2010

100018-11

:2010

()

()

ii

NH4OH
573K O2 1%Au/Al2O3 CO+O2
Au/TiO2 250K 100 CO

iii

Abstract
The poisonous gas carbon monoxide which is colorless and tasteless isnt found
easily. It causes a serious threat to our life. We create a poisonous gas purifier that can
issue an alert and convert carbon monoxide into carbon dioxide in short time. It means
this works is promising and special.
The paint of the works is to start the conversion operation in formal temperature.
We also focus on analyzing and promoting the activity of Au catalysts made with
incipient-wetness impregnation method. We found using NH4OH solution and burning
in 73K O2 could activate catalysts efficiently. Even using the same method on Au/TiO2
catalysts can convert up to 100% at 250K. The range of activity temperature is very
wide.
In our experiment, the purifier can convert carbon monoxide completely and make
the concentration under the safe standards. To expend the activity of Au catalysts, we
designed closed gates that can avoid dusts impacting the catalysts when the purifier
doesnt work.
This works with a lower cost of catalyst production process, also can be recycled
and revived. The component of the machine is not only easier to be replace, but also has
high safety. It can effectively prevent poisoning accidents.

iv


98 12 99 1 13
82

CO

2010/01/22

1. (Gold(III)Chloride) AuCl3Strem99
2. (gamma-Alumina) -Al2O3Stremlow soda 99%S.A. =146 m2/g
3. (Titania) TiO2Degussa P25( 15 rutile anatase)S.A.
57.2m2/g
4. (Ammonia) NH4OHMerck25%0.91 g/cm3
5. (Oxygen) O2 99.8+%
6. (Helium) He 99.995+%
7. (Hydrogen) H299.999+%
8. (Oxygen) O2 20% O2 in He
9. ( Carbon monoxide ) CO4% CO in He

()
1.
4-way Valve, Valco
10-way Valve, Valco
sampling Valve, Valco
Gas Purifer, Alltech
Oxygen Trap, Alltech
Mass Flow Controller, Tylan General(FC-280)
Mass Controller Box, Tylan General(RO-28)
U Pyrex 1/4OD 1cm
2.
ADAM-401116 bit Analog Input Module
ADAM-4520Isolated RS-232 to RS-422/485 Conveter
PWR-243Switching power supply for panel mounting
3.
(GC)Shumuzu GC-8A
TEM (High Resolution Transmission

Electron MicroscopyHRTEM)

CO Analyzer Summit 707



1.

Masatake Haruta
COO2

1
Au-Cl
AuCl3
pH Cl- OH- pH 9
Au(OH)4
4

Y. M. Wang pH Au
NH4OH
Au-Cl
NH4OH Cl 1

1
1

Product

Advantage

A.
Impregnation

B.
Deposition-

Defect

X
CO

()

CO

precipitation
C.

Ours

Load

50 mL

1

CO

B.

2. Gas Chromatograph

1
2
3 U
4
5
6 Column1Chemsorb 102 (5*1/8,S.S)
7 Column2Molecular Sieve 5A (5*1/8,S.S)

(1) GC
(2) He
1CO(7.6 torr) 10
O2(76 torr) 2CO(15.2 torr) 40SCCM20
run bypass

(3) CO+O2 10
GC 60

(4) 1 He
2 4
(5)

steady state

3.

GC
GC
GC


GC

4.

CO C-
CO C-Balance bypass

C-Balance

C Balance = PCO + PCO2

)P

CO , feed

CO Conversion =

PCO
PCO + PCO2

5.
Differential Form

CO
CO Activity = CO Conversion 40

cm 3
1mol
1 min
1 0 0 or 2 0 0 CO

Au catalysts
3
min
60 sec
22414 cm

weight ( g )

6.TEM

 10

7.

8.

Electronic fan

Warning

Circuit

Airflow Poisonous Purifier

Process

Catalyzer

Recycle

Analysis


1.
(1)

SnO2
0.005%0.5% CO
CO

(2)
(2.1)
(2.2) ppm CO

10

2.
(1) 1%Au/Al203
(1.1)
80120nm Al203
N2 823K
823K O2 1 ( N2O241)
O2 N2

(1.2) B.C
BDeposition-precipitation
1g Al203 50ml
11 Ph 10.5 AuCl3
10ml AuCl3
1.5 1

COurs
Al2O3 AuCl3
10ml

11

 Au/Al2O3
11 pH 7 383K 4

(1.3) GC
(2) 1%Au/Al203
(2.1) 573K O2
(2.2) GC
(3) 1%Au/Al203
(3.1)
(3.2)NH4OHNaOH
(3.3) GC
(4) 1%Au/Al203
(4.1) 573K O2
(4.2) GC
(5) 1%Au/Al203 1% Au/TiO2
GC

12

(NH4OH)

13

5V 4V LM393 4.5
4.5V

1.
sensor

14

15

2.

1
2
3
4
5
11
12()
13
14
16


454545cm3
CO

CO Analyzer Summit 707

(1) 1%Au/-Al2O3

17

CO

-1
Sensor
-1 -4
Test1 COppm
-1
Sensor

18

(2) 1%Au/TiO2

-6
-5 1%Au/TiO2
1%Au/Al2O3

1%Au/TiO2

19

-4-5
-1 -6
6400ppm 10000ppm

-7

1%Au/Al203

, B
, C

-8

20

 10000ppm
CO -8 C
425K 100 B
C 300K 80
1.

2.

1%Au/Al203

, B
, C

-9
-8
O2

21

-9 573K O2

1.

-9 C 325K 100

2.

1%Au/Al203

, B NH4OH
, C NH4OH
, Cn

NaOH

-10

1.

-10 Cn
300K 38
NH4OH NaOH

2.

NH4OH

22

 1%Au/Al203

, B NH4OH
, C NH4OH
, Cn

NaOH

-11
-11 -10 O2
Cn 300K
100
1.

300K C
NaOH Cn

23

1%Au/Al203 1% Au/TiO2

1%TiO2

-12
-12 C
O2 TiO2 C
1.

-12
(250K) 100%
230C

2.

24

1%Au/Al203 1% Au/TiO2

1%TiO2

1%TiO2

13
13
1% Au/TiO2 200
NH4OH 573K O2
280K CO
100

25

 C 1%Au/-Al2O3
(A) TEM

Activity@573K(moleCO/g-cat./s) 1.190d

-6

(B) Au
100

Average = 2.2nm

90
80

Particle Numbers

70
60
50
40
30
20
10
0
0

10

12

Au Particle Size (nm)

-7

Au(311)

26

14

16

 C 1%Au/TiO2
(A) TEM

-8
(B) Au
100

Average = 3.1nm

90
80

Particle Numbers

70
60
50
40
30
20
10
0
0

10

12

14

16

18

Au Particle Size (nm)

-9

Au(311)

27

20

22

() 10ppm
CO CO
1.5

LED

()
20050
(Check Valve)

NH4OHpH 11.04 AuCl3

2~3nm NH4OH NaOH

28

1%Au/Al203 300K
10000ppm 83% 1%Au/TiO2
273K 100%

B() C (
)

NH4OH

CO

2010 4

29

CO+O2

http://www.scientificamerican.com/article.cfm?id=splitting-carbon-dioxide

James E. Miller (2009) Why not split harmful carbon dioxide into
harmless carbon and oxygen

(2005)
/

Dong-Hai Li, Yan-Xia Jiang, Ying Wang and Shi-Gang Sun

(2008) Silver Nanoparticles Confined in SBA-15 Mesoporous
Silica and the Application as a Sensor for Detecting Hydrogen
Peroxide

Y. M. Wang (1999) The NO+CO reaction over Al2O3- and

30

modified Al2O3 supported Au catalysts / Yuan-Ze University,

Taiwan, The Master Thesis

Jun-Hong Liu, Ai-Qin Wang, Yu-Shan Chi, Hong-Ping Lin,and

Chung-Yuan Mou*

(2008) Synergistic Effect in an Au-Ag Alloy

Nanocatalyst: CO Oxidation

Masatake Haruta (1997) Size- and support-dependency in

catalysis of gold

1K

10K2

330

LED

TIP126

LM393

31

C9012

the

32

SnO2
SnO2

CO 0.005%0.5% CO

Sensor

33

detector
CO

TiO2
Au/TiO2 DRS

Catalyst

TDR

Au Particle size (nm)a

T1/2 (K) c

XRDa

TEM

fresh

O2 573K

29.6

--

>573

310d

a Au(311)
c T1/2

34

1%Au/Al2O3
2
Test 1

Test 2

Test 3

Ppm

sec

ppm

sec

ppm

sec

14

15

16

18

19

20

24

25

26

30

10

31

10

32

10

35

12

33

12

37

12

37

14

38

14

39

14

42

16

43

16

44

16

46

18

47

18

48

18

54

20

55

20

56

20

60

22

61

22

62

22

62

24

63

24

63

24

63

26

64

26

62

26

61

28

62

28

61

28

60

30

61

30

60

30

57

32

58

32

59

32

55

34

56

34

57

34

54

36

55

36

56

36

52

38

53

38

54

38

50

40

51

40

52

40

49

42

50

42

51

42

46

44

47

44

48

44

46

46

47

46

48

46

44

48

45

48

46

48

42

50

43

50

44

50

40

52

41

52

42

52

39

54

40

54

41

54

39

56

40

56

41

56

38

58

39

58

40

58

36

60

37

60

38

60

35

62

36

62

37

62

34

64

35

64

36

64

35

35

66

36

66

37

66

33

68

34

68

35

68

32

70

33

70

34

70

31

72

31

72

33

72

29

74

30

74

32

74

28

76

29

76

32

76

28

78

29

78

30

78

27

80

28

80

29

80

26

82

27

82

28

82

25

84

26

84

27

84

24

86

25

86

26

86

24

88

25

88

26

88

26

90

27

90

28

90

22

92

23

92

24

92

23

94

24

94

25

94

22

96

23

96

24

96

23

98

24

98

22

98

22

100

23

100

24

100

22

102

23

102

24

102

21

104

22

104

23

104

21

106

22

106

23

106

21

108

22

108

23

108

19

110

20

110

21

110

18

112

19

112

19

112

18

114

19

114

18

114

36

1%Au/TiO2
3
Test 4

Test 5

Test 6

Ppm

sec

ppm

sec

ppm

sec

14

15

16

22

23

24

29

30

31

35

10

36

37

10

44

12

45

46

12

49

14

50

11

51

14

53

16

54

13

55

16

57

18

58

15

59

18

60

20

61

17

62

20

63

22

64

19

65

22

63

24

64

21

65

24

62

26

63

23

64

26

61

28

62

25

63

28

60

30

61

27

62

30

58

32

61

29

60

32

56

34

57

31

58

34

56

36

57

33

58

36

55

38

56

35

57

38

53

40

54

37

55

40

51

42

53

39

53

42

48

44

49

41

51

44

47

46

48

43

49

46

45

48

46

45

47

48

43

50

44

47

45

50

40

52

42

49

43

52

40

54

41

51

42

54

39

56

40

53

41

56

39

58

40

55

41

58

37

60

38

57

39

60

37

62

38

59

39

62

37

36

64

37

61

38

64

35

66

36

63

37

66

35

68

36

65

37

68

34

70

35

67

36

70

34

72

35

69

36

72

33

74

34

71

35

74

32

76

33

73

34

76

30

78

31

75

32

78

27

80

28

77

29

80

25

82

26

79

27

82

25

84

26

81

27

84

23

86

24

83

25

86

23

88

24

85

25

88

21

90

20

87

23

90

21

92

21

89

22

92

21

94

22

91

23

94

20

96

21

93

22

96

20

98

21

95

20

98

18

100

18

97

19

100

38

/
/
/ Dr. James L.Miller
/
/
/
/

/
/
/
/
/

39