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Synopsis :
Hydrogen is the most abundant element in the universe.
It is the 9th most abundant element in the earth's crust.
It occurs only in the combined state except in volcanic gases where it occurs in free state.
• It is the first element in the periodic table.
• It is the lightest of all the elements.
• It is the only element without neutrons i.e. Protium.
• It is the element with ambiguious position in the periodic table, as it resembles both I-A and
VII-A group elements.
• Hydrogen should belong to the s-block as its electron configuration is 1s1.
• The properties in which hydrogen resembles alkali metals are
a) Like alkali metals it has one electron in s-orbital of valence shell.
b) Like Alkali metals, it forms H+ ion.
c) Like Alkali metals it forms monoxides and peroxides.
d) Like Alkali metals, it acts as reductant.
• The properties in which Hydrogen resembles Halogens are
a) Like Halogens it exists as diatomic molecule (H2)
b) Like Halogens it gains one electron to attain inert gas configuration
c) The I.P value of "H" is similar to that of Halogens.
d) Like halogens it forms univalent anion i.e H–.
• Hydrogen has 3 isotopes. They are
Protium 1H
1
Deuterium 1H
2
Tritium 1H
3
• Theoritically the number of possible Hydrogen molecules is six. They are H2, D2, T2, HD, HT
and DT.
• Ordinary Hydrogen contains only 0.02% Deuterium.
• Hydrogen and Deuterium can be separated by gas diffusion principle.
• Hydrogen is more reactive than Deuterium.
• All the isotopes of Hydrogen have
a) same chemical properties
b) same atomic radii
c) same bond lengths
• The isotopes of Hydrogen differ widely due to large difference in mass numbers.
a) Number of neutrons b) Chemical reactivity
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• This reaction provides chemical evidence for the presence of H– in these hydrides
• This type of hydrides are formed only by elements with electronegativity value that is less than
2.1.
• Hydrogen compounds of high electropositive metals may be regarded as the metal hydride.
• The density of these hydrides is greater than that of the metal from which they are formed.
• These ionic hydrides are stoichiometric and have high heats of formation.
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3) By reduction of certain compounds by nascent hydrogen (or) by using reducing agent like
LiAlH4 (ether solution)
AsCl3 + 6(H) ⎯⎯→ AsH3 + 3HCl
SnCl4 + LiAlH4 ⎯⎯⎯
ether
→ LiCl + AlCl3 + SnH4
s tan nane
• Molecular hydrides are soft, have low melting point and low boiling point.
• Molecular hydrides are volatile in nature have low electrical conductivity.
METALLIC HYDRIDES:
• Most of the d-block elements and f block elements from metallic hydrides on reacting with
hydrogen.
Ex. CrH, CrH2, ZnH2, ThH2
• Metallic hydrides are normally prepared by heating the metal with hydrogen under high
pressure.
• Most of the metallic hydrides are metallic conductors and have variable composition.
• These hydrides have properties similar to those of parent metals.
• Metallic hydrides are hard, have metallic lustre and have magnetic properties.
• The density of these hydrides is less than that of the parent elements.
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Deutero Ammonia
Ca3P2
⎯⎯ ⎯
⎯→ Ca(OD) 2 + PD 3
Deutero phosphine
CaC2
⎯⎯ ⎯
⎯→ Ca(OD)2 + C2D2
Deutero acetylene
Al C
⎯⎯4⎯
⎯3
→ Al(OD) 3 + CD 4
Deutero methane
⎯→ Be(OD)2 + CD 4
Be2C
⎯⎯ ⎯
Deutero methane
Uses of D2O:
i) D2O is used as a moderator in nuclear reactors to slow down the neutrons.
ii) As tracer in studying reaction mechanisms.
Ex.: Mechanism of electrophilic substitutions of Aromatic compounds, Metabolic processes.
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• Perhydol is 30% (w/v). Its Morality is 8.9M Normality is 17.8 N and it contains 300g/lit (or)
0.3g/ml.
• On long standing or on heating H2O2 undergoes decomposition. The equation for the
decomposition of H2O2 is
2H2O2 → 2H2O + O2
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• The standard reduction potential values indicate that H2O2 is a strong oxidising agent in acidic
medium and weak oxidising agent in basic medium.
Oxidising properties of H2O2:
black PbS
⎯⎯ ⎯ ⎯⎯→ H 2 O + PbSO 4 white
⎯⎯ ⎯ ⎯ ⎯⎯→ Fe 2 (SO 4 )3 + H 2 O
Ferrous salts
FeSO 4 +H2SO 4
KI+H O
⎯⎯ ⎯2⎯→ l 2 + KOH
Na SO
⎯⎯ ⎯
2
⎯
⎯3
→ H2O + Na2SO 4
Sod.sulphi te
KNO
⎯⎯ ⎯
⎯2
→ H 2 O + KNO 3
H2O2 Pot.Nitrite
Na AsO
⎯⎯ ⎯
3
⎯⎯
3
→ H 2 O + Na 3 AsO 4
sod. Arsenite
K [Fe(CN) ]
⎯⎯4 ⎯ ⎯ ⎯⎯
6
→ H2O + K 3 [Fe(CN)6 ]
pot.Ferrocyanide
potassium ferri-cyanide
acidified K Cr O
⎯⎯ ⎯ ⎯ ⎯2 ⎯2 ⎯
⎯7
→ blue coloured CrO5 in ether
(or )chromicacid
HCHO
⎯⎯ ⎯⎯→ HCOOH + H 2 ↑
alkaline pyrogallol
C H / FeSO
⎯⎯6⎯6 ⎯ ⎯ ⎯
⎯
4
→ C 6H5 OH + H 2 O
• The bleaching action of H2O2 is due to its oxidising nature. H2O2 → H2O + (O)
• H2O2 is used to bleach silk, wool, ivory and hair.
• H2O2 is used to bleach black hair to golden yellow colour under the common name Auricome.
• The fundamental equation for reducing property of H2O2 is
H2O2 + (O) → H2O + O2
• In both acidic and basic media, H2O2 shows reducing properties as
(oxidation)
H2O2 ⎯⎯ ⎯ ⎯ ⎯⎯→ O2 + 2H+ + 2e− (E° = −0.67 V )
(acidic )
2OH
− + (oxidation⎯) → O + 2H O + 2e −
H 2 O 2 ⎯⎯ ⎯ ⎯ ⎯ (E° = +0.08V )
2
(basic ) 2
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→ Mn 2 + + O 2
acidified KMnO
⎯⎯ ⎯ ⎯ ⎯ ⎯⎯
4
Cl
⎯⎯⎯
2
→ HCl + O 2
Br
⎯⎯⎯
2
→ HBr + O 2
moist Ag O
⎯⎯ ⎯ ⎯ ⎯
2
⎯→ Ag + O 2
alkalineK [Fe(CN) ]
⎯⎯ ⎯ ⎯ ⎯
3
⎯⎯⎯
⎯
6
→ K 4 [Fe(CN)6 ] + O 2
pot Ferrocyanide
NaOCl
⎯⎯ ⎯⎯→ NaCl + O 2
H2O NaOBr
⎯⎯ ⎯⎯→ NaBr + O 2
PbO
⎯⎯ ⎯
⎯2
→ PbO + O 2
acidified MnO (black )
⎯⎯ ⎯ ⎯ ⎯ ⎯2⎯ ⎯⎯→ Mn2+ + O2
alkaline Fe3 + (Ferricsalts )
⎯⎯ ⎯ ⎯ ⎯ ⎯ ⎯ ⎯ ⎯⎯→ Fe 2+ (Ferrous ) + O 2
O 3 (disproportionation )
⎯⎯ ⎯ ⎯ ⎯ ⎯ ⎯ ⎯ ⎯→ O2 + H2O
H
O
0 1 1.48A°
94 .48
O Open book
H
structure of H-
1110.301
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