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Apparatus required:
Electronic balance
China dish
Beaker stirrer
Bunsen burner
Stand
Clamps
Log table
Tripod stand
Wire gauze
Thermometer
Chemicals required:
Distilled water
Sodium Chloride (NaCl)
Zinc Sulphate(ZnSO4)
Ammonium Chloride(NH4Cl)
Boiling-point elevation:
Boiling-point elevation describes the
phenomenon
that the boiling point of a liquid (a solvent)
will be higher
when another compound is added, meaning
that a
solution has a higher boiling point than a pure
solvent.
This happens whenever a non-volatile solute,
such as a
salt, is added to a pure solvent, such as water.
Tb=Kb .msolute.i
Non integer i factors result from ion pairs in
solution,
which lower the effective number of particles
in the
solution.
Together with the formula above, the boilingpoint
elevation can in principle be used to measure
the
degree of dissociation or the molar mass of
the
solute. This kind of measurement is called
ebullioscopy (Greek "boiling-viewing").
Procedure:
Measuring
the mass of solute and
solvent :
Take a clean, dry and empty beaker.
Measure the weight of the beaker with the
help of balance
Now pour some distilled water into the
beaker and again weigh the beaker by
subtracting this mass from initial mass of
beaker
We get mass of solvent(water).
Now , add some salt to the beaker and shake
the beaker so as to dissolve the salt in water
and again weigh the beaker.
This calculated mass when subtracted from
the mass of the beaker will give the mass
of the salt dissolved.
Observation:
Solvent used=water
End error and correction in the
thermometer
Observed melting point of ice = 3 C
Real melting point of ice = 0 C
Error in reading = -3 C
Correction e = 3 C
i = Tb*Mb*Wa/Kb*Wb*1000
i = 1 X 161.5 X 39
8 X 1000 X 0.52
i = 1.5
Vant Hoff factor for ZnSO4
is 1.5
x = 86.84 gm
z= 162.86 gm
wa =y-x= 63.87 gm
f) Mass of solute wb =z-y=12.15 gm
1. Molecular mass of solute Mb = 118.90 gm
e) Mass of solvent
96.0OC
T1 =
100.0 C
= 97.5OC
O
d) Elevation in boiling point Tb = 1.5 C
c) Boiling point of solution
1.80
KBr is 1.80
Inference:
It was experimentally proved
that the boiling
point of water increases on
addition of a non
volatile solute.
The value of vant Hoff factor
for
1. NaCl = 1.8
2. ZnSO4= 1.50
3. NH4Cl= 1.65
4. KBr=1.80
5. CH3COOH =0.60
The Vants Hoffs factor for
these salts was found to be
greater than 1 (One).Hence,
the compounds dissociates
into ions when dissolved in
water.
Precautions:
The Pans of the balance
should be clean dry and
dust free as the mass of dust
may be more than sensitivity
A clean and dry beaker must
be used The beaker should
never be heated directly on
the burner
The error in the thermometer
should be determined and
apply the corresponding
correction
i (named
afterfreezing
J.of
measure
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aof
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such
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and
point
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is
dissolved,
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mass.
electrolytes
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inas
essentially
Hoff
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H. van
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isfactor
aHoff
measure
ifactor
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after
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The
between
van
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the
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actual
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and
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asas
calculated
For
most
non-electrolytes
from
its
mass.
dissolved
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the
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