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DsRed
Cy-5
3~5%
Abstract
Energy crisis has become more and more serious in recent years, which
makes recycled-energy development is a must. Among different recycled
energies, solar power has two advantages, that is, easy-to-use and endless
supply. However, the conventional solar cell makes poor use of the solar
spectrum
because
the
solar
spectrum
is
mainly
composed
of
short-wavelength, which cant fit to most of solar cells which is more sensitive
to long-wavelength. Currently, the major method to improve the efficiency is
change the function of spectral response, such as concentration lens, tracking
devices, and antireflection coating. Up to now, no one notices the possibility of
changing solar spectrum yet.
This research provides an insight into this issue. Instead of changing the
function of spectral response, I changed the solar spectrum, which irradiates
solar cells through spectrum conversion to improve solar cells efficiency. This
research uses one kind of coral fluorescence proteins (DsRed) and one kind
of artificial fluorescence dyes (Cy-5) as the materials of spectrum conversion.
Then coat them on the low-cost and high-market-share mono-crystal-Si.
According to the theories I researched and my experiments, the improvement
of the efficiency is about 3~5%, which proves it is actually useful to elevate the
efficiency of solar cells through spectrum conversion.
3
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()
1 ..........................................................................................................................9
2 ...........................................................................................................11
3 ....................................................................................................................13
4 ........................................................................................................................15
5 ....................................................................................................................16
6 ..........................................................................................17
7...................................................................................................................................18
()..........................................................................................................................................20
()....................................................................................................................................................20
... .................................................................................................................................. 21
()
()
........................................................................................................................................ 222
.......................................................................................................... 233
INVERTED PYRAMID...................................................... 233
ANTIREFLECTION COATING ............................................... 244
..................................................................................... 244
................................................................................. 244
DSRED.............................................................................. 255
CY-5 ................................................................................. 255
................................................................................................................... 266
EXCITATIONEMISSION .................................. 277
PHOTOBLEACHING ...................................................................................... 287
............................................................................................................................. 28
SPECTRAL RESPONSE.......................................................... 28
................................................................................................................. 29
DSRED.........................................................................29
CY-5............................................................................... 30
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................................................................ 321
............................................................ 321
FLUORESCENCE PROTEIN ............................................................. 32
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5
.................................................................................................... 35
................................ 36
............................ 36
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.................................... 37
DSRED ................................. 38
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()
Spectral Response
()
1
2
3
4
5
()
Utrecht
()
1.
-
(1)
(Eg)-
JL(max)=qFEg
F q
JL =
0 R
H X
JL 0 =0 F
pn
JSC=JL
n p
Jsc=Jn+Jp+Jdr
n+/p
9
5%~12%
2%~5% 90%
(2)
Voc = AkT/qln(
Isc
I0
+ 1)
I(V)=0 V=Voc
(3) R R Rm
Pm = Vm Im
FF =
Pm
Vm Im
=
Voc Isc Voc Isc
FF FF FF
A
10
2.
Pin
(1)
(2)
(3)
pn
11
(4)
(5)
x x
pn
(6)
12
3.
n0
1.5 n s 3.3 n 2. 2 0.58m
0=0.58m 70nm~80nm
TCO TCO
TCO
12mA/cm2~16 A/cm2
18mA/cm2~19 A/cm2
(3)
13
(4)
14
4.
n( ) ( )
JL =
Eg
J L ( ) d
Eg (spectral response) Sr ( )
p-n
in ( ) R( )
S r ( )
J L ( )
q0in ( )[1 R( )]
inc ( ) I in ( ) Pin
I in ( ) = hinc ( )
Pin = dx dy d I in ( )
h
15
5. &
(1)
green fluorescence protein 238 26,888 Da
1992 Friday Harborjellyfish, Aequorea victoria
GFP
1994
reporter
1 DsRedDiscosoma sp
Cy-5
(2)
[1]
[2]
[3]
Excitation
Emission
(3)
16
6.
(1)
[1]
[2]
[3]
[4] DsRed
[5] Cy-5
(2) ()
=
(3)
ExcitationEmission
(4)
= F(, , )
(5)
( 4 ) ( 2 ) 6%
17
7.
(1)
[1]
pipette 10 g
[2]
[3]
90 g
[4]
543nm
[5]
100 g
[6]
[7]
P=IV
18
(2)
1.
2.
3.
4.
DsRed
Cy-5excitationemission
5.
**
19
()
1.
(1)
3%~5% 6% 50%~83%
(2)
20
(3)
3%~5% 6% 50%~83%
(4)
2.
(1) 500nm
500nm
(2)
()
20
()
(1)
(2)
(3)
(4)
()
Spectral Response
21
()W.G.J.H.M. van Sark and A. Meijerink, Modeling Imprivement of Spectral Response of
Solar Cell by Deployment of Spectral Converters Containing Semiconductor Nanoctystals
Semiconductors, Vol. 38, No. 8, 2004, pp. 962-969.
()S. Silvestre, A Fast Low-Cost Solar Cell Spectral Response Measurement System with
Accuracy
Indicator
IEEE
TRANSACTIONS
ON
INSTRUMENTATION
AND
()( 93)
22
inverted pyramid
23
antireflection coating
24
DsRed
Cy-5
25
26
excitationemission
photobleaching
27
Spectral Response
28
DsRed
29
Cy-5
30
31
Select Sample
Dispose Buffer
Excitation
fluorescence protein
32
33
34
35
36
37
DsRed
38
39
40
Si-