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QuestionRevision

Question1.
Forthereaction:
constant

,thecorrectrelationshipbetweendegreeofdissociation

andequilibrium

is:

[A]

[B]

[C]

[D]

Question2.
Foragivenindicator,HIn,thefollowingequilibriumapplies,

.TheindicatorisredatpH

<4andblueatpH>6.Whichoneofthefollowingisfalse?
[A]
[B]

AtpH=11.5,theindicatorwillbemainlyinthe

[C]

In0.2

[D]

In0.05MHCl,theindicatorwillbered

form

In0.1NaOH,theindicatorwillappearblue
,theindicatorwillbered

Question3.
Thetwoequilibrium,
constants,

and
respectively.Theratioof

aresimultaneouslymaintainedinasolutionwithequilibrium
to

[A]

Directlyproportionaltotheconcentrationof

[B]

Inverselyproportionaltotheconcentrationof

[C]

Directlyproportionaltothesquareoftheconcentrationof

[D]

Inverselyproportionaltothesquareoftheconcentrationof

inthesolutionis:

Question4.
Theequilibriumconstantfortheallgasequilibrium(at1000K)
molesofNO,2.0molesof

and7.0molesof

is

.Ifyouweretobeingwith3.0

,inaclosedcontainerat1000K,andallowequilibriumtobeestablished

[A]

Theconcentrationof

wouldgoup

[B]
[C]
[D]

Theequilibriumconstantwouldchangetosomeothervaluebesides1.20
Therewouldbemorethan3.0molesofNOpresent
Theamountof
woulddecrease

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Question5.
Someammoniaissealedinacontainerandallowedtoequilibrateatsomeconstanttemperature.
Thereactionisendothermic.

Whichofthefollowingwillcausethereactiontoproceedtotheright?
I.Someammoniaisadded
II.Somehydrogenisadded
III.Thevolumeofthecontainerisdecreased
IV.Thetemperatureisincreased
Thecorrectchoiceis:
[A]
[B]
[C]
[D]

IandII
IandIII
IandIV
IIandIV

Question6.
Theequilibriumconstantfor:

is0.5at500K.Whatisthestateofvesselshownbelow?

[A]

Thecontentofthevesselarenotinequilibrium,withanexcessof

[B]
[C]

Thecontentofvesselareinequilibrium
Thecontentofthevesselarenotinequilibrium,withanexcessof

[D]

Nothingcanbepredictedregardingtheequilibriumjustfromthediagramgivenabove

Question7.
At200oC,nitrogenoxidereactswithoxygentoformnitrogendioxideasfollows:

Inamixtureofthespeciesatequilibrium,wecanaccuratelypredictthat
[A]

TheconcentrationsofbothNOand

willbemuchlargerthantheconcentrationof

[B]

TheconcentrationsofbothNOand

willbeequalthantheconcentrationof

[C]

TheconcentrationsofeitherNOand

[D]

Theconcentrationof

(andpossiblyboth)willbemuchsmallerthantheconcentrationof

willbeexactlyonehalftheconcentrationofNO

Question8.
Atsometemperature,thefollowingpartialpressuresaremeasuredinaclosedreactionvesselinwhichchemicalequilibriumhasbeen
reached:

Whatis
[A]
[B]
[C]

atthistemperatureforthereaction

11
26
0.091

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[D]

QuestionRevision

4.6

Question9.
dissociatesintotwo

molecules.When0.50moleof

equilibrium,thefinalconcentrationof

isplacedina2.0Lflaskandallowedtocometo

is0.10mol/L.Whatistheequilibriumconstantforthedissociationof

under

theseconditions?
[A]
[B]
[C]
[D]

0.20
0.90
0.23
4.44

Question10.
Whichofthefollowingsolutionswillactasbuffersolutions?
I.10mLof0.1MNaOH+5mLof0.1MHCl
II.10mLof0.1NaOH+15mLof0.1M
III.10mLof0.1

+15mLof0.1M

IV.10mLof0.05MNaF+5mLof0.1MHF
Thecorrectchoiceis:
[A]
[B]
[C]
[D]

IandII
IIandIII
II,IIIandIV
Allwillactasbuffersolutions

Question11.
WhichofthefollowingsolutionswillhavepHcloseto1.0?
[A]
[B]
[C]
[D]

Question12.
Agroupofstudentsleftamixtureofcalciumhydroxideandwatertoequilibrateat20oC.Theytitratedtheresultingsaturatedsolutionand
foundthatitcontained

of

ions.Thesolubilityproductconstant

atthistemperatureis

therefore:
[A]
[B]
[C]
[D]

Question13.
WhichofthefollowingaqueoussolutionsisabufferwithapHgreaterthan7.0?
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For

andfor

[A]

10mLof0.1M

[B]

10mLof0.1M

+5.0mLof0.1M

[C]

10mLof0.1M

+10mLof0.1M

[D]

10mLof0.1M

+10mLof0.1M

+5.0mLof0.1M

Question14.
Whichoneofthefollowingpairsofreactantswillgiveaneutralsolutionwhenmixedtogetherinequimolaramounts?
[A]
[B]
[C]
[D]

Question15.
Ifweakbasehastheionizationconstant

ofitsconjugateacidisgivenby:

[A]
[B]
[C]
[D]

Question16.
MYand

,twonearlyinsolublesalts,havethesame

wouldbetrueinregardtoMYand

valuesof

atroomtemperature.Whichstatement

[A]

ThemolarsolubilityofMYandNY3inwaterareidentical

[B]

ThemolarsolubilityofMYinwaterislessthan

[C]

ThesaltsMYand

[D]

TheadditionofthesaltofKYtosolutionofMYand

aremoresolublein0.5MKYthaninpurewater
willhavenoeffectontheirsolubility

Question17.
Asolutionis0.10Min
solutionof

ions.Whichcompoundwillprecipitateatthelowest

whena

isadded?

[A]
[B]
[C]
[D]

Question18.
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WhatisthepHofa
[A]
[B]
[C]
[D]

molarsolutionofHCN?(ForHCN,

10
Between7and10
7
Between4and7

Question19.
Inthetitrationofaweakacidwithastrongbase,
[A]
[B]
[C]
[D]

TheequivalencepointoccursatapHlessthen7
TheequivalencepointoccursatapHgreaterthen7
TheequivalencepointoccursatapHnear2
TheequivalencepointoccursatapHof7

Question20.
Whichofthefollowingsaltsresultinbasicsolutionswhendissolvedinwater?

[A]
[B]
[C]
[D]

Question21.
Considerthefollowingreactionwhichproceedspredominantlyfromlefttoright

Fromtheinformationgivenitisclearthat
isastrongeracidthan

[A]

isaweakerbasethan

[B]

isastrongerbasethan

[C]

isaweakerbasethan

[D]

Question22.
Additionofsolidsilverchloridetoasaturatedsolutionofsilverchloride
[A]
[B]
[C]
[D]

wouldcause

Thechlorideionconcentrationtobelargerthanthatinthesaturatedsolution
Nochangeinthechlorideionconcentration
Thechlorideionandsilverionconcentrationstobelargerthanthatinthesaturatedsolution
Thechlorideionandsilverionconcentrationstobesmallerthanthatinthesaturatedsolution

Question23.
Whichspeciesbelowhasthesamegeneralshapeas

[A]
[B]
[C]
[D]
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Question24.
Thegeometriesofthemolecules

and

aretrigonalplanarandtrigonalpyramidal,respectively.whichstatementbest

accountsforthedifference?
[A]
[B]

NismoreelectronegativethanB
isionic,
iscovalent

[C]

Butilise

[D]

Nhasnonbondingpairofvalenceelectrons,whileBdoesnot

hybridization,whileNdoesnot

Question25.
Whichofthefollowingisnottheexpectedgeometryoftheindicatedmoleculesorion?
regulartetrahedron

[A]

linear

[B]
[C]

triangularpyramidal

[D]

trigonalplanar

Question26.
Howdoesthemagnitudeof

bondanglesveryinthesespecies?

[A]
[B]
[C]
[D]

Question27.
Whichmoleculewillhavethesmallest

bondangle?

[A]
[B]
[C]
[D]

Question28.
Whichofthefollowinggroupsofmoleculesandionsdoesnotcontainanexamplewithaplanargeometry?
[A]
[B]
[C]
[D]

Question29.
Whichofthefollowinghybridizationpatternsbestdescribesthecarbonatomin
[A]

sp

[B]

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[C]
[D]

Question30.
AccordingtoVSEPRtheorywhichofthefollowingmoleculesis(are)bent(nonlinear)?
I.

II.

IV.

V.

III.

Thecorrectchoiceis:
[A]
[B]
[C]
[D]

Allofthese
III,IV
III,IV,V
OnlyIII

Question31.
Ablockconnectedbyamasslessspringwithafixedwedgeasshowninthefigureisreleasedwiththespringinitsnaturallength.Friction
isabsent,maximumelongationinthespringwillbe:
(Assumelengthofinclinedplaneislarge)

[A]
[B]
[C]
[D]

Question32.
Aparticleofmass3misprojectedformthegroundatsomeanglewithhorizontal.ThehorizontalrangeisR.Atthehighestpointofitspath
breaksintotwopiecesmand2m.Thesmallermasscomestorestandlargermassfinallyatadistancexfromthepointofprojection
wherexisequalto:
[A]
[B]
[C]
[D]

3R

Question33.
Aballofmassm=60gmisshotwithspeedv 0=22m/sintothebarrelofspringgunofmassM=240ginitiallyatrestonafrictionless
surface.Theballsticksinthebarrelatthepointofmaximumcompressionofthespring.
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Thespeedofthespringgunaftertheballstopsrelativetothebarrel,is:
[A]
[B]
[C]
[D]

2.2m/s
4.4m/s
6.4m/s
Noneofthese

Question34.
Aballofmassm=60gmisshotwithspeedv 0=22m/sintothebarrelofspringgunofmassM=240ginitiallyatrestonafrictionless
surface.Theballsticksinthebarrelatthepointofmaximumcompressionofthespring.

Whatfractionofinitialkineticenergyoftheballisnowstoredinthespring?
[A]
[B]
[C]
[D]

0.2
0.8
0.4
0.6

Question35.
Aparticleofmass1kgismovingalongtheliney=x+2(here,xandyareinmeters)withspeed2m/s.
Themagnitudeofangularmomentumofparticleaboutoriginis:
[A]
[B]
[C]
[D]

Question36.
AparticleissuspendedthroughpointOwithastringoflengthR.Itisgivenavelocity

atthebottom.

VelocityofparticleatpointBis:
[A]
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[B]
[C]
[D]

Question37.
AparticleissuspendedthroughpointOwithastringoflengthR.Itisgivenavelocity

atthebottom.

TensioninstringatDis:
[A]
[B]
[C]
[D]

7mg
5mg
9mg
4mg

Question38.
ThreeparticlesA,BandCofequalmassesmovewithequalspeedsvalongthemediansofanequilateraltriangle.Theycollideatthe
centroidOofthetriangle.AftercollisionAcomestorestwhileBretracesitspathwithspeedv.
ThevelocityofCisthen:

[A]
[B]
[C]
[D]

Question39.
AblockofmassmispulledbyaconstantpowerPplacedonaroughhorizontalplane.Thefrictioncoefficientbetweentheblockandthe
surfaceis
.Maximumvelocityoftheblockwillbe:
[A]

[B]
[C]
[D]

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Question40.
AthincircularringofmassMandradiusrisrotatingaboutitsaxiswithconstantangularvelocity
.Twoobjects,eachofmassm,are
attachedgentlytotheoppositeendsofadiameterofthering.Thewheelnowrotateswithanangularvelocity:
[A]
[B]
[C]
[D]

Question41.
Adiscofradiusrrollswithoutslippingonaroughhorizontalfloor.Ifvelocityofitscentreofmassisv 0,thenvelocityofpointP,asshown
inthefigure

[A]

,is:

v0

[B]
[C]
[D]

Question42.
Aballwhosesizeisslightlysmallerthanwidthofthetubeofradius2.5misprojectedfrombottommostpointofasmoothtubefixedina
verticalplanewithvelocityof10m/s.IfN1andN2arethenormalreactionsexertedbyinnersideandoutersideofthetubeontheball:
(Width<<radiusoftube)

[A]
[B]
[C]
[D]

N1>0formotioninABC,N2>0ofmotioninCDA
N1>0formotioninCDA,N2>0formotioninABC
N2>0formotioninABCandsomepartofCDA
N1isalwayszero

Question43.
AcubicalblockofsideLandmassmrestsonaroughhorizontalsurfacewithcoefficientoffriction
.AhorizontalforceFisappliedon
theblockasshown.Ifthecoefficientoffrictionissufficientlyhigh,sothattheblockdoesnotslidebeforetoppling,theminimumforce
requiredtotoppletheblockis:

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[A]
[B]
[C]

QuestionRevision

Infinitesimal
mg/4
mg/2

[D]

Question44.
Twoendsofaconductingrodofvaryingcrosssectionaremaintainedat

respectively.

Insteadystate:

[A]
[B]
[C]
[D]

TemperaturedifferenceacrossABandCDareequal
TemperaturedifferenceacrossABisgreaterthanthatofacrossCD
TemperaturedifferenceacrossABislessthanthatofacrossCD
Temperaturedifferencemaybeequalordifferentdependingonthethermalconductivityoftherod

Question45.
Twoidenticalconductingrodsarefirstconnectedindependentlytotwovessels,onecontainingwaterat
containingiceat

andtheother

.Inthesecondcase,therodsarejoinedendtoendandconnectedtothesamevessels.Letq1andq2g/sbe

therateofmeltingoficeinthetwocasesrespectively.Theratio

is:

[A]
[B]
[C]
[D]

Question46.
Abodycoolsdownfrom
[A]
[B]
[C]
[D]

in5minutes.Itwillcooldownfrom

in:

5minutes
Lessthan5minutes
Morethan5minutes
Lessthanormorethan5minutesdependingonwhetheritsmassismorethanorlessthan1kg

Question47.
Arope1cmindiameterbreaksifthetensioninitexceeds500N.Themaximumtensionthatmaybegiventoasimilarropeofdiameter2
cmis:
[A]
[B]

500N
250N

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[C]
[D]

QuestionRevision

1000N
2000N

Question48.
TheplotsofintensityversuswavelengthforthreeblackbodiesattemperaturesT1,T2andT3respectivelyareasshown,Their
temperaturearesuchthat:

[A]
[B]
[C]
[D]

Question49.
2kgoficeat

ismixedwith5kgofwaterat

inaninsulatingvesselhavingnegligibleheatcapacity.Calculatethe

finalmassofwaterremaininginthecontainer.Given:specificheatcapacitiesofwaterandiceare
respectively.Latentheatoffusionof
[A]
[B]
[C]
[D]

7kg
6kg
4kg
2kg

Question50.
EqualmassesofthreeliquidsA,BandChavetemperature
hasatemperatureof
havetemperatureof

respectively.IfAandBaremixed,themixture

.IfBandCaremixed,themixturehasatemperatureof

.IfAandCaremixed,themixturewill

[A]
[B]
[C]
[D]

Question51.
Displacementofaparticleofmass2kgmovinginastraightlinevarieswithtimeas:S=(2t3+2)m
Impulseoftheforceactingontheparticleoveratimeintervalbetweent=0andt=1sis:
[A]
[B]
[C]
[D]

10Ns
12Ns
8Ns
6Ns

Question52.
Asshowninthefigureabodyofmassmmovingverticallyhitsasmoothfixedinclinedplanewithspeed3m/sandreboundswitha
velocityv f inthehorizontaldirection.If
ofinclinedplaneis
,thevelocityv f willbe:

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[A]

QuestionRevision

3m/s

[B]
[C]
[D]

Thisisnotpossible

Question53.
FromauniformdiscofradiusR,anequilateraltriangleofside

[A]
[B]

iscutasshown.Thenewpositionofcentreofmassis:

(0,0)
(0,R)

[C]
[D]

Noneofthese

Question54.
Inthefigureshown,thetwoidenticalballsofmassMandradiusReachareplacedincontactwitheachotheronthefrictionless
horizontalsurface.ThethirdballofmassMandradiusR,iscomingdownverticallyandhasavelocity=v 0whenitsimultaneouslyhits
thetwoballsanditselfcomestorest.Then,eachofthetwoballsatsurfacewillmoveaftercollisionwithaspeedequalto:

[A]
[B]
[C]
[D]

Noneofthese

Question55.
Inthegivenfigure,asphereofradius2mrollsonaplank.Theaccelerationsofthesphereandtheplankareindicated.Thevalueof
angularaccelerationofthesphereis:

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[A]
[B]
[C]
[D]

QuestionRevision

2rad/s 2
4rad/s 2
3rad/s 2
1rad/s 2

Question56.
Ayoyo,arrangedasshown,restsonafrictionlesssurface.WhenaforceFisappliedtothestring,theyoyo:

[A]
[B]
[C]
[D]

Movestotheleftandrotatescounterclockwise
Movestotherightandrotatescounterclockwise
Movestotheleftandrotatesclockwise
Movestotherightandrotatesclockwise

Question57.
Thefigureshowsaballwhichmovesonaroughhorizontalsurfacewithoutsliding.Itascendsacurvedtrackuptoheighthandreturns.
Valueofhish1forsufficientlyroughcurvedtracktoavoidslidingandish2forsmoothcurvedtrack,then:

[A]
[B]
[C]
[D]

h1=h2
h1
h2
h1
h2
h2=2h1

Question58.
AmassmismovingatspeedvperpendiculartoarodoflengthdandmassM=6mwhichpivotsaroundafrictionlessaxlerunning
throughitscentre.Itstrikesandstickstotheendoftherod.ThemomentofinertiaoftherodaboutitscentreisMd2/12.Thentheangular
speedofthesystemjustafterthecollisionis:

[A]
[B]
[C]

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[D]

Question59.
Asolidsphereofmassmislyingatrestonaroughhorizontalsurface.Thecoefficientoffrictionbetweenthegroundandsphereis
ThemaximumvalueofF,sothatthespherewillnotslip,isequalto:

[A]
[B]
[C]
[D]

Question60.
Inthepulleysystemshown,ifradiiofthebiggerandsmallerpulleyare2mand1m,respectivelyandtheaccelerationofblockAis5m/s 2
inthedownwarddirection,theaccelerationofblockBwillbe:

[A]
[B]
[C]
[D]

0m/s 2
5m/s 2
10m/s 2
m/s 2

Question61.
Whichofthefollowinggraphsaregraphsoffunctions?

[A]
[B]
[C]

IandII
IIIandIV
I,IIandIII

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[D]

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II,IIIandIV

Question62.
Thedomainofthefunction

is:

[A]
[B]
[C]
[D]

Noneofthese

Question63.
Let

,thenrangeoff(x)is:([x]denotesthegreatestintegerlessthanorequaltox)

[A]
[B]
[C]
[D]

Question64.
Theperiodofthefunction
[A]
[B]
[C]
[D]

is:

5
8
12
40

Question65.
If
isanonrealcuberootofunity,thenthevalueoftheexpression:
is:

[A]
[B]
[C]
[D]

Question66.
Inageometricalprogression,firsttermandcommonratioareboth

.Thentheabsolutevalueofthenthtermofthe

progressionis:
[A]
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[B]
[C]
[D]

1
Noneofthese

Question67.
If
[A]
[B]
[C]
[D]

,thenumberofpossiblevaluesof

fordifferent

is:

3
2
4
1

Question68.
Ifp,q,rarepositiveintegersand

isanonrealcuberootofunityand

,then

[A]
[B]
[C]
[D]

Question69.
If

,thenf(n)isequalto:

[A]

[B]
[C]
[D]

Noneofthese

Question70.
If
[A]
[B]
[C]
[D]

,thenthepossiblevalueofxis:
2
1
4
3

Question71.
ThecommondifferenceofanA.P.,thesumofwhosefirstntermsisSn,is:
[A]
[B]
[C]
[D]

Question72.

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Thesumofthefirstntermsofthesequence
forall
[A]
[B]
[C]
[D]

isoftheform

.Thenthevalueof

is:

2
3
4
0

Question73.
Let

.Thenthevalueof

forwhichtheequation

hasexactly3real

anddistinctrootsis:
[A]
[B]
[C]
[D]

2
4
6
Noneofthese

Question74.
Whichofthefollowingfunctionsisanevenfunction?
[A]

[B]

[C]
[D]

Question75.
If

,then:

[A]

[B]

[C]

[D]

Question76.
If

,thenf(x)isequalto:

[A]

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[B]

[C]

[D]

Question77.
If

,thenzis:

[A]
[B]
[C]
[D]

Noneofthese

Question78.
If

,thenthevalueof

is:

[A]
[B]
[C]
[D]

Noneofthese

Question79.
Thegreatestandtheleastvaluesof
[A]
[B]
[C]
[D]

if

and

arerespectively:

31,19
25,19
31,25
Noneofthese

Question80.
Thevalueof

is:

[A]
[B]
[C]
[D]

Question81.
If
[A]
[B]

then

isequalto:

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[C]

[D]

Question82.
If

,thenkisequalto:

[A]
[B]
[C]
[D]

100
110

Question83.
ThreepositivenumbersformanincreasingG.P.IfthemiddleterminthisG.P.isdoubled,thennewnumbersareinA.P.Thenthe
commonratiooftheG.P.is:
[A]
[B]
[C]
[D]

Question84.
Apackcontainsncardsnumberedfrom1ton.Twoconsecutivelynumberedcardsareremovedfromthepackandthesumofthe
numbersontheremainingcardsis1224.Ifthesmallerofthenumbersontheremovedcardsisk,thenthevalueofkis:
[A]
[B]
[C]
[D]

15
20
25
30

Question85.
Thefundamentalperiodofthefunction
[A]

is:(wherecisaconstant)

[B]
[C]
[D]

Cannotbedetermined

Question86.
If

,then

isequalto:

[A]

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[B]

[C]

[D]

Question87.
Ifzisacomplexnumberofunitmodulusandargument

,then

isequalto:

[A]
[B]
[C]
[D]

Question88.
Let

beacomplexnumberwherexandyareintegers.Then,theareaoftherectanglewhoseverticesaretherootsofthe

equation
[A]
[B]
[C]
[D]

is:

48
32
40
80

Question89.
Thesumofintegersfrom1to100thataredivisibleby2or5is:
[A]
[B]
[C]
[D]

3600
3050
2500
3550

Question90.
Let

.Thenwhichofthefollowingnumbersisprime?

[A]
[B]
[C]
[D]

Noneofthese

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