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_______ 46. Using the Van der Waals equation, calculate the pressure and
compressibility factor of 100g of CO2 contained in a volume of 6Lat 60oC.
a = 3.59 atm L2 mol 2
b = 0.0427 L mol 1
_______ 47. The vapor pressure of liquids
a.) is the same at 100oC
b.) is the same at their freezing point
c.) increases with the volume of liquid present
d.) decrease with increasing volume of the container
e.) increases with temperature
_______ 48. The critical temperature is:
a.) the temperature below which a gas undergoes cooling when expanded
into a vacuum
b.) the temperature at which a gas liquifies at one atmosphere pressure
c.) the temperature at which the average kinetic energy of the molecules is
maximum
d.) the temperature above which it is impossible to liquefy the gas
_______ 49. In the phase diagram below, a change from point A to point B corresponds to
A
B
a.)
vaporization
d.) liquefaction
b.)
condensation
e.) freezing
c.)
sublimation
_______ 50. In the phase diagram below, a liquid can be present at temperature and
pressures corresponding to the points.
A
D
B
G
a.) A, B, G
d.) A. C only
b.) A, C, G, D
e.) A, C, D, F
c.) G, C, D, E
_______ 51. Which of these gases can be liquefied at 25 0C?
a.) CH3Cl (critical point: 144oC, 66 atm)
b.) SO2 (critical point: 158oC, 78 atm)
c.) CH4 (critical point: - 82oC, 46 atm)
d.) Both a and b
e.) None of the above
146.0 and 129.7 kJ/mol respectively. This means that Cu 2O, exposed to oxygen at room
temperature, will convert spontaneously to CuO.
_______ 9. For the process CO2(s) CO2 (g), we expect both H and S to be positive.
_______ 10. For the process referred in (9), S should decrease with increasing pressure
_______ 11. Reactions for which H and S have the same sign will tend to reverse at
high temperature.
*MULTIPLE CHOICE: Write the letter only.
_______ 1. For the reaction at 25oC and 1atm:
CH4 (g) + 2O2 (g) CO2 (g) + 2H2O (l)
Which of the ff. Statements is not true?
a.) the reaction is exothermic
b.) the reaction is spontaneous
c.) G < 0
d.) work has to be done to make the reaction go
_______ 2. Vaporization is an example of a process for which:
a.) H, S and G are positive at all temperatures
b.) H and S are positive
c.) G is negative at low T, positive at high T
d.) H is strongly pressure dependent
_______ 3. For which of the ff. reactions would you expect S to be nearest zero?
a.) C (s) + O2 (g) CO2 (g)
b.) 2SO2 (g) + O2 (g) 2SO 3 (g)
c.) CaSO 4 (s) + 2H2O (l) CaSO 4 2H2O (s)
d.) CO (g) + O2 CO2 (g)
_______ 4. The reaction CaO (s) + H2O (l) Ca(OH)2 (s) is spontaneous at 298K. The
reverse reaction becomes spontaneous at high temperature. This means that
a.) H is +, S is +
c.) H is +, S is b.) H is -, S is d.) H is -, S is +
_______ 5. The free energy of formation of AgCl is 26.2 kcal/mol. G for the reaction:
2AgCl (s) 2AgCl (s) + Cl2 (g) is:
a.) 52.4 kcal
c.) + 26.2 kcal
b.) -26.2 kcal
d.) + 52.4 kcal
_______ 6. For a certain reaction, H = +2.5 kilocalories, S = 10 calories/mol K. This
reaction will be at equilibrium at about
a.) 0.25 oC
c.) 23oC
o
b.) 25 C
d.) cannot tell
_______ 7. The change in the Gibbs energy of a certain constant pressure process was
found to fit the expression G = - 85.40 + 36.5T where G is in Joules and T in Kelvin.
What is the value of S for the process?
a.) 48.9 J
d.) - 36.5 J
b.) 48.9 J
e.) 129.9 J
c.) 36.5 J
_______ 8. What is the change in molar Gibbs energy of hydrogen when it is compresses
isothermally from 1.0 atm to 100.0 atm at 298K?
a.)
11 kJmol 1
d.) + 250 kJmol 1
b.)
11 kJmol 1
e.) 25 kJmol 1
c.)
1
250 kJmol
_______ 9. When the pressure on a 35-g sample of a liquid was increased isothermally
from 1atm to 3000 atm, the Gibbs energy increased by 12kJ. What is the density of the
liquid?
a.) 0.89 g/cc
c.) 3.2 g/cc
b.) 1.1 g/cc
d.) 0.76 g/cc
_______ 15. Consider the ff. reaction and determine which of the conditions will change
the value of the equilibrium constant?
4NH 3(g) + 5O2 (g) = 4NO (g) + 6H2O(g) + heat
a.) adding a catalyst
c.) increasing the temperature
b.) adding more water
d.) none of the above
_______ 16. The equilibrium constant Kc for the ff. reaction at 2127 oC is 2.5 x 10 3 . What
is Kp at this temperature?
N 2(g) + O2 (g) = 2NO (g)
a.)
2.5 x 10 3
d.) 4.9 x 10 1
b.)
1.3 x 10 5
e.) 6.4 x 10 8
c.)
1
9.7 x 10
_______ 17. If the equilibrium constant, K for the conversion of isobutane to n-butane is
2.5, what is the equilibrium constant for the reverse reaction?
a.) 2.5
d.) 1.0
b.) 0.4
e.) 6.25
c.) 1.3
***Nos. 18 23: Assume that the system below is at equilibrium. A stress is applied as
described below:
_______ 28. One mole of SO 3 was placed in a liter reaction vessel at a certain
temperature. When equilibrium was established in the reaction. 2SO 3 = 2SO 2. The value
of the equilibrium constant is:
a.) 0.36
d.) 0.54
b.) 0.68
e.) 0.18
c.) 0.45
_______ 29. Iodine vapor dissociates according to the equation
I2 = 2I
The equilibrium constant for this reaction is 3992 and 0.0002 at 1000 oC and
600oC respectively. What is the % dissociation of iodine vapor at 900 oC?
a.) 0.569
c.) 0.325
b.) 0.978
d.) 0.759
_______ 30. Alcohol boils t 79oC and H2O boils at 100oC at 1atm pressure. A mixture of the
two will have a boiling point
a.) lower than 79oC
c.) higher than 79oC
o
b.) higher than 100 C
d.) between 79oC and 100oC
I.
Chloroform, CHCl3, and carbon tetrachloride, CCL 4 form ideal solutions. At 70 oC, the
vapor pressure of pure chloroform is 1.341atm, and the vapor pressure of pure
A vessel contains a liquid mixture of 50% toluene by weight at 100 oC. The vapor
pressure at 100oC are as follows:
560 mmHg
What is the average molecular weight of the vapor in contact with the solution?
III.
If toluene is steam distilled at 1atm, calculate the boiling point and the kg of steam
required to carry 5 kg of toluene into the distillate.
Antoines Constant
Benzene
Toluene
6.90565
6.95464
1211.033
1344.800
220.79
219.482