Professional Documents
Culture Documents
PROCEEDINGS
OF THE
SEVENTH OIL SHALE SYMPOSIUM
VOLUME
69, NUMBER 2
APRIL 1974
QUARTERLY OF THE
COLORADO SCHOOL OF MINES
Volume 69
April 1974
Number 2
PROCEEDINGS OF THE
SEVENTH OIL SHALE SYMPOSIUM
James H.
Gary, Editor
Colorado School
by
American Institute
Metallurgical
and
of
of
Mines
Mining,
Petroleum Engineers
$6.00
Guy
T. McBride, Jr.
President
1974
by
and
of Mines
Published quarterly
Second-class postage
at
Raese, Director
ii
of
of
America
Publications
CONTENTS
Foreword
Energy Source
Sidney Katell, Reid Stone, and
In Situ
Paul Wellman
Richard D.
Ridley
21
Associated Minerals
Ben Weichman
Oil Shale
25
Processing Methods
Thomas A. Hendrickson
Oil Shale
and
the
45
Energy Situation
Wayne E. Glenn
The Environmental
71
Story
79
H. Michael Spence
Colorado's Involvement in
of
John W. Rold
Water Prospects for the
Felix L. Sparks
Air Pollution Aspects
of
in Northwestern Colorado
103
Lane W. Kirkpatrick
of
109
Cooley
John S. Gilmore
and
or
Boon
Mary
K.
Duff
119
125
Robert E. Giltner
and
Water
Roland C. Fischer
Cultural Resources
of
133
Western Colorado
James J. Hester
Development
of
Harry C.
Colony
141
Technology for In
Carpenter
and
Harold W. Sohns
143
Paul W. Marshall
Oil Shale: A Roadblock
171
and a
Solution
Clifton W. Livingston
Fischer
Assay of Oil
185
Shale Procedures
Lawrence Goodfellow
Rapid Determination
of
and
of
Mark T. Atwood
.205
by
Thermal Analysis
P. Robert
Reed, Jr.,
and
Philip
L. Warren
iv
221
FOREWORD
The Colorado School
recognition of the
Colorado
same
February 9, 1874,
funds for
Territory
of
the construction
following
of
of
signing
of
the
in
year
centennial
bill appropriating
Scientific American
the
contained
stone
rock as protection
itself ignited.
has
caused
which
by
place
and
to be
experiments
made
with
Sickels,
this substance,
quality."
The
of rock.
The
for
general superintendent of
analyses
proves
produced
item:
news
oil
thus obtained is
of excellent
Despite the
above
processing was
Shale Symposium
the threshold
not
the
of
the
first time
to
shale oil
to the energy
from
being
oil shale.
This is
needs of
their country.
In
on
for
view of
the
and
increasing
that
now
to
supplement
It is the
the
purpose of
to the development
of
liquid
disseminated.
participants
this
who
and gaseous
fuel
needs of
the
this
industry by providing
value of
contribute
our
and
anticipation of
decreasing reserves
industry
held in
was
wish
through
to
the
workers
express
their
work
forum
in this field
appreciation
and
contribute
at which
the
be discussed
can
to the
presentations
country.
authors
and
establish
the
symposium.
Sidney Katell1,
Reid Stone2,
and
Paul
Wellman3
ABSTRACT
The
need
to
time to satisfy
meet new or
is
not
take its
future.
higher
supplemental
but
definite
sources and
with
at
the
same
flexibility
to
requirement
for
today.
developed to
to be
needs
resources,
our nation
place
among
High-grade oil
Colorado, Utah,
equivalent of
energy
standards as we move
desirable,
only
Shale oil,
develop
shales
and
of oil which
estimated
is
equal
to
contain
to the total
the
known
Environmental
industrial
complex
This
and region.
the
concerns
but
the
are
broad
effect on
presentation
encompass
the surrounding
is focused
responsibilities of a potential
and
on
not
only the
socio-economic area
developer.
INTRODUCTION
publication, Bureau of Mines Technical Progress Report
dated October 1971, presented a description of one of the processes
44,
that
previous
could
be
refined
to
system
was
used
to
produce
various
analyzed
operating costs,
and
and
liquid
to
a product
products.
included the
The
that could
be further
economics
of
estimated
on a
capital
such
investment,
12-percent discounted
cash
xChief,
Department of the
Quarterly
flow
(DCF)
rate of return.
that evaluation
The
into
of the
Colorado School
The
the
size of
plant
of
that
Mines
was considered
100,000-barrel-per-calendar-day unit.
study for a 50,000-barrel-per-calendar-day
in
was a
present
account the
increased
costs
due to
in the economy
changes
takes
plant
and some
additional
waste
and
disposal
The study is
still
development
( R&D )
identified
will
be
as
of an
An
day
for
program.
changes
Therefore,
additional
be necessary
locations.
are
equipment
struction
(plants),
working
produce
of
interest
capital
and
chemicals
during
and
87.304 tons
per stream
catalyst,
development
day
or
for mining,
installation
equipment
and
DeBeque, Colo.,
retorting, pipelining to
In addition, the costs
to
estimate
oil shale
Included
and
both in
area considered
leasing
allow
and
for the
to
preliminary
required
The
interest
(mine),
account.
The
78,574 tons
during
con
startup expenses,
is designed
mine
per calendar
day
of
of
mid-
indexes.
The total
coke,
operating cost,
price of
annual
the oil
would
after
taking
credit
byproducts,
is
$59,620,000,
barrel
at
be $5.66
per
and
the selling
allowing for
12-percent DCF.
The 100,000-barrel
report
was
reevaluated
incorporating
the
modi
A brief description
calendar-day
plant.
of
the processing
Oil Shale
8
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53
U
I
X
a O
at
IS
uat
at
Quarterly
Colorado School
of the
of
Mines
MINE
Development
The
development
mine
be
will
three headings
by driving
started
from the outcrop into the top bench of the minable section of the oil shale
seam. The headings will be 30 feet wide by 31 feet high with 60-foot
center
be
heading
be
turned and
be
headings
clear of
be the
main return
will consist of
three
outcrop.
in
entries similar
The
airway,
heading
that at 600
assumed
will
the
It is
ment
will
heading
be
can
develop
function
size and
to
main
the
this
is to
the
system
ventilation
mine
The left
be
will
haulage
and
the
mine
the working
Also,
time.
plan
area
the
limits
the retreat.
With
mine until
mined on
production
in the
shortest possible
be concentrated, better
will
will
be
side will
full
at
the
right side of
and
result,
general
of
control
supervision
will
be
enhanced.
Sufficient
The
crews will
places
be
be
will
provided
The
a
heading
wide.
around
Sixty-foot
and
by
1,020 feet
28-foot bench
square
scaling
and
bolting
trucks.
1,860
33-foot
60 feet
and
load
heading jumbo,
equipped with a
to
pillars,
road.
using
The headings
regularly spaced,
are
are
left for
support.
main
jumb,
loaders,
and
The
panel.
be
crushers
discharge to
roof will
be
main
wil
60-inch belt
haulage belt
supported
by
be left between
Ventilation will be provided
barriers
rigs,
bulldozers, front-end
The
bolting
trucks.
ore will
The
and
roof
panels and
by
conveyor which
transports
conveyor.
bolts
on
6-foot
development
centers.
on main
Sixty-foot
headings.
at
the
main
Oil Shale
Direction
portals.
of
Portable blowers
and overcasts.
tubing
with
by
crosscuts, regulators,
provide
ventila
secondary
tion.
provide
is
24-hour
conveyed
day,
stream
shale
the
is
run-of-mine shale
The
3,638 tons
The
crusher
per stream
directly
underground
surge storage.
to the primary
or
conveyed
concrete
hoppers
are
to
sized
hour.
Six conveyors, 42 inches wide by 200 feet long, are required. The
is dumped into six parallel feed bins sized for 30-minute holdup. From
feed bins
crushers
shale
the
The
is fed
the size
where
is then
shale
conveyed
from the
by
to 24-hour
surge storage.
storage
screens
fraction is fed to
shale
the crushers
where
it is
in
reduced
the
with
size
to
undersize
from the screens, is then conveyed to the tertiary crusher feed bins.
The shale from the tertiary crusher feed bins is fed by vibratory
feeders over grizzly bar screens (3-inch openings) to the crushers. Sixty-
five
is
crushed
the
to
percent of
to
the
is fed to the
most, but
all,
feeds
The double-deck
screen and
screens are
screens, along
and the
in the
splitter
not
screens and
surge storage
of
the
directly
hoppers,
screen
fines,
to the
so
the
fed
with
minus
by
the
house. The
surge
screens remove
percent
plant.
retorts
of
is then
conveyed
day
of shale
the
bypasses the
retorting
material
The
shale
plant.
through the
vibratory feeders.
from
can accommodate
the shale
remainder
product
per stream
screen.
of
the
briquetting
screens
86,400 tons
65
The
crushers.
From the
The
minus
crushers
surge
top
shale passes
per stream
day,
are sent
to the
Quarterly
Colorado School
of the
Mines
of
BRIQUETTING PLANT
The fines
20-inch belt
the
mills
feeder is
pan
hammer
horizontal
used
is
forces
to
size
number
from the
material
by
conveyor
14-mesh.
minus
(binder). The
the
on a
2. A vibratory
to two parallel double-paddle
bin
surge
milled shale
it is
number
vibratory feeders to
by
in
reduced
to
bin
surge
is then fed
it is
conveyed
feed the
mixers where
shale
mills where
shale
to
briquetting
to the
The fine
conveyor.
three parallel
From the
are conveyed
mixers and
it falls into
briquetting machines.
the
The briquettes
are conveyed
are sent
back to the
feed
retort
to
bin
surge
number
and
then
conveyor.
RETORT PLANT
The retorting plant, consisting
close
56-foot-diameter units,
of six
will
be
to the mine.
The
from
shale
briquetting
One belt
bins
plant are
fed
briquettes from
the
and
feed hoppers
to the retort
(atop
tripper is
the
used
the
retorts).
feed
to
the
retorts.
The
discharge
and
Cameron
The
mechanisms.*
feeding
Jones improved
and
discharge
and
in
3, July 1965,
Each
and produces
86,242,000
tons
day
per stream
The
shale
bed in the
per square
zone
to the
the
the
shale
to the
Reference to
standing
retorts
at the
is
top
and
bed,
maximum
specific
not
day
60,
Symposium.
of
shale
of crude shale
low-Btu gas,
maintained at a
of
the
makes
imply
or
area,
the retort.
and
and
oil,
11,160
models
of
preheated
at a rate of
moves
approximately
by
the
500
off gases
pounds per
through the
preheat
of about
recycled
endorsement
is
depth
low-Btu
temperature
the
unit
The shale,
use recycled
percent of
does
of excess
of cross-sectional
combustion zone of
About 82
foot
shale
day
stream
per stream
day
per
hour
point of
feet
per
v.
of spent shale.
from the
9,693 barrels
standard cubic
Quarterly,
14,361 tons
processes
retort
briquettes
a paper presented
feeding
mechanisms are
of
by
gas
1,300F.
equipment
is
the Bureau of
made
to
Mines.
facilitate
of
the
under
Oil Shale
is
retort and
discharge. The
fed
directly
The
to
used
the
The
removal, to supply
flows
to
is
for
fuel
is fed to
oil,
of
separation
pumped
compressed
other plant
for
either
recycle
after
or,
sulfur
requirements.
60-inch
a common
conveyor
a canyon.
by
prior
electrostatic precipitators
is then
is
gas
spent shale
The
to approximately 200F
the retorts,
of
and
crude
The low-Btu
into
top
rotoclones
charge
spent shale
from
gases
The
the
cool
to the combustors.
flow through
site.
pipeline
day,
per stream
DeBeque, Colorado.
near
proposed
consists of
two
to
for H2S
alternately
The
removal.
and six
system
identical tanks,
carbon
small
amount
number
of
and
Regeneration is
ammonium
number
The
until
the
number
tanks 2 through
The
carbon.
vapors
cumulated
tank
The
dissolving
1
This
is then
treatment
is
and
number
5 from
A few
drained
relatively
where
they
am
residual
the solution is
contacts
solution
steamed and
percent solution of
immersed in
are
is fed to tower
bed for
pumped
the sulfur,
extraction
in tank
content of about
number
solution
layers
is first
by
from
sulfur
service.
condenser
are pumped
to
and
free
The
ac
solution
4.
After the
tank
so
solution
15
in tank
number
solution
4,
carbon
from
carbon
for
by extraction with
by steaming of the
followed
sulfide
gas
sour
carried out
as evidenced
process
has been
repeated
several
times,
the
number
6 from
is heated
where
with
it flows
steam
and
by
gravity to the
the
polysulfides
evaporator.
are
The
decomposed.
in tank
number
5.
Quarterly
of the
Colorado School
The
solid sulfur
The
to 85
long
The
tons
in
water
day,
per
purified gas
is
is
from
removed
in
of
bottom
the
Mines
of
the
evaporator.
a centrifuge.
from
used as plant
fuel.
direct
be
will
water runoff
constructed
below the
watershed.
vent
surface
water
falls
water which
After
directly on
sufficient
for
ground
percolation
the pile
could
it is
be
bulldozers
compacting the
to
pile
shale
to
pile.
pre
Therefore, only
rain
contaminated.
completed
proposed
two
Also,
spent
disposal,
waste
and
to afford space
to slurry the
spent
under
shale
and
disposal
area.
It is
be
The
to
would
cost of
anticipated
used without
an aid
It
system.
slurry
that
treatment
within
the
ing disposal
operations.
However,
treatment
in slurrying the
treatment
such
water collected
spent material
downtimes
Consequently,
require release
an allowance
is
to
dur
be
re
streams
made
for
REFINERY
The
crude
is
is
crude oil
preheated
separated
into
from
in
storage
furnace
50
about
is
charged
enroute
percent
to
distillation
to a
column.
distillation. The
The
crude charge
and
50
per
cent
as
vapor
described later.
The bottoms from
to
being
the cokers,
charged
coker
flow through
to the coking
distillate,
is
The feed is
preheated
drums. The
cooled and
product
depropanized
preheat
to about 940 F
and
then,
of
together
Oil Shale
distillation overhead, is
the
with
60
835
1,500 psig
and
from
gas streams
follows:
hydrogen sulfide from the
an
ammonia-
gas.
The
is
off
traces
remove
pressurized
monia
(137.75 tons
for
to
the
produce
for hydrogen
day)
the
is
plant
coking,
and
dis
recoverable
The
streams
to remove the
used
is then heated to
is
reacted with
per calendar
The
sale.
which
hydrogen
is
generation
manner), the
day)
ammonia-
which
water solu
is cooled, condensed,
result
conversion
am
and
treating section is
for hydrocracking. The
to
gas
produce
hydrocarbons in the
involves two
76
percent of
->
-*
the gas.
gas react
in
an
steps:
CO + 3H2
(1)
(2)
C02 + H2
being
CH4 + 2H20
reaction
needed
converted
( other
CO +H20
the overall
from the
CH4 + H20
The first
for
washed gas
methane as an example
analogous
for
and
per calendar
hydrogen theoretically
with
is
The hydrogen
and stored
to 230 psig
percent of
steam reformed
Using
The
in liquid form.
sale
About 89
the
range.
storage.
water wash
hydro-
containing
are used
(42.75 tons
sulfur
hot liquid
tion is
gas used
to
pumped
sulfide which
of ammonia.
recovered as a
stored
removal,
coke
hydrogen
the
The
sale.
boiling
170F to drive
The
coker and
in
for
hydrogenation, delayed
used
air
is
hydrogen
of
stored
gasoline
sulfur
product
the
are processed as
to
is
materials
acid
for
hydrogenation.
to
in the
treatment
after
gases,
day,
per calendar
uncondensed
tillation
charged
takes
place
->
C02 + 4H2
in tubes
at
50 psig
(3)
and
1400 to 1500F
The hydrogen
800F,
as
hydrogen
yield
is increased
illustrated
purification
cracker units.
by
by
before
compression and
A hypersorber is
used
for
10
Quarterly
of the
Colorado School
of
Mines
CAPITAL INVESTMENT
A summary
the
capital
per
catalyst
and
expense,
and
for
the estimated
mine and
tons
the
of
shown
The total
capital.
working
equipment
required
necessary to
in table 1.
to
develop
87,304
process
Included
development
during
interest
chemicals,
investment
are
initial
(mine), startup
estimated capital
investment
for
vestment of
shown
in table 2.
The
cost of
box"
type
arrangement and
of
Table
1Capital
investment summary
50,000-barrel-per-calendar-day
Mine (initial
Retort
plant
$15,602,300
investment only1)
plant:
67,074,300
Retorting
Crushing and
Briquetting
Refinery
11,104,600
1
2,950,700
2,922,400
71
Utilities
42,149,200
Faci 1 i ties
14,218,900
Solid
Total
sulfide
removal
catalyst
plant
Interest
and
during
construction
Startup
expenses
(pi ant)
Total
-i
capi
tal
capital
,854
,500
and
tax
(plant)
base)
234,736,600
10,956,700
(mine)
468,100
7,450,600
253
,612
,000
25.838.100
investment
Deferred capital
,800
5,553,900
chemicals
(insurance
cost
,305
229,182,700
construction
Initial
Total
disposal
waste
Hydrogen
screening
279,450,100
Oil Shale
Table
2.Capital
investment summary
100,000-barrel-per-calendar-day
(initial investment
Mine
Retort
11
plant
$31,901,400
only1)
plant:
Retorting
Crushing and
Briquetting
Solid
Hydrogen
screening
,731
disposal
waste
133,365,900
21,577,500
1
5, 835, SCO
5,840,900
sulfide
systei.i
removal
Refinery
,500
124,248,000
Uti 1 i ties
80
Facilities
24,564,100
Total
Total
catalyst
plant
Interest
and
during
construction
Startup
expenses
11,110,300
chemicals
(insurance
cost
and
tax
440,214,900
base)
(plant)
20,415,700
(mine)
950,100
(plant)
13,882,700
Working
,500
429,104,600
construction
Initial
,039
475,463,400
46,912,000
capital
522,375,400
Iltef erred
capital
investment
shown on
table.
An
allowance of
capital requirements
assumes a
The
2-year
construction period.
cost of
compressed
ministrative
plant
facilities. A summary
of
utility
and
facility
costs
is
given
in table 4.
12
Quarterly
Colorado School
of the
of
Mines
3.-
Table
Working capital
50,000-barrel-per-calendar-day plant
Cash
Accounts
receivable
Inventory
30 CD operating
cost...
$5,167,600
90 CD operating
cost...
15,502,900
30 CD operating
cost...
5,167,600
Total
1001
25
includes $5,380,300
for the
,838,
mine.
OPERATING COST
See table 5 for
the
25
the
raw water
mines,
surance, royalty,
872,700 before
summary
per
of
for the
payroll
and
credit
overhead,
35
catalyst
payroll
percent of
and
labor,
are
costs
the
for
costs
overhead
for
payroll
chemicals,
taxes, in
depreciation. The annual operating cost is $62,for the byproducts and $58,620,000 after credit. A
the estimated
day plant
plants and
annual
charges,
operating
Included in operating
plant.
the
percent of
summary
50,000-barrel-per-day
labor supervision,
of
annual
operating
costs
for the
100,000-barrel-
is found in table 6.
A summary
of
byproduct
credits
is
shown
in table 7.
UNIT COST
A breakdown
of capital and
cessing systems,
including
hydrogen
removal,
sulfide
$18,045,700
required
per
of
daily
for
of
barrel
partially
of
refining, is
and
$3,519,400
considerations.
capacity,
refined crude.
cost charges
mining, retorting,
ecological
operating
and
solid
shown
of
The
to the
waste
disposal
in table 8.
the annual
capital
major pro
A total
operating
amounts
and
costs
of
is
to $360.91
per
barrel
Oil Shale
13
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14
Quarterly
of the
Colorado School
5.Estimated annual
Table
of
operating
50,000-barrel-per-calendar-day
Mines
cost
plant
$164,700
Natural gas
Water use charge...
...390
gDh
8,760 hr/yr
Operating
Operating
$0.026/M
ot}
,273
,500
?q ?nn
htc
7nn
oci onn
^51,200
maintenance
labor..
3,075,700
07I 'cnn
375,500
1,323,700
124,200
6,198,400
of
labor...
665,400
supervision).
1,624,900
plant maintenance
plant...
...(25%
of
plant
labor
and
overhead, mine...
...(35%
of mine
labor
and
supervision)..
Royalty,
$0.12/ton
at
of
shale
mined
ati on
Annual operating
Byproduct
Net
oS'SX
plant...
...20%
Depreci
onn
gal...
supplies, mine
supplies,
Payroll overhead,
Payroll
annual
cost
174,100
452,200
398,900
2,394,000
2,112,400
2,474,500
2,183,400
3,400,200
17,452,500
58,620,000
$62,872,700
18,250,000
After credit,
,800
4,252,700
credit
Cost/barrel of oil
Before credit,
673
62,872,700
cost
operating
2,220,800
1
$58,620,000
18,250,000
*0
t~
nc
$3-45
01
$3'21
Oil Shale
6.Estimated annual
Table
cost
operating
100,000-barrel-per-calendar-day
15
plant
Annual
Annual
catalyst
...720
gph x
and
8,760
Maintenance labor,
hr/yr
supplies,
mine
supplies,
plant
plant
maintenance
labor)
plant
overhead,
gal
plant
Payroll
$0.025/M
chemicals
Operating
Operating
164,000
6,557,000
4,344,500
596,200
5,224,300
463,700
5,224,300
7,747,100
563,200
1,799,100
372,600
12,396,700
1,137,600
2,657,200
3,668,700
supervision)
56,670,265
Royalty
Annual
operating
Byproduct
tpy
$0.12/ton
Cost/barrel
of
t
5J'13
eo on
$2*89
36,500,000
7.Byproduct credit
Table
50,000-barrel-per-calendar-day
Sulfur (retort gas)
.85
,500
oil
$105,500,900
Annual Credit
x
365 CD/yr
Coke
855 t/CD
365 CD/yr
Total
t/CD
$20/ton
365 CD/yr
42.75 t/CD
.137.75
plant
t/CD
Sulfur
..
4,740,300
4,182,700
4,324,300
3,815,500
32,162,500
6,800,400
105,500,900
cost
After credit,
Ammonia
913,600
806,100
8,651
$114,152,400
36,500,000
261,100
114,152,400
cost
Before credit,
2,900,300
credit
Net operating
cost
5329,400
Natural gas
Water use charge.
$20/ton...
$5
365 CD/yr
620,400
312,100
1,560,400
$35/ton.
1,759,800
$4,252,700
Quarterly
16
of the
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Oil Shale
17
FINANCIAL ANALYSIS
Table 9 is
based
on a
financial
analysis
12-percent discounted
for
cash
the
flow
50,000-barrel-per-day
plant
takes into
(both before
and after
startup) and the present value of the positive cash flow after depreciation
is taken. A selling price for the oil of $5.66 per barrel is required to
balance the present value of the positive cash flows, using 12 percent com
pound and
the
discount factors
100,000-barrel-per-day
and a
unit,
and a
selling
same
price of
information for
$5.15
per
barrel,
is
The depletion
assumed value
allowance used
for the
in the financial
$2.80
per
analysis
barrel.
is based
on an
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Richard D.
Processing
has
tion
from this
long
Mining
dramatically less,
have to be less,
processing
of
dream
the
immense
the ore
and
and
as
several
systems.
and
failure
times
result
point
alone
been tried in
between
success,
know,
in
situ
oil
is
shale
this
to
closely
such as
being
But in
Accepting
to
no
almost
Some
wells.
we concluded
modified
tightly
in-situ
packed
facts
process
of negligible
consists
but broken
and subsequent
breakage
for
in tight
flow
technical
fractures,
even
porosity
and
would
yield
situ process
of
oil shale
of
caused the
limited
this
met
has
techniques have
paths
the
overcome
and
For
and
partially
negligible.
that a modified in
advantages
projected
flow
for
prospect
is it found in
which
fracturing
maintain combustion
known
had any
no
commercial success.
alone,
conventional
obvious
was also
essentially
Development Company has taken
and
the
to
recoverable
and aboveground
Garrett Research
which
create adequate
spaced
able
not
factor,
tests. Most
an attempt
mining
even
approach.
advantages were
increase the
would
formations. It is
of most
oil produc
in-situ
the total
one
as most of you
The
as
The latter
economically.
by
been
nations
obvious.
reserves
of oil shale
processing
Ridley
proven
creating
by
overlying
oil shale
by
different
permeability,
many
the
of
disadvantages.
underground
mining the
The
chimneys
of
the
use of conventional
explosives.
In its
simplest
form,
the Garrett
process consists of
three basic
Garrett Research
21
and
Development
the
steps:
over
normally
Company, Grand
22
Quarterly
in NTU
using
the
creates
step
Colorado School
of the
lying
the
to
zone
oil shale
the surface,
in the form
void volume
it may
where
be
The
retorted.
be
either
The mining
retorting.
underlying or over
mined is conveyed to
room
rock
step in the
second
added
or
and vegetated
stacked
The
of a
Mines
of
to
consists
process
of
with appropriate
timing delays
to fill the
entire
volume, that
volume of
the
the
top
rock
bottom
and
through the
rock
aid of an outside
fuel
ward
the
retorts
left
the
the
on
Part
top
incoming
or
air and
drains
Field
produce shale
carbon
simple
testing
chimneys with
of
low
be formed
drop. In
Bureau
of
in
control
the
the Garrett
Mines has
top
with
the
released
required
fuel. The
additional
it is
in
collected
excess of
fuel.
concentration
significantly in
process started
demonstrating
the
retorted
subsequently
first tests
run at
overall
in
mid-
in
oil
sump
is burned
with
by
another
showing that
efficiently
are scaleups of
Laramie. In
concept
relatively large
and
the
the oxygen
retort where
The
the
part of
needed
down
concept.
sense, these
one
of
to both
circulated
at
the
and
room
The heat
hours.
gas,
becomes
then
bottom
Air is
is initiated
some
oil,
the
spreads out
a matter of
underground storage.
were aimed at
could
for
power generation
is
process
to the
to
for
a potential
tests
and combustion
source
This
shale.
and pumped
The
to
shale
pile,
of
volume
carried out.
of
flows
retorting is
and
breaks,
so
with a
low
NTU retorts,
sense,
pressure
such as
the
however, they
are
dramatically
reactor
vessel
having
system
may
relatively
also
small
be tall but
must
cross section.
have
blasting
target a
distribution
technique must
maximum of
15
contained
Fischer
in
assay.
with
retort
40 to 45
distribute
large
The
retorts
cross section
loading
system
percent void
the mined
in the Garrett
for high
yields
assures an even
volume;
the Garrett
has
as
its
percent.
of
Twelve-hundred barrels
of
60
broken
shale
at
25
of oil were
percent
based
on
storage.
A few
other
interesting
points
can
be
reported
on
this
particular
In Situ Processing
The
experiment.
drilling
2 feet
into it
rock
broken
mass
five locations
at
60 feet thick
was
showed
23
Oil Shale
of
that
subsequent
and
to
rubble existed
1 to
within
the anticipated
agreed, to
rate
modeling
of
a great
the complete
as expected with
recycled,
2 to 4
we were able
did
swered
seal
gas
being
produced
Carbon
normal
and
mining
breadth
new
location,
and width
all
been
an
scaleup to commercial
prepare a 250-foot high retort
now on
We will, in 1974,
of over 100 feet each.
near
have
feasibility
process
the emphasis is
and
affirmatively
first
to
with
will
This
be
room
mined
will
be
at a
essentially
as
commercial room.
Lets turn
situ
this noxious
mathematical
as well as some
proceed safely.
in
with
by
key locations.
in
The
the
CO
percent
to
The
reaction system.
Even
inerts.
and
carbons
extent,
our
processing
attention
to the
now
and compare
them
original
with
this
list
for
of advantages
process as
presently
being
developed.
(1)
A true in
process
greatly
eliminate it. In
be
The Garrett
the
reduces
fact,
the
mining
required
but does
not
mines.
(2)
Spent
is left
shale
nature
of
the
underground
process
requires
so
(3)
that there is
am not
vious
deposition
free to discuss
the
that
spent
will
not
reduced
retort
is
confined
and
kept
In addition, the
location
was minimal
for leaching.
economics, but it
mining
The very
chimneys be
process.
occur.
at our present
process
aboveground
the
shale
that a greatly
most of
in the Garrett
should
be
ob
potential
for
reduced costs.
(4)
Because the
shale
costs are
averaging 25
gallons per
ton;
proceeding
Quarterly
24
with a room
contains
in
10 to 15
yield
industry
low-grade
amount of
reasonable
Because
pillar
the added
of
mining,
several
a given
be
been demonstrated
being
commercial
scaled
process
work
ahead
scale-up.
does
situ
With
to
can
be
This
will
be
be
retorts can
rooms
pillars
160
by
between
ac
160
rooms,
70
obtain
percent of
some
most, but
processing
possible
unforseen
we
do
date.
of
the
oil
all,
of
the
field
It has
conditions
reaching fullscale
There is a lot of
problems
not
of oil shale.
under actual
the objective
with
Nevertheless,
potential
believe it is
totally feasible.
the earliest
and
large
of
yields of
at
in-place to
location
given
systems.
40-foot
work,
for in
up rapidly
operations
development
in the
on a
other
comparable
appear
we
spacing
of our present
chimney,
Admittedly,
processed
rate, but
yields obtained.
would
arise
close
in
it is
for
projected
feet in breadth
On the basis
and
height
high
loss
and economically.
complished and
the pillars
this
be
rock must
recovery from
Mines
of
reserve calculations.
retort
overall
times that
of
is
and
oil-production
(5)
ton
gallons per
government and
large
Colorado School
of the
will
probably
any technological
process unattractive.
Ben Weichman
THE SUPERIOR PROCESS
Oil
processed
in
one
a substantial and
and
integrated
both
of
locally
which, in part,
devastating
Oil
low
if
These
Nitrogen
partial
and
disturbance
simultaneously
offsets
process more
air,
bicarbonate,
be
contradicts a recent
of shale will
may
can
be
than
also
be
produced as
benefit.
the individual
by
process.
because
the environment.
closed-cycle, noncontaminating
and maximum
into
processed
a net enhancement of
be
have
of
processing
dawsonite
This
and
land,
products could
will
be
energy
containing nahcolite
fuel oil, natural sodium
compounds.
the total
other
any
the
on
shale
sulfur
products
of
impact
can
domestic energy
The beneficial impact would be
"mining
quotes
that
produce products
the availability
on
dawsonite
nahcolite and
as well as nationally.
news article
the recovery
to
the environment.
have
a more
operation
beneficial impact
the upgrading
experienced
the minerals
Processing
costs of each
This inte
operation
all
their
with
three minerals
shale
oil only.
The Superior
operation.
The
generalized
steps as
they
description
occur
of each
step is
understand
necessary.
The
oil
follows, beginning
with
Step
I.
Mining
Step I:
To
as
25
26
Quarterly
of the
>
Q
Z
3
Colorado School
Mines
of
LU
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Superior Process
Parachute Creek
Figure 2 is
the
member of
a structure
major syncline
to be
from
shown
located in the
cross section
and
Mahogany
the
which shows
the
three
the
basin
location
the
with a
of a cross
basin.
formation.
also shows
south end of
27
Oil Shale
northern portion of
This map
center.
of
of
map
Figure 3 is the
is
the
Development
for
zones
the
member.
Mahogany
and
It
Upper
the middle,
base.
Zone
and
Mahogany
zones
and
combined
are
Zone"
referred
thin
at
to as the
the
in this
The
paper.
is very
600 feet in the
Mahogany
northern
southern part of
crop
"Mahogany
are made
up
of
It does
Zone.
Mahogany
only the
southern out
not contain
ap
dawsonite.
Leach Zone
The
middle zone
is
the "Leach
called
Zone."
The
This porosity represents salts that were originally deposited in the oil
shale but have subsequently been leached out by ground water entering
via
fractures. The
the zone,
and
have
leaching
of
so weakened
the
the
salts
left
oil shale
voids
that it
as a result of
has
collapsed
leaching
of
into
rubble
the salts,
with
saline water.
Because
of
the
zones
economically feasible to
parts of
the
Much
of collapsed
rock
and
saline
water, it is
through this
zone
not
in many
basin.
geology and
investigated, but I refer you to
to the AIME in Chicago.
more
hydrology
a paper
of
that Weichman
( 1973 )
should
be
presented
Lower Zone
28
Quarterly
of the
Colorado School
of
Mines
cq
Superior Process
for
Development
of
Oil Shale
29
CO
p
o
l-l
30
Quarterly
the minerals
is
restricted
by facies
restricted
Figure 4 is
of
the
The
also shows
that the
nahcolite
the
of
within
that the
It
to the subsurface.
Mines
of
of nahcolite and
the extent
dawsonite. The
nahcolite and
Lower Zone is
Colorado School
of the
significant
dawsonite
and the
extent
This
resume of
plan
is to
Lower Zone
Leach
Zone,
by
the
mine
is
Approximately
65
Because
vary
with
of the
inclined
by
planned
mine plan.
dawsonite from
nahcolite and
room-and-pillar method.
to the
access
containing
the
understand
the
of
overlying
from the out
adit
depth, lithology
estimated
to
room-
in the
is
the
be
area.
in
removed
panels.
Figure 5
losing
a safeguard against
the entire
Great
Zone,
as
guard
against
induced
square enclosed
Mining
an entrance.
mine
care
1,500 feet
to
unexpected water
must
be
fracturing
in
by
panels
is
flow from
upward
into
the
If
Leach
excessive
water
can
entrance.
Any normal amounts of water flowing into the mine can be pumped
directly into the processing system and consumed without being exposed
to
contaminate
the
surface waters.
Step II:
crushing
raw
and
Nahcolite Recovery
nahcolite, is
screening
separated
process.
from the
Figure 6
in the
oil shale
shows
the normal
The
shale.
by
oil shale
approximately 80
shale and
from the
shale
by
screening.
percent pure.
the
photosorting
with
percent pure
from the
scale
The
The
being
mine zone
by
processing, as little
as
60
is
estimated
to
be
fractions are
can be further
various screen
80
goal
percent
nahcolite
percent
this
percent
recovery
process.
may be
of
separated
expected
to
purified
by
the nahcolite, 80
However,
recovered
in
by
commercial
this
process.
Superior Process
for
Development
of
r>
v/
Oil Shale
31
32
Quarterly
of the
Colorado School
Mines
of
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id
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Superior Process
for
Development
of
Oil Shale
OIL SHALE
NAHCOLITE
NODULES
Figure
in
oil shale.
33
34
Quarterly
by
The
percent of
leach
water
Colorado School
of the
the
be
nahcolite can
and recovered
in
Mines
of
separated
the
oil shale
from
the
Step III,
retort.
Step III:
In
retort.
various
the
kerogen in the
is proprietary
this
shale oil
and
is
cess used.
The type
by
Much
cooling.
of
the
most
entirely dependent
retort anticipated in this
and
technology
retort process
time; however,
cases,
low Btu noncondensable gas.
in
at
character of each
the
shale and
into liquid
condensed
liquid
Retorting
The
percentage
almost
on
of
process
is
and
pro
a closed system.
similar
Superior
to the
is
retort process
anticipated
that low
ground
will
to its point
be
oil
refining
mixed
tested at this
and
step.
The
the
spent
with
gas
be
can
produced
in the
and
shale
it is
returned
under
pyrolysis where
pipable
however,
time;
of origin.
Step IV:
The
fuel
sulfur
retort system
being
still
the dawsonite is
takes
decomposed
place
by
in the
heat
Step
III
retort
and converted
will
be
called
into
"alumi
num
The degradation
equation
(1)
of
dawsonite
when
heated in the
is
retort
shown
in
Heat
The
oxide
num
C02
The
sodium
and
>
2NaAl[OH]2C03
aluminum
sodium
carbonate
carbonate
render
insoluble
The
when
much of
the
370 C
(dawsonite) degrades
(Smith 1967).
The
reaction
and
heating
In the
alumi
degradation,
is temperature
above about
sensitive.
670 C
can
available aluminum.
into
(1)
delivered to
in the
light
spent shale
caustic
leach.
Superior Process
Development
for
of
Oil Shale
35
is
mine
dry, by
using the
ion
aluminum
beneficiates
three-
filter to
from
remove
liquor
by filtration.
and conveyed
to the
mine
Figure 8 is
The
liquor
decolorizer
The
ash.
soda
and
dried for
The
market.
in the
heated
of
purge
is
ash
soda
in barometric
covered
system
then
high
The
diagram
a generalized
is beneficiated to
third
is
pure
spent
leached
is
which
separ
is dewatered
shale
of
which
is left
saturation
to evaporate the
liquor,
evaporated
run
The
centrifuged
system
re
is periodically
soda ash
and
the
and
is
crystallizers
mixed with
through
from the
separated
process.
the aluminum is re
after
the
is
clarified
Carbonation
shale.
(Al[OH]3)
spent
decantation
liquor is
saturated
aluminum compound
the
If
for disposal.
sodium carbonate-rich
moved
in the
counter-current
trihydrate
the
ated
Zone.
sodium
or
precipitates aluminum
seeding
sodium carbonate
four-step
liquor. The highly
the pregnant
the Leach
aluminum oxide
and
from
saline water
the
out of
one
the
is the
for market;
fourth is the
under
ground.
Step V:
In
Step V,
dewatered
shale can
size,
The
individual
to the
mine
be
to
plant will
Figure 9 is
shale
first
top.
By
returned
mine
by
for disposal.
conveyor, or,
returned
dictate
by
and wash
The leached
depending
pipeline as a slurry.
which procedure
tanks is
on
spent
the grain
Operations
creep.
by
be
spent shale
to the
and returned
of each
up
leached
the
is
roll
Then,
packed
in the
packing the
the
top
spent shale
eight
feet
tive,
the
in the
The packing
of
the
shale
or so
by
shale and
the
up
the
rooms
the introduction
contains
of
high-speed belt
rooms
top
is filled
to the
in the
to
similar
slinger.
of an addi
to shotcrete.
36
Quarterly
of the
Colorado School
of
Mines
Superior Process
for
Development
of
Oil Shale
37
00
Quarterly
38
of the
Colorado School
of
Mines
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Superior Process
Development
for
excessive
Returning
the removal
cause of
of
all of
the
The
from
eliminates
can
to the
mine
is
50 percent,
by
volume,
will
about
50
per
to
percent
about
90
leached
the
of
spent
is
interstitial
the shale as
is further
of
contained
be noneffluent,
The processing
place
features
for the
except
of all
in
three
by
of
by
back
surface
added
is
water and
shale
to the
not available
the enclosed
underground
disposal. The
spent shale
for
shale-filled panels.
outflow of product.
products
simultaneously
indi
offsets the
cost of
Step VI:
VI is the
Step
railhead, at
the plant
An 80,000 ton
50,000 barrels
colite
2,800 tons
If
so
2,300 tons
The
fairly
per
about
day
per
desired,
per
site,
to
will
day
of oil per
product;
Marketing
delivery
of
the
and
Products
large
market of a
be
is
movement.
the
be
possible
of the
any
water
One
the possibility of
mine.
The
settling.
original rock.
emplacement
tied up in
39
and
maturity
and reduces
of about
processing
volume
pillar
spent shale
The swelling
leached
during
cent of
entering the
water
Oil Shale
of
volume of products.
necessary.
day;
15,000 tons
3,000 tons
per
day
per
of
day
of nahcolite or nah
aluminum
trihydrate;
and
of soda ash.
be
calcined
into
about
day of alumina.
product use of
The
obvious.
potentially be
fuel oil,
aluminum
of major
is
compound
and soda
ash
is
importance.
Nahcolite Use
The
nahcolite product
ecological
of
S02
under
according to
controlled
equation
(2).
(2)
Quarterly
40
Two
parts
nahcolite
percent
from the
to the
in
ticulates
sulfur oxides
tests
various
greater than
90
from
the
absorbed
removed
in
percent of
is
the absorption
nahcolite
prototype opera
is readily
at
least 90
has
also re
tests
equipment
S02 by
of
agent
par
In this process,
in the reaction.
used
the
shown
by
scrubbing
various
The
gas.
stack
dry
Superior in
by
tested
nahcolite
sodium sulfate.
surface
percent efficiency.
than 80
more
percent of
product
has
from
sulfate,
high
gas streams
which pass
The
has been
and
sodium
with
nahcolite
prototype equipment
the
percent of
moved
nearly 100
to
equipment
S02 in
the 13.0
more
gas stream at
The
tions.
Using
powdered
Mines
of
to form
S02
part
one
with
area as
0.5
reacts
dioxide.
Colorado School
of the
nahcolite
is primarily
be 95
percent-plus
to
product
marketable within
the available
limits.
market
implementation
economic
gardless of
its character, to be
emissions standards
Nahcolite
can
defined
be
shale production
than
ton
will
of
nahcolite
produced
shale operation
free for
day
of
Figure 10
shows
shale
sulfur
175
million
Figure 11
with
the
energy
per
year).
nahcolite
use
6.3 tons
by
available
herein,
and
re
violating the
as
will
byproduct from
One
production operations.
of
percent
per
sulfur
day
of
free for
coal
at
nahcolite,
per
day
94,500 tons
use about
oil
oil
per
that the
oil
use
15,000 tons
instead
of
percent
per
day
per year.
of
day
per
nahcolite
This is the
sulfur
western
50,000 barrels
of
0.3
would
equivalent
of nahcolite would
This is
combination of
and
barrels
shows
nahcolite
values
day
without
coal,
percent
cheaply
made
described
more
from direct
allow
will
by law.
proportions.
stoichiometric
used
this process
of
per
day
coal
were
coal, the
than the
combined
300,000 tons
used
(330-day
Superior Process
for
Development
of
Oil Shale
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41
42
Quarterly
of the
Colorado School
of
Mines
Superior Process
At this
estimated
Oil Shale
to be
over
technology
have to define
will
However,
Pilot mining
operations
high
nahcolite
would
nahcolite
to the
free
production
barrels
The
major
development
94,500 tons
clean
of oil per
could
day
of
43
150
years of
the Parachute
a use or safe
problems
are not
1974,
and
as much as
day
of
marketing
production
disposal for
the
level,
sodium
impossible.
concentrating initial
5,000 tons per day of
day
of nahcolite per
This is the
for
326,000
minerals
equivalent
of
available as clean
and
be
wildlife
in
deliver
clean and
At that
certain
about
energy.
energy
would
per
nahcolite,
overcome.
beginning
in 1975.
surface
over
of
zones,
these
day
per
have to be
problems would
sulfate produced.
on
place
300,000 tons
production of
logistic
ly
in
of
member.
At
new
Development
production, there is
supply
Creek
rate of
for
a more
"devastating
domestic,
consumed without
degradation
a net enhancement of
impact
on
the
land,
adequate,
the
air,
of
environ
water
and
REFERENCES
Weichman, B. E., 1973, Depositional history and hydrology of the Green River oil
Paper presented,
shale, Piceance Creek basin, Rio Blanco County, Colo.:
Am.
Metall.
Petroleum
Mtg.
Inst. Mining
Engineers, Feb.
Chicago, 102d Ann.
25-Mar. 1.
Smith,
J. W..
1967,
Personal
communication:
U.S. Bur.
Mines, Laramie,
Wyo.
Thomas A. Hendrickson
INTRODUCTION
When considering
liquid
usable
and
gaseous
the
views of
several
Retorting
material under
retorting
dolomite,
retorting
purpose of
quartz, clay,
shale
"kerogen")
to conveniently
emerges
this author to
processes of current
(called
oil
always
fuels,
It is the
appropriate process.
for converting
processes
the
as
present
most
brief
re
interest.
decomposing
the
or
of a
inorganic matter,
and
When
such
oil shale
is
RETORTING PROCESSES
The Fischer
Let's
can
learn
the assay
( 1949 )
procedure
is
obtained
to
retorting
hurry. Developed
( 1965 )
assayed
by
from
Fischer
the
the
Miniature
in
assay.
U.S. Bureau
Stanfield
by
of
We
Mines,
and
Frost
laboratory
procedure
(932F)
in
placed
attaining 500C
method
simple
retorting
The 100-gram sample is
sealed
Retorting Process
Hubbard
shale
accepted
lot from it in
and
Oil
may be
start with
AssayA
after
The
40
for evaluating
sample
minutes.
45
oil shale.
is heated
is then
at a specified
It is held
at
rate,
932F for 20
Quarterly
46
As kerogen
minutes.
through cooling
decomposes,
the
vapor
of
Mines
products
pyrolysis
of
pass
and
and uncondensed
Consider
Colorado School
of the
now
what
can
we
learn
about
retorting
Table l.Data
from the
obtainable
of oil
follow in tables
shale
( 1951 )
modified
from
shale
Fischer assay
Typical Values
For Very
Low
Grade
Shale
011,
gal/ton
Oil
weight percent
Water,
weight
Spent shale,
10.5
4.0
0.5
percent
Table
2. Physical properties
Grade
For High
Grade
Shale
26.7
10.4
1.4
85.7
2.0
0.5
94.4
1.1
weight percent
of
For
For Medium
Grade
Shale
Very
High
Grade
Shale
36.3
61.8
23.6
1.1
70.4
4.2
0.7
13.8
1.5
82. V
2.2
0.4
of
g/t
10.5
26.7
36.3
57.1
61.8
75.0
4.0
10.4
13.8
21.9
23.6
28.7
assay:
raw
shale
Sp. Gr.,@60/60F
.925
.930
.911
.918
.919
.918
23.72
18.19
17.10
17.12
17.28
18,510
18,330
18,680
18,580
18,510
18,440
Pour point, F
80
75
85
80
80
75
centl stokes
Table 3
Grade
.Chemical
of raw
Carbon,
g/t
shale,
weight
80
75
85
80
composition
17.8
18.8
19.5
21.4
22.3
29.8
36.6
38.0
51.8
84.54
84.84
83.77
84.32
84.72
84.80
84.26
85.26
84.82
assay:
Hydrogen,
weight
11.32
11.38
11.17
11.40
11.72
11.60
11.76
11.76
11.68
Nitrogen,
weight
2.01
2.00
2.13
2.03
1.86
1.96
1.91
1.70
2.05
.49
.76
.58
.60
Sulfur,
C/H
weight
ratio
.58
7.5
.51
7.5
7.5
7.4
7.2
7.3
.58
7.2
.69
7.2
.71
7.3
Table
of
oil shale
47
Fischer assay
and
products
Raw Shale:
Grade, Gal/Ton
Gross
10.5
Heating Value,
Assay Products:
Oil, weight %
Water, weight %
Spent Shale, weight %
Gas, weight %
Gas, ft '/ton shale
Loss, weight, 7
Gross
of
Heating
61.8
5.510
75.0
6,010
7,000
10.4
13.8
21.9
23.6
.5
1.4
1.5
1.2
1.1
1.5
85.7
82.1
72.3
70.4
63.6
1.1
2.0
66
2.2
337
3.9
445
28.7
4.2
1051
4.6
1073
1207
1.6
.5
.4
.7
.7
18,330
18,680
18,580
18,510
Value
18,510
-
Shale, Btu/lb.
1000 Btu/ton
Products
250
18,440
330
1,160
1,090
973
926
562
1,214
897
1,006
49
255
453
739
758
1,018
shale
obtained
from
80
Btu/ft3
expected
3,080
4.0
Water
Spent
57.1
36.3
2,340
94.4
Assay Products:
Oil, Btu/lb
Gas,
Gas,
26.7
1,020
Btu/lb.
are
typical
those to
of
in the
1,250
be
absence of
air.
The
built
name
to
was given
the Nevada-Texas-Utah
by
the
Company
of
to
cation
retorts were
of
review of
retorting
is
retort
late 1940s.
not suitable
for
appli
Energy
and are
Research Center in
Wyoming,
brief
the
retorts on
on a commercial
built recently
Mines Laramie
during
modern shale
two NTU
Bureau
near
Because it is
retorting
of
Mines
at
of one of
Anvil Points
retorts
built
by
the U.S.
1971).
A
at the
shale
view of
Laramie
Energy
retort
of
Research Center is
on
shown
retort
the shale.
passes
of
the
of
the
to
started at
the
retort.
operation
is
spent
air
is
admitted
into the
support combustion
A fire is
The
Mines
the ground.
NTU
in figure 2.
of
shut
to
provide
down
and
the
dumped
out
Quarterly
48
of the
Colorado School
of
Mines
_-c
Hoist for
Telescoping
Charging
Tube
WASTE GAS
STACK
=4
.^
Portland
Cement &
Calcined
Aggregate
Fire Brick
u.*!"/
<4"
*-.^
iff
REFLUX
ACCUMULATOR
Figure
1. Design
because it
inch
to this
methods
relates
process.
particular retort.
pounds.
size.
retort
at
7,500
of
when
presented
shale
one
About 20
to the
reason
The Bureau
One block
the
percent of
of
for the
interest
of shale
feed
current
for this
coarse
run weighed
than 20-
encountered
reason
during
in
for
such coarse
situ
retorting
of shale.
Figure
2.
49
at
of
the Laramie
Mines).
50
Quarterly
Table
5.
of the
Summary data
for
Colorado School
run
number
of
Mines
2 in the 150-ton
retort
at
Laramie
Length
days..
12.25
Shale charge
tons..
Retort pressure
psig..
Air rate (dry)
scfm..
Do
scf/ton shale..
F..
Avg air temp into retort
Recycle gas rate (dry)
scfm..
Do
scf/ton shale..
F..
Avg recycle gas temp into retort
Oxygen content of retorting gas
pet..
ft3
gas/ft2
Space velocity
bed/min..
178.67
3.0
135
13,300
28
67
6,600
43
14.5
1.94
177
17,400
42
4,100
0.6
26
1.75
1,600
5.6
of
Operating
run
conditions:
Avg
Avg
Max
Bed
Oil
ambient
scfm..
shale..
scf/ton
shale..
(dry)
scfm..
in.
press
advance
rate
compaction
pet
initial
of
properties:
Fischer assay
Water content
Bulk density
Gross heating
Recovery:
Oil
Spent shale
Oil recovery
Oil properties:
25.4
2.9
80.0
2,267
gal/ton..
gal/ton..
lb/ft3..
Btu/lb..
value
2,830
125.86
62.2
gal..
tons..
Vol
pet
of
Fischer
Gravity
Pour
H2O.
F.
in/hr..
F..
height..
temp
retorting
bed temp
shale
scf/ton
point
SUS
Viscosity
at
Hydrogen
Nitrogen
Sulfur
Carbon
Ash
Gross heating value
Spent shale properties:
Fischer assay
Gross heating value
assay..
API..
F..
100
F..
wt
pet..
wt
pet..
wt
pet..
wt
pet..
wt
pet..
25.2
70
79
11.76
1.77
0.76
84.58
0.01
18,660
Btu/lb..
0
117
gal/ton..
Btu/lb..
R&D
program conducted at
Anvil
the Anvil
and
Points
Points,
a research
facility
on
the
conducted extensive
demonstration
operations.
lot
R&D
of
behind the
work
The
cess
flows
pro
continu
by
ously
of
51
lower
in the
It is
(fig. 3)
the retort
part of
ing
convenient
zone, the
combustion
Combustion
in the
shale
in this hot
air plus
combustion
liberate heat.
zone,
Some
is
the
spent shale
gas are
some recycle
zone.
residual
zone also
and
Fuel in the
carbon which
cooling zone.
injected into the bed
recycle
is
gas
burns in
present on
air
of
to
shale particles
of
combustion.
Some
the
serves
function
combustion
cooling hot
of gases
of solids.
in the
This flow
the gas-to-solids
cause
spent shale
the
of
downward from
flowing
retort
direct
provides
heat
is upward,
transfer
has
counter
gas-to-solids
proven
to the
heat
of
Mines
Typical
the
at
Anvil Points is
performance
are
shown
downward
Be
exchange.
to be excellent, gas
retort and
zone.
The flow
flow
of
by
com
the U.S.
in figure 4.
to
an
injected into
"rock
process
shale
inverted-cone-shaped
to supply
support combustion
air
shale
features
feeding
retorting
moving bed
all
bed
of shale.
product vapors
solids.
is
The flow
of
downward,
air,
of
is
open
is
of
the direct-
coarsely
process
a retort of novel
necessary
device that
vessel which
process
crushed
heat.
design. This
retort
into
overflow
the vessel
walls
at
the
countercurrent
to the
upward
flow
of shale
52
Quarterly
of the
Colorado School
of
Mines
a
C
o
CO
w
O
35
<
33
a
Figure
4. 150
ton/day
U.S. Bureau
gas
of
combustion
retort
at
53
Facility
U.S. Bureau
Mines).
of
of
of
the
Quarterly
54
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rt
kl
rt
ki
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w
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v
h
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w j:
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ki
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uuuvuuuu
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kl
e o o 9
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UTrt
Ck
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0J
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3
**
OJ
rt
ki
c
M
8 8
in figure
evident
which
novel
was
design
5,
built
and
of
55
drawing
of
operated
in
western
flowsheet become
demonstration
day
Colorado
during
the
retort
period
1954-58.
Hot gases,
carbon
cause
generated
remaining
to
pyrolysis
on shale
occur
feeding
cold
kiln. Pyrolysis
carbon occurs
in the
being
incoming
occurs
in the
below the
zone
fed into
device. Heat is
Conversely,
the
is
flow downward
pump
ing.
in the
the
in the
kiln
by
is heated
at
the
direct
as
zone.
the
exchanged
shale
combustion
bottom
by
the
solids-to-gas contact
it flows
through
upward
the
surface of
the retort,
where
OIIVE-
SPfNT
SHAlf
SPIl
HOWS
SEFAIATOI-
ZONE
SM
ich
&ses
hot
TO
ShaiI
Oil
SF
COOLING
SHAIE
ING
TO
SIOIACf,
>WsW/AV///vW/A\^^^
5. Union
Oil
shale retort.
WHICH
ZONE
UtNING
ifAl
IN
MEHEATED
l$
All
Figure
rock
HOW
Oil
The
incoming
HYOIAUUC
MIST
and
Kllf
OUT
CTUNDEI
Quarterly
56
Colorado School
of the
Mines
of
in tables 7
and
8.
Table
Shale feed
Fischer assay
Total feed (wet)
Feed rate (dry)
Retorting
gal.
27.9
157.7
25.44
/ton
tons
tons/day
conditions
Retorting
lb.
rate.
138
10,700
0.32
011
shale/hr./sq.
atm.
7.5
2200
800
1 25
production
vol.
011 recovery
011 collected
011 collected
011 collected
011
/ton feed
do
do
do
do
% Fischer assay
2.6
1.4
0.2
23.6
27.8
99.5
gal.
feed
% Fischer assay
% Fischer assay
23.6
86.2
84.4
gal. ton
wt.
vol.
yield summary
011
yield
(incl.
011
011
yield
(do)
(do)
mist
and
sludge)
25.2
92.3
90.4
gal. /ton
Fuel
yield
gas
production
Wet
gas
Dry
gas
wt.
vol.
% Fischer assay
% Fischer assay
s.c.f./ton
feed
do
located
near
Rifle, Colorado, is
shown
17,350
14,430
which was
in figure 6.
The TOSCO II
ing load
ferring
of
heated
oil shale
ceramic
the necessary
retorting
balls
process
process
heat-carrying
finely crushed
as the
heat to
features the
use of a circulat
medium
oil
shale
for trans
to
effect
57
8. Product properties
of oil
Gravity
A.P.I.
Specific gravity
Viscosity--
@60F.
@60F.
S.U.S. @1
Visccsity
20.7
0.9297
113
46
90
0.81
1.90
22F.--
S.U.S.@210F.~
Pour point
Sulfur
F.-'
-Wt.
Nitrogen
Water
dovol
Ash
Distillation
Initial
iO
20
30
40
50
60
70
--
trace
wt.
0.04
285
509
576
622
666
688
701
cracked
(dry)
B.t.u./s.c.f.
Water content
Analysis (dry basis)
vol.
%-
mol
%-
80.8
12.4
Air-
2.2
56.9
0.7
4.6
30.3
2.2
0.1
0.9
0.6
0.4
0.4
0.2
0.3
0.1
0.1
N2-
AC0C02H2H2S-
C2
C2
C3
c3
C4
C4
c5
Properties
Organic
Mineral
of
ash
residue
content
carbonate
Figure
content-
6 350
Wt.
Wt.
% CO
0.08
0.49
process
demonstration
retort.
58
Quarterly
the
pyrolysis of
kept
air.
under an
Pyrolysis
Colorado School
of the
kerogen. The
shale's
internal
pyrolysis
of
drum,
vessel, a rotating
5 psig to
pressure of about
Mines
is
prevent admittance of
occurs under
occurring in the
retort.
furnace.
(TOSCO) developed
as a refinement of
inventor
who
led to the
work
Aspegren,
named after
his inventions to
not reduced
development
tracted early
DRI's
had
Swedish
TOSCO
practice.
( DRI )
work
24-ton/day
construction of a
con
.
in Denver
pilot plant
in 1957.
In
1964,
Development
Colony
to
changed
retorting
operations, using
a
Colorado
new sponsor
Field
as
operations
well as retort
subsequentiy
serving
name
a retort of about
site until
formed (the
was
Colony
operator, is
now
1972,
through
demonstrations,
with
project,
in the
which
involved the
include
mine
semi-
Field
continued at
ARCO,
relatively
design
commercial
and
phase.
developments
expenditure of about
$55
as
mil
lion.
A flowsheet for the TOSCO II
shale
process
retorting
is
presented
in
figure 7.
Minus M-inch
shale
feed
material
gases
from the
gas-fired
Pyrolysis is
of
are
about
from
charged
(500F)
of shale.
sufficient
into the
oil shale
for
from the
of
to
above
drum to
balls
the level
of
the
atmosphere.
furnace fired
ball-heating
drum (after
gas).
extraction
of
naphtha,
The heated
mix
balls, at 1200F,
incoming preheated
with
2 tons
of
pyrolysis.
ized
heated in
are
proportion of about
Retention time
pyrolysis
in the
500 F in
the pyrolysis
elevated
are
in
M-inch diameter
gas,
by
about
is discharged to the
gas
accomplished
8 feet in diameter
balls
ball heater. In
solids
pyrolysis
ceramic
shale
to
preheated
The hot
is
shale solids
lose
ball
mill.
As
oil shale's
kerogen is
strength and
become
finely
drum
at about
950 F
pulver
by the balls.
The
solid materials
leaving
the
pyrolysis
consist
59
O
u
cn
O
H
o
l-l
0.
V)
c
Ui
^7
1joivdVdas^^
-j
^^
*ov^^
^Sfrs.
in
LO
3
,.3dld
uj
Uli.. 038
OB
it
>
ointd
3SVHd
simia
60
of
Quarterly
finely
Colorado School
of the
separated
from
spent shale
diameter
/2-inch
from
exit, consisting
The balls
balls,
shale,
are elevated
by
heavy-duty
are
rotating
The trommel
shell.
bucket
balls. Balls
ceramic
trommel, which is a
holes punched in the
by
Mines
of
elevator
to a gas-fired
ball-heating
balls flow
heater is
by
gravity to the
to
published
pyrolysis
lift
drum.
and preheat
concerning
Flue
gas
incoming
cold shale
heat
conventional
feed.
and material
balances for the TOSCO II retorting process. Lenhart (1969) has pointed
out that TOSCO plant yields may not be compared directly with Fischer
assay
and
the overhead
Also,
duced
and not
heavier
Results
July
107.6
condenser
in the
condenser operates at
semiworks plant
operates
100 F.
and
yields on plant
from the
compounds
of a
7-day
run at
reported
percent
volume
concerning the
the
of
semiworks
(Hall
TOSCO II
oil
at around
liquid
recover
yield
was
produced.
Balance
Period
or
of
Run,
Hours
Total Dry
Average
Shale
C4+
Yield
as
Percent
of
Feed,
Rate,
Volume
Weight
Tons
Tons/Hour
Percent
Percent
13.53
358.42
26.5
108.8
106.9
12.47
344. G5
27.6
106.5
104.3
13.05
361.26
27.7
107.1
104.9
11.12
312.31
28.1
105.3
103.9
24.10
704.47
29.2
109.9
108.7
12.80
391.64
33.2
107.6
105.6
11.00
324.19
29.5
106.2
105.4
13.00
386.99
29.8
105.1
103.1
11.18
336.52
30.1
108.7
107.0
10
12. 7<3
390.88
30.6
109.1
106.6
11
10.97
316.89
23.9
110.4
108.3
12
17.12
511.44
29.9
105.3
104.1
163.12
4739.66
29.1
107.6
10S.9
Average
during
1968), showing
in table 9.
Raw Shale
butanes
pilot plant
Length
oil pro
liquids.
Yardoumian
and
Fischer assay
Table
gas stream as
32 F
Data
61
all
probability,
at commercial rates.
near
Rifle, Colorado, is
view
shown
are
could
of
well
advanced
and
day
demonstration
in figure 8.
"semiworks"
has been
TOSCO II
retort.
retort
Quarterly
62
Colorado School
of the
Mines
of
LURGI-RUHRGAS PROCESS
Lurgi-Ruhrgas
the
such as sand
shale
oil shale
The
to the
oil
derived from
flow
pipe and
tinuous,
with
raw
feed
entering the
No heat
by
mixing hot
carrier
Retorting
occurs
of
oil
Some
the solids
Hot
and
recycle
from the
heated
screw.
bins
and elevated
solids overflow
The
heat-carrier
surge
the
top
process
solids
by
of
is
are
a
the
con
continually
screw.
balances
all
to
for definition
are available
and
have been
of process
Private demonstra
at
of
required).
shale
comparable as
made on
European
and on
United States
facility
In
or material
performance.
be
by
through
lift
part of a
fuel (if
tions
the raw
finely
would
heat-carrier
discharges into
screw conveyor
lift
in
retort
for retorting
process
during
into
solids
use of
particles,
To
process.
coke
grains,
retorting
solids with
indirect-heated
an
It features the
size,
offers
oil
shale
at a small
been leased
of
and
vertical
tests
will
be
conducted
facility
in Colorado has
there.
air will
be
admitted
combustion process
For
kiln ) for
a second phase of
that
recycle
shale
the
shale
demonstration,
the retort
will
be
arranged so
gas
(making
of
of
the shale.
kiln
shown
the type to
in figure 10.
be
An
used
in
c
H
rH
(TI
0)
0)
Vl
Q.
>
&
<0
&
U)
r-t
U
0)
u<
<0
V)
>
<)
c
o
UJ
b o
c
l/l
0)
Vl
u
c
o
T3
r-l
UJ
01
</>
o
-u
-H
0.
Ai
UJ
*j
rH
</>
r-l
<u
O o
?J
Ul
63
rr
c
-h
<J
Ai
"0
41
X
0>
Ai
Ai
X V) Ifl
m H 3 rJ
o z a X
U)
a>
o
o
O
rinnvmioho
b0
o
4-r
a>
iH
8
J3
5b
tH
3
i-l
<D
I
o>
Quarterly
64
of the
Colorado School
Shale
Rotating
of
Mines
rock
spreader
Shale
vapors
to oil
recovery
unit
Gas /air
mixture
Gas/air
Moving
grates
mixture
Spent shale
falls through
grates
Spent
shale to
disposaf beds
Figure
10. Vertical
shale
.
The Petrosix
to the gas
combustion air
sary for
oil shale
that
retorting.
heated
of shale
Brazil, is
similar
to provide the
heat
than
neces
The
oil
intendeney da
Over 15
from
and
company)
nicely
State
feed/ day
of shale
Parana,
of
near the
town
is
national
operation
built
facility
and
performing
Petrobras in the
by
of miles across
in
now
retorting
of
plant comes
for hundreds
outcrops
within
Brazilian
years
tons
short
department
( the
Industrializacao do Xisto.
2200
name
65
and
formation,
southern
which
Brazilian
Rio Grande do
Sul,
displays
Sao
states of
indicated in
as
figure 12.
Irati formation
oil
shale
by
A flowsheet
of
occurs,
an
the Petrosix
typically,
as
intermediate layer
shale
retorting
an
of
upper
( fig.
limestone
process
is
lower
and
shown
13 )
in figure
14.
Crushed
the
oil
kiln
vertical
with particles
shale,
retort and
drying, heating,
Retorting
is heated in
flows downward
and
retorting,
in slurry form to
pumped
process
cm
one
dimension,
enters
The
cooling.
in
shale
retorted
solids
are
disposal pond.
heat is
a separate gas
up to 15
supplied
heating
by a recycle stream
furnace designed to
of off-gas which
or process gas as
spent shale
recycle gas
The
temperature
A
the
this
of
to
ascend
through the
spent
flowing
out of
the
retort
Kiln
removal
the
shale
lower
part of
heat.
by the downward
form, which is carried
an oil mist
solids, causing
flows
off-gas stream.
to
Good heat
exchange occurs
of particulates
part
is
used
of sulfur and
No heat
controlled.
be
solids.
off-gas
compressed,
recovery
by
is easily
second recycle
retort
recycle stream
for recycle,
LPG, leaving
or material
The final
droplets.
and
a
the
remainder
final fuel-gas
the Petrosix
plant or process.
for Petrosix
Bruni
(1971) has
in table 10.
gas
is
for
product
processed
is
for
product.
released
reported
by
the
Petrobras for
specifications
66
Quarterly
of the
Colorado School
Mines
of
J3
a
o
Ctf
N
i=i
at
.a
-a
c
a
CD
rHU
5
UNOSOOK
0
?
U3 H < l-i H
3
<
u z k.
a. J i
m e
S in
'
< Q
~
Ki
i-i
3
a
'
;sHsa:fa
o,
!ll3iSM!3liiSEsh
67
BG NOT
'
DEVONIAN SHALES
CRETACEOUS
outcio^i
PARA-
PARAlgA
AM A / ON A
SHALES Of MARANHAO
cootf-iuu o.
coaoa-
OA OI!C
CEARA-
CRETACEOUS
OUTCAO**
CRETACEOUS
SHALES Of
CAATO
SHALES Of AlASQAS
%U Maiaui fo Sul
CWtTAXEOUS SHALES Of BAHIA
OUTCROP*
HAAAkl
OUTCAOP
OO AAA.iUl
aALl
AMAPA'
SHALES
(S)
BRASILIA
SHALES
12.Location map.
Figure
^^^
^$JL
-*
upper
zn
LA,6rf
SHiL
flvl HAOt
5^f^TT^T^T-7
i
r_
'
,
NTEf.Hf.URTt
0>
rL,0T HASt
'
*"*W
lAl(H
l o*
f I '[
-
-_L.
oi
-1
Of
7^.,h
i
j_
*'Wy
.^
8
.
Oil
*-_s I-
_
T{RS^~
6^0 Mf
".
TH.CANfS',..NTfcAL
A.fWAot %
r7^. rp
L
/ONES
DH.
BASf
.'ON.*
;
?
8 60 MfliRS
U0%
;jh
*f
-i
-
_J.
17^
J_.1
i
i
Figure
,i
13. Typical
n*r
i
cut
jrs
rr^nr
of
,
"
'-^^-J -
Irati formation.
''
'
'
I
';;;
!
68
Quarterly
OIL
SEAL
of the
SHALE
Colorado School
Mines
of
FEED
GAS-
r
HIGH BTU GAS
FEED HOPPER
PRODUCT FOR
PURIFICATION
*=*
SHALE
ELECTROSTATIC
DISTRIBUTOR
CONDENSER
PRECIPITATOR
CYCLONE
^1
DC
COMPRESSOR
SEPARATOR
LIGHT
SHALE
OIL
HEAVY
SHAIE OIL
WASTE
WATER
COOL GAS
RETORTED SHALE
FACILITIES
SEAL SYSTEM
WATER
Figure
flow diagram.
Table
Density, API
Diolefins, wt. %
Corrosion, 3 hr. @ 122F.
Sulfur, wt. %
Nitrogen, wt. %
Paraffin, wt. %
19.6
15.0
Strip
1.06
0.86
0.02
Aniline point, F
Pour point, F
Viscosity
At 2000 tons
should
yield
elemental
of
100 F,
sulfur
86
25
shale
20.76
centistokes
1000 b/d
The Petrosix
shale.
at
ASTM 4a
oil
shale/day
input,
the plant
14 tons
of
United States
oil
and
daily.
process
has
not
been demonstrated
on
69
CITED REFERENCES
Bruni, C. E., 1971, Brazilian oil shale development: Eighth World Petroleum
Congress, Moscow.
Clampitt, R. L., 1971, Gas combustion retorting performance in a large demonstration
retort:
100th Ann. Mtg., Am. Inst. Mining Metall. Petroleum Engineers, Mar.
Cramer, R. H., 1969, Evaluation of pilot plant results from the gas combustion retort
ing process for oil shale: 90th Ann. Mtg., Am. Inst. Mining Metall. Petroleum
Hall,
Engineers.
R. N., and
production
by
the TOSCO II
process:
neers.
A. E., 1971, Some results from the operation of a 150-ton oil shale retort:
U.S. Bur. Mines Tech. Prog. Rept. 30.
Hubbard, A. B., 1965, Automated Fischer retorts for assaying oil shale and bituminous
materials: U.S.*Bur. Mines Rept. Inv. 6676.
Lenhart, A. F., 1969, The TOSCO process economic sensitivity to the variables of
production:
34th Midyear Mtg., Am. Petroleum Inst., Am. Inst. Mining Metall.
Petroleum Engineers, Chicago.
Ruark, J. R., et al., 1971, Gas combustion retorting of oil shale under Anvil Points
lease agreement: Stage II: U.S. Bur. Mines Rept. Inv. 754.
Stanfield, K. E., and Frost, I. C, 1949, Methods of assaying oil shale by a modi
fied Fischer retort: U.S. Bur. Mines Rept. Inv. 4477. (Revision, R. I. 3977).
Stanfield, K. E., et al., 1951, Properties of Colorado oil shale: U.S. Bur. Mines Rept.
Inv. 4825.
Harak,
UNCITED REFERENCES
Feldman, H. F.,
et
al.,
1966,
Production
of pipeline
York.
no.
gas
by
hydrogasification
of
oil
36.
shale:
Am.
Wayne E. Glenn
very thoughtful
appreciate
of you
shale and
the
tomorrow, my focus
problems.
In the process, I
be
expected
it
The American
was called
ages
it
negatives,
but it
break
we can
the
lives
also
old
of
motorists on
the country
aspects of
lost
who
The
people on oil
subject
today
America's energy
the
about
role
at
habits
such a
embargo
lasting
trying
and
impres
circumstance;
the energy
short
their jobs
hardships. The
had
usually leaves
through
went
oil embargo.
touched the
around
the broader
this
will
just
caused
people, particularly
on
circumstances
people
the Arab
be
much
many knowledgeable
will
how
to emphasize
want
was
be here.
presence of so
the thoroughness
It
with you
the opportunity to
Recognizing
and
to be
am pleased
least
due to
cutoff of
one plus:
economic
Mideast
it
oil
showed us
slowdowns, the
had
that
amounts
bundle
of
as a nation
energy in
of
process.
conservation
energy
we can
go
barred"
type of
If that
wasteful consumption
happens,
we could
As the Arab
embargo
all
bets
are off on
be in trouble
again
and soon!
illustrated, dependence
on
imported
oil
is the
possibility
and Israel
Uncertainty
which
that
about
the
is in the Middle
we
President,
look for
answers
continued
Eastmakes
to
our
availability
it both
energy
foreign
reasonable
problems right
oil
and
most of
imperative
here in
our own
71
Quarterly
72
of the
Colorado School
Mines
of
country.
problem
three things
only three basic pieces to the energy
be done to improve the supply situation for the short term, the
There
that
must
are
term
medium
First,
and
just
third,
it
use
a new
two
as well:
of
be built;
must
America's energy
all of
resources
and
them;
to
conserve
energy
more efficiently.
at each of
lies
few
to get
minutes
feel
some
ahead.
tion,
without
new
150,000
with
domestic demand.
A few
haul
fully develop
we must continue
magnitude of
Refinery
build
we must
one or
Let's look
for the
long
more
second,
not
for the
taking
account
barrel-a-day
refineries will
have been
new refineries
a number of expansions
the impact
is
well
needed
constructed
facilities
to existing
industry
be
conservation
every
may
year
have, five
keep
to
up
years and
But
even with
are underway.
forced to play
and
catch-up.
Some
people ask
plans made
is that the
finery
to improve the
has been
opposition,
stalled
of actual
imports, is continuing
getting its
down
out
to
The
According
build
years at a
reject
recently
As
limit the
else.
we still
efforts
to
lack
answer
new re
environ
by
15
site
dependent
refineries
New Hampshire.
in
there.
on
Mr.
Meanwhile,
in
protested
These
companies
amount of gasoline
a realistic attitude
area most
are not
of
But
more refineries.
coast, the
new refineries.
made available
crude oil
to build
new refineries
total
The
critical.
and
east
attempts
tions to
for
shortages,
wasn't anticipated
capital requirements.
oil
for
need
uncertainties about
the tremendous
and
the
shortage
before it became
situation
construction
mental
isolated
cases.
Association,
have been
rejected
applica
in
recent
eastern seaboard.
refining capacity
will
regardless of
how
continue
that
much
can
to
be
foreign
or anywhere
Oil Shale
Even
capacity, the
be
at
least,
at
to
beon
doing
to
achieve
expand
importantbut
to
possible
everything
independence"
calls
energy self-sufficiency
in domestic energy
energy
to
industry
being
efforts
by
for
that gap
bring
can bring
years
of acceleration
progress
proposed will
an allout national
to
us
duction 37
That
in just 6
But that's
nuclear
and
that's
a position of
plants and
19
shale oil
this is
plants, 13
1980
also means
oil-from-coal
of
from
this
to the
dollars
times on
on
moment
winds
were
most of
forthcoming
these
time
for
if
435
from
Many
is
all
threw
oil
company
profits
coal mines
years
is 2 to 5
to
bring
on a new oil
The
years.
new nuclear
years.
the public
If
irresponsibly
we
standably,
9,000
building
a sour note.
assumed
and
frame. It takes 3 to 10
is lagging.
production
plants, 30 gas-from-coal
somehow, there's
orchestrated
constraint
billion
basic lead
outside
coal
action and
all
environmental
of
increased
and
Self-sufficiency by
hundreds
geothermal plants.
into
Even if
190,000
nation we could
years.
not all.
plants, 8
of people
would mean
1970,
to
percent as compared
percent.
coal mines
the
close
self-sufficiency.
Let's
176
its refinery
keep
the
or,
by
73
wide
for
with us
Energy Situation
and the
becoming increasingly
a considerable under
Necessary legislation
unresolved, and,
confused and
under
angry
about
energy issues.
So,
of
the energy
equation.
energy demand is
mates range
Council to
dustrial
from
low
There
expected
high
of
1.7
by
of
1980?
to grow
4.2
during
the
percent suggested
to the bare
by
next
by
at
the
how
6
demand
much
years.
side
domestic
These
esti
the Ford
Foundation, if
in
minimum.
at 3 per
The Federal Energy Office's estimate falls in the
cent a year.
Using the FEO figure as an average, total domestic energy
demand is expected to reach the equivalent of 92.9 quadrillion Btu by
middle
74
Quarterly
Colorado School
of the
be in 1980. The
to
pected
75.5
at about
what
domestic energy
and
demand
of
11.5
Btu
quadrillion
day )
of oil per
is
each source
expected
percent;
coal, 25 percent;
percent;
gas
from
from
crease
plied
by
levels,
present
these two
to
fuels
prefer,
from now, is
gap between supply
years
about
to
be
available
five-and-one-
stimulation,
in
1980, here's
gas, 61.3
oil and
hydroelectric,
0.7 percent;
geothermal,
percent.
account
the
although
in
will
percentage of
decline. Greater
will
be
still
supplies are ex
conventional
play:
nuclear
sources
you
expected
or nuclear
coal
not
annually.
if
(or,
Btu
quadrillion
realistic, though
most
Mines
of
contributions
by
the
other
up the difference.
But there still will be an 11.5 quadrillion Btu energy shortfall in
1985 that must be met by imported oil. If our goal is energy self-suffici
energy
by
ency
that
time, let's
domestic energy
shale
resources.
One
of
do
to
these is the
oil.
Assuming
that production
levels,
at about present
jump from
barrels
the
of
conventional
contribution
of oil per
100,000 barrels
per
necessary
by
an output
in
remains
excess of
12
million
day
realistic estimate of
sources
energy
in
day. This
idea
of
the
difficulty
the
has been
exceed,
estimated
all
the crude
be felt
oil won't
Coal is only
energy
and
that
until
oil
But the
at
be tapped to
help
number of other
to
domestic
recovery for
realistic
to
shoot
oil
for
in
known
50
reservoirs
percent
is 31
recovery
years
creased
or
contribution of shale
to,
the earliest.
the solution.
present rate of
We believe it is
in Saudi Arabia.
one part of
demand. Here
deposits in Colorado
The
shale
would mean
the
percent.
rate within
encourages
can
be in
addition of more
Oil Shale
billion barrels
than 80
and the
to
of crude oil
following
first
the
Energy Situation
domestic
75
That is
proved reserves.
oil well
pipeline
million
will
to the
to
confirm whether
fields
smaller
The
or
the Prudhoe
only
one of
outer continental
the United
shelf of
domestic
as
Recently,
a source of substantial
it"an
development along
This
acceptable
study by
tion in the
the
council on
the
coastal waters
in the Gulf
no sale
Mexico. But
Atlantic coast,
even
oil
and
an area of
gas
Quality
came
impact
environmental
of
in
Interior has
has
after
that
they
put
year-long
1973
During
been held
supplies.
accelerated offshore
yet
greatest
reported
recommendation
new
activity
giant"
potential
offshore petroleum
years
and
thus
lease
sales
Survey
there
estimates
may be up to 58 billion barrels of crude oil and 222 trillion cubic feet of
natural gas out there. And that's more than the proved domestic reserves
of oil and close
council will
These
be
to the total
a
for
are ways
to
add
Hopefully,
natural gas.
to the
this
report
by
the
development
The
key to
developing
ending energy shortages in this country once and for all lies in
in reducing our dependence on petroleum.
America's full energy
This can be achieved only through greater contributions by every energy
potential
resource at our
among
disposalshale
oil, coal,
fuels,
others.
nation can no
longer
afford
the
provincial attitude
to have
ample supplies
provided
by
other parts
the
of
nation.
There
was a
time
when
heat
their
homes
mobiles and
states and
I
at
submit
their
energy
the
coal mined
in
the
rest of
another
handful
of states.
fingertips,
and
That
era
handful
has
have energy
not obstruct
by
the
of
ended.
available
search
terminals even
for
if it
76
Quarterly
We
to
have
also must
Prices
work.
in the process,
There's
The
the
The
domestic
more
oil and
to
of
we will
energy
lies in
in
one
use, and,
We
but
need
no
basket. It's
to
not an
eggs
a number of
forth.
and so
a chance
available.
nuclear
to
and
one
new
them
and
the
use
need
all
on
or
finding
and
more
producing
to
choice:
the
make
fuels
plants,
thing is
one
gas,
be
will
synthetic
of
any
to
answer
bringing
building
coal,
not
it
better.
Whether it's
of
kind
synthetics
oil, nuclear,
sooner
is
Mines
of
the
domestic energy
key
either/or situation.
shale
determine
no panacea
panic either.
in the
confidence
will then
more
Colorado School
of the
certain:
continue
follow
to
strict
conservation
fuels.
And that is
in
are
what we'll
If
progress.
have to do
longer-term developments
these
while
we underrated conservation
earlier,
do it
we must not
now.
levels. It is the
same as
A study
the United States
annually.
uses
211
developing
published by
is the
our standard of
report adds.
same as
could
living
That's
or
It
This
2,930
developing
be
says
that
energy
achieved without
by
2000,
the year
each year as
reducing the
it
now
growth
in
naturally depends
on
the
taking
other
energy-saving
Conservation is
important is
develop
will
an
in the
essential
effort
all-out
1985 to
and
by
one of
that the
meet
the most
the
world's
expensive
Equally
situation.
industry
in the
and
now
must
energy
petroleum
of money.
industry
free
current
the
estimates
public
steps.
York
be
the American
cooperation of
to
find
future. That
spend
energy
of
and
effort
New
requirements.
privately financed
projects
That
in the
effort will
history
of
man.
To
get the
job done
will
take a
lot
more
than money,
however. A
Oil Shale
national commitment also
and the
is
needed
Some
say that
skeptics
that private
petroleum
public's requirements
The
way.
ice to the
our
By
problems.
energy
any industry's
ful:
the American
been
and
Great
ahead.
But
living
unprecedented
challenges
as
I travel
face the
around
wealth of
I'm
knowledge,
confident
is its
energy
view
it
another
record of serv
in the
at reasonable prices.
propel
history
nation's
of
experience and
talking
you
will
be
bring
years
with
of A.I.M.E.and
dedication
future
the world.
the membership
It has
the
responding to the
the 1970s. I
success
all
oil
for
consumer
fronts
complex world of
ultimate criterion of
public.
to get
companies
in the
77
Energy Situation
the
see
to the task
met successfully.
H. Michael Spence
My
tion
in correcting,
negligent
for
as anyone who
of
of
the
to
discuss
to
this,
mental
scheme and
regulatory
would
paper which
discuss in
to
the
business undertaking
One
as
considerable
general
developer
of oil shale.
facility
involves the
which
is
very large
commitment
of
and
large
of
components which
has
a significant effect
and on
toward the
have
and reviewed on
included in
are
a reality.
fact,
In
standpoint of a prospective
geared
definitive
and which
like
on
and was
select,
Leasing Program,
become
not
which
the Environmental
complex
I did
which
kind.
study,
occasions similar
The
trepida
attempt
shale environmental
from the
my talk,
Rather than
is
sumed, it is nothing
detail in
symposium
The title
and uneasiness.
many
in this
participation
the
of various major en
Colorado.
Throughout this talk, some distinctions will be made of the differences
between development on private lands and development of federal lease
vironmental
lands. At
and
the
present
relate
time,
there is a significant,
oil shale
occur
of
tasks as they
to
there
are
two
of
vironmental
and regulation,
stipulations,
they
as well as
are
to
subject
to
operational
plans, the
are subject
specific
to
to
large
lease terms
special
body
and en
environmental
compliance with
substantial
Vice President, Environmental Affairs, The Oil Shale Corporation, Golden, Colorado.
79
re
private
of certain specific
western
although
land. Development
federal law
in
re-
Quarterly
80
Colorado School
of the
of
Mines
Advisory
federal land
the
Finally,
to
proper
business
fashion,
and
meet
the
with
comply
federal
of
it must, in
First,
purpose.
leases,
objectives
in
timely
requirements
of
lease.
the
Secondly,
be
its
least two
must accomplish at
properly
and
in the case
regulation,
law,
on
most
industrial projects,
attain
scheduled
operations
shale
unlike other
order
oil
constitute
able
to
importance,
and of equal
the
communicate
public and
be translated into
environmental
carry
in
out
impossible
trained
mind
decision making
obligation
is
perhaps
great
requires
which
insignificant
will, in
the
most
diplomacy,
detail,
to the
gathered
in terms
to
judgmental factors
information
project management
because it
practice
termination,
to
This latter
environment.
environmental
government, the
fit the
the
can
which
fact, bene
difficult to
strong de
and an
ability to
weigh
,the
The
are all
This
in
environmental
environmental
manager's
environmentalists,
diversity
of
we
do
litigation.
problem
although
we
among the
opinion
because
arises
same
species
is illustrated
by
an
anecdote
and a
the
as
several
looked up
lion
in
salvation was
minutes
and
to
his
appeared
when
prayer which
he had
surprise
not yet
too."
said
the missionary
"Yes,"
said
praying for
the
lion, "But
salvation.
am
been
"Oh,"
praying.
he began
with
there is
relief, "I
with some
fervor.
the missionary
eaten
was
also on
difference between
The
saying
The missionary
moral of
us.
his knees
Christian
You
are
have different
management
views as
to how to get
decision making
of an environmental manager
clearly
a requirement
for
requirements of a
a successful project.
lease
is less
or of
subject
law,
it is
81
The
is devoted to
some
of
the way to en
vironmental salvation.
The first
major environmental
Environmental
established
healthy
any
of
Through its
impact
1969,
the National
national
of
maintaining
federal
environmental
of
statement
analysis prior
of
detailed
policy
and
preserving
procedural
NEPA
called
commonly
a
purposes
and consideration
preparation
and
of
and
environment,
environment.
setting
other
among
federal level is
the
at
"NEPA."
Act
Policy
law
government takes
major action.
The
(which is generally
required statement
"impact
an
an
referred
to as
"NEPA
"environmental
or
have
my talk, today, to
it,
vironmental
Program is
outline
those matters in
U.S. Department
the
of
detail. For
the Interior
six-
those
volume
an
of
point
who
En
Leasing
The
and seems
of
federal
likely
interpretation
to
continue
and of
has been,
action
to
be,
a subject of
"major"
and
to
the impact
use
statement procedure
in
which
has
federal
serious
act
is
implications. If the
is
question
major
an
developer
such
Alaska
those
tives
bears the
who
pipeline.
In terms
saving
and
respect
to
risk
and
as evidenced
of capital costs
to
the
millions of
certainty
oil shale
dollars
of
be
an
planning
the
at
the
need
impact
costs
the
inflationary
per month.
and
wrong, it is
delay. The
of
trans-
economy,
strong impetus to
development,
no
alone, in
create a
environmental
by
costs
to
timing
legally,
and, thus,
proves
required
the
a close one
consider care
earliest possible
for NEPA
date.
statements
been
prepared
principal
NEPA
question
82
Quarterly
remaining is
Colorado School
of the
federal
major
Plans
lease terms,
suggested
will
that
From the
largely
the
The
action
separate
development
preparation
various
for
leading
water
projects
significant
actions
federal
which
statements
is
considered.
plan
If the
addressed.
be
hearings it
NEPA,
may trigger
and
from the
rights-of-way
the
impacts
actions
federal
occur,
the
of
NEPA
lands. That
by
need
oil shale
to the
for
is
For
matters.
or
exam
federal
required, if
are
if
other
takes
major
place
requiring
NEPA statement must be
a second question
whether a
NEPA
statement
impacts"
of
"secondary
under
facilities. In
that
Para
near
chute
which
only the
also
be
contacts
that
state
regard, the
compasses
re
statement will
government
second question
scope
of
likely
rights-of-way
expands
be
will
plants on private
This
have
groups
seems certain
impact
involve ancillary
directly
the
the
to
and
question of need
answer
considered.
an off-site
the
by
performed
impact
public
arises
corridor
utility
be
requiring federal
federal action,
setting
to
up to those hearings.
if
for
or
lands,
must
in
plants, but
tween oil
to
the Detailed De
on
environmental
developers for
major
Some
NEPA.
standpoint of environmental
or combination of
oil shale
amount
with
work
environmental
supplemental
procedures
ment applies
ple, if
together
which
with
comply
hearings
public
in the
occur
the
and
since
moot,
full
lessees,
of
quired at
for
program provides
Statement
mental
lease terms
the
under
the In
of
actions.
The lease
velopment
the Department
by
subsequent actions
whether
Mines
of
the
en
activities on private
land. Those studies, which were caused to be carried out by Colony, have
been delivered to the Bureau of Land Management for its evaluation and
use
in NEPA
compliance which
In summary,
ties
of private
under
lands,
the
is
now underway.
of
NEPA
is
not
which are
required, the
by
application
even
NEPA. On
private
to early oil
if technical NEPA
those required
by
shale
appli
the stipulations
lands, because
of
the
than
potential
for
83
off -site
holder in
with
the Piceance
the
Basin,
federal government,
the
and
which
is
land
a major
from
severe
failure to carry out early environmental planning, the need for, and likeli
hood of, detailed environmental and ecological evaluation is high.
The
second
of
system
environmental
is
regulation
air
quality
implementation
program, the
quality
quality regulations in Colorado rests with the
control.
direct
major
administration of air
air
that both
early in
order
view,
quality
be initiated
work must
establish
design,
and
ning
to
point of
and
plan
with
The
need
regulatory
plant operations.
the
Modeling
for legal
dispersion
and
work.
design
of pollution
air
control
protection
connection with
for design
programs
project
and
planning
and
evaluation
engineering
are
which
systems
in
standpoint of
required
Authority
to Construct
formal
quality
Early
control equipment.
project
to
scheduling
obtain adequate
The
on
air
quality
The third
major
level. Regulation
building
appear
and on private
tier
of
Rio Blanco
county-wide
applicable
by
collection
land
for
regulations.
division
to industrial operations,
of
and emission
for
essential
are
Failure
with emission
development
is
the county
at
use controls.
the
of
In
regulation
occurs
use of
which most of
upon
lands.
County, (in
zoning
design
to apply equally to
environmental
regulations provide
Both Garfield
the
or
Zoning
lowed
at
data
by
of commencement of construction.
regulations
review
data
obtain
based
permits are
and of plant
and
planning
timing
and
These
thorough engineering
meteorology data
and
to
and a
applications and a
staff of air
the
most
land for
lands
private
federal
connection
particular purposes.
land)
with
are
have
certain use
held)
Procedures for
and
enacted
of
land
may be
al
public hear-
84
Quarterly
of the
of an
Colorado School
impact
statement
by
the
of
Mines
applicant
may
also
be
required.
Experience
operations.
under
However,
the requirements
for impact
applications.
separately
and considered
again significant
The
the
However,
delays
foregoing
in
suffice
if
for county
be
administered
timing
schedules or
must
plant
Thus,
to
could occur.
major
environmental
laws
in this discussion.
My
ered
with
NEPA.
by
also
these applications
connection
statements appear
required
should
for industrial
There is,
which
of
apply
purpose
and which
have
not
been
cov
to
emphasize
the
that early
effectively.
regulatory
schemes
is
essential
to
carry
out
that
work
The title
Problems
of
for this
theme
the
each of
portion of
problem
in
papers, it is
oil shale
evident
the titles
that each
the
Evaluating
State
paper
the total
Colorado,
of
it
for the
for
and speakers
here
constitutes a
program and
my
role
in
development.
title or a
the
"Environmental
Admittedly,
as
serve as a
actually
one evaluates
development.
that my
attempting to
ago
As
background in
priate
could
entire meeting.
other
program
Development"
Oil Shale
of
indicated in the
paper
my
that
committee was
shale
nearly 10
years
Advisory Committee.
in tune
with
the times,
and consisted of
of our oil
shale resources.
on earlier
abortive attempts
development
In
shale
of
1970,
leasing
of
develop
both
federal
program,
asked
First, "Is
development
program,
and
to
encourage
the
and
leasing
federal lands.
private and
the Department
portant questions.
impact
to
technology
adequately
development?"
protect
prevent
economically
to minimize the
Second, "Would
now available
the
establishment
industry?"
In
and
order
to determine the
answers
chairmanship
nomics of
of
John B.
Tweedy,
set
called
Environmental Protection
Vice
85
subcommittee,
under the
( SCEEP )
and
up
The
Chairman,
subcommittee sought
Committee
on
Oil Shale
86
Quarterly
from knowledgeable
representation
in
January 1971,
of
the
"state
from
able
This
of
to the
the
ment
from
would not
be
report, "The
recognizing the
approximately 7
for
need
recommendations
as
ment,
( 2 ) The
Joint
local
needing
surface
ap
composed of
fed
develop
to evaluate several
information:
water,
development impacts.
and
revegetation,
Thomas W. Ten
Natural Resources,
the committee.
accepted
people
the
report
director
and
the
chairman,
and
local
citizen
recom
on
T. W. Ten Eyck
with
the
and rec
(COSEP),
of
appointed a
Oil
as
development,
citizens
executive
to their solution.
Eyck,
approximately 50
slope
estimated as
water,
western
have been
industry
regional
oil shale
its final
of
vegetation and
ommend approaches
200
wildlife,
of
mendations of
by
this protection
of
Advisory Committee
additional
underground
Governor Love
ed
(a)
(b)
( c)
(d)
tion
costs
an underground or surface
information,
and representatives of
subjects
committee of
percent
additional
of a
state and
eral,
technology
present
follows:
Establishment
Department
increments for
operating facilities
avail
Second,
also estimated as
First,
adequate
were
is
report
$2.00.
environmental cost
proximately 7
( 1)
The
prohibitive.
commercial, the
Survey for
impact.
significant negative
re
specific conclusions.
Its
the problem.
understanding description
development and processing I have
permitted a short
two
Colorado
and
best, brief,
the
of oil shale
report reached
attacked
governor and
Colorado Geological
the
Mines
of
interested federal
and
diligently
and
still represents
If I may be
ever seen.
and
industry,
port,
Colorado School
of the
governmental
agencies,
representatives
of
and
be
affect
both local
environmental
or
ganizations.
The
committee
areas:
immediately began
also the
overall
an
long-range
environmental
not
only the
environmental
problems
evaluation
of
categorized
inventory
and
these
impact;
prob
rehabili-
Colorado's Involvement
tation and revegetation;
Consequently, four
formed
were
and regional
87
in
development
and
land
use planning.
subcommittees of
to address
each
to:
(1)
(2)
evaluate and
delineate
to
the
solve
problem;
secured on
requirements
searching, discussion
soul
basis
the
of
totalled
approximately
financial participants,
in table 1.
The
First,
also
the
and
supply from
the impact of
to
make
only
potential
of
The
ing
an
determining
if
velopment of
of
changes
final
date
no oil shale
4-6
in
the impacts
or
of
de
develop
the
agency
Survey.
select
This
the
project
be
July 1, 1974.
to take place;
plants was
barrel
ecological
not
only
was selected as
which
group
oil shale
day full-scale
a
but
occur
if
upon
a moderate
the
de
impact
of
nationally known
with
would
Boulder, Colorado,
environmental
and
highly
experience
considerable
respected
in
similar
the investigator.
Its
project
is
contracted
to
be
com
by January 1975.
The
the
and
research
pleted
and
the
the
environment
lems,
supplies.
environmental
ecologically
problems
and a
assigned completion
development in
Institute
sources, but
mining
the mining
The
problems.
subsurface
the industrial
related
waters on potential
of
one-third
potential
impact
was
available on
funding
this study
to
funds,
to three closely
understood
underground
both
not
these
con
company
funds
allocation of
but lesser
abundant
ment on
the
$725,000. After
federal grants,
one-third
exact source of
was addressed
water project
available
Second,
ed
The
government support.
some
negotiations, the
and
local
conduct
research.
Surprisingly, budget
siderable
consulting firms to
rehabilitation
problems
and
and revegetation
potential
methods
of
study
was
aimed
rehabilitating
and
at
evaluating
revegetating
88
Quarterly
Colorado School
of the
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o o <
-H
Colorado's Involvement
spent
the site
on and off
shale
during
is knowledgeable in these
Its final
is
completed and
the
involve
would
of
Phase Two
which
entailed
elevation,
is
report
development
only the
was selected as
required
land
and
presented a somewhat
use
planning or socio
different problem. Success here
acquisition of additional
land-use-decision-making
development actually
on
1975.
by January
data, but
planning
for in
telligent
disturbed both
surface
not
89
planting
area of regional
impact
the
for distribution.
available
several years.
economic
of and
problems
The
life
report of
for
be
considerable mined
a contractor.
total industry.
plant or the
mine,
has had
those
and also
shale,
in
basis
regional
when
if
and
oil
shale
Part
impacted.
the
of
an
office.
economic
impact data
but the
Institute
ary
final
their
report
If successful, this
mechanism,
mission or
must
be
no
work
is
these
by
themselves,
much
not
will
it be the
have
no
original
socio
local decision
a contract was
and
and
staff
additional
the
only
to
Associates, Inc.,
Den
Denver Research
working
should
be
Their
available soon.
date.
termination
papers.
successful
Planning
Com
exercises
presented not
we
be needed,
project
in
ning
fact that
the
expended
was
Commission to THK
now at
to be properly
These
study
whether
menting if the
ment are
this
results of
overall
Planning
planning
and
would
oil companies
funds for
Recognizing
maintain
makers,
took place.
had
only
questions
will
of
this
major
industrial
develop
handled.
other
answers
neither
impacts
basic
but
research.
Many times,
the research
the information
have to be
nor
foresight to
addressed
by
the
anticipate.
individual
has
begin
Many
companies
of
or
governmental agencies.
An
obvious problem
shortage
that
will occur
Quarterly
90
in
New
velopment.
accrue
hospitals,
This
available
will
is
aimed at
oil
tax
school
facilities,
their wives
services
systems,
de
shale
facilities,
recreational
and,
the
has initiated
an
additional
continuing
This project, titled simply "Fiscal
providing local governments with an evalua
funded
Study,"
by
problem
serious
Mines
be impacted
demanding
transportation
federal-state-privately
Shortfall
influx
Although taxes
be
will
of
long-range benefit to
as a
required.
to the
rapid
the jails.
even
that
communities
people
This
communities.
tion systems,
Colorado School
and children
yes,
local
the
each of
of the
project.
tion of:
(1)
the
magnitude of
cies and
(2)
the
list
front
Funding for
currently
available
governmental agen
be
end
available
fiscal
for
use
by
local
and state
financial
of potential
alternate
re
and
solutions
that
in solving the
governments
this study is
being
derived
industry
federal,
and will
commitment,
total
$36,000.
some
Because information
ly
local, federal
"recipe
or
might
local
on
local communities;
(3)
possible
reports
distribution.
administrative
federal
without
distribution
will
be
This information
will
to
developers to
who
have
tion
should
an
interest in
allow
also
meet
be particularly
allow
government
essential
the
widest
valuable
to
protection;
to the industrial
local
be
and
to
citizens
The informa
the environment.
for
to prepare itself
potential
future development.
The
sored research
and roster
become
of speakers
presenting final
of
the
for this
meeting.
Three
speakers or
worked on
their employers
were
of state-spon
evaluates
speakers
funded
by
the
are
program
essentially
the project.
financial participants,
and
Ten
actively
things, however,
following
and
can
be
Colorado's Involvement
minimized,
and
government,
The
industry
potential
shale
and
oil
for this
mental
is
resource
can
target is
of
be
total society
rich
in
solved.
face
such
importance. Economic
so great
that I
be set,
guidelines can
and
immense energy
enough
that it assumes
am
that
not
return and
convinced
shortage.
(600
magnitude
to
be
only
the
mined and
economic
societal
that adequate
technology
that
tremendous
thick
enough and
technology),
an
We
91
can
evolve
but
demand
environ
to
meet
those guidelines.
environmental
evaluation and a
ations.
both known
beginning
and unforeseen
at a neutral
mation available
and strategic
enough
to
me
to provide
both
in
the
its
role
in the
been
history
in that
made
environmental problems.
past
enough and
environmental
now
available,
impacts
of
and more
oil
shale
of mankind.
program.
After
and
More information is
evaluation of potential
now
position,
incentive is large
have
technical and
The State
of
Colorado
can
study
and
development
development
be justly
proud of
of
Cameron
and
Jones to
obvious problem at
That
oil production.
was projected
least
tion
be
industry
barrels
the
considerably thereafter.
For planning purposes, the
day
rels per
was used.
that the
mated
trial growth
It
should
the
be
we are concerned
diversions, because
stream
next
increase
would require
An
to
Jones
and
consumptive use
noted
at
primarily
the
this
130,000
of
point
indus
acre-feet of
bar
report esti
River Basin
Colorado.
would
of oil per
achieved within
within
was
could not
that the
one-million
will
the outset
industry
con
the estimated
make an appraisal of
oil shale
the
employed
to the
and
than
the Upper
various states
based
barrel
day industry
estimated
that
a one-million
145,000
The
vironmental
issued
estimates as contained
in the
average
in the "Final En
Program,"
Leasing
earlier
same production
consumptive
use
of
water
of
the In
to
an
of
various
estimated
The
panies,
contained
155,000
is
Colony
expects
later this
year
Development
to initiate
in
western
Operation,
construction on
a
a
consortium
50,000 barrel
Colorado. Average
daily
93
per
production
day
com
plant
from this
94
Quarterly
plant
22
is
On the basis
be
sumption would
Colony
have
and
with a
million
information
the
of
Cameron
at
barrels
industrial
Colony
the
daily
Mines
of
water
consumption
day,
per
the
be identical
in
the
is the only
operation
not
Obviously,
requirements.
of
con
water
This does
specific
A summary
barrels,
175,000
about
Nevertheless,
operations.
Colorado School
of a
associated municipal
proposed
we
46,000
estimated at
acre-feet.
clude
of the
for
one
which
this time.
various estimates
is
follows :
as
Colony
and
Jones in
(extrapolation), 175,000
acre-feet.
As
you can
see, the
strongly
suspect
and we
two estimates
did
disposal,
cessed shale
high
revegetation,
earlier estimates
and
the staff
upon
the
of
too
made are
increased
state
and
barrel
carbonate, from
all
estimates
industry. Until
shale oil
factors,
heretofore
day
demonstrated, the
support a million
is actually
250,000
calcium
between 200,000
ment
attention
water
pro
Based
for
water requirements
concentrations of
being
to
not
be
required
lesser
require
planning is proceeding
state
this
on
basis.
The
most comprehensive
has been
study
of all aspects of
the oil
consisting
of
conducted extensive
field
experiments
The disposal
relating to
millions
tons
pollution
problems.
obviously
residue
Colony
oil shale
is both
is
dissolved
of
In
shale
contamination of the
residue
addition to en
be
Colorado
a permissible
After
pro
indicate that
of
problems, further
percolation of
In place,
cessing, the
The
industry
shale
carried on
the
problems can
shale residues.
the
be
solved
by
the
Field demonstrations
residual material
to
a state
Water Prospects
impermeability. With
of relative
lizer
3
water, the
and
This
years.
by
ized
significant
water which
in the 1950s
water
the
process
will
follow
question
in Colorado to
water available
environmental
with a
by
aggravates
pattern
figure
impact
of
into
already
also
on
other
If this figure is
acre-feet.
water
hand,
estimated
an
that
conclusions.
there is
sufficient
day
industry.
per
itself to this
from
point and
a realistic
being
viewpoint,
ground
storage
water
to indicate
meant
both
process
On the
relies
favorable
barrel
statement addresses
160,000
believe this
or not
support a million
we
no
stream.
the answer to
we
such
of whether
basis. We believe
use,
is that
problems, it
some as
However,
available on an annual
apparently
25,000,000
into the
to the
will return
more careful
up
Colony development
comes
The
a period of about
by Colony.
The in-situ
deserves
in
1960s.
and
proposed
We
problem.
ferti
supply
established
the
that
requirements
fact in
revegetated
much of
95
and adequate
contouring
be
group
for
process accounts
Colony
the
proper
Oil Shale
for
figure
of
availability for
an
too
supplies
a considerable amount of
study, together
with a con
siderable amount of
is
still available
the Upper
pact and
The
problem with
any study is that no one can actually define the precise amount of
to which Colorado is entitled under the terms of the compacts. In
some
Basin
of
uncertainties
to the
differences
tion.
Based
there
is
will
various states of
in
addi
tion to existing
Treaty
water
At
some
be taken to
upon various
the
future time it
Colorado River
release of water
appears
likely
to satisfy
that these
studies,
no water available
for the
the
for the
some predictions
oil shale
have been
industry. Such
resolu
made
that
predictions are
error.
All
water
supply
studies
are made
by
estimating
the
consumptive
96
Quarterly
use
requirements
Colorado River
of
least 800,000
there is at
annual
basis
conditional
of
is in
ago
used,
under
the
for
use
the
of
allocations
by
the
be
further
as
it is
under
interpretations
Mexican
and
unused
water
is
overshadow
Since the
years
take place in
exploration
in terms
Valley
water resources
Less than 20
would
activity
Grand
the
required.
the
of
most restrictive
determining
water will
was
in
obvious problems
the
all
although
an
industry.
oil shale
where
certainty that
The fact is that
to Colorado on
this currently
of
portion
significant
to
under
the
on
impossible,
not
available
acre-feet of water
not
if
an actual usage.
being
determining
it
into
develop
decrees
decrees. It is
now
Water Treaty.
One
is
which
the available
available
difficult,
status of conditional
will not
Mines
of
conditional
and
It is
its tributaries.
and
decrees
such
absolute
existing
Colorado School
of the
of
of potential
are
as compared
to the
main
In the Grand
open
to the
adequate
water
delivery
the
other course
will
oil
of
water
is the
of
are
would
these
the
of
provide
is to
courses
purchase of
briefly discuss
On
One
supply.
stem
an
immediate
secure
and
for
contracts
projects.
reclamation
existing privately
action
of
The
contractual
for
use
in
project,
the
could
Grand
a unit of
supply
Valley
about
the
Fryingpan-Arkansas federal
70,000
acre-feet of water
basis. There is
on a contractual
annually
some con
certainly
industrial
preclude
The
the
not
construction of
velopment of a
that
project
requirement
is in
doubtful
firm
acre-feet
of
water
could
also
be
A firm
would almost
reservoir.
provided
from
the
reclamation project.
will
municipal and
status.
About 80,000
authorized, but
of
Water Prospects
In
water
addition
rights that
to
federal
be
could
Oil Shale
for
sources, there
purchased
97
are a number of
if the
owned
privately
is right. In fact,
price
various
rights have already been purchased and will provide the water for at
least the initial oil shale production as now planned. Private rights with
historic dates
than 1930
earlier
virtually insulated
However, there is
are
mands under
any de
against
a
factor
limiting
in the
In the necessary
change in use, our
diversion
priators,
or
though
even
that in
means
most cases
Only
law
state water
be
must
greater
provides
that
point of
other
appro-
and
depletion than
in
change
protected
the purchase
in any
right.
junior,
for
court proceedings
the original
existed under
proceedings
can
this
be de
matter
termined.
to
industry,
some extent
is to initiate
In
ripen
of
third
an obvious
almost all of
the
filings for
original
Because
worthless.
could
by
Actually,
tributaries.
panies.
there is
courses of action
however. There is
no
way
This
made
by
were made
These
many
cases
are
shale
industry
various com
these
claims as
the
exception
anything
industry.
do
not see
this
its
and
we
oil
third course
the
pursued
we regard most of
right.
water
usable
on
into
has been
course which
rights
for
secure water
water
numerous
to
re
we see no
mature
expense
oil
in
expense as
placing any
serious limitation upon oil shale production.
However, the White River
Basin poses an entirely different problem, which I shall briefly discuss.
The Piceance Basin of the White River produces an almost insig
connection with such a
supply,
resources
in the
basin,
we
While there
do
not
resources will
be
of
any long-range benefit to the industry. The ground water contained in the
deeper formations is of such poor quality as to present a serious disposal
problem.
to
us a
If
a major
foregone
industry
conclusion
is to
that
develop
in the Piceance
Basin,
it
seems
area.
produces
about
610,000
acre-feet of
98
Quarterly
Of that amount,
water annually.
On
consumed.
be
would
than
more
to
entitled
through
problem
system
of
in
prior
quantity
the river
leave
which
River
rado
in the
use
in
other
of
for
Subsequently,
ized
as the
Yellow Jacket
project
sponsoring
thorny
the Colorado
River
shale
of
the
of the
of
delayed pending
basin. When it
White River
high-grade
vised
to
the
was
to
deposits,
potential
feasibility
District
Conservancy
was organ
even
it
1956,
industrial
completion
contain
was
of
for
the
feasibility
the
perceived
clearly
the
the overwhelming
Yellow Jacket
demands
of municipal and
has
and
develop
report was
appeared
oil shale
reflect
feasibility
The
resources.
energy
This
industry.
authorized a
therefore
use
and contractual
was
ment of
for
the White
a number of years
study
the
now committed
consideration
under
the potential
Ute Indian
northern
situation on
awaited resolution
of
government
uncommitted water
that the
not mean
that it
contends
federal
the
within
also remains
parts
if any,
being
can
system
industry
Utah
of
flows. There
little,
for
is
acre-feet
of water
appropriations
River is hopeless.
50,000
seem
The State
Mines
of
which
Colorado,
than
would
the case.
not
a portion of
claims an unspecified
reservation
is
little less
for
adequate
such
alone, it
arithmetic
basin. However,
is
Colorado School
of the
of
in 1972
water
the
preponderance
oil
shale
and provides
The
industry.
for the
furnishing
annually.
water supply.
I strongly
authorize construction of
of
the
other six
position
the project,
we
solution
we attempted
we would
do
committed.
recognize
We
face
These
states.
exist.
that if
that the
position, but
suspect
that a serious
but it
to get Congress to
states would
in
water
of
to Colorado
are not
one
take the
supply
will not
problem
be
does
easy.
entitled
by
any interpretation
of
the compacts.
All
of
Water Prospects
this
water
Actually,
times this
several
for
retrieved
conditional
many
degree
ed
for federal
awarded
to municipalities.
the exercise
in
to these
450,000
depletion to
this
The total
projects.
estimated at
the validity
the
of
It
to
does have
decrees award
the state
those conditional
of
to
individuals,
Colorado
are seven
have
which
not yet
depletion for
annual
acre-feet.
However,
western
recognize
reclamation projects.
constructed.
basin
the
little
have been
which
condi
industry.
shale
been
irrevocably
decrees
of control over
decrees.
is included in existing
is
water
the oil
99
volume of water
this
of
by
use
The Colorado
to
awarded
decrees. Much
tional
be
has been
Oil Shale
for
would
be
these
to
possible
before
decrees
seven projects
is
reallocate some of
of
all
awarded
the
projects
are
constructed.
Such
require a revision
of priorities
decision
would require
Colorado
and of
am afraid
the
to
to
by
to
serve
the
board,
this
some resolution of
this
still
aquifer
and
pumping
industry.
would
intensifying
saline
employment
However, I
reached
in
have heard
we
resources of the
industry,
the final
the
staff of
the
will
siderable problem
be
into
of major
state water
summarize
water
to the
to the development
of a
levels, thereby
for irriga
waters
may
that are
aquifers
importance in
less
much
oil shale
industry.
water
supply
full-fledged
prob
ground water
board is
waters
disposal
wildlife and
of some predictions
ground
Prolonged
by
develop
These
lower
used
full
under
short
very
fresh. While
To
hoped
long
be
to
as
In addition,
to
However,
about
case.
have
tion
the
may be the
have
ing
a reallocation
by
I terminated my
problem will
become increasingly
lems
until
served
industry. I had
oil shale
and
water
the ground
alluvial
will
the
be delayed
could
be best
would
would
Essentially, it
government.
state
whether or not
ment
the
best. It
the
future.
near
In
that
as
a painful process at
with
be
reallocation would
re
now
water
sustain
optimistic
poses a con
oil shale
industry.
Quarterly
100
The
is
problem
be
Earlier
during
these remarks,
lem,
have
a major
in part,
States
and
Water
California,
is
having
impact
the Republic
near
Treaty
upon
also contend
said
in the
supplies
adequate water
the
further
that
dissolved
of
this
oil shale
long-standing
supply
the international
will
solids
states of
that the
the
increasing
dispute between
pursuant
lower basin,
of
salinity
those
not
is in order,
statement
boundary
the
contamination of
of
1944. The
of
elaboration on
grows out of a
livered to Mexico
can
industrial
materialize, an
percolation
Some
permissible practice.
will
depend entirely
will
solution
municipal and
needs
Mines
of
made available.
for
needs
The
the demonstrated
upon
Colorado School
of the
areas
be
since
prob
United
the
de
of waters
to the Mexi
and
particularly
865
There is
standards
dissolved
total
solids.
considerable
the
we
on
river.
controversy
In Colorado,
taken
at
cannot
federal
to the
agree
expense
salinity
proposed
to abate
some of
the
dissolved
the introduction of
control projects on
the appropriation
salinity
may
8275,000,000 to
about
further
contamination of the
construction of various
This legislation
construct
feasibility
of
to
as
carried on without
Most certainly,
various
minimized
specified
salinity
investigations for
mamtaining the
as of April 1972,
ultimate cost of
by
about the
develop
adding
oil shale.
However, it
large-scale
significant contamination
operations
will
still remains
to be
processing can be
to the Colorado River.
oil shale
be carefully
monitored
by
state
and
agencies
encouraged
new
whether or not
all
authorizes
industry.
this information is
demonstrated
by
The
the
federal
also authorizes
control measures.
None
would authorize
of the
well
possible
salinity
now
The legislation
control works.
additional
of
There is
solids.
to
companies,
through
and
further
we
research
and experiments.
problem can
However,
at
be
this
Water Prospects
time we are not certain, and only time
will conclude
by stating that
industry.
perhaps
as
be
If the
much
as
we
for
will reveal
have
made available
arises, this
need
400,000
Oil Shale
acre-feet.
no
doubt
annually to
amount
101
that at
could
However,
least 250,000
be increased
there
will
be
to
cor
any
means
supply for
will
be
implying
that it
an extensive oil
required.
desirable, but
To many
to others
of our
such readjustments
may
seem
necessary.
not
be
Lane W. Kirkpatrick
INTRODUCTION
It's
distinct honor
to
of
My biggest
substantial push
concern
by
the
oil
regarding
federal
shale
government and
big industry
to
this
get
industry
new
state.
It's gratifying to
havior
by having
governor and
of
Mines
of
Paraphrasing
seeing
seminar
change
here today,
general
in this
make
passive
be
by looking
in
advance
destroy, by
Colorado
attractions
main
the concern of
to
state's
developments.
Colorado's
careful not
reputation
for
our
overdeveloping
in
tarnished
and
One
that
this
start
the Colorado
at such proposed
be
in Colorado
started
threat to
clean
air,
a still
which
shiny but
mountain
beauty,
to
qualities
live. Energy de
somewhat
slightly
and a comfortable
climate.
In
regard
emissions
from
to
air
pollution, I
oil shale
will cover
processes,
the
carcinogens
development
following
in
oil
items:
shale,
and
expected
the esti
My
staff
is reviewing
an
"authority
to
application
from
Technical Secretary, Colorado Air Pollution Control Commission, and Acting Director,
Air Pollution Control Division, Colorado Department of Health, Denver, Colo.
103
104
Quarterly
Colony
Colorado School
of the
Development Operation.
proposed good
My
feels
staff
the
Mines
that this
emissions.
for
of
This
development has
Colony develop
of oil shale.
40,000 barrels
furnaces.
fugitive dust
mining
Dust
from
be partially
can
day. The
of oil per
the
at
from
bins. Controls
on
processed, this
of shale
beginning
mine
of
controlled
proposed
the process,
and other
vents, roads,
by
Starting
are expected
emissions
operations.
using dust
ton
and
dry
veyed
to
ventilated
point, the
wetting
baghouse for
emission
major
( ceramic
elutriator
and
ball
hourly
emissions
be
will
because
of
include the
sources
process.
bin
surge
control
reheat and
fractionation
to the
crusher
enclosed and
its fineness.
oil
From this
preheaters, the
shale
cleaning process )
For this 40,000 ton
from the
fully
and
the
spent shale
oil shale
processing
in
1.
table
It is
our
preliminary
conclusion
de
signed
the
to
meet air
ultimate
impact is
CARCINOGENS
Mr. Todd Reynolds,
has
assisted
body
in preparing this
of scientific
laboratory
portion of
my
paper.
knowledge is inadequate to
ently
concerned
with
possible
unless
the
controlled.
air
assess
to
also
instructed
if unhealthy levels
are
problems
approve an
I have
properly the
Nevertheless,
health-related
supervising chemist,
We think the available
to
detected. Besides
we are suffici
that I
"authority
have in
to
adequately identified
compounds and
carcino
to
and
require ambient
process
hydrocarbon emissions,
Am Pollution
of
105
bo
O
Qi
O
O
M
ft
bo
o
I
106
Quarterly
of the
o
o
CO
Colorado School
sd-
o
o
Mines
CO
ON
1
1
1
u">
l-l
tf
o
as
of
IT
CM
IT)
l-l
CO
CO
5.
v.
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v.
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o
o
o
CM
vO
l-l
l-l
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(Vi
CO
CO
C^j
CO
Q
25
o
o
o
o
o
o
o
CO
r^
1
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IT
o
o
m
SO
CO
o
U
c/d
o
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o
o
t-l
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1
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PQ
<
w
o
s
o
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to
<&
w
O O
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IS
< ?s z
11
JE
rJ
I-H
(OSrJ
to p
wc5
M ^
O 05
o
H
to
ass
ss
<
to
ex
SP
w
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w
H
.-J
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t-l
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35
CO
l-J
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o
H
O 13
CO
Air Pollution
of
107
be
transported
Since
operation,
information
decisions. We
and permit
we must
on which
rely
base
to
on other organi
our
final regulatory
by
prepared
effect
may
for health
zations
light
by blowing
are
"Investigation
Shale
of
the Hydrocarbon
of
C. H.Prien;
Structure
Formation,"
by
of
J. J. Schmidt-Collerus
and
and
( PAC )
Shale Ash
the
of
and
PAHs
Green River
Formation,"
by J.
includewhat
(PAHs)
How
present?
humans
Carcinogens in the
C. H. Prien.
Some
carbons
of
and
or enter
hydro
polynuclear aromatic
identities
the PAHs
will
into food
regarding
be transported into
the
of
contact
with
chains?
quality
the
standards
is
state standards
micrograms
will
cubic
and
federal
ambient air
Rio Blanco
I doubt the
meter, respectively.
Counties,
45
and
standards
15
will
amount of
have to
deny "authority
The ability to
to
meet ambient
its
difficult
ambient air
since
the
quality
unless
air standards
Also,
In Garfield
questionable.
for
tolerate the
posed
per
question of
the
must
standards can
be
analyzed
standards.
The decision
choose
be
met.
using
to
air
recon
on standards will
be
designed to
citizens of that area and of the state want to sacrifice the present particu
late
matter
standards, hence
air
clarity, to
help
relieve a national
energy
problem?
Even if
ambient air
quality
the
national
forests,
development
areas.
in valley areas,
should remain in
The
be the
main
Quarterly
108
tool
for
of the
Colorado School
that downwind
demonstrating
pollution
air
Mines
of
problems
will
not
occur.
What
drafted
indirect
sources
for
and scheduled
sources
and equipment.
such as office
be
be
should
hearing
modeled.
Indirect
buildings,
Commission regulations,
modeled?
in
Direct
sources
June,
require
sources
include
that
include industrial
motor vehicle
shopping centers,
both direct
now
and
processes
traffic generators,
highways, housing
subdivisions
CONCLUSION
I trust that
complete environmental
plans made
that
ecosystems,
as well as
also
state
best
reflect
toward making
public
interest.
the
location
scenic,
inventories
will
be
of significant natural
cultural and
critical environmental
historic
prepared and
amenities and
resources of
land
use
this area.
guide
the
decisions in
the
Frank G.
My
remarks will
to the Persian
shale
documents in
Cooley
the White
Gulf;
an oil shale
River;
and a
discussion
of
key
the
library.
The
most
important fact
January 1, 1974,
about
the Piceance
the posted
price of
per
oil,
barrel to 18^
The
per
on
around
5^
barrel.
run
$1.5 billion
The
year.
per month.
added cost
Other
The
of
India is
of
consequences
have
When the
and
Sri Lanka
associated
evil
the increase
and
India
sad
of
(Ceylon)
and
Africa
consequences
oil
seem closer
to
prices
are not
million per
upon
Indian
surprising to
and
us
be
here
$800
about
Bangladesh, Zaire
cause we
to the economy
the
consider
and
Philippines, Korea
the effects
Uruguay.
The
upon
effects
us.
The pricing structure for world crude, and particularly for oil from
the Persian Gulf, is now related to oil from shale in the Piceance Basin in
several ways.
limit for
countries.
the
This
price
One
of
the
there appear to
factors is
the
and
109
from
syn-
Quarterly
110
thetic
oil
from
Another is the
shale.
briefly
wish
sound
to
consequences of
Secretary
the
of
for
the
future
the
about
growth of
economic
resolution of
"failure to do
have
we cannot
sources.
the
of
grasp
world
At the Washington
urged
coal and
the United
of
sincerity
factors because
these
energy crisis.
State Henry Kissinger
questions
prospects
the oil
of
from
oil
of
program
Mines
of
particularly
vigor or apparent
mention some of
understanding
mental
Hemisphere
in the Western
sources
Colorado School
of the
all
Energy
the
Conference in
basis
"funda
the
countries,
hopes for
global
February, Kissinger
of cooperation and
said,
depressions
and
crisis raises
developing
the
of
so would threaten
that the
says
such
as
led to
the collapse of
1930s."
world order
in the
Secretary
Schlessinger
to the possibility
In
is, for
a
oil
barrel,
(1)
bluntly
more
barrel to be
has to
one
has
assume
weapons
political
hundreds
that
to continue, that
from $8 to $12
priced at
one
to
and referred
and
(2)
the problem
of unilateral action
for the
order
stated
of millions of
dollars in
aircraft
contribute
will
to
stability;
that in times
of
famine
crisis,
and
pestilence,
heads
cool
will
prevail;
(3)
that Europe
prosperity
will
North America
bravely
tonics,
predestined and
that it is
treasure
and
logical,
should
be
10
owned or
the
wealth
result of plate
tec
and
controlled, practically
world's
all of
it,
on
The total
effects of
only too
the increase in
Expectations
grimly.
small
Applied to
oil
make some
(1)
and
the
Gulf.
years are
these,
foreordained;
that any
have
reasonable
All
which
stoically
their lot
it
is
prosperity because
and
(4)
and
Oil
others, but
you will
find
same
thing.
hypotheses. If
the
you
don't like
hypotheses:
shale
Gulf
shale,
is essentially the
is
crude.
The
in the
long
for Persian
run wish
further to
111
the development
long remain
then the
to
move
development
a stimulation
Another
from
world oil
best lead
from
moderate
embargo
Just
And
accelerated.
becomes
to others to
velopment of shale.
at
be
will
at
the
shale,
a program of
talisman
of
sources and
further
not
the opposite.
least,
oil prices
coal or
foreign
of
stimulate
Another
If
shale or coal.
shale will
of oil
from
our
(2)
the
above
of oil
the de
reserves
in the
ownership
of several anticlines.
(3)
Internationalization
Gulf
crude prices
the extraction of
(4)
The development
pace
only
as
of oil
long
from
for
as
S7.
(5)
requires the
less
needs are
development
factor
a significant
historic
of
prices.
a small river
Utah,
in
northwest
which
Colorado
in turn is
which
tributary
flows
of
the
South Fork
Plateau,
and
in two
the North
branches,
Fork,
in
now carries
in beautiful
which
about
valleys, the
glacial
500,000
along the north edge of the Piceance Creek Basin. Piceance Creek
accounts for only 10,000 acre-feet a year, mostly in the winter. There are
year
more problems
than
water
in Piceance
Creek,
so we'll concentrate on
the
White River.
year,
about
It is necessary to
per
in
day to acre-feet.
cubic
feet
of quantity.
per
at
525,000
second,
half
million
acre-feet annually.
measure water
Water isn't
above a
quantity
and
sold or measured
flow measurement,
to
equate
barrels
of oil
in barrels. It is
measured
in acre-feet,
a measure
or
112
Quarterly
Colorado School
of the
50,000 barrel
(1)
If
(2)
your
day
3 barrels
plant requires
day,
Mines
of
of water
for
than 300
third of an acre-foot
or about one
day,
The
water
the Upper
Sixty
Basin,
direction
ties of
development,
It is,
generally
Frank Welder
conceded
amounts of
water
of
course, the
within
basin,
the
has been
the
may
of
vindicated
course and
in their
Survey
estimates
formation itself.
depth
It
are now
of
large
appears
in the Piceance
distance from
lower in the for
the
and with
Piceance Creek
quanti
tremendously
the
the vast
States Geological
mouth of
alter
recognition of
least 25
with
streams shrink.
Ben Weichman
been
He
it to carry
the
creates
of
supply
runoff.
in the field.
newcomer
to the
that spring
the United
to have
that there is at
probable
of
the rivers in
in the spring
in 120 days. This
river
symposium, there
oil shale
in the formation.
water
waters of all of
mountains
of oil shale.
and
not apparent
capture some of
the
down the
do this, he must
him through the
pany
water comes
develop
River, like
comes
the
7,000
about
in the White
percent of
one of
must
three, is
times
being
and
or an
of
the
be
big
new
statement
to
a period
dustry. The
use of
back to the
go
50,000 barrels
figure
us, but
facing
logical
Let's
challenges
of oil per
rule
of
the
25
might
be
The
source.
of shale and
sustained
water
To
The
in
from the
in the
degree the
area
of
140,000
disposal,
the
saline and
water
northwest
for
acre-feet of water
a million
may be
water within
in the formation is
a significant
rivers
processed shale
one
barrel
per
acre-feet.
a significant portion of
crushing
7,000
of
is
water equation.
thumb
million acre-feet.
shale
formation
against
as
from
of oil
day
Apply
the
many
this
saline
in the mining
used
in
and
years of production
formation.
it is
not a
replenishing
re
Colorado
and
the Bureau
of
113
sources
continuing
of
variety
industry
high quality
of
reservoirs
pipelines,
tional
water
which
the
under
rights
other
and
for
provide water
for
as
well,
having
projects, mostly
adjudication
water
There are,
water.
condi
Colorado,
of
system
industry. The
an oil shale
mation.
dam
from
is approximately 800,000
large
Piceance Basin
and
the
lifts
basin. The
called
Yampa. The
the
nearly two
would produce
Yampa
the
on
River,
original
required are
less
on
be
reservoir
in
of water
a cost problem
the
only
side of
aspects of
should not
delivery
difficult. It is
than those
power generation
to be
the
design
present
acre-feet.
The
the Juniper
of
capacity
million acre-feet.
large
develop
would
the
still
overlooked.
The West Divide project, on the Crystal River and in the area of
Divide Creek opposite the town of Silt, would provide more than 70,000
for
acre-feet of water
River. This
municipal
and
industrial
be
to many to
project appears
uses
more
velopment of shales
within
Creek
area of
the
cludes
water
water,
for
and the
uses
oil shale
development
and
the
on
upper reaches of
in the Milk
provide more
for
coal.
The
project
in
capacity
capability
and
for industrial
active
an
on
of water
two reservoirs,
River, having
is
Yampa River.
including
project
shales
of
of
basin.
The Yellow Jacket project, like most reclamation projects proposed
today, has encountered objections from wildlife interests and environ
mental groups. For the past several years, the project has been involved
in
a complex
and adjustments
objections.
the
need
negotiate
planning
in
the project
With the
for its
and
to
developing
water
with
problems
in these
for
adjust
The
of
features in
symposia
by
of
being
to
move
given
to
variations
overcome or meet
these
industry,
environmental
destined to
water
order
necessity
an oil shale
the
study
impacts
and
to
concerns, this
forward.
persons
better
than I.
114
Quarterly
Particularly,
discussion
the
Speakers in
Colorado School
of the
Northcutt
by
have thoroughly
past years
ation
Colorado's
is
rivers
to a share
Basin for
which
total river
system.
Colorado
The Mexican
known to
the
a small share of
and
Treaty
the
in
flowing
water
in the
VA
of
anomalous situ
western
and
water
obligation
the
illuminating.
was
the
the
of
it
in the
water
annually is
acre-feet
million
complex questions
Colorado River
upper
produces
Mines
in 1967
pointed out
of
to others,
obligated
Ely
of
raises
cussed.
New
in
Mexico,
75
1922,
the
states of
Lees
river at
Ferry
in Santa
to
agreed not
to be depleted below an
Fe,
cause
aggregate of
million acre-feet
The
average
period
dry
cycle
was
to 11,183,000 acre-feet.
These
versions of as much as
average
The
million acre-feet.
14,874
Lees
discharge
virgin
Ferry
During
acre-feet.
flows reflecting
are residual
estimated at
12,426,000
at
flow,
was
down
di
upstream
by
unaffected
the 52
years.
Clearly,
satisfy the
there is
assumption
under
which
was
made.
In Santa Fe in
entered
51.75
was allocated
percent of
after
Applying
of
50,000
what
atives
nually
the
and
other
Upper Basin
states
Colorado
1948, Colorado
out of
is
acre-feet of water.
perhaps more
share of water
Nearly
third of
and
limited finite
are
harsh,
the
may be approximately
this water is taken an
used on
the east
side of
competing to
commit
evapor-
this
unused
for
the
shale
availability
of
areas
creases
Any
water
the
furnished to Mexico
states.
concentration of salts
increase in salinity
and
Each diversion
of
for the
high quality
only
compounds
water
in
the
Colorado.
existing
problems.
of waste water
use of populous
of
It is impossible to
overlook
populous southern
tion to
dry
end
up in
area and
to say it.
The
115
speaking to the
conclusions of anyone
in
subject of water
rela
subject of water
be
comments should
Somehow,
suspect.
hope to
we
home
strike
with
the
same recommendations.
projects of
of water
the Bureau
in
Features
to
and
wide
provide
region and
for
tee a supply
the
spring
during
supply
Secondly,
to
there is
oil
by
need,
have
from
appropriate
diversions supplying
it is
Thirdly,
now
Water Conservation
variety
time
Board,
the
those
projects
for
the
will guaran
shale.
means, to
assure cooperation
It
will
not
be
variety
and
its list
rearrange
months.
mining locations.
of
for Colorado,
to
dry
now
that
among the
stabilize
whatever
water
projects
water
press on with
for making
of water
of
to
runoff
should
nation
assured
requires storage of
or the environment
and
support
Reclamation. An
of
Colorado
western
flows
stream
for
there is a need
First,
to
subject
for
of priorities
water pro
pressures.
sary.
reclamation projects.
tion may be
as great as
Finally,
to
be
celeration of
be
the
problem.
dation
of
transbasin
the
for
no
doubt
by
by
as
years.
ceased
The
are national.
ac
transmountain
congressional action
Colorado River
long
sufficient reason
projects of
10 years, but it is
problem of
Colorado
diversion.
transmountain
At the
least,
should
ing Colorado
waters of
the
water.
Such
stop
diluting
the
by
to
commitment
for the
oil
build
will
structures
make
shale process.
by
to
sure
At the
demand
capture and
that there is
same
transmountain
time, we
diversion.
116
Quarterly
Colorado School
of the
Mines
of
the
dozens
are
in the draft
following
as
the
of oil shale
of
the
bibliographies. Some
environmental
current
top twenty
impact
which
lists
excellent
statement.
should
are
suggest
lead into
other
sources :
1. Grand Junction
Kirkham's
Sentinel.
2. The March
finest
Daily
short
9, 1964,
discussion
3. The
ever
is the finest
issue
of
different
There
the State
two
account
to
be had.
on
Leasing
Advisory Committee, January 1971,
of print.
are
and
Gaylord
and
done.
day-by-day
The Oil
Report: Report
Tweedy
Helene Monberg's
printings and a
third
has been
now out
made
by
ing Program,
of
the
Interior, Washington,
D.C. $28.75.
Review of the Prototype Oil Shale Leasing
Program Final Environmental Impact Statement by the Environmental
5. A Scientific
and
Policy
of
October 1973.
Washington, $2.00.
6. U.S.G.S. Bulletin 1082-L:
Tertiary Geology
and
sources
Department
of
the
Lithology
and
and
Oil Shale Re
White Rivers
Smith. 1970.
8. Profile of Development of an Oil Shale Industry in Colorado, Uni
versity of Denver Research Institute, Prien, Shanz & Doran, for the Oil
Shale Regional
9. Impact Analysis
1973.
an
Oil Shale
10. Environmental
logical Inventory
by Colony
by
Development
11. Water
rado,
by
Setting
and
and
U.S. Department
of
117
$6.50.
data
and
Country
information
Fact
sources, 1974.
18. Attitudes
and
am not
fully
satisfied with
Denyi, Weichman,
discussions
twenty.
the
and several
foregoing
others,
list. It does
including
the
not
do justice
AEC. The
quick shot at
water
the
top
John S.
This
facing
paper
much of
and opportunities
In
Oil
Duff2
It is
facing
more
us
Colorado.*
assumptions:
shale
development,
Colorado,
is
the-art
mining
of
expected
be widely
Assuming
that the
both
to
use
now
be imminent in
thought to
technology found
within
the present
undertaken
in the
near
future.
technology, it may be
present state-of-the-art
land
announcement of construction
the 1973
announcement
plant
holds up,
with
a combined
by
1987
will occur
by
intentions. This
by Colony
in Colorado
first
that if
statement suggests
be in
operation
in Colorado
processing
years,
postulated
western
state-of-
and
circumstances and
might
K.
following
on
Mary
one
prepared
should
and
hastily developed.
developed in
BOOM OR BOON
unit would
involve
per
day
mining
2 to 3
force
of
such plant
119
120
Quarterly
Colorado School
of the
of
Mines
would
an estimated
Growth,"
next
costs
that may
be
anticipated.
Suffice to say here, there also are many policy and operating decisions
that must be made by local government from 2 to 5 years ahead of the
time
when
present
in
the
in the three-county
matters of water
tion
and education
trol; hospitals,
both
These
supply; planning
facilities;
public
which
are
and
for
services
will
zoning;
health
actually be
decision-making
services cover
new communities
and mental
safety,
transportation;
policy;
recrea
facilities;
and
determining
diversified community
maintaining
the residents of this region now live.
a
lems
requirement
region.0
in
that
the
or
people
similar
to
readily identifiable
(or
mining) boom:
(1)
(2)
(3)
the quality
of
life
of present residents
industrial productivity
local
government's
is
degraded;
and
profitability suffer;
fiscal viability is impaired.
to ignore the
ernment neither
to
for them.
pensate
costs.
It is
ameliorate
Some
com
follow.
examples
The quality of life is degraded. The cost of living goes up, particu
larly the cost of rental housing. The supply of available housing quickly
dwindles. The availability and quality of services suffer; recreation facili
ties
are
crowded, telephone
1987, we forecast a
Garfield, Mesa, and Rio Blanco
Looking
of
degenerates.
service
oil shale
to
development. This is
well-diversified at
this
there is
years unless
development
we
to
be
generally
about
the
three-county
147,000
described,
people
prosperous regional
a collapse of
have
time,
population of
the
if it takes place,
region
without
economy,
next several
The
oil shale
that
requirements.
regional
op.
Impacts
160,000
lation
to this
people
160,000
people
people.
This
is
create
would
the
of
oil
This development
and
covers popu
operation, basic
The
service employment.
additional
to 12 percent,
forecasted
121
construction
shale
( 10
Oil Shale
region.
local
related
growth rate
doubling
the
plus
employment,
three-county
directly by
supported
of
(5 percent)
rate
may be
which
conservative
without oil
shale,
and a
tripling of the present rate (3 percent); the growth rate in western Gar
field County, or in Rio Blanco County, might go to 25 or 30 percent.
We
20,000
about
require
would
estimate
another
10,000 to 11,000
housing
were available at
If the
housing
additional
units
of
the time it
shale
during
related
housing
permanent
homes
mobile
oil
and
this period,
( one
was needed
population
if
type
probably
permanent
of
lead-time
problem).
would
involve the
up to 5,000 homes
construction of
during
per year
some
years of
This
new population
resulting from
over
of
demand for
massive
retail
and
services.
with
tion would
quiring
include
again
furnishing
200
new
an
there
the
rooms
staffing these
influx
sudden
an additional
Here
be
this
1,500
in
additional
(and
be lead-time
facilities
at
school
related school
problems.
One
would grow
new popula
children,
re
facilities).
problem would
Another involves
some years).
facilities to
too
44,000
schoolrooms
would
a year
of people.
estimated
school
school
facilities
public
building
and
emplo
accommodate
construction
Crowding
are
and
increased traffic
relative
frustrating.
Health services, particularly,
build
new
facilities;
in
a rural
1;
in
suffer
in
boom;
it is difficult to rapidly
area, it is particularly
if the facilities
were
in
difficult to
place on
time. In Sweet
physicians
The
attract
is 3,300 to
caseload
in the
county mental health clinic increased tenfold while the population went
from 18,000 to 30,000 in 3 years. This increase generated a different type
122
of
Quarterly
i.e.,
caseload,
holism,
and
In
of the
higher incidence
much
of
Mines
of
alco
down-and-outs.
Gillette, Wyoming,
dropout rates,
mobile home
lacking
Colorado School
as
jobs
parks
boom steeply
an earlier
increased
and wages
sprung up;
Massive,
steeply.
colonies
sometimes
high
escalated
facilities
school
unplanned
trailers
of
proliferated.
to
tunity
and no encouragement
Social
Crime
other.
of
typical
lacking
small rural
and
towns in Colorado
mental
stress
health
level for
a community.
distress feed
and
Rock Springs
recrea
insufficient;
increased, lead
are
is
newcomers
on each
country
oil shale
opportunities
educational/cultural
to increased
ing
of
the
in
participate
In Gillette
increase.
facilities
tional
newcomers
caseloads.
personnel
and
high
cost
in cost,
million escalation
inevitable in
market problems
employee
it resulting from
boom town. This
much of
turnover and
lowered productivity
The boom-inflated
by
at
$1,000 to $1,200
$500 to $700
a month construction
to
increase,
month, may
while
( and
Police
prob
wage
rates
be particularly tempted
jobs.
for
in
bonding )
municipalities
is
( See
following table. )
Population Versus Assessed Valuation
Green River
1970
Rock Springs
tainty
Population
Valuation
Per Capita
4,196
$ 5.1 million
$1,215
7,000
5.6
1970
11,657
$15.7
18,000
16.8
"
million
800
$1,347
"
933
greatest
tied to
Valuation
1973
1973
The
Assessed
threat to
Impacts
it damaged
(by
Colorado,
west
boom
123
Oil Shale
of
bust tied
with a
The bust is
the end.
on at
not
inevitable, but
it
Boom
The
to
challenges
An
two
boon? So
or
dilemmas
strategic
(1)
Should the
(2)
risk of
Should
a substantial part of
ties
These
maintain
Or
with expected
economy be
deliberately
the
a specialized oil
maintained as a
di
programming
the
in throwaway boom
homes?
mobile
comes out of
diversity?
area
modated
local
it be
into the
to
policy-making
regional
should
economy, at the
versified
are considerable.
boom
oil shale
Or
growth
by
posed
shale economy?
to
boom
tremendous.
century be developed?
be considered in light of national and
accom
settlements
permanent
should
be
growth
population
next
concerns.
Nationally,
United States
contained
another
energy
Locally,
the
ards should
be
30
or
should
quality
welfare
next
sources
environmental
unique
shared
the
over
50
40
accommodated
in the
Nationally, continentally
be developed. Nationally, areas of
should
(including
years.
be
the
Locally,
preserved.
desired way
be defended. Locally,
maintained.
be
of
life)
of people
in
the
fruits
of
the
booms
should
be
equitably.
Oil
shale
will require
development (and
intensive
mineral
planning.
Oil
shale
will generate
development (and
immense
The implementation
cash
ing
so
that the
of effective growth
beneficiala
mineral
affected regions
management,
be economically
and
and
their citizens
all of us.
based
socially
on
carefully
self-sustain
WESTERN COLORADO:
Robert E. Giltner
It
be
should
apparent at this
development
the
oil shale
boom
To
that
put
The
however Moffat
are about
9,500
be 82,000
persons
consider
in
is growing
on
County
other end of
fueled
by
normal
estimated
growth of
of
the
growth
The
other
will
continue.
healthy,
success,
60,000 to 160,000
the
shale
three-county
City
an oil
persons
workers
a part of
Director of
up
the
mag
Garfield,
Planning
region,
and
The three
Man
counties
to
a population estimated
and
County
is the least
County
in 1972.
as a regional
Carbondale,
the impact
of
is
and
growing
area
Regional
development there
area
by 1988,
same period.
to
live,
will
roughly 14
be
another
years.
not
communities.
now
as a place
in this
but
Colorado
in the three-county
that are
and
numbers
oil shale
Grand Junction
attractiveness of western
persons
of
make
is the
now.
Pitkin
70,000
oil
are
extents.
that
level
consists of
own
shale oil.
lesser
to
Because
only
few
describe
this to be the
estimated
not
the
cite a
will
Rio Blanco
Grand Junction.
its
on
figures
have
area and
Mesa
in 1974.
city
the
this
like to
development
oil shale
grown
would
these
populated
the
Colorado. There
square miles
largest
tains the
at
about
won't.
County
Region 11 for
agement
by
and
center
feelings
the problem.
nitude of
Mesa
Hopefully,
are mixed
western
will
you
in
industry
of an oil shale
those who
at
82,000
persons
could
be 150,000
persons
126
Quarterly
15
after
of the
Colorado School
300,000
industrial
successful
The
recent
Colorado
and
kind
this
Arab
figures
is both exciting
of growth
Wyoming lease
15
persons after
years of
operation.
prospect of
With the
Mines
of
the
sites, it is
be
might
leasing
successful
becoming
The
reached.
frightening.
and
both the
of
and more
more
the
of
citizens
likely
region
only now becoming aware of what might occur under these conditions.
A year ago, an extensive attitudinal survey was undertaken in the
are
region
they
determine how
to
might react
their present
residents viewed
The
to growth.
results
lifestyle
how
and, in part,
interesting,
were
and
predictable.
The majority
of
to
ways
complaints about
overall, there
The
lack
of
shopping facilities
rapid growth.
fears
Some
voiced
the
substantially
magnitude
Some growth, it
if it
was
tive impact
water,
deemed
alter
of
maintained,
existing
housing,
were mild
However,
potential
negative
percent.
highly
successful
of
"desir
of growth
oil
shale
industry.
might
services.
Of
utmost
It became
and schools.
effects
this
This type
growth
feared that
on
of
desirable; however,
from 35 to 90
were
It
of
was
involved the
growth was
of
satisfactory
and entertainment.
lack
the
the population,
the
There is
the people.
communities, there
smaller
for
of
life,
of
the region.
of
greatest
would not
the
some of
most of
tempo
present
friendliness
for
and
was an appreciation
beauty
the
and
In
it.
spend
the general
leisure time,
ample
currently
liked the
area residents
a nega
concern was
the impact on
from
interviews that
obvious
have
be
the
However,
the
choice
in
western
growth"
rapid
growth,
growth are
local
and
largely
explosive
beyond
growth.
the control of
The
circumstances
the people
of
causing
this
units of governments.
the
First,
concerns of
on the
that
let
review
us
what
to
be.
income to
the
growth are
likely
positive side:
be
will no
doubt
bring
additional
This demand
will enlarge
the market
The
New
future
and
industry
different types
and
As the
populations.
127
to
should continue
doubt develop.
will no
addition of a new
economy.
Growth
businesses
for
further
will
jobs
of
be
will
grows, the
region
diversify
available
the
regional
to the present
industry
and a
dustry but
entirely dependent
not
from dependence
Growth
upon a single
bring
will
this
some circles
to the
be
would
healthy
trend away
industry.
be welcome,
might not
it,
upon
While in
area.
New
status quo.
ideas to the
people might
bring
to
seem
them
with
stronger voice
have
could
Oil
legislature. The
state
beneficial impact
on
the
of
human
resources
region.
shale
broadening
focus
to
state
likely
As
growth.
veloped
to
be
example, Colorado
an
for the
use of western
if
addressed
remain
The
provide
them.
beyond
For the
the
These
with
will
now apparent
housing
facilities,
already tight
be in
This
as
they
provided
in
units
desirable
ions
or
great
a
with
timely
demand in any
mean
a new
philosophy
of new people.
and
ex
government
by
to
growth, this
provide
necessary
could
manner,
play
upon
opinions
The
lifestyle that
It is
growth situation.
capable of
continued
depending
Present majority
the influx
to
attempt
housing industry
will
undesirable,
the judgment.
of
impacted
communities
costs
if
local
of
high
ing
they
budgets.
that there is
needs.
capability
smaller
tremendous start-up
Housing
as
likely
facilities.
ed
by
are spotlighted
negative side:
panded services
havoc
Colorado. Other
be further de
in the background.
On the
means
they
the
meeting
housing
views of
the
project
values
changes can
be
consists of
the
be hard
best
and
viewed
person mak
region will
not
put
parts
to
opin
evolve
of the old
128
Quarterly
Yet to be determined
not
First, I
To
the
area
towns
following
For
the total
area of
the three
counties
levels
the expected
land
of growth
in the
moderate oil
of these
frightening
(70,000 persons)
shale development
Much
when
cultural
the
the
land
you
area
is
added
too
urbanized
consider
and
the
These are,
be
next
15 years,
of
the
be
urbanized:
region.
square miles
15
square miles
26
square miles
14
square miles.
miles
the
of
spaces
is
the region
for
not
three-
are
develop
terrain too
rugged
valleys and a
we
square
unavailable
course,
considerably.
Here
40
area
however. Within
excluded.
White River
land
of
present
wide-open
not available
should
to the
The
few
is further
problem
also
is
This
suitable mesas.
some of
a significant
the
compli
best
competing
agri
use
for
be
the
developable land.
Secondly,
cost of
munity there
them
after the
land
what will
met,
this growth?
We have
with
estimated
will
be
that
million.
an
expenditure
capital plant.
and police
required
the necessary
$1
be
region consists of
the available
the
to
figure for
forests.
areas
Colorado
by
cated
of
need
possible
national
narrows
relatively
development
oil shale
figures
county area.
All of that land
of the
to
(231,000 persons)
tion. These
and
growth"
For intensive
ment.
housing
Garfield, Mesa,
of
(131,000 persons)
several
for
amount of additional
For "normal
too
described,
already
area requirements
cities and
will
amount.
accommodate
Any
they
now
of one percent of
insignificant
The
region
it?
accommodate
tenth
order of magnitude
the requirements to
would
three-county
the
occurs on
one
the
on the environment of
Assuming growth
total
impacts
are
Mines
of
resources
and natural
probably
Colorado School
of the
added
to
million
to
provide
persons
of
$3
com
protection,
governmental
If the community
will
buildings,
be increased
by
water
reponsi-
an additional
built, they
are
for
salaries
the
the
for these
supplies
41
about
of
needs
$400,000 to $500,000
to
will amount
same
population
The
1,000 increment in
This money
annually.
new
129
the
service
Growth
capital expenditures.
be
to
will need
necessary to
costs
operating
only the
represent
for
plus
that it
will
annual
population
take to
service
costs
for
go
will
and
people.
To be sure, there will also be revenues from these new area residents.
Those who buy homes or businesses will contribute through ad valorem
taxes. There may be
This
nue.
additional
$430,000 in tax
taxes
sales
1,000
or other
persons
With
revenues.
taxes to
be
can
to
assumed
produce
some manipulation
greater
appears
that operating
This does
from
include
not
an oil shale
Some
dustry
bonuses
show a
It
capital
improvements that
Under
tion.
the next
15
at
the
national
county
in the
jurisdictions
it
will
have
royalties
in
these
be necessary to
growth, this
oil shale
and
area and
three-county
of
oil shale
levels
state
any degree
region.
terns that
land
after
uncertainties
growth with
will
base,
be in taking
this
support
take
will
$210
development,
this
the
care of
new popula
million over
figure
could
million.
And, thirdly,
The
of
or a
taxes.
With intensive
years.
of growth
lucky
normal
conditions of normal
increase to $690
terns
to their
appears
covered with
consideration
industry.
added
be
costs can
about
costs,
what will
be the
likely
area?
development
and
land-use legislation
it difficult to
make
project
population
three-
of
However,
pat
pat
Assuming
the
hub
next
of
wood
15
the region,
in
Grand Junction,
years.
Springs,
second
normal economic
as
and
Meeker,
rate of growth.
and
all at
Rifle,
that growth.
the intersection of
major
routes,
Glen-
will
be
Newcastle
will
share
in the
growth
to a lesser
have
direct in
extent.
With
fluence
on
oil
shale
development,
community
growth.
plant
If there
location
are
will
moderately
130
Quarterly
Colorado School
of the
and
focus
the
from
County. Rifle
feel the
will
lower Piceance
Grand Junction
impact
major
then the
lesser
extent.
to work,
close as possible
as
Garfield
area to eastern
a
major
towns
will
to the
already described
normal growth
If intensive
and on
Under this
the impact
growth
development
oil shale
of
center,
The Rifle
growth.
area
Three
takes
condition, Meeker
new
They
general
physical
of
would
are
patterns
(1) laissez-faire
are
controlled expansion of
would
the
of
feel
more
be important
still
Grand Junction
location
again
will
oil
as
would
be
shale plants.
however.
(little
for the
possible
control
no
existing communities,
of
the three
(2)
growth),
(3) development
or
deter
will
Broadly described,
or
The
region.
governing bodies
take.
possibilities
growth
new
Rangely
and
policies and
of
and
the
place
distribution
change.
of
Creek,
Meeker to
and
amenities
urban
Mines
of
of new
communities.
growth
scattered
would
grow, probably in
Much
of
the
the growth
development
This type
of
forethought
of
to
landowners
requires
might
land.
available
take
place
and
The
Rangely
in
would
too
communities
unincorporated
areas,
routes.
leaving
districts.
distinct possibiltiy. It takes the least amount
a minimum of land-use controls.
There is
seek services
is
of growth
Meeker
would
areas
and
on
even some
ber
Valley between
Secondarily,
experience
of
through
since
special
potentially, the
of urban
largest
development
on
num
their
land.
Administratively,
advantages
and
would
school
which
were
community.
this
give
pattern would
way to long-term
districts tried to
urban
in
be
nature
Fortunately,
provide
but too
these
a nightmare.
grief as
scattered
problems are
to
short-run
county
commissioners
to
developments
services
efficient
The
make
beginning
to
recognizable
be
recognized
of
pattern
would
The
see
the contiguous,
medium-size
controlled
communities
al-
for
to the
for
that
urban sprawl
and
the
serve as
is certainly
pattern
govern
existing
nucleus
preferable
philosophy
or control
growth.
It
come
cause
also
would
to many
would not
be
of
There is
some
able
handle this
to
not
Substantial
problems.
expense.
of
This
greatly
131
Growth
for
Existing
growth
new
be willing
to
or able
effect
these
changes.
Considerable
the community.
between
will
between
cooperation
communities
be necessary to
lifestyle
bring
and
about such
a pattern.
The
New services,
vantages.
in
The
a renewed
of
the
the
A true
If
new
new
the
growth,
less land
take
should
is
the
suggested
be
nation are
these
of
several
raises
by
the very
possible under
communities
absorb some of
scattered urbani
out
sensing
lands.
that might
This
to
opposed
world and
pattern
existing
present size.
help
the
agricultural
numbers of people
absorb all of
of new
when
development
possible
development.
shale
time
ad
existing towns
compact growth of
importance in
A third
will
of agricultural use at a
tude
costly,
long-run
however, has
control,
over or
ernmental
zation.
of
while always
compact communities
boom is
degree
acceptance of a
are
magni
intensive
oil
to be expected to
to
this growth.
It
re
first inhabitant. No
with
the
unit of government
new
In
Colony
spite of
the
the
eventual
difficulties,
at
they
in the
will need
delivery
least
to
be involved in the
of services
one new
to any
town is
of
Garfield
distance
of
Roan Creek
new
being
made
site
townsite.
considered.
preliminary
County
regarding a new
townsite on the mesas south of the existing community of Grand Valley.
This site would conveniently service plant operations in Parachute Creek
presentations
and
is
to the
also within
C-b. Another
would
new
driving
community in the
northern part of
intensive
and
area
federal lease
site
region
point
for
Quarterly
132
The
controlled growth of
of one or
two
for
pattern
population
share
in
new
that
2- to
although
considerable
congress and
ever, the
attuned
the
state
right choice of a
development
existing
distribution
of
communities would
to
planned
western
come on stream
Colorado
at either
legislature.
to
development
to
5-year future.
level,
the
all
be
could
is coming to
growth
Mines
towns
in the
of
communities plus
existing
The
growth.
Substantial
both
This
the region.
in the
Colorado School
new
there
of the
to
the
shown
at
its
own
when
national or state
in the
In the immediate
make
time
decisions
subject
future,
while
by
how
keeping
Are local
beginning
governments
of efforts
money.
course,
to find
Money
One
solutions.
the
of
major problems
required capital
facilities
and
is,
of
money
for them before they become necessary. Appeals have been made
to both the state and federal governments for help in this regard. The
to
plan
question now
is how
soon and
in
the
those
be
first
to
make some
major
which
influx
deliberate
of people
by
to
growth
the
lifestyle
form
will
is sparsely
the
help
arrive.
populated.
into the
challenge
overwhelmed
live.
area
follow. The
some semblance of
to
what
There is time
The
handling
the pattern
for
accommodate
which makes
the
Roland C. Fischer
most
controlled, and,
therefore,
litigated
river
in the
you
Colorado is the
two
subject of
world.
Congressionally
As
ratified
and one
international treaty.
The 1922
River
Lees
at
Nevada)
and
Wyoming).
Ferry, Arizona,
to Mexico.
that the
compacts and
In my
Colorado's
most
(California,
Arizona
and
per year
duces.
compact
the
The
treaty divided up
I
remarks
will
appropriation system.
litigation is
than the
assume
Further,
the Mexican
river pro
understands
Treaty has
recently
increased controversy because the federal administration has in
terpreted it very broadly to include water quality which was not men
caused
tioned
to
at all
Much
of
the
near
will come
in
beneficial
Colorado,
use.
specifically
Colorado.
of
its
if
"energy
rado's
primarily because
you
prefer,
emphasize
shale
and
oil
For
be neatly
background,
the primary
western
Secretary-Engineer,
Springs, Colo.
water,
energy
interest here
oil
as related
shale,
coal
will
crisis or
today is Colo
I
to water.
be
heavy
will
energy
thermal electric
separated.
the
Colorado
The
the nation's
and your
although
actually
of
Colorado
water
River
policy
Water
133
body,
and
the
Conservation
principal
head-
District, Glenwood
Quarterly
134
waters of
lies
within
established
by
for Colorado
same
the
fought
the
since
to
little
which
in the
of origin so
the
it
has
courts
was
would
be
established, it
when
Colo
of
the
Colorado,
and safeguard
entitled
was established at
some water on
there
of
area of
is equitably
appropriated water
to hold
All
over one-fourth of
develop
state
The
corporation
the time is
quasi-municipal
waters
compact.
transversions
in the basins
like
of
all
time. Ever
for
is
which
Mines
(fig. 1).
miles,
of
its boundaries
the 1922
need
Colorado School
originate within
square
The District is
state.
under
of the
has
for
the
anticipated
It looks
now.
mentioned
the
geographic
WYOMING
division
of
SEVERAL SELECTED
RESERVOIRS THAT CAN
SUPPLY OIL SHALE
WATER
Figure
1.Colorado
basins.
Well,
far
as
Upper
and
District.
Ferry
is concerned, approximately 53
as water volume
flow
the gaged
Approximately
be
the
and
450,000
tainly
the
dissolved
high quality
taking
of
solids
concentration
in
entire
at
Lees
waters and
the
has
lot
cost us a
(currently
about
Colorado. Cer
detrimental effect on the
transverted to eastern
are
year),
this
The
state.
the
of
acre-feet per
Colorado River
in the
flow
limit Colorado to
compacts
and
much
But the
scarce
used anywhere
Continental Divide
percent of
the District.
originates within
water
percent of
Lees
at
of
135
Water
and
has
water
Colorado,
western
the
measurable
with
indeed, in
and,
Mead.
The
reduce
some
the
Colorado River
some
example,
Board's
the
parts
in the
main
slope, the
for
claims
east slope
but
water
and
not
will put
it belongs.
approximately 500
Denver! For
of
transversion.
Eagle-Piney
are
certainly
is concerned, Colorado is di
audience
will
where water
west
there
stem
the
use on
proposed
controversial
Colorado
to
water
into three
Colorado
western
controversies
often recite
vided
in
cfs
that are
Well,
on
the
of
conditionally
senior in priority
Shale
per
day
oil
units.
the
energy
will
requirements
have developed in
-they are worth
But
reliable.
we
doubt
be. So I
our office:
just
are
the
not
optimum size.
numbers, but I
quirement
probably
of rock are
comparable quantities
concerned with
will
what
that
will
these
they
anyone
cost
using them
has his
I think everybody
as
you;
a guide until
the
what
numbers we
to
free
just
industry
advice
about as
tells
us
differently.
For
production of each
approximately 8,000
there
will
160,000
be
breakdown is
as
of
per
day
oil,
be totally consumed;
barrel per day industry,
no return
acre-feet
50,000 barrel
flow. So for
water
follows:
will
million
be totally
consumed.
The
percentage
136
Quarterly
40%
60%
of the
Colorado School
of
Mines
64,000
evaporated
and
chemically
mechanically locked in
96,000
160,000
acre-feet
For
each
people-
above
and
estimate,
the
are
neither
thermal
associated
power
require
ments.
The
largest,
and
appropriation
available
of
given
an
recognized
the
a solution.
After
time,
digital
shale
deal
and
lutely
of
determine the
any time
on either
for any
essential
especially
White Rivers.
first
by
efforts
many
at
water
this time
toward
trying
no
give
to find
long
people over a
will
CORSIM II.
amount
of
period
answers
reliable
water
available
river. CORSIM
operation
coal, that
II, or a
involving large
will
similar
capital
require water
Of the 15 participants, 10
or
River,
the
it is
to
kind
point at
the
of effort
not mean
who
it
the White
computer
does
a river
much water
a great
II,
including
tool
oil
is in
water
the
Under Colorado's
one
of
by
south
by
the north
on
White River
the
bounded
are
at
any
tool, is
of
its
given
abso
investments,
directly
oil
shale
Service
Company
of
Colorado).
CORSIM II
David
hoff Quade
,
A
shale
and
great
lease
Douglas
shale ventures
and
was
of
and
Parsons,
Brinker-
New York.
deal
sales
$475,000
venture of
cost
of
They
land
and
four
are:
ON FEDERAL LAND
Colorado federal
oil shale
tract Ca:
Colorado federal
oil shale
are
oil
oil
in the
and
137
Water
ON PRIVATE LAND
announced
50,000 BPOD
Colony Group
Colorado River
plant:
Basin
The
announced
18-company
Bureau
Paraho retorting
Although
some
have heard
direct-flow
federal
quite a
of
Rifle, Colo
Mines Anvil Points facility, testing the
bit
way
near
process:
of
at the old
rado,
Company
plant:
The
Union Oil
water
under
about
the
Colorado
oil shale
tracts Ca
and
be
required
to
ensure
reliable
industrial
As
of now
it
appears
the
provide
storage
will
industry
will need
to
its
surface water
and
associated
own storage
one
room
industry.
This is simply
short of
for the
of
The issue is
true.
establishes
in
for
water
fairly
waters of
priorities
the
not
acre-feet
80,
the Gunnison
Any
River;
contract entered
and
and
its tributaries
paragraph
as
(c)
finally (4)
the
shale
Secretary
provide
of
Interior
for interruptions
the
follows:
the confluence
above
in
which covers
(1) agricultural and domestic uses existing as of June 15, 1937; (2)
losses; (3) future domestic and irrigation requirements in western
rado on
oil
complex
consumptive use of
an
river
Colo
with
industries.
and a shale
when water
is
for any of the first three priorities. The River District believes
that the future domestic and irrigation requirements will be significant.
required
These domestic
the
will
requirements will
as a result of
the
shale oil
their
and
future towns in
water requirements
industry. We have
lated
that
138
Quarterly
Green Mountain
of
that the
water
industry
construction
for
available
industry,
this
Fork River
The Basalt
water.
uses will
In addition, Ruedi is
an
draw
is usually
level below
it left
in the
Ruedi Reservoir is in
even
recreation
many
recreation
out
level
is 1,000
of
Further,
Ruedi
to
be
feet,
used
At this
required
gave
reservoir.
to
point
meet
that there is
is
the
Part
decrees.
senior
funds
although
industry,
of
Ruedi's
it
will
Ruedi
water
much
Ruedi
must
we wish
the
neither
be
to
subject
for
7,000
requirement
District's
long-range
as
acre-
to interruption.
point out
Green Mountain
40,000
low
of maybe as
contract
water will
Reclamation
of
upon as reliable
oil
and
amount of
The Bureau
a replacement requirement
Therefore,
that
is,
replace
imposed,
voir
that
the construction
part of
is
not want
so
shut off.
do
necessarily be
Some
acre-feet.
Reservoir,
nonreimbursable recreation
replacement
The dead
in Ruedi the
pool;
acre-feet.
transversion project
Basin,
similar
without a shale
reservoir.
are
Ruedi Reservoir.
be drawn
present water
102,000
at
on
to be the
considered
personnel and
variation at all
costs of
there
project will
Further,
important
storage pool
want
industry,
water
domestic
Forest Service
to the
contract
Ruedi Reser
acre-foot
area
what extent
they
the industrial
subsidize
in the 102,000
firm
water
short-term
acre-feet of water
any
able to
are not
supply.
uncertainties about
oil
stored
already existing
thereby
and
to point out
wants
users
of storage
the
taking
anticipate
cannot
Mines
of
Further,
water.
finance the
water
Colorado School
of the
nor
sources of
Ruedi Reservoirs
large
opinion
for
a shale oil
can
be looked
amounts of water
for
a shale
industry.
The necessary
structed on
comments
water storage
decrees held
here
are
by
the
industry
and
probably be
the River District.
will
by
decrees, however,
con
My
and the
for
White River
Yellow Jacket
139
Conservancy
heard
District may be
Water
industry
Basin, decrees held for
an oil shale
and
available
a certain
to supply
point storage
supply
In the
by
the
some re
will
be
re
to pay
at
all
least in
comments
part
the 3732
percent allocated
But the
industry
money, be
County
cannot
to Colorado
from
the
federal
land lease
oil
sales.
pay its own way and will probably, with front end
help. For instance, two Garfield County commission
must
asked
that
to
look to the
receipt of
problem
amounts or
in
pay for the front end problems that are fast coming upon the
And they say that industry must supply money to help solve
county.
these problems that are being created by the industry's activities. These
time to
funds
help
are required
They
County to meet the large
on.
facilities actually
oil
impact
between
expenses
generate tax
We
revenues.
to satisfy these
its responsibility to
work
are
sure
requirements and
and
the time
now and
the
the
shale
industry
is willing to
meet
help
solve
state
to
the problem.
for the
willing to trade
peaches vs. a
its
barrel
the
of oil.
own
energy
in
about
Colorado
are not
the
irrigation projects;
agricultural
as
relative value
used must
Colorado is perfectly
decisions,
be
made
the
in
or
we
base
environmental
is to be
our western
We just
decisions
rado's water
not
totally
production of energy.
can
off
decisions
of a
all of
bushel
these
capable of
as
to
of
uses
making
how Colo
Colorado, by Colorado,
Washington, D. C.
and
James J. Hester
The
Colorado, both
historical,
development
oil shale
of
the Piceance
with
federal
impending
a result of the
as
remains
destruction
archaeological and
these
salvage or preservation of
that
agencies
lands in the
manage
region.
The Office
regional
study
spective
land
to their
basic
of the
inventory
and
owners
for
addition,
such
wise
Such
an
inventory
management
inventory
an
be formed
carried
out
mined, studied,
useful
in the
the prior
Therefore,
study
needed
the
oil
The
re
relative
In
development
shale
need
frequently
of remains on
either
for
to
regional
be
a regional
practiced sea
of prior
to provide the
selection of areas
inhabitants
balanced understanding
is
to
prior
information
never provide a
by
of
would provide
sonal migrations.
funded
and
federalin a proportion
private, state, and
respective ownerships.
prerequisite
project
that
recommends
land-use
will
pat
terns.
So
by
far,
party directed
by
of
the
University
of
Colo
in terms
On the basis
that the
of
their
of
the
oil
shale
lands
archaeological and
of studies
of
are
historical
surrounding regions,
as yet
completely
potential.
we
may
be found
basin.
Acting Colorado
State Archaeologist,
anticipate
within
the
142
Quarterly
The
place
to
earliest
peoples
areas
Later,
date
began
region
for
since
the
of
headdresses
figures
the
in
Mines
Their
beans
corn,
and
of pithouses
permanent villages
as
shelters.
often
from
moved
who
occupying rock
5,000 to 6,000 years B.C.
Known
they both
and
above-
They
are perhaps
designs
on
best known
the sandstone
region.
are
Within
find
the
rockshelters,
remains
perishable
cordage,
which
basketry,
they
also
occupied,
headdresses. Use
istic.
gatherers
and
and animals.
we also
as
of
living
lived in the
their art
early
rooms.
masonry
hunters
the year,
in the
peoples
squash and
cliffs
as
Colorado School
were
place throughout
camping
ground
of the
of
Later
peoples shifted
temporary
occupied
campsites on
These later
villages.
back to
peoples
hunting
the ridge
and
gathering economy
tops,
rather
Utes,
than
and
permanent
"wickiups,"
structures, termed
Finally
we
still stand.
have
evidence of
The
horse traps
Our
be destroyed in
estimate of
field party
of about
the
30
remains of
of
Colorado's historical
our search
size of
current
for
heritage,
heritage
laboratory
a summer
staff of
10. The
laboratory
The total
analysis
costs
thus
of
materials
recovered
and
$1/2
research
million.
report
writing.
Harry C.
Carpenter
Harold W. Sohns
and
ABSTRACT
Laboratory
Mines
of
the Laramie
at
ment of
in
research
indicate that
centration
vance rate
does
situ
Energy
retorting
being conducted by
Research Center to
for treating
processes
fairly
is
flux, but
Oils
retorting
and a
higher
produced
pressure
permeability
aboveground
many
an effect on oil
of a
bed
of
yield,
broken
Retorting
this
ad
produced
by
retorting
Total
oil shale
of
in
situ
pour
lower-boiling
percentage of
by
has
have lower
develop
velocity
oxygen
the
Bureau
Results
oil shale.
support
the
during
will oils
system
gas
decreases the
retorting.
INTRODUCTION
Liquid fuels have been
produced
from
oil
shale
in
various parts of
from
of
oil shale
liquid
try.
the
since
petroleum
During
the
relatively high
middle or
in 1859
1920s,
price
of
interest in
the Bureau
of
and
shale oil
several
revived
pilot
Mines (Gavin
of petroleum at
the
petroleum,
by
including
discoveries
large
However,
two
soon ended
of
143
and
because
of the
plants were
built,
Desmond 1930).
decline in
of the
Interior,
144
Quarterly
the price of
petroleum,
to
under
tensive
and
of
was
facility
25
in
and
used
by
oil companies
working
in the Department
shale
is
of organic and
only slightly
pressure. For
1966 )
efforts
limited
were
to
to
of
do
in
produce
Production
from
constituents.
common
The
solvents
processing
place
to
and
program
interest
of
at
ambient
mining
is
organic material
solid and
temperature
be mined,
may have
and
crushing,
organic
material.
requires pyrolysis
the shale must
economic
be
disposing
and
must
provide adequate
a series of
Develop
Colony group
retorting,
situ
in
and
retorting, the
oil
fractured in
hydrocarbons
culminated
leasing
oil shale
of organic
situ
became
products
in
oil
has
research on aboveground
aboveground
of oil
petroleum
be
discrepancy
Garrett Research
industry.
the Interior
inorganic
soluble
increasing demand
fuels. As the
this interest
and
with
highly
of crude oil
production
a plant
temperatures to
the in
experiments on
for
as
demand for
and
government and
the government
ation of
conducted an ex
developed,
the rapidly
pace with
principally
recent weeks
announced plans
fluids
years of operation
retorting
demonstration-scale plant
et al.
domestic
the
kept
not
is conducting field
crushed
Mines
were
Bureau's
the
and
activities
Oil
and
( Matzick
years
domestic supply
increased,
from
methods
conducted,
discontinued
has
of
Synthetic
the
passage of
process
near
liquids has
natural gas
ment
Mining
program.
the past
During
apparent
in
successful
small-scale work.
relatively
tween
commercially
5, 1944. In approximately 11
combustion retort
were
April
research
refining
develop
to
act and
research
activities
from
oil
during
resume efforts
for producing
Mines
of
Colorado School
of the
and
process
elimin
retorting
environmental
be
by
advantages
Beginning
in the early
concentrated on
1960s,
development
of
Bureau
in
situ
of
Mines retorting
retorting
methods.
research was
Batch
retorts
Technology
145
for
search on
experiments
recovery
and
and
the
on
liquids
gases and
horizontally
ating
first
the
The
the
experiment
oil, 190
of
quantity
In the
fractured
barrels,
the
no significant
quantity
achieved
was
shale
Analysis
rates
to
is
evaluation
surface
area
was
produce
liquid
products.
Mines
of
at
and
of
for
several
weeks.
sustain
present a
indicate
system
high
enough
field
third
the
that
reaction
experiment
variables needed
has
temperatures
pyrolyzes
to
part of
the
produce about
66
that
obvious
shale
depth
the particle-size
and
the
research
velopment of an
results of
this
optimum
it
provide
When
oil shale
solid
is heated to
organic
matter
for combustion, it
should
to supply energy
shale.
factors
projects
in
be
for the
combustion of
distribution
If the in
that
of
the
the
possible
to
process and
carbonaceous
bed,
situ operation
the
amount of
is to be
conducted
and
that must
are
situ process.
research.
the
and composition of
in thick seams,
describe
on
bed,
the
and oil.
organic material on
at great
percent
carbonaceous residue
the gas
residue are
to a
remains
by
Currently
situ retorting.
using
for in
organic material.
of
carbonaceous residue
The
the
order
on
conducted
way to
bum
being
the operating
shale and
research
pilot-plant
the
At
ignition
and
laboratory
values of
to
to
available
experiment
However,
fracture
the
of
In this
the
fractured
shale was
sustained
was
while
underway.
The
Bureau
combustion
and
and
been designed
phase
produced.
was
results
of
insufficient
oil
deton
by
terminated
and was
second experiment
pump
oil shale
experiment produced
by detonating
of
by
fractured
to the
well
wells
recovery
injection
the
several
nitroglycerin
a significant
fractures to
through
well.
through
compressed air
formation. In
By
(Burwell, Sterner,
conducted
Carpenter
based
ing
designed
were
be
being
We
considered.
conducted
also
include
In
total
system
this paper we
to support the
summaries
of
de
recent
146
Quarterly
of the
Colorado School
Mines
of
and
150-ton
gas
injection
bed,
used
composition, the
and
rates
of
being
retorts are
the
and
the effects
the
bed have
retorting
distribution
particle-size
of
the
retorting results, in
on
first
heating
rate and
total
hydrogen,
is using
future
and
In this
retorting gas,
gases,
retort
the
including
carbon
free-standing
by
created
chimney
that might
Laboratory
a
large in
situ
into an
bed
a chimney.
process
retorting
the retorting
by
1974)
operation and
overall model of
a small
means,
of oil shale
to any
Experiments
the retorting
Operation
best be
mathematical modeling.
Carpenter
and
tall,
were
(Fausett, George,
phase of
a short
in
encountered
nuclear or nonnuclear
retort was
conducted
be
is to
develop
extended to
One
models
approach
for
each
smaller models
process.
of a
nominal
size, 10
A flow diagram
gas
burner
mounted
of
the 10-ton
through the
retort
retort
is
shown
lid is
used
in figure 2. A
to initiate
natural
combustion
the
shale charge.
products
containing
through a packed
positive
some
water
and
oil
mist
are
passed
successively
and a water-cooled
heat
ex-
Technology
for
147
7-r--ton hoist
k
6
Refractory lining
Figure
148
Quarterly
of the
Colorado School
of
O O
Mines
Z
-o
^2
a-
OH-
-a-
a:
pCM
rO^
il L#3
"H*
-<
6
as
6b
cs
a>
E
Q>
TEflHI
^-H
Ji
I
o
IC
/^v
o
2C
*>
w
L>
or
II
OC
22
ZZZZZ2ZZgZ3g3
Li-
<_>
J
=dm
q>
S
-J
s
o*
Technology
to
changer
is
vented
burner to
tion
it
some of
excess
the
remove most of
can
be
to the
oxidize
the
recycled
The
stack.
The
shale.
retort
earlier
Fischer
has been
recent
with
15
the
and
for
gas stream
that potential
analysis of
inch in size, 60
smaller
the test
Fischer
pollu
No
piece was
of
5.59
flux
oxygen
from
The
points.
For
the
to
better
is
96
varies with
flux
The
the
more
assay
gallons per
70
and
ton.
than 1
percent was
Oil
recoveries
ranged
in these experiments
volume-
Superficial
measure of
recovery
the total
was
low
foot
shale, the
oil
velocity
degree
recovery
Stepwise
the
equation
of
bed.
effects of
multiple regres
curve
fitted to these
flow
superficial gas
for this
in the test
required
for
curves
family
data. The
rate of
family
of curves
curves
The flow
plotted
velocity
a
maximum oil
indi
recovery
conditions
correspond
to
an
scfm/ft2.
of success of
as percent of the
not
1.22
high.
effects of
The
of
volume-percent.
variation
0.60 to 0.70
This is obviously
from
from 8 to 21
for the
based
gas velocities
retort ranged
lean
velocity
in figure 4.
the
were
of about
oil
lean
than 20 inches.
equation
section
oxygen content of
oil
taken to be the
charge.
cross
superficial gas
the
The
assay.
charge with an
inches,
in figure 3.
conception of the
percent of
maximum
oxygen
bed
presented
that the
experiments with
obtain
oxygen content of
of curves
explains
the
correlation of oil
cate
feet
and
larger
oil
than 4
the empty
standard cubic
results
blended
that 27
Using
Fischer
used
determined
ton as
from 12.8 to 16
cross-sectional area of
high
shale
variables studied
The
oil
1968)
were
used
grades of oil
assay.
The operating
obtain a
shale showed
the
percent of
Fischer assay
ton.
Sohns
gallons per
Sohns 1972 )
and
to
and
these studies
than 10 inches.
percent of
80
different
two
process
25 to 30
from
of oil
oil shale
gallons per
to
used
experiments were
25-gallon-per-ton
showed
Size
Yields
( Dockter, Harak,
study
of about
for
in the
(Carpenter, Tihen,
work
assay.
from two
and
to
is
combustible components
on
is
stack
desired,
if
retort
gas stream
control.
The 10-ton
by
to increase
149
entrained material.
displacement blower
a positive
split;
for
the tests
Fischer assay
criterion
of
by
the
oil shale
which
these
Quarterly
150
of the
60
Colorado School
Mines
of
1
O
O
</>
**^\
10
a>
40
u.
*-
"o
>
20
>
o
OR.
UJ
R2=0.87
or
S.E.
_j
1.549 +
I48.3(0.F.)-
F)2
108.6(0.
of est. =2.79
02
0.4
0.6
0.8
OXYGEN
Figure
3. Oil
60
FLUX,
oxygen
versus
recovery
1.0
SCFM/ft2
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lean
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20
Oil recovery
21.673
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QI
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10
Standard
error of estimate
12
SUPERFICIAL GAS
Figure.
4. Oil
recovery
versus
gas
1.94
VELOCITY,
scfm/sq ft
retort
lean
oil
shale
tests.
Technology
tests
is
can
be
evaluated.
recovered as oil
In figure
5,
is
for
The
is the
significant and so
the retorting
flux
advance rate
in the feed
recovered
is
heating
151
shale
that
value.
flux.
At
an oxygen
of
case
s
J
/o
4
J=
0
CS
OJ
/o
LU
O
>
Q
ro
/o
0.2
0.4
0.6
0.8
OXYGEN
Figure 5.-Retorting
advance
rate
FLUX,
versus
lean
oil
1.2
1.0
scfm/sq ft
oxygen
shale.
retort
tests
with
152
Quarterly
A
distribution
and shale
Emphasis
placed
was
recovery from
approximately 42
compared with
charge.
bed
effects of
By
retort.
series,
Mines
of
series of experiments
particle-size
Colorado School
of the
on
gas
percent
flow
for
patterns
a normal mine-run
and pressure
drops
Initial
volumes.
results
drop
some pressure
radi
bed,
there is a
and
level
at the retort wall indicate some air bypasses the bed
by channeling down
the retort wall. Data on oil yield and oil properties are not complete for
axis of
this
the
experiment at
A few
have been
has little
experiments
using
Preliminary
flow
stack gas
effect on
same vertical
this time.
planned.
the
creases
taken at the
results show
the
rate and
heating
advance rate or
retorting
that addition of
maximum
gas
retorting
in
steam
the
stack gas.
the
in table 1.
by
retort
from higher
properties of oil
for
the
entire series of
Comparing
retort and
inch
generally
or greater
the 10-ton
operated on charges
retort
from the
in the higher
Operation
Construction
1971)
is
similar
fractory-lined
with an
of
at the
support
the 150-ton
to that
the
containing
major
of
The
other retorts
than &
oils produced
in API gravity
by
and
retort
(Harak, Dockter,
45 feet high
shale
differences in
lower
in the 10-ton
no shale smaller
percentage of
opening
bottom to
of
The
oils produced
with
difference.
there are
and
pro
blend
grade shale
However,
were
experiments,
by
The
and
Carpenter
retort vessel
is
a re
shale and a
hinged
and
grate at the
the
methods of
Technology
153
for
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154
Quarterly
the two
operation of
The 150-ton
has been
istics
Mines
of
ranging in
size
distribution
large
pieces as
of oil
for this
of charges
4-foot
as
grade
cubes.
shale, ranging in
For
up to
size
charge
of
The operating
Superficial
content of
to 2.85
piece
included in the
was
to
The
including
large
experiments one
10,000 pounds,
used
Colorado School
retort
of the
standard cubic
feet
foot
retorting
of
bed
from 0.83
The
per minute.
from 8 to 21
volume per
cent.
Maximum
oil
volume percent of
retorting
As
in figure
shown
linearly
7, retorting advance
flux. However, optimum
with oxygen
the
0.3
feet
standard cubic
advance rate of
This
4 inches
more rapid
25 to 30
charge
of experiments
hour
of
gal/ton used
series
experiment except
foot
from
probably
in the 150-ton
about
an oxygen
flux
0.15
of about
and
0.5.
oil
shale
to the
series
richer
retort compared
in the 10-ton
series of
bed. A retorting
of
from
to increase
for this
between
was
results
gal/ton
retort.
this
results
rate
series of experiments
on oil yield
ment
per
appears
oil yield
advance
using 15
flux
oxygen
rate
operating conditions
for average particle size20 inches
experi
earlier
as compared
to 6
that
were
shale
bed
somewhat
contained
of
Fischer assay
of
62
smaller.
finer
material.
was realized
volume-percent
Only
for the
the lower
An
oil
and
recovery
upper
of
55
thirds
of
the
volume-percent
using the
smaller average
particle-size charge.
The
same
as
in the 150-ton
essentially the
in the 10-ton retort. The API
retort are
Technology
for
155
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CM
o
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Quarterly
156
5.0
*.
Colorado School
of the
1
A
Test
All
Mines
of
c)
R-ll
tests
other
'
4.0
;J=
Rate
-0.529
+8.86(oxygen
flux)
LU
r
R2 =
=
0.98
3.0
LU
CJ
z
Standard
estimate
error of
0.19
So
<t
>
o
<t
o
z
2.0
os
S
p
cr
o
r
LU
1.0
o9r
0.2
0.3
0.4
0.J>
FLUX,
scfm/sq ft
0.1
OXYGEN
Figure
7.
Retorting
to 1.19 weight-percent,
rate
advance
and
the
versus
oxygen
nitrogen content
0.6
retort.
weight-
percent.
Operation
of a
information
of
these
on
and
an electric
pressure closure at
differential
of
a maximum pressure of
oil
from
of water.
shale
5
to
the
top
To
obtain
under
1,500 psig,
only
exceed
never
pressures
few inches
characteristics
retort
is
pressures
different
a small high-
designed.
The high-pressure
enclosed
total
up to
Operating
inch gauge,
the retorting
system pressures
and
the 150-ton
atmospheric.
above
the bottom
and
the
As
furnace to supply
top
that is
used
shown
in figure
external
to
32 inches
8,
the
heat. It has
long
retort
is
a standard
to the
retort
Technology
for
157
V*
\
F
Figure
8. High-pressure oil
shale retort.
158
and
Quarterly
to
discharge
of the
spent shale at
Colorado School
the
Mines
of
of
the
Liquid
vessel
and
through
and
date,
had
the
potential
for
of
content
oil
to include particles
31.1
gallons
between %
and
per
ton.
4.9
The
% inch.
A flow diagram
together
of
this
retort
is
shown
with excess
and out of
1
High
Gaseous
product
pressure
retort
Inlet
flowmeter
Outlet
flowmeter
Back
pressure
Gas from
shipping cylinders
regulator
"7
Gas
compressor
Packed
column
Phase
separator
Liquid
product
Liquid
product
Figure
9. Flow
diagram
of
high-pressure
retort.
Technology
159
for
products and
gases are
The
heating
effects of
and
rate,
rate, total
to the
and vented
being
gas
has been
system
14 to 136 F
completed.
hour,
per
from
pressures
feet
of products
as
retorting
ranging from
to 1,500 psig, and flow
heating
atmospheric
standard cubic
These
atmosphere.
are
rates
for analysis,
sampled
metered,
remove
rates
foot
per square
bed
per
shows
the
pressure,
oil
of
minute.
Preliminary
analysis
interaction between
increases
yield
decreases
at
increasing
with
torting
have
retort was
this study is
shown
and
36 inches
ing
and
high,
unloading
mounted above
gland on
the
the
between
the
allow
in figure 10.
was
heaters
a
plate and
first
/s
outside of
temperature
46.7
and a
the
rise of
retorting,
schematic of
The
of re
for
finned
convenience
heater
shale
packing
was
was
in the
at
space
drilled, tapped,
liquid
and also
to
bed.
from
cylinder
was mounted
load
during
extending through
thick, close-fitting
gas
in
used
10 inches in diameter
A high-pressure hydraulic
the piston
permeability
the equipment
body,
retort
equally
spaced
ring
hour.
per
in this study
to
functions
a simulated overburden
125 F
crushed
3-inch-
fittings to
the
and
decreases
oil yield
oil properties as
at each end
with
retort
which operated
The
flanged
operations.
thermocouples to
The
during
oil shale
top flange. A
flow rates,
heating rates
been determined.
and operated.
higher
broken
designed
constant
Simulated-Overburden Retort
of a
To determine the
constant
Variations in
not yet
Operation
of a column of
At
heating rates.
the
rate at
experiments
At
complex.
increase in flow
pressure.
variables
be
to
variables
with an
lower
the
of
determined
three grades-20.6,
was of
by
Fischer
and screened
to
assay.
remove
The
fines
31.4,
and
shale was
of
less than
inch.
To
conduct a run
gen was
the
the
filled
retort was
desired
sealed,
a constant
of nitro
flow
160
Quarterly
6-in
of the
Colorado School
of
Mines
wide-flange
supporting
structure
Recording
barometer
Water
Pressure
manometer
controller
Mercury filled
Gas heater
100-in.
manometer
Programmable
temperature
controllers
for ring
heaters
N2
Oil
inlet
reservoir
Drain
Figure
cylinder.
After the
system
had
come
the
bed,
further
compression of
to
the run.
start
the
Gas
pressure
difference between
Each
shale
differential
was
few
the
apparent
millidarcys or until
injection
three grades
the shale
of
the
response of
for
to the
used
bed
to
by
no
turned
on
calculating
pressure.
of
which would
have
the oil
affected gas
shale
density,
the
the
oil
at
data collected,
plotted for the
describe
is
No
of oil
by
permeability
were
determined
bed dropped to
to equilibrium, as indicated
bed to
gas
perme
injection.
from injection
viscosity,
point
and volume.
Technology
The
wellhead on a
The
for
161
the type of
data that
be
could
measured at
changes
from
about room
lated
shale
at
heated
was
different
simu
would
pressure, the
are
be
expected when
height
the
of
The
effects of
of
heating
a packed
bed decreases
as
height influences
heating
under pressure
At lower tem
for the
shown.
rich shale.
breakpoint
bed
occurs at
pressure
for
an extended period of
time
to
instance,
improve, probably
1,000
5;:=3^^
100
O00 psi
^'^-rr.
'
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s^
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?-
\x-900p$i
Ul
UJ
-
10
1 '
100
200
300
400
500
600
700
800
900
TEMPERATURE, F
Figure
11
Permeability
change with
temperature
for 20.6
Quarterly
162
1,000
of the
Colorado School
Mines
of
rr
100
10
.01
300
200
100
800
700
600
500
400
TEMPERATURE, F
12.
Figure
Figure 14 is
figure 15
by
the
the
deposition, but
The
in this
case
previously
the pyrolysis of
temperature
for
The
effects of
retorting
has been
under pressure
on rich oil
blackened
compressed
into
by
carbon
a solid mass.
published
kerogen into
shale
particles are
of a
Development
Using
lean
deposition
change with
a photograph of a
we show
blackened
Permeability
data (Hubbard
oil and
gas,
and
bitumen,
Robinson
1950)
on
Technology
Mil 1 1
i" III 1 1
for
163
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ci
164
Quarterly
of the
Figure
Figure
Colorado School
of
Mines
600
psi.
Technology
Figure 16.-46.7
This
model
first-order
is based
on a
reactions and
summarized
165
for
fit to the
thermal
three
600
data
experimental
decomposition
system
second-order reactions.
psi.
was
devised.
consisting of two
The reactions are
in table 2.
Table
2 Thermal
decomposition of kerogen
Kerogen
->
Bitumen
Bitumen
->
Oil
Kerogen + bitumen
->
Bitumen + bitumen
Kerogen + bitumen
->
Oil
Kerogen + bitumen
*5
and
and
> Carbon
gas
gas
+ bitumen
residue
+ bitumen
Quarterly
166
The
to the
Colorado School
of the
temperature
upon
according
relation
In k
where
T is the
Using
least
b/T,
absolute
the
squares procedure on
table
dependent
Mines
of
data,
experimental
reaction rate
in
3.
Table
3 Values
of
of kerogen
Specific
Temperature
k4i/
kcl/
5'
0.064
0.490
0.211
0.198
0.004
0.175
1.400
0.400
0.390
0.008
0.389
0.820
0.880
425
698
0.003
450
723
475
748
In general, k^
for a
constant
have
will
--v.
term
is
for
and
as
For
term.
reaction
are
all
this
fraction,
k5,
the
represents
second-order
expressed
k3, k4,
concentration
generally
because the concentration term
concentration
500
For
reaction.
include
(time"1) only if ki
units
first-order
will
units
for the
(min"-1-)
constants
k3l/
T7
rate
ki
the
units
Data
modified
to
account
for
production of
carbon residue
-
\Kerogen
"
'
Oil
and gas
'
^\Bitumen
^s^
Carbon
residue on shale
-
*^
16
32
TIME,
Figure
__i
24
40
48
min
by
model at
425 C.
the
work,
unity.
rate
i
56
Technology
Concentration
in table
stants
by
suggested
3,
Allred
support
curves generated
in figure 17.
are shown
(1966),
to Allred's
is
shown
conjecture
The
for
upon
the amount
the rate
con
modified as
in figure 18.
This
character of
that the
167
data,
original
comparison
similarity in the
lends
for
decomposition
bitumen present.
rate
of
of
of
SUMMARY
Assuming
created
in
The
gas
an oil shale
yield of
liquid
Depending
injection
1,0
in
area
retorting to proceed,
situ
distribution
upon size
Retorting
optimize yield.
with oxygen
gas pressure
^N.
is influenced
product
flux, but
In
creasing
allow
surface
by
a number of
to
wide ranges
linearly
bed to
and
have been
laboratory
research
factors.
'
'
'
inert retorting
an
does
increase
fairly
almost
not occur at
atmosphere
(nitrogen),
the
in
oil yield.
Data
grade, retorting
adjusted over
advance rates
decreases
be
interacting
modified
to
II
account
for
production of
carbon residue
.8
CO
UJ
o
\Kerogen
=3
Oi 1
and
gas
-
.6
CO
u.
o
CO
2
?-
or
-*
r-
Z
CJ
NJIitumen
z
o
CJ
N.
Carbon
on
residue
shale
.2
rf^T
Xi
32
TIME,
24
16
of
40
48
56
min
Hubbard
and
Robinson
( 1950)
at
425C.
168
Quarterly
The quality
variables
quality
of oil
from many
150-ton
by
produced
liquid
in these
used
of
of the
in
situ
The
are
aboveground retorts
Based
retorting
oil
of
by
Mines
in operating
differences in the
changes
obvious
from
of oil
on
and
produced
overburden pressures
in
in
most
the products
High
not affected
There
studies.
retorts.
than
is
product
distillate fractions
Colorado School
tall
vertical
aboveground
equipment.
be
the same.
will
about
chimney
ever,
retorting continues,
some
small
occur.
ACKNOWLEDGMENTS
The
tive
agreement
Interior,
between
the
and
this
the
University
report
Bureau
of
is based
of
was
done
under a coopera
the
of
Wyoming.
REFERENCES
Allred,
V.
55-60.
Burwell, E. L.,
T.
Chem. Eng.
Prog.,
situ retorting:
paction of
16
oil
v.
62,
no.
recovery
8,
p.
by
in
Jour. Pet.
broken
oil shale
during
retorting:
p.
Campbell, G. G., Scott, W. G., and Miller, J. S., 1970, Evaluation of oil-shale fractur
ing tests near Rock Springs, Wyo.: U.S. Bur. Mines Rept. Inv. 7397, 21 p.
Carpenter, H. C, 1972, Engineering aspects of processing oil shale by in situ retorting:
Presented, 71st Natl. Mtg., Am. Inst. Chem. Engineers, Dallas, Tex., Feb.
Carpenter, H. C, Tihen, S. S., and Sohns, H. W., 1968, Retorting ungraded oil shale
as related to in situ processing:
Preprints, Div. Petroleum, Am. Chem. Soc, v.
Apr.
p.
no.
F50-F57,
13,
2,
Dockter, Leroy, Harak, A. E., and Sohns, H. W., 1972, Retorting random-sized lean
in
batch-type
retort
an
150-ton
and
the
Technology
Hubbard,
A.
B.,
for
and
169
Colo
Matzick, Arthur, Dannenberg, R. O., Ruark, J. R., Phillips, J. E., Lankford, J. D.,
and Guthrie, B., 1966, Development of the Bureau of Mines gas-combustion oil
shale
retorting
process:
p.
INTRODUCTION
Development Operation is
Colony
ing
four
of
active members:
lantic Richfield
Company (A.R.Co.),
have
joint
and
Ashland
Shell,
Oil, Inc.,
the oil
operator of
shale
pay 25
each
and
Shell Oil
percent of
the
precon
to join in construction
of
of
expressed a willingness
a plant.
Colony s
western
some
200
the
Basin
miles west of
Colorado. This
western
of
semiworks plant
world's
is
on private
Parachute
Denver in
Creek,
area encompasses
largest known
site of
reserves of oil
80 billion barrels
formation,
site
Colorado's Piceance
shale.
of shale
recoverable
oil,
by
modern methods.
In
like"
to
a recent press
begin
release, the
mits
to
informed that
Colony "would
public was
used
to obtain
the
about
35
governmental
fall
of
in the fall
1974
must
regulatory agency
of
be
per
The
ing facilities,
revegetating.
four basic
areas:
mining,
crush
hourly personnel.
like to begin by describing,
salaried and
I'd
Mining Engineer,
Atlantic Richfield
in
general
terms, the
171
operation of a
172
Quarterly
Figure
1. The
of the
Colony
Colorado School
Development
operations
of
Mines
mining the
ventional
Fork
of
facility.
shale
in
shale
operation
involves
This is a con
Colony's
mining
mining adit will be on the Middle
Parachute Creek Canyon at an elevation of about 7,100 feet
(fig. 2).
scaling
oil
173
system.
The mining
and roof
cycle of
bolting
66,000 tons
and
hauling,
f&a'M
m:;.it'**y
%
A^
LI
;tfk>i4
-6
******
^rtjrtrrf
^tjetrrf
>,
I protective
MIDDLE
benches
FORK
Figure
OP
2 mine
aoits (61
PARACHUTE CREEK
3 primary
8 MINE
crusher
BENCH
change house
ROAD
Fork Canyon.
parking
6 Culvert
174
Quarterly
day.
This
production
rate
in detail
The
the
after
in the
feet
the
To
using
oil shale
complete.
no
be
plant will
in
and ranges
by
or slope and
being fine
be fed to the
to the mining
covered conveyor
on
the
plateau
from 7,400
elevation
crushed
retort
for
to
for
added.
The
After 20
years of
depleted. Processed
this 4,500 acres.
pyrolysis.
operation,
4,500
genation unit
that
to
be
can
liquefied
petroleum
upgraded
to
An
in the
tract
after
of oil shale
being
demonstrate
routed
the
the
through an on-site
extremely high-grade
sulfur-free
Progress
realistic.
ward evaluation
in
to
designing
Colony's
indication
of
1972
and
data
the
hydro
sulfur and
fuel
can
oil or
product
Date
engineering test
commercialization
Colony
collected
and
efforts
during
of
programs were
oil
shale
was
a commercial plant.
objective
the
of
of
processing
produce an
in the fall
area.
feasibility
completed
acres
processed
gas.
be
will
800
native wildlife of
The
pro
hydrogen to the
adds
cooled when
to sustaining the
shale.
product,
nitrogen,
acre
have been
recovered
is
will
The
spent shale
(fig. 4).
Colony has
is then
shale will
It
The
another run.
material
and
larger
no
deemed
or
fed into
transfer to complete
be
is
under
marbles are
of
beds
will return
to
largest
the
mine
prepare
what
H20 is
incline
above sea
an
Mines
of
crushed
The processing
be
then
world.
overview sketch
transported through
size and
Colony's
make
will
Colorado School
of the
is to
degree
develop
of seriousness about
As
an
at
175
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Q
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it
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C
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7
II
u
X
Quarterly
176
of the
Colorado School
of
Mines
13
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UJ
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rr
u
/
ui
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CD
UJ
u
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ct
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o
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w
g
o
l-l
fe
oo
ii
177
OA3ANOO 31VHS
Q3SS3DOad
bfi
o
U
ft
rt
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8
IO
13nd
ox SVD
p
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0.
178
Quarterly
present
ning,
is spending
of the
dollars
over a million
detailed engineering,
in proceeding
aspects
Colorado School
project
have been
Management
obtain permits
for
pipeline
covers a
right-of-way
This
Parachute Creek to
on upper
Environmental
the processing
an
existing
and
application
from the
route
Land
of
facilities
permit
pipeline
thoroughly
plant site
for
other
many
to the Bureau
submitted
permit.
the
and
work,
plan
engineering
this magnitude.
of
Impact Analyses
(EIA)
(BLM) to
a month on
environmental
with
Mines
of
pipeline
proposed
Lisbon,
at
Utah.
COMMERCIAL MINING
tary deposits
associated
large,
that
with
are
flat
lying
employing the
equipment
is
comparison
may be
similar
Access to the
be
to that
or
room-and-pillar
diesel
mined with
used
in large
mining
of sedimen
An
advantage
is that
system
The
equipment.
open-pit
commercial
mines,
mobile
although
this
an oversimplification.
mine will
of
be from
bench
a portal
Parachute Creek
the level
at
constructed
the
of
in the
Mahogany
Zone outcrop (fig. 1). The bench will be about 250 by 750 ft of flat
ground or about 4.5 acres plus an additional 1.5 acres of sloping fill.
Limited parking, changehouse,
service
equipment
crusher
dump
crusher will
be
stations,
point will
on
the
be
canyon
mine
mine
on
and
water
electrical
the
portal
substation,
bench
portal
and
surface.
bench
primary
The primary
and surrounded
for
into the
on each side of
be
men and
shale,
mine
widened
to 50
the canyon.
ft inside
will
These
the mine.
be through
will
30
openings or main
The
routes
Approximately
six
be
by
30 ft
haulage-
for
removal of mined
ten 50
by
30 ft
at various sites
venti
along the
The 60-ft thick, rich oil shale horizons will be mined with two
benches or stages (fig. 6). Of the 20-year reserves at present held in the
privately
about 35
owned
gallons
179
bo
.3
CJ
C
cu
ft
i
o
o
I
CD
180
Quarterly
Colorado School
of the
Mines
of
The
bench
upper
be
will
30 feet
and about
deep
bench, wedge-cut
nonelectric blasting cap, and
Each
upper
The broken
loaders
the
next
blast,
but did
bolting
&-inch diameter
of
the
will
mine
mine
the
bench
be
be
of
roof.
bolt
whereas all
holes,
with straight
dynamite
and
size range.
yard,
front-end
The trucks
will
hydraulic backhoe
rig.
that
by
was shattered
capable of
scaling
opening.
cycle.
mining
The
roof control.
Steel
roof
Mahogany
bolts
marker,
of
a
feet
This layer is more difficult to drill through for
bolts. A rotary percussion drill was used for drilling
of
roof
for
used
cubic
remove rock
the
a part of
tuffaceous
installation
the
upper
boom jumbo.
ANFO.
involves
scaling
fall to the
than 60
not more
twin
Upper
bench.
cycle
face to
by
10 to 15
by
portal
mechanical
ribs and
will
to a
not
the
high,
primed with
charged with
the mining
of
the
rock on
Roof
then
crusher on
step
converted
the
scales
be
round will
onto a
The
30 feet
of
be drilled
will
be loaded
will
rock
mined
dimensions
feet wide,
a
bench
the
oil
other
marlstone, is about 5
or
shale
in the
drilling
mine was
accomplished
rotary drills.
same
lower bench
inal 30-foot
will
feet high
and
the
mined after
be employed,
will
be drilled
deep holes
Hence,
tern.
cycle
mining
be
will
with
with a standard
be drilled in
will
bench. Essentially
few alterations. The
upper
widely
used
quarry
nom
round pat
the
"downholes"
pneumatic
task
loading
will
which
of
is
these
A 10
bench
percent
access and
will
operations
necessitated
holes
is
by
the horizontal
bench
are sometimes
used
grade, 300-foot
upper
long
ramp
will
be
equipment as
and
80-ton trucks.
constructed
operation.
the
to
provide
rig.
will
half
181
The
is
be
expected to
minimal.
is bolted
ROCK MECHANICS
The two-bench
described
design
the
studies
in
of pillars
tory tests,
room-and-pillar
was
analytical
and
two-stage
or
Colony
pilot mine.
Experimental
a competent
to obtain
failure, loading
mode of
just
system
to obtain
conducted
were
mining
conditions,
stress
distributions,
and strength
Subsidence
The
will
room-and-pillar
involve the
extraction of
operations planned
mining
large tonnages
of ore
commercial
if
necessary.
is little information
ties
(i.e.,
creep)
rock progresses
mine
expansion,
available on
to
phases of
oil
to failure
shale,
creep to
under
available on
failure in
is
the
of
a given
during
continuously
in the
to
deformation
process
smaller magnitude
rock
of
deformation
relative stress
the
and mine
the mine
and
me
a slow
a stress
All
which causes
of
gathered
the time-dependent
Creep
regard
dimensions,
stability
be
will
pillar
of oil shale.
is little information
spans,
structural
Stress data
operations.
throughout the
mine plan
roof
orientation
analyzed
to determine the
and
to creep,
proper
whereby
than the
and
values, particularly
progress
finite time.
through the
Laboratory
there
with
various
tests
of oil
samples
for jointing.
mine at
Anvil
Information
from
Points, Colorado,
that pillars
Mines
have been
experimental
able
to
stand
182
for
Quarterly
approximately 20
a period of
The
Colorado School
of the
years
Mines
of
major
without
failure
problems.
effect of
commercial
design is
conservative.
As
design
be
commercial mine
the
will
resource as practical.
increase the
will
more
data
in
altered
to
an effort
An increase in the
gained, the
recover as much of
extraction
of
ratio,
course,
Roof Falls
Roof falls
be
can
expected
to
lying formations,
improper
bances,
and stress
concentrations.
studied
by Colony
tion
the
on
failures in the
type mine,
in
failure,
strength,
of
the
experienced
in the
occur
rected
possible
by
this information
has
confident
Based
that
potential roof
instrumentation.
The
falls
can
Monitoring
hazards to
potential
be
activities can
with
pillars
to
having
The
design
roof
likely
be di
cannot
falls do
be
develop
not
to substantially
used
mine would
35
the
final
reduce
commercial mine
Approximately 60
the
West property,
property is about 20
extracted
mine personnel.
be extracted,
support
proto
mines,
pillar
the
be
stress
into the
gone
Because
place shale
certain
on studies of
to the
abruptly,
in
has been
prototype mine
over
distur
seismic
operation,
years.
commercial mine.
is reasonably
and
due to incompetent
have been
ed.
of
mines
Colony
was
All
prototype mine.
Colony
The
blast damage
and
design
structural
design
mine
for approximately 9
mode of
concentrations,
in
occur
remainder
percent of
being
A 60-ft-thick
left in
the
will
in-
place as
section of oil
ton,
de
be
shale,
extract
or about
There
were
are
intensely
years.
three reasonably
studied
at
the
pilot
been described.
common
The large
studied.
tions
presented somewhat
The third
will
be
handled,
design
unique
in
commercial
dust
fumes that
Very little data existed
United States had never
the
was that of
study
The
(1)
Which
on
and
samples
following
the
eight questions:
respirable, does
and
through
each
seg
federal health
and
(3)
based
(2)
mine,
problems.
on oil shale
their
extensively
as well as concentra
faces in
the working
at
area of extensive
generated
diesel horsepower
of
large
ventilation of such a
183
What techniques
and
dust
safety
in
concentrations
excess of state
standards?
are practical
for reducing
dust
excessive
con
centrations?
(4)
(5)
How
total
much
dust
emission would
be
(This
total
will affect
generated
by
a mine of
commercial size?
(6)
What is the
nature
how
they be
and
(7)
What is the
the
blast
required
statistical
analysis
free
were used
during
re-enter
the study.
statistically analyzed.
principles, were used to eliminate or
The final
program also
the
may safely
such as
men
a computer and
The
before
how
and
area?
fumes,
exhaust
blasting fumes,
What is the
were placed
diesel
controlled?
dispersal time is
much
(8)
can
and concentration of
results
dust
were used
to
dust?
Data
Rules, based
retain
on
question
determine the
areas
delved into
other
dust
and
fume
related
questions,
dust.
In closing, I
pleted
before
want
pilot
to
mine
mention
operations
purpose of this
mining program. The
60-ft thick mining horizon could be
were
cut
back
program was
mined
in
last test
to
was
projects com
the
full
determine if
one stage
instead
seam
the
full
of
two
184
Quarterly
stages or
benches
which
equipment,
lower
had
be
aligned
top holes
were
angles and
geologic
is worthy
full
on
seam
The
bolting
rig
a slant
up toward the
that
cage with a
they bottomed
The full
seam
upper
Brunton
roof
were
The
at predetermined
rounds
compass.
employed
to
mine
seam pillar.
method of
of
so
parting.
high full
Mines
of
bench mining
30-foot high face height, was
roof
drilled
distances
roof
around one
This
from the
Colorado School
always operated at a
used
to
at
of the
full
seam
further investigation.
OIL SHALE:
Clifton W. Livingston
INTRODUCTION
Piceance Basin is
valuable not
locked up in tight formations below the oil shale. The Basin may be
divided into a White River drainage portion to the north and a Colorado
River drainage
portion
to the
south.
Eighty-five
percent of
the
oil
shale,
The
ment of
the
nahcolite
following
Although
leasing
recent
is encouraging
and
the
velopment of a
contains
to
industry
underlies a
efficiency,
development
of a
by
to
government
of
effective
30
mile
United States
result
thus
shale oil
has
long-term de
area,
protores, in
problems which
industry
remain unchanged.
development,
can
to
develop
resources
energy
in tight formations
water resources
and contribute
25
sodium-aluminum
Uncoordinated development
habitat.
by
controlling
shale oil
with respect
cessful
lens
land
for development
conditions
United States
developed
of oil shale
need
never
cally
remarks relate
and
places
up to
overlies
is located
grazing,
only in
ranges
criti
and wildlife
waste
and
in
suc
industry.
is
as
true
today
mense region?
will
be
water
as when written:
Its
resources, on
greatest
which
this im
unfolded.
of
will
development
of
pend."
its
de
Quarterly
186
Colorado School
of the
of
Mines
Figure 1
Recognizing limitations
culties
every
imposed
under
effort must
in the interests
be
of
existing legislation
made
the
of
to
reconcile and
nation's
which
and
shale
is based
of
development become
upon
Dyni (1968).
the distribution of
the
It
work of
shows
salt
by
to
overcome
these limitations
future.
and
these
apparent
Donnell
by
( 1971),
reference
Hite
and nahcolite-dawsonite
of
and
for
long-
to figure 1
Dyni
( 1967),
(1)
and
(2)
mineralization,
Oil Shale:
Roadblock
Solution
and
187
Limits
oil shale.
of
serves of natural
the
bottom
the
Yellow Creek
about
(2)
Water
the
of
developed
re
The basin is
saucer-shaped with
elevation of
vicinity.
The requirements
(1)
gas,
base
are:
White River
resources of the
must
be effectively
regional and
industrial
The existing
growth.
from reaching
prevented
for
used
does
be
now prior
to mining.
(3)
The halite
zone
must
area.
Provision
(4)
age and
(5)
must
be
for
made
and use of
the
reclaimed
handling
materials
the problems
handling
of
be
must
a shale oil
industry,
Basin
The
(7)
growth are
to
ore
shale
tailings
must
overcoming
disposal and of
be developed.
near-simultaneous
industry,
development
of
Piceance
and a
of
base
power and
and
processing,
peaking
power must
industrial
and
regional
be
accomplished.
Additional townsites,
ational
thick
and
toward
spent
a sodium-aluminum
supply
be
for
directed
land
industry.
natural gas
available
made
increased if mining,
(8)
and
overburden
Provision
(6)
system
drain
facilities
must
access
roads, schools,
be developed
hospitals,
through joint
and recre
government-
industry planning.
With 85
by
controlled
and
lack
nated
or
by
eral.
of
percent of
the
and with
government,
reserves,
who
is
the
solution
does
The
and
problems are
and
development? The
regulation;
land
government
not one
primarily those
not
of
leading
to be
involve
towards
solved
one
by
coordi
legislation
industry but
engineering, planning,
sev
and co
ordination.
The
between
nature
of
developing
the
problem
the ore
arises
developing
the
The
present approach
to development
of
United States
shale oil
Quarterly
188
industry fails
adequately to
developing
the
Unless
and until
taken to
of a vast area.
is guaranteed, Colorado
shale
greatest
of
the
and a potential
assets,
Furthermore,
the nation
it,
this
for the
western
will
history
this
of
a
of oil
one
industrial
nation will
source
a single
recognized
be denied
greatest stage of
not
water resources
the supremacy of
nation
be denied
will
the
fundamental difference is
correct
and
developing
including
resources,
this
does
recognize
natural
Mines
of
Colorado School
of the
be
its
of
growth
suppressed.
to, if
equal
not
greater
Deidesheimer in 1860
Philip
Nevada,
the
where
be
not
mined
by
on
ly
accepted
practice, but
Jackling faced
copper
porphyry
or
that a
as
then
new
existed
Mining
the ground
square set
so
heavy
Deidesheimer
departure from
that
went
general
and overcame
deposits. In
industry
and
conventional methods.
similar
situation
in
developing
the
deposits few
high-grade ore,
view of
low-grade porphyry
thought that
confronting
Comstock Lode in Virginia City,
the
at
than that
industry
such
in Michigan.
of
ore
is
a radical
departure from
Bradley,
at
ing
only $1.00
Certainly,
to the past.
the
per
ton
feasibility
with gold at
accomplishments
Just
challenge of
tribution toward
as
mining low-grade
$20.67 per ounce.
of
the
of
today's problems in
making the
world a
capable of
triggering
industries,
regional and
and coal
base
mining
industry
are not
of a
a chain reaction
overcomes
affecting the
to the oil
shale oil
con
industry
is
water resources
shale region
to
United States
industrial growth,
adjacent
limited
dedicated
mineral
the
development,
for electrically
generated
power.
Paradoxically,
creasing the supply
rather
of
oil,
coal as a source of
Oil Shale:
oil shale
oil,
base
power
dustry,
and
Roadblock
promotes
mining
for
oil shale
for
regional and
the
use of
processing, for
industrial
Solution
and
189
for electrically
coal
generated
in
a potential sodium-aluminum
growth.
a result of
fense
of
Each
of
the elements
of
the
control of
trajectory,
control of
granulometry,
control of
stability,
blasting
new
technology,
in its application,
limited to the
it improves
proposed
the
upon
including
mining
include
and
which
coal and
method
technology
for
The
yards.
technology
deep
basin mining,
it is
and
is
not
instead
mining.
ing
it
span
possible
to
concepts of
complete a
but successfully
stability
facility
that
was
rock were
successfully
that
have
could
caving
At
blasting
control
excavated
closed
the
canal
to
depend
that
following
evolved,
65 ft
116-ft
Fifteen
mak
unsupported
span.
3 ft
opened
the stability
wide
to
million yards of
block
of a
of rock
several years.
process control
principal variations
at a
fracture
canal.
restore
for
were
thickness
upon the
discussion
mining
of
the
method
includes three
the
of overburden and
method
is limited to
one
variation
in
of pillars
covery
between cells,
unit).
In
mining advance,
mined-out cells
adjacent
at
note
in
except pillars
(the final
the
the
CC,
various stages of
relation
mining
units
parallel
terrace
to the
direction
construction above
2)
cell
at
the row
of
of
the
cells
Quarterly
190
of the
Colorado School
TERRACE
HIGH
INTERMEDIATE
PLANT
Mines
of
TERRACE
TEJWACE
-"-
\Vi
mm 1'ou.c
etvi.
L.
unn
fe
u*
CC
SECTION
PILLARS
two
cat
MHCt)
COVERED 8t
ARtA
RGS
4,5, AM) S
/
^
OIRECTION
OF
CELL
MliN6
ACMWCE
/N
13
+
CHk
on i. atm
r-~T
--
gM[
c'
--r
i_
_____j
-
MMH.
rum*
JMX
PILLAR RECOVERY
UBJL una*
IMT
TYPICAL
UNff-
PROCESS
unit-
MHUNO
STORAGE LAYOUT
AND PUMPED
MINING
BREAKAGE
BARODYNAMICS. INC.
COLORADO
GRAND JUNCTION.
-CELL
CONTROL
(RATENTS
MINING METHOD
PENDING)
Figure 2
view
figure 3. Construction
flow
terrace
of
processing plant
upward into terrace
elevation.
into
The
and
mined-out cells.
of
farther
to
used
construct
In figure
how
5,
how the
surface
the overburden
looks
downward
dikes surrounding
dikes
after all
to the
la
steps
of
com
the
results are ac
and
to the interior
mining is
are visible.
us return
complished and
access
we show
the tops
Only
Now let
for
storage
ponds.
In figure 4
plete.
is
the
to ore
of
remainder
After retorting,
Part
ponds.
for disposal
ponds
is illustrated. Broken
of materials
the terrace
looking
lb,
we show
overburden.
Figure
6, step 2
it is
available
of
the
is developed
in figure
7,
an
preparation
Removal
which
is
step 3.
for
illustration
area,
of
trajectory
leaving build-up
control
muck on
blasting
top
of
of muck
the bench
overburden
underground
from the
area of a
using tunnel
boring
shown
Oil Shale:
Roadblock
and
Solution
191
CO
Quarterly
192
of the
Colorado School
of
Mines
193
Solution
and
OVERBUROEN
FACE
OVERBUROEN
^r?
v.
>
PREPARATION
OREBOOY
FACE
JttliTi,
OREBODY
AND OVERBURDEN
STEP
FACE
PREPARATION
la
OVERBURDEN
FACE
PREPARATION
OREBOOY
FACE
V-trajECTORY
<Xv-~
ENTREE SYSTEM
CONTROL
PREPARATION
PROOUCT
PREPARATION
FACE
SLOT
CONTROL
ENTREE
ENTREE
STEP
SYSTEM
PREPARATION
AREA
lb
Figure 5
cess
A typical mining cell adjacent to the face preparation area and pro
plant pillar is shown in figure 8. Dimensions of the cell are determined
both
by
400 feet
mile
the thickness of
thick
intervals
Access to
covered
400 feet
mining
of ramps or
by
overburden and
from
cell either
overburden,
to the
face
underground
predetermined vertical
of
thickness of ore.
intervals
by
oil shale
one-
multiple entrees
within
For
the pillars.
downward
by
way
and cross-entrees
at
194
Quarterly
of the
Colorado School
of
Mines
BUILD-UP
MUCK
OVERBURDEN
CONTROL.^TRAJECTORY
CROSS-
and
ENTREES
EXPLOSION
OREBOOY
CHAMBERS
MUCK
TRAJECTORY
STEP
TRAJECTORY
FACE
AND
CONTROL
ROW
PREPARATION
BUILD-UP
BLASTING
TO
AREA,
MUCK
REMOVAL
Figure 6
BREAKAGE
EMBANKMENT
BLAST
ACCESS
8ENCH
-EMBANKMENT
LIMIT
MUCK
AREA
SLOT
SYSTEM
ADVANCE
.^rz.
STEP
CELL
DEVELOPMENT
AND
ROW
FOR
EMBANKMENT
Figure 7
MATERIALS
BLASTING
TRENCH
>
Oil Shale:
Roadblock
and
Solution
195
SECTION
LONGITUDINAL
Figure 8
The
from the
stability
blasting
10,
step
by trajectory
oil shale
from
Ramp
zone, is
to
crush
shown
the
and
4,
in
control
first row
dike
horizontal
minimize oversize
damage is
a zone adjacent
we
successive
control
In figure
ping
blasting
product control
into the
mining downward in
cell
autogenous
slices, using
access
of
sequence
illustrate the
to the
prevented
by
resumption of overburden
blasting following
using
pillars.
excavation
and
strip
removal
of
of cells.
construction
11, step 5.
Terrace
to
be
ponds are
constructed at
the
formed to
top
of ore
body
elevation
from
between
a retort plant
adjacent
dikes
(fig. 12).
In figure
of
cells,
we
the terrace
13, longitudinal
illustrate
ponds
cross section
a subsequent
EE
parallel
to the
long
axis
have been
constructed
196
Quarterly
of the
Colorado School
of
Mines
05
W
X
D
O
Oil Shale:
Roadblock
and
Solution
197
w
as
P
O
198
Quarterly
of the
Colorado School
of
Mines
.8
/<
0UJ
a
as
D
O
3 5
i :
GO
uj
I-
x
U.
<
o
UJ
cc
uj
Oil Shale:
Roadblock
and
Solution
199
Ol
LU
CC
CO
to
LU
cr
co
CO
CO
CO
Ul
CO
CO
1
LU
o
(j
<
<
o
o
<
Ul
o
CJ
<
200
Quarterly
of the
Colorado School
of
Mines
CO
w
OS
o
>-t
fe
Oil Shale:
between
the
is
The final
shown
201
Solution
and
Drainage
terrace ponds.
adjacent
spent shale
Roadblock
and
of water
recovery
from
also shown.
result
of
mining, overburden
and spent
disposal is
shale
continuing land
use.
Although
does
space
sources
and pumped
mining
layout,
the
water
is
the
in
lower
pool
the
by
storage
during
overburden-filled
for
description
complete
hydropower development
manner
( fig.
15 ) in
turbines to
mining
cells
made
solar evaporation
high
for
release
a part
during
in terrace ponds,
dams
conven
periods of
storage
and
the
flow is
for collection,
of
re
whence
in
an upper pool as
stream
water
"lower pool";
hydropower development.
periods of
as
of
which conventional
to
elevate water
reversible
permit
White River
elevated
tional pumped
storage
we show
constructed on the
not
for
low
stream
of saline
and use
control of surface
drainage.
CONCLUSION
A
roadblock
industry
exists
to long-range
because
the
development
of a
United States
shale oil
simply
cannot
PILLARS
HIGH TERRACE
NTERMEDIATE
PLANT
SPILLWAY
VOIDS
STRUCTURE
STORAGE
INTAKE-
RETORT
PLANT
Figure 14
SITE
ACCESS
TERRACE
TERRACE
ACCESS
ACCESS
202
Quarterly
CONTROL
'LOOO
of the
Colorado School
of
Mines
'"OCL
SECTION
WATER
RESOURCES
AA
CELL
DEVELOPMENT
Figure 15
The
solution
of mine
of
these
layout
de
and mine
resources
is
essential
of oil shale.
to development
by
oil shale of
the 16,000
the
of
Colorado, Utah, and Wyoming requires the joint efforts of industry, local,
These
state (Colorado, Utah, and Wyoming), and federal government.
efforts must
If
Upper
be effectively
moisture
and
falling
upon
the
region
if
stream
is to be
beds
and
drainage basins
made available
if
stream
are not
follows day);
night
plant and
protected
the
and
methods of
the
interdependence of
velopment
first
the
must
natural resource
be
natural
land becomes
than a gravestone
recognized.
at
disposal is to be avoided;
to be destroyed by mining
pollution
spent shale
subsidence
with requirements of
both to
environment;
a monument
of
it,
in
to
his
if
accordance
and
if
as a
vision rather
Oil Shale:
The
events of
the past is to
deny
for energy
living
Roadblock
are we
to
this
in the face
set
time
To follow
of a
and
its
policy that
changing
time again
perpetuates
greatest assets.
continuing
by
203
Solution
nation one of
up to examples
and
by
and
our
In the
growing demand
way of life or by
fession?
REFERENCES
Carrol, R. D., Coffin, D. L., Ege, J. R.,
Bureau
U.S. Geol.
on
J.
Donnell,
and
of
geology
and
White River:
U.S. Geol.
Survey
Bull.
1082-L.
the Piceance
Dyni,
no.
structure
of
the
northern
part
of
Smith,
J.
from Colorado
core
hole
no.
1:
oil shale
U.S. Bur.
of
Green
Lawrence
Mark T.
and
Atwood2
ABSTRACT
Fischer assay
laboratory
to analysis
applied
can
be
of
carried out.
from
alyzing
eters and
commercial
processing
to producing
and
complete
techniques
material
are
balances
estimate oil
When
of oil shale.
large-scale,
its tech
also applied
by
discussed along
to monitoring
application
to
cores,
niques
Equipment
retorting
and
collecting
an
precommercial
retorting
operations.
INTRODUCTION
Colorado
marlstone,
embedded
in
up
of
gen."
Except for
oil shale
does
not yield
hydrocarbons
benzene
soluble
"kero
bitumen,
at normal temperatures.
Oil
be
can
from
obtained
oil shale
by
pyrolysis.
This
results
in de
the
of
carbons remain
The
function
estimate
in the
yield of product
of
the
the
hydrocarbons from
percentage of
percentage
of
kerogen
and
determine its
kerogen in the
kerogen in
Smith
ore
is
almost
entirely a
processed. We can
being
by determining
oil shale
(1971)
chemical
oil shale
was able
composition.
to isolate nearly
Relationships
205
its
per
pure
which
206
Quarterly
developed demonstrate
were
is divided
from
by 0.8052,
view,
kerogen
than the
kerogen is
of
from the
the
specific
tions
be
of
the
( Smith
Fischer assay
mation of
Stanfield
determination
routine
the
of pyrolysis
oil
oil shale.
of
calculation
by
used
applied
for
esti
Cook 1974).
described
(1946)
of
from 100-gram
coal, to the
samples
of
gas,
water, and,
material
oil and
gas, water,
obtained
be
product
must
carbonization
yields
correla
older
applied
previously
and
of
application of
and
modification
(Miknis, Decora,
oil yields
Frost
and
have been
from
and
oil shale
techniques
magnetic resonance
Fischer assay
1969 )
used
Nuclear
thus,
estimation of
can
within
the
amount of recover
content.
gravity
shale
However,
calculated.
interested in the
we are
Mines
of
the percentage
a practical point of
Colorado School
of the
the
simply measuring
than that
oil
yield,
since
there is
significant value
in
Hubbard
(1965)
described the
apparatus
used
by
the Bureau
of
in
for
a short
core
analysis,
of
Haberman,
and sulfur
and
to that
balances
determination
equal
the
weight of
able
to
when applied
these
as a
of product
core
due to
"gas
"TOSCO
procedures
to
establish a material
ferred to
be
assayed
balances
and
stainless
steel,
application to
( Goodfellow,
carbon,
nitrogen
were reported.
When the
Fischer
(1962) for
Product balances
oil, water,
Smith
by
used
Atwood 1968).
and
Our procedures,
yields of
time.
Personnel
both
large
since a
product gas
balance
material
time
is
involve
limitations. We
plus
which,
to this
collec
report
the
This
totaled,
"modified
when
procedure as
collected and
closure.
years.
not
loss"
refer
balance
consistently for 8
analysis, do
analyzed,
we are
second procedure
(TMBA). We have
is
re
used
Fischer Assay
207
Oil Shale
of
analysis of core
ing from
smaller than
any
by
a stream of
diamond
by
saw
diameter,
than 2 inches in
core greater
on
sample,
water, the
processing.
After
is
removal of surface
through
passed
The
65
This is
gallon
65
65
minus
by
using
mesh
The %
The
School
of
diameter
Jones
it
mill and
is then
riffle.
was
and
then
adapted
the wheel,
in bottles in the
and mechanical
in the bottles.
than Vi gallon
at
used
the Colorado
holders
offset
motion.
20 inches in
Sam
such as
the
and
nonrepetitive
less
than &
the entire
return
interruptors,
less
"blending
on a
from that
offset sample
The interruptors
to give a
blended
ball
on
the periphery
of
bearings,
are placed
of
the bottles
positioning
The
to
about
containing
is to
Ray
particle size
a volume of
then split to
approximately 20
which rotates at
the
have 0.024-inch
mill
shale
good procedure
four times
wheel
to
split
the
reduces
in the Raymond
blending
combine
through an 8-inch
passed
giving comminuted
particles (0.0082 inch).
mesh material
lengths,
mill reduces
mesh.
is then
screens used
This
crusher.
round perforations
percent minus
The
four
minus
hammer-type
jaw
sized
mesh material
The
mesh.
diameter,
99
four
minus
mond mill.
minus
laboratory
to approximately
sample size
are
samples
left
on
the
are
is
split on a small
then ready
for
preparation
samples
Jones riffle,
of
and
be
the
stored
separate
in
100-gram
samples
library.
The
65
mesh
that the
requirement
and
Fischer assay
sirability
of
bulk
sample
be
ground
tedious
ever, follows
core or
time-consuming step in
blends. Our
guidelines
suggested
finer grinding
who reported on an
and
sample preparation
by
Taggart (1966).
of samples was
investigation
confirmed
of replicate assays of
by
to
minus
samples
comparison
for
to
technique, how
Further,
Reeves
both
minus
the
de
(1964)
8
mesh
208
Quarterly
and minus
65
with
the
finer
Colorado School
of the
The
Mines
of
data
obtained
procedures
specified
precision of
better.
above.
7-ounce Coors
transfer
used
disks
are placed
in the
between
the periphery
A tarred
obtained
weighed
to the
of
to
head
and
0.001
balance. The
and
intervals in the
prevent
As
the
nearest
beer can,
aluminum
steel retort.
the
following
or other suitable
sample
The
is
to cover the
placed
is
sample
Mettler P-160
loading
into
sample
dusting,
shown
the retort,
Thermocouples
and
in figure
and
is
sample
three
a top-
on
poured
heat
aluminum
sample.
Glass
wool
1,
an aluminum gasket
are placed
is
both in the
is
four
sample and on
sealed retort
is then
placed
in the
tube
retort
are connected
to the
atmosphere.
gram
condenser
cooling
system
is
ensure
an
inert
at
ice
water
temperature
tions given
temperature
curve of
by
of
Table
1. Fischer
conforms
profile
is
to the
given
specifica
in table 1.
( Internal Thennocouple )
Time
(Minutes)
Approximate Temperature
78
113
10
212
15
311
20
419
25
536
30
662
35
761
40
860
45
914
50-70
932
(F)
Fischer Assay
of
209
Oil Shale
HEAD
THERMOCOUPLE
ALUMINUM GASKET
HEAT TRANSFER
ALUMINUM CAN
BASE
DISC
THERMOCOUPLE
RETORT
Figure 1.
Retort
assembly.
DISCS
210
Quarterly
of the
Colorado School
of
Mines
CHAMBER LID
CAL ROD
BASE
HEATER
HEAT
REFLECTOR
-TRANSITE
Figure
2. Retort
heater
HEATER
assembly.
CHAMBER
Fischer Assay
of
211
Oil Shale
GAS
TO BE
VENTED
THERMOCOUPLE
NITROGEN
TO
PURGE
CONDENSER
ICE
WATER
CENTRIFUGE
ICE
Figure
The
couple
rate of
to
3.Product collection
heat input is
a programmer
controlled
and
power
assembly
WATER
basic.
supply (not
TUBE
outside
shown).
thermo
The internal
Dennis Dworak
of
Atlantic Richfield
at
932
the
thermocouple
was used
for this
improved
purpose.*
As indicated,
F.**
(Colony) demonstrated
after
system.
*Private communication.
**J. W. Smith ( 1962) suggests
to be sufficient.
40-minute
soak period.
We have found 20
minutes
212
Quarterly
The
tube are
is then
retort
allowed
The
removed.
Colorado School
of the
to
by
for
pipette
and
The
measurement.
gravity
by
weight of
obtained
subtracting the
weight
liquid
of
rpm.
the
of
and a sample
is
oil
specific
warmed
2,000
minutes at
to
approxi
The
is
oil
volume
removed
is then
retort
The
centrifuge
and
adapter
is stoppered,
centrifuge tube
the
and
cool
Mines
of
opened
weight of product
water, assuming
unit specific
Measurement
product.
the
of
gravity of the oil permits calculations of oil yield in gallons per ton.
The total weights of the liquid products (oil and water) plus spent
shale residue, figured on the basis of 1 ton of dry raw shale feed, are
specific
from 2,000
subtracted
loss."
The
the
comparison of
calculated
difference in these
figure that
is
valuable
attributable
to
oil shale
is
placed
temperature
accord with
cooled
tube,
centrifuge
"tee"
and
ice
the
means of a
mercury
drop
then
profile given
driven
water.
analysis
to
out
Oil
of
the
system and
By
the
sure
in the
gen.
The
for
of
be
or
is
in
tube
a centrifuge
and
are
water
and
usual
gas
bomb is
gas
From the
analysis.
nitrogen, the
and condenser
in the
bomb.
evacuated gas
the
by
the solenoid
system
is
returns
to
through
passed
bomb.
procedures, the
bomb is
one
into the
is
and water
condensed
into the
shown
above, hydrocarbon
the
handling
noncondensable gases go
indicated. The
to the
Pressure
by
in
As the temperature
which
loss figure
(TMBA)
in the TMBA
figure 4. The
in
plus
Any large
check.
physical
"gas
errors.
recording
represents
is usually
values
analyses
regression
using
to give
pounds
raised
by
to atmospheric
the
bomb
The
pres
chromatography
and
the
laboratory
determined
volume
can
calculated.
Analysis
components
product.
and
then
This
nitrogen
analyses.
of
hydrocarbons,
carbon
monoxide,
acid
balance
gases
closure on
balances
after
completion
of
the
and
other
the total
carbon, sulfur,
appropriate
elemental
Fischer Assay
of
Oil Shale
213
<
PQ
S
H
'rt
O
u
O
H
I
s
a
o
0)
S
O
W
a
P
o
l-H
fa
214
Quarterly
of the
Colorado School
of
Mines
be traced to inadequate
for Fischer
shale samples
meaningful
results.
Our
accuracy can
Inaccuracies in
procedures.
Fischer assay itself result from varying the heating rate from that pre
scribed above, inaccurate measurement of the specific gravity of the oil,
and
successfully carrying
out material
interface in the
product receiver.
of procedures can
balance
be
resolved
by
bal
ances.
In
order
a statistical
to
the
establish
basis,
we prepared
replicate analyses on
each
in table 2.
The
are given
0.5
percent on a volume
Table
2. Standard
four
using the
standard
Fischer
assays on
deviation
Results
basis.
deviation
analyses
and
95
percent confidence
using TOSCO
modified
limits
on replicate
assay
95% Confidence
Sample
Number
of
Standard Deviation
Mean
Limit
(gpt
(gpt)
(%)
(gpt)
(%)
20
44.82
0.25
0.6
0.52
1.2
21
29.95
0.11
0.4
0.23
0.8
29.82
0.19
0.6
0.49
1.6
26
32.90
0.19
0.6
0.39
1.2
Description
Determinations
Specific Gravity
Standard
Deep Core
C-b Plot
TG 71 Core
Composite
Grab Sample
balance
runs
per
day
was
(TMBA)
TOSCO II
facility
subsequently
north of
operated
for
Grand
over
Fischer Assay
of
Oil Shale
215
year
as
tons
of oil
TMBA data
comparison
is
shown of average
the semiworks
Table
3. The
TOSCO II
summary
Semi-Works
and
Lighter
Plant Yield
TOSCO Material
wt% of
Balance Assay
Fischer Assay
Plant
C3
to
(Lenhart 1968).
unit
10.78
11.72
92.0
105.84
104.14
101.6
116.62
115.86
100.7
9.92
10.28
96.5
126.54
126.14
100.3
Gases
C4 and Heavier
Hydrocarbons
Sub-
Total
Acid Gases
Total Products
gas"
The
the two
close parallel
yields and
hydrocarbon"
"C4
and
Acid
gas
This
close
illustrated in
of
similarity
more
the
semiworks and
detail in table 4
( Lenhart
lating
of oil
the
from
a yield of
semiworks yield
100
pounds
99.59
1968 )
from
and
4, involves
We
All
re
is
in tables 3
expected
product slates
of
to that
given
TMBA
by
TMBA
assume
semiworks
semiworks
on a repre
in
mathematical proportion.
Comparisons
given
in tables
The
close
operations and
mating
of organic
5, 6
and
distributions
are
7.
parallelism
TMBA
carbon,
provides a simple
commercial yields
of product slates
from
216
Quarterly
Table
4.- The
of the
Colorado School
TOSCO II
of
Mines
Semi-Works
TOSCO Material
Plant
Balance Assay
.41
.91
.22
.84
.45
.37
.06
0
2
2
c2-
.84
.16
.17
1,
1,
1,
1,
10,
11,
i-c4
0,
0,
n-C,
0,
0,
C4"
1.
1. 10
1.
1.
1. 17
0. 69
0.
,76
0. 34
0. 36
0. 13
c3
c
.62
.41
Sub-
Total
.78
.13
.68
,38
,67
^8
C8+
Fischer
.63
.41
.72
,07
,67
,14
0. 10
Assay
oil
99. 59
100. 00
Sub-Total
105. 84
104. 14
116. 62
115. 86
8. 58
9.14
1. 34
1.14
126.54
126.14
Total
co2
HoS
GRAND TOTAL
Fischer Assay
Table
5. The
TOSCO II
of
217
Oil Shale
distribution
( Basis :
100 lb
of organic carbon
in feed )
Semi-Works
TOSCO Material
Plant
Balance Assay
Oil
64.5
64.6
Gas
11.0
10.5
75.5
75.1
21.9
24.6
0.6
0.0
2.0
0.3
100.0
100.0
Sub-Total
Spent Shale
Total
Table
6. The
TOSCO II
(Basis: 100 lb
of sulfur
Se mi -Works
Plant
distribution
in feed )
TOSCO Material
Balance
Assay
Oil
13.9
14.8
Gas
20.4
19.2
0.8
Water
Sub Total
Spent Shale
Accounted for losses
_.-_
35.1
34.0
68.3
69.2
1.2
-4.6
-3.2
100.0
100.0
218
Quarterly
Table
7. The
of the
TOSCO II
( Basis :
Colorado School
of
Mines
100 lb
of nitrogen
in feed )
TOSCO Material
Semi-Works
Balance
Plant
Oil
distribution
Assay
50.9
49.8
3.0
3.9
53.9
53.7
44.3
50.0
Gas
Water
Sub-
Total
Spent Shale
Accounted for losses
1.2
0.6
-3.7
100.0
100.0
With
in
significant changes
commercial process
configurations, this
useful
SUMMARY
Techniques have been
(1)
outlined
for:
from
core or other
bulk
configur
ations,
(2)
conducting
TOSCO
lected
material
percent confidence
1.6
balance
assays
in
of
the
limits
statistical precision
of replicate
assay
of
the
oil yields
data
to
show
the 95
be between 0.8
percent.
The
to
where
and analyzed.
Determinations
and
Fischer assays,
and
collected,
(3)
modified
application of
the
material
(TMBA)
is illustrated.
Fischer Assay
of
219
Oil Shale
REFERENCES
Cook, E. YV., 1974, Green River shale oil yields: correlation with elemental analysis:
Fuel, v. 53, p. 16-20, Jan.
Goodfellow, Lawrence, Haberman, C. E., and Atwood, M. T., 1968, Modified Fischer
equipment, procedures and product balance determinations, Division of
assay
Hubbard,
bituminous
materials:
1971,
Ultimate
Green River
oil shale:
Reed, Jr.,
and
Philip L. Warren
INTRODUCTION
Detennination
of recoverable oil
bitumen
oil shale
determined
and
bitumen
and
Recoverable
with
kerogen
kerogen
chromatograph.
Chromatographic data
results.
in Green River
well
oil
in Green River
with
Fischer assay
that it is possible to
confirmed
separate
thermally.
INSTRUMENTATION
The MP-3
techniques in
of
the
combines
temperature as
they
volatiles was
GC
The
instrumentation.
one piece of
grammed manner.
the
both
by heating
it
(EGA curve)
liquid in a pro
thermogram
as a solid or
the
passed through
obtained
by trapping,
detector. A
then
function
of
gas chromatogram of
backflushing
them through
column.
A flow diagram
of
the MP-3 is
shown
solids
ber
chamber,
could
number
(FID).
Emerging from
1,
valve number
sample
is
split
2,
the
column
and
ballistically
and valve
(TC) detector,
with Porapak Q
filled
remaining half is trapped in a sampling loop
SE-30 on Chromosorb G. For the typical sample, the
to the GC
detector,
and
trap is backflushed
221
the
one
222
Quarterly
Colorado School
of the
VfN 1
KOW DIAGRAM
Mines
IO OlMli ANAtVZItS
IIMP
of
HOOItMMII
':
OITICTOI.VAlVf
SAMPII
-fr
OV1N
omoNAi
HAM!
oiuctoa
(~
CMAMSIt
OTAtV VAIV1S
ISOllOSl
OC
OVIN
sTUS
*Oii
inj
IIAI/MtAflt
GASIS/llOUlOf
OTAMftfl
HOW CONttOllIt
I I
OAS CHtOMAIOOIAM
OAS JUMIT
1. The
Figure
sample
can
record
wanted
trapped
The GC
the
with
for
used
of
swept
known
heat is
programmable
a reactant
switching
to
this flow
valve number
valve number
sample.
Also,
1 to the
solvents or
3 to the
The TC
and
removal can
vent position.
be
to
can
detector is turned
provides a means of
H20
solvents or water
thermal
or valve number
flows
the TC
furnace
bypass
400C
a maximum of
section.
number
to
liquid
system
heated
Alternatively,
through the
to
through the
system
substances
sends
torting,
ing
heating
constituents
spiked with
column
The versatility
for
analysis.
FID detectors
By
identifying
be
Rapid
port.
FID
The
and
operator
it is heated.
for further
volatiles can
injection
"slug."
TC
as a means of
minute;
the
system permits
the
same
chromatogram.
During
switched
a sample
bed.
by
switch
run,
valve
or reject selected
a stripper or catalyst
by
the sample.
monitored
to collect
off.
adding
are removed
heating
be
be
be
added to the
Recoverable Oil
223
Thermal Analysis
by
EXPERIMENTAL CONSIDERATION
The format
single-phase
and
3,
the
of
data for
thermogram
respectively.
The
is the
preferred method of
is insensitive to
intensity
signal
while
( FID )
to
ordinates correspond
usually a smooth,
shown in figures 2
detection for
oil
in
shale, because it
oil
relative
to
its
INTENSITY
DEGREES
Figure
2Thermogram of oil
recorded
CENTIGRADE
shale, 34.7
simultaneously
with
The
gal/ton.
TC
and
FID
upper and
detection,
lower traces
respectively.
were
That
"sees"
"sees"
the TC
600
SOO
4 00
300
200
everything
and
the FID
only
organic
materials
is
224
Quarterly
Colorado School
of the
of
Mines
CS
INTENSITY
2 00
DEGREES CENTIGRADE
Figure
3. Chromatogram
observed
GC.
here
of
volatiles
were
The temperature
retention
indices
as
program
high
as
3800
rate
can
was
Sample Preparation
Representative Green River
U. S. Bureau
of
Mines.
According
from the
samples assayed
between 10
shale.*
and
Spex Shatter
Box,**
sample preparation
Spex
sieve set
to investigate the
A bituminous frac
traction for 36
Research
benzene
ex
hours.
by
were obtained
of
Mines,
Laramie
Energy
Recoverable Oil
Thermal Analysis
by
225
Thermal Conditions
Randomly
in
contained
M in. OD
ranging from 10 to 60 mg in
selected samples
20cc/min
at
tube
quartz
at
40 psig,
tector
sensitivities
number
was
in
with
each
150
current was
For
indicated.
are
size were
oil
250C. De
ma at
determinations,
yield
valve
"BACKFLUSH"
the
or vent
Each
position,
measurement required
so
15 to 30
minutes.
Chromatograms
Chromatograms
were recorded
temperature programming
with
LIMIT'
steel,
TC
flow
packed with
and
FID
20
was
cc/min.
The
SE-30
percent
column
Chromosorb
on
termined
response of
by
peak
by
on previous
recording
large
as
less
calcite,
heated,
yield
as a
were
The
The
G, H.P., 80/100
mesh.
function
of sample
loading
de
was
Peak
error
error
such as
stainless
Data
of
percent.
& in.
triangulation.
experience.
were
Helium
integration techniques
and
the
MP-3
height
as
the
6 ft
mode.
indicated in figures.
sensitivities are
Measurement
The
was
at
dolomite,
is
clay,
only inorganic
while
due to
sample
errors could
be
inhomogeneity depends
on
integration
not well
feldspar,
gases
plus
pyrite and
quartz,
which
do
not
water,
interfere
with
when
flame
ASSAY RESULTS
Both
for
peak
height
MP-3
and
than
known Fischer
figure 4. The
3.8
mean
percent
for
anticipated on
deviation for
peak
the thermogram
assays.
function
each
correlation of
the
height. Both
10 determinations
The
were measured
of
were somewhat
per sample.
larger deviations
226
Quarterly
Colorado School
of the
of
Mines
900-
800-
700
600.
Area
(mm^)
MP-3
500-1
400
300-
200-
100-
~i
10
20
in Oi I
Oi I
30
Shale
40
"T
50
60
(gal/ton)
by Fischer Assay
Figure
response
were
each point
An increase in
shown
4. MP-3 response as a
in figure 5.
particle
L. Goodfellow
into
by
increasing
et al.
(1968).
various
200,
fractions
+100. A
with
distribution
a sieve
set.
of
The
Recoverable Oil
THERMAL-
227
Thermal Analysis
by
RESPONSE
VS
SIZE
MESH
(25.
GAL/TOn)
2.0-
-65
*
IS
PEAK
&
-60
AREA
A,
HEIGHT
(mm/mg)
(mm^/mg)
16
-5f>
0
m
m
liJ
LJ^
-so
l
-200
-IOO
-MOO
SIZE
MESH
Figure
function
5.Thermal response as a
(Goodfellow, Haberman,
with
of mesh
size.
As
1968),
Atwood
and
with
an
the
Fischer assay
increase in
oil
yield
increasing
in the MP-3
sample
solid
by
temperature pro
maximum
temperature and
tained
Similarities
low
temperature
matographic
fraction
information
and
also
appeared
the benzene
and
chromatograms
in the
Chro
light hydrocarbons
heavier hydrocarbons
make
are
up
A 22 mg
sample of
34.7
to the
dences
7); (3)
chromatogram
as
indicated
as
gal/ton
follows:
Green River
(1)
25 to 300C (fig.
of
the
by the
dots. The
arrows
showed numerous
indicate
pristane and
coinci
phytane,
Quarterly
228
Oll_ SHALE
Colorado School
of the
Mines
of
FRACTION
chromatogram
FID 32
fraction
thermal
25to300c
IOO
AT:i2C/Mirsi
,25
TO 320C
200
DEGREES C
Figure
6. Chromatogram of
The
( fig. 9 )
The
of
34.7
resembles
the
phytane,
left to
bitumen
extract
right.
OIL SHALE
FRACTION
THERMAL FRACTON
IOO
C20
CIS.
_,_
JIfwJJ
i
KA
i!
i
C25
u>W
i
200
300
IOO
DEGREES C
Figure 7. -Chromatogram
This
the increased
is the
the
of
was recorded
from the
abundance of
right shoulder on
first
thermal
remains of
the
C18,
fraction.
lower
the
of
sample used
Phytane
in
Recoverable Oil
OIL
SmAlE
229
Thermal Analysis
by
FRACTOf
FID'
126
OO
&T
i2Cv>iim.2S
^O 320C
M*
200
DEGREES C
Figure 8.-Chromatogram of 375 to 475 C thermal fraction of 34.7 gal /ton oil shale.
This chromatogram, recorded from the remains of the sample used for
figure 7, shows primarily the decomposition of kerogen. Much of light
retorted
shale
results
ExTBAC"
BENZENE
F O
oil
IOO
iTl2C/MiN,2,-0 32:
200
DEGREES C
Figure
benzene
9. Chromatogram of the
mark
peaks
coincident
with
C18
retention
is the left
indices.
those
solvent
peaks,
phytane
shoulder of phytane.
is the
Pristane
and
most
C17
prominent
have
similar
230
Quarterly
respectively, in
Colorado School
of the
order of
increasing
index. A
retention
Mines
of
subsequent
investi
tions, there
fraction.
The
heating
was
an
the
thermal
second
sample
same
hydrocarbons C15
abundance of
by
Furthermore,
the low
indices
retention
and
they
by
two
with
spiking
linear hydrocarbons.
which
were
relatively
were not
appeared
in this
fraction. The
thermal
in this fraction
more prominent
They
greater
used
and
to arise
on
of phytane or pristane or
heating
the
features in this
the most
prominent
from
decomposition
the
Low
of
molecular weight
hydrocarbons
arise
by
are
primarily
kerogen.
DISCUSSION
Experimentally,
shale with
the
was
resembles
programmably heated.
complete, hence
gases
of
carbon
the
once
routine
time considerably.
crease calculation
Since the
However,
whereas
evolved,
integration
more
organic carbon
framework
are
to
consistent
hydrogen
Consequently,
method
that can
oil shale
industry
*D. Scrima
and
P.
be
where
Warren,
can
thermal analysis is
used on-site
many
results
to
be
a
kerogen hydro
applied
to all
relatively
shale
Green River
inexpensive, fast
samples must
be
the
ratio and
published.
be
assayed.
Recoverable Oil
by
Thermal Analysis
231
REFERENCES
Soc.,
equipment,
procedures
and product
balance determinations:
Am. Chem.