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Slide 1 of 41
3. 0
Slide 2 of 41
Slide 3 of 41
Slide 4 of 41
Heat is added to the container below while being allowed to expand freely
against atmospheric pressure. The temperature and pressure, however,
remain constant before and after.
U is,
1. positive.
2. negative.
3. 0
Slide 5 of 41
Heat is added to the container below while being allowed to expand freely
against atmospheric pressure. The temperature and pressure, however,
remain constant before and after.
U is,
1. positive.
2. negative.
3. 0
Slide 6 of 41
H = -572 kJ
1.
7.4 kJ
2.
-7.4 kJ
3.
5.0 kJ
4.
-5.0 kJ
5.
2.5 kJ
Slide 7 of 41
H = -572 kJ
1.
7.4 kJ
2.
-7.4 kJ
3.
5.0 kJ
4.
-5.0 kJ
5.
2.5 kJ
Slide 8 of 41
The volume of the Pacific Ocean is about 300 km3. Without the use of a
calculator, estimate the heat that is required to raise the temperature of the
Pacific Ocean by 1 oC (assume the density of water is 1 g cm-3 and the
specific heat is 4 J g-1 oC-1.
1. ~103 J
2. ~106 J
3. ~1012 J
4. ~1018 J
5. ~1025 J
Slide 9 of 41
The volume of the Pacific Ocean is about 300 km3. Without the use of a
calculator, estimate the heat that is required to raise the temperature of the
Pacific Ocean by 1 oC (assume the density of water is 1 g cm-3 and the
specific heat is 4 J g-1 oC-1.
1. ~103 J
2. ~106 J
3. ~1012 J
4. ~1018 J
5. ~1025 J
Slide 10 of 41
In 1 minute the sun shines about 40 kJ m-2 of energy on Earth s surface and
about 1018 J is required to raise the temperature of the Pacific by 1 oC.
Assuming that all of the sun s energy is absorbed, how long must the sun
shine on the Pacific to raise its temperature by 1 oC? The area of the Pacific
ocean is about 100 km2.
1. 4x1021 min
2. 2.5x1011 min
3. 2.5x105 min
4. 2.5x10-5 min
5. 4x10-10 min
Slide 11 of 41
In 1 minute the sun shines about 40 kJ m-2 of energy on Earth s surface and
about 1018 J is required to raise the temperature of the Pacific by 1 oC.
Assuming that all of the sun s energy is absorbed, how long must the sun
shine on the Pacific to raise its temperature by
1 oC? The area of the Pacific ocean is
about 100 km2.
1. 4x1021 min
2. 2.5x1011 min
3. 2.5x105 min
4. 2.5x10-5 min
5. 4x10-10 min
Slide 12 of 41
The figure below shows the heating curve for water. It traces the changes in
temperature as ice, initially at -20 oC, is gradually heated to produce liquid
water at +20 oC. When the ice (the system) melts,
1.
2.
3.
Slide 13 of 41
The figure below shows the heating curve for water. It traces the changes in
temperature as ice, initially at -20 oC, is gradually heated to produce liquid
water at +20 oC. When the ice (the system) melts,
1.
2.
3.
Slide 14 of 41
The figure below shows the cooling curve for water. It traces the changes
in temperature as water, initially at 20 oC, is gradually cooled to produce ice
at -20 oC. When the water (the system) freezes,
1.
2.
3.
Slide 15 of 41
The figure below shows the cooling curve for water. It traces the changes
in temperature as water, initially at 20 oC, is gradually cooled to produce ice
at -20 oC. When the water (the system) freezes,
1.
2.
3.
Slide 16 of 41
You take two frozen steaks and put them into room temperature water for a few
hours to thaw. The heat gained by the steak (system) equals the heat lost by
the water (surroundings). The best equation to express this, where subscript
s refers to steak and the subscript w refers to the water, is,
1. sw mw Tw = ss ms Ts
2. sw mw Tw = ss ms Ts
3. sw mw Tw = ss ms Ts
Slide 17 of 41
You take two frozen steaks and put them into room temperature water for a few
hours to thaw. The heat gained by the steak (system) equals the heat lost by
the water (surroundings). The best equation to express this, where subscript
s refers to steak and the subscript w refers to the water, is,
1. sw mw Tw = ss ms Ts
2. sw mw Tw = ss ms Ts
3. sw mw Tw = ss ms Ts
Slide 18 of 41
q Te = q H 2O
200 g Te
(100 oC)
100 g H2O
25 oC
50 oC
3. 2 J g-1 oC-1
4. 4 J g-1 oC-1
5. 10 J g-1 oC-1
Slide 19 of 41
q Te = q H 2O
200 g Te
(100 oC)
100 g H2O
25 oC
50 oC
Slide 20 of 41
1. 250 kJ,
251 kJ
2. 250 kJ,
249 kJ
3. -250 kJ,
-251 kJ
4. -250 kJ,
-249 kJ
5. -250 kJ,
-250 kJ
Slide 21 of 41
V2= 0.110 m3
1x105 Pa
qP = 250 kJ
T=300 K
1. 250 kJ,
251 kJ
2. 250 kJ,
249 kJ
3. -250 kJ,
-251 kJ
4. -250 kJ,
-249 kJ
5. -250 kJ,
-250 kJ
Slide 22 of 41
V2= 0.110 m3
1x105 Pa
qP = 250 kJ
T=300 K
2. an endothermic process.
3. neither exothermic nor endothermic
since the temperature of the system
remains constant (0 oC at 1 atm).
Slide 23 of 41
2. an endothermic process.
3. neither exothermic nor endothermic
since the temperature of the system
remains constant (0 oC at 1 atm).
Slide 24 of 41
C4 H10 (g) +
13
O2 (g) 4CO2 (g) + 5H 2O(g)
2
Slide 25 of 41
C4 H10 (g) +
13
O2 (g) 4CO2 (g) + 5H 2O(g)
2
Slide 26 of 41
Slide 27 of 41
Slide 28 of 41
Given the heats of formation of the potential products of the Ostwald process,
which reaction is most exothermic?
1. NH 3 (g) +
3
O2 (g)
4
2. NH 3 (g) + O2 (g)
1
3
N 2 (g) + H 2O(g)
2
2
1
3
N 2O(g) + H 2O(g)
2
2
3. NH 3 (g) +
5
3
O2 (g) NO(g) + H 2O(g)
4
2
4. NH 3 (g) +
7
3
O2 (g) NO 2 (g) + H 2O(g)
4
2
Slide 29 of 41
H / kJ
mol-1
N2
N 2O
82.1
NO
90.2
NO2
33.2
Given the heats of formation of the potential products of the Ostwald process,
which reaction is most exothermic?
1. NH 3 (g) +
3
O (g) !
4 2
2. NH 3 (g) + O2 (g)
1
3
N 2 (g) + H 2O(g)
2
2
1
3
N 2O(g) + H 2O(g)
2
2
3. NH 3 (g) +
5
3
O2 (g) NO(g) + H 2O(g)
4
2
4. NH 3 (g) +
7
3
O2 (g) NO 2 (g) + H 2O(g)
4
2
Slide 30 of 41
H / kJ
mol-1
N2
N 2O
82.1
NO
90.2
NO2
33.2
Given the heats of formation of the potential products of the Ostwald process,
which reaction is most exothermic?
H / kJ
mol-1
N2
N 2O
82.1
NO
90.2
NO2
33.2
NH3 = -46.11kJ/mole
Slide 31 of 41
Given the heats of formation of the potential products of the Ostwald process,
which reaction is most exothermic?
H / kJ
mol-1
N2
N 2O
82.1
NO
90.2
NO2
33.2
Slide 32 of 41
The equations for the complete and incomplete combustion of octane are given
below.
Hf / kJ
25
C8 H18 (l) +
O2 (g) 8CO2 (g) + 9H 2O(l)
mol-1
C8 H18 (l) +
17
O2 (g) 8CO(g) + 9H 2O(l)
2
Slide 33 of 41
CO
-111
CO2
-394
The equations for the complete and incomplete combustion of octane are given
below.
Hf / kJ
25
C8 H18 (l) +
O2 (g) 8CO2 (g) + 9H 2O(l)
mol-1
C8 H18 (l) +
17
O2 (g) 8CO(g) + 9H 2O(l)
2
Slide 34 of 41
CO
-111
CO2
-394
A. C4 H10 (g) +
9
O2 (g) 4CO(g) + 5H 2O(l)
2
5
B. C4 H10 (g) + O2 (g) 8C(graph) + 5H 2O(l)
2
Hf = -111 kJ mol-1
Given that the heat of formation of CO(g) is -111 kJ mol-1, which reaction is
more exothermic and by how much?
1. Reaction A by 111 kJ mol-1.
2. Reaction B by 111 kJ mol-1.
3. Reaction A by 444 kJ
Slide 35 of 41
mol-1.
A. C4 H10 (g) +
9
O2 (g) 4CO(g) + 5H 2O(l)
2
5
B. C4 H10 (g) + O2 (g) 8C(graph) + 5H 2O(l)
2
Hf = -111 kJ mol-1
Given that the heat of formation of CO(g) is -111 kJ mol-1, which reaction is
more exothermic and by how much?
1. Reaction A by 111 kJ mol-1.
2. Reaction B by 111 kJ mol-1.
3. Reaction A by 444 kJ
Slide 36 of 41
mol-1.
Given the bond energies below, estimate the enthalpy change for the
addition of Br across the double bond in ethene.
+
CC
C=C
CBr
BrBr
350 kJ mol-1
600 kJ mol-1
300 kJ mol-1
200 kJ mol-1
1. 150 kJ
2. -150 kJ
3. 220 kJ
4. -220 kJ
5. Not enough data to determine rH
Slide 37 of 41
Given the bond energies below, estimate the enthalpy change for the
addition of Br across the double bond in ethene.
+
CC
C=C
CBr
BrBr
350 kJ mol-1
600 kJ mol-1
300 kJ mol-1
200 kJ mol-1
1. 150 kJ
2. -150 kJ
3. 220 kJ
4. -220 kJ
5. Not enough data to determine rH
Slide 38 of 41