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Subhasish Mitra
M.Tech
Department of Chemical Engineering
IIT Kanpur
Brief Introduction:
GTL technology:
The key concept is chemical conversion of natural gas to
longer chain hydrocarbons that typically remain in the
range of middle distillate i.e. transportation fuel.
Process steps:
GTL process consists of four basic
steps:
• Fischer-Tropsch conversion to
produce desired long chain
hydrocarbon liquids.
FT
reactor
GTG
FT
reactor
GTG
Integration
Integration loop-4 loop -1
Auto-thermal Reaction:
2CH4 + H2O + 0.5O2 5H2 + 2CO
2CH4 + 2H2O + O2 6H2 + 2CO2
Combustion Reaction:
CxHy + z(x+y/4)O2 xCO2 + (y/2)H2O
CxHy + z(x/2+y/4)O2 zxCO + (z.y/2)H2O
FT reaction product distribution: [2]
[2] www.fischer-tropsch.org/primary_documents/presentations/acs2001_chicago/chic_slide04.htm
FT reaction product distribution: [3]
Chain growth
probability factor
Alpha = 0.95
[3] Simulation, integration and economic analysis of gas-to-liquid process. Buping Bao, M.M.El-
Halwagi, Nimir.O.Elbashir, Fuel Processing Technology, 2010 (in press)
Modeling Strategy:
Process Simulator:
Hysys Version: V7
Thermodynamic models:
Vapor phase : Peng-Robinson EOS
Unit operations:
Turbine driven compressor : Compressor + Gibbs reactor +
expander
Simulation strategy (Contd):
Power generation
Compressor
Combustor
Turbine
Simulation Process Flow Diagram – Air
Compression Section
Process Simulation Flow sheet – Overall
Plant:
Heat integration
primary loop
Heat
integrati
on
seconda
ry loop
Simulation Figures:
E-31 10910
Cooling MW Total CW
consumers duty requirement
GTG Condenser 12.98
E-101 348.32 MW
Process Air 5.81
Compressor inter-
stage coolers
FT product cooler 58.33
(C-41)
K66 turbine 271.2
exhaust cooler
Summary: