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Waste Management
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Article history:
Received 8 November 2010
Accepted 4 April 2011
Available online xxxx
a b s t r a c t
With 2020 energy targets set out by the EU fast approaching, the UK is trying to source a higher proportion of its energy from renewable resources. Coupled with this, a growing population and increasing
trends in consumer demand have resulted in national waste loads increasing. A possible solution to both
issues is energy-from-waste (EfW) technologies. Many studies have focused on municipal solid waste
(MSW) as a potential feedstock, but appear to overlook the potential benets of commercial and industrial waste (C&IW). In this study, samples of C&IW were collected from three North West waste management companies and Lancaster University campus. The samples were tested for their gross and net
caloric value, moisture content, ash content, volatile matter, and also elemental composition to determine their suitability in EfW systems. Intra-sample analysis showed there to be little variation between
samples with the exception two samples, from waste management site 3, which showed extensive variation with regards to net caloric value, ash content, and elemental analysis. Comparisons with known
fuel types revealed similarities between the sampled C&IW, MSW, and refuse derived fuel (RDF) thereby
justifying its potential for use in EfW systems. Mean net caloric value (NCV) was calculated as 9.47 MJ/
kg and concentrations of sulphur, nitrogen, and chlorine were found to be below 2%. Potential electrical
output was calculated using the NCV of the sampled C&IW coupled with four differing energy generation
technologies. Using a conventional incinerator with steam cycle, total electrical output was calculated as
24.9 GWh, based on a plant operating at 100,000 tpa. This value rose to 27.0 GWh when using an integrated gasication combined cycle. A nal aspect of this study was to deduce the potential total national
electrical output if all suitable C&IW were to be used in EfW systems. Using incineration coupled with a
steam turbine, this was determined to be 6 TWh, 1.9% of the national demand thereby contributing 6.5%
towards the UKs 2020 renewable electricity target.
2011 Elsevier Ltd. All rights reserved.
1. Introduction
There is little doubt that waste management has emerged itself
as a major challenge in modern society. Urbanisation, population
increase, and higher consumer demand, has put pressure on waste
management companies, landll operators, and local authorities.
As a result, many landll sites are reaching their stated capacities.
At present, the UK produces approximately 335 million tonnes of
waste per annum. Of this, 100 million tonnes results from minerals
extraction, which is not subject to control under the EU Waste
Framework Directive (Defra, 2006a). The remaining 225 million
tonnes is predominantly composed of municipal solid waste
(MSW, waste derived from domestic/household sources, e.g. foodstuffs and packaging), commercial and industrial waste (C&IW,
waste derived from commerce and industry, e.g. packaging, paper,
metals, and catering), and Construction and Demolition Waste
Corresponding author. Tel.: +44 07764926480.
E-mail address: c.lupa@lancaster.ac.uk (C.J. Lupa).
0956-053X/$ - see front matter 2011 Elsevier Ltd. All rights reserved.
doi:10.1016/j.wasman.2011.04.002
Please cite this article in press as: Lupa, C.J., et al. The use of commercial and industrial waste in energy recovery systems A UK preliminary study. Waste
Management (2011), doi:10.1016/j.wasman.2011.04.002
technologies (e.g. gas engine). However, not all wastes can be used
in EfW technologies. In order to achieve good process dynamics
and a favourable economic return, the feedstock must be of certain
standard to gain suitability for EfW processes. For example, an
ideal feedstock should be of high caloric value (CV, largely related
to organic content), low moisture, and low inorganic content. Furthermore, elemental composition should be low with respect to
sulphur, nitrogen, and chlorine as they can preclude thermal conversion and produce undesirable products (detailed in Section 3.2).
As a result, C&DW, which makes up 32% of the UKs total waste
arisings (Defra, 2006a), is not suitable for EfW processes due to
its low CV and high inorganic content. The two key waste streams
that are suitable, however, are MSW, and C&IW. National waste
arisings show that MSW and C&IW are not the largest contributing
streams (9% and 25%, respectively) (Defra, 2006a), but appear to receive a disproportionate amount of attention and legislation, largely as a result of their recovery potential.
As a result of its high organic content, and therefore CV, many
studies have focused on MSW for EfW processes (Baggio et al.,
2008; Lawrence, 1998; Nakamura et al., 2010; Psomopoulos
et al., 2009). In spite of this, C&IW accounts for a larger proportion
of the total annual waste arisings in the UK and is thought to contain a comparable organic content. Two major sub categories of
C&IW, which are not too dissimilar from MSW, are Mixed Ordinary
waste (undifferentiated, similar to MSW), and Non-Metallic waste
(paper, wood, food, glass, etc.). Although much of the Non-Metallic
component will have been removed for recycling, a substantial
proportion remains in the residual stream as a result of contamination from liquid residues thereby deeming it unrecoverable. These
two sub categories make up an estimated 43% of UK C&IW arisings,
approximately 36 million tonnes (FoE, 2003), and are suitable feedstocks for EfW applications. Other C&IW sub-categories include;
Metallic, Chemical, Mineral, and Healthcare wastes all of which
are not widely accepted as suitable waste streams for EfW.
Previous studies have shown that C&IW is being somewhat neglected for use in EfW processes (Envirolink Northwest, 2009). Furthermore, lack of characterisation data has meant little is known
about its true thermal recovery potential. With increasing pressures from environmental NGOs and the EU, it is likely that
C&IW will be an important resource for future energy generation.
This paper examines North West (NW) UK C&IW samples to determine the suitability of this waste stream in EfW systems. Samples
were tested for their gross and net CV (GCV and NCV), moisture
content, ash content, volatile matter, and also underwent elemental analysis. The relevance of the values for EfW will be discussed
and potential issues highlighted. The study concludes with a theoretical based mass balance analysis to determine potential energy
output generated by the waste if used in EfW systems.
2. Methodology
2.1. Sample collection and preparation
A waste sampling campaign was conducted between February
and March of 2010 where C&IW samples were collected from three
NW waste management sites in addition to Lancaster University
campus. A sampling strategy was devised according to CEN/TR
15310 and adhered to as practically and safely feasible. At each
site, a thick 3.9 m 4.9 m polyethylene tarpaulin was used as a
surface to separate and mix the waste material. Refuse bags, collected from separate locations on-site, were emptied onto the tarpaulin and thoroughly mixed using a two-handed stainless steel
spade. Items greater than 10 cm2 were reduced in size using hand
shears. From this, a 10 kg gross waste sample was obtained after
removing recyclable products, such as plastics and metals. This
Table 1
NW C&IW samples. Recyclates removed refers to those manually sorted before
sampling whereas Residual refers to sorting conducted by the site operator. New
and Old refer to the amount of time the waste was left to decompose prior to
collection. In this case, Old was approximately 2 weeks.
Sample
Site
1
2
3
4
5
6
Lancaster University
Waste Management Site
Waste Management Site
Waste Management Site
Waste Management Site
Waste Management Site
Condition
1
1
2
3
3
Recyclates removed
Recyclates removed
Residual
Recyclates removed
New pre-sorted and shredded
Old pre-sorted and shredded
3. Results
Data was rst examined within data sets, and then subsequently compared against known fuel data obtained from the Energy research Centre of the Netherlands (ECN).
3.1. Intra-sample results
The mean and standard deviations based on the triplicate samples for each test are presented in Fig. 1 for each waste sample
(note the use of scaling for total sulphur, nitrogen, and chlorine).
Note AR is as received material, Dry is dry material and DAF
is dry, ash-free material. The standard deviations show intrasample variations were minimal with the exception of samples 5
and 6. These samples differed from the others as they were collected in a pre-treated state (shredded and sorted) and, particularly
Please cite this article in press as: Lupa, C.J., et al. The use of commercial and industrial waste in energy recovery systems A UK preliminary study. Waste
Management (2011), doi:10.1016/j.wasman.2011.04.002
Fig. 2. Mean waste data and standard deviations comparison with other known fuels.
mechanical whereby recyclables and compostable materials are removed, followed by drying and shredding of the waste to produce a
combustible product. As most EfW technologies have been optimised for use with MSW, it too was included as a benchmark for
C&IW comparison. Furthermore, a technology that uses MSW as
a feedstock could potentially use C&IW with minimal adaptation.
Pure biomass is also included within the comparison. Anthracite
coal is used as comparative data marker as it is widely used for energy generation. All values were determined using an average of
the same fuel type. Note some parameters have been removed
due to unavailability of data for some of the stated fuel types.
In most cases, it was observed that the performance of C&IW as
a fuel did not differ considerably with the other known fuel types.
GCV was calculated as 22.98 MJ/kg, which is comparable to RDF
and MSW (24.4 and 18.7 MJ/kg, respectively). Anthracite coal,
however, has a GCV 55% greater than that of the mean waste sample. This is to be expected as result of its near 100% organic content
which is largely related to CV. The NCV of the waste showed a 59%
drop when compared with GCV (9.5 MJ/kg). This is as result of the
high moisture content within the waste sample. It is necessary to
ensure the feedstock is as dry as possible prior to thermal conversion as dryer fuels obtain higher temperatures and thermal efciencies (Miskam et al., 2009). Moreover, McKendry (2002a,b)
suggested a fuel with a moisture content of above 30% would be
Please cite this article in press as: Lupa, C.J., et al. The use of commercial and industrial waste in energy recovery systems A UK preliminary study. Waste
Management (2011), doi:10.1016/j.wasman.2011.04.002
difcult to ignite and would reduce the heating value of the resultant gas. However, the NCV was still higher than that of MSW
(6.4 MJ/kg), a key waste stream for EfW processes (note only one
NCV value was available for MSW). This is further supported by literature values that suggest unsorted MSW has a NCV between 8.5
and 9 MJ/kg (Dong and Daji Li, 2003; MacDonald, 2008).
Ash content was calculated as 24.7% but with a large standard
deviation as a result of samples 5 and 6, discussed previously.
Ash is the end product of a material after thermal treatment and
comprises of inorganic mineral oxides that form the residual,
non-combustible fraction of the material. Ash precludes thermal
processes, such as gasication, and requires removal to ensure
thermal efciencies are at an optimum level. At high enough temperatures, ash forms a liquid slag which can increase the risk of
feed blockages. It is benecial, therefore, to use a feedstock that
is of high CV and low ash content. However, since CV is largely related to organic content, it is unlikely that a feedstock with high CV
would have a high ash content.
Volatile matter was high in all fuels apart from coal. No data
was available for biomass pellets but is thought to be comparable
to waste (Miskam et al., 2009). Tar formation is proportional to volatile matter and so fuels with high volatile content are undesirable
as they can cause problems within a thermal conversion system
(Miskam et al., 2009). It is therefore necessary to adapt the system
(e.g. gasier) design to ensure tar formation does not inhibit the
process (Turare, 1997).
Sulphur, nitrogen, and chlorine content was especially low for
all fuel types; calculated as 0.43%, 1.3%, and 1.5%, respectively for
the C&IW sample. The issues surrounding sulphur content include
sulphur dioxide (SO2) production with subsequent emission to the
atmosphere a precursor for acid rain. However, concerns regarding SO2 emissions usually lie with fossil fuels, such as coal, as a result of their higher sulphur contents (0.83%, approximately twice
that of the waste sample). SO2, however, will only form if oxygen
is present to allow for oxidation. Under anoxic conditions, used
in gasication for example, sulphur preferentially combines with
hydrogen to form hydrogen sulphide (H2S) and minor amounts of
COS (carbonyl sulphide) (Jazbec et al., 2004). Both require removal
from the synthesis gas, typically using calcium oxide (Yang and
Chen, 1979). Similarly, nitrogen forms the basis of nitrogen oxides
(NOx) and can too produce atmospheric contaminants such as tropospheric ozone (O3) (Jacob, 2000). Chlorine content in the waste
sample (1.5%) was comparable to MSW but an order of magnitude
greater than RDF, biomass pellets, and coal. Other literature values
have suggested lower chlorine contents (Wenchao et al., 2010). In a
thermal conversion process, chlorine promotes the formation of
toxic chlorinated organic compounds such as dioxins. If, however,
low oxygen levels are employed in the process, such as in gasication, hydrogen chloride (HCl) is formed (McKendry, 2002b) and
will require removal to prevent degradation of mechanical components. Hydrogen content was higher than that of sulphur, nitrogen,
and chlorine (7.2%). Concentrations did not vary considerably compared with RDF (8.4%), MSW (5.2%), or biomass pellets (5.7%).
However, anthracite coal contains only 3.5%, less than half that
of the waste sample. Hydrogen is a key component if using the derived syngas for energy generation due to its combustion properties. Oxygen content was similar across all fuel types apart from
anthracite coal. As coal is predominantly made up of high-energy
carboncarbon bonds, very little oxygen is to be expected within
its chemical structure. Conversely, in waste derived fuels, lower
energy carbonoxygen bonds are present thereby causing the elevated oxygen concentrations. Indeed, bond energies are a key factor affecting CV (McKendry, 2002a).
Table 2
Potential electrical output using sampled C&IW and typical EfW technologies. Output was calculated on the basis of using a hypothetical, 100,000 tpa plant (scenario 1), current
annual Northwest C&IW EfW usage (scenario 2), total annual output if all qualifying waste in the NW is used in EfW (scenario 3), and total annual output if all qualifying C&IW in
the UK is used in EfW (scenario 4).
Technology
Electrical output
(scenario 1) (GWh)
Electrical output
(scenario 2) (GWh)
Electrical output
(scenario 3) (GWh)
Electrical output
(scenario 4) (TWh)
23
19
25
31
24.9
20.5
27.0
33.5
12.4
10.3
13.5
16.8
223.6
184.7
243.1
301.4
6.0
4.9
6.4
8.0
Please cite this article in press as: Lupa, C.J., et al. The use of commercial and industrial waste in energy recovery systems A UK preliminary study. Waste
Management (2011), doi:10.1016/j.wasman.2011.04.002
5. Conclusions
C&IW has the potential to be of great benet for the future of
renewable energy generation. MSW is a proven feedstock for use
in energy generation systems and analysis of C&IW has shown
there to be similarities between the two waste streams. Furthermore, waste arisings data has shown a higher production rate of
C&IW in the UK. It is for these reasons that C&IW must not be overlooked when considering future fuels for energy generation. Furthermore, appropriate use of this waste would reduce the
amount being sent to landll with an estimated Northwest diversion of 22% if all qualifying C&IW was used in EfW (Envirolink,
2009). There are, however, difculties associated with the use
C&IW in EfW systems. MSW, although largely heterogeneous, does
not vary as greatly as C&IW. There are two predominant C&IW substreams that can be used, discussed previously, which may require
segregation from a gross waste stream depending on the waste
management company. In the case of this study, the samples collected were from management sites that only dealt with mixedordinary C&IW. Furthermore, C&IW is dealt with by private
companies whereas MSW is the responsibility of the local authorities. Issues surrounding the use of waste derived syngas in energy
conversion systems remain. Further work should be undertaken to
characterise the syngas derived from a C&IW stream to determine
its suitability in large-scale gas engine, or gas turbine, applications.
This will indeed unveil any issues surrounding gas quality and help
determine design retrot, if any, of existing EfW plants.
Acknowledgements
Thanks go to Stopford Energy and Environment, the Engineering
and Physical Sciences Research Council, and the Technology Strategy Board who helped fund this project.
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Please cite this article in press as: Lupa, C.J., et al. The use of commercial and industrial waste in energy recovery systems A UK preliminary study. Waste
Management (2011), doi:10.1016/j.wasman.2011.04.002