Professional Documents
Culture Documents
The Science
of the Total
Environment
162 (1995)
l-11
of Geochemistry,
Siberian
Branch,
Received
Russian Academy
Russian
Federation
14 June 1994
Abstract
Geochemical surveys were undertaken for dispersion flows in Irkutsk, and its surroundings, with the aim of
selecting a rapid pollution assessment approach (1 sampling point/l4 km). Bottom sediments (< 0.25, 0.251, l-3
mm fractions), overflood sediments ( < 0.25, 0.25-l mm), surface water and plants were sampled. The samples were
analyzed by rapid semi-quantitative (partly quantitative) atomic emission spectroscopy (AES) methods for Ag, Pb,
Zn, Cu, As, Ni, Co, MO, Cr, Li, Ga, Ge, Y, Bi, Sn, Mn, V, Ti, W, Be, P and B, as well as for Hg, F and U (by
quantitative methods). Single-element maps, maps of geochemical classes (element associations) and ecological-geochemical regionalizations were compiled. The average concentration of the majority of trace elements in water and
alluvial sediments are similar to those for other regions of the world. Overflood sediments (particularly the fine
grained fraction) are enriched in the majority of trace elements. Anomalies in the fine fraction of over-flood
sediments are large and they coincide with hydrogeochemical and biogeochemical anomalies. Pollution anomalies
correlate with industrial and economic activity: the industrial-settled zone of Irkutsk (Ag, Cu, Zn, Pb, Hg, Ni, Cr); the
zone around Shelekhov with an aluminium plant (F, U, Cu, MO, Pb, Cr, Ni); and the agricultural zone (Ni, Co, Ti, V,
P, F, U, Mn, Hg). Small-scale geochemical surveys on the fine fractions (< 1 mm) of overflood sediments, based on
cheap and rapid semi-quantitative multi-element AES analysis (up to 50 elements) may be successfully applied to the
assessment of pollution by heavy metals and trace elements over large areas.
Keywords:
Siberia
1. Introduction
*Corresponding
author.
0048-9697/95/$09.50
0 1995 Elsevier
SSDI
0048-9697(95)04319-I
Science
BV. All
rights
reserved
geochemical
mapping,
ecological-geochemical
surveys of stream sediment dispersion flows may
be applied to such areas in conjunction with hydrological networks.
The present work considers the initial results of
an ecological-geochemical
study of sediment dispersion flows in the Irkutsk region and the NearAngara agricultural-industrial
zone.
2. Geology and landscape
limits
0.01
4s
Pb
2.0
Zn 30
cu 10
As 30
Ni
2.0
co
2.0
MO 0.3
mm
PLgg-
emission spec-
__-.-.
V
10
Ti 100
W
1.0
Be 10
B 10
Hg 0.005
U
1.0
GA
A9
n-10a2ppm)
Belogolow
/Sci.
Stream sediment
Size frOcti0n (mm) : f-3
Total En&on.
1.3
I.3
3.0
m
mu
100
* 100
34.0
O-Sampling
POinfS
Overbank sediment
A9
(n-fd*zPpm) Size fraction (mm) : d 0.25
. . . %3
A9
nofOm2mkg/Z)
_-:1
I-II
Stream
A9
n. W*pprn )
10.0
l-
162 (1995)
s&men+
St ream
water
f.3
(;.A. Brlogolotur
/Sci.
Total Entiron.
162 (1995)
I-11
Moss
A9
(n.foappm)
4.5
6
a
r5
22
Surface waters in the region are soft. The average concentrations of the majority of trace elements analyzed are comparable with those of
river water from other world provinces. However,
they are marked by lower Ag and Pb concentrations and a higher Mn, P, F and U content.
The anomalous concentrations of different elements in surface waters are observed over almost
the whole region (Fig. 5). Silver, F, Cu, Co and Ni
anomalies are particularly high. The left bank of
the Angara River near Shelekhov is marked by
increased F concentrations.
The average composition of the alluvial sediments of different facies are comparable, in gen-
eral, with those for alluvial soils from other regions of the world (Table 3) [4,10]. Overflood
sediments, as distinct from stream sediments, also
show increased concentrations together with a
dispersion of the majority of trace elements, except for Pb. This is especially evident for those
elements which form the intensive anomalies in
river water, e.g. Ag and Cu. The composition of
different alluvium fractions from the same facies
(bottom or top overflood sediments) are markedly
similar.
Geochemical
anomalies from alluvium
are
observed over the whole area of the industrial
zone, (Fig. 4). Overflood sediment anomalies, par-
.- .~~~~~~
Fig. 3. Distrihution
G.A. Belogolotia
Pb
@pm,
Stream
Overbank
sedimen f
Size frdction(mm): 40.25
water
. . . . . _. .
. . . ..I.
. . , . ..
. . . . . - *.. .
Pb
&earn
WOmm)
sediment
Pb
IPPml
Branches ofwill~w
6
7
G.A. Belogolota
/Sri.
Total Endron.
v
0,
162 (1995)
I-II
-V
f&m
G.A. Belogolow
Table 2
Concentration of trace ( fig/l)
Elements
-.__
4
Pb
Zn
CU
Ni
CO
Sn
V
Ti
Cr
P
U
Jk
FCO;
HCO,
clso:K+
Na+
Ca? Mg
162 (1995)
l-l
Element contents
Irkutsk region
Background
Average
Maximum
Minimum
Average element
content in river
waters [2,6]
0.03
0.4
20
6
0.9
0.5
0.4
4
13
3.8
160
0.57
0.03
0.3
9.2
109.3
17.6
12.9
10.5
8.9
31.1
6.4
8.8
2.5
219.0
139.0
8.1
4.9
18.7
26.1
68.3
26.6
1500.0
3.0
0.5
5.6
33.6
222.0
105.1
70.0
260.0
31.0
60.0
25.0
0.02
0.1
5
1.1
0.1
0.1
0.1
0.5
1
0.5
5
0.02
0.003
0.02
2.4
30.5
4.3
4
0.5
1.3
4.8
1.9
0.3
3
20
7
0.3
0.2
0.5
3
1
20
0.04
0.1
58.4
7.8
11.2
2.3
6.3
14.6
4.1
0.02
0.1
15
3
0.4
0.2
0.3
4
7
3.0
100
0.4
0.1
Maximum
permissible
concentration [l]
(0.2)
(1)
(20)
(7)
(2.5)
(0.3)
C-J
(1)
(3)
(1)
(40)
(0.5)
(0.07)
to.11
50
30
5000
1000
100
1000
100
100
100
100
0.5
l-l.5
-
350
500
50
120
180
100
__-
Hg
U
Pb
Zn
cu
Ni
co
MO
Cr
Sn
V
Ti
P
0.11/8.8
ll/lOO
83/2200
70/2200
32/220
15/33
1.6/11
49/440
4.1/11
85/165
2036/4400
122/550
-
mm
0.02
8
58
19
28
10
1
39
3.9
78
1944
96
-
Background
0.05/3.0
12/200
51/100
22/150
16/30
10/20
1.8/5
57/200
3.8/6
52/80
2370/6000
115/300
-
Average
< 0.25
Contents
region
0.02
5.7
52
19
15
7.8
1.9
52
3.8
52
1920
96
-
mm
0.02/0.4
8.5/100
41/80
17/40
9.8/20
6.9/20
1.1/2.0
30/60
2.3/4
39/80
2139/5000
73/150
Average
___-
0.25-l
sediments
Background
in bottom
maximum
concentrations,
numerator
in alluvium
according
to Shacklett
0.02
8
39
19
19
10
1
52
3.8
58
1931
96
0.01
2.5
Averagea
0.1 l/6.6
11/110
64/1100
51/2200
28/110
12/33
1.5/22
58/550
4/22
77/166
2306/4400
130/660
0.04/1.5
3.4/17
0.25-l
Background
sediments
flows (ppm,
< 0.25
in overflood
dispersion
Average
Contents
in alluvial
aDenominator
indicates
bAverage
concentrations
As
Elements
Table 3
Element content
0.02
5.8
39
16
7.8
5.7
1.0
19.2
1.9
29
1931
52.6
Background
l-3
mm
0.05/4.4
28/2200
S6/220
32/220
16/44
11/33
1.8/4.4
38/88
4.2/110
60/165
1776/3300
96/220
Averagea
0.02
6
40
15
10
8
1
30
3.0
40
1700
80
-
Background
-.-
--
0.05
18
58.5
27
19
9
5.8
54
4.5
58
2000
-
Average contents
alluviumb
in
IO
G.A. Be1ogoloc.n
162 (1995)
I-11
6. Conclusions
Medium-to-small
scale geochemical mapping of
stream dispersion flows, based on multi-element
semi-quantitative
optical emission spectroscopy,
may be successfully applied for rapid pollution
assessment and monitoring over large areas, planning further economic evaluations and detailed
environmental study.
The fine ( < 0.25 mm) fraction of the overflood
sediment surface layer (O-10 cm) is the preferred
sampling media. However, for detailed study of
the environment, in addition to the analysis of
natural and man-made effects, simultaneous sampling of several related media (fine fraction of
overflood and stream sediments, water, plants) is
essential.
Geochemical comparisons of different media
and fractions from dispersion flows, as well as
different biota, is a promising approach for environmental assessment as well as for recognition
of pollution sources and trends.
Acknowledgements
6. Ag, Cu; Pb, Zn, Ni, Cr,/Ag, Cu, Co, Zn, Ni, Uz
7. cu, Ni, Ph. Cr, Ag;/F,, U,
8. Ph, Cr, Ni, Ag, Mn, Co, Cu, ZnJctm1I ~-- zone of Shelekhov aluminium plant:
0. Vu,,, Hg, Ag: Pb,/F:,, Pi Pb, Ni, Cu, MO,
II). Ni, V, Co, 1.i: U,/F:,, Cu, MO, Pb, U,
I I. Uj Ni, B, Cr,iF,
12-15
agricultural zone:
1. Hg,,f+
1.;. ,/Co,, Ni,, Ti,,
14. Ni : P, Li 1 U_,i Mn, Cr2/Co,, Ni, Ti, P4 U1 F7 Mn,
i5. Ni, B, Cr-. Ti. MnZ/Co,,, Ni,,, Ti, F, Mn,.
[2]
[3]
[4]
[5]
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(Handbook), Khimiya. Moscow, 1989. pp. 368 (in Russian).
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V.N. Evdokimova, Automated processing of geolopicalgeochemical data via multi-dimensional
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Cieochemical Methods of Prospecting of Ore Deposits
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11
[IO] H.T. Shacklette and J.G. Boerngen, Element concentration in soils and other surfacial materials of the conterminous United States. U.S. Geol. Surv. Prof. Pap.,
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