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8. Polymers (8 pt)
An alternating copolymer has a number average molecular weight of 160 000 g/mol and a
number average degree of polymerization of 2500. If one of the mers is tetrafluorethylene,
identify which of the following polymers is the other mer: ethylene, propylene,
tetrafluorethylene and vinyl chlorine. Given: mstyrene = 104.14 g/mol, methylene = 28.05 g/mol,
mpolypropylene = 42.08g/mol, mtetrafluoroethylene = 100.02 g/mol, mvinyl chlorine = 62.49 g/mol.
(Hint: the mer molecular weight in alternating co-polymer of ababab. = 0.5 x ma + 0.5 x
mb)
Appendix
Useful Formulae
Hx
Hz
Hy
Hz
2G1 Q
Ur
1
V y uH
2
V 1 H
HT
ln 1 H
VT
KH Tn
U=
nO
V y2
nA / N A
Vc
a
2
k l
rate
Ae Q
t recrx
Ace Q RT
V o kyd
Hs
K 1V n
V fs
uH f
2d sin T
d hkl
Nv
Qv
N exp
RT
RT
1
E
10
W R V cos I cos O
2E
2
VT
Q
K 2V n exp
RT
V theoretical #
V y Vu
toughness |
H s
Vm
a
V o 1 2
Ut
Vm
a
2V o
Ut
Vc
2 EJ s
Sa
Vc
2 E J s J p
Sa
Vy
K
K
2Sr
f y T
YV Sa
K
B t 2.5 Ic
Vy
3F f L
2bd 2
6
V min
V max
WL
S
u 100
RS
WD
R
u 100
RS
CD Co
u 100
CD CL
Co CL
u 100
CD CL
D (T 0 T ) E
VA VB
Er ( t )
VAo VBo
RT X
ln
nF Y
EwA
U
Es
Us
Ec
Ec
E f V f E mVm
Em E f
EmV f E f Vm
x M
Mw
w M
DPn
nn
Mn
m
DPw
nw
Mw
m
Ff
E f / Em
=
Fc
E f / Em Vm / Vf
lc
Mn
V *f d
2W c
% crystallinity
Uc (Us Ua )
u 100
U s (Uc Ua )
Useful Constants
6fjmj
r d n
or r O n
Vt
U
Es
Us
Ff
Ef Vf
=
Fm
Em Vm
Q
rate of hardenig v exp
RT
Ewll
W
wu
wy
V t
Ho
R = 8.314 Jmol-1K-1
i.e. d { O
t
V o exp