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Transacticns on Eletc
i l
Ins-i+ in V-ol.
I-21 No .5,, 0
'
-Q
36
Jr C
ABSTRACT
In order to stimulate further thought and research within
the science of dielectrics, this paper discusses the remarkable correlation between acoustic theory and the physics of
electrical breakdown in dielectrics.
Following a brief, simplified review of acoustic theory and the propagation and attenuation of soundwaves in gases, liquids and solids, three areas
in dielectrics are addressed in which the breakdown mechanisms
require further clarification.
These are the relative electrical
strengths of gases and mixtures; streamer initiation in liquid
hydrocarbons; and the incubation period before treeing or breakdown occurs within solid dielectrics.
Acoustic analysis of gas
breakdown clearly shows that the relative electrical strengths
of gases and mixtures vary as the inverse square of sound
velocity, and consequently, are closely related to both the
molecular weight and specific heat ratio of the gas or mixture.
For liquid hydrocarbons, an analysis of acoustic emission levels
from partial discharges combined with acoustic cavitation theory,
supports the hypothesis that cavitation (collapse) of microbubbles attached to dust particles may provide the conditions
for streamer initiation.
1.
INTRODUCTION
Z,
E PE
-i-L--
-rIf =I-PS;
-T. " !-! -n
-
-4--i
_.L
cllef--trjj,-,--3..'t-i-
Acoustic Imrpedance
The characteristic impedance or specific acoustic impedance of a material depends on the product of the
..-
'' I
vo
,
L.
-,--
I - - - ----
- -
RO
2. 3
(PlCl-P2C2)/(PlC1
P2c2)
(1)
In gases
/Pp/P
(2)
e V21-p
=
(3)
where K is the bulk modulus. For liquids which are compressible, ethyl ether for example
e =
ryK/P
(4)
c =
Y/pY(l-b)
(5)
In solids
2. 4
(6)
py-,yi cs of
3.
The analogy between acoustics and these factors controlling the electrical breakdown in gases is that
acoustic waves propagate in gases by molecular collision
and the molecular weights of the gases influence the
penetration and velocity of the acoustic waves. A way
in which this analogy can be critically examined is to
compare the acoustic wave velocities in gases and mixtures with a large amount of uniform field gas breakdown
data. Fortunately, Vijh [6], in examining the correlation between the relative electrical strength and molecular weights of gases, accumulated and normalized a
large amount of data. These data are relative to the
dielectric strength of N2 as unity and are for atmospheric pressure and, presumably, mostly at room temperature. In addition, Wootton [7] has examined the electrical strength of mixtures of SF6 and He, and Pelletier
[5] the strength of N2-He mixtures. This author [8] has
measured the acoustic wave velocities in SF6-He and
other mixtures, Table 1. There are, therefore, about
100 electrical breakdown data points available covering
the range of 0.1 to 10, relative to N2; with measured
acoustic wave velocities ranging from -140 m/s (SF6) to
-960 m/s (He).
These data are plotted in Fig. 1, and a very clear relationship is observed between the relative electrical
strength (RES) and acoustic wave velocity c, i.e. the
Table I
GCs Mixture
rn/sec
-2
-8
100%
Gas Mixture
H-
Sound
Gas mixture
Velocity
135
100%
a/sec
136
SF8
Sound
Velocity
a/sec
100%
135
90%
10
143
90%
10
142
9l
10
138
80%
20
149
80%
20
150
60%
20
143
70%
30
156
70%
30
161
70%
30
149
60%
40
168
80%
40
177
60%
40
155
50%
60
180
50%
60
198
60%
60
161
40%
80
198
40%
60
217
40%
80
168
30%
70
213
30%
70
260
30%
70
178
20%
80
247
20%
80
308
20%
80
187
10%
go
274
10%
90
444
10%
90
204
100%
345
100%
061
100%
217
ct11* 751673-1
1U
Ir
:5
8
o
,;
SF6-C02t.
....
RES. 1C2
SF sf6.fH
H~~~~~~~~~~~~~~~~~~~~
O
200
I Cl
400
00
oD
10
1200
gases
n-
.,
.4
.%
- an
f,
Table II
Gas
Monatomic Gases
Helium
Argon
Diatomic Gases
Air
Hydrogen
Oxygen
Triatomic Gases
Carbon Dioxide
Sulphur Dioxide
Nitrous Oxide
Te
k-l
X tE l
1.630
1.667
0-17
4-17
5-14
1.40112
4-11
16-34
1.300
1.260
1.324
1.407/8
1.400
.n
4
.
1i n XVs*
-.i
1N.;
'
4 xlO1
r-
Theory
With Ionizaion"d SF by He
+ +
SF6, He+ only
Experiment
J L Pack, Glow Discharge
Ij
v J LMoruzzi
& J D Craggs
Spatial Current Growth
O LI Kline, etal.J
J L Moruzzi, Breakdown Voltage
& J D Craggs
~~~6
---
Polyatomic Gases
Benzene (C6H6)
20
1.40
Trichloroethylene (CM4)
Sulphur Hexafluoride (SF6)
20
1.130
1.2
(Calc. from
E
v
sonic wave
velocity)
0.1
Relative Values
* Based on Acoustk
Wave Velocty
10
I
%
100
SF6
Fig. 2:
values
Harrold: AcO-&tij
p-ys_i
theory can help in understanding and predicting- electrical breakdown phenomena in gases. In any event, it
is clear that simply by making laboratory measurements
of soundwave velocity in gases and mixtures, good estimates can be made of their relative electrical
strengths.
bre,k;dow-
of electrical
in
dielectric -7-76.
lU
Positive Streamer
Point-to-Insulated Plane
-)
UI
.a
Point b Plane
IC
100Ee rcll
0.4
la,4
ki
L-
tn
Point Discharge
E102
,.'
.=lo10
Ca
-,
Plane 10 mm,-
~~~Series
>
o
Point-to-Insulated
;: ID ~~~Comns Discharges in O li
Z~ ~~\
Tatvio l 21) l
cL
Insulation
Point Discharge
8 kV I Ogihara (20)-
10
1
10-3
,,
al,,
,,1,,i ,,1,,
i ,,1,,
lii
1o02 1o61
(WEI
10
lo,
I,
lo
i -t-
'i-s._e-t-
o i_ - ct-%' 'tT-- o l -t
(7)
-6X10-7 ,J.
pJ
i . >-
Nc
-, OC obe-
1986
Table III
Phenomenon
Acoustic Emissions From
1 to 10 pC PD in
Mineral Oil
Cavitation (Collapse) of
10 5 to 10 4 cm [0.1 to hPm]
Radius Gas Bubbles in
Mineral Oil
2 to 6 x 10 7 UJ
20 to 2000 x
10-7
#J
ppIied to t r,-s
p h.yic s.
levels of impurities; but also for an acoustic examination of the RES of liquids when reliable breakdown
data are available.
Curve 751894-A
3 xlo8
of
period? An acoustic approach, which can yield information regarding the structure and composition of a dielectric, is a simple measurement of the sound velocity
and attenuation in the dielectric.
As discussed earlier, the velocity of sound in a
solid depends upon its density, Young's modulus and
Poisson's ratio, and can be expressed as:
p-(-b)
I-
Eu
(8)
I.)
Vm
(cm3)
Fig. 5:
The
molecular
c
s.
=p -r
-~-It
-tr
-tr
In
LI---
.nVt
Ttna
A-2-1
Table IV
Sound Velocity and Bulk Modulus of Plastics
(E. M. Zacharias, Jr., M. W. Zacharias, and R. A. Parnell, Modern Plastics, May 1974) [26]
1)
2)
3)
4)
5)
6)
7)
8)
9)
10)
11)
12)
13)
14)
15)
16)
17)
18)
19)
20)
21)
22)
23)
24)
25)
26)
27)
28)
29)
30)
31)
32)
33)
34)
Polyester casting
AM1000 ABSb
CIT-31336 ABSb
DH-10OO ABSb
resilno
KA10 ABSb
LE-1000 ABSb
TD-1001 ABSb
X7-1000 ABSb
X17-1000 ABSb
X27-1000 ABSb
800-1000 ABSb
Polyester GRPc
25053 HDPEd
35063 IIDPEd
Styron 475 high-impact PS d
Styron 678 general-purpose PSd
LDPE type 950d
LDPB type XlP-4212.35d
DC 306 silicone e
Silastic 4505 filled silicone
rubber e
XRi 90504 silicone e (discont.)
Vespel SP-1 polyimide
Vespel SP-21 polyimide f
Surlyn 1650 ionomer resin
Surlyn 1652 ionomer GRP
Teflon FEP resin f
Teflon TFE resins
Tefzel ETFE fluoropolymer
B995 phenolic with wood flour
and cotton flock filr
Nylafil G-1/30 6/6 nylon with
30% long glass fibersh
Nylafil G-10/40 6/6 nylon with
40% long glass fibersh
Nylafil G-12/40 6/10 nylon with
40% long glass fibersh
Sound Velocity,m/sec
At 25*C
At 50*C
Temp. Coeff.
(per 'C)
g/Ccc
Density
(25"C)
Modulus,10 psi
Adiabatic Bulk
2983
3044
2475
2148
2143
2214
2032
1991
2091
2141
2196
2208
2228
2618
2269
2313
2122
2264
1988
1968
2606
977
2870
2983
2353
2091
2045
2152
1954
1926
2030
2078
2119
2146
2156
2401
2096
2176
2048
2195
1777
1745
2448
911
-4.56
-2.46
-4.88
-2.31
-3.93
-2.48
-3.14
-2.60
-2.43
-2.55
-3.09
-2.50
-2.90
-8.68
-6.95
-5.52
-2.95
-2.78
-8.47
-8.93
-6.30
-2.66
1.46
1.49
1.23
1.05
1.08
1.05
1.19
1.02
1.04
1.04
1.06
1.06
1.39
1.80
0.93
0.96
1.04
1.05
0.92
0.91
1.86
1.74
18.9
20.1
11.0
7.02
7.27
7.52
7.18
5.89
-6.63
6.95
7.43
7.52
10.0
18.2
7.05
7.50
6.80
7.84
5.36
5.21
18.5
2.44
1866
2507
2594
1887
2053
1258
1456
1610
2941
1706
2314
2349
1741
1852
1164
1331
1504
2824
-6.41
-7.75
-9.86
-5.87
-8.07
-3.77
-5.00
-4.23
-4.72
1.15
1.42
1.57
0.95
1.09
2.15
2.21
1.71
1.35
5.87
13.1
15.6
4.98
6.75
4.99
6.87
3.80
17.0
2517
2348
-6.75
1.36
12.6
2594
2422
-6.88
1.48
14.6
2422
2269
-6.16
1.42
12.2
1 e
Harrold: Ac:o_
1--'-makt-doi, - nr
d e1 etr
2284
2137
-6.26
1.31
10.0
2215
2091
-4.98
1.40
10.1
2368
2206
-6.52
1.52
12.5
2377
2240
-5.51
1.62
13.4
2173
2101
-2.89
1.20
8.23
2176
2093
-3.34
1.20
8.29
2180
2094
-3.43
1.20
8.32
2582
2615
2647
2651
2401
2451
2389
2552
2554
2205
-5.27
-9.05
-3.79
-3.90
-7.85
1.15
1.16
1.19
1.37
11.2
11.7
12.1
12.2
11.6
2613
2493
-4.81
1.32
13.2
2509
2387
-4.87
1.39
12.7
2148
2081
-2.70
1.36
9.15
1816
2221
2313
2252
5930
5965
5840
5730
4120
5360
5310
5520
1715
2171
2116
2173
5900
5900
5790
5695
4100
5305
5275
5470
-4.06
-2.01
-7.89
-3.16
-1.15
-2.54
-2.02
-1.36
-0.88
-2.22
-1.34
-1.88
2.12
1.24
0.94
1.39
2.77
2.68
2.79
4.40
8.40
7.76
7.92
7.79
10.2
8.92
7.41
10.3
141
139
138
210
207
324
324
344
a--American Cyanamid
MIL:500 PCi
Lexan
grade 9034-112,
40)
Mfl:250 PCi
41) Lexan grade 9034-112,
MIL:375 PCi
42) Polypenco nylon 101k
43) Polypenco nylon 901k
44) Plexiglas acrylic (sample
#1)1
laminatem
48) MX-1403 grade CE, medium-weave-
1.19
canvas
b--Borg-Warner
c--Cincinnati Milacron
d--Dow Chemical
e--Dow Corning
m--Synthane-Taylor
n--3M Co.
o--Union Carbide Corp.
$C B9
Ti.-
_'
22
F
0/
0/
18
r-
16
x
0
14
L-l
l a= KT-2e1
No
Oc
ex-
This effect was especially evident in the first two temperature runs of the old polyethylene, with signals increasingly varying from 700 to 750 pV at 250C and from
50 to 150 iPV at 500C. The third temperature run, with
old polyethylene, produced much less signal change, as
did the two runs with new polyethylene. At 500C, all
the experiments exhibited a substantial change in signal level. Due to these signal fluctuations, the best
way to present these dat-a is to take average readings
and convert these to signal attenuation values in decibels, for example, 6 dB represents a signal reduction
of 2:1 and 20 dB, 10:1. In Fig. 7 the signal attenuation values are plotted against temperature for the
%.0
a//
/
/
6
*
0?w
4 _
/
e 00'
2 _
0
200
'-70'1
II
600 1000 1400 1800 2200 2600 3000 3400
(C) Sound Velocity Meters/ Sec. 250C
in Old and
This author carried out some sound velocity and attenuation experiments using old and new polyethylene of the
same density ( 0.87 gm/cm3) from RG59B/U 75 Q RF coaxial
cable. The old sample was at least 10 years old and had
been kept in a laboratory drawer. It had apparently
turned yellow with age. The new sample was white and
fresh from a new supply in the laboratory storeroom.
Curve 752007-A
100
II
,II
*I
80
07
'O
5.1
12
10
:-
04
=p C2
l_.
20
I-t
70
.2
'60
$::
'cr50
V
Old
Polyethylene
_
Newhl
Polyethylene> I
40
=3
Q30
-
H eat
Cool
20 _-
10
nV
.
II
10
20
30
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~I
40
5)
Temperature C
40
30
20
10
H-iarrold : A-COU
o--
6-
SUMMARY
The thrust of this paper has been directed toward introducing the reader to the remarkable correlation'
between acoustic theory and the physics of electrical
breakdown in dielectrics. Several different phenomena
associated with electrical breakdown in gaseous, liquid,
and solid dielectrics have been examined from an
acoustic viewpoint. Acoustic analysis of gas breakdown
data clearly shows that the relative electrical
strengths of gases and mixtures vary as the inverse
square of sound velocity, and consequently, are closely
related to both the molecular weight and specific heat
ratio of the gas or mixture. Based on this analysis,
it is anticipated that laboratory measurements of
soundwave velocity can be used for predicting the relative electrical strengths of gases and mixtures.
In the area of liquid dielectrics, the cavitation
hypothesis of breakdown initiation has been addressed.
Specifically, this hypothesis was examined by comparison of the relative energies associated with both
partial discharges and with the collapse of microbubbles. This analysis suggests that a breakdown streamer
in, for example, mineral oil, begins with electric
field-induced cavitation (collapse) of a microbubble
Jri f c-I.
V-
de-z
t,-j
-;..I
7.
REFERENCES
[1]
[2]
[3]
[4]
[5]
[6]
[7]
[8]
[9]
~--
tJ
--E
rIE
[14] P. K. Watson and J. B. Higham, "Electric Breakdown of Transformer Oil", IEEE Symp on Insulating Materials, 1953.
_trn i
-t:v- ,l-1
T-
i3
&,