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Performance &

Industrial Chemicals
Reference Guide

Solvents, Intermediates
& Surfactants

Vinyl Monomers

Performance Polymers

Specialty Chemicals
INTERNATIONAL SPECIALTY PRODUCTS

Performance & Industrial Chemicals


Reference Guide

Introduction

International Specialty Products is a specialty chemicals company that strives


to exceed our customers expectations by providing innovative technology,
performance-enhancing products, and exceptional service.
Integral to the current success of our above and beyond efforts is ISPs
exceptional technical service organization, which works directly with
formulation and application scientists. We keep abreast of market trends to
provide for our customers future needs.
With over 2,800 employees in more than ninety locations around the globe, ISP
serves such industries as adhesives, coatings, oilfield, digital printing,
electronics, HI&I, metallurgy and plastics - as well as other markets as diverse as
pharmaceutical, agricultural, food, beverage and personal care. Our more than
325 specialty chemicals, while sometimes representing a relatively small
portion of customers production costs, generally constitute key ingredients in
the end products in which they are used.
For more information visit us at www.ispcorp.com

Map Key
Regional Headquarters
Major Sales Office
Major Technical Service Labs
Manufacturing Facilities

Performance & Industrial Chemicals


Reference Guide

Contents

Introduction ................................................................................................2

Performance Polymers
PVP (Polyvinylpyrrolidone).......................................................................19
ViviPrint 540 ..........................................................................................21
PVPP (Polyvinylpolypyrrolidone)..............................................................21
Disintex Disintegrants ............................................................................22
ViviPrint PS-10.......................................................................................22
Vinylpyrrolidone Copolymers....................................................................23
Ganex/Antaron Copolymers..................................................................23
PVP/VA Copolymers..................................................................................24
Polectron/Antara 430 ...........................................................................25
Copolymers of Vinylpyrrolidone/Alkylaminomethacrylate and
Alkylaminomethacrylamide .....................................................................25
Copolymer and Gafquat..........................................................................26
Gafquat HS-100 ......................................................................................26
Styleze CC-10 .........................................................................................27
ViviPrint 121 & 131 ................................................................................27
Setleze 3000 ..........................................................................................27
Styleze W Series.....................................................................................27
Acrylidone 1005......................................................................................28
Styleze 2000 and Acrylidone LM..........................................................28
Vinylcaprolactam Polymers ......................................................................29
Copolymer VC-713 ....................................................................................29
Aquaflex SF-40 .......................................................................................30
ViviPrint 200 ..........................................................................................30
ViviPrint 300 ..........................................................................................31
Chromabond Dye Complexing Polymers ................................................31
Sorez 100 ...............................................................................................32
Aquazol Polymers ...................................................................................32
Gantrez Copolymers................................................................................33
Stabileze Rheology Modifiers .................................................................35
EasySperse Polymeric Dispersant ...........................................................35
I-Rez 160................................................................................................36
Aquaflex FX-64 .......................................................................................36
Aquaflex XL-30 .......................................................................................37

Contents.......................................................................................................4
Product Overview........................................................................................5
Solvents, Intermediates & Surfactants .....................................................6
Vinyl Monomers .......................................................................................6
Performance Polymers..............................................................................7
Specialty Chemicals ..................................................................................7
Solvents, Intermediates & Surfactants
Propargyl Alcohol .....................................................................................8
Butynediol................................................................................................8
Butenediol................................................................................................9
Butanediol................................................................................................9
THF (Tetrahydrofuran) ..............................................................................10
BLO Solvent.............................................................................................10
Pyrrolidones
2-Pyrol Solvent .......................................................................................11
M-Pyrol Solvent......................................................................................12
Other Alkylpyrrolidones
NEP Solvent........................................................................................12
HEP Solvent........................................................................................13
CHP Solvent........................................................................................13
Surfadone LP-100...................................................................................14
Surfadone LP-300...................................................................................14
Easy-Wet 20...........................................................................................15
Microflex Microemulsifier.......................................................................15
Engineered Solvents .................................................................................16
Vinyl Monomers
V-Pyrol Reactive Monomer .....................................................................17
V-Cap Reactive Monomer.......................................................................17
Rapi-Cure Vinylethers .............................................................................18

Specialty Chemicals
Silcron Silica Gels ....................................................................................37
Escalol UV Absorbers ..............................................................................38
Emulsifier, Dispersants and Lubricants .....................................................38
Carbonyl Iron Powders (Micropowder Iron) ............................................40
Iron Pentacarbonyl ...................................................................................40
Applications Chart.......................................................................................41a-c

Performance & Industrial Chemicals


Reference Guide

Product Overview

This brochure is organized into four categories representing major chemical


families of ISP products:

Solvents, Intermediates
& Surfactants

Solvents, Intermediates & Surfactants


Vinyl Monomers
Performance Polymers
Specialty Chemicals
We invite you to explore ISPs broad range of innovative products and the many
performance-enhancing properties they offer.

Vinyl Monomers

Performance Polymers

Specialty Chemicals

Performance & Industrial Chemicals


Reference Guide

Vinyl Monomers

Solvents, Intermediates
& Surfactants

The common characteristic of these chemicals is their ready solubility in


hydrophilic media.

Vinyllactams and vinylethers are offered for applications based on the utility of
their olefin linkage.

Propargyl Alcohol and Butynediol due to their high electron density of the
acetylenic bond function as metal complexing and corrosion inhibiting agents.
Butenediol, having a cis double bond enters into Diels-Alder Reactions and
Butanediol finds application as a plasticizer and humectant.
All four alcohols function as precursors to numerous derivatives such as
esters, carbamates, polyesters and urethanes.
Tetrahydrofuran is an inert solvent for numerous polymer and
organometallic reactions and is the precursor of polytetramethyleneglycol.
BLO (-Butyrolactone) is a polar solvent for ionic substrates and functions as
an acid donor in aqueous media at elevated temperatures.

V-Pyrol (N-vinyl-2-pyrrolidone) is water soluble and undergoes free radical


homo- and copolymerizations as well as grafting reactions. V-Pyrol RC is a
low viscosity reactive diluent for UV radiation curing processing.
V-Cap (N-vinyl-2-caprolactam) is only slightly soluble in water but can
function in many applications similar to V-Pyrol.
Fully-formulated UV-curable Gafgard Coating Systems impart abrasion and
solvent resistance to a wide variety of surfaces.
Rapi-Cure Vinylethers are produced with a variety of functionalities
imparting hydrophobicity or hydrophilicity, polarity, crosslinking capability,
rigidity or flexibility into coatings prepared by either cationic, charge transfer
or free radical polymerization.
The Rapi-Cure Vinylethers have low toxicity and are designed for UV
radiation curing applications.

Pyrrolidones: This family of chemicals varies in properties as a function of


substitution on the lactam nitrogen atom. All members are characterized by low
vapor pressure, high flash point, high dipole moment, ready complex formation,
surface activity as the alkyl chain lengthens and biodegradability when the alkyl
chain is linear.
2-Pyrol (2-pyrrolidone) the first member, is used as a humectant, cosolvent
with water, coalescent aid and plasticizer.
The lower alkyl pyrrolidones, most notably M-Pyrol (N-methyl-2 pyrrolidone),
are excellent polymer solvents, paint and photoresist strippers, paint
coalescents, industrial cleaners and extraction solvents.
The Surfadone alkyl pyrrolidones are hydrophobic in nature, functioning as
excellent wetting agents and effective dispersing and cleaning aids.
Engineered Solvents, based on M-Pyrol, are formulated to meet a variety of
industrial cleaning requirements.

Performance & Industrial Chemicals


Reference Guide

Specialty Chemicals

Performance Polymers

The largest family of polymers produced by ISP is based on N-vinyl-2-pyrrolidone.


These include PVP (polyvinylpyrrolidone) homopolymers and copolymers. The
latter contain functionality from co-reactants which include vinyl acetate,
PVP/VA; -olefins, Ganex/Antaron (1); dimethylaminoalkylene- methacrylate
or -methacrylamide copolymers and their derivatives make up the product lines,
Gafquat and ViviPrint copolymers, the latter polymer developed for ink jet
media coating; and styrene, Polectron/Antara 430 (2). We have recently added
the new Chromabond - vinylpyridine based polymers containing either
nitrogen oxide or betaine functionalities, and Aquazol - poly-2-ethyloxazoline
polymers. Many properties are shared among the groups, but each also has
unique characteristics, varying with structure, for example:

Ultraviolet Absorbers: The Escalol family of UV absorbers are high boiling,


water insoluble liquid esters with a broad absorption in the UV-B radiation
region (290 to 320 nm).

PVP, high polarity, dispersancy, hydrophilicity, adhesion, cohesivity and high Tg.
PVP/VA, thermoplasticity, oxygen permeability, varying hydrophilicity and
adhesion.
Ganex/Antaron, hydrophobicity, an emulsifier and dispersant for
nonaqueous systems.
Gafquat, basicity, substantivity, and high charge density.
ViviPrint, ink-binding, water resistance, high gloss and transparency, light
stability (fastness).
Polectron/Antara, thickening and opacifying emulsion.
Chromabond, dye complexation and soil anti-redeposition.
Aquazol, thermoplastic, hydrophilicity, adhesion, cohesivity, thermal and
shear stable and high decomposition temperature.

ISP also offers a wide variety of industrial biocides sold under the Nuocide,
Nuosept, Integra and Fungitrol tradenames and industrial alginates
(sodium, potassium, ammonium, and propylene glycol alginate) sold under the
Kelgin, Keltex, Manutex, Manucol and Collatex tradenames.

Emulsifiers, Dispersants and Lubricants: The Ceraphyl and Cerasynt


product line includes a variety of water insoluble esters and polyol-esters which
are useful as emulsifiers, dispersants, and lubricants.
Carbonyl Iron Powder: Micropowder Iron is characterized as fine, high purity,
micron size spherical particles with superior electronic and magnetic properties.

ISP Elastomers offers a full range of emulsion SBR (styrene-butadiene rubber)


for tires, industrial rubber products, adhesives and sealants.
Please contact your local sales office for additional information.

ISP also offers polymers based on V-Cap. These include vinylcaprolactam


homopolymers, copolymers with vinylpyrrolidone and terpolymers containing
both lactam monomers and dimethylaminoalkylene-methacrylate or
-methacrylamide. These polymers are generally more hydrophobic than the
V-Pyrol based products mentioned above, but offer many of the functional
properties inherent in the lactam ring. Among other applications, Inhibex
polymers are highly efficient as inhibitors of gas hydrate formation.
A range of alternating copolymers based on methylvinylether and maleic
anhydride are produced by ISP:
The Gantrez AN family of methylvinylether/maleic anhydride copolymers
are characterized by aprotic polar solvent solubility, reaction with protic
compounds such as water, alcohols and amines with facile film formation.
The hydrolyzed Gantrez S polycarboxylic acid resins function as dispersants,
divalent cation binding agents and polymeric acidifiers.

(1)
(2)

Ganex is sold as Antaron in Europe and Canada.


Polectron 430 is sold as Antara 430 in Europe and Asia Pacific.

Performance & Industrial Chemicals


Reference Guide

Solvents, Intermediates
& Surfactants

Propargyl Alcohol (2-propyn-1-ol)

Butynediol (2-butyne-1,4-diol)

Applications
Iron dissolution inhibitor in mineral acids.
Corrosion inhibitor during oil well stimulation and acid pickling.
Electroplating bath additive giving bright, uniform metal deposition without
film formation.
Precursor to Iodopropynylbutyl Carbamate (IPBC), a coating fungicide.

Applications
Iron dissolution inhibitor in mineral acids.
Corrosion inhibitor during acid pickling.
Nickel electroplating bath additive giving bright, uniform metal deposition
without film formation.
Oven cleaners.
Photoresist Strippers.

Physical Properties
Boiling point...................................................115C
Vapor pressure ................................................11.6mm Hg @ 20C
Flash point .....................................................35C
Freezing point.................................................-50C
Viscosity..........................................................1.6 cP @ 25C
Specific gravity ...............................................0.9485 @ 25C

Physical Properties
Boiling point...................................................238C
Vapor pressure ................................................2.5mm Hg @ 100C
Flash point .....................................................157C
Melting point..................................................54C
Specific gravity ...............................................1.17 @ 25C

Chemistry
There are three reactive sites in propargyl alcohol; the triple bond, methyne
hydrogen and hydroxyl group. The triple bond has a high electron density and
thereby an affinity for a number of industrially important metals. Both the methyne
and hydroxyl hydrogens can be substituted with appropriate chemical reagents.

Chemistry
Butynediol is commercially available as a solid or in 35% aqueous solution. The
triple bond in butynediol has a high electron density and an affinity for metals
similar to propargyl alcohol. The two hydroxyl groups undergo typical reactions
such as ethoxylation to produce Butoxyne 497, a 100% active liquid with a
melting point of approximately -15C.

Performance & Industrial Chemicals


Reference Guide

Solvents, Intermediates
& Surfactants

Butenediol (2-butene-1,4-diol)

Butanediol (1,4-butanediol)

Applications
Butanediol is used mainly as a co-monomer in classical diol-condensation
reactions with:

Applications
Diels-Alder reactions to produce Vitamin B-6, Endosulfan, etc.
Diacylation with bromoacetic acid to produce a paper slimicide.

Terephthalic acid to produce polybutylene terephthalate (PBT).


Diphenylmethane diisocyanate (MDI) yielding polyurethane foams, elastomers
and adhesives.
Adipic acid to yield polyesters with biodegradability characteristics.

Physical Properties
Boiling point...................................................234C
Flash point .....................................................135C
Freezing point.................................................7C
Viscosity..........................................................22 cP @ 25C
Specific gravity ...............................................1.07 @ 25C

In general, polymers produced from butanediol exhibit greater hydrophobicity,


crystallinity, strength, hydrolysis resistance and better low temperature
flexibility than those produced from ethylene glycol.

Chemistry
Butenediol, as produced by ISP, is 93-97% cis isomer, facilitating its use in 1,4addition reactions. The two hydroxyl groups undergo the typical reactions of
alcohols. Butenediol readily dehydrates to 2,3-dihydrofuran in the presence of
acids and polymerizes above 165C.

Physical properties of butanediol make it useful as a plasticizer and


humectant.
Physical Properties
Boiling point...................................................228C
Vapor pressure ................................................<0.075mm Hg @ 24C
Flash point .....................................................139C
Viscosity..........................................................71.5 cP @25C
Specific gravity ...............................................1.017 @ 25C
Chemistry
Butanediols reactive sites are its hydroxyl groups, which undergo all the typical
reactions of alcohols. In addition to the condensation reactions noted above, it
can be converted to simple esters, halides, dehydrated to tetrahydrofuran and
dehydrogenated to -butyrolactone.

Performance & Industrial Chemicals


Reference Guide

Solvents, Intermediates
& Surfactants

THF (Tetrahydrofuran)

BLO (-Butyrolactone)

Applications
Solvent for vinyl polymers used in PVC pipe adhesives, industrial cleaning,
magnetic tape coatings, vinyl fabric topcoats among others.
Reaction medium for organometallic reagents, including linear low density
polyethylene catalyst manufacture.
Monomer for polytetramethylene glycol, a Spandex intermediate.

Applications
Electrolyte dissociating solvent for nonaqueous capacitors.
Photoresist stripper.
Solvent for a wide spectrum of polymers and an effective substitute for
chlorinated hydrocarbons.
Paint strippers, industrial cleaners and lithographic developers.
Hydrolyzed in water at elevated temperatures to yield 4-hydroxybutyric acid,
leading to its use as an acid donor in nylon fiber dyeing.
Stabilizes urea in fertilizers.

Physical Properties
Boiling point...................................................66C
Vapor pressure ................................................161mm Hg @ 20C
Flash point .....................................................-14C
Freezing point.................................................-108.5C
Viscosity..........................................................0.5 cP @20C
Dipole moment...............................................1.75D
Specific gravity ...............................................0.886 @ 25C
Dielectric constant ..........................................7.52

Physical Properties
Boiling point...................................................204C
Vapor pressure ................................................0.16mm Hg @ 20C
Flash point .....................................................93C
Freezing point.................................................-44C
Viscosity..........................................................1.2 cP @25C
Dipole moment...............................................4.27D
Specific gravity ...............................................1.124 @ 25C
Dielectric constant ..........................................39.0

Chemistry
THF (stabilized with 250-400 ppm BHT) is an excellent polymer solvent,
combining rapid dissolution and evaporation with significant solubilizing
capacity for many high molecular weight polymers at moderate viscosity. It has
unique characteristics in Grignard and other organometallic reactions. As noted
above, THF undergoes an acid-catalyzed ring opening polymerization reaction to
produce polytetramethylene glycol.

Chemistry
Although BLO is stable under a wide range of conditions, at elevated
temperatures and in the presence of appropriate reagents, it serves as an
intermediate in a variety of useful syntheses, such as:
Precursor to 2-pyrrolidone and the extensive family of alkyl pyrrolidones
produced from ammonia and primary amines.
Reacting with phenols to yield phenoxybutyric acid derivatives with
applications in pharmaceuticals and as photographic coupling agents.

10

Performance & Industrial Chemicals


Reference Guide

Solvents, Intermediates
& Surfactants

2-Pyrol (2-Pyrrolidone)

Pyrrolidones
The family of 2-pyrrolidones offered by ISP has a variety of properties primarily
derived from the unique features of the lactam ring and modified by
substitution on the nitrogen atom. The general characteristics of these
compounds result from the polar N-C=O linkage in the five-membered ring. The
reactivity, physical properties and stability of these molecules results from the
well documented amide resonance. In anionic media, the partially positive
nitrogen readily coordinates with negatively charged species while in acidic
systems the electron-rich carbonyl oxygen is rapidly protonated.

Applications
Solubilization of complex organic molecules in water.
Humectant and cosolvent in digital printing inks.
Coalescent or plasticizer for acrylic resins, especially in floor polishes, inks
and adhesives.
Physical Properties
Boiling point...................................................245C
Vapor pressure ................................................<0.1mm Hg @ 20C
Flash point .....................................................129C
Freezing point.................................................25C
Viscosity..........................................................13.3 cP @ 25C
Dipole moment...............................................3.5D
Specific gravity ...............................................1.116 @ 25C
Chemistry
The reactive site of 2-Pyrol is its labile hydrogen on the nitrogen. It can undergo
vinylation with acetylene, alkylation with alkylhalides and acylation with acylhalides.
Hydrolysis in basic media produces -aminobutyric acid. It is also available as
95% active solution that freezes/solidifies at 12C to ensure ease of handling.

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Performance & Industrial Chemicals


Reference Guide

Solvents, Intermediates
& Surfactants

M-Pyrol (N-Methyl-2-Pyrrolidone)

NEP (N-Ethyl-2-Pyrrolidone)

Applications
Polymerization medium for polyethersulfones, polyaramids, polyesters,
polyamide-imides.
Polyamide-imide diluent for wire enamel coatings.
Paint and photoresist strippers.
Coalescent in latex paints allowing excellent formulation latitude.
Polydifluoroethylene solvent in rechargeable battery manufacture.
Industrial cleaners; neat or in combination with numerous other solvents.
Solvent for extraction of aromatics from lube oil.
Solvent for separation of acetylene and butadiene from light hydrocarbon streams.
High precision electronic cleaning agent.

Applications
Low temperature reaction solvent for temperature sensitive pharmaceutical
active ingredients.
Circuit board/defluxing/stencil cleaners - used as a co-solvent, usually in
combination with other water-soluble solvents such as glycol ethers or
tetrahydrofurfuryl alcohol and surfactants for removal of flux residues, oils
and greases. Used as an alternative for N-methyl-2-pyrrolidone.
Physical Properties
Boiling point...................................................200C
Vapor pressure ................................................0.2 mm Hg @ 20C
Flash point......................................................92.8C
Freezing point.................................................< -70C
Viscosity..........................................................3.5 cP
Specific gravity ...............................................0.993 @ 25C

Physical Properties
Boiling point...................................................202C
Vapor pressure ................................................0.27 mm Hg @ 20C
Flash point .....................................................90C
Freezing point.................................................-24C
Viscosity..........................................................1.7 cP @ 25C
Dipole moment...............................................4.06 Debye @ 25C
Specific gravity ...............................................1.027 @ 25C
Dielectric constant ..........................................32.2
Soluble in water and most organic solvents; sparingly soluble in aliphatic hydrocarbons.

Chemistry
M-Pyrol is extremely resistant to hydrolysis from pH 2-10, even at elevated
temperatures. Beyond these limits, hydrolysis to 4-(methylamino) butanoic acid
occurs at a rate dependent on pH and temperature. A large body of chemistry
has been developed on the reactions of strong nucleophiles with M-Pyrol. High
purity, low trace metal grades are sold under the Micropure and Pharmasolve
tradenames for the electronic and pharmaceutical industries.

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Performance & Industrial Chemicals


Reference Guide

Solvents, Intermediates
& Surfactants

HEP (N-Hydroxyethyl-2-Pyrrolidone)

CHP (N-Cyclohexyl-2-Pyrrolidone)

Applications
Photoresist Strippers - used as a co-solvent, usually in combination with
M-Pyrol (N-methyl-2-pyrrolidone) solvent, to enhance performance by
broadening solubility range.
Paint Strippers - as a solvent in high temperature stripping applications for
chemically resistance coatings.
Silk Screen Cleaners - as a co-solvent in cleaning formulations to enhance
removal of inks from silk screen fibers.
Hard Surface Cleaners - used as a co-solvent with glycol ethers in oven
cleaning formulations.
Intermediate for alkoxylated derivatives used in gasoline additives.

Applications
Photoresist Strippers - used as a co-solvent, usually in combination with
M-Pyrol (N-methyl-2-pyrrolidone) and BLO (-Butyrolactone) solvents, to
enhance performance by broadening solubility range.
Circuit Board Fabrication - used in chemical polishing of copper and copper
alloys to increase the stability of hydrogen peroxide in acid brightening baths.
Dye Carrier or Dyeing Bath Additive - used in dyeing of aromatic polyamide
fibers (i.e., Duponts Kevlar and Nomex, Teijins Conex) as a swelling/
diffusion agent to enhance dye and flame retardant penetration.
Paint Strippers - as a solvent in high temperature stripping applications for
chemically resistant coatings.
Silk Screen Cleaners - as a co-solvent in cleaning formulations to enhance
removal of inks from silk screen fibers.

Physical Properties
Boiling point...................................................295C
Vapor pressure ................................................<0.005 mm Hg @ 20C
Flash point......................................................160C
Freezing point.................................................20C
Viscosity..........................................................53 cP
Specific gravity ...............................................1.139 @ 25C

Physical Properties
Boiling point...................................................284C
Vapor pressure ................................................<0.005 mm Hg @ 20C
Flash point......................................................145C
Freezing point.................................................12C
Viscosity @ 25C..............................................11.5 cP
Specific gravity ...............................................1.026 @ 25C

13

Performance & Industrial Chemicals


Reference Guide

Solvents, Intermediates
& Surfactants

Surfadone LP-100 (N-Octyl-2-Pyrrolidone)

Surfadone LP-300 (N-Dodecyl-2-Pyrrolidone)

Applications
Soil penetrant and softener in hard surface cleaners, laundry prespotters and
metal cleaning.
Wetting agent for dishwashing, industrial and institutional cleaners.
Isopropyl alcohol replacement in fountain solutions.
Solvent for polymers and hydrophobic substances.
Pigment dispersion aid and pigment conditioning solvent.
Component of photoresist strippers.
Wetting agent for aqueous systems.
Component in microemulsifying systems.

Applications
High boiling solvent for polymers and hydrophobic substances.
Substitute for fluorocarbon surfactants used for oil well stimulation.
Additive in hand or automatic dish wash detergents.
Ingredient in pressure sensitive adhesives.
Physical Properties
Boiling point...................................................145C @ 0.2 mm Hg
Flash point......................................................116C
Freezing point.................................................10C
Viscosity..........................................................17 cP @ 25C
Minimum equilibrium surface tension............26 mN/m @ 20 ppm

Physical Properties
Boiling point...................................................100C @ 0.3mm Hg
Vapor pressure ................................................<0.001mm Hg @ 25C
Flash point......................................................113C
Freezing point.................................................-25C
Viscosity..........................................................8 cP @ 20C
Minimum equilibrium surface tension............28 mN/m @ 0.12%
Minimum dynamic surface tension.................35 mN/m @ 10 bubbles/sec

Chemistry
Surfadone LP-300 is sparingly soluble in water (0.002 weight percent) and
soluble in most organic solvents. It is a low foaming, nonionic surfactant with an
HLB of 3 and has no critical micelle concentration (CMC). Like its lower homolog,
Surfadone LP-300 interacts with anionic surfactants forming mixed micelles
which greatly enhances its solubility resulting in a synergistic surface tension
reduction and wetting enhancement. Appropriate combinations of Surfadone
LP-300 and anionic surfactants produce viscous solutions and gels.

Chemistry
Surfadone LP-100 is a low foaming, nonionic rapid wetting agent with an HLB
of 6 having no critical micelle concentration (CMC). Due to the electron
delocalized lactam ring, Surfadone LP-100 interacts with anionic surfactant
micelles. This greatly enhances its water solubility, resulting in a synergistic
surface tension reduction and wetting enhancement at low concentrations.

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Performance & Industrial Chemicals


Reference Guide

Solvents, Intermediates
& Surfactants

Easy-Wet 20

Microflex Microemulsifier

Applications
Hard surface cleaners.
Glass and tile cleaners.
Industrial and institutional cleaners.
Textile processing.
Pigment wetting.
Agricultural and industrial products.

Applications
Microemulsifier for hydrophobic active solubilization.
Delivers permethrin active in shampoos.
Preparation of stabilized silicones delivered from aqueous solutions.
Formulation of aqueous wood preservatives.
Dispersions of waxes and polishes.
Benefits
Optimized microemulsifier with particle sizes < 0.06.
High solvency for many hydrophobic water-insoluble organic chemicals
(active ingredients).
Concentrates prepared are compatible with high levels of emulsifiers
(anionic and non-ionic).

Benefits
Faster wetting.
Lower use levels.
Low contact angles.
Improved spreading on most surfaces.
Better equilibrium surface tension.
Enhanced cleaning performance.

Physical Properties
Physical form ..................................................Yellow liquid
pH...................................................................3.5
Viscosity..........................................................100-140 cP
Specific gravity @ 25C ...................................1.0-1.1

Physical Properties
Physical form ..................................................Clear liquid
pH (10 wt% aq.) .............................................4.0-6.0
Viscosity @ 25C..............................................15-30 cP
Specific gravity @ 25C ...................................0.92-0.95
Chemistry
Easy-Wet 20 is a proprietary super-wetting agent in a convenient to use liquid
form. Easy-Wet 20 is a cost-effective, premium wetter/surfactant suitable for
HI&I cleaning, textiles, pigments, agricultural and other industrial applications
where superior wetting and spreading performance is required.

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Performance & Industrial Chemicals


Reference Guide

Solvents, Intermediates
& Surfactants

Engineered Solvents Products

Engineered Solvents
ISP produces a family of Engineered Solvents based on M-Pyrol, which are
designed to meet the needs of specific cleaning operations. These include:
ShipShape, FoamFlush and PartsPrep, which are each recommended for
unique applications when M-Pyrol alone cannot meet certain cleaning
requirements. In addition to their excellent solvency, our Engineered Solvents
are formulated for low VOC and low toxicity. They are effective replacements for
methylene chloride, acetone, MEK and halogenated solvents.

Product

Uses

ShipShape Resin Cleaner

Cleaning and flushing fiberglass resins


from tools and equipment.
Two component epoxy cleanup
applications.
Low VOC cleanup solvent for paint and
resin manufacturers.

FoamFlush Urethane Remover Cleaning and flushing mixing heads, tools,


conveyors and molds of rigid and flexible
polyurethanes foams.
PartsPrep Degreaser
Metal degreasing and specialty optics
(sold as PartsReady in Europe) cleaning operations.

Engineered Solvents Properties


Physical Properties

ShipShape
Resin Cleaner

FoamFlush
Urethane Remover

PartsPrep
Degreaser

Physical form @ 25C

Light yellow
clear

Clear liquid

Clear liquid

1.07

1.05

1.03

Melting point F (C)

22.0 (-20.0)

22.0 (-20.0)

14.0 (-24.4)

Boiling point F (C)

396-399
(202-204)

396-399
(202-204)

396
(202)

Flashpoint F (C)

197 (91.7)

197 (88.3)

193 (89.4)

2.02

2.09

2.49

Density (g/ml)

Viscosity @ 25C (cP)

16

Performance & Industrial Chemicals


Reference Guide

Vinyl Monomers

V-Pyrol (N-Vinyl-2-Pyrrolidone)

V-Cap (N-Vinyl-2-Caprolactam)

Applications
Reactive diluent for radical initiated UV radiation curing used in vinyl
flooring, wood coatings, release coatings, inks, etc.
Numerous conventional polymerizations to generate an array of materials
with a variety of properties as noted in the following Polymer Section.
Gafgard 233, a formulated UV radiation curable coating containing V-Pyrol
RC and a multifunctional acrylate, is used to impart high levels of abrasion
resistance to coatings for plastic lenses, protective window films, credit cards, etc.

Applications
Reactive diluent for radical initiated UV radiation curing used in inks
(especially silk screening), vinyl flooring, wood coatings, release coatings, etc.
Conventional polymerizations to generate materials which have more
hydrophobic character than analogous V-Pyrol based products.
Gafgard 300, a formulated UV radiation curable coating containing V-Cap
RC and a multifunctional acrylate. It is used in applications similar to that of
Gafgard 233, but the resultant coatings are more hydrophobic.

Physical Properties
Boiling point...................................................193C @ 400 mm Hg
Melting point..................................................13C
Vapor pressure ................................................<0.10mm Hg @ 20C
Flash point......................................................96C
Viscosity..........................................................2 cP @ 25C

Physical Properties
Boiling point...................................................116C @ 10mm Hg
Melting point..................................................35C
Vapor pressure ................................................<0.1mm Hg @ 20C
Flash point......................................................114C
Viscosity..........................................................3.5 cP @ 40C

Chemistry
V-Pyrol is a clear liquid stabilized with insoluble sodium hydroxide or soluble
N,N-di-sec-butyl-p-phenylenediamine. The latter inhibitor is supplied in
V-Pyrol RC and V-Pyrol/Amine at concentrations of 25 ppm and at 100 ppm,
respectively for radiation curing and nonradiation curing applications. This
monomer is known to be a supercooled liquid well below its freezing point of
13C. It can remain as a liquid at room temperature for extended periods. Rapid,
exothermic crystallization under these conditions should not be confused with
bulk polymerization.

Chemistry
V-Cap is a pale yellow crystalline solid stabilized with 10 ppm N,N-di-sec-butyl
p-phenylenediamine having chemical reactivity characteristics similar to those
cited above for V-Pyrol. Polymers synthesized from V-Cap are significantly
more hydrophobic than their V-Pyrol analogs, but still exhibit the adhesiveness,
strength and complexing capability characteristic of the lactam functionality.
As with V-Pyrol, V-Cap is a super cooled liquid and can remain as a liquid at
room temperature for extended periods.

V-Pyrol RC accelerates UV curing rates as the reactive diluent; typically


formulated with an acrylate oligomer it imparts unique solution viscosity
reduction and enhanced adhesion to non-polar substrates. The activated double
bond of V-Pyrol facilitates its use in free radical homo- and copolymerizations
and grafting reactions. The products of these reactions are either linear or crosslinked homopolymers and nonionic, anionic and cationic copolymers. Polymers
from V-Pyrol are amorphous and the pyrrolidone ring imparts hydrophilicity,
adhesiveness, strength and complexing capability.

17

Performance & Industrial Chemicals


Reference Guide

Vinyl Monomers

Rapi-Cure Vinylethers

Applications
Reactive diluents for cationic, charge transfer and free radical radiation
curable coatings.
Co-monomers in specialty coating manufacture.
Effective in generating low surface energy release coatings.
Monomers for tackifying adhesives with varying properties.

Chemistry
Vinylethers can undergo three distinct types of polymerizations; cationic, charge
transfer or free radical.
Cationic Polymerization: The vinylether double bond is unusually electron rich
and forms rapidly polymerizing carbocations in the presence of initiators such as
Lewis and Bronsted Acids. These reactive intermediates are generated in
conventional and UV-curing vinylether homo- or copolymerizations.

Physical Properties
Properties of available commercial vinylethers

Charge Transfer Polymerization: The electron-rich vinylether double bond is


capable of forming charge transfer complexes with a variety of electrondeficient substrates. These copolymerizations can be carried out under either
ground state or photochemical reaction conditions. Typical examples of
electron-deficient olefins are maleates, fumarates and fluoroalkenes.

Rapi-Cure DVE-3 (Triethyleneglycol Divinylether)


Physical form ..................................................Clear, colorless liquid
Boiling point...................................................120-126C @ 18 mm Hg
Characteristics.................................................Difunctional, flexible backbone
Viscosity..........................................................2.6 cP

Free Radical Photopolymerization: Although vinylethers do not undergo


homopolymerization by free radical initiation, appropriately formulated
mixtures of acrylate oligomers and vinylethers can be useful UV-curing systems.

Rapi-Cure HBVE (4-Hydroxybutylvinylether)


Physical form ..................................................Clear, colorless liquid
Boiling point...................................................243C
Characteristics.................................................Dual functionality
Viscosity..........................................................5.4 cP

Rapi-Cure DVB1D (Butanediol Divinyl Ether)


Physical form ..................................................Clear, colorless lquid
Boiling point...................................................62-64C @ 10 mm Hg
Characteristics.................................................Difunctional, flexible backbone
Viscosity..........................................................4.3 cP

18

Performance & Industrial Chemicals


Reference Guide

Performance Polymers

PVP (Polyvinylpyrrolidone)
Applications
Dye transfer inhibition in detergents using K-15 and K-30 to complex fugitive
dyes in wash water.
Textile dye stripping and strike rate control through complexation and
dispersion with K-30.
Photoprocessing where sulfide salts are complexed by K-30 in developing
baths to inhibit redeposition on film.
Laundry detergents where K-30 inhibits soil redeposition.
Emulsion polymerization where K-30 latex stabilizer, functioning as a
protective colloid, facilitates redispersion of a brokenlatex end-use application.
Dispersions using K-30 and K-90 for nonaqueous dye and pigment-based
writing ink delivery systems.
Production of expandable polystyrene, with K-90 used as the protective colloid.
Polyvinylpyrrolidone and a number of its copolymers find use as media
components in digital ink jet printing.
Hollow fiber membrane manufacture in which K-90 and K-30 create voids
and hydrophilic domains in polysulfone membranes.
In oil field cementing, where K-30 and K-90 serve as fluid loss control agents.
On lithographic plates using hydrophobic inks, where K-15 provides
enhancement of the nonimage area.
K-85 and 90 in stearate-based adhesive sticks for arts and crafts applications.
Both ends of toilet paper rolls, utilizing K-60 as an adhesive.
In fiber glass sizing, using K-30 and K-90 film forming action to promote
polyvinylacetate adhesion.
As combustible ceramic binders, using K-30 and K-90 to enhance green strength.
In tablet binder formulations, where K-30 and K-90 are used for industrial
and pharmaceutical applications.
In CRT fabrication using negative photoresist technology, where K-90 is used
with a chemical crosslinker in water-based coating systems.
Production of electrolead hydrogels, where K-90 is crosslinked by E-beam
irradiation to produce a conducting medium.
As metal quenchant bath where K-60, K-90 and K-120 are effective thickeners.
The use of K-30 and K-90 for enzyme stabilization.
Production of nano-sized metal pigments.
Dispersant for carbon nano-fibers.

Polyvinylpyrrolidone is a hygroscopic, amorphous polymer supplied as a white,


free flowing powder, or in clear aqueous solution. Available in several molecular
weight grades, each characterized by K-value, it is used in various applications.

19

Performance & Industrial Chemicals


Reference Guide

Performance Polymers

PVP (Polyvinylpyrrolidone)
Physical Properties
Grade
K-15
K-30
K-60
K-85
K-90
K-120

K-Value Range
13-19
26-35
50-62
83-88
88-100
114-130

Chemistry
Polyvinylpyrrolidone can be plasticized with water and most common organic
plasticizers. It is considered to be physiologically inert. Applications take
advantage of one or more properties inherent in the polymer, typically due to
the lactam ring:

Molecular Weight (GPC/MALLS)


9,700
66,800
396,000
825,000
1,570,000
3,470,000

High Polarity and the resultant propensity to form complexes with hydrogen
donors, such as phenols and carboxylic acids, as well as anionic dyes and
inorganic salts;

Water absorbtivity.............................................~17% water @ 60% RH/20C


Glass transition temperature.............................Maximum 180C, increases with
Mw to Max. 180C
Film formation ..................................................Hard, glossy, transparent,
oxygen permeable
Film refractive index..........................................~1.53 @ 25C

Dispersancy, where components in a mixture are uniformly distributed through


the use of Polyvinylpyrrolidone;
Hydrophilicity, where the substantial water solubility of Polyvinylpyrrolidone is
its dominant feature and frequently a factor along with other properties
valuable to numerous applications;
Adhesion, taking advantage of the higher molecular weight Polyvinylpyrrolidones formulating in aqueous media, then evaporating sufficient water
to generate a solid product for the desired application; and

Solubility Characteristics
Soluble in water and most polar solvents.
Insoluble in esters, ethers, ketones and hydrocarbons.

Cohesivity, where cohesive strength is achieved through a variety of dry


blending and granulation techniques.

K-60, K-85 and K-120 are currently available only as aqueous solutions. All other
PVPs are available as dried powder or in solution.

Polyvinylpyrrolidone is cross-linkable to a water insoluble, swellable material


either in the course of vinylpyrrolidone polymerization, by addition of an
appropriate multifunctional comonomer, or by post-reaction; typically through
hydrogen abstraction chemistry.

20

Performance & Industrial Chemicals


Reference Guide

Performance Polymers

ViviPrint 540 (Polyvinylpyrrolidone)

PVPP (Polyvinylpolypyrrolidone)
PVPP is a highly cross-linked, amorphous, white free flowing polymer produced
through a unique proliferous (popcorn) polymerization. Although insoluble in
water, acids, bases and organic solvents, the polymers offered have swell
volumes of between 4 and 8 ml/g in water. PVPP strongly complexes with
phenols, such as tannins, flavonoids and dyes, adsorbing these compounds
within its interior cavities.

Applications
Digital printing media.
Oilfield shale stabilization.
Rheology modifier.
Physical Properties
Physical form ..................................................10-12% aqueous solution
Brookfield viscosity.........................................5,000-20,000 cps as supplied
650 cP @ 5% solids
Molecular weight............................................600,000-800,000 (GPC)
1,500,000-2,000,000 (MALLS)
Tg....................................................................174C
Chemistry
ViviPrint 540 is produced by a proprietary in-situ process resulting in a 2-phase
matrix consisting of soluble PVP and nanoscale PVP particles approximately 320
nm in size. This unique matrix allows for high viscosity, greater flexibility, better
adhesion, curl resistance and improved water-fastness in inkjet media as
compared to PVP K-90.

21

Performance & Industrial Chemicals


Reference Guide

Performance Polymers

Disintex Disintegrants

ViviPrint PS-10 ( Polyvinylpolypyrrolidone )

Applications
Tablet and granule disintegrants, high capillary activity and hydration capacity.
Physical Properties
Physical Properties

Disintex 75

Disintex 200

Disintex 600

Chemistry

PVPP

PVPP
inert salt

PVPP
inert salt/cellulose

Particle size

75

150

750

Use level

2%

2%

4-5%

Applications

Hard tablet
> 10 tons
Dishwashing
tabs

Applications
Digital print media.
Synergistic absorption effects with silica for both dye and pigment based inks.
Improve silica aqueous dispersions by reducing hard pack.
Dye binding pigment useful in non-aqueous coatings.

Hard tablet
Soft tablets
> 10 tons
< 3 tons
Dishwashing Laundry tabs
tabs
Water-softening
tabs

Chemistry
ViviPrint PS-10 is 100% PVPP with an average particle size of 15-30. The
hydroscopic nature of pyrrolidone enhances the ability of PS-10 particles to absorb
liquid rapidly, and its highly hydrophilic nature leads to rapid dispersion in water.

Chemistry
The Disintex series are propertiary blends of PVPP, cellulose and/or inert salts.
They are used extensively as disintegrants in laundry and dishwashing detergent
tablets, taking advantage of their high swell volumes. The cross-linked PVPP
homopolymers are highly hydrophilic and will rapidly absorb water on contact to
swell and create internal stress points that will break-up tablets.

22

Performance & Industrial Chemicals


Reference Guide

Performance Polymers

Ganex (Alkylated Polyvinylpyrrolidone)

Vinylpyrrolidone Copolymers

Sold as Antaron in Europe and Canada.

The copolymers of vinylpyrrolidone and a number of other vinyl monomers, are


described on the following pages. These products are used in applications that
benefit from both the unique characteristics of the pendant pyrrolidone ring in
combination with the properties of the co-monomers functionalities.

Applications
The Ganex family of Alkylated Polyvinylpyrrolidones are relatively low molecular weight
polymers varying in degree of hydrophobicity from water soluble powder (P-904LC) to
water insoluble flaked solid (WP-660) and are useful in the following applications:
Emulsifiers and dispersants in nonaqueous systems.
Desensitizer/wax dispersant in melt-cast explosives.
Dye dispersant for candles and shoe polish.
Water resistant film former in wood coatings.
Kinetic inhibitor against hydrate formation in oil field operations.
Oil pipeline dewaxer.
Pigment dispersant in solvent based coatings and inks.
Physical Properties

1
2

Product

Co-Polymer
Composition1

Tg/
Melting Pt.

Viscosity2

Supplied As:

Ganex
P-904LC

90% VP,
10% C4 -olefin

155C

14 @ 25Ca

White powder

Ganex
V-516

50% VP,
50% C16 -olefin

150C

300 @ 25Cb

55% actives in
IPA3

Ganex
V-216

20% VP,
80% C16 -olefin

Melting Pt.
8.5C

2500 @ 50Cc

Viscous liquid

Ganex
V-220

20% VP,
80% C20 -olefin

Melting Pt.
~35C

20M @ 80Cd

Wax

Ganex
WP-660

20% VP,
80% C30 -olefin

Melting Pt.
~63C

Flaked solid

VP= Vinylpyrrolidone, C4 -olefin= 1-butene, C16 -olefin= 1-hexadecene, C20 -olefin= 1-eicosene, C30 -olefin= 1-tricosene.
Brookfield, cP. a) RVT#2, 20rpm/10%solids; b) RVT#3, 20rpm/as is; c) RVT#2, 20rpm/neat; RVT# 5, 20rpm/neat.

Chemistry
Ganex resins are copolymers produced from -olefins and vinylpyrrolidone. The
alkyl component varies from a C-4 to C-30 moiety, in concentrations from 10 to
80%. The combination of vinylpyrrolidone and alkyl functionalities produce a
balance of dispersing and waterproofing capacity in the Ganex line of polymers.

23

Performance & Industrial Chemicals


Reference Guide

Performance Polymers

PVP/VA (Vinylpyrrolidone/Vinylacetate Copolymers)

Applications
PVP/VA copolymers produce transparent, flexible, oxygen permeable films
which adhere to glass, plastics and metals. These properties, coupled with the
ability to control their hydrophilicity through monomer composition, lead to
extensive industrial use:
Chemistry
Polyvinylpyrrolidone/vinyl acetate (PVP/VA) resins are linear, random
copolymers produced by the free-radical polymerization of the monomers in
ratios varying from 70/30 to 30/70 vinyl acetate to vinylpyrrolidone.

In remoistenable, hot melt adhesives.


In repulpable, pressure sensitive adhesives, where the water solubility of
S-630 facilitates recycling.
In a hot melt adhesive for a diaper wetness indicator system.
As a binder for dry film photoresists.
In solder masks utilizing aqueous processing.
Inkjet coatings improves print receptivity.

The PVP/VA copolymers are thermoplastic resins with molecular weights from
approximately 15M-60M. Their glass transition temperatures vary from 70 to
115C and hydrophilicity increases with vinylpyrrolidone content.
PVP/VA copolymers are available as white powders or clear solutions in ethanol,
isopropanol and water. Polymers in the four ranges of vinylpyrrolidone content;
30, 50, 60 and 70%, are produced in ethanol or isopropanol. The PVP/VA
copolymers with 60 and 70% vinylpyrrolidone content are available as solids or
as 50% aqueous solutions.

Physical Properties

PVP/VA Grades

Supplied As

~Mw

Glass Transition
Temp. of Copolymer
in C; low to high
Mw Range

In addition to being soluble in alcohols, the PVP/VA copolymers dissolve in esters


and ketones, but are insoluble in ethers and aliphatic hydrocarbons. The water
soluble PVP/VA copolymers exhibit a 5% aqueous cloud point, i.e. the 60%
vinylpyrrolidone content resin has a minimum critical solution temperature of 68C.

E-335, -535, -635, -735 50% Ethanol 29,000-57,000 69, 96, 106, 117
solution
I-335, -535, -735

50% IPA
solution

13,000-22,000 71, 89, 108

W-635, -735

50% Aqueous 15,000-27,000 99, 114


solution

S-630

Dry powder

51,000

110

24

Performance & Industrial Chemicals


Reference Guide

Performance Polymers

Polectron 430 (PVP/Polystyrene Latex)

Copolymers of
Vinylpyrrolidone/Alkylaminomethacrylate or
Alkylaminomethacrylamide

Sold as Antara 430 in Europe and Asia Pacific.


Applications
Polectron 430, with a glass transition temperature of approximately 100C,
gives transparent, thermoplastic films which readily adhere to glass, plastics
and metals. The emulsion, compatible with many polymers and surfactants, is
typically used as:
An opacifier and thickener for cleaning products.
Hydrophobic coating for ink jet recording media.
Oil resistant coatings.
Cold seal adhesive component.

Applications
These polymers have a number of unique properties, such as substantivity to
anionic materials, that make them useful as:

Chemistry
Polectron 430 is a white, thermoplastic, 38-41% solids, latex produced as a
graft, emulsion copolymer of 30% Polyvinylpyrrolidone and 70% styrene in the
presence of an anionic surfactant. The size distribution of the emulsion is such
that 90% of the particles are <0.5 micron with a maximum 25C viscosity of
750cps @ pH 2.0-5.0. Polectron 430 is thermally and mechanically stable in the
presence of a variety of ionic compounds. The viscosity is unaffected after three
freeze-thaw cycles between ambient and -20C, the emulsion is unbroken at
25C after 1/2 hr @ 10,000 rpm and does not coagulate on addition of 1%
hydrochloric acid, calcium chloride, alum or sodium borate.

Dye receptors in ink-jet and digital printing media.


Adjuvant for electrodeposition of copper in printed circuit board fabrication.
Chemistry
The copolymers of vinylpyrrolidone and dimethylaminoethylmethacrylate
(VP/DMAEMA, X=O, y=2) or vinylpyrrolidone and dimethylaminopropylmethacrylamide (VP/DMAPMA, X=N, y=3) are supplied as viscous solutions in either
water or ethanol. These polymers serve to a great extent as precursors for
cationic polymers through quaternization reactions on the pendant tertiary
amino function. These polymers are described on the following pages.

25

Performance & Industrial Chemicals


Reference Guide

Performance Polymers

Copolymer and Gafquat (Vinylpyrrolidone/


Dimethylaminoethylmethacrylate Copolymers)

Gafquat HS-100 (Vinylpyrrolidone/Methacrylamidopropyl


Trimethylammonium Chloride Copolymer)

Two VP/DMAEMA copolymers are quaternized with diethylsulfate producing


Gafquat 755/755N and Gafquat 734 which give transparent, glossy, tack free,
flexible films. The polymers are substantive to negatively charged surfaces and
compatible with anionic and amphoteric surfactants.

The copolymer of methacrylamidopropyltrimethyl-ammonium chloride


(MAPTAC) and vinylpyrrolidone, Gafquat HS-100 gives transparent, glossy,
tack free, flexible films. Presence of the amide linkage in the MAPTAC moiety
imparts greater hydrolysis resistance. Typical of this cationic polymer family,
Gafquat HS-100, is substantive to negatively charged surfaces and compatible
with anionic and amphoteric surfactants. (Material is not listed on the US EPA
TSCA inventory).

Physical Properties
Mw1

Product

Solution

Copolymer 845

20% H20

1,000,000 172C

20,000-70,000

Physical Properties

Copolymer 937

20% H20

1,000,000 104C

20,000-70,000

Product

Solution

Mw1

Copolymer 958

50% Ethanol

60,000- 100C
1,100,000
1,000,000 155C/
149C
60,000- 140C
110,000

60,000-90,000
Gafquat HS-100

20% H20

900,0001,200,000

Gafquat 755/755N 20% H20


Gafquat 734

50% Ethanol

Determined by GPC using polyethyleneoxide standard.

cP as is, @22-23C, RVT #7, 30 rpm.

Tg

Brookfield
Viscosity2

20,000-70,000
30,000-70,000

26

Determined by GPC using polyethyleneoxide standard.

cP as is, @22-23C, RVT #7, 30 rpm.

Tg

Brookfield
Viscosity2

184C 50,000-125,000

Performance & Industrial Chemicals


Reference Guide

Performance Polymers

Styleze CC-10, ViviPrint 121, 131 & Setleze 3000

Styleze W-10 & W-20 (Vinylpyrrolidone/Dimethylamino


propylmethacrylamide/Methacryloylaminopropyl Lauryl
Dimethyl Ammonium Chloride Terpolymer)

(Vinylpyrrolidone/Dimethylaminopropylmethacrylamide Copolymer)

Applications
Digital printing media (ViviPrint 121 and 131).
Settling agent for hard surface cleaner (Setleze 3000).
Physical Properties
Properties

Styleze CC-10

ViviPrint 121

pH (as is)

6.0-8.0

6.5-7.8

ViviPrint 131
& Setleze 3000
6.5-7.8

10,000-35,000

6,000-24,000

6,000-24,000

Viscosity (cP)
Mw
Nanoparticles
Neutralized
Tg

Applications
Thickener for strong acid formulations such as toilet bowl cleaners.
Inkjet receptive media.
Physical Properties
Physical form ..................................................Slightly hazy aqueous solution
% Solids..........................................................10% (W-10), 20% (W-20)
pH (as is).........................................................3.5-5.0
Viscosity..........................................................<5000 cP (W-10)
40,000-100,000 (W-20)
Molecular weight............................................2,700,000
Tg....................................................................135C

1,200,000-1,500,000 1,500,000-2,000,000 1,500,000-2,000,000


No

Yes

Yes

H2SO4
161C

H2SO4
167C

HCI
167C

Chemistry
These high molecular weight copolymers have a strong affinity for anionically
charged substrates, which can be further enhanced through quaternization. It
produces transparent, flexible high gloss coatings with improved water
resistant. Cross-linking significantly improves water resistance. Presence of the
amide linkage imparts greater hydrolysis resistance. Compatible with nonionic,
cationic and amphoteric surfactant, soluble in ethanol and water, insoluble
(Styleze CC-10) and partially soluble (ViviPrint 121/131 and Setleze 3000)
in acetone. ViviPrint and Setleze are produced by a proprietary in-situ process
resulting in a 2-phase matrix consisting of soluble copolymer and nanoscale
particles approximately 320 nm in size that impart improved water-resistance,
light fastness and curl resistance in digital media applications.

Chemistry
Styleze W polymers are random terpolymers of vinyl pyrrolidone,
dimethylaminopropyl methacrylamide and methacryloylaminopropyl lauryl
dimethyl ammonium chloride. They promote and stabilize foam through their
ability to reduce surface tension, excellent adhesion to high energy substrates
and are flexible, elastic, low tack and heat resistant films. Additional solution
viscosity improvements can be achieved by the addition of salts. (Material is not
listed on the US EPA TSCA inventory.)

27

Performance & Industrial Chemicals


Reference Guide

Performance Polymers

Acrylidone 1005 (Vinylpyrrolidone/Acrylic Acid


Copolymer)

Styleze 2000 & Acrylidone LM (Vinylpyrrolidone/


Acrylic Acid/Lauryl Methacrylate Terpolymer)

Applications
Inkjet coatings.
Membranes.
Rinse aids.

Applications
High efficacy styling gels.
Rinse aid in automatic dish detergent.
Metal quenching.
Ink jet receptive media.

Physical Properties
Physical form ..................................................White, free flowing powder
Molecular weight............................................120,000-150,000
Tg....................................................................143C

Physical Properties
Physical form ..................................................White, free flowing powder
Molecular weight............................................1,010,000
Tg....................................................................176C

Chemistry
Acrylidone 1005 is a random copolymer of vinyl pyrrolidone (25%) and acrylic
acid (75%). It forms transparent films that adhere to glass, plastics and metal. It
is soluble in alcohol/water blends, basic solutions, M-Pyrol (N-methyl-2pyrrolidone), propylene glycol and insoluble in ethers, esters, ketones, and
aliphatic and chlorinated hydrocarbons. It is water dispersible and cross-linkable.

Chemistry
Styleze 2000 is a high molecular weight, film forming anionic terpolymer
composed of Vinyl Pyrrolidone and Acrylate backbone with a hydrophobic
pendant C-12 chain. Styleze 2000 is insoluble in ethanol and water until
neutralized for easy dispersion. Exhibits synergistic thickening when combined
with associative rheology modifiers.

28

Performance & Industrial Chemicals


Reference Guide

Performance Polymers

Vinylcaprolactam Polymers

Copolymer VC-713 (Vinylpyrrolidone/Vinylcaprolactam/


Dimethylaminoethylmethacrylate Terpolymer)

Applications
Vinylcaprolactam derived polymers give hard, glossy transparent films with
excellent adhesive and cohesive properties. These products are also available
in 2-butoxyethanol for application as kinetic gas hydrate inhibitors. The
polymers also find use in many of the markets noted for polyvinylpyrrolidone.
In general, vinylcaprolactam imparts reduced water solubility and cloud point
relative to vinylpyrrolidone-based polymers, while enhancing the
hydrophobicity of the resin.

Sold as Gaffix VC-713 in North America.

Gas Hydrate Inhibitors


A range of V-Cap and V-Pyrol homo- and copolymers have been developed, in
a variety of solvents, to facilitate the uninterrupted flow in natural gas field
pipelines at the varying environments defined by brine content, temperature,
pressure, composition and residence time from field to collection point. They are
cited below as Inhibex polymers.

Applications
Gas hydrate inhibition.
Flocculating agent.
Film former in hair styling products.
Inkjet receptive media.

Physical Properties
Product

Monomer
Composition

Solution

Inhibex
101
Inhibex
301
Inhibex
501

100% VCL

50%
butoxyethanol
50%
butoxyethanol
50%
butoxyethanol

VCL/DEAEMA
50% VCL/
50% VP

Determined by GPC using polyethyleneoxide standard

Brookfield cP, as is, @25C, RVT #3, 20rpm

Mw1

Viscosity2

2-5x103

~2000

6-9x103

5-8x10

Physical Properties
Physical form ..................................................Viscous ethanol solution
Molecular weight............................................82,700
Tg....................................................................152C
Chemistry
Vinyl caprolactam imparts increased hydrophocity and reduces tack. Watersoluble film former, pseudo-cationic functionality, substantive to negatively
charged surfaces; Quaternization yields cationic polymer; Compatible with
anionic, nonionic and cationic surfactants, silicones and thickeners.

3000-6000

29

Performance & Industrial Chemicals


Reference Guide

Performance Polymers

Aquaflex SF-40 (Vinylcaprolactam/Vinylpyrrolidone/


Dimethylaminopropylmethacrylamide Terpolymer)

ViviPrint 200 (Vinylcaprolactam/Dimethylaminopropylmethacrylamide/Hydroxyethylmethacrylate Terpolymer)

Applications
Digital printing media.
Applications
Film forming polymer in hair styling products.

Physical Properties
Physical form ..................................................Slightly hazy, viscous
aqueous solution
% Solids..........................................................29-31
Viscosity..........................................................3,000-15,000 cP
Molecular weight............................................1,000,000-1,500,000
Tg....................................................................139C (freeze-dried)
pH...................................................................6.5-7.8

Physical Properties
Physical form ..................................................Clear viscous ethanol solution
Molecular weight............................................37,500
Tg....................................................................119C
Chemistry
Transparent, flexible glossy films; Pseudo-cationic, substantive to negatively
charged surfaces; Quaternization yields cationic polymer; Decreased tackiness
and improved hydrocarbon compatibility due to V-Cap; Water and ethanol
soluble. (Material is not listed on the US EPA TSCA Inventory)

Chemistry
ViviPrint 200 polymer is a terpolymer of V-Cap/DMAPMA/HEMA, neutralized
with HCl, specifically engineered to provide light fastness in formulated coatings
for inkjet media. Pseudo-cationic, substantive to negatively charged surfaces,
crosslinkable with azridine and glycidyl ether. When dried, forms flexible high
gloss films. Compatible with many nonionic, cationic and amphoteric chemicals.
Soluble in ethanol, isopropanol and water and compatible with PVOH, Aquazol
and gelatins.

30

Performance & Industrial Chemicals


Reference Guide

Performance Polymers

ViviPrint 300 (Dimethylaminopropylmethacrylamide/


Hydroxyethyl Methacrylate Copolymer)

Chromabond Dye Complexing Polymers

Chromabond S-100

Chromabond S-400

Applications
Dye transfer inhibitors
Hard surface cleaners.
Applications
Digital printing media.
Excellent adhesion to metal substrates.

Physical Properties
Physical Properties

Chromabond Chromabond Chromabond


S-100
S-400
S-403E

Physical Properties
Physical form ..................................................30% aqueous solution
(with <3% IPA)
% Solids..........................................................29-31
Viscosity..........................................................3,000-15,000 cP
Molecular weight............................................250,000-400,000
Tg....................................................................102C (freeze-dried)
pH...................................................................9.5-10.5

Physical form

Aqueous solution Aqueous solution Aqueous solution

% Solids

38-42

38-42

33-37

850

350

90

Molecular weight

35,000

28,000-32,000

9,000-17,000

pH (5% solution)

4-7

4-5

4-5

Viscosity (cP)

Chemistry
Chromabond vinylpyridine based polymers contain either nitrogen oxide (S400 and S-403) or betaine (S-100) functionalities. Chromabond is a new family
of premium dye transfer inhibitors (DTI), developed and used in color-safe
laundry detergents. Chromabond polymers demonstrate superior complexing
of fugitive dyes at cost effective levels, under different temperature and
surfactant environments. Its chemical structure promotes dye complexation up
to 60C, while resisting interaction with anionic surfactants. Chromabond
polymers are soluble in water and water-alcohol mixtures, but insoluble in most
other solvents.

Chemistry
ViviPrint 300 polymer is a copolymer of DMAPMA and HEMA specifically
engineered to provide improved dry times of formulated inkjet media where
high levels of organic solvents in inks impact unfavorably on dry times. Excellent
absorption of water and high solvent based inks, excellent dry times, excellent
adhesion to metallized substrates, excellent chelator and cross-linkable with
azridine or epoxides. Soluble in ethanol, isopropanol and water. Partially soluble
in acetone.

31

Performance & Industrial Chemicals


Reference Guide

Performance Polymers

Sorez 100 (Polyethylene Glycol Polyester Copolymer)

Aquazol (Poly-2-ethyl-2-oxazoline)

Applications
Soil release agent in laundry detergents, fabric softeners and pre and post
wash stain removers.
Ironing aid.
Physical Properties
Physical form ..................................................Slightly turbid amber liquid
% Solids..........................................................75-77%

Applications
Metal quenchants.
Adhesives.
Ceramic binders.
Fiberglass sizing.
Paper coatings.
Inkjet coatings.

Chemistry
Sorez 100 is a modified polyester copolymer concentrate in water-soluble
form. The product imparts wicking properties to hydrophobic textiles. It provides
soil release and anti-redeposition properties while reducing the electrostatic
charge of treated polyester. The polymer forms a thin film on the substrate,
enabling effective soil removal during subsequent wash cycles.

Physical Properties
Physical form ..................................................Off-white solids
% Active .........................................................100%
Specific gravity ...............................................1.14
Tg....................................................................69-71C
Chemistry
Aquazol is poly (2-ethyl-2-oxazoline) and is available in four molecular weight
grades ranging from 5,000 to 500,000. They are non-ionic and soluble in polar
organic solvents and water. They have good adhesive properties and excellent
temperature stability. The long polymer chains provide high molecular weights
with low viscosity solutions that do not degrade over time. Its excellent
thermoplasticity allows it to be used in plastic extrusions.

32

Performance & Industrial Chemicals


Reference Guide

Performance Polymers

Gantrez Copolymers
Physical Properties
Specific Viscosity1

Molecular Weight2

Gantrez AN-119

0.1-0.5

130,000

Gantrez AN-139

1.0-1.5

690,000

Gantrez AN-149

1.5-2.5

1,250,000

Gantrez AN-169

2.6-3.5

2,500,000

Grade

1% in MEK @25C, Cannon Fenske, Tube Size 100

SEC/LALLS detector

Reaction of the anhydride functional group with essentially any molecule


having an active hydrogenopens a wealth of opportunities to synthesize
useful derivatives.

Gantrez AN
(Polymethylvinylether/Maleic Anhydride) Copolymer

Chemistry
As produced, Gantrez AN copolymers contain alternating units of
methylvinylether and maleic anhydride. The fundamental character of this
polymerization requires a maleic anhydride unit must be adjacent to a
methylvinylether unit and vice versa, resulting in a true alternating copolymer.
As shown in the table above, Gantrez AN (anhydride form) is available in the
molecular weight range of 130M-2500M. The polymers are white, hygroscopic
powders soluble in tetrahydrofuran and M-Pyrol; insoluble in aliphatic and
halogenated hydrocarbons. All five grades cited have a glass transition
temperature of 151-154C, independent of molecular weight and form
transparent, tack-free films.

Applications
Because of their unique chemical structure and reactivities, Gantrez
Copolymers function well as:
Dispersants for fluorescent light phosphors.
Microcapsule clusterants in carbonless paper and latex systems.
Complex coacervates with gelatin to form the microcapsule wall in
carbonless paper.
Calcium encrustation inhibitors in laundry detergents.
Acid layers in diffusion transfer film to neutralize alkaline developers and dyes.
Intermediates in adhesive applications and liquid laundry detergent stabilizers.
Imide derivatives for anti-reflective layers on silicon wafers prior to
photoresist coating and light exposure.
Gas fade inhibitors for Spandex fibers.
Water retention aid in concrete.
Metal sequestrant.
Anionic polyacids.

33

Performance & Industrial Chemicals


Reference Guide

Performance Polymers

Gantrez S
(Poly(Methylvinylether/Maleic Acid) Copolymer)

Gantrez ES
(Poly(Methylvinylether/Maleic Acid) Half Esters Copolymer)

Applications
Calcium encrustation inhibitors in laundry detergents.
Dispersant aid.
Aluminum surface conditioning.
Diagnostic test strips.
Base-activated adhesive for peel apart instant film.

Applications
Pigment dispersants in cosmetic formulations.
pH dependent soluble films (enteric coatings).
Chemistry
Ethyl, isopropyl and n-butyl half esters are produced by opening up the
anhydride in alcohol. These polymers, based on AN-119, are sold as 50%
solutions in ethanol or isopropanol. They are water soluble when neutralized
greater than 40% using either an organic or inorganic base. Adhesive strength
can be adjusted through controlling the degree of neutralization. Films are
flexible, clear and glossy and have improved water resistance compared to
Gantrez S.

Chemistry
Gantrez S95S and S97 have repeating co-maleic acid units produced by
hydrolysis of Gantrez AN. The polycarboxylic acid derivatives with a pH of ~2 at
5% concentration are available either as viscous solutions or white powders. The
vicinal dicarboxylic acid functionality of these materials is useful in a number of
applications. The free acid forms are water-soluble, giving clear and tacky films.
Solution rheology can be modified by the addition of salts and bases.

Gantrez MS
(Poly(Methylvinylether/Maleic Acid) Mixed Salts Copolymer)
Applications
Bioadhesives.
Inkjet coatings.
Chemistry
Gantrez MS-955 is a mixed salt of sodium/calcium and is supplied as a
free-flowing powder. The copolymer is soluble in water and produces solutions
with high viscosity.

34

Performance & Industrial Chemicals


Reference Guide

Performance Polymers

Stabileze (Poly(Methylvinylether/Maleic Anhydride


Decadiene) Crosspolymer)

EasySperse Polymeric Dispersant (Poly(Methylvinylether/Maleic Acid) -Butyl Ethyl Ester, Sodium Salt)

Applications
Stabileze rheology modifiers yield clear, aqueous gels that are shear thinning
and slightly thixotropic, having good shear, temperature and UV-A radiation
stability. Stabileze is effective as a rheology modifier for:
Applications
Dispersant for hydrophobic insectides, fungicides, herbicides.
Dispersant for hydrophobic organic compounds (fragrances, emollients,
essential oils, etc.).

Thickener.
Coatings and inks.
Sealants.
Electroconductive gels.
Deicing fluids.
Pigment dispersant.

Chemistry
EasySperse dispersant is a copolymer of the monobutyl/ethyl ester of poly
(methyl vinyl ether/maleic acid) partially neutralized with sodium hydroxide. The
material is supplied as a 25% aqueous solution and is an excellent film former.

Chemistry
Stabileze is produced in a manner similar to that of Gantrez AN but with the
added monomer decadiene present to yield a crosslinked, water swellable resin.
The polymer is a white, free-flowing powder with a glass transition temperature
of approximately 150C. The powder is available in two particle sizes; < 850
microns (Stabileze 06) and < 75 microns (Stabileze QM). The solid can be
dispersed in water without coagulating and the anhydride function will
hydrolyze directly or through the action of base. A neutralized 0.5% solution in
water at pH 7 and 25C has a viscosity range of 45,000-70,000 cP.

35

Performance & Industrial Chemicals


Reference Guide

Performance Polymers

Aquaflex FX-64 (Isobutylene/Ethylmaleimide/


Hydroxyethylmaleimide Copolymer)

I-Rez 160 (Isobutylene/Maleic Anhydride Copolymer)

Physical Properties
Physical form ..................................................Free flowing white powder
Molecular weight............................................78,000-94,000
Tg....................................................................164C

Applications
Film former.
Adhesive/cohesive properties.

Chemistry
I-Rez 160 is a linear, alternating copolymer of isobutylene and maleic
anhydride that forms transparent, tack free films and reacts with alcohols/
amines to yield half esters/amides. Soluble in aprotic solvents, forms gels with
ketones and esters. Water solubility control by degree of neutralization.
Insoluble in alcohol and aliphatic hydrocarbons.

Physical Properties
Physical form ..................................................Yellow viscous liquid.
Molecular weight............................................39,000
Tg....................................................................135C
Chemistry
Aquaflex FX-64 is an imidized isobutylene/maleic anhydride copolymer that
produces low tack, glossy films supplied as 40% hydroalcoholic solution.
(Material is not listed on the US EPA TSCA inventory)

36

Performance & Industrial Chemicals


Reference Guide

Specialty Chemicals

Performance Polymers

Aquaflex XL-30 (Isobutylene/Dimethylaminopropyl


maleimide/Ethoxylatedmaleimide/Maleicacid Copolymer)

Silcron Silica Gels


Silcron silica gels have high chemical purity, so compatibility with other formula
components is not a problem. Silcron silica gels are versatile enough to be used
in a wide range of narrow and wide format inkjet media formulations including
those based on paper, vinyl, foil coatings, wallpaper, art canvas and others.
Applications
Specialty absorbent in ink jet media.
Matting agent in industrial coatings, printing inks, and plastics.
Anti-block and anti-plate out agent in plastic films.
Anti-setoff and anti-block agent in printing inks.
Moisture scavenger in metallic pigmented industrial coatings.
Skid resistance in printing inks.
Rheology modifier in liquids.
Carrier/conversion of liquids to flowable powders.
IJ grades exhibit high gloss in polymer inkjet coatings.

Applications
Film former, flexible coating with low coefficient of friction.
Physical Properties
Physical form ..................................................Straw-like hazy, viscous
aqueous solution.
Molecular weight............................................86,000

Physical Properties
Properties

Chemistry
Aquaflex XL-30 is an isobutylene dimethylaminopropylmaleimide/ethoxylated
maleimide/maleic anhydride copolymer that produces highly flexible, glossy
and humidity resistant films and forms clear gels with anionic rheology
modifiers. (Material is not listed on the US EPA TSCA inventory)

Silcron
G-100 G-601 G-602 G-650 G-860 G-900 IJ-25 IJ-50

Supplied as

37

Amorphous silica gels

30% solution

Pore volume
(ml/g)

1.5

1.2

1.2

1.2

1.6

0.6

Surface area
(m2/g)

260

290

280

290

340

715

125

50

Median particle size


(Malvern, microns)

5.5

7.0

9.5

4.3

6.0

8.0

0.025 0.050

pH
(5% aq slurry)

7.5

7.0

7.0

7.0

4.0

2.5

3.5

3.5

Oil absorption
(g/100g)

280

210

210

220

300

70

Loss on drying
(at 105C, % max)

4.5

3.5

3.5

3.5

4.5

3.2

Performance & Industrial Chemicals


Reference Guide

Specialty Chemicals

Escalol UV Absorbers

Emulsifiers, Dispersants & Lubricants

ISP offers a number of UV absorbers for industrial applications under the


Escalol trademark. The three octyl-esters; Escalol 557, 587 and 597 are high
boiling, water insoluble liquids, have strong and broad absorption in the UV-B
region between 290-320 nm and refractive indices in the range of 1.50-1.55. The
benzophenone derivatives; Escalol 567 and 577, are solids also having
absorbance in the UV-B region.

ISP has a broad family of water insoluble esters and hydroxyesters sold under the
Ceraphyl and Cerasynt trademarks as lubricants, dispersants and emulsifiers.
These chemicals typically are surface active and find use in HI&I, plastics, textile,
photography, inks and coatings markets. A variety of esters are available with a
range of properties, including liquids and waxy solids. In addition, amide and
quaternary-ammonium salts are available.

Physical Properties
Product

A representative group of this product line is shown on the following page.


Chemical Name

Boiling or Melting Point

Escalol 507

2-Ethylhexy-pdimethylaminobenzoate

Bp 362C

Escalol 517

1-(4-Methoxyphenyl)-3-(4-terbutylphenyl) propan-1,3-dione

Escalol 557

2-Ethylhexyl-pmethoxycinnamate

Escalol 567

2-Hydroxy-4methoxybenzophenone

Mp 62C min.

Escalol 577

5-Benzoyl-4-hydroxy-2methoxybenzene sulfonic acid

Mp >120C

Escalol 587

2-Ethylhexyl salicylate

Bp 150C @ 3mm Hg

Escalol 598

2-Ethylhexyl 2-cyano-3,3diphenylacrylate

Bp 218C @ 1.5mm Hg

Bp 198-200C @ 3 mm Hg

38

Performance & Industrial Chemicals


Reference Guide

Specialty Chemicals

Product

Chemical Name

Applications

Ceraphyl 28

Hexadecyl lactate

Tissue paper lotion


Printing plate protection

Ceraphyl ODS

Octyldodecyl stearate

Ceraphyl RMT

Castor oil monomaleate

Ceraphyl 31

Lauryl lactate

Tissue paper lotion

Ceraphyl SLK

Isodecyl neopentanoate

Ceraphyl 41

C12 - C15 Alkyl lactate

Plasticizing effects

Cerasynt 303

Ceraphyl 45

Bis (2-ethylhexyl) malate

Ceraphyl 50

Tetradecyl lactate

Dispersant aid for


electroluminescent devices
Viscosity regulator in laundry
detergents

Diethylaminoethyl
stearate
Polyoxyethylene (20)
stearate

Ceraphyl 55

Tridecyl neopentanoate

Ceraphyl 140

Decyl oleate

Ceraphyl 140A

Isodecyl oleate

Ceraphyl 230

Diisopropyl adipate

Ceraphyl 368

2-Ethylhexyl palmitate

PVC plasticizer
Textile finishing surfactant
O/W emulsions
Plasticizing effects
Lubricant
Hard surface cleaners
Erasable markers
Mold release agent
Inkjet inks
Circuit board cleaning
Hard surface cleaners
Tissue paper lotion
Lubricant

Ceraphyl 375

Isostearyl neopentanoate

Pigment dispersion

Ceraphyl 424

Tetradecyl
tetradecanoate

Hard surface cleaner


Dispersant in magnetic
Recording media

Ceraphyl 494

Isocetyl stearate

Ceraphyl 791

Isocetyl stearoyl stearate

Ceraphyl 847

Octyldodecyl stearoyl
stearate

Ceraphyl CE

Cetyl esters

Ceraphyl GA-D

Maleated soybean oil

Ceraphyl ICA

Isohexadecanol

Cerasynt 840

Polycarbonate mold release agent

Inkjet inks, pigment


dispersions
X-ray contrast compositions
Hard surface cleaner
Fabric softening compositions
Degreasing detergents
Anti-fogging agent
Polyamide fiber lubricant
Fiber finishing
Metal working fluids
Circuit board defluxing
Detergents

Cerasynt GMS

Glyceryl monostearate

Cerasynt 945

Glyceryl stearate and


polyoxyethylene lauryl
ether

Cerasynt D

Stearic monoethanolamide
stearate
2-Hydroxyethyl stearate
Opacifier and pearlizing agent
and ethylene glycol
2-Hydroxyethyl stearate, Opacifier and pearlizing agent
sodium laureth sulfate and
hexylene glycol

Cerasynt IP
Cerasynt LP

Inkjet inks, pigment dispersion

Cerasynt M

2-Hydroxyethyl stearate

Pearlizing agent
Liquid detergent compositions

Pigment dispersions

Cerasynt MN

Anti-fogging agent

Pigment dispersions
Polycarbonate mold release agent

2-Hydroxyethyl stearate
and potassium stearate

Cerasynt PA

Propylene glycol
monostearate

Hard surface cleaners


Asphalt microdispersions
Circuit board defluxing detergents

Cerasynt SD

Glyceryl stearate

Pigment dispersions
Mold release
Graffiti removal
Polyester finishing agent

39

Performance & Industrial Chemicals


Reference Guide

Specialty Chemicals

Micropowder Iron
Carbonyl Iron Powder (Fe)

Iron Pentacarbonyl (Fe(CO)5)

Applications
Carbonyl iron powder is manufactured by the chemical decomposition of iron
pentacarbonyl. The resulting iron particles are uniform gray microscopic spheres
with only traces of carbon, oxygen, and nitrogen. Over 25 different grades of iron
powder are manufactured through this process and marketed under the
tradename Micropowder. Specific applications include:

Applications
Iron pentacarbonyl is an intermediate that has found utility in a variety of
applications. In the past, it has been used as a fuel antiknock agent, a
photochemical additive and an intermediate for many iron products. The most
important current applications are:
Catalyst: for coal liquefaction, Fischer-Tropsch hydroformylation, olefin
isomerization, and water gas shift reactions.
Precursor: for chemically pure iron, iron oxides, iron catalysts and thin iron films.
Desulfurization: removal of sulfur from coal and petroleum products.

Radar absorbing materials (RAM).


Precision electronic cores.
Electromagnetic interference shielding products (EMI/RF).
Metal Injection molding (MIM).
High performance powder metallurgy products.
Magnetic fluids.
Halogen solvent waste remediation.
Pharmaceutical Iron supplement (Ferronyl Iron)

Physical Properties
Boiling point...................................................103C
Melting point..................................................-20C
Specific gravity ...............................................1.453

Physical Properties
The fine size and high purity of the carbonyl iron powders are the principal
reasons for their superior properties compared to other forms of elemental iron
powders. Distinct characteristics of the Micropowder Iron products include:

Chemistry
Iron pentacarbonyl is a specialty chemical that is produced as an intermediate
during the manufacture of carbonyl iron powders. It is produced from a high
pressure reaction between high grade iron and carbon monoxide. This
organometallic compound exists as a liquid at room temperature. It may ignite
spontaneously in air and is decomposed by heat to metallic iron and carbon
monoxide. In air it decomposes to iron oxides, and in sunlight to iron
nonacarbonyl. While Fe(CO)5 is highly reactive, it is stable in dark storage under
nitrogen. It is soluble in common organic solvents such as acetone or toluene
and insoluble in water or liquid ammonia. It is unreactive with most acids.

Very fine spherical size.


Submicron to 10 micron particle diameter.
High purity with up to 99.5% iron content.
Unique onionskin structure with cubic crystalline lattice.
Superior electromagnetic properties.
Uniform particle size distribution.
Chemistry
In terms of fundamental properties there are two product families, the S
grades and R grades. The S grades are standard iron grades with a purity level
of approximately 97.5%. The impurity is comprised of carbon, oxygen, and
nitrogen and is the cause of the iron particles unique onionskin structure.
R grades are higher purity iron grades with an average purity of 99.5%. Through
a hydrogen reduction process most of the residual carbon and nitrogen have
been removed from the iron particle producing a higher purity iron grade which
is lower in durometer hardness and lacking the unique onionskin structure.

40

Performance & Industrial Chemicals


Reference Guide

Application Chart

Coatings
&
Adhesives

HI&I/Textiles

Metallurgy

Oil/Chemical

Plastics

Electronics

Printing/Inks

Miscellaneous

Adhesives
Coatings, Industrial
Coatings, Specialty & Imaging
Paints/Latex Systems
Radiation Curing (RC)
Detergents
Fiber Dyeing
Industrial & Institutional Cleaners
Surface Cleaners
Textile Processing
Tabletting
Acid Pickling
Electroplating
Metal Cleaners
Metal Quenchants
MIM/PM Products
Precision Electronic Cores
Catalysts
Gasoline & Oil Additives/Processing
Oil/Gas Well Maintenance
Petrochemical Processing
Reaction Solvent
Polymer Intermediate
Polystyrene Manufacture
Battery Manufacture
Radar Absorbing Material
EMI/RF Shielding
Photo-Resist Processing
Printed Circuit Boards
Lithographic Developers
Paper Manufacture
Printing Inks
Dispersants
Gel Former
Paint Stripper
UV Absorbers
Lubrication
Emulsification
Membranes

41a

ShipShape Resin Cleaner

Microflex Microemulsifier

Easy-Wet 20

Surfadone LP-300

Surfadone LP-100

CHP (N-Cyclohexyl-2-Pyrrolidone)

HEP (N-(2-Hydroxyethyl)-2-Pyrrolidone)

NEP (N-Ethyl-2-Pyrrolidone)

M-Pyrol (N-Methyl-2-Pyrrolidone)

2-Pyrol (2-Pyrrolidone)

BLO

THF (Tetrahydrofuran)

Butanediol

Butenediol

Butoxyne 497

Butynediol

The following table is a cross-reference of the ISP


products cited throughout the text and their uses
in a wide variety of industrial applications.

Propargyl Alcohol

Solvents, Intermediates & Surfactants

41b

Copolymer VC-713

V-Cap Polymers

Styleze 2000

Acrylidone 1005

Styleze W-10 & W-20

Setleze 3000

ViviPrint 121 & 131

Styleze CC-10

Gafquat HS-100

Gafquat 734, 755 & 755N

Vinyl Monomers

VP Alkylamino Copolymers

Polectron / Antara 430

PVP/VA Copolymers

Ganex / Antaron Polymers

ViviPrint PS-10

PVPP (Polyvinylpolypyrrolidone)

ViviPrint 540

PVP (Polyvinylpyrrolidone)

Rapi-Cure Vinyl Ethers

Gafguard 233 & 300

V-Cap/RC

V-Pyrol/RC & non-RC

PartsPrep Degreaser

FoamFlush Urethane Remover

Performance & Industrial Chemicals


Reference Guide

Performance Polymers

Performance & Industrial Chemicals


Reference Guide

Application Chart

Iron Pentacarbonyl

Carbonyl Iron Powders

Ceraphyl & Cerasynt Emulsifiers

Escalol UV Absorbers

Silcron Silica Gels

Aquaflex XL-30

Aquaflex FX-64

I-Rez 160

EasySperse Dispersant

Stabileze Rheology Modifier

Gantrez Copolymers

Aquazol Polymers

Sorez 100

Chromabond S-100, S-400 &S-403E

ViviPrint 300

ViviPrint 200

Aquaflex SF-40

Specialty Chemicals

The information contained in this brochure and


the various products described are intended for
use only by persons having technical skill and at
their own discretion and risk after they have
performed necessary technical investigations,
tests and evaluations of the products and their
uses. While the information herein is believed to
be reliable, we do not guarantee its accuracy and
a purchaser must make its own determination of
a products suitability for purchasers use, for the
protection of the environment, and for the health
and safety of its employees and the purchasers of
its products. Neither ISP nor its affiliates shall be
responsible for the use of this information, or of
any product, method, formulation, or apparatus
described in this brochure. Nothing herein waives
any of ISPs or its affiliatesconditions of sale, and
WE MAKE NO WARRANTY, EXPRESS OR IMPLIED,
OF MERCHANTABILITY OR FITNESS OF ANY
PRODUCT FOR A PARTICULAR USE OR PURPOSE.
We also make no warranty against infringement
of any patents by reason of purchasers use of any
information, product, method or apparatus
described in this brochure.
Trademark registration applied for
Registered trademark of the ISP group
International Specialty Products. 2005
Aquazol is a registered trademark of Polymer
Chemistry Innovations Inc. The products are
marketed and sold exclusively by ISP globally for
industrial applications.
Silcron is a registered trademark of Millennium
Specialty Chemicals Inc., a Lyondell Company.
WORLD HEADQUARTERS
International Specialty Products
1361 Alps Road, Wayne, New Jersey 07470, USA
Tel: +1 973 628-4000
Fax: +1 973 628-3311
www.ispcorp.com

INTERNATIONAL SPECIALTY PRODUCTS

41c

Performance & Industrial Chemicals


Reference Guide

The information contained in this brochure and the various products described are
intended for use only by persons having technical skill and at their own discretion and
risk after they have performed necessary technical investigations, tests and
evaluations of the products and their uses. While the information herein is believed to
be reliable, we do not guarantee its accuracy and a purchaser must make its own
determination of a products suitability for purchasers use, for the protection of the
environment, and for the health and safety of its employees and the purchasers of its
products. Neither ISP nor its affiliates shall be responsible for the use of this
information, or of any product, method, formulation, or apparatus described in this
brochure. Nothing herein waives any of ISPs or its affiliatesconditions of sale, and WE
MAKE NO WARRANTY, EXPRESS OR IMPLIED, OF MERCHANTABILITY OR FITNESS OF ANY
PRODUCT FOR A PARTICULAR USE OR PURPOSE. We also make no warranty against
infringement of any patents by reason of purchasers use of any information, product,
method or apparatus described in this brochure.
Trademark registration applied for
Registered trademark of the ISP group
International Specialty Products. 2005
Aquazol is a registered trademark of Polymer Chemistry Innovations Inc. The
products are marketed and sold exclusively by ISP globally for industrial applications.
Silcron is a registered trademark of Millennium Specialty Chemicals Inc.,
a Lyondell Company.
For more information visit us at www.ispcorp.com

43

GLOBAL LOCATIONS FOR SALES & CUSTOMER SERVICE


WORLD HEADQUARTERS
INTERNATIONAL SPECIALTY PRODUCTS

INTERNATIONAL SPECIALTY PRODUCTS

1361 Alps Road, Wayne, New Jersey 07470, USA


Tel: +1 973 628-4000 Fax: +1 973 628-3311
www.ispcorp.com info@ispcorp.com

CUSTOMER SERVICE:
Toll Free: 1 (800) 622-4423
Fax: +1 973 628-4001
info@ispcorp.com

SAMPLE CENTER:
Toll Free: 1 (800) 243-6788
isp@chemicalmarketing.com

PERFORMANCE CHEMICALS
WAYNE, NEW JERSEY
Tel: +1 973 628-3169
Fax: +1 973 628-4117
acalvani@ispcorp.com

FOOD INGREDIENTS
SAN DIEGO, CALIFORNIA
Toll Free: 1 (888) 472-5446
Fax: +1 619 557-3128
foodinfo@ispcorp.com

USA & CANADA REGIONAL SALES OFFICES


PERSONAL CARE
LOMBARD, ILLINOIS
Toll Free: 1 (800) 323-2272
Tel: +1 630 932-4022
Fax: +1 630 495-0245
jdressler@ispcorp.com

PHARMACEUTICALS
WAYNE, NEW JERSEY
Toll Free: 1 (877) 389-3083
Fax: +1 973 628-4117
emitchell@ispcorp.com

PERSONAL CARE
SHERMAN OAKS, CALIFORNIA
Toll Free: 1 (800) 505-8984
Fax: +1 818-906-3504
ujenkins@ispcorp.com

CANADA
Tel: +1 905 607-2392
Toll Free: 1 (800) 465-5094
Fax: +1 905 607-9086
adumancic@ispcorp.com

LATIN AMERICA CUSTOMER SERVICE


ARGENTINA
Tel: + 54 11 4314-8971
+ 54 11 4314-0659
+ 54 11 4314-3293
Fax: + 54 11 4314-8976
ispargentina@ispcorp.com

BRAZIL
Tel: + 55 11 3649-0469
+ 55 11 3649-0477
Fax: + 55 11 3835-4212
ispbrasil@ispcorp.com

COLOMBIA
Tel: + 57 (1) 636-0618
Fax: + 57 (1) 691-8540
ldiaz@ispcorp.com

MEXICO
Tel: + 52 55 5276-6110
Fax: + 52 55 2614-2939
isp_mexico@ispcorp.com

VENEZUELA
Tel: + 58 212 991-4545
+ 58 212 992-9703
+ 58 212 991-7775
Fax: + 58 212 991-9705
dnelson@ispcorp.com

TURKEY & MIDDLE EAST


Tel: +90 (0) 216 485-0972
Fax: +90 (0) 216 485-0973
info.turkey@ispcorp.com
info.middleeast@ispcorp.com

EUROPE, MIDDLE EAST & AFRICA CUSTOMER SERVICE


AFRICA
Tel: +49 (0) 2236 9649-237
Fax: +49 (0) 2236 9649-212
info.africa@ispcorp.com

CZECH REPUBLIC
Tel: +420 (0) 2 72 123-332
Fax: +420 (0) 2 72 123-305
info.czech@ispcorp.com

HUNGARY
Tel: +36 (0) 1 385-8288
Fax: +36 (0) 1 466-2550
info.hungary@ispcorp.com

POLAND
Tel: +48 (0) 22 556 25 20
Fax: +48 (0) 22 556 25 22
info.poland@ispcorp.com

AUSTRIA
Tel: +43 (0) 1 360 27-71220
Fax: +43 (0) 1 360 27-71221
info.austria@ispcorp.com

FRANCE
Tel: +33 (0) 1 49 93 21-58
+33 (0) 1 49 93 21-59
Fax: +33 (0) 1 49 93 21-62
info.france@ispcorp.com

ITALY
Tel: +39 (0) 2 75 419-642
Fax: +39 (0) 2 75 419-644
info.italy@ispcorp.com

RUSSIA
Tel: +7 095 232-0214
Fax: +7 095 232-3385
info.russia@ispcorp.com

NETHERLANDS
Tel: +31 (0) 20 65 45-361
Fax: +31 (0) 20 65 45-368
info.netherlands@ispcorp.com

SPAIN & PORTUGAL


Tel: +34 93 298-0700
Fax: +34 93 298-0705
info.spain@ispcorp.com

NORDEN
(Denmark, Estonia, Iceland,
Finland, Norway, Sweden)
Tel: +46 (0) 8 519 920-10
Fax: +46 (0) 8 519 920-12
info.norden@ispcorp.com

SWITZERLAND
Tel: +41 (0) 1 439 53-66
Fax: +41 (0) 1 439 53-68
info.switzerland@ispcorp.com

BELGIUM
Tel: +32 (0) 2 626-49 30
+32 (0) 2 626-49 34
Fax: +32 (0) 2 626-49 32
info.belgium@ispcorp.com
BULGARIA
Tel: +359 (0) 2 958-2596
Fax: +359 (0) 2 850-5480
info.bulgaria@ispcorp.com

GERMANY
Tel: +49 (0) 2236 9649-260
+49 (0) 2236 9649-264
+49 (0) 2236 9649-266
Fax: +49 (0) 2236 9649-295
info.germany@ispcorp.com

UK
Tel: +44 (0) 207 519-5054
+44 (0) 207 519-5055
Fax: +44 (0) 207 519-5056
info.uk@ispcorp.com

ASIA PACIFIC CUSTOMER SERVICE


N.S.W. AUSTRALIA
Tel: +612 9648-5177
Fax: +612 9647-1608
roppy@ispcorp.com

GUANGZHOU, CHINA
Tel: +8620 3758-9970
Fax: +8620 3758-9907
hwong@ispcorp.com

MUMBAI, INDIA
Tel: +9122 2837-0472
Fax: +9122 2837-0449
ekalyanpur@ispcorp.com

TOKYO, JAPAN
Tel: +813 5566-8661
Fax: +813 5566-8682
myamashita@ispcorp.com

SINGAPORE
Tel: +656 223-3778
Fax: +656 226-0853
ffoo@ispcorp.com

VICTORIA, AUSTRALIA
Tel: +613 9899-5082
Fax: +613 9899-5102
roppy@ispcorp.com

SHANGHAI, CHINA
Tel: +8621 6249-3900
Fax: +8621 6249-3908
hwong@ispcorp.com

KOREA
Tel: +82 2 554-6622
Fax: +82 2 554-6944
ksoh@ispcorp.com

TAIWAN
Tel: +886 2 2508-0212
Fax: +886 2 2504-3543
cchiang@ispcorp.com

BEIJING, CHINA
Tel: +8610 6515-6265
Fax: +8610 6515-6267
hwong@ispcorp.com

HONG KONG
Tel: +852 2881-6108
Fax: +852 2895-1250
hwong@ispcorp.com

INDONESIA
Tel: +6221 530-7181
+6221 530-7182
Fax: +6221 530-7183
mchondrodihardjo@ispcorp.com

MALAYSIA
Tel: +60 5513-1498
Fax: +60 5512-8311
ffoo@ispcorp.com

THAILAND
Tel: +662 267-8103
Fax: +662 236-0041
pwilliams@ispcorp.com

CHENGDU, CHINA
Tel: +8628 8557-1040
Fax: +8628 8557-2313
hwong@ispcorp.com

HYDERABAD, INDIA
Tel: +9140 5584-4000
Fax: +9140 2331-1090
ekalyanpur@ispcorp.com

OSAKA, JAPAN
Tel: +816 6838-5752
Fax: +816 6838-5566
myamashita@ispcorp.com

PHILIPPINES
Tel: +632 848-7188
Fax: +632 848-7191
rcomagon@ispcorp.com

Trademark registration applied for Registered trademark of the ISP group International Specialty Products. 2005 Designed & Printed in USA.

Product Code: Revised PECH0017 9/2005

The information contained in this brochure and the various products described are intended for use only by persons having technical skill and at their own discretion and risk after they have performed necessary technical investigations,
tests and evaluations of the products and their uses. While the information herein is believed to be reliable, we do not guarantee its accuracy and a purchaser must make its own determination of a products suitability for purchasers
use, for the protection of the environment, and for the health and safety of its employees and the purchasers of its products. Neither ISP nor its affiliates shall be responsible for the use of this information, or of any product, method,
formulation, or apparatus described in this brochure. Nothing herein waives any of ISPs or its affiliates conditions of sale, and WE MAKE NO WARRANTY, EXPRESS OR IMPLIED, OF MERCHANTABILITY OR FITNESS OF ANY PRODUCT
FOR A PARTICULAR USE OR PURPOSE. We also make no warranty against infringement of any patents by reason of purchasers use of any information, product, method or apparatus described in this brochure.

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