49

030212

1000ml 150ml 5g
1000 ml 180ml 3.5g

Four-gas 1
NOx 1
1
R-2 1
1
1 3
1000ml200ml 6 1000ml 2
500ml2 2 2 3 2 6
2 12
NaOH1 CH3OH500ml 24 1kg 1 CH3COOH
500g 1 1
2.6L 8 10L 2

BOSCH Four-gas
Four-gas HCCOO2 CO2

NOx
NOx
2

NOx Four-gasHCCOO2
CO2

1.

1 1000ml 100ml 3.5g

2 1000ml 120ml 3.5g
3 1000ml 150ml 3.5g
4 1000ml 150ml 5g
2.

1 1000ml 150ml 5g
2 1000ml 180ml 3.5g
3 1000ml 180ml 7g
4 1000ml 220ml 10g

1. 2000RPM5500RPM
500RPM
2.Four-gas NOx 700RPM2700RPM
500RPM

60 1
1

pH
50ml 60 1
1
60 1

1000ml

- 1000ml

1000ml
60 1

60

pH

pH

pH

pH

10

11

50ml
60 1 60 1

50ml

12

13

Four-gas

14

1
2 20ml
3
1000ml 150ml 3.5g
4

1. 1000ml 100ml 3.5g
2. 1000ml 120ml 3.5g
3. 1000ml 150ml 3.5g
4. 1000ml 150ml 5g

15

5 6
1000ml 180ml
3.5g 7
8

5. 1000ml 150ml 5g
6. 1000ml 180ml 3.5g
7. 1000ml 180ml 7g
8. 1000ml 220ml 10g

HC
CO
O2

CO2 NOx
NOx

16

 100%

70

D ie se l( )
B io -d ie s e l ( )
B io -d ie s e l( )

(%)

60

50

40

30

20

10

0
15 00

2 00 0

25 00

3 00 0

35 00

4 00 0

45 00

5 00 0

55 00

600 0

(R P M )

100%
12

11

HC ( PPM )

10
9
8
7
6
5
4
700

950

1200

14 5 0

1700

1 95 0

2200

2450

27 0 0

2950

( R PM )

HC HC
HC

17

 100%

0 .020

0 .018

CO ( % )

0 .016

0 .014

0 .012

0 .010

7 00

95 0

120 0

145 0

170 0

1 950

2 200

2 450

27 00

29 50

( RPM )

CO CO
CO

100%

18.0

17.8
17.6

O2 ( % )

17.4
17.2
17.0
16.8
16.6
16.4
16.2
16.0
700

950

1200

1450

1700

1950

2200

2450

2700

2950

( RPM )

O2 O2

18

 1 0 0%
3 .4

3 .2

CO2 ( % )

3 .0

2 .8

2 .6

2 .4

2 .2
7 00

9 50

1 20 0

1 45 0

1 70 0

19 5 0

22 00

2 4 50

2 70 0

2 95 0

( RPM )

CO2 CO2
CO2

100%

150

140

NOx ( PPM )

130
120
110
100
90
80
70
7 00

950

120 0

145 0

17 00

19 50

2 200

2 450

270 0

295 0

( RPM )

NOx NOx

B5B20 B50 HC B70

B100 CO B100
19

 B5 B20 O2
B5 B50 B100 CO2
B100 NOx
B100 NOx

60
55

B5
B 20
B 50
B 70
B 100

(%)

50
45
40
35
30
25
20
15
10
5
1500

2000

2500

3000

3500

4000

4500

5000

5500

6000

(R PM )

7.5

B5
B 20
B 50
B 70
B 100

6.5

HC (PPM)

5.5

4.5

3.5

2.5

1.5
700

950

1200

1450

1700

1950

2200

2450

2700

2950

(RP M )

HC
B70 B100 HC
B5B20 B50
HC

20


0.019

B5
B 20
B 50
B 70
B 100

0.017

CO (%)

0.015

0.013

0.011

0.009

0.007
700

950

1200

1450

1700

1950

2200

2450

2700

2950

(R PM )

CO
CO B100
B5 B20
CO

18.2

17.8

O2 (%)

17.4

17.0

B5
B20
B50
B70
B100

16.6

16.2

15.8
700

950

1200

1450

1700

195 0

2200

24 50

2700

2 950

(RPM )

O2
O2 B5
B50 B100

21


3.50

B5
B20
B50
B70
B100

3.25

CO2 (%)

3.00

2.75

2.50

2.25

2.00
700

950

1200

1450

1700

1950

2200

2450

2700

2950

(RPM)

CO2
CO2
B100
CO2

120

B5
B 20
B 50
B 70
B 100

115
110

NOx (PPM)

105
100
95
90
85
80
75
70
700

950

1200

1450

1700

1950

2200

2450

2700

2950

(RPM )

NOx
B100 NOx
NOx

B5 B100 HC CO
B100 B5 B20
22

 O2 B5 B100
CO2 B50 B70
B100 NOx
B100

60
55

B5
B 20
B 50
B 70
B 100

(%)

50
45
40
35
30
25
20
15
10
5
1500

2000

2500

3000

3500

4000

4500

5000

5500

6000

(RPM )

7.5

B5
B 20
B 50
B 70
B 100

HC (PPM)

6.5

5.5

4.5

3.5

2.5

1.5
700

950

1200

1450

1700

1950

2200

2450

2700

2950

(RPM)

HC
B5 B100 HC
B5 B20
B100 HC
23


B5
B20
B50
B70
B100

0.017

CO (%)

0.015

0.013

0.011

0.009

0.007
700

950

1200

1450

1700

1950

2200

2450

2700

2950

(R PM )

CO
CO
B100 B5
CO

18.00
17.75
17.50

O2 (%)

17.25
17.00
16.75

B5
B20
B50
B70
B100

16.50
16.25
16.00

700

950

1200

1450

1700

1950

2200

2450

2700

2950

(RPM)

O2
O2 B5 B100
B50 O2

24


3.50

B5
B20
B50
B70
B100

3.25

CO2 (%)

3.00

2.75

2.50

2.25

2.00
700

950

1200

1450

1700

1950

2200

2450

2700

2950

(RPM)

CO2
CO2 B50
B70 B100

12 0
11 5

B5
B20
B50
B70
B100

11 0

NOx (PPM)

10 5
10 0
95
90
85
80
75
70
7 00

9 50

12 00

145 0

170 0

1950

2 200

2 450

2 700

29 50

(RPM)

NOx
NOx B100
B70B50B20 B5
NOx

25


1
B1 B100
1

18596
5157

, g/cm3

0.889

0.835

185

96

, mm2/s

6.03

3.8

-2

- 15

51

57

kcal/kg

9,800

10,930

10ppm

0.2%()

(Cetane number )

B1B20 B100

CO
2C + O
2CO
2
26

 C O2
CO2
C +O
CO
2
2

HC C CO2 H2
O2
2H + O
2 H O
2
2
2 (g)

HC
NOx N2 O2
N +O
2 NO
2
2

NO O2 NO2
2 NO + O
2 NO
2
2

NOx NO NO2
1000ml 180ml
3.5g
1000ml
150180ml 3.5g5g

()

O
H

H C O C R 1

R1 C O CH 3

H C OH

NaOH
H C O C
R 2 3 CH OH R 2 C O CH 3 H C OH

O
H C OH

H C O C
R3
O
CH
R3 C

3
H

H
O
O

()

27

()

O
H

H C O C R1

H C O C
R2

O
H C O C
R3

H
O

R1 C O Na +
O

C H OH
2
5
+ 3 NaOH R 2 C O Na + +
O Na +
R3 C

()

H C OH

H C OH

H C OH
H

()

O
H

H C O C R 1

H C O C
R2

O
H C O C
R3

H
O

1000ml 150ml 3.5g

1000ml 150210ml
3.5g5g

28

1000ml 150ml 3.5g

HC
NOx CO

B100
HCCO NOx
B5B20B50 B70

29


(2008)
(2008)
(2006)
(2007)
(2006)-
2008 4 18
BiodieselGrowing a New Energy Economy Greg Pahl Chelsea Green Publishing Company

2005-
Biodiesel Lubricity
Leon Schumacher The Biodiesel Hand
book Gerhard Knothe and et. al., AOCS Press, 2005
-//
/http://www.biodiesel-tw.org/ Green
-http://www.fengyuan.gov.tw/

30

030212