Professional Documents
Culture Documents
________
________
________
________
24.
________
(10 points)
TOTAL(100 points)
__________
Gas Constant
8.314
Speed of light
3.00 x 108
Faraday Constant
9.65 x 104
Avogadro
NA
or
m/sec
Boltzmann
C/mole
also
J/(mol oK)
C + 273.15 = K
Multiple choice- select the best answer and mark it on the scantron sheet.
1. Which of the following is NOT true:
a. A reaction which increases the entropy of the system is always spontaneous
b. A reaction which increases the entropy of the universe is always spontaneous
c. A spontaneous reaction has a negative free energy of reaction
d. A reaction which decreases free energy is increasing the entropy of the universe.
2.
a.
b.
c.
d.
e.
Which one of the following is always positive when a spontaneous process occurs?
Ssys
Ssurroundings
Suniverse
Hsys
Huniverse
CO
SO
NO < CO < SO
SO < CO < NO
SO < NO < CO
CO < SO < NO
CO < NO < SO
H = -304.2 kJ;
S = -414.2 J/K
11. Use Hess's law to calculate Grxn using the following information.
CO(g) C(s) + 1/2 O2(g)
Grxn = ?
CO2(g) C(s) + O2(g)
CO(g) + 1/2 O2(g) CO2(g)
Grxn = +394.4 kJ
Grxn = -257.2 kJ
a. +523.0 kJ
b. +651.6 kJ
c. -60.0 kJ
d. +137.2 kJ
e. -265.8 kJ
12. Below what temperature does the following reaction become nonspontaneous?
2 HNO3(aq) + NO(g) 3 NO2(g) + H2O(l)
a. 151 K
b. 475 K
c. 39.2 K
d. This reaction is nonspontaneous at all temperatures.
e. This reaction is spontaneous at all temperatures.
13. What is the oxidation state of N in NO2-?
a. +5
b. +4
c. +3
d. -1
e. -3
14. What element is being reduced in the following redox reaction?
Cr(OH)4(aq) + ClO(aq) CrO42-(aq) + Cl(aq)
a. Cr
b. O
c. H
d. Cl
15. Define a salt bridge.
a. A pathway between the cathode and anode in which ions are oxidized.
b. A pathway in which no ions flow.
c. A pathway by which counterions can flow between the half-cells without the solutions in the
half-cell totally mixing.
d. A pathway between the cathode and anode in which ions are reduced.
e. A pathway, composed of salt water, that ions pass through.
16. Which of the following is the strongest oxidizing agent? (see standard reduction potentials
in table below)
a. Cr(s)
b. Sn4+ (aq)
c. Cr3+ (aq)
d. Sn2+ (aq)
e. Sn(s)
Reduction half reaction
E (V)
0.15 V
-0.14 V
-0.73 V
17. Determine which of the following pairs of reactants will result in a spontaneous reaction at
25C. (see standard reduction potentials in table below)
a.
b.
c.
d.
e.
E (V)
1.09 V
0.80 V
0.34 V
-0.036 V
-0.13 V
-0.23 V
-1.66 V
-3.04 V
18. What is the shorthand notation that represents the following galvanic cell reaction?
Pb(s) + Cu(NO3)2(aq) Pb(NO3)2(aq) + Cu(s)
a. Pb(s) | Pb2+(aq) || Cu2+(aq) | Cu(s)
b. Cu(s) | Cu2+(aq) || Pb2+(aq) | Pb(s)
c. Pb(s) | NO3-(aq) || NO3-(aq) | Cu(s)
d. Cu(s) | Cu(NO3)2(aq) || Pb(NO3)2(aq) | Pb(s)
19. Use the tabulated half-cell potentials to calculate G for the following balanced redox
reaction.
3 I2(s) + 2 Fe (s) 2 Fe3+ (aq) + 6 I(aq)
a.
b.
c.
d.
e.
+4.9 x 101 kJ
-3.3 x 102 kJ
+2.3 x 102 kJ
-1.1 x 102 kJ
-9.7 x 101 kJ
E (V)
+0.54 V
-0.036 V
20. Calculate the cell potential for the following reaction that takes place in an electrochemical
cell at 25C.
Sn(s) Sn2+(aq, 0.022 M) || Ag+(aq, 2.7 M) Ag(s)
a. +0.01 V
b. -0.83 V
c. -0.66 V
d. +1.01 V
e. +1.31 V
E (V)
0.80 V
-0.14 V
Questions 21-24: 10 pts each. Show All Work for Partial Credit.
21. Consider the following reaction:
Fe2O3(s) + 3 CO(g) 2 Fe (s) + 3 CO2 (g)
Estimate Go for this reaction at 400 K and predict if or not the reaction will be spontaneous.
G (kJ/mol)
Fe2O3(s)
CO(g)
Fe (s)
CO2 (g)
-742.2
-137.2
-394.4
Gorxn=npGop - nrGor
Gorxn={2x0 + 3x(-394.4)} {1x(-742.2) + 3x(-137.2)}
Gorxn= -29.2kJ/mol
spontaneous
Go = 82.3 kJ/mol
Qp = P2H2PS2/P2H2S
Qp=0.1502 x 0.100/0.2002 = 0.0625
G = Go + RTlnQ
G = -82.3x103 + 8.31x323.15ln0.0625 = -89745 J/mol or -89.7 kJ/mol
24. A student builds his own galvanic cell based on the chemical reactions:
Mg(s) + Mn2+(aq) Mn(s) + Mg2+(aq)
Please sketch a good diagram this cell with the following information:
E (V)
-1.18 V
-2.37 V
Extra Credit Question for Exam #3. 8 pts. Show All Work for Partial Credits.
Note: with extra credit, a maximum grade of 100 pts on exam 3 will be allowed.
25. Calculate the pH for the solution that is prepared with a mixture of 150.0 mL of 0.50 M C 2H5NH2
(ethylamine) with 60.0 mL of 0.30 M C2H5NH3Cl.(ethylammonium chloride) Given that Kb (C2H5NH2) =
5.6 x 10-4.
pH = pKa + log([base]/[acid])
pH = pKa + log(nbase/nacid)
nbase = 0.150 x 0.50 = 0.075 mol
nacid = 0.060 x 0.30 = 0.018 mol
Ka = Kw/Kb = 10-14/5.6x10-4 = 1.78 x 10-11
pKa = 10.7
pH = 10.7 + log (0.075/0.018) = 11.3