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Colorfastness of textiles as per consumers need

Introduction
Todays consumer is more sophisticated than ever. They are conscious not only of style and comfort,
but also of care & durability. They demand a quality product. Market studies show that consumers
many purchase choices based on color. Therefore, a fabrics ability to retain its original color is one of
the most important properties of a textile product.

Colorfastness or color retention of cotton textiles is influenced by a number of variables that occur
both pre-consumer & post-consumer. This report summarizes how variations in raw materials,
chemicals, manufacturing processes & consumer practices all have an effect on performance
characteristics of a fabric. Manufacturers must understand how many variables affect colorfastness to
achieve the ultimate goal of consumer satisfaction.

Colorfastness and test methods


Colorfastness is defined by the American Association of Textile Chemists and Colorists as resistance
of a material to change in any of its color characteristics, to transfer its colorant(s) to adjacent
materials, or both, as a result of exposure of material to any environment that might be encountered
during processing, testing, storage, or use of the material. In other words, it is a fabrics ability to
retain its color throughout its intended life cycle. There are many types of colorfastness properties
that must be considered to provide consumer with an acceptable product. The American Association
of Textile Chemists and Colorists has over thirty test methods that evaluate different colorfastness
properties. These include, but are not limited to wash, light, crock, dry cleaning, perspiration,
abrasion and heat. The type of product being manufactured determines which types of colorfastness
are important and therefore which test methods are relevant. For example, upholstery fabrics must
have excellent lightfastness & crockfastness properties, whereas washfastness is important for
clothing fabrics. Manufacturers must know a fabrics intended end use in order to make processing
decisions that will produce a product of acceptable performance.

Textile manufacturing processes affecting colorfastness


1. Preparation
Many aspects in textile manufacturing process of taking a loom state fabric to a finished product have
an effect on colorfastness properties. Preparation is the first stage of textile wet processing. Cotton
fibers are approximately 95% cellulose. The non-cellulosic portion consists of natural products such as
waxes, sugars, metals, & man-made products such as processing aids, grease, plastic, & rubber. To
achieve optimum dyeing & finishing conditions, it is important that these impurities are thoroughly
removed with minimal damage to the cotton fiber.

2. Dye Selection
Dyeing is the crucial step in determining colorfastness performance of a fabric. The American
Association of Textile Chemists & Colorists defines a dye as a colorant applied to or formed in a
substrate, via molecularly dispersed state, which exhibits some degree of permanence. Dyeing is
accomplished by immersing textile in a dye bath, applying heat & chemicals to drive dye onto textile,
& then rinsing substrate to remove surface dye. These principles are illustrated below. Different dye
classes are used for each fiber type. Table below shows which dyes can be used for which fibers.

Dye classes available for different fibers


Fiber
Cotton & manmade cellulosics
Polyester
Nylon
Acetate
Wool & Silk
Acrylic

Dyestuffs
Direct, Vat, Sulfur, Naphthol, Reactive, Pigment
Disperse, Basic
Disperse, Acid, Premetallized
Disperse
Acid, Premetallized
Dispersed, Basic

Dye selection must be based on desired performance criteria, manufacturing restrictions & costs a
market can bear for each end product. Every dye has unique colorfastness properties. Some dyes are

known for their excellent wash fastness characteristics & others are known for their lightfastness
properties. Structure of dye, amount of dye, its method of bonding to fabric & dyeing procedures all
contribute to a dyes performance characteristics. Dye combinations in a specific formulation must
also be evaluated for their effect on colorfastness. Heavy shades often have reduced fastness
properties. When high concentrations of dye are required, proper rinsing & washing off procedures
are essential. However, due to entrapped dye particles within cellulose structure, some unbound dye
molecules can still remain & contribute to color loss and dye transfer

Dyes for cotton


Dyes can be categorized based on mechanism by which they become fixed to a fiber. Dyes used for
cotton fibers can be categorized into surface bonding, adhesion, or covalent bonding mechanisms.
Pigments are sometimes used to color cotton fabrics; however they are not considered dyes. They are
completely insoluble in water & have no affinity for cotton fibers. Some type of resin, adhesive, or
bonding agent must be used to fix them to cotton fiber. Typically, they exhibit good colorfastness to
light and poor colorfastness to washing.

Direct dyes are water soluble & categorized into surface bonding type dye because they are absorbed
by cellulose. There is no chemical reaction, but rather a chemical attraction. Affinity is a result of
hydrogen bonding of dye molecule to hydroxyl groups in cellulose. After dyestuff is dissolved in
water, a salt is added to control absorption rate of dye into fiber. Direct dyes are fairly inexpensive &
available in a wide range of shades. Typically, they exhibit good lightfastness & poor washfastness.
However, by applying a fixing agent after dyeing washfastness can be improved dramatically.

Vat, sulfur, & naphthol dyes are fine suspensions of water insoluble pigments, which adhere to cotton
fiber by undergoing an intermediate chemical state in which they become water-soluble & have an
affinity for fiber. Typically, vat dyes exhibit very good colorfastness properties. Sulfur dyes are used
to achieve a low cost deep black. They exhibit fair colorfastness properties, although lighter shades

tend to have poor lightfastness. Naphthol dyes are available in brilliant colors at low cost, but application
requirements limit their use. They exhibit good lightfastness & washfastness, but poor crockfastness.

Reactive dyes attach to cellulose fiber by forming a strong covalent (molecular) chemical bond. These
dyes were developed in the 1950s as an economical process for achieving acceptable colorfastness in
cellulosic fibers. Bright shades and excellent washfastness properties are trademark of reactive dyes.
One concern regarding reactive dyes is their susceptibility to damage from chlorine. Another is that
lighter shades tend to have reduced lightfastness properties.

Following table summarizes fastness properties of dye categories or classes available for dyeing
cotton fabrics. Keep in mind that these are generalizations. Every dye is unique and some dyes within
a particular class may behave differently.

Finishing
Finishing is the final stage of textile wet processing. Different types of finishes can be utilized
depending on desired performance characteristics of end product. Resin & enzyme treatments are
common finishing techniques that can influence colorfastness of textile fabrics. Crosslinking resins are
used to improve durable press or wrinkle resistance of a fabric. Generally, resin treated fabrics
demonstrate improved color retention to laundering. However, this increase in color retention comes
at expense of reduced physical properties of fabric. Silicone softeners incorporated into resin finish
bath may further improve color retention for some fabrics. Softeners & resins play a key role in
reducing surface abrasion & therefore improved overall wash performance. Cellulase enzymes are
used to remove surface fibers that can create a fuzzy appearance on surface of a fabric. Generally,
enzyme treated fabrics show improved ability to maintain their original color & appearance after
multiple home launderings. Degree of improvement from any of these finishing techniques is highly
dependent on individual dyes used in a particular formulation to achieve a given shade

Consumer practices

Manufacturers can follow every recommendation & precaution to produce a fabric with optimum
performance characteristics. However, colorfastness properties are also influenced by consumer
practices. These include laundry detergent selection & wash procedures. Therefore, when evaluating
colorfastness properties of a product it is important to use appropriate test method that accurately
reflects consumer laundry practices. Due to higher energy costs consumers are laundering clothes at
lower temperatures. For this reason detergent with color safe or activated peroxy bleaching agents,
which improve cleaning efficacy at lower wash temperatures, are one of the fastest growing segments
of home laundry market. Some fabrics may fade a little when home laundered with standard
detergent, but fabrics laundered with detergents containing activated bleach can show significant
losses in color strength as determined by sensitivity of dye to those detergents. Another type of
detergent available to consumers is those containing enzymes, which remove surface cellulosic fibers
from fabric. Many times loss or apparent loss of color can be attributed to surface changes in fabric
caused by abrasion during laundering. Detergents containing enzymes generally reduce color change
associated with home laundering by decreasing fuzziness of a fabrics surface. Wash procedures also
influence a fabrics ability to retain its color. Consumer practices such as washing clothes inverted,
reducing wash load size, adding softener to final rinse & reducing tumble dry time minimize color loss.

Conclusions
The colorfastness of cotton textiles can be a complicated subject. Fiber quality, yarn formation, fabric
construction, textile wet processes and consumer practices can all have an influence on performance
characteristics of a fabric. Of these variables, choices made during textile wet processing have most
significant effect on the colorfastness properties. Dye selection is of the utmost importance. Consumer
practices such as detergent selection & laundering techniques also play a major role in color retention
of a fabric. Customer satisfaction should improve as manufacturers gain experience and knowledge in
understanding and controlling the many aspects that influence colorfastness