ORG./INO.

CHEMISTRY

TARGET : JEE (Main) 2017

NO. 35

Course : AADHAAR(EB)

This DPP is to be discussed in the week (25-01-2016 to 30-01-2016)

DPP No. # 35
Total Marks : 51

Max. Time : 35 min.

Single choice Objective ('1' negative marking) Q.1 to Q.13

Subjective Questions ('1' negative marking) Q.15
Match the Following (no negative marking) Q.14

1.

(3 marks, 2 min.)
(4 marks 3 min.)
(8 marks, 6 min.)

[39, 26]
[04, 03]
[08, 06]

Which of the following will not show tautomerism

fuEu esa ls dkSu pyko;ork ugha n'kkZrkA

(1)
2.

(2*)

(3)

(4)

Which one of the following compound does not exist in enol form

fuEu ;kSfxdksa esa ls dkSu bZuksy :i iznf'kZr ugha djrk gSA

O
O
||
||
(1)
CH3 C CH2 C C 2H5

(2)

(3)

(4*)

Sol.

Easy
(4) All carbon atoms are sp2 hybridized.
(4) lHkh C ijek.kq sp2 ladfjr gSA

3.

Which of the following compound will not show tautomerism.

fuEufyf[kr esa ls dkSulk ;kSfxd pyko;ork iznf'kZr ugha djrs gSA

(1*)

Ph C Ph
||
O

CH3 CH NO2

(2)

CH3

Sol.

For tautomerism -H must be present.

pyko;ork ds fy, -H mifLFkr gksuk pkfg,A

4.

Tautomerism will be exhibited by :

fuEu esa ls fdlds }kjk pyko;ork iznf'kZr dh tkrh gSA

(1) (CH3)2NH

(2) (CH3)3CNO

(3)

(4)

CH3 C CH2 C CH3

||
||
O
O

(3) (CH3)3C CN(4*) RCH2NO2

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Sol.

5.

In which of the following compound. Dexchange will take palce in OD/D2O solution ?
fuEu esa dkSulk ;kSfxd OD/D2O foy;u esa D-fofue;(Dexchange ) djrk gS\

(1)

(2)

(3*)

(4)

6.

Stability order among these tautomers is :

mijksDr pyko;oh;ksa ds LFkkf;Ro dk lgh e dkSulk gS %

(1) I > II > III

(2) III > II > I

(3) II > I > III

(4*) II > III > I

(3) I = II

(4) Can not predict

(3) I = II

(4) Kkr

(3) I = II

(4) Can not predict

(3) I = II

(4) Kkr

7.

Which of these tautomers is more stable ?

(1) I
(2*) II

fuEu esa ls dkSulk pyko;oh :i vf/kd LFkk;h gS \

(1) I

(2*) II

ugh fd;k tk ldrk

8.

Which of these tautomers is more stable ?

(1) I
(2*) II

fuEu esa ls dkSulk pyko;oh :i vf/kd LFkk;h gS \

(1) I
9.

(2*) II

ugh fd;k tk ldrk

The correct acidity order is :

vEyh;rk dk lgh e D;k gS\

O
||
CH3 C OH
(Y)

(1) X > Z > Y

(2*) Z > X > Y

O
||
H C OH
( Z)

(3) Y > Z > X

(4) X > Y > Z

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10.

Sol.
Sol.

The compound in which the CH3 group causing increase in acid strength and decrease in basic strength are
respectively :
;kSfxd ftlesa CH3 lewg vEyh; lkeF;Z dks c<+krk gS rFkk {kkjh; lkeF;Z dks ?kVkrk gS e'k% gS :
(1) CH3COOH

(2)

(3)

(4)

(5)

(6)

(1) 3 and rFkk 5

(2) 1 and rFkk 6
(3*) 3 and rFkk 4
(4) 2 and rFkk 5
Due to ortho effect CH3 group in 3 is increasing acidic strength & in 4 is decreasing basic strength.
vkFkksZ izHkko ds dkj.k '3' esa CH3 lewg dh vEyh; lkeF;Z c<+rh gS rFkk 4 esa {kkjh; lkeF;Z ?kVrh gSA

Write up : (Q.11 to Q.13)

Observe the following sequence of reactions

vfHkf;k vuqe dk izs{k.k dhft;sA

11.

The correct stability order is

LFkkf;Ro dk lgh e gSA

(1) III > II

(2) IV > II

(3*) III > IV

(4)

> IV

Sol.

III is more stable becose OH group show I effect but in compound IV O show + I effect

12.

In compound II which of the following electronic effect is absent

(1) Inductive effect
(2) Delocalisation of electrons.
(3*) Hyperconjugative
(4) Negative mesomeric effect

fn;s x;s ;kSfxd II esa fuEu esa ls dkSulk bysDVkWfud izHkko vuqifLFkr gSA
(1) izsjf.kd izHkko
(2) bysDVkWuksa dk foLFkkuhdj.k
(3*) vfrla;qXeu
(4) +_.kkRed eslksesfjd izHkko
Sol.
Sol.

(3) Sp3 - Hydrogen is absent

(3) Sp3 - gkbMkstu vuqifLFkr

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13.

Which of the following is not an acid

fuEu esa dkSulk vEy ugha gSA

Sol.
Sol.

(1) I
(2) II
(4) Due to absence of acidic Hydrogen
(4) vEyh; gkbMkstu dh vuqifLFkfr ds dkj.k

14.

Match the column :

feyku fdft, &

Column I
Compounds

(3) III

(4*) IV

Column II
Kb

(1)

(p)

5.6 107

(2)

(q)

4 10 4

(3)

NH3

(r)

4.6 10 9

(4)

CH3 CH2 NH CH3

(s)

10 10 4

Ans.

(1 p) ; (2 r) ; (3 q) ; (4 s)

15.

How many of the following will show tautomerism ?

fuEu esa ls fdrus ;kSfxd pyko;ork iznf'kZr djsxs \

O

NH
Ans.

2 (II & IV)

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029

PAGE NO.- 4