Professional Documents
Culture Documents
2014 Edition
ABBs history of powering primary aluminium plants started 45 years ago. Ever since,
we have been supplying complete electrification solutions and substations to more than
60 aluminium smelters worldwide. Demands for improved environmental performance
and increased energy efficiency, price fluctuations and intense competition are the
major challenges aluminium producers face today. ABB meets these challenges by
providing state-of-the-art electrification, automation and process optimization solutions
always with the objective to increase your productivity and maximize your return on
investment. For more information, visit us at www.abb.com/aluminium
Managing Director
The first small, shining globules of aluminum reduced through the Hall Process. They
are referred to as Alcoas crown jewels. Shown here on a page of handwritten minutes
from a company meeting, circa 1890.
1886-1920. The Hall family home in Oberlin, Ohio. Hall discovered the aluminum process
in a summer kitchen attached to the back of the home.
Quick Action
Aware of the other efforts, Hall moved
immediately to protect his method. He
wrote immediately to the U.S. Patent
Office, submitting his process.
Patent number 400,655, granted to
Hall in 1889, changed the aluminum
industry forever.
Drawing of the interior of the Smallman Street works of the Pittsburgh Reduction Company
depicting the reducing pots used in the companys process. (1888)
Even as his success and net worth increased, Halls work ethic remained
solid. He was not just satisfied with
having someone else promote his
process, Edwards wrote. Although a
director and vice president of his company, he worked long hours at the plant,
determined that the success of his process and (of the) company should far
exceed any of his original prophecies.
Science wasnt Halls only interest,
however. He had a lifelong love and
appreciation of nature, and music had
been a passion for him since childhood. Playing the piano was a source
of relaxation his entire life, and helped
him clarify scientific problems, Edwards wrote.
He also fed his soul. He attended
church regularly, and drew strength
from the stories of great men who
sacrificed for their convictions. The
creed which found most significant
expression in his works and deeds emphasized the importance and value
of good character, said his brother,
George Hall.
While Hall helped to change industry
and make many goods available to the
masses that would otherwise have
been unaffordable, he never forgot
what helped make him a success. Upon
his death, Hall bequeathed Oberlin
College more than $5 million.
First ingot being charged into remelting furnace at Alcoa Tennessee Plant. (1920)
INDEX
Special Feature
p. 9-12
Global Issues
p. 13-17
p. 19-59
p. 61-87
p. 89-95
Company Profiles
p. 97-103
p. 104
tmeic.com/cranes
1-540-283-2250
TMEIC Corporation
1325 Electric Road
,>i]6{n
1-540-283-2000
SPECIAL FEATURE
U >V
Gage Control
U
VViV
Compensation
U >i
U V>V}
Email: cranes@tmeic.com
TMEIC Japan
/->i>`i]L>
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+81-(0)3-3277-5511
tmeic.com | info@tmeic.com
SPECIAL FEATURE
TMEIC
Serving the Aluminium Industry
p. 10-12
AWJ 2014
10 SPECIAL FEATURE
Aluminum Strip
AWJ 2014
11
Customer Service
water cooled 3,300 volt drives have
been supplied worldwide to rolling
mill applications.
Process models are critical in the
aluminum industry to provide the
demanding product specifications.
TMEIC has worked with aluminum
companies to provide complete
control automation including level 2
and models or systems that allow for
the customers proprietary models.
Inner-stand cooling
Remote diagnostics
12 SPECIAL FEATURE
Authors:
Paul Weary, Metals Sales
Manager, TMEIC
Phone: (+1) 540-283-2110
Jim Trexel, US Metals Sales
Manager, TMEIC
Phone: (+1) 540-283-2193
GLOBAL ISSUES
UC Rusal
New Horizons
p. 14-17
AWJ 2014 13
14 GLOBAL ISSUES
Focus on efficiency
In 2013, China produced over 25 million
tonnes of primary aluminium, almost
half of the global output. However,
further development of the Chinese
aluminium industry is subject to certain limitations in terms of power consumption and emissions by operating
smelters.
Efficient resources utilization is one of
the urgent issues now in China where
over 90% of primary aluminium smelters source energy from coal-fired power
plants that account for 75% of all CO2
emissions in aluminium production.
The government is also encouraging
reduction in consumption of power,
which accounts for about 40% of a
smelters operating costs.
364"-
AWJ 2014 15
364"-
16 GLOBAL ISSUES
364"-
Company profile
UC RUSAL is the worlds largest aluminium producer, accounting in 2013
for approximately 8% and 7% of global
aluminium and alumina production
respectively. The Companys current
capacity allows it to produce 4.5 million
tonnes of aluminium and 11.9 million
tonnes of alumina per annum.
UC RUSAL is vertically integrated to a
high degree, having secured substantial supplies of bauxite and alumina
production capacity. RUSALs assets
include over 40 smelters and production facilities in 13 countries, across 5
continents. RUSAL employs 67,000
people.
AWJ 2014
17
AP Technology
TM
18
p. 20-23
p. 24-45
p. 46-48
FLSmidth
MLLER Alumina Handling Systems
p. 49-51
Streamline.
Sensotech
ECL
makes your
Inline
concentration
monitoring
operations easier.
p. 52-55
Power Jacks
Precise Anode Beam Positioning from Power Jacks
p. 56-59
ecl.fr
AWJ 2014 19
Streamline.
ECL makes your
operations easier.
ecl.fr
Regulation system to improve quality of the metal sucked during tapping operation
AWJ 2014 21
I/P
Master loop
PTA
compressed
air line
ejector
Short loop
P/I
vacuum pipe
Crucible
Conclusion
The regulation system is a selfadaptive system. It requires no action
or adjustment from the operator. The
system provides transparency and
combines good process quality with
fast potline operation.
Author:
Anne-Galle Hequet
ECL Communication and Public
Relations Manager
AWJ 2014 23
Table 1: Most Advanced Reduction Cell Technologies as at the Year 2000, excerpts from [2]
UPBN: Universal Prebake Cell Nomenclature, proposed by Tabereaux
Company
Cell Type
UPBN
I / kA
Alcan
A-275
AC-28
A-310
AC-31
P-225
A-817
Alusuisse
EPT-18
Comalco-Dubal
CD-200
Hydro
HAL-230
HAL-250
Kaiser
P-80
KA-18
190
Pechiney
AP-30
AP-30
300 - 325
Reynolds
P-20S
RY-17
170
P-23S
RY-18
180
CA-180
VAW-18
180
CA-240
VAW-24
240
CA-300
VAW-30
V-350
VN-35
C-255
C-300
Alcoa
VAW
Venalum
Russia/VAMI
China
Pots installed
Year
Remarks
280
1981/92
310
n. inv.
n. inv.
AA-23
225
n. inv.
n. inv.
Massena, Tennessee
AA-30
300
n. inv.
n. inv.
Portland
AS-18
180
n. inv.
n. inv.
CD-20
200
1990
HAL-23
230
n. inv.
n. inv.
HAL-25
250
n. inv.
1981
2040 + 720*
n. inv.
n. inv.
n. inv.
Alcasa, Alscon
n. inv.
n. inv.
115
1980
1980/93
300
1992/93
320
n. inv.
Test cells
RU-26
255
n. inv.
n. inv.
RU-30
300
1992/93
P-280
CH-28
280
n. inv.
n. inv.
Qingyang
P-320
CH-32
320
30
n. inv.
AWJ 2014 25
3.500
Al Price LME spot
Mean
3.000
Median
Mode
2.500
2.000
1.666
1.552
1.500
1.164
1.000
500
AWJ 2014 27
AWJ 2014 29
HAL230
(HAL-23)
HAL250
(HAL-25)
Unit
Amperage (design)
230
250
kA
Amperage (operation)
230,3
258
kA
172 / 1
54 / extension
96
94
0,044
n.a.
AE/(day pot)
13,5
13,2
kWh/kg aluminium
Value
Unit
Amperage
420
kA
Number of Pots
Test cells
95
% (assumed)
Pot Voltage
4,1
< 0,03
AE/(day pot)
12,83 12,93
kWh/kg aluminium
2010 Google
2011 LeaDog Consulting
2011 GeoEye
The HAL-32 technology based Qatalum smelter cost was 9.000 USD/ktpy
installed capacity [38].
Figure 4: Land Usage of 1 AP Potline vs. 2 HAL Potlines (yellow lines: 1000 / 250 m long)
AWJ 2014 31
AP3X
(AP-30/39)
Unit
19 + 3 *
PLs
Total Pots
5274 + 810 *
Pots
Average Pots
Pots/PL
Mtpy
Average Output
ktpy/PL
V/PL
*: 3 PLs with 810 pots under construction in Iceland and India; pots not included in below
calculations
**: assuming 4,2 V/pot
Table 5: RTA AP3X and AP50 Cell Performance Data as per [45], [46], [47]
Parameter
Value
Unit
Amperage
300 500
kA
94,1 96 ,0
Pot Voltage
4,2
AE/(day pot)
13,01 13,41
kWh/kg aluminium
OA-300M1
(SU/RA-30)
RA-300
(RA-30)
RA-400
(RA-40)
RA-500
(RA-50)
Unit
Smelter Site
IrkAZ
KhAZ/ *
SAZ/ **
SAZ
Amperage (design)
300
300
400
500
kA
Amperage (operation)
330
320
415 435
520
kA
Number of Pots
200
336 + 672*
16 + 672**
94
95
> 93,5***
> 93,5***
Pot Voltage
4,33
n.a.
4,3 - 4,4***
4,3 - 4,4***
0,13
0,15
< 0,05***
< 0,05***
AE/(d pot)
13,73
n.a.
< 13,8***
< 13,8***
kWh/kg Al
AWJ 2014 33
4.5 Dubal
Dubal started operations in 1979 with
3 potlines implementing National
Southwire technology (an improved
DX
(DU-35)
DX
(DU-38)
DX+
(DU-44)
Smelter Site
Emal 1 *
Dubal
Dubal, Emal 2
Amperage (design)
340
340
440
kA
Amperage (operation)
380
380
440
kA
Number of Pots
756
40
5 + 444
95,8
95,5
95
Pot Voltage
4,2 4,22
n.a.
4,24
0,1
< 0,02
< 0,05
AE/(day pot)
13,12
13,04
< 13,4
kWh/kg aluminium
Unit
4.6 Venalum
In 2000, Corporacin Aluminios de
Venezuela S.A. (CAVSA) presented
a technology website describing its
so-called V-350 aluminium reduction
cell developed by the CVG Venalum
R&D department. The V-350 (VN-35)
cell was designed for operation at 320
350 kA and test pots were said to
be operating at 322 325 kA [73].
Further performance data mentioned
are presented in Table 8.
In 2004, Berrueta presented a paper
at TMS on the planned expansion of
the Venalum smelter by two potlines
with 240 reduction cells each of V-350
(VN-35) type. Groundbreaking was
scheduled for March 2004 and the
first of the two potlines (potline 6) was
planned to be commissioned from
the end of 2006. The additional electric power was to be provided by CVG
Edelca, a state-owned power provider
within the same CVG group, which was
said to have included some generating units in the Caruachi dam project
on the Caroni River to provide for the
Venalum demand. This hydroelectric
power project was supposed to generate energy by 2005.
Berrueta also presented an estimate
of the capital expenditure (CAPEX)
necessary for one potline, including
casthouse, carbon and dock facilities.
The estimated CAPEX of 652 mUSD,
for a production capacity of 220 230
ktpy, would translate into a specific
investment of around 2900 USD per
tonne installed capacity [74].
However, according to Pawleks PASaPoW [26], no further potline construction activities have been recorded at
Venalum, and the V-350 test pots are
supposed to have been taken out of
service and dismantled.
The author therefore believes that Venalum cell technology development
was ceased altogether.
4.7 Chalieco-SAMI
SAMI had initially developed Sderberg
cells (until the mid 1970s) and by the
AWJ 2014 35
Value
Unit
Amperage (design)
320 350
kA
Amperage (operation)
322 325
kA
95 96
Pot Voltage
4,1 4,2
0,1 0,2
AE/(day pot)
13,0 13,3
kWh/kg aluminium
4.8 Chalieco-GAMI:
GAMI seems to have followed a similar
development to SAMI, although there
is very little publication. The GAMI
development was initially based on a
160 kA cell - first commercialized in
the Guangxi smelter in 1994. It appears,
from an evaluation of information
provided by Pawlek in his PASaPoW
directory [26], that GAMI has further developed this technology into the 200
280 kA range. A number of potlines are
reported to have been commissioned
using GAMI reduction cell technology
in this amperage range, though there
is no primary source that confirms this
[26]. In 1998, the GP320 reduction
technology was jointly developed by
GAMI and the Pingguo Aluminium
Company (PGAC). The first GP320 pots
came on stream in October 1999, in a
30 cell trial potline. This trial potline
achieved a current efficiency of 94,4 %
with specific energy consumption of
13,323 kWh/kg Al, operating at up to
325 kA. The cell voltage was reported
as 4,18 V with anode effect frequency
of 0,3 0,4 AE/(d pot) [79]. Further
performance data for GAMI technology
appear to be publicly unavailable.
As there is little GAMI publication,
Pawleks PASaPoW seems to be the
only accessible source of information
about GAMI. However, due to limited
information about Chinese aluminium
smelters in general, this directory also
remains vague on China and some of
the information is contradictory (e.g.
there sometimes appears to be a mismatch between amperage, number
of pots and output) which cannot be
finally resolved by the author. That said,
evaluation of PASaPoW for explicit
Table 9: Overview of Chinese Smelters based on SAMI Cell Technology 300 kA as per [26], SAMI and Chinese Technology lumped
together for better match with [77]
Cell Technology (UPBN)
Parameter
SY300
(SY-30)
SY400
(SY-40)
SY500
(SY-50)
SY300
(SY-30)
SY400
(SY-40)
SY500
(SY-50)
Unit
Smelter Status
operatg.
operatg.
operatg.
u/c
u/c
u/c
27
20
PLs
Total Pots
6310
5902
1236
2256
2584
Pots
Average Pots
240*
290
310
275
325
Pots/PL
4,17
4,84
1,71
2,45
3,51
Mtpy
1010
1220
1300
1160
1365
V/PL
GAMI high amperage ( 300 kA) reduction cell technology (with one attempt
to mend an obvious mismatch and
back-calculating some missing data
in the directory) has resulted in the
following tentative overview of GAMI
technology proliferation (to be read
with due caution), see Table 11. In addition, > 2,8 Mtpy capacity appear to
be based on GAMI 200+ kA cells which
seem to have been fairly frequently implemented during the past 12 years besides the high amperage technologies.
Outside of China, GAMI has licensed its
technology to some smelter projects.
The GP320 technology has been the
basis of an expansion of the BALCO
smelter, located in the Korba district, India. The project comprises one potline
of 288 GP320 pots with a capacity of
Table 10: Summary of SAMI Cell Technology Performance Data ( 300 kA) as per [77], [78]
Cell Technology (UPBN)
Parameter
SY300
(SY-30)
SY350
(SY-35)
SY400
(SY-40)
SY500 (u/c)
(SY-50)
Unit
Amperage (operation)
300 335
348 378
400
500
kA
Number of Pots
3074
444
n.a.
288
93,8 95,7
94,15 - 94,5
94,16
94
Pot Voltage
n.a.
n.a.
4,19
< 3,94
0,1
< 0,3
0,08
0,05
AE/(d pot)
12,9 0,06
12,8 13,5
13,26
< 12,5
kWh/kg Al
AWJ 2014 37
GP300
(e.g. GP-30)
GP400
(e.g. GP-40)
GP500
(e.g. GP-50)
GP300
(e.g. GP-30)
GP400
(e.g. GP-40)
GP500
(e.g. GP-50)
Unit
Smelter Status
operatg.
operatg.
operatg.
u/c
u/c
u/c
26
PLs
Total Pots
6322
510
288
840
Pots
Average Pots
280*
260
290
210
Pots/PL
5,75
0,55
0,39
0,76
Mtpy
1175
1100
1220
880
V/PL
*: excluding some obvious test sections and 2 short potlines of 84 pots/138 ktpy
**: assuming 4,2 V/pot
There are different shapes and patterns of protrusions under test, all with
the aim of reducing the metal rotating
velocity and ultimately, although not
explicitly mentioned, lessening the
Table 12: Tentative Overview of Chinese Smelters based on NEUI Cell Technology
300 kA as per [26]
Cell Technology (UPBN)
Parameter
NEUI300
(NE-30)
NEUI400
(NE-40)
NEUI500
(NE-50)
Unit
Smelter Status
operatg.
operatg.
operatg.
PLs
Total Pots
180
1006
Pots
Average Pots
180
250
Pots/PL
0,15
1,19
Mtpy
760
1050
V/PL
7.000
6.000
Reduction Cells in Operation
ACD. The test pots are reported to operate at around 3,7 V resulting in 12,0
kWh/kg specific energy consumption
and achieving 93 % CE [84].
5.000
300 - 399 kA
400 - 499 kA
> 500 kA
4.000
3.000
2.000
1.000
Alcoa
Hydro
RTA
Dubal
Venalum
Rusal/VAMI
SAMI*
GAMI*
NEUI*
*: estimated
RTA
Dubal
Venalum
Chalco / Chalieco
Rusal/VAMI
NEUI
SAMI
Cell Type
I / kA
Pots
Capacity / Mtpy
installed
u/c
installed
u/c
none
Remarks
A-817
AA-32
320
448
none
0,388
HAL-230
HAL-26
240 - 258
ca. 410
none
0,285 e
none
HAL-275
HAL-30
290 - 320
1044
none
0,90
none
SU4, Qatalum
Portland
420
none
negl.
none
300 - 400
5274
1194
5,25
1.22
HAL4e
HAL-42
AP30/40
AP-30/40
AP50
AP-57
570
41
none
0,065
none
AP60
AP-60
600
none
none
none
none
DX
DU-38
380
796
none
0,85
none
Dubal PL 8, Emal 1
DX+
DU-42
440
449
none
0,55
none
V-350
VN-35
325
none
none
none
RA-300
RA-33
330
536
672
0,47
0,59
RA-400
RA-44
435
16
672
0,02
0,75
RA-500
RA-52
520
none
none
SY300
SY-30-38
300 - 375
4.752
4,17
SY400
SY-40-45
400 - 450
4.402
2.256
4,84
2,45
SY500
SY-50-52
500 - 520
1.236
2.584
1,71
3,51
CT300/350
CT-30-35
300 - 350
1.558
1,32
400
1.500
1,63
300 - 365
6322
840
5,75
0,76
China
unspec CT400
GAMI
UPBN
CT-40
GP300/370
GP-30/37
GP400
GP-40
400
510
0,55
GP500
GP-50
500
288
0,39
NEUI300
NEU-30
306
180
0,15
NEUI400
NEU-46
415 - 460
1006
1,19
6 PLs u/c: ??
NEUI500
NEU-50
500
modeling completed ?
AWJ 2014 39
Electrolysis
Near ambient temperature and/or water based electrolytic process (maybe
similar to copper): aluminium hardly
dissolves in aqueous solutions, and
if, its position in the electrochemical
series favours reduction (= production)
of other components of such systems
instead of aluminium.
Electrolytic process closer to
aluminiums melting point of 660 C,
say at around 700 C (instead of 950
Novel Processes
Carbothermal Reduction (preferably
similar to the iron blast furnace
process): the quick answer is that
thermodynamically, carbon can only
reduce alumina above 2000 C, and
that the product is an unwanted and
unstable Al4C3 instead of aluminium.
However, the issue is much more
complicated and can be summarized as
follows: up to 2.160 C, only an aluminacarbide slag (AlO, AlO2, AlC) but no
liquid aluminium metal is produced;
above 2.160 C there is also a second
phase: something like liquid metal
but in fact it is an aluminium-carbon
alloy with some 10 % C; at the required
AWJ 2014 41
Upcomer
Terminal
anode
Downcomer
Bipolar
Terminal
cathode
Anode - cathode
space
Aluminium
sump
The ASP consists of electrolysing AlFigure 9: Sketch of Alcoa Smelting Process Electrolyser [87]
7 Acknowledgements
Special thanks go to my former colleagues, Dr. Robert Minto and Thiago
Heitling, who helped establishing the
first edition. For this second edition,
I would like to thank Anne Tappen
for her friendly support and Rudolf
Pawlek for his private communications regarding latest intelligence on
Chinese smelters.
References
AWJ 2014 43
[80] XIQUAN, Q. et al., Successful commercial operations of NEUI400 Potline, in: Light
Metals 2010, Proceedings of the Annual TMS
Aluminium Committee Meeting, JOHNSON,
J. (Editor), A Publication of TMS, Warrendale
2010, 359 363
[81] BAN, Y. et al., Baking Start-up and Operation Practices of 400 kA Prebaked Anode
Pots, in: Light Metals 2010, Proceedings of the
Annual TMS Aluminium Committee Meeting,
JOHNSON, J. (Editor), A Publication of TMS,
Warrendale 2010, 369 373
[82] DINGXIONG, L. et al., New Progress
on Application of NEUI400kA Family High
Energy Efficiency Aluminum Reduction Pot
(HEEP) Technology, in: Light Metals 2011,
Proceedings of the Annual TMS Aluminium
Committee Meeting, LINDSAY, S. (Editor), A
Publication of TMS, Warrendale 2011, 443
448
[83] DINGXIONG, L. et al., Development of
NEUI500kA Family High Energy Efficiency
Aluminum Reduction Pot (HEEP )
Technology, in: Light Metals 2011, Proceedings
of the Annual TMS Aluminium Committee
Meeting, LINDSAY, S. (Editor), A Publication
of TMS, Warrendale 2011, 455 460
[84] JIANPING, P. et al., Development and
Application of an Energy Saving Technology
for Aluminium Reduction Cells, in: Light
Metals 2011, Proceedings of the Annual TMS
Aluminium Committee Meeting, LINDSAY, S.
(Editor), A Publication of TMS, Warrendale
2011, 1023 1027
[85] BALOMENOS, E. et al., Theoretical
Investigation of the Volatilization Phenomena
Occurring in the Carbothermic Reduction of
Alumina, Erzmetall 64 (2011), 6, 312 320
[86] Grjotheim, K. et al., Aluminium
Electrolysis, 2nd Edition, Aluminium-Verlag,
Dsseldorf 1982, 17 21
[87] Thonstad, J. et al., Aluminium Electrolysis,
3rd Edition, Aluminium-Verlag, Dsseldorf
2001, 340 341
Author: Dr.-Ing. Joachim Heil
Contact Information:
jogaheil@t-online.de
AWJ 2014 45
Results
Intensity (kA)
550
94.2
SEC (kWh/t)
13260
Introduction
A new milestone for reduction technology has been recently reached with
the successful start-up of the Arvida
Smelter, AP60 Technological Center
in Jonquire, Quebec, Canada. Since
December 2013, the 38 first generation AP60 cells deliver an annual production capacity of 60,000 tons of
aluminium.
Starting from the development of
the first prototype AP60 cells, this
article presents the start-up of the new
smelter in 2013 and gives an overview
of the future Rio Tinto Alcan reduction
technology developments to come.
Fig 2: AP60
Cells start-up
The 38 cells of the smelter were started
in Q4 2013. The first two cells were
started at 550 kA while the remaining
36 were started at 560 kA. Each AP60
cell required the addition of up to 14 t
of liquid bath.
Before adding the liquid bath to the
cell, the preheating phase was critical
to limit the risks of infiltration. This
phase was carefully controlled using
AWJ 2014 47
The Arvida Smelter, AP60 Technological Center will be the platform for
future development of the AP60 technology. Table 2 shows the targets for
the development of this technology.
13,5
kWh/t
Intensity
(kA)
570
600
12,0
SEC
(kWh/kg)
13.3
13.0
11,5
Production
(t/day)
4.31
4.51
AP50
13,0
AP60
Second
Generation
Conclusion
The 38 AP60 cells have been successfully started in the new Arvida smelter
AP60 Technological Center. In delivering the project, Rio Tinto Alcan teams
14,0
AP60
First
Generation
ment), APXe will benefit from the industrial validation of AP60 at Arvida
Smelter.
12,5
450
Hi Productivity
AP60
LE
APXe
500
550
Amperage (kA)
600
650
APXe
Busbar
Common
Shell
Common
Superstructure
Common
Common
Anode assembly
Common
High productivity
Low energy
Shell ventilation
High productivity
Low energy
Gas flow
High productivity
Low energy
Common
Common
Buildings
Common
Norsk Hydro
Dubal
Expertise in
Alumina handling
FLSmidth is your expert in handling of fresh alumina, reacted alumina, crushed bath
and aluminiumfluoride
s
s
s
s
s
Dosage systems
s
s
s
s
AWJ 2014 49
About FLSmidth
FLSmidth is a market-leading supplier of equipment and services to the
global minerals and cement industries.
FLSmidth supplies everything from
single machine units to complete minerals and cement flow sheets including
associated services.
With more than 15,000 employees,
FLSmidth is a global company with
headquarters in Denmark and local
presence in more than 50 countries
including project and technology
centres in Denmark, India, USA and
Germany.
FLSmidth has over the past 131 years
developed a business culture based on
three fundamental values: competence,
responsibility and cooperation.
It is FLSmidths vision to be the customers preferred full-service provider
of sustainable minerals and cement
technologies. This is reflected in focused research and development efforts aimed at fulfilling customers
future needs in terms of innovative
technical solutions, high reliability and
availability, minimum environmental
impact and the lowest possible product
lifecycle costs.
MLLER Technology
Through its MLLER technology,
FLSmidth specializes in design, engineering, procurement, erection and
commissioning of pneumatic material
handling systems for turnkey projects
and components for the alumina industry. Our capabilities of handling fresh
alumina, reacted alumina, crushed bath
and aluminium fluoride comprise:
Large capacity storage silos (up to
85.000 t realized) including antisegregation filling and discharge
MLLER airlift conveying systems
(up to 6oo t/h realized)
Pressure vessel dense phase conveying either with MLLER Turbuflow or our standard conveying
pipe
MLLER screw pump conveying
systems
Truck/wagon loading and unloading stations
Dosage systems
MLLER Fluidflow pipe air slide
and rectangular air slide conveying
systems
MLLER direct pot feeding systems either with 100% MLLER
Fluidflow pipe air slide conveyiing technology or as a hybrid of
MLLER Turbuflow conveying
pipe and MLLER Fluidflow pipe
air slide
PTM filling stations
Modular designed systems plug
and play For more than 75 years the MLLER
brand has stood for high quality standard systems with more than 5.000
references worldwide.
Presently FLSmidths Hamburg office
is executing three main orders in the
aluminum smelter industry.
AWJ 2014 51
Figure 1: Directly in the bath the LiquiSonic analyzer of SensoTech measures quickly and accurately the cleaner concentration and
degree of contamination.
Figure 2: The pickling process can include several LiquiSonic measuring points for optimal process monitoring.
AWJ 2014 53
Figure 3: For concentration measurement in a 3-component mixture, a LiquiSonic measuring point consists of a sonic velocity flange
or immersion sensor and a conductivity probe.
Use at AMAG
The company AMAG Austria Metall AG
is the nations leading manufacturer
of aluminium semis and casthouse
products for the processing industry.
The group purchased the LiquiSonic
analytical technology of SensoTech that
is used successfully to optimize the
processes in the aluminium pickling
plant. The bath operates with caustic
soda at a temperature between 50
C and 70 C. Therefore, it consists of
water, sodium hydroxide and sodium
aluminate. Sodium aluminate results
from the reaction of sodium hydroxide with aluminum. In the past AMAG
worked in a batch process and used a
titration analysis to control the pickling
bath. However, this measuring method
presents problems because of manual
sampling and time delays of the measuring results. Consequently, the goal
was to control inline and in real time
the quality of the pickling bath.
By the installation of the LiquiSonic
analyzer, this challenge has been satisfactorily resolved. The combination
of sonic velocity and conductivity measurement makes it possible to analyze
the pickling process continuously. The
concentration of caustic soda is determined by an immersion sensor made
of stainless steel and the concentration
of sodium aluminate by a conductivity
probe made of PEEK. Both sensors are
mounted with flange fittings in a DN
50 pipeline close to each other. The
rugged sensor design, non-corrosive
materials and the resistant sensor and
controller housing prepare the analyzer
for best usage under tough production
conditions. Figure 4 shows the installed
LiquiSonic immersion sensor in the
pickling plant of AMAG.
Via Profibus the measuring data are
passed to the process control system. The results are reproducible and
logged in the LiquiSonic controller.
In case of exceeding or falling below
a predefined threshold, or if process
Figure 4: In the pipe of the aluminium pickling plant of AMAG Austria Metall AG the LiquiSonic
immersion sensor is installed to monitor inline the concentration of caustic soda.
Conclusion
The inline analytical technology LiquiSonic measures precisely, continuously and directly in the process the
cleaner concentration as well as the
degree of contamination in various
bath liquids. This enables an accurate and automatic replenishment
of cleaner and an efficient control of
bath changes. An application focus is
pickling baths in the metal industry,
for example. In these kinds of baths,
the analyzer monitors the concentration of the pickling solution and of the
metal salt. Via common interfaces,
the analyzer can be integrated into
existing control systems.
Author:
Ms. Rebecca Dettloff
Marketing Manager
SensoTech GmbH
Steinfeldstr. 1
D-39179 Magdeburg-Barleben
GERMANY
Contact:
Headquarters
SensoTech GmbH
Steinfeldstr. 1
D-39179 MagdeburgBarleben
Germany
U.S. Office
SensoTech, Inc.
1341 Hamburg Tpk., Suite 2-3
Wayne, NJ 07470
USA
SensoTech:
For over 20 years SensoTech has been
focused on the development, manufacturing and sales of inline analysis systems for process liquids. With
worldwide installed, highly precise
and innovative measuring systems for
monitoring of concentrations, compositions and changes of chemicals
as well as properties directly in the
process, SensoTech has significantly
contributed to the enhancement of the
state-of-the-art. In addition to the measurement of concentration and density,
the phase interface detection as well as
the monitoring of chemical reactions
like polymerization and crystallization
are typical applications. SensoTech
inline analyzers set standards in the
technological and qualitative valence,
user friendliness and reproducibility
of process values. Special calculation
methods and sophisticated sensor
technologies enable reliable and precise measuring results even under the
most difficult process conditions.
The knowledge and the experiences
of the highly motivated and committed SensoTech staff are the result of
many different applications supported
by well-known customers from the
chemical and pharmaceutical industry,
food technology, semiconductor technology, automobile and metal industry
as well as many other industries. In
addition, these experiences also open
up unimagined solution possibilities
for new measuring challenges.
T + 49 39203 514100
F + 49 39203 514109
info@sensotech.com
www.sensotech.com
T +1 973 832 4575
F +1 973 832 4576
sales-usa@sensotech.com
www.sensotech.com
AWJ 2014 55
Hydro
Dubal
AWJ 2014 57
Dubal
Alusuisse
Pechiney
www.powerjacks.com
AWJ 2014 59
p. 62-65
Hydro
historical evolution of closed type anode baking furnace technology
p. 66-71
p. 72-73
Innovatherm
Operational and environmental benefits of the new baking furnace
at Boyne Smelters by use of an advanced firing technology
p. 74-81
p. 82-87
AWJ 2014 61
By Belbachir Salima,
Solios Carbone and
Alix Courau,
Solios Environnement
Green anode plant activities for
aluminum smelters generate noxious
vapors containing CTPV (Coal Tar Pitch
Volatiles) especially PAHs (Polycyclic
Aromatic Hydrocarbons). Fumes
collection and treatment prevent the
release of these pollutants into the
working environment and atmosphere.
Traditional pitch volatile capture has
been performed with coke injection
followed by filtration (conventional
dry scrubbers).
In recent years, RTOs (regenerative
thermal oxidizers) have been used
at some plants to improve PAHs
destruction particularly on the lighter
fractions characterized by their low
boiling point. In order to increase
destruction efficiency at lower operating
costs, Fives Solios provides a dual
approach based on the combination
of a conventional dry scrubber and an
RTO. In such an approach, the RTO is
dedicated to hot pitch fumes, while
the dry scrubber is dedicated to lower
light PAH fraction emissions
This combined solution is named Eolios
and has been successfully installed
in Mosjen, Norway and in Qatalum,
Qatar.
amount of light PAHs. This phenomenon was first confirmed at the Alcoa
Deschambault paste plant, (Canada)
where light PAH emissions were multiplied by six after paste cooler installation.
Coke + Pitch
Paste Mixer
+Water
Paste Cooler
Coke Fines Injector
RTO Description
AWJ 2014 63
Stack
Dry Scrubbing System
Calcined
Petroleum Coke +
Liquid Pitch
Paste Mixer
Coke Fines
Injection
RTO
+Water
Paste Cooler
decreases pitch fumes concentration, taking the RTO away from auto
thermal mode. A full RTO of 50,000
Nm3/h, requires around 100 m3/h of
gas, whereas a RTO integrated in the
Eolios technology will only consume
about 20m3/h of gas. The hybrid RTO
requires even higher gas consumption, up to 120m3/h (hybrid flow rate:
3,000Nm3/h & main RTO inlet: 27,000
Nm3/h).
EOLIOS
RTO: 5 000
Dry Scrubber: 45,000 m3/h
m3/h
97/98% (Proven)
1mg / Nm3 (Measured)
RTO: 50,000
m3/h
Full RTO
Conclusion
Environmental emissions treatment
requirements are becoming more and
more stringent, especially for suspected
carcinogenic substances such as PAHs
AWJ 2014 65
Abstract
This paper summarizes the historical
evolution of the closed anode
baking furnace technology from the
Riedhammer design to the Hydro
Aluminium concept in the Norwegian
carbon plants; rdal and Sunndal over
the last 50 years.
The increasing demand for higher
production and larger anodes during
the last 30 years has required Hydro
Aluminium (HAL) to design a proprietary
high capacity HAL baking furnace
concept. Some major aspects and
challenges connected to the rebuilding
of the furnaces are described, including
maximum utilisation of the existing
factory space, allowing a low CAPEX
per annual production capacity.
Development of new repair and
maintenance methods for critical
Introduction
Historical Development at Sunndal
Furnace
The production of prebaked anodes
in Sunndal was initiated in connection
of the paste plant start-up in 1968.
The first anodes were produced in
a closed type Riedhammer furnace
designed for an annual capacity of
54,000 tonnes.
Until 1984, Norsk Hydro (SV) had five
anode baking furnaces of the closed
Riedhammer design in operation in
Norway. The total annual production of
these furnaces was 160,000 tonnes.
The need for higher metal production
volumes and consequentially bigger
anodes initiated a strategic plan for the
Sunndal furnace
SNC
Start Operation
Technology
Annual capacity (t/y)
Ardal furnace #1
AAKI
Ardal furnace #2
AAK2
Ardal furnace #3
AAK3
Ardal furnace #4
AAK4
1968
1958
1958
1970
1971
Riedhammer
Riedhammer
Riedhammer
Riedhammer
Riedhammer
54,000
18,000
15,000
34,000
34,000
Number of fires
Number of sections
28
24
24
30
30
Number of pits/section
Number of anodes/section
108
60
60
90
90
514
257
214
388
388
1984
HAL 1st. gen
1977
1989
high extensions
high extensions
63,000
22,000
22,000
53,000
Start Operation
Technology modification
Annual capacity (t/y)
Number of fires
Number of sections
28
24
24
30
Number of pits/section
Number of anodes/section
126
60
60
105
514
314
314
605
Start Operation
Technology modification
Annual capacity (t/y)
1997
HAL 1st. gen
2004
HAL 1st. gen
1998
HAL 2nd. gen
80,000
112,000
102,000
Number of fires
Number of sections
28
30
30
Number of pits/section
Number of anodes/section
126
168
168
652
913
832
Table I. Overview of historical evolution of baking furnace technology in SV furnaces in Sunndal and rdal
AWJ 2014 67
Section B-B
Figure 3. Schematic drawing of the flue
gas pattern for closed type HAL baking
furnace.
Riedhammer
Sunndal furnace
11,500
10,000
rdal furnace #3
12,500
11,000
rdal furnace #4
12,500
HAL2nd. generation
Table II. Overview for tonnage of installed refractory material for furnaces.
10,800
10,500
Section A-A
Figure 6. Cross sectional view of the Riedhammer design furnace #3 section from
1970. Section with 5 pits, exhaust manifold
is connected to the exhaust outlet.
Section A-A
Figure 8. Cross sectional view of the HAL 2nd
generation design furnace #3 section after
retrofit in 2004. Direct exhaust take off is
from the section cover.
AWJ 2014 69
120
100
80
60
40
20
0
500
1000
1st
1500
2000
[days]
andLifetime
2nd generation
of the flue walls at furnace #3.
Conclusion
Increased potline amperage and
expanded metal production at SV
during the 80s resulted in a demand
for larger anodes. As a consequence, a
new HAL anode baking furnace concept
was developed and introduced through
1st and 2nd generation evolutionary
phases. All rebuild changes were done
References
[1.] Holden et al., New process control system
applied on a closed baking furnace, TMS Light
Metals 2006, 603-608
[2.] Anders Ruud, Baking furnace concept
new headwall design, TEK95/015, Internal
report, 1995
[3.] Nigel Anderson, Differences in flue gas
distribution between take off from headwall and
cover, TEK93/110, Internal report, 1993
[4.] Nigel Anderson, Anders Ruud, Direct take
off from section cover for HAL furnace. Test
summary from Dec. 93 - Feb 94, TEK 94/023,
Internal report, 1994
[5.] E. Sandvik, J. H. Skaar, Development of
cover for baking furnace with larger section,
TEK96/156, Internal report, 1996
[6.] Anders Ruud, Cover design HAL7P
Dimensional stability and temperature profile in
steel frame, TEK97/149, Internal report, 1998
[7.] Fredleiv Fosse, AAK baking furnace 3,
Concrete tub for baking furnace, Building
evaluation of construction, Urheim AS
Consultant engineering, External report, 2002
[8.] Aage Jsang, Pressure loss calculation
HAL7P and HAL7Ps furnace 3 AAK, Research
centre Porsgrunn, Internal report, 2001
[9.] Aage Jsang, Heat balance sidewall
HAL7P furnace 3 AAK, Research centre
Porsgrunn, Internal report, 2001
[10.] Aage Jsang, Heat balance bottom pit
and sidewall HAL7P furnace 3 AAK, Research
centre Porsgrunn, Internal report, 2002
[11.] Henrik Bruzell, FE analyses of AAK
Furnace 3, Validus Engineering AB, document
ref: R0501-02_revA, External report, 2008
[12.] Anders Ruud, Refractory materials for
baking furnace, testing criteria with respect
to selection of material quality, TEK90/100,
Internal report, 1996
[13.] Anders Ruud, Maintenance of brickwork
for furnace AAK3. Recommended activities and
reparation methods, Internal note, 2004
[14.] Holden et al., Safe Operation of Anode
baking Furnaces, TMS Light Metals 2008,
905-911
AWJ 2014 71
PROOF OF CONCEPT
Gate
2
Gate
1
Generate idea and
assess potential
PROTOTYPE
Gate
3
Evaluate and
validate at
pilot scale
DEPLOYMENT
DEMONSTRATION
Gate
4
Demonstate and
optimize in lead
plant
Gate
5
Encapsulate the
technology in a
commercial
package
spiral spring
electrical conductive
uid X
expands by heat
Anode
Fig 1. Mechanical and Electrical connection
Electrical Connection
Stubhole Spline
Stubhole Defects A.
Stubhole Defects B.
AWJ 2014 73
Abstract
In February 2012, a new baking furnace
was commissioned at Boyne Smelters
Limited (BSL) on Boyne Island,
Australia. This new furnace replaced
the production of two existing closed
type furnaces and set new benchmarks
in production performance.
The advanced firing technology was
based on latest safety requirements
Introduction
Now part of Pacific Aluminium, Boyne
Smelters Ltd. (BSL) is a primary
smelter put into operation in 1982
by Comalco Aluminium and its joint
venture partners. BSL has undergone
extensive expansion over time. The
smelter underwent a A$1 billion
expansion in 1997 introducing a
third reduction line which increased
aluminium production from 260,000
to more than 550,000 tons per annum.
The company has further undergone
a significant modernization with the
re-building of Carbon Baking Furnace
3 (CBF3) and the construction of a
new Carbon Baking Furnace 4 (CBF4)
to upgrade the baking technology.
The new baking furnace replaced the
two existing closed type furnaces that
were obsolete and fully outdated in
terms of energy efficiency, emissions of
greenhouse gases and high refractory
maintenance and operational cost. An
aerial view of the smelter is provided
in Figure 1.
Details of the Carbon Bake
Furnace 4
The new baking furnace is an open-type
Rio Tinto Alcan AP design. It consists
of 66 sections, each with 9 flues and 8
pits. BSL operates 4 fire groups on this
furnace. The configuration includes 3
sections in the preheat area, 3 sections
in the firing area and 6 sections in the
cooling area. Figure 2 shows the actual
fire configuration.
The fire cycle time can vary between
24 and 32 hours, depending on the
production requirements.
AWJ 2014 75
AWJ 2014 77
4
Section
Figure 8: Cooling principle with Zero Point and controlled blower ramp
Blower manifold
(controlled)
Zero Point
Ramp
Firing Area
Cooling manifold
1
Last filled section
Week 1
Week 2
Week 3
Week 4
Results
Operational Safety and
System Reliability
All existing baking furnaces at BSL
have a hard-wired connection between
each of the ramps of the fire group to
connect the draught safety release
signal. This system has been in use
for many years and provides a high
level of inherent safety to the fire
control system due to the physical
connection of equipment with a lead.
The disadvantage is the need for leads
to be placed across the floor of the
furnace, and mechanical faults with
the plugs and leads as the equipment
ages.
For CBF4, a full wireless fire control
system would not satisfy the AGA
regulations. The design was adapted
to incorporate a hardwired connection
29/05/12
31/05/12
02/06/12
04/06/12
06/06/12
08/06/12
AWJ 2014 79
Parameter
Baking level
Units
Typical Value
1,225 (40)
Electrical resistivity
O.m
57 (4.5)
kg/m3
1560 (7)
94 (2)
CO in furnace off-gases
mg/Nm3
25 40
200 250
1.9 2.1
Table I Early CBF4 furnace and anode property data. Standard deviation
shown in brackets
Anode Quality
For BSL, the goal with the CBF4 startup was to commission all four of the fire
groups and achieve an acceptable initial
baked anode quality in the shortest
possible time frame. BSL were not
able to sustain the operation of three
furnaces due to pressure on green
anode supply and manning, so it was
important to have enough confidence
in the early baked anode quality to shut
down the existing closed furnaces.
A summary of the early anode quality
Summary
This paper describes the results that
can be achieved when a commissioning
team comprised of experienced start-up
and operations personnel is combined
with a bake furnace fire control system
with advanced process control
functionality. It also demonstrates
that the adoption of modern Wi-Fi
communications technology and more
stringent furnace safety requirements is
no barrier to high system availability.
BSL has entered into a new era of
anode baking capability, and is well
prepared for the present and future
Authors
Andreas Himmelreich, Detlef Maiwald;
Domenico Di Lisa,
innovatherm GmbH&Co.Kg
Am Hetgesborn 20,
Butzbach 35510, Germany
Integrated Technology
Firing and Fume Treatment for Anode Baking Furnaces
ProBake
Advanced Firing Systems
Lowest energy consumption
Total pitch burn
Higher quality consistency
ProClean
Fume Treatment Technology
Higher adsorbtion ratios
Lower emissions
Higher reliability
ddilisa@innovatherm.de
www.innovatherm.de
Abstract
Aluar Aluminio Argentino has been
operating with two closed type furnaces
for the production of anodes for more
than 35 years. Due to the continuous
expansion by amperage increase in the
potlines, these furnaces were replaced
by two new open type baking furnaces,
due to present anode requirements
only one was started. As a result, the
existing Fume Treatment Plant had to
be upgraded to cope with higher volume
and temperature requirements.
This paper explains the most
economical solution for an FTC
concept upgrade, which integrates
major existing components but in
parallel enhances the plant by new
equipment and process technologies to
attain the targets. Finally it outlines the
actual results achieved by presenting
key performance figures, including
emission levels.
Introduction
The Aluar Aluminium Smelter at Puerto
Madryn (Argentina) had a production
capacity of 250.000 tons/year before
the last expansion project was initiated.
Cooling tower
The conditioning cooling tower is
designed as a direct current cooler.
AWJ 2014 83
The pre-cleaned and conditioned offgases are channelled through the lower
side conical outlet into the main reactor
chamber. Fresh alumina, sourced from
Filter chambers
The adaptation of the existing filter
chambers is strongly depending on the
existing infrastructure and the existing
design. The process requirements for
a redesign of an existing filter chamber
was easy to formulate, but not easy
to realize. The design target was the
enlargement of the fabric surface in the
space of the existing filter chambers.
An additional chamber was no option
due to economical aspects. The future
value of the filter surface load should
be favourable in a range of < 1,0 m3/
m2 and minute. High gas flow rates
in a range of 18 m/s in the ducts and
reactors have to be reduced in steps
to less than 1 m/s in the area of the
filter bags. The separation of heavy
particles (agglomerates) needs to be
executed prior to the filtration cake.
In this area gas speeds of < 2m/s are
obligatory.
AWJ 2014 85
Conclusion
After all these aspects have been
technically realized, the desired
performance for higher production
was available. As a positive effect the
dosing of fresh alumina after finetuning was minimized to 800kg/h;
this corresponds with a fresh alumina
load of 7,8g/Nm3 flue gas.
If the right balance is found between
fresh and recirculated alumina, the
wear and tear in all aspects of the FTC
Operational results
The fluorides and total dust values
were obtained following the US EPA13a
method. Each monthly value was
obtained as an average of two or three
individual values.
The condensed soluble tars values were
obtained following EPA429 method
and correspond with international
standard test measurements.
The total dust concentration obtained
by this method during these measurements was 0.54 mg/Nm3, which is
equivalent with the monthly average
obtained by the other method.
Summary
The results presented above show
impressively that the upgraded
FTC technology even in the given
boundary conditions can achieve or
surpass emission values stipulated
by international regulations by far.
The project was executed in time
and in budget which finally assured
the technological and economical
benefits for the carbon plant of ALUAR
Aluminium.
Total dust at stack measured and is showing values far below the
environmental limits:
Authors
E. Cobo; L. Beltramino; J. Artola,
Aluar Aluminio Argentino
Dr.-Ing. F. Heinke; Dipl.-Ing. D. Maiwald;
D. Di Lisa;
Innovatherm
Prof.-Dr. Leisenberg GmbH & Co KG,
Butzbach, Germany
AWJ 2014 87
Our knowledge goes beyond materials handling.
Being an aluminium producer we understand
how oursystems impact yourprocess. Alesa is a
full servicetechnologies supplier thatalso offers
automation,pot controls systemsand
reductiontechnologies.
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TECHNOLOGY
8 88 ANODE
GLOBALPLANT
ISSUES
p. 90-91
Siwertell
Siwertell unloaders offer industry changing advantages for
p. 92-95
alumina handling
AWJ 2014 89
AWJ 2014 91
AWJ 2014 93
Per Karlsson
We know how to load and unload
alumina, and our units meet all the
known regulations related to safety
and the environment, says Mr Karlsson. Over the years Siwertell screwtype ship unloaders have become the
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Yearly intake
Operating hours/day
20 hours
Ship size
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Efficiency, Siwertell
70 percent
152 days
US$3.8 million/year
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A saving of US$2 million per year is possible in shipping costs alone using a highly
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Website: www.siwertell.com
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1974
40 2014
AWJ 2014
YEARS
95
The long standing problem of flatness measurement and control in aluminum hot
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AWJ 2014 97
We are helping thousands of clients all over the world to boost their productivity and yield
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ABB has developed a completely new
way of performing measurements
with eddy current technology. It is
a method that makes it possible to
measure, in real time and in line, dimensions and other attributes with
exceptional accuracy.
98 MATERIALS
COMPANY PROFILES
HANDLING AND TRANSPORTATION
A non-contact, non-optical
measurement system
The Millmate Strip Scanner System
determines the edge position of a
metal strip in a rolling mill down to
millimeter resolution. High, consistent
quality is always the aim when producing steel, aluminum or copper strip.
This is equally true in rolling mills and
process lines.
AWJ 2014 99
Hycast
Hycast
AFM/FM
www.hydro.com
PAGE No.
COMPANY
WEB ADDRESS
www.abb.com/measurement
96
www.abb.com/aluminium
Alcoa Inc.
www.alcoa.com
1/4
Cargotec/Siwertell
www.siwertell.com
95
ECL
www.ecl.fr
20
Fives
www.fivesgroup.com
FLSmidth
www.flsmidth.com
49
Hycast A/S
www.hycast.no
100
66/103
60/106
Hydro
www.hydro.com
Innovatherm
www.innovatherm.de
81
Power Jacks
www.powerjacks.com
56
www.riotintoalcan.com
18
RTA AP-Technology
www.ap-technology.com
46
www.rta-alesa.com
88
Sensotech
www.sensotech.com
52
TMEIC
www.tmeic.com
UC Rusal
www.rusal.ru/en/
Vigan
www.vigan.com
104
ADVERTISERS
COMPANY PROFILES
AND WEB INDEX
8
14
90/105
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