrons of antimony atom form covalent bond with four valence
electrons of individual germanium atom and fifth electron is left free which is loosely
bound to the antimony atom.
This loosely bound electron can be easily excited from valence band to conduction
band by the application of electric field.
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Thus every pentavalent impurity (Sb) atom donates one electron for conduction, this
atom becomes positively charged ion

Conduction in N-Type Semiconductor:


When the voltage is applied to N-type semiconductor, the electrons flow out of the
negative terminal, through the circuit and into the positive terminal of the source as
shown in fig. This constitutes a current flow. Thus the conduction is predominantly by
electrons. The holes are less in number hence the electron current is dominant over
the hole current
P-Type Semiconductor

Germanium (Ge) has 4 valence electrons and antimony (B) has 3 valence electrons as
shown in fig(a).
Each boron atom forms covalent bond with surrounding 4 germanium atoms.
Thus three valence electrons of boron atom form covalent bond with four valence
electrons of
individual germanium atom leaving one bond incomplete which gives rise to a hole.
Trivalent impurities (B) are called acceptor impurity because it accepts free electrons in
the place of
holes.
Thus every trivalent impurity (B) atom donates one hole for conduction, this atom
becomes negatively
charged ion.
Conduction in P-type Semiconductor:

When the voltage is applied to P-type semiconductor, the holes flow out of the
positive terminal, through the circuit and into the negative terminal of the source as
shown in fig. This constitutes a current flow. Thus the conduction is predominantly by
holes. The electrons are less in number hence the hole current is dominant over the
electron current.
Mass Action Law:
It states that under the thermal equilibrium for any semiconductor the product of
number of electrons & number of holes is constant & it is independent of donor &
acceptor impurities.
Drift current:
When a voltage is applied to a semiconductor, the free electrons try to move in a
straight line towards
the positive terminal of the battery.
The electrons, moving towards positive terminal collide with the atoms of
semiconductor and

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connecting wires, along its way. Each time the electron strikes an atom, it rebounds in
a random
direction.
But still the applied voltage
make
the
electrons
drift
towards the positive terminal.
This drift causes
current to flow in a
semiconductor,
under
the
influence
of
the
applied
voltage.
This current produced due to drifting of free electrons is called drift current and the
velocity with which
electrons drift is called drift velocity.
Thus drift current means the flow of current due to bouncing of electrons from one
atom to another,
travelling from negative terminal to positive terminal of the applied voltage. This is
shown in fig.

Diffusion current:
This is the current which is due to the transport of charges occurring because of nonuniform
Concentration of charged particles in a semiconductor.
Consider a piece of semiconductor which is non-uniformly doped. Due to such nonuniform doping, one type of charge carriers occurs at one end of a piece of
semiconductor.
The charge carriers are either electrons or holes, of one type depending upon the
impurity used.
They have the same polarity and hence experience a force of repulsion between them.
The result is that there is a tendency of the charge carriers to move gradually i.e. to
diffuse from the
region of high carrier density to the low carrier density. This process is called diffusion.
This movement of charge carriers under the process of diffusion constitutes a current
called diffusion
current. This is shown in the Fig.
The diffusion current continues till all the carriers are evenly distributed throughout the
material.
A diffusion current is possible only in case of non uniformly doped semiconductors while
drift current
is possible in semiconductors as well as conductors
(It is possible for an electric current to flow in the semiconductor, even in the absence
of the applied
voltage provided the concentration gradient exists in the material).
Mobility (
Mobility

Where,

:
is defined as the ratio of the drift velocity to the electric field.

-Drift velocity; -applied electric field. It is expressed in

Current density:

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The current density J is current per unit cross-sectional area hence,

J=

Where, I- current; A- area of cross section;


J=

where I=

where, N- no.of electrons passing through the area A in time T. q- Charge of an electron;
J=

where T=

L- length in meter;

drift velocity

J= nq where
w.k.t
J= nq

---(1)

The current density is related to an electric field E by Ohm's law as


J=

---(2)

where
comparing equns (1) and (2),

Resistivity,
Drift Current Density of a Semiconductor:
The current density is related to an electric field E by Ohm's law as,
J=

where

=n

The mobility of free electrons is denoted as

which is different than the mobility of

holes which is denoted as


Thus the drift current density for free electrons is given by,
=n

qE

.(1)

While the drift current density for holes is given by,


=p

qE

Thus the total drift current density of a semiconductor is given by,


J=

qE

... (2)

Diffusion Current Density:


The diffusion observed non-uniformly semiconductors. Consider a p-type semiconductor
bar which is non-uniformly doped, along its length, in the direction of 'x' as shown in the
Fig.

Let p be the concentration of holes but it is not constant but changing with respect to x
due to non-uniform doping. At x = 0, p = p(0)and is maximum.
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As x increases, the concentration of holes decreases, as shown in the Fig. (b).


The slope of the graph is the ratio of change in concentration to the change in distance
which is called concentration gradient.
Slope of graph = Concentration gradient =
Due to such concentration gradient, holes move from high concentration area towards
lower concentration area hence diffusion current flows.
The diffusion current density is proportional to the concentration gradient.
For p type bar,
where

=Diffusion current density due to holes

=q
where Dp =Diffusion constant for holes in m2/sec.
The slope

is negative hence

for holes is negative. But current due to holes is in the

direction of conventional current which is treated positive. Hence to get total positive
sign, a negative sign is used for
=

i.e. diffusion current density for holes.

While diffusion current density due to electrons is expressed as,


=q
where

= Diffusion constant for electrons in m2/sec

Total Current Density due to Drift and Diffusion


The drift current density for electrons and holes can be expressed as,
=n

q E and

=p

qE

The diffusion current density for electrons and holes can be expressed as,
=

and

=q

Total current density due to the electrons is,


=n

qE+q

Total current density due to the holes is,


=p

qE

Thus the total current density is =


Einstein Relationship for Semiconductor:
It defines the relationship between mobility & diffusion coefficients of a particular
type of charge carriers in the same semiconductor.
K-Boltzmanns constant, T-Temperature, q-charge, D-Diffusion coefficient,

-Mobility

Intrinsic concentration and conductivity of semiconductor:


In an intrinsic semiconductor, at any temperature at any instant, the free electrons and
holes are present in equal numbers. This concentration is called intrinsic concentration
denoted as
n=p=

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Using n=p=

Subject Code/Name: EC6202/Electronics

in conductivity of a semiconductor we get the expression for the

conductivity of intrinsic semiconductor denoted as

q ;

Frm the basic equation of conductivity, the conductivity of n-type material can be
expressed as,
q
Let,

= concentration of free electrons in n- type

= concentration of holes in n- type


But

as holes are in minority hence,

Frm the basic equation of conductivity, the conductivity of p-type material can be
expressed as,
q
Let,

= concentration of free electrons in p- type

= concentration of holes in p- type


But

as holes are in minority hence,

2.OPERATION AND V-I CHARACTERISTICS

In a piece of semiconductor material, if one half is doped by P-type impurity and the
other half is doped
N-type impurity, a PN junction diode(anode, cathode)
is formed as shown in fig. The plane dividing the
two halves or zones is called PN junction.
Formation of Depletion region and barrier
potential(and sketches for charge density, electric
field intensity and potential energy barriers at the
junction )
As shown in fig , during unbiased condition, At the PN
junction
there is a tendency for the free electrons to diffuse
over to the Pside and holes to the N-side.
As the free electrons move across the junction from N-type to Ptype, the donor ions becomes positively charged. Hence a net
positive charge is built on the N-side of the junction
The free electrons that cross the junction uncover the negative
acceptor ions by filling in the holes. Therefore a net negative
charge is established on the P-side of the junction
The region, in which the net negative charge and the net
positive charge are present, is called depletion region.
The net negative charge and positive charge, setup the barrier
near the junction which prevent the
further movement of
charge carriers.
As a consequence of the induced electric field(E) across the
depletion region, an electrostatic potential difference is
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established between p and N regions, which is called the


barrier potential(V0) or contact potential
The electrostatic field across the junction caused by the
positively charged N-type region tends to drive the holes away
from the junction and negatively charged P-type region tends to
drive the electrons away from the junction.
The majority holes diffusing out of the P-region leave behind
negatively charged acceptor atoms bund to the lattice, thus
exposing negative space charge in a previously neutral region.
Similarly, electrons diffusing from the n region expose
positively ionised donor atoms and space charge region builds
up at the junction shown in fig(a) and
(c)
The space charge layers are of opposite sign to the majority
carriers diffusing into, which tends to reduce the diffusion rate.
Thus the double space of the layer causes an electric field to be
set up across the junction directed from N to P regions, which is
in such a direction to inhibit diffusion no of majority electrons
and holes, as illustrated in fig (d)
In order to make the flow of charge carriers across the junction,
the external voltage, greater than the barrier potential, is
applied.
The process of connecting external voltage source is called bias.

Forward bias

Positive terminal of the battery is connected to the P-region of the diode & negative
terminal of the
battery is connected to N-region of the diode (as shown in fig). This type of connection
is called Forward
bias.
The holes move towards the junction, as the positive terminal of the battery is
connected to P side
The electrons move towards the junction, as the negative terminal of the battery is
connected to N side
The above type of movement of the holes and electrons towards the junction reduces
the width, the
width of depletion layer which we get with no voltage.
As the voltage is increased (for a voltage > 0), the
width of depletion is further decreased.
When the applied voltage exceeds the barrier
potential, then the depletion region will disappear and
large number of majority charge carriers can cross
the junction. So the conduction takes place in the
diode. It causes forward current.
Reverse Bias

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Positive terminal of the battery is connected to the N-region of the diode & negative
terminal of the battery is connected to P-region of the diode (as shown in fig). This type
of connection is called Reverse bias.
Since the positive of battery is connected to N side, it attracts the holes, so that the
holes move towards the positive of battery .The negative of battery is connected to P
side, it attracts the electrons, so that the electrons move towards the negative of battery.
This increases the width of depletion layer.
As reverse voltage increased, the width of depletion is further increased. It prevents the
flow of charge carriers across the junction.
But the minority charge carriers i.e., electrons in p side and holes in N- side which
constitute a small amount (

of current (reverse saturation current(I0))

If the reverse voltage is increased beyond particular value, large amount of reverse
current flows. This leads to the breakdown of the PN junction.
V-I Characteristics:
Fig. shows the characteristic curve (relationship between voltage and current) for the
forward and reverse bias of the PN junction diode.

(i) In forward bias: as VF increases the current is almost zero till it reaches a value, which
is called
threshold voltage (VTH)
(ii) beyond the threshold voltage, current increases as voltage increases as shown in the
Fig. the value of
the threshold voltage will always be equal to barrier potential of the material (V0).
Forward resistance of diode:
The resistance offered by the p-n junction diode in forward biased condition is called
forward resistance, the forward resistance is defined in two ways,
1. Static forward resistance: this is the forward resistance of p-n junction diode when p-n
junction is used in d.c circuit and the applied forward voltage is d.c.this resistance is
denoted as

and is calculated at a particular point on the forward characteristics.


=

Dynamic forward resistance: the resistance offered by the p-n junction under a.c
conditions is called
dynamic resistance denoted as

In reverse bias:
(i) as voltage is increased the width of the depletion layer increases and it prevents the
flow of charge
carriers across the junction,
(ii) Theoretically no current should flow. But in practice, a very small current
(reverse saturation current, I0) flows as shown in Fig,
(iii)For large applied reverse bias: the free electrons (from the N-type, moving towards
the positive
terminal of the battery) acquire sufficient energy to dislodge valence electrons from
semiconductor
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atoms (in the crystal).


(iv)Thus a large number of free electrons are formed which is commonly called as an
avalanche of free
electrons. This leads to the breakdown of the junction leading to very large reverse
current.
(v)The reverse voltage at which the junction breakdown occurs is known as breakdown
voltage (VBD).
The breakdown voltage depends upon the amount of doping. If the diode is heavily
doped, depletion
layer will be thin & consequently breakdown occurs at lower reverse voltage(V z ).
Reverse resistance of diode
The p-n junctuion offers large resistance in the reverse biased condition called reverse
resistance. This is also defined in two ways,
1. Reverse static resistance: this is reverse resistance under d.c conditions, denoted as
. It is the ratio of
applied reverse voltage to the reverse saturation current
=
2. Reverse dynamic resistance: this is the reverse resistance under the a.c conditions,
denoted as

. It is

the ratio of incrementa change in the reverse voltage applied to the corresponding
change in the
reverse current.
=

Breakdown Mechanism
The diode breakdown may occur in 2 methods.

Zener breakdown

Avalanche breakdown

Zener breakdown
When a PN junction is heavily doped the depletion layer is very narrow.
So under reverse bias condition, the electric field across depletion layer is very intense.
WKT, Electric field = voltage per distance. Due to narrow depletion layer and high
reverse bias
voltage it is intense.
Such an intense electric field breaks the covalent bonds of the crystal structure. and
generates large
number of free electrons. Such a creation free electrons is called Zener effect.
These charge carriers constitute very large current and it
breaks the junction. This mechanism is called
Zener breakdown. Zener break down occurs during 5V to
6V.
Avalanche breakdown
It is the process of avalanche(carrier) multiplication.
In reverse biased diode, as reverse voltage increased, the
minority
charge carriers increasingly accelerate. These accelerated charge
carriers breaks the covalent bonds of the crystal structure.
If the applied voltage is increased, the velocity and the kinetic energy
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of electron increases.Such electrons breaks the co-valant bonds. Thus


one by collision create an an electron hole pair as shown in fig.
These secondary particles also accelerated by high reverse bias and
participate in collisions that generates
electron-hole pairs. This
phenomenon is known as carrier multiplication.
These Electron hole pairs are generated quickly and in large number and this constitute
very large
current and it breaks the junction. this mechanism is is called avalanche breakdown.
Avalanche break down occurs above 6V.
Comparison of zener breakdown and avalanche breakdown:
S.N
o
1

zener breakdown

avalanche breakdown

Both sides of PN junction are heavily Both sides of PN junction


doped
doped
Depletion layer is narrow
Depletion layer is large

A strong electric field is produced

are lightly

Electric field is not so strong

Large number of holes and electrons Electron hole pairs are generated
are produced
5
Zener current is independent of Charge carriers acquire energy from the
applied voltage
applied potential
Applications of PN Junction diode:
Used as:
a) a Rectifier in power supplies
b) a Switch in digital logic circuit
c) Clamping networks
d) Clipping circuits
e) Demodulation circuits
Energy band structure of PN junction in open circuit

PN junction has p-type and n-type materials in close physical contact at the junction on
an atomic scale. The energy band diagrams of these two regions undergo relative shift
to equalise the Fermi level.
The Fermi level
distribution of
Fermi level

should be constant throughout the specimen at equilibrium. The


or holes is dependent on the position of the Fermi level.

is closer to the conduction band edge

to the valence band edge


Conduction band edge

in the n-type while it is closer

in the p-type.
is higher than the conduction band edge

. Similarly

higher than
w.k.t,

The barrier potential is given as,

,
10

(1)

Total shift in Fermi level.

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From the fig,

,
Shift in Fermi level from intrinsic semiconductor to p-type.
Shift in Fermi level from intrinsic semiconductor to n-type.

Add equ (2) & (3)

Since
W.K.T,
(Mass Action Law)

Taking natural logarithm on both sides,

Fermi level for n-type material:

Fermi level for P-type material:

Sub

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Boltzman constant

PN Diode Currents:
It is indicated earlier that when a p-n junction diode is forward biased a large forward
current flows, which is mainly due to majority carriers. The depletion region near the
junction is very small, under forward biased condition.
In forward biased condition holes get diffused into n-side from p-side while electrons
get diffused into p-side from n side.
So on p-side, the current carried by electrons which is diffusion current due to minority
carriers, decreases exponentially with respect to distance measured from the junction.
This current due to electrons, on p-side which are minority carriers is denoted as
Similarly holes from p-side diffuse into n-side carry current which decreases
exponentially with respect to distance measured from the junction. This current due to
holes on n-side, which are minority carriers is denoted as
If distance is denoted by x then,
(x) = Current due to electrons in p-side as a function of x
(x) = Current due to holes in n-side as a function of x

At the junction i.e. at x = 0, electrons crossing from n-side to p-side constitute a


current,

(0) in the same direction as holes crossing the junction from p-side to . n-

side constitute a current,

Hence the current at the junction is the total conventional current I flowing
through the circuit.
I=

(0).

Now

(0) +

(0)

(x) decreases on n-side as we move away from junction on n-side. Similarly

(x) decreases on p-side as we move away from junction on p-side.

But as the entire circuit is a series circuit, the total current must be maintained at I,
independent of x.
This indicates that on p-side there exists one more current component which is due to
holes on p-side which are the majority carriers. It is denoted by

(x) and the addition

of the two currents on p-side is total current I.


(x)= Current due to holes in p-side.

Similarly on n-side, there exists one more current component which is due to electrons
on n-side, which are the majority carriers. It is denoted as
the two currents on n-side is total current I.
(x) = Current due to electrons in n-side.
On p-side I =

(x) +

(x)

On n-side I =

(x) +

(x)
12

(x) and the addition of

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These current components are plotted as a function of distance in the Fig.

The current
becomes

decrease towards the junction, at the junction enters the n side and
which further decreases exponentially.

Similarly the current


side and becomes

decrease towards the junction, at the junction enters the pwhich also further decreases exponentially.

Derivation of Current equation for PN junction diode:


In the case of a forward biased PN junction diode: When a voltage V is applied, as the
distance increases from the junction, the concentration decreases exponentially (as
shown in fig).

The total current, I, in a diode is the sum of the hole current and electron current:
I=

(1)

We know that, the diffusion hole current in N-side, at x,


Aq

(2)

- Diffusion constant of hole


area of cross section
charge of a hole
- hole concentration at any distance, x, from the junction
as seen in the Fig:
=

(3)

- Hole concentration at thermal equilibrium,


- Excess hole concentration, at a distance x from the junction.
(4)
- Excess hole concentration at the junction (as seen in Fig.),

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[=

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(5)

- Total hole concentration at the junction


- Diffusion length of holes.
Eqn.(4) in Eqn.(3):
=

(6)

Differentiating Eqn.(6) w.r.t x:


=

(7)
(as seen in Fig.)

Eqn.(7) in Eqn.(2):
(8)
At the junction x=0, equation (8) becomes
=

(9)

We know that, for an applied voltage V:


=

(10)

, volt equivalent of temperature


Eqn.(10) in Eqn.(9):
=

(11)

Similarly: the electron current at the junction, in P-side, is given by:

(12)

Eqn.(11) and Eqn.(12) in Eqn.(1)


I=
=

+
+

(13)

I=

(14)

Where:

For actual diodes, the expression becomes:


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(15)
Where, n = ideality factor, a number between 1 and 2 which typically increases as the
current decreases.

Effect of temperature on PN junction diodes


The rise in temperature increases the generation
semiconductors and increases their conductivity.
The diode current equation is given by,

From the above equation, we can observe that the diode current depends on the

reverse saturation current

of

electron-hole

pairs

in

and volt equivalent temperature

The increase in reverse saturation current

with T is

for the silicon

and germanium.

Since

rise in temperature.
At room temperature (300K),the value of barrier voltage (or)cut-in voltage is about
0.3V for Ge & 0.7V for Si.The barrier voltage is temperature dependent & it decreases
by 2

, the reverse saturation current approximately doubles for every

for both Ge & Si

(i.e)
Where

=saturation current of the diode at temperature


= saturation current of the diode at temperature

Ge diode can be used upto a maximum of

C and Si diode to a maximum of

C.
Switching Characteristics of PN junction diode
When the diode is switched from forward biased to reverse biased or vice versa, it
takes finite time to reach the final steady state. The behavior of diode during his time
called switching characteristics of diode.
To study the switching characteristics of diode consider simple diode circuit and an
input waveform as shown in the fig (a) and (b).
The following events will takes place due to the nature of the applied voltage

Event 1: till time , the forward voltage applied is

and diode is forward biased. The

value of R is large enough such that drop across R. The forward current is then

neglecting forward resistance of diode.


Event 2: at time , the applied vltage is suddenly reversed and reverse voltage of

is

applied to the circuit. Ideally diode also must become OFF from ON state instantly. But
this does not happen instantly .the number of minority carriers takes time to reduce
from

to zero at the junction as shown in fig (c).due to this, at

15

current just

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reverses and remains at that reversed value


reduces to zero. This current is given by
During time

to

till the minority carrier concentration


. This continues to flow till time .

the minority charge carriers remain stored and decrease slowly to

zero. Hence this time is called storage time denoted as


Event 3: from

onwards, the diode voltage starts to reverse and the diode current starts

decreasing as shown in fig (d). At t=

; the diode state completely gets reversed and

attains steady state in reverse biased condition.


The time from

to

i.e., time required by the diode current to reduce to its reverse

saturation value is called the transition interval or transition time denoted as

The total time required by the diode which is the sum of storage time and transition
time, to recover completely from the change of state is called reverse recovery time of
the diode and dented as
The reverse recovery time depends on the RC time constant where C is transition
capacitances of a diode.to have fast switching from ON to OFF f a diode; the transition
capacitance should be as small as possible.
Thus the transition capacitance plays an important role in the switching circuits using
diodes.
Most commercially available switching dides have the reverse recovery ime ranging frm
a few snanoseconds to one microsecond. However, diodes are specially manufactured
having reverse recovery time as small as only a few picosecnds.
The total switching time
dide. Hence

puts the limit on the maximum operating frequency f the

is an important data sheet specification. To minimise the effect f the

reverse current, the time perid f the operating frequency must be atleast ten times
T= 10
= =

Fig:
The

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waveform in(b) is applied to the diode circuit in(a); (c) the excess carrier density at
the junction;
(d) the diode current; (e) the diode voltage

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