Professional Documents
Culture Documents
2014
PET 113E
INTRODUCTION TO PETROLEUM
AND NATURAL GAS
ENGINEERING ( & ENERGY)
Abdurrahman Satman
Sept. 2014
CONTENTS
World Energy Statistics
-Reserves-Production-Consumption
-Prices, Emissions
-Strategies About Energy
Renewable Energy Geothermal
Turkey Energy Statistics
Energy: Terms and Definitions-Units
Introduction to PNGE
8.9.2014
What is Energy?
8.9.2014
Energy Careers
Engineering
Business
Earth Sciences
Energy Companies
What is ENERGY ?
Energy makes change possible. It moves cars along the road,
bakes food in the oven, lights our homes, operates televisions
and computers, and does a lot more.
8.9.2014
Fossil Fuels;
Oil, Coal,
Natural Gas
Wind
Energy
Geothermal
Energy
Hydro Power and
Ocean Energy
Nuclear Energy
Solar Energy
Clean Fuel
Wood
17. Century
Coal
Petroleum
19. Century
N. Gas
20. Century
Hydrogen
21. Century
8.9.2014
2000
As the primary source, the shift from wood to coal occured in 1885
and from coal to oil in 1960. The question is what is next?
8.9.2014
2013
33.3
Renewable Energy
Sources
Wind
Solar
Non-Renewable Energy
Sources
Nuclear
Oil
Geothermal
Hydro
Power
Biomass
Natural Gas
Coal
8.9.2014
World Energy
2013
ENERGY STATISTICS
TERMS
Energy
Fossil fuels
Primary energy
Secondary energy
Conventional x unconventional energy
Renewable x nonrenewable energy
Supply x demand, production x consumption
Energy density x efficiency x intensity
...
...
8.9.2014
8.9.2014
1
1
1
1
1
1
1
Calorific equivalents
One tonne of oil equvalent (= 7.33 barrels of oil equivalent) equals
approximately:
Heat units
10 million kilocalories
42 gigajoules
40 million Btu
Solid fuels
1.5 tonnes of hard coal
3 tonnes of lignite
3
Gaseous fuels 1111 m natural gas
0.82 tonnes LNG
Electricity*
12 megawatt-hours (energy content of
electricity)
* Primary energy equivalent of one million tonnes of oil or oil equivalent
produces about 4400 gigawatt-hours (=4.4 terawatt-hours) of electricity in a
modern thermic power station with an average thermal efficiency of 37%.
The primary energy equivalent of geothermal energy is calculated assuming an
efficiency of 10% so one million tonnes of equivalent geothermal energy
produces about 1.2 terawatt-hours of electricity.
8.9.2014
iea(2013)
iea(2013)
10
8.9.2014
11
8.9.2014
2011
% change
Population (billion)
5.5
8.1
+27%
25
70
+180%
Coal (Mt)
4 474
7 520
+68%
Oil (Mt)
3 179
3 973
+25%
2 176
3 518
+62%
Nuclear (TWh)
2 106
2 386
+13%
Hydropower (TWh)
2 286
2 767
+21%
12 607
22 202
+76%
21
30
+44%
12
8.9.2014
13 113 Mtoe
World Total
Primary
Energy Supply
from 1971 to
2011 by fuel
(Mtoe)
(IEA, 2013)
BALANCE TABLE
World Total Primary Energy Supply and Consumption (2011),
by fuel (Mtoe)
(IEA, 2013)
13
8.9.2014
(BP, 2013)
14
8.9.2014
(BP, 2013)
113 Years
53
55
(BP, 2013)
15
8.9.2014
(IEA;WEO, 2011)
16
8.9.2014
World Population
10000
WORLD POPULATION
Ref: United Nations, http://esa.un.org/unpp, 2007
9.19
9.19 milyar
billion
%0.50
%0.98
2030
2012
6000
2005
%1.6
4000
%1.9
2.535billion
milyar
2.535
1975
2000
1950 1960 1970 1980 1990 2000 2010 2020 2030 2040 2050
77
YEAR
33
700
600
500
400
2014
Population
20
30
20
20
20
10
20
00
19
90
19
80
300
200
100
0
9
8
7
6
5
4
3
2
1
0
19
60
Population,
Billion Persons
19
70
milyon
Population,
million
Population,
8000
17
8.9.2014
53 Years
(BP, 2013)
18
8.9.2014
(BP, 2013)
19
8.9.2014
(iea, 2013)
20
8.9.2014
(BP, 2013)
21
8.9.2014
U.S. $/Gallon
m
er
G
y
an
I ta
ly
et
N
nd
la
r
he
Gasoline Cost
.
.K
U
.S
U
Taxes
Source: EIA, Weekly Petroleum Status Report
(Average for Jan-May 2004)
(BP, 2013)
22
8.9.2014
Turkey
927
Active Wells
(TPAO, 2012)
23
8.9.2014
Turkey
36
BOPD/Well
(TPAO, 2012)
NATURAL
GAS
24
8.9.2014
118.4 trillion m3
185.7 trillion m3
25
8.9.2014
(BP, 2013)
(BP, 2013)
26
8.9.2014
(BP, 2013)
iea(2013)
27
8.9.2014
Natural Gas
Venezuela
Saudi Arabia
Canada
Iran
Iraq
Kuwait
United Arab Emirates
Russian Federation
Libya
Nigeria
Iran
Russian Federation
Qatar
United States
Saudi Arabia
United Arab Emirates
Venezuela
Nigeria
Algeria
Iraq
(BP, 2013)
28
8.9.2014
Reservoir properties
affects everything
29
8.9.2014
Conventional
Resources
Visible Part
ENERGY ICEBERG
Gas Hydrates
30
8.9.2014
31
8.9.2014
32
8.9.2014
(IEA, 2012)
(IEA, 2012)
33
8.9.2014
(BP, 2010)
34
8.9.2014
Heavy Oil:
Make it Light
Heat Delivery
69
Tar
Sands
Resources Available!
Oil Shale
70
35
8.9.2014
72
Industry has moved from fixed to floating structures to develop oil and gas in deeper water
36
8.9.2014
37
8.9.2014
Source: The End of the Oil Age The Economist, 25 October 2003.
38
Increasing Cost
8.9.2014
COAL
39
8.9.2014
Total reserve: 892 (lignite: 456) billion tonnes, R/P ratio: 113 years
(BP, 2013)
40
8.9.2014
3.88 billion toe 7.8 billion tonnes of total coal (hard coal, lignite and others) by mass
(BP, 2013)
(BP, 2013)
41
8.9.2014
iea(2013)
42
8.9.2014
NUCLEAR ENERGY
(IEA;WEO, 2011)
43
8.9.2014
iea(2013)
Turkey: -
(BP, 2013)
44
8.9.2014
Cooling Towers
HYDROELECTRICITY
45
8.9.2014
(BP, 2013)
iea(2013)
46
8.9.2014
Renewable energy
(BP, 2013)
47
8.9.2014
(BP, 2013)
SECONDARY ENERGY
ELECTRICITY
48
8.9.2014
22 126 TWh
World
Electricity
Generation*
by Fuel
from 1971
to 2011
iea(2013)
iea(2013)
49
8.9.2014
iea(2010)
50
8.9.2014
8 918 Mtoe
Total Final
Consumption
by Fuel from
1971 to
2011 by fuel
(Mtoe)
iea(2013)
3 633 Mtoe
Oil:
Total Final
Consumption
from 1971 to
2011 by
Sector (Mtoe)
iea(2013)
51
8.9.2014
1 380 Mtoe
Natural Gas:
Total Final
Consumption
from 1971 to
2011 by
Sector (Mtoe)
iea(2013)
904 Mtoe
Coal:
Total Final
Consumption
from 1971 to
2011 by
Sector (Mtoe)
iea(2013)
52
8.9.2014
1 582 Mtoe
Electricity:
Total Final
Consumption
from 1971 to
2011 by
Sector (Mtoe)
EMISSIONS
53
8.9.2014
54
8.9.2014
109
Carbon Capture
Types of Carbon
Sequestration
Geologic Sequestration
Ocean Sequestration
Terrestrial Sequestration
Novel Sequestration Concepts
110
55
8.9.2014
Porous rock bodies surrounded by impermeable rock are ideal for CO2 storage
Oil and gas reservoirs: Inject CO2 to improve recovery
Coal bed methane: Inject CO2 into coal seams to extract methane
Inject into deep saline (salt) formations: No direct economic benefit
Geologic Sequestration
111
(Sprunt, 2006)
112
56
8.9.2014
57
8.9.2014
iea(2013)
58
8.9.2014
(IEA;WEO, 2011)
59
8.9.2014
(IEA;WEO, 2011)
(IEA;WEO, 2011)
60
8.9.2014
(IEA;WEO, 2011)
61
8.9.2014
Other Projections
Other Projections
(BP, 2011)
62
8.9.2014
(IEA;WEO, 2011)
(IEA;WEO, 2011)
63
8.9.2014
RENEWABLE ENERGY
64
8.9.2014
Renewable energy
It is any energy resource that is naturally
regenerated over a short time scale and either
derived directly from solar energy (solar
thermal, photochemical, and photoelectric),
indirectly from the sun (wind, hyrdopower, and
photo-synthetic energy stored in biomass), or
from other natural energy flows (geothermal,
tidal, wave, and current energy).
Renewable resources can be converted to
nonrenewable resources if they are depleted or
degraded by humans faster than natural
processes renew them.
129
Renewable Energy
65
8.9.2014
Heat-only
renewable sources
and technologies
Hydro
Geothermal
Wind
Solar thermal
Geothermal
Biomass
(solid, gas,
Liquid)
Tide,wave,
ocean
Solar
photovoltaic
131
(REN21, 2011)
66
8.9.2014
(REN21, 2011)
(REN21, 2011)
67
8.9.2014
135
Renewables - Biomass
Biomass is a collective term for all
organic substances of relatively recent
(non-geological) origin that can be used
for energy production, including
industrial, commercial, and agricultural
wood and plant residues; municipal organic
waste; animal manure; and crops directly
produced for energy purposes. Biomass
can be solid (e.g., wood, straw), liquid
(biofuels), or gaseous (biogases).
136
68
8.9.2014
Biomass Resources
Energy Crops
Woody crops
Corn
Agricultural crops
Waste Products
Wood residues
Temperate crop wastes
Tropical crop wastes
Animal wastes
Municipal Solid Waste
(MSW)
Commercial and industrial
wastes
Soybeans
Sugar Cane
Wood Chips
Municipal
Solid Waste
137
http://www.eere.energy.gov/RE/bio_resources.html
Biogas is produced from the decay or digestion of organic matter and is considered a renewable
resource. The organic matter can be plant or animal waste, such as that found in landfill, agricultural or
forestry waste, sewage, or energy crops, including possibly algae.
69
8.9.2014
Landfill Gasses
Renewables biofuels
Biofuels cover bioethanol, biodiesel, biomethanol,
biodimethylether, biooil.
Liquid biofuels are mainly biodiesel and bioethanol,
both are used as transport fuels. They can be
made from new or used vegetable oils and may be
blended with or replace petroleum-based fuels.
The natural plant feedstock includes soya,
sunflower and oil seed rape oils.
Biodiesel
Bus
70
8.9.2014
Renewables hydropower
Potential and kinetic energy of water are converted into
electricity in hydroelectric plants. It includes large as
well as small hydro, regardless of the size of the plants.
Electrical
Energy
Potential
Energy
Electricity
Kinetic
Energy
Mechanical
Energy
Solar Panel
71
8.9.2014
Solar PV Applications
Spacecraft
Probably the most successful use of solar
panels is on spacecraft, including most
spacecraft that orbit the Earth and Mars,
and spacecraft going to other destinations
in the inner solar system. In the outer solar
system, the sunlight is too weak to produce
sufficient power and radioisotope thermal
generators are used.
Residential
Solar arrays can provide electricity and hot water to residences in
isolated, well-lighted areas
Generate
electricity
Schematic
10 megawatt
solar thermal
central
receiver
power plant,
Solar I.
72
8.9.2014
(REN21, 2011)
(REN21, 2011)
73
8.9.2014
Resource
Potential
Wind Power
Density at 50 m
W/m2
Wind Speed
at 50 m
m/s
Wind Speed
at 50 m
mph
1
2
3
4
5
6
7
Poor
Marginal
Fair
Good
Excellent
Outstanding
Superb
0 200
200 300
300 400
400 500
500 600
600 800
> 800
0.0 5.9
5.9 6.7
6.7 7.4
7.4 7.9
7.9 8.4
8.4 9.3
> 9.3
0.0 13.2
13.2 15.0
15.0 16.6
16.6 17.7
17.7 18.8
18.8 20.8
> 20.8
74
8.9.2014
kW
1500
1000
500
mph
10
20
m/s
4.5
8.9
30
149
40
50
13.4
2006
5 MW
600
Offshore
Wind
Farms
Larger
Turbines
75
8.9.2014
Renewables
tide/wave/
ocean
energy
152
76
8.9.2014
Renewables hydrogen
Hydrogen is like electricity in that it is an energy carrier,
not a primary source-it is derived from the conversion of
some other form of energy. It can be manufactured from
a variety of sources, including natural gas, coal, nuclear
energy and all forms of renewable energy.
When used as a fuel in combustion processes or in fuel
cells, hydrogen has minimal emissions relative to
conventional fuels.
Potential end uses of hydrogen include fuel cell vehicle
technology as well as stationary power generation.
As a potential complement to electricity as one of the two
primary long-term energy carriers, hydrogen ultimately
could offer a transition from todays energy mix that is as
significant as that from wood to coal, or coal to oil.
Hydrogen-Powered
Vehicles
Renewables hydrogen
Although hydrogen has about three times the energy
density of gasoline per kilogram, making it ideal as a
rocket fuel, it has a very low energy density on a
volumetric basis.
This poses significant economic and technical challenges
to the transmission and storage of hydrogen.
Hydrogen vs. Methane
Units Hydrogen Methane
Density
kg/m3
0.0887
0.707
Gravimetric Energy
MJ/kg
142.0
55.6
Volumetric Energy
MJ/m3
12.7
40.0
77
8.9.2014
Disadvantages of Hydrogen
Renewables geothermal
Geothermal energy is the energy in the form of
natural heat flowing outward from within the
earth and contained in rocks, water, brines, or
steam. This heat is poduced mainly by the decay
of naturally occuring radioactive isotops of
thorium, potassium, and uranium in the earths
core.
It is exploited at suitable sites:
* For electricity generation usuing dry steam or
high enthalpy brine after flashing
* Directly as heat for district heating,
agriculture, etc.
156
78
8.9.2014
Heat flow outward from Earths interior. The crust insulates us from
Earths interior heat. The mantle is semi-molten, the outer core is liquid
157
and the inner core is solid.
Renewables geothermal
Earth Core
It is the central region of the earth, originating at a depth
of about 2900 km, outside of which are the mantle and the
crust.
It is thought to consist of a molten outer core and a solid
inner core; the temperature of the inner core is not known
but has been estimated at 5000-7000oC.
Crust
It is the outermost region of the earth, from the surface
itself to a depth of about 70 km beneath land surfaces
(continental crust) and 10 km below ocean surfaces (oceanic
crust).
158
79
8.9.2014
http://www.worldbank.org/html/fpd/energy/geothermal/technology.htm
Renewables geothermal
Geothermal reservoir:
It is a subsurface system consisting of a large volume of hot
water and steam trapped in porous and fractured hot rock
underneath a layer of impermeable rock; some reservoirs can
be commercially developed as an energy source.
Geothermal system:
It is a localized geological environment in which circulating
steam or hot water carries some of the earths natural
internal heat flow close enough to the surface to be employed
for productive human use. It describes the total hydrological
system consisting of the reservoir and its natural recharge
and discharge parts.
160
80
8.9.2014
162
http://www.geothermal.ch/eng/vision.html
81
8.9.2014
163
Natural steam from the production wells power the turbine generator.
The steam is condensed by evaporation in the cooling tower and pumped down
an injection well to sustain production.164
82
8.9.2014
165
http://www.ees4.lanl.gov/hdr/
83
8.9.2014
Since Roman times, we have piped the hot water into pools to better control
the temperature. These are photos of outdoor and indoor pool and spa bathing
in Turkey, Japan, the US, and Europe.168
84
8.9.2014
Hot water from one or more geothermal wells is piped through a heat
exchanger plant to heat city water in separate pipes. Hot city water is
piped to heat exchangers in buildings
170to warm the air.
85
8.9.2014
86
8.9.2014
NPC/USA, 2007
NPC/USA, 2007
87
8.9.2014
88
8.9.2014
NPC/USA, 2007
89
8.9.2014
Turkey
ENERGY STATISTICS
DNYA
DER
%13
D. GAZ
%24
KMR
%30
TRKYE
DER
%14
D. GAZ
%31
PETROL
%33
KMR
%31
PETROL
%26
(ETKB, 2013)
90
8.9.2014
+121
2012
Nfus art
Hayat kolaylatran fakat ek enerji
talep eden yeni teknolojiler ve
tketici rnlerinin artmas (hayat
standartn ykseltme abalar)
ehirleme
Sanayileme
-
Growth in Population
Better Living Standards
Urbanization
Industrialization
91
8.9.2014
100.0
%0.34
10000
98.95 milyon
9.19 milyar
%0.95
%0.50
8000
TRKiYE
%1.9
60.0
%0.98
2005
%1.6
40.0
2030
DNYA
4000
%1.9
2.535 milyar
21.48 milyon
20.0
%2.6
6000
Nfus, milyon
Nfus, milyon
80.0
1975
http://esa.un.org/unpp (2007)
2000
1950 1960 1970 1980 1990 2000 2010 2020 2030 2040 2050
YIL
92
8.9.2014
+
Hidrolik Dier
Hidrolik
Kmr
OHBA*
%63
OHBA
Petrol
%8
Kmr
Hidrolik Dier
OHBA
Hidrolik
Kmr
Petrol
%26
Dier
Dier
Kmr
OHBA
D. Gaz
Petrol
%26
2012
1990
Kmr
Kmr
D. Gaz
%31
Petrol
%45
1970
Dier
Hidrolik
OHBA
Kmr
OHBA
D. Gaz
Petrol
%42
1950
OHBA
%56
Hidrolik
Petrol
Hidrolik
OHBA
D. Gaz
Kmr
%55
Petrol
%7
Petrol
%0.4
Trkiye/Dnya Oran, %
Kii bana enerji ve
elektrik tketimi dnya
ortalamasndan dk!
Nfus: 1.1
Birincil Enerji Tketimi: 0.9
Elektrik Tketimi: 1.0
Fosil
Kaynaklar
Rezerv
retim
Tketim
Kmr
0.2
0.5
0.9
Petrol
0.02
0.03
0.8
Doalgaz
0.004
0.06
1.2
Kaynak
fakiriyiz
thalata
bamlyz
Primary energy and electricity consumption per capita for Turkey is lower
than the world average. Turkey is poor in reserves and production of fossil
fuels. Only the gas comsumption per capita is above the world average.
93
8.9.2014
(TPAO, 2014)
94
8.9.2014
2,4
2012
2013
95
8.9.2014
Southeastern Anatolia:
Oil Production
(PGM, 2012)
96
8.9.2014
Seismic Explorations
(TPAO, 2014)
Exploration;
1770
Production;
1703
(PGM, 2013)
97
8.9.2014
Oil in Place
Producible
Reserve
Cumulative
Production
Remaining
Producible
Reserve
98
8.9.2014
Kurtarm
API
Yerinde
Petrol
Miktar
(milyar
varil)
Oran
(RF,
%)
Toplam
Petrol
retimi
(milyon
varil)
Kalan
retilebilir
Petrol Miktar
(milyon varil)
API < 18
2.64
215
8.1
119
97
1.20
260
21.7
181
79
26 < API
0.84
247
29.4
211
35
15.4
511
TPAO
API Gravity
4.68
Oil in Place
(billion barrel)
722
Producible
Reserve
(million barrel)
Recovery Cumulative
Factor, % Production
(million barrel)
211
Remaining
Producible
Reserve
(million barrel)
(TPAO, 2009)
99
8.9.2014
51% is imported from Iran, 17% from Iraq, 12% from Russia, and 2% from Saudi Arabia.
100
8.9.2014
101
8.9.2014
Industry; 20%
Power Generation;
56%
(EPDK, 2011)
102
8.9.2014
Gas in Place
Producible
Reserve
Cumulative
Production
Remaining
Producible
Reserve
103
8.9.2014
(EPDK, 2011)
104
8.9.2014
(National Pipelines)
105
8.9.2014
106
8.9.2014
Existing Planned)
Planned
International Natural Gas Pipeline Projects (Existing,
Planlanan
Mevcut + Planlanan)
Uluslararas Doal Gaz Boru Hatt Projeleri (Mevcut
(BOTA, 2013)
107
8.9.2014
Transit and
Trade Income
Security and
Diversification
of Supply
108
8.9.2014
109
8.9.2014
(3%)
(20%)
(0.8%)
(5%)
(18%)
(4%)
Yllk
Tketim,
109 m3
Depo
Says
Depolama
Kapasitesi,
109 m3
Depolama
Kapasitesi/Yllk
Tketim, %
Depolama
Kapasitesi/Konutsal
Tketim, %
ABD
657
417
110
17
48
Rusya
420
23
90
21
61
Ukrayna
60
13
34
57
109
Almanya
82
41
19
23
105
Fransa
44
15
12
27
52
talya
78
10
12
15
65
Trkiye
~38
1.6
18
110
8.9.2014
Trkiyenin
lk ve Tek
Yeralt
Doal Gaz
Depolama
Tesisi:
TPAO Silivri
DGYDT
Kuzey
Marmara
Doal Gaz
Sahas
(TPAO, 2012)
111
8.9.2014
(TPAO, 2012)
(TPAO, 2014)
112
8.9.2014
Coal in Turkey
Trkiyede Kmr
Linyit rezervi ~14 milyar ton ve takmr rezervi 1.3
milyar ton kadardr. ETKBna gre son 5 yl iinde 3.2
milyar ton ek linyit rezervi tespit edilmitir.
2012 ylnda yerli kmr retimi linyit iin 77 ve ta
kmr iin 2.3 milyon ton ve ta kmr ithalat 23
milyon ton oldu.
Linyitten elektrik retim potansiyeli toplam 120 milyar
kWh/yldr. Not: Bu potansiyel 8.3 milyar ton linyit
rezervi iin geerliydi. Yeni rezerve (14 milyar ton)
gre potansiyel yeniden hesaplanmal!
Linyitlerimizin sl deeri dktr (toplam rezervin
%66snn sl deeri=1000-2000 Kcal/kg).
(ETKB, 2013)
113
8.9.2014
2013 Yl Trkiye
Linyit Rezervleri
114
8.9.2014
(ETKB, 2013)
115
8.9.2014
Electricity - Turkey
116
8.9.2014
* Temmuz 2014
itibariyle kurulu
g 67.4 bin MW
oldu.
(DEKTMK, 2011)
117
8.9.2014
Kurulu G*, MW
KARA
DENZ
TOPLAM
47 849
10 464
~58 Bin
Parabolik
Aynal Sistem
PV Sistem
118
8.9.2014
II
I
NAFZ
III
V
EAFZ
VI
VI
IV
IV
20 oC
20 - 45 oC
45 - 75 oC
75 - 100 oC
T> 100 oC
__
Faults
I
Aegean Geothermal Region
Western Anatolia
II
Ankara Geothermal Region
III Kayseri Geothermal Region
Central Anatolia
VI Amanos Geothermal Region
V
Erzurum Geothermal Region
VI Diyarbakr Geothermal Region Eastern Anatolia
NAFZ Northern Anatolian Fault Zone
EAFZ Eastern Anatolian Fault Zone
119
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: Gen Volkanlar
__: Faylar
Scaklk Aral, oC
25.2-30
30-40
40-50
50-60
60-70
70-80
80-90
90-100
100-120
120-150
150-278.4
2 705 MWt
310 MWe(~6200MWt)
~ 9 000 MWt
Elektrik
120
8.9.2014
Hidroelektrik
Teorik Potansiyel: 442 milyar kWh
Teknik Potansiyel: 237 milyar kWh
Teknik-Ekonomik Potansiyel: 216 milyar kWh*
Kurulu G: 22.3 bin MW (2013)
retilen Elektrik: ~ 60 milyar kWh (2013)
Kapasite Kullanm: %32 (2013)
* Kaynak: DS(2014)
CONCLUSIONS-1
SONULAR-1
Trkiye birincil enerji kaynaklar tketiminde
stratejik enerji kaynaklar olan fosil kaynaklarn
pay %88dir.
Trkiye kiibana enerji tketiminde dnya
ortalamasnn altnda olup, fosil kaynak
rezervlerinde fakir saylabilir, ithalat bamls
bir lkedir.
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CONCLUSIONS-2
SONULAR-2
Trkiye, 2020 ylna kadarki 6 yllk dnemde bugnk
elektrik retim kapasitesini %60-70 artrmak
durumundadr.
Rzgar dahil tm yenilenebilir enerji kaynaklar ve
yerli konvansiyonel enerji kaynaklarmzn tamam
kullanlsa dahi, talebin karlanmas olanakl
grlmemektedir.
Enerjide da bamll azaltmak iin Trkiyenin
enerji yatrm portfynde enerji tr
eitlendirilmesi asndan mmkn olan her enerji
trnn yer almas zorunludur.
Rezerv ve potansiyel deerleri statik deildirler,
rakamlar gncellenmelidir.
Energy
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Energy
It is defined classically as the capacity to do work.
It is used to perform useful functions for humans,
such as heating or cooling buildings, powering
vehicles and machinary, lighting, coolking foods, and
so on.
Forms of energy: Potential energy, kinetic energy,
thermal energy, nuclear energy, electromagnetic
energy, and gravitational energy.
Energy can be transformed from one form to
another. For example, a steam turbine converts
thermal energy to mechanical energy.
A form of matter that can transport energy from
one point to another, e.g., electricity, hydrogen. So
they are called energy carriers.
Energy
123
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Energy
Forms of Energy
124
8.9.2014
125
8.9.2014
(IEA;WEO, 2011)
(IEA;WEO, 2011)
126
8.9.2014
Classification
and definition
of coal types
(IEA;WEO, 2011)
127
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Fuel
Any substance burned as a source of heat
or power. The heat is derived from the
combustion process in which carbon and
hydrogen in the fuel substance combine
with oxygen and release heat.
The provision of energy as heat or power in
either mechanical or electrical form is the
major reason for burning fuel.
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Secondary
Petrolum products
Manufactured
solid
fuels and gases
Biofuels
Renewables
Non
Renewables
Nuclear
Combustible
Coals
Crude oil
NGLs
Natural gas
Oil shale
Wastes
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Conventional energy
It describes energy sources that have been
widely used in the industrial world for an
extended period of time, such as petroleum,
natural gas, or coal, as opposed to alternative
sources such as wind or solar energy. Large scale
hydropower and nuclear power generation are
usually also considered conventional forms of
energy.
Conventional oil and gas
It is a term for oil and gas obtained by
traditional production methods (e.g., well drilling)
from deep-lying geologic formations, rather than
from unconventional sources such as shale, tar
sands, coalbed methane, biofuels, and so on.
Nonrenewable energy
It describes the energy source formed
and accumulated over a very long period
of time in the past, such as a fossil
fuel, whose rate of formation is many
orders of magnitude slower than the rate
of its use, so that it will be depleted in
a finite time period at the current rate
of consumption.
It is not renewed at a rate comparable
with human use; likely to be effectively
depleted or exhausted at some future
date.
262
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From:
gal U.S.
gal U.K.
bbl
ft3
m3
multiply by:
0.8327
0.02381
0.1337
3.785
0.0038
1.201
0.02859
0.1605
4.546
0.0045
Barrel (bbl)
42.0
34.97
5.615
159.0
0.159
7.48
6.229
0.1781
28.3
0.0283
Liter (l)
0.2642
0.220
0.0063
0.0353
0.001
264.2
220.0
6.289
35.3147
1 000.0
266
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kg
lt
st
lb
multiply by:
Kilogram (kg)
0.001
9.84x10-4 1.102x10-3
2.2046
Tonne (t)
1000
0.984
1.1023
2204.6
1016
1.016
1.120
2240.0
907.2
0.9072
0.893
2000.0
Pound (lb)
0.454
4.54x10-4
4.46x10-4
5.0x10-4
267
TJ
Gcal
Mtoe
MBtu
GWh
multiply by:
Terajoule (TJ)
238.8
2.388x10-
947.8
0.2778
Gigacalorie
4.1868x10-3
10-7
3.968
1.163x10-3
Mtoe*
4.1868x104
107
3.968x107
11630
Million Btu
1.0551x10-3
0.252
2.52x10-8
2.931x10-4
Gigawatt-hour
3.6
860
8.6x10-5
3412
268
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Units of Measure
Pressure
1 Pascal (Pa) = 1 Newton / square meter
100 kPa = ~ 1 atmosphere = ~14.5 psi
1 MPa = ~10 atmospheres = ~145 psi
Temperature
Celsius (C); Fahrenheit (F); Kelvin (K)
0 C = 32 F = 273 K
100 C = 212 F = 373 K
269
Crude oil*
From
Tonnes (metric)
1
Kilolitres
0.8581
Barrels
0.1364
US gallons
0.00325
Barrels per day
Products
Liquefied petroleum gas (LPG)
Gasoline
Kerosene
Gas oil/diesel
Fuel oil
kilolitres
1.165
1
0.159
0.0038
To convert
barrels
tonnes
to tonnes
to barrels
Multiply by
0.086
11.6
0.118
8.5
0.128
7.8
0.133
7.5
0.149
6.7
US
barrels
gallons
Multiply by
7.33
307.86
6.2898
264.17
1
42
0.0238
1
kilolitres
to tonnes
tonnes
to kilolitres
0.542
0.740
0.806
0.839
0.939
1.844
1.351
1.240
1.192
1.065
tonnes
per year
BP, 2009
49.8
To
Natural gas and
Liquefied natural gas
From
1 billion cubic metres NG
1 billion cubic feet NG
1 million tonnes oil equivalent
1 million tonnes LNG
1 trillion British thermal units
1 million barrels oil equivalent
billion cubic billion cubic million tonnes million tonnes trillion British million barrels
metres NG
feet NG oil equivalent
LNG
thermal units oil equivalent
Multiply by
1
35.3
0.90
0.73
36
6.29
0.028
1
0.026
0.021
1.03
0.18
1.111
39.2
1
0.805
40.4
7.33
1.38
48.7
1.23
1
52.0
8.68
0.028
0.98
0.025
0.02
1
0.17
0.16
5.61
0.14
0.12
5.8
1
270
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Units
1 metric tonne = 2204.62 lb = 1.1023 short tons
1 kilolitre = 6.2898 barrels = 1 cubic metre
1 kilocalorie (kcal) = 4.187 kJ =3.968 Btu
1 kilojoule (kJ) = 0.239 kcal = 0.948 Btu
1 British thermal unit (Btu) = 0.252 kcal = 1.055 kJ
1 kilowatt-hour (kWh) = 860 kcal = 3600 kJ = 3412 Btu
BP, 2009
Calorific equivalents
One tonne of oil equivalent (Toe) equals approximately:
Heat units
Solid fuels
Gaseous fuels
Electricity
Joules
per hour
3.6 MJ
3.6 TJ
per year
31.54 GJ
31.54 PJ
Kilowatt-hours
per year
8760
8.76x109
Oil equivalent
per year
0.75 toe
0.75 Mtoe
Coal equivalent
per year
1.1 tce
1.1 Mte
Other Quantities
Quantity
Mass
Length
Speed
Area
Volume
Energy
Power
Unit
1 lb (pound)
1 t (tonne)
1 ft (foot)
1 yd (yard)
1 mi (mile)
1 km hr-1 (kph)
1 mi hr-1 (mph)
1 knot
1 acre
1 ha (hectare)
1 litre
1 gal (UK)
1 gal (US)
1 eV (electron-volt)
1 HP (horse power)
SI equivalent
= 0.4536 kg
= 1000 kg
= 0.3048 m
= 0.9144 m
= 1609 m
= 0.2778 m s-1
= 0.447 m s-1
= 0.5144 m s-1
= 4047 m2
= 104 m2
= 10-3 m3
= 4.546x10-3 m3
= 3.785x10-3 m3
= 1.602x10-19 J
= 745.7 W
Inverse
1 kg = 2.205 lb
1 kg = 10-3 t
1 m = 3.281 ft
1 m = 1.094 yd
1 m = 6.214x10-4 mi
1 m s-1 = 3.6 kph
1 m s-1 = 2.237 mph
1 m s-1 = 1.944 knots
1 m2 = 2.471x10-4 acre
1 m2 = 10-4 ha
1 m3 = 1000 litre
1 m3 = 220.0 gal (UK)
1 m3 = 264.2 gal (US)
1 J = 6.242x1018 eV
1 W = 1.341x10-3 HP
272
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Sub-Multiple
deca (da)
hecto (h)
kilo (k)
mega (M)
giga (G)
tera (T)
peta (P)
exa (E)
10-1
10-2
10-3
10-6
10-9
10-12
10-15
10-18
deci (d)
centi (c)
milli (m)
micro ()
nano (n)
pico (p)
femto (f)
atto (a)
273
INTRODUCTION TO
PETROLEUM & NATURAL GAS
137
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138
8.9.2014
139
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Petroleum
280
140
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Petras
Oleum
Rock
Oil
Crude Oil
Raw oil
Natural Gas
CH4
141
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What is
Petroleum?
Crude Oil
Natural Gas
Crude oil : The word petroleum means rock-oil. The word comes from
the Greek words petras meaning rock and oleum meaning oil. Petroleum is
basically made of lots of hydrogen and carbon molecules. The oil that we
find in the ground is not exactly the same as the oil or gasoline you put in
your car. We call raw oil from the ground crude oil. Crude oil can be
straw-colored, black, dark green, brown, or red. It can be very thick like
honey to very thin
Natural Gas : Petroleum can also be gas. We call petroleum gas Natural
Gas. Natural gas is primarily methane, CH4.
Natural Gas
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Antifreeze
Fuel
Refrigerants
Synthetic Rubber
Each item shown here either
1) was made from a petroleum product,
2) was manufactured with machines that Paint
used fossil energy for heat or power, or
3) used a petroleum as energy to move
Food Preservatives
Wire Coatings
Dyes
Vitamin
capsules
Gasoline
Plastics
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Petroleum
(Organic Theory to explain the origin of oil)
It assumes that both the hydrogen and carbon that make up petroleum
which is an organic substance derived from the remains of plants and animals
living on land and in the sea .
Millions of years ago, rains washed prehistoric plant and animal remains into
the seas along with sand and silt, and layer upon layer piled up on the sea
bottom. The layers of organic material were compressed under the weight of
these sediments, and the increasing presure and temperature changed the
mud, sand and silt into rock and the organic matter into petroleum. This rock
is refered to as source rock.
In the beginning
Earth started out as a
mass of molten rock
Surface cooled and
formed a hard crust
With time the earth
shrank and the crust
buckled and formed hills
and valleys
Water condensed to
form oceans
Convection currents within
the earths mantle caused
the crust to move
Mountains built and
destroyed
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Nile Delta
Formation of Beds
146
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Rock
Compaction
Sandstone consists primarily
of quartz (SiO2).
Rock
Compaction
147
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Petroleum Formation
Organic Theory
Rivers carried both rock sediments and organic materials
Materials covered by sand and silt isolated from oxygen and decay
Over time, pressure, temperature and bacteria converted organic
material to petroleum
Petroleum Reservoirs
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Anticline
Water
Fault
Stratigraphic
Salt Dome
Lenses in
sand/limestone
Oil and
Cap
Rock
Gas
(Gas Cap)
Oil
Water
(Aquifer)
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Hydrocarbon Reservoirs
Requirements for a
Hydrocarbon Reservoir
A source: material from which hydrocarbon is
formed: carbon and hydrogen, the remains of land
and sea life that was buried in the mud and silt of
ancient seas or bodies of water.
Porous and permeable beds in which hydrocarbons
may migrate and accumulate after being formed.
A trap: subsurface condition restricting further
movement of hydrocarbons such that it may
accumulate in commercial quantities.
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Water Influx
If the pressure in the oil (or gas) reservoir is
reduced below the pressure in the aquifer,
water will flow from the aquifer into the oil
reservoir.
If producing wells are drilled and completed
in the oil-bearing zone, the pressure in the oil
reservoir decreases as oil is produced.
Water influx displaces oil to the producing
wells and helps to maintain the reservoir
pressure.
Natural Water Drive
Summary
We may define a reservoir as an
accumulation of hydrocarbon in porous
permeable sedimentary rocks.
A reservoir is a combination of physical
conditions that will cause hydrocarbon
liquids and/or gases and water to
accumulate in porous and permeable
rock and prevent them from escaping
either laterally or vertically.
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Summary
A reservoir consists of an impervious
cover or cap rock overlying a porous and
permeable rock.
The density differences between the
oil, gas and water phases can result in
boundary regions between them known
as fluid contacts (oil-water and gas-oil
contacts).
Petroleum
comes from
underground
Petroleum
Traps or
from
petroleum
reservoirs.
304
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1.Finding
&Drilling
4. Refining
2. Pumping
3. Transporting
5. Selling Products
153
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154
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Geophysicists
Seismic studies to map the subsurface structure
155
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Geology:
Geophysics:
Subsurface Mapping
Sound waves are sent into the ground at one point. These waves are
reflected off the layers of rock and are measured by lines of detectors on
the surface (geophones).
Sound
Laser
waves
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Geophysical Study
Seismic Activity
Seismic
Modern-day oil prospectors use sound waves to locate oil. In one technique,
(1) a signal is sent into the rock by a vibrator truck, (2) the reflected waves
are received by geophones, and (3) the data is transmitted to a laboratory
truck.
Geophysical
Study
Seismic Maps
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View of A Reservoir
158
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Exploration
Geologists and
Geophysicists generate
subsurface contour maps
identify possible traps.
Contour lines join points at
the same subsurface depth.
Exploration (Contd)
Drilling Engineer
Reservoir Engineer
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Getting to it (Drilling)
After we have an idea of where
petroleum is located we have to get to it.
Many times petroleum is very deep within
the ground. To get to petroleum we drill
a hole anywhere from 13 to 4 in
diameter into the ground. (Drilling Rig)
Drilling Activity
Offshore
Platform
Onshore
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Types of Drilling
Conventional
Directional
Horizontal
Not all wells are straight and vertical. Horizontal drilling has
become a very profitable way to increase production by having the
wellbore contacting more of the formation.
Drilling
for Oil
322
161
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Offshore platforms
Drilling Activity
The parts of a conventional
drilling rig
163
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Glossary/Terms
Bottom hole pressure: This is the pressure at the bottom of the
wellbore at or near the depth of the oil producing formation rock and
it is usually measured in pounds per square inch (psi). This pressure is
imposed on the walls of the wellbore. It is the sum of all pressures
imposed, including hydrostatic column pressure, annular pressure (due
to drilling mud going up the annular space carrying rock cuttings), and
pressure imposed by the rotating drill bit.
Formation pressure: It is the pressure of the formation fluid within
the pore spaces (the pores are the spaces between the grains of the
rock) of the formation rock.
Fracture gradient or formation fracture pressure: Pressure above
which injection of fluids (drilling mud) will cause the rock formation to
fracture hydraulically.
Porosity: It is ratio of the formation rocks pore volume to its total
volume.
Permeability: It is the property of rocks that is an indication of the
ability for gases or fluids to flow through rocks.
Drilling Activity
1.
2.
3.
4.
Place the drill bit, collar and drill pipe in the hole.
Attach the rotary table and begin drilling.
As drilling progresses, circulate mud through the pipe.
Add new sections (joints) of drill pipes as the hole gets deeper.
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Wellbore or
borehole
Drilling fluid, also called drilling mud, is used: (1) to lubricate the bit so it
doesnt get stuck and (2) to flush the rock pieces (cuttings) to the surface.
These cuttings are examined by a mud logger, who looks for signs of oil and gas.
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Drill
Bit
Rotary Table
167
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Lost Circulation
If the bottom hole pressure
of the mud column in the
wellbore exceeds the
formation pressure of the
rock, the drilling mud will
infiltrate the formation.
Well Kick
If the bottom hole pressure
falls below the formation
pressure a gas/oil kick from
the formation into the
wellbore occurs. If the kick is
not controlled, it can lead to
a blow-out, which represents
one of the most severe
threats associated with oil
and gas exploration.
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Surging is caused by the drill string being lowered into the hole at a fast rate
pushing drilling mud ahead of it which will surge against the formation rock at a
bottom hole and may cause the drilling mud to infiltrate the formation.
Swabbing is caused by removing the drill string from the wellbore which causes
formation fluid to infiltrate into the volume previously displaced by the drill string.
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Once a well has been drilled, a logging tool is lowered down the well on
electrical wire. Logging tools are special sensors that measure properties of
the rock surrounding the borehole, with results recorded.
Well Logging
Many different kinds of well logs have been developed. The Gamma Ray tool
shows rock layer boundaries and shale content. The Neutron Log is a porosity
measurement tool. Since salty water conducts electricity while oil and gas do
not, electrical resistivity logs can be used to detect the presence of oil and gas
in the pore spaces.
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Core Sampling
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Well Treatment
Wells often may be treated to improve the natural
drainage pattern, or to remove barriers within the
production fluid (oil, gas or geothermal water)-bearing
formation which prevent easy passage of fluids into the
well bore.
Opening up new channels in the rock for the oil and gas
to flow through is called stimulation. Two stimulation
treatments are commonly used: (1) hydraulic fracturing
to split the rock and prop it open with proppants, (2)
injection of acid to partially dissolve the rock, (3) or use
of other special chemicals such as injecting chemicals to
break emulsions (mixture of oil and water forming a very
thick mass which impairs flow of fluids to the well bore).
Hydraulic Fracturing
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Vertical vs.
Horizontal
Formation
Exposure and
Fracturing
Stages
173
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(AllConsulting, 2012)
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Frac Equipment
(Trucks, tanks, engines,...)
Acidizing
Acid
2 + 3
Hydrochloric
Acid
Calcium
Carbonate,
Limestone
2 + 2 + 2
Calcium
Chloride
Water
Carbon
Dioxide
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Producing it/Getting to it
After we reach the petroleum we have to get it to
the surface of the earth. Sometimes when oil, gas,
and water underground are under a lot of pressure at
first, it naturally flows to the surface. If not, we
have to pump it or find other ways to make it flow to
the surface.
Sometimes gas is injected at the bottom of the well,
and as it expands, it lifts the oil up to the surface.
This is called gas lift.
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(API, 1979)
The energy in the gas or salt water (brine) occuring under high pressures with the oil
that creates the force to drive or displace the oil through and from the pores of the
reservoir into the wells.
Oil has dissolved gas that
emerges and expands as the
reservoir pressure is reduced.
Gas drives oil through the
reservoir toward the wells and
assists in lifting it to the surface.
Dissolved-gas drive
Gas-cap drive
Water drive
Seal
Straw
Pepsi
Cola
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Expansion of free
gas
Evolution of dissolved
gas
Flow of mixture of
gas and liquid up
straw
Cola and
Pepsi
and
Gas
Gas
Expands
Gas
Evolves
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PA
PA
P
Poi
Crude Oil
1.31BBL
PB
Free Gas
676 ft3
Free Gas
567 ft3
Crude Oil
1.04BBL
Crude Oil
1.00BBL
Free Gas
2.99 ft3
Crude Oil
1.333BBL
Crude Oil
1.21BBL
PA=3500 psia
PB=2500 psia
P=1200 psia
PA=14.7 psia
PA=14.7 psia
T=160 oF
T=160 oF
T=160 oF
T=160 oF
T=60 oF
PA=Poi=initial pressure,
Note: Bubble point pressure is the pressure at which the first bubble of the
gas leaves the liquid phase.
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Gas
Surface
Stock
Tank
Crude Oil
Water
Well
Oil, or
RESERVOIR
Oil+Gas, or
Oil+Gas+Water
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Gas
Condensate ?
Surface
Water
Well
Gas, or
Gas+Water
RESERVOIR
Production Pump
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(API, 1979)
SANDSTONE
Open-Hole Completion:
When the oil-producing
zone is not loose, the
hole is left open; barefoot completion.
(API, 1979)
Completion With a
Casing: Drilling a well
without a tubing. Casing
is used to conduct fluids
to surface; geothermal
well completion
182
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Separators
Well fluids produced at the well
head may be a mixture of oil, gas,
and water. Thus they must be
separated into oil, gas, and water.
The equipment used to separate
the liquids from the gases is
referred to as a separator. An oil
and gas separator is a small tank in
which the force of gravity is used
to separate the oil and gas. Oil,
being heavy compared to the gas,
falls to the bottom of the tank
from which it goes into storage
tanks. Gas, being lighter, rises to
the top of the tank and goes from
there into a gas-gathering system.
Separators
(API, 1979)
(API, 1979)
In a horizontal separator, the oil and gas mixture enters at inlet A. The mixture hits
a baffle (B) where the heavier liquids fall to the bottom of the tank while the gas
and spray rise. The the wet gas passes through a chamber (C) and a mist extractor
(E) where liquid particles are removed from the gas.
The liquid moves along the bottom of the tank to the oil outlet (H) and the gas goes
through the top portion of the tank and into the gas outlet (F).
A horizontal oil and gas separator; gas flow follows the path
shown by the arrows, oil is withdrawn through the oil outlet H.
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Storage Tanks
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Well Testing
There are a large number of types of well tests, and each is conducted to obtain
certain information about the well, the reservoir, and the fluids produced. A list of
common well-tests:
Fluid Measurements
Oil flow rate: BBL/day, (m3/day or tonne/day)
Gas flow rate: MSCF/day or MMSCF/day (sm3/day)
Water flow rate: BBL/day, (m3/day or tonne/day)
Oil gravity, gas gravity, water salinity
M=103, MM=106
Well Testing
Potential Test
It is a measurement of the largest amount of oil and gas a well will produce in
a daily period under fixed conditions. This test is normally made on each
newly completed well and often during its production life. Producing
allowables (proper production rates) are determined according to the results
of the tests, and the results are used to design the proper size of the
surface production equipments.
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Productivity Tests
Well Testing
Productivity tests are conducted on oil, gas, and geothermal wells, and
include both the potential test and the bottom-hole pressure test. The
purpose of this test is to determine the effects of different flow rates
on the pressure within the reservoir. The maximum potential rate of flow
can be calculated without risking possible damage to the well which might
occur if the well rate produced at its maximum possible flow rate.
+
Reservoir Drives
Natural Energy
What causes oil to flow from reservoirs?
-
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Water Drive
Production Behavior
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Perforating
12-15% of OOIP
Hydraulic Fracturing
Water Injection
Gas Injection
Water is injected into reservoirs for two reasons: (1) to increase the oil
recovery, (2) to dispose of salt water that is produced with oil. Gas is
injected into an oil reservoir to increase recovery of oil. Both water and gas
displace oil and force it to flow toward the production wells.
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Steam-assisted
gravity drainage
(SAGD) process
for producing
heavy oil.
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Porosity
Porosity is
defined as the
ratio of the
pore volume
(the void space)
in a rock to the
bulk volume of
that rock.
The greater the
porosity, the
more fluid the
reservoir can
hold.
Porosity
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SATURATION
Saturation of A Fluid in Porous Media =
Volume of the Fluid in Pores/Pore Volume
So, Sw, Sg : Oil, water and gas saturation,
respectively.
So=Volume of Oil/Pore Volume
So+Sw+Sg=1.0
If only oil and water exist in pores:
So+Sw=1.0
SH=Hydrocarbon saturation=So+Sg
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Permeability
It is a measure of the rocks
capacity to transmit fluids.
Viscosity
Viscosity is a measure of the internal friction of a
fluid the resistance to flow.
Milk thin,
lower viscosity
Honey thick,
higher viscosity
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co
1 V
V P T
Example
A sample of reservoir oil was placed in a PVT cell at
5000 psig and 220 oF. The volume was 59.55 cc.
Pressure was reduced to 4000 psig and the volume
increased to 60.37 cc. Calculate co.
Solution
co
1 59.55 60.37
13.76 106 psi-1
59.55 5000 4000
Fluid Compressibility
Relative change in fluid volume related to a change in
pressure Fluid Compressibility in a container of a
constant volume of 200 liter is schematically shown below.
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Pore
t0 = 0, p0 = pres
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Example
The density of a stock-tank oil at 60 oF is
51.25 lbm/cu.ft. Calculate the specific gravity
and API gravity.
o o
w
Specific Gravity
51.25
0.8217
62.37
API gravity
API
141.5
131.5
o
141.5
131.5 40.7 o API
0.8217
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Terrestrial routes
Pipeline Transportation
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Why do
we
refine it?
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TERMINOLOGY
AND
SUPPLEMENTARY NOTES
Petroleum
(Crude Oil)
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403
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409
410
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Associated gas
Industry
Treatment
Production of
crude oil and
associated gas
Separation
Crude oil
NGL
Refinery
Residential,
Commercial,
Agriculture
Petrochemical
industry
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Natural Gas
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Natural gas
Natural gas
It comprises several gases, but consists mainly of
methane (CH4), or the simplest hydrocarbon chain.
It is colorless, odorless, tasteless, and is lighter
than air.
It is gaseous at any temperature over -107.2oC and
its specific gravity of 0.6 is lower than air.
The quality and composition of natural gas varies
greatly depending on the reservoir, field or
formation from which is produced.
When natural gas is produced, it contains a number
of other components such as CO2, helium, hydrogen
sulphide, nitrogen, water vapor and other
contaminants which may be corrosive or toxic.
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Natural Gas
Typical Composition of Natural Gas
Methane
CH4
Ethane
C2H6
Propane
C3H8
Butane
C4H10
Carbon Dioxide
CO2
0-8%
Oxygen
O2
0-0.2%
Nitrogen
N2
0-5%
Hydrogen sulphide
H2S
0-5%
Rare gases
A, He, Ne, Xe
trace
70-90%
0-20%
Natural gas
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Natural gas
Natural gas produced from an oil reservoir with oil is
called associated gas, whereas production from a gas
reservoir not associated with oil is non-associated
gas.
When a gas contains an appreciable quantity of
butane and heavier hydrocarbons (natural gas liquidsNGL), it is said to be a wet gas.
Dry gas consists mainly of methane with relatively
small amounts of ethane, propane, etc.
To facilitate transportation over long distances,
natural gas may be converted to liquid form by
reducing its temperature to -160oC under atmospheric
pressure. When gas is liquefied, it is called liquefied
natural gas (LNG).
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424
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426
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Production of
crude oil and
associated gas
Separation
*Gas flared
*Gas vented
*Gas injected
Removal of liquids
in natural gas
processing plants
Production of
non-associated
gas
Associated gas
Marketed
gas
Non-associated
gas
Removal of sulphur
and impurities
Colliery gas
Coal mines
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Natural gas
433
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Salt caverns
Caverns in salt deposits may exist naturally or be
formed by injecting water and removing the brine.
They are generally smaller than the reservoirs
provided by depleted oil and gas fields or aquifers
but offer very good withdrawal rates and are well
suited for peak-shaving requirements.
The amount of gas in a cavern is divided into two
parts; the recoverable (or working) gas and the
cushion gas.
The cushion (or base) gas is the volume which must
be present to maintain pressure and operability. It
cannot be withdrawn during the operating life of the
443
cavern.
Effects of relative
positions of
freshwater
injection and brine
withdrawal in
direct leaching
(left) and reverse
leaching (right).
More salt is
dissolved at the
level of water
injection, creating
a wider cavity at
that depth.
Injection and
withdrawal levels
can be modified to
control cavern
shape.
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446
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