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O O

DsRed
Cy-5
3~5%

Abstract
Energy crisis has become more and more serious in recent years, which
makes recycled-energy development is a must. Among different recycled
energies, solar power has two advantages, that is, easy-to-use and endless
supply. However, the conventional solar cell makes poor use of the solar
spectrum

because

the

solar

spectrum

is

mainly

composed

of

short-wavelength, which cant fit to most of solar cells which is more sensitive
to long-wavelength. Currently, the major method to improve the efficiency is
change the function of spectral response, such as concentration lens, tracking
devices, and antireflection coating. Up to now, no one notices the possibility of
changing solar spectrum yet.
This research provides an insight into this issue. Instead of changing the
function of spectral response, I changed the solar spectrum, which irradiates
solar cells through spectrum conversion to improve solar cells efficiency. This
research uses one kind of coral fluorescence proteins (DsRed) and one kind
of artificial fluorescence dyes (Cy-5) as the materials of spectrum conversion.
Then coat them on the low-cost and high-market-share mono-crystal-Si.
According to the theories I researched and my experiments, the improvement
of the efficiency is about 3~5%, which proves it is actually useful to elevate the
efficiency of solar cells through spectrum conversion.
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() ......................................................................................................................................... 7
() ......................................................................................................................................... 7
() ......................................................................................................................................... 8

()
1 ..........................................................................................................................9
2 ...........................................................................................................11
3 ....................................................................................................................13
4 ........................................................................................................................15
5 ....................................................................................................................16
6 ..........................................................................................17
7...................................................................................................................................18

()..........................................................................................................................................20
()....................................................................................................................................................20
... .................................................................................................................................. 21
()
()
........................................................................................................................................ 222


.......................................................................................................... 233
INVERTED PYRAMID...................................................... 233
ANTIREFLECTION COATING ............................................... 244
..................................................................................... 244
................................................................................. 244
DSRED.............................................................................. 255
CY-5 ................................................................................. 255
................................................................................................................... 266
EXCITATIONEMISSION .................................. 277
PHOTOBLEACHING ...................................................................................... 287
............................................................................................................................. 28
SPECTRAL RESPONSE.......................................................... 28
................................................................................................................. 29
DSRED.........................................................................29
CY-5............................................................................... 30
....................................................................................... 30
................................................................ 321
............................................................ 321
FLUORESCENCE PROTEIN ............................................................. 32
....................................................................................... 33
..................................................................................................................... 33
....................................................................................................................... 33
........................................................................................................ 34
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5

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............................ 36
............................ 37
.................................... 37
DSRED ................................. 38
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()

Spectral Response

()
1
2
3
4
5

()

Utrecht


()
1.
-

(1)
(Eg)-

JL(max)=qFEg
F q

JL =

qF( )[1 - R] ( )e- ( )x dx}d

0 R
H X
JL 0 =0 F
pn

JSC=JL
n p
Jsc=Jn+Jp+Jdr
n+/p
9

5%~12%
2%~5% 90%

(2)

I(V) = Isc - I 0 [eqv/AkT - 1]


V A T K I0

Voc = AkT/qln(

Isc
I0

+ 1)

I(V)=0 V=Voc
(3) R R Rm

Pm = Vm Im

ImVm Voc Isc Pm


FF

FF =

Pm
Vm Im
=
Voc Isc Voc Isc

FF FF FF
A

10

2.

Pin

(1)

(2)

(3)
pn
11

(4)

(5)
x x

pn

(6)

12

3.

(1) PERL(passivated emitter rear rocally diffused)


SiO2
Al-Si

(2) (antireflection coating)

n0
1.5 n s 3.3 n 2. 2 0.58m
0=0.58m 70nm~80nm
TCO TCO
TCO
12mA/cm2~16 A/cm2

18mA/cm2~19 A/cm2
(3)

13

(4)

14

4.
n( ) ( )

JL =

Eg

J L ( ) d

Eg (spectral response) Sr ( )
p-n
in ( ) R( )

S r ( )

J L ( )
q0in ( )[1 R( )]

inc ( ) I in ( ) Pin

I in ( ) = hinc ( )

Pin = dx dy d I in ( )
h

15

5. &
(1)
green fluorescence protein 238 26,888 Da
1992 Friday Harborjellyfish, Aequorea victoria
GFP
1994
reporter
1 DsRedDiscosoma sp
Cy-5

(2)

[1]
[2]
[3]
Excitation
Emission

(3)

Clontech 632437 100 g PBS -20

16

6.

(1)
[1]
[2]
[3]
[4] DsRed
[5] Cy-5

(2) ()
=

(3)
ExcitationEmission

(4)
= F(, , )

(5)
( 4 ) ( 2 ) 6%

17

7.
(1)

[1]

pipette 10 g
[2]

DsRed PBS-bufferPBS10 Mm EDTA


10 glycerol PBS EDTA glycerol

[3]

90 g
[4]

543nm

[5]

100 g
[6]

[7]

P=IV

18

(2)
1.

2.

3.

4.

DsRed

Cy-5excitationemission

5.

**

19


()
1.
(1)

3%~5% 6% 50%~83%

(2)
20

(3)

3%~5% 6% 50%~83%

(4)

2.
(1) 500nm
500nm
(2)

()

20


()

(1)

(2)

(3)

(4)

()

Spectral Response

21


()W.G.J.H.M. van Sark and A. Meijerink, Modeling Imprivement of Spectral Response of
Solar Cell by Deployment of Spectral Converters Containing Semiconductor Nanoctystals
Semiconductors, Vol. 38, No. 8, 2004, pp. 962-969.
()S. Silvestre, A Fast Low-Cost Solar Cell Spectral Response Measurement System with
Accuracy

Indicator

IEEE

TRANSACTIONS

ON

INSTRUMENTATION

AND

MEASUREMENT, Vol. 48, No. 5, 10, 1999


()B. Lounis, J. Deich, Photophysics of DsRed, a Red Fluorescent Protein, from the Ensemble to
the Single-Molecule Level J. Phys. Chem. ,Vol.105, 2001, 5048-5054 Geoffrey
()S. Baird and David A. Zacharias, Biochemistry, mutagenesis, and oligomerization of DsRed,
a fluorescent protein from coral PANS, Vol. 97, No. 22, 10. 2004, pp 11084-11989
()A.Luque and L.Cuadra, FULLSPECTRUM: A NEW PV WAVE MAKING MORE
EFFICIENT USE OF THE SOLAR SPECTRUM Nineteenth European Solar Energy
Conference and Exhibition, 7-11 June 2004.
()H. Field, Solar Cell Spectral Response Measurement Errors Related to Spectral Band Width
and Chopped Light Waveform 26th IEEE Photovoltaic Specialists Conference, September
29-October 3, 1997
()Robert P. Kenny and Andreas Ioannides, SPECTRAL EFFECTS ON THE ENERGY
RATING OF THIN FILM MODULES European Commission
()C.B. Honsberg and A.M. Barnett, PATHS TO ULTRA-HIGH EFFICIENCY (>50%
EFFICIENT) PHOTOVOLTAIC DEVICES 20th European Photovoltaic Solar Energy
Conference, 6-10 June 2005.
() 95

()( 93)

22

inverted pyramid

23

antireflection coating

24

DsRed

Cy-5

25

26

excitationemission

photobleaching

27

Spectral Response

28

DsRed

29

Cy-5

30

31

Select Sample

Dispose Buffer

Excitation

Mix Protein with Buffer

fluorescence protein

32

33

34

35

36

37

DsRed

38

39

40


Si-

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