Professional Documents
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Properties of Carbon
Student: ______________________________________________________________________
1.
A.
B.
C.
D.
E.
2.
1,1,3-triethyl-2-methylbutane
1,1-diethyl-2,3-dimethylpentane
2,4-diethyl-3-methylhexane
3-ethyl-4,5-dimethylheptane
None of these choices is correct.
A.
B.
C.
D.
E.
2-isopropyl-2,3,4-trimethylbutane
2-isopropyl-2,3-dimethylpentane
2,3,3,4-tetramethylhexane
1,1,2,2,3-pentamethylpentane
None of these choices is correct.
3.
A.
B.
C.
D.
E.
4.
A.
B.
C.
D.
E.
5.
1,2-diethyl-1-methyl-3-propyl-4-isobutylhexane
1,6,6-trimethyl-1,2,4-triethyl-3-propylhexane
1,1,6-trimethyl-3,5,6-triethyl-4-propylhexane
4,6-diethyl-2,7-dimethyl-5-propylnonane
3,5-diethyl-1,1,6-trimethyl-4-propyloctane
2,4,5-tripropylheptane
6-methyl-3,4-dipropylnonane
4-ethyl-5,7-dipropyloctane
5-ethyl-2,4-dipropyloctane
4-ethyl-7-methyl-5-propyldecane
A.
B.
C.
D.
E.
ortho-dipropylcyclopentylhexane
2,3-dipropylcyclopentylhexane
2-hexyl-1,5-dipropylcyclopentane
1-hexyl-2,3-dipropylcyclopentane
1,2-dipropyl-3-hexylcyclopentane
6.
A.
B.
C.
D.
E.
7.
A.
B.
C.
D.
E.
8.
ortho-ethylheptylcyclopentane
meta-ethylheptylcyclopentane
1-ethyl-2-heptylcyclopentane
ethylcyclopentylheptane
ortho-ethylheptylbenzene
1-ethyl-3-methylcyclohexane
1-methyl-5-ethylcyclohexane
meta-ethylmethylcyclohexane
meta-ethylmethylbenzene
3-ethyltoluene
A.
B.
C.
D.
E.
cis-2-methyl-4-heptene
trans-2-methyl-4-heptene
cis-6-methyl-3-heptene
trans-6-methyl-3-heptene
cis-2-methyl-3-heptene
9.
A.
B.
C.
D.
E.
cis-3-ethyl-2,6-dimethyl-6-propyl-4-nonene
trans-3-ethyl-2,6-dimethyl-6-propyl-4-nonene
cis-7-ethyl-4,8-dimethyl-4-propyl-5-nonene
trans-7-ethyl-4,8-dimethyl-4-propyl-5-nonene
None of these choices is correct.
A.
B.
C.
D.
E.
cis-2-methyl-2,3-dipropyl-4-octene
cis-7-methyl-6,7-dipropyl-4-octene
cis-4,4-dimethyl-5-propyl-6-decene
trans-7,7-dimethyl-6-propyl-4-decene
cis-7,7-dimethyl-6-propyl-4-decene
A.
B.
C.
D.
E.
cis-2,3-dimethyl-4-hexene
trans-2,3-dimethyl-4-hexene
cis-4,5-dimethyl-2-hexene
trans-4,5-dimethyl-2-hexene
trans-4,5-dimethyl-2-heptene
A.
B.
C.
D.
E.
cis-2,5-diethyl-6-methyl-3-nonene
2,5-diethyl-6-methyl-3-nonene
cis-4,6-diethyl-3-methyl-6-nonene
4,6-diethyl-3-methyl-6-nonene
trans-2,5-diethyl-6-methyl-3-nonene
A.
B.
C.
D.
E.
2-ethyl-3-pentene
4-ethyl-2-pentene
3-methyl-4-hexene
4-methyl-2-hexene
None of these choices is correct.
A.
B.
C.
D.
E.
1,1-diethyl-3-butyl-3-hexene
5-butyl-3-ethyl-5-octene
4-butyl-6-ethyl-3-octene
3-ethyl-5-propyl-5-nonene
4-butyl-6-ethyl-3,4-octene
A.
B.
C.
D.
E.
1-butyl-4-pentyl-3-propylcyclohexene
1-butyl-4-pentyl-5-propylcyclohexene
2-butyl-5-pentyl-6-propylcyclohexene
4-butyl-1-pentyl-2-propylcyclohexene
1-butyl-4-pentyl-3-propylbenzene
A.
B.
C.
D.
E.
1,1-dimethyl-1-cylcopentyl-2-pentane
1,1-dimethyl-2-hexene-cyclopentane
2-cyclopentyl-2-methyl-3-hexene
5,5-dimethyl-5-cyclopentyl-3-pentane
5,5-dimethyl-5-cyclopentyl-3-pentene
A.
B.
C.
D.
E.
2-ethyl-4-propylcycloheptene
3-ethyl-5-propylcycloheptene
6-ethyl-4-propylcycloheptene
7-ethyl-5-propylcycloheptene
3-ethyl-5-propylcyclohexene
A.
B.
C.
D.
E.
4-ethyl-1,1,5-trimethyl-2-heptyne
4,5-diethyl-1,1-dimethyl-2-heptyne
5-ethyl-2,6-dimethyl-3-octene
3-ethyl-3,7-dimethyl-5-octyne
5-ethyl-2,6-dimethyl-3-octyne
A.
B.
C.
D.
E.
5-butyl-4,4-dimethyl-3-propyl-1-heptene
5-ethyl-4-4-dimethyl-3-propyl-1-nonyne
5-ethyl-6-6-dimethyl-7-propyl-8-nonyne
4,6-diethyl-5-5-dimethyl-4-decyne
5-ethyl-4-4-dimethyl-3-propyl-1-nonene
A.
B.
C.
D.
E.
4-4-diethyl-2-pentyne
2,2-diethyl-3-pentyne
2-ethyl-2-methyl-4-hexyne
4-ethyl-4-methyl-2-hexyne
2-ethyl-2-methyl-4-hexene
A.
B.
C.
D.
E.
2,5-dimethyl-3-octyne-6-cyclobutane
4-cyclobutyl-1-isopropyl-3-methyl-1-hexyne
3-cyclobutyl-4,7-dimethyl-5-octyne
6-cyclobutyl-2,5-dimethyl-3-octyne
3-cyclobutyl-4,7-dimethyl-5-octene
A.
B.
C.
D.
E.
meta-chloroethylcyclohexene
1-chloro-5-ethylcyclohexene
meta-chloroethylbenzene
1-chloro-5-ethylbenzene
1-chloro-3-ethylcyclohexane
A.
B.
C.
D.
E.
1-chloro-2-ethyl-3-propylcyclohexane
1-chloro-2-ethyl-3-propylcyclohexene
1-chloro-ortho-ethylpropylbenzene
1-chloro-meta-ethylpropylbenzene
1-chloro-2-ethyl-3-propylbenzene
A.
B.
C.
D.
E.
ortho-butylethylbenzene
meta-butylethylbenzene
para-butylethylbenzene
1-butyl-2-ethylcyclohexene
1-butyl-2-ethylcyclohexane
A.
B.
C.
D.
E.
ortho-dibromobenzene
meta-dibromobenzene
para-dibromobenzene
1,4-dibromocyclohexene
1,4-dibromocyclohexane
A.
B.
C.
D.
E.
para-bromochloro-2-ethylbenzene
4-bromo-1-chloro-2-ethylbenzene
5-bromo-2-chloro-1-ethylbenzene
1-bromo-4-chloro-3-ethylcyclohexene
4-bromo-1-chloro-2-ethylcyclohexane
A.
B.
C.
D.
E.
3,4-diethyl-4-methyl-2-butanol
2,3-diethyl-4-pentanol
3,4-diethyl-2-pentanol
3-ethyl-4-methyl-2-hexanol
3-ethyl-4-methyl-2-hexanal
A.
B.
C.
D.
E.
3-ethyl-2,3-dimethyl-1-propanol
2,3,4-trimethyl-1-butanol
2,3-dimethyl-1-pentanol
3,4-dimethyl-5-pentanol
2,3-dimethyl-1-pentanal
A.
B.
C.
D.
E.
A.
B.
C.
D.
E.
33. Excluding cyclic compounds, how many possible isomers exist for C4H8?
A. 2
B. 4
C. 5
D. 6
E. 7
34. Including cyclic compounds, how many possible isomers exist for C4H8?
A. 2
B. 4
C. 5
D. 6
E. 7
35. Which of the following features do cyclohexene and 3-methyl-1-pentyne have in common?
A. same physical properties
B. same chemical properties
C. same boiling point
D. same molecular weight
E. same number of double bonds
A.
B.
C.
D.
E.
addition
elimination
substitution
oxidation
reduction
39. Select the correct reaction type for the following process.
A.
B.
C.
D.
E.
addition
elimination
substitution
oxidation
reduction
40. The reaction of bromine with an alkene such as cyclopentene is a good laboratory test for
the presence of a double bond in a compound. What type of reaction is it?
A.
B.
C.
D.
E.
addition
elimination
substitution
displacement
reduction
A.
B.
C.
D.
E.
addition
elimination
substitution
oxidation
displacement
A.
B.
C.
D.
E.
addition
elimination
substitution
oxidation
dehydrogenation
A.
B.
C.
D.
E.
addition
elimination
carbonylation
dehydration
oxidation
A.
B.
C.
D.
E.
addition
elimination
substitution
oxidation
reduction
A.
B.
C.
D.
E.
aldehyde
ketone
alcohol
ester
carboxylic acid
46. Vanillin is a flavoring agent which occurs naturally in the vanilla bean, the seed of an
orchid. Identify the functional group circled.
A.
B.
C.
D.
E.
aldehyde
ketone
alcohol
carboxylic acid
carbonyl
47. One source of a musky odor in perfumes is civetone, a compound extracted from the scent
gland of the civet cat. Identify the functional group circled.
A.
B.
C.
D.
E.
aldehyde
ketone
alcohol
carboxylic acid
oxide
48. Aspirin is an effective and widely used pain reliever. Identify the functional group circled.
A.
B.
C.
D.
E.
aldehyde
ketone
ester
carboxylic acid
carbonyl
49. Enflurane is an effective gaseous anesthetic with relatively low flammability. Identify the
functional group circled.
A.
B.
C.
D.
E.
aldehyde
ketone
ester
ether
alcohol
50. Anethole, a derivative of anise, is used in flavoring and as perfume in soap and toothpaste.
Identify the functional group circled.
A.
B.
C.
D.
E.
aldehyde
ketone
alcohol
ester
ether
51. Glycerin is used in cosmetics as a moisturizer. Identify the functional group circled.
A.
B.
C.
D.
E.
carboxylic acid
alcohol
ester
ether
aldehyde
52. Glucose is an important sugar in a person's metabolic cycle. Identify the functional group
circled.
A.
B.
C.
D.
E.
aldehyde
ketone
alcohol
ester
carboxylic acid
A.
B.
C.
D.
E.
aldehyde
ketone
alcohol
ester
carboxyl
54. The compound shown below is responsible for the odor in rancid butter. Identify the
functional group circled.
A.
B.
C.
D.
E.
aldehyde
ketone
alcohol
carboxylic acid
carbonyl
55. Benzocaine is from a family of chemicals that are good local anesthetics. Identify the
functional group circled.
A.
B.
C.
D.
E.
aldehyde
ketone
ester
carboxylic acid
carbonyl
56. Putrescine is produced during the decay and protein breakdown of meats and is responsible
for some of the odor found in them. Identify the functional group circled.
A.
B.
C.
D.
E.
aldehyde
ketone
amide
nitrile
amine
57. Serotonin transmits nerve impulses through the body. Identify the functional group circled.
A.
B.
C.
D.
E.
aldehyde
alcohol
amide
amine
nitride
58. Acetominophen is a widely used and an effective pain reliever. Identify the functional
group circled.
A.
B.
C.
D.
E.
aldehyde
alcohol
amide
amine
carbonyl
59. Urea carries waste nitrogen from the body in urine. Identify the functional group circled.
A.
B.
C.
D.
E.
aldehyde
alcohol
carboxyl
amine
amide
60. The millipede ejects the compound shown below to protect itself from its enemies. Identify
the functional group circled.
A.
B.
C.
D.
E.
nitrile
alcohol
amide
amine
nitro
61. Amygdalin (Laetrile) was once touted for its potential anticancer activity. However, the
claims were never scientifically verified. Identify the functional group circled.
A.
B.
C.
D.
E.
carbonite
ether
amide
amine
nitrile
62. Which one of the following classes of organic compound does not contain the carbonyl
(C
O) group?
A. aldehydes
B. carboxylic acids
C. ketones
D. alcohols
E. esters
63. Identify the principal organic product of the reaction between butane and chlorine.
A.
B.
C.
D.
E.
CH3Cl
CH3CH2Cl
CH3CHClCH3
CH3CH2CHClCH3
None of these choices is a major product of the reaction.
64. Identify the principal organic product when benzyl chloride reacts with aqueous sodium
hydroxide.
A.
B.
C.
D.
E.
65. Identify the two principal products of the reaction between ammonia and ethyl propionate.
A.
B.
C.
D.
E.
A.
B.
C.
D.
E.
67. Identify the products for the reaction between cycloheptene and bromine.
A.
B.
C.
D.
E.
A.
B.
C.
D.
E.
69. Identify the products of the reaction between 2-bromopentane and potassium ethoxide.
A.
B.
C.
D.
E.
70. Identify the principal organic products for the following reaction.
A.
B.
C.
D.
E.
None of these choices is among the principal organic products of the reaction.
71. Identify the organic product when cyclohexanol reacts with excess potassium dichromate in
the presence of sulfuric acid.
A.
B.
C.
D.
E.
72. Identify the organic product when 3-cylcobutyl-1-propanol reacts with excess potassium
dichromate in sulfuric acid.
A.
B.
C.
D.
E.
73. Identify the organic product for the reaction of 2-pentanol with sulfuric acid.
A.
B.
C.
D.
E.
74. Identify the organic product when cyclopentanol reacts with sulfuric acid.
A.
B.
C.
D.
E.
75. One characteristic of the monomers that form condensation polymers that is not common in
monomers which form addition polymers is
A. the presence of pi bonds.
B. the presence of two functional groups.
C. the presence of alkyl side chains.
D. the ability to form free radicals.
E. the presence of sulfur atoms.
76. Which of the following polymers is a condensation polymer?
A. polystyrene
B. Teflon
C. polyvinylchloride
D. polypropylene
E. Dacron
83. Draw and name two non-alkenes with the formula C4H8.
84. Draw and name all stable molecules with the formula C5H12.
85. Draw and name four alkenes with the formula C4H8.
90. In one sentence, what is the general requirement for a molecule to be optically active?
91. a. Draw two different structures with the molecular formula C2H6O.
b. Name the functional group in each structure.
c. Which one will have the higher boiling point, and why?
93. Write down the structure of the missing organic reactant or product(s) in the following
reactions, and name the type of reaction involved (inorganic products may also be formed):
94. Describe and contrast fibrous and globular proteins in terms of their amino acid
composition, their structure and their function.
99. Given that each 3-base sequence in DNA is a "code word" for a particular amino acid, how
many different code words are possible using a 3-base sequence and the bases available in
DNA?
100. Because organic compounds are associated with living organisms, their properties are
governed by fundamentally different chemical principles from those of inorganic
compounds.
Difficulty: E
True False
O units.
(p. 636) D
2.
(p. 636) C
3.
(p. 636) D
4.
(p. 636) E
5.
(p. 643) D
6.
(p. 643) C
7.
(p. 643) A
8.
(p. 643) C
9.
(p. 643) B
10.
(p. 643) E
11.
(p. 643) D
12.
(p. 643) B
13.
(p. 643) D
14.
(p. 643) C
15.
(p. 643) A
16.
(p. 643) C
17.
(p. 643) B
18.
(p. 643) E
19.
(p. 643) B
20.
(p. 643) D
21.
(p. 643) D
22.
(p. 652) C
23.
(p. 652) E
24.
(p. 644) A
25.
(p. 652) C
26.
(p. 652) B
27.
(p. 651) D
28.
(Sec. 15.2) D
29.
(Sec. 15.2) C
30.
(p. 651) C
31.
(p. 639) B
32.
(p. 639) D
33.
(Sec. 15.2) B
34.
(Sec. 15.2) D
35.
(Sec. 15.2) D
36.
(Sec. 15.3) E
37.
(Sec. 15.4) B
38.
(Sec. 15.3) C
39.
(Sec. 15.3) A
40.
(Sec. 15.3) A
41.
(Sec. 15.3) B
42.
(Sec. 15.3) B
43.
(Sec. 15.3) E
44.
(Sec. 15.3) D
45.
(p. 651) E
46.
(p. 651) D
47.
(p. 651) B
48.
(p. 651) C
49.
(p. 651) D
50.
(p. 651) E
51.
(p. 651) B
52.
(p. 651) A
53.
(p. 651) B
54.
(p. 651) D
55.
(p. 651) C
56.
(p. 651) E
57.
(p. 651) D
58.
(p. 651) C
59.
(p. 651) E
60.
(p. 651) A
61.
(p. 651) E
62.
(p. 651) D
63.
(Sec. 15.4) D
64.
(p. 654) A
65.
(p. 659) B
66.
(p. 658) B
67.
(p. 649) B
68.
(p. 649) A
69.
(p. 652) C
70.
(p. 652) B
71.
(p. 652) B
72.
(p. 652) C
73.
(p. 650) D
74.
(p. 650) B
75.
(p. 664) B
76.
(p. 665) E
77.
(p. 664) C
78.
(p. 665) D
79.
(p. 666) C
80.
(p. 667) A
81.
(p. 669) E
82.
(p. 672) B
83.
(p. 643)
Difficulty: E
84.
(p. 643)
Difficulty: M
85.
(p. 643)
Difficulty: M
86.
Difficulty: M
87.
Difficulty: M
88.
b. cyclooctene
c. toluene (methylbenzene)
Difficulty: E
89.
b. C7H16
c. C4H8
Difficulty: H
90.
(p. 639) In order to be optically active, the compound must have a non-superimposable mirror image.
Difficulty: M
91.
b. ether
c. ketone
d. aldehyde
e. carboxylic acid
f. amide
Difficulty: E
93.
(Sec. 15.4) A.
B.
C.
D.
E.
F.
G.
H.
Difficulty: M
94.
(p. 669) Fibrous proteins are composed of relatively few amino acids in a repeating pattern. Their structures are helices or
sheets, and they are found in hair, skin and muscle. Globular proteins use more amino acids in their structures, and they
have various of irregular shapes. Their functions are various: messenger molecules, enzymes (catalysts), etc.
Difficulty: M
95.
S
H side chains react to form a covalent
S
S
link between the two regions of the protein backbone. The two regions of the protein backbone are thus held
together.
Difficulty: H
96.
(Sec. 15.6) A salt bridge is the result of ionic attraction between a side chain with a carboxylate (
Difficulty: E
98.
(p. 671) Each nucleotide along a single strand of DNA has one of four possible bases, namely guanine (G), cytosine (C),
adenine (A) and thymine (T). The double helix of DNA is held in place by hydrogen bonds between pairs of bases, one
base being on each of the two strands. G always pairs with C and A always pairs with T. Thus, the base sequence on one
strand determines the base sequence on the other strand, and the strands are "complementary" to each other.
Difficulty: M
99.
(p. 671) 4 4 4 = 64
Difficulty: M
100.
101.
102.
103.
104.
105.
106.
107.
108.
109.
110.
111.
112.
113.
114.
115.
116.
117.
118.
119.