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BOOK 546.D 17 pt c.
DALTON # NEW SYSTEM OF CHEMICAL
PHILOSOPHY
i
T1S3 0Q],33t,0M
NEW SYSTEM
CHEMICAL PHILOSOPHY,
PART
BY
I.
&
E.,
M.R.I.A.
SECOND EDITION.
LONDON:
JOHN WEALE, ARCHITECTURAL LIBRARY,
HIGH HOLBORN.
PRINTED BY SIMPSON AND GILLETT, BROWN STREET, MARKET STREET, MANCHESTER.
1842.
I'?
u>
^(7
TO THE
OTHER RESIDENTS
OF
an& ^ncottragem^nt
TO THE
TO THE MEMBERS
OF THE
UNIFORMLY PROMOTED
ijts
IS
HIS RESEARCHES,
wmovk
RESrECTFULLY INSCRIBED, BY
THE AUTHOR.
publish
to
it
it
in
entire in
two
when
one volume
this
to press
now induced to
which it may be proper
but he
is
announce.
Various essays of his were read before the Literary and
Memoirs,
in the
5th
in 1802.
Volume of
their
The
and important.
and soon
cir-
medium
In 1803, he was
it is
brief outline of
them was
work
first
to exhibit
and
elucidate.
Royal Institution
in
left for
but he
is
publication in
not informed
since been
no time
in
communicating the
own
by
and
his
807,
PREFACE.
VI
he was induced
On
these occasions he
to
attainments
be of the
first
Upon
made
to be
manner was
other
Several
to be new,
and arrangement.
These considerations,
mean
it
can be completed.
it
may
In the
May,
1808.
PAGE
Chap.
I.
Section
On
1.
Heat or Caloric
On
for measuring
2.
On Expansion
3.
On
4.
On
5.
On
23
hy heat
it
Theory of
47
of bodies
the specific heat
of
^^
elastic fuids
the
by
combustion^ ^c
6.
On
the
75
82
7.
On
the
heat,
arising
from
inequality
of
temperature
.
99
8.
On
9,
On
the
Phenomena of
of water
the
Congelation
133
CONTENTS.
11
PAGE
CifAP.
II.
Section
On
1.
the Constitution
On
of Bodies
constitution
the
of pure
141
elastic
145
fluids
2.
On
constitution
the
of mixed
elastic
150
fluids
3.
On
the constitution
of
liquids,
and
the
and
4.
Chap.
III.
On
On
elastic fluids
the constitution
of solids
Cheinical Synthesis
94
208
211
217
The
first
of print for some years, the Author has been induced at the
request of several of his friends to publish a second Edition,
The
it.
illness
now preparing
1.
2.
from a
five years
;
but he
On Microcosmic
On the Sulphate
Salt.
Soda.
3.
4.
1842.
NEW SYSTEM
OP
CHEMICAL PHILOSOPHY
CHAPTER
I.
ON HEAT OR CALORIC.
The
ture of caloric,
is,
that of
its
being an
elastic fluid
When
all
by
all
other bodies.
quiescent state
in
ther
we
is
in
whe-
equal bulks.
affinity for
portion of the
fluid, in
order to be in equilibrium
ON HEAT OR CALORIC.
Were
quantities
would con-
Attempts of
this
Whether
From
moment.
there seems
but
cific
it is
is
an enquiry of some
little
doubt of
its
made
being nearly so
equal weights.
methods
It is
because the
same
results,
by
But before
we should
this subject
first settle
can be
what
is
w^ell
considered,
intended to be meant
ON TEMPERATURE.
SECTION
I.
ON TEMPERATURE,
AND THE INSTRUMENTS FOR MEASURING
The
IT.
may be
of temperature,
at the bottom,
liquid,
to the sys-
all
(See Plate
Fig. 1.)
1.
The
to the horizon.
and
rises
to
and
them
thermometer
poured
perature.
in,
in the
is
if
all,
and
it
in the
tube
the water
is
notion, then,
it is
obviously intended
According
to this
ments of temperature.
This view of the subject necessarily requires,
that
if
ON TEMPERATURE.
4
ture,
to
by each
will
ties
it
For, in elastic
true.
may
is
be nearly consis-
well known, an
fluids, it is
the same.
It is
by
heat, in-
more.
provided
all
bodies
but as this
is
Suppose
it
were
minated
caloric, to the
body of which
it
was
to
air to
to
me
be suffered to
be confined to
It
appears to
ON TEMPERATURE,
whilst
m =
its
hulk
is
elastic fluid 10 in
711
-\-
= the
when
10,
Let
temperature in
this case
then
suffered to expand,
d being the
diff'er-
by the body
in the
two
Now,
cases.
-^
m =
the
ture
will
but -^
in the
(m + d) cannot
second case
it
If these principles be
may be
admitted, they
solids
it is
by an
we
suffer
it
its
to
if
expan-
increments
temperature uniformly.
were applied
If
condense a liquid
fluids.
by analogy probably
liquids
and
solids, is
in
air,
dif-
and
ON TEMPERATURE.
air
supposed
and that a
contain 2005 of tem-
to
its
granted
if
become 2000,
till it
may
or
still
be considered as
capacity invariable.
This may be
temperature,
having
when
equivalent to
is
volume of
changes of temperature consequent to the condensation and rarefaction of air have never been
determined.
Vol.
eff'ects
density of
easily
is
affected as if in
medium
am
but the
Mem.
air into a
air,
air,
acquainted with
they
may perhaps
facts I
raise the
The
is
Upon
that the
it
may be
concluded,
change of temperature,
is
productive of consider-
ON TEMPERATURE.
able effect on
we
its
on
elastic fluids,
M. De Luc
solids.
and
still
at the freezing
weights of water
peratures, 32 and
indicated
meter
its
on liquids and
less
is
thermo-
122
if
he
for,
in
Now
the
both these
water of these
its
bulk
this
com-
pression,
is
all
mean.
It is
may be
mean
as
low
as 110 of Fahrenheit.
It
tions of
any
liquid, of equal
if
two por-
weight but of
differ-
it
But
is
if
and
an
the
ON TEMPERATURE.
preceding observations
be
correct,
it
may be
mixed
as above.
measure.
its
the
mean by
the mixture
1st.
is
This can-
always below
for in-
whereas
it
appears
122
mean
is
the true
ON TEMPERATURE.
Heat
is
it
it is
If the
phenomena
Philo-
alike.
variation, or
sion,
to
meters.
my
Since
by
heat,
and those of
Gay
all
it
permanhas been
sources.
it
occurred to
me
as probable,
ON TEMPERATURE.
10
is
as the
freezing points.
this
and the
deviation observable
is
exact-
known
ature,
little
By
curial
and water
were comparable
probably extend to
all
it is
phenomena
same law.
It
may be
seen in
Mem.
my
Vol.
5,
Essay on the
Part 2.) that
little
surprising to
me
scale
; it
was
want of per-
ON TEMPERATURE.
was owing
feet eoineidenee
awed by
to
11
to inaeeuraey in the
thermometer
but over-
who seemed
more than
had determined
was probably 3 or
;
heat,
De Luc
4, as
by
However
it
12,
seemed unwar-
now appears
increments
are
above-mentioned law.
The
force of
by the above
air to
law,
do the same
manently
was natural
it
;
elastic fluid)
for, air
to
vary
to expect that of
Accordingly
pands
in
it
trial
as above.
Steam
ON TEMPERATURE.
12
it is
rendered
in-
Gay
found by
air
fluids.
expands as the
but I
it
is
almost
trait
body in cooling
is,
that
its
7nediwn
Thus
if
and from 10
to 1,
adopt the
common
is
ought
all to
be the same.
scale, as is well
known
if
;
we
the
in the
upper
but the
new
scale
ON TEMPERATURE.
13
is
1st.
and mercury, expand from the point of their congelation, or greatest density, a quantity always
as the square of the temperature
2nd.
The
as water,
progression
to
increments
of
geometrical
temperature in
arithmetical progression.
3rd.
is
The expansion
of temperature.
4th.
trical
The
refrigeration of bodies
is
in
geome-
its
lower
;
the
14
ON TEMPERATURE.
ON TEMPERATURE.
15
The
first
The concurrence
Fahrenheit.
of so
many
to
analo-
but then
it
heat, or
are to be applied to a
its
ordinary
state, is to
reason of
its
be requisite, by
increased capacity.
The
175, denotes
first
the point at
The
calculations
68
100.
to 212
By
are
made
above the
comparing
for
last
this
are perceived
new
scale,
40.
every 10 from
number,
for
every
new
common one
num-
scale
and the
observable at 122'
ON TEMPERATURE.
16
being 12
able.
obtained thus
column,
is
opposite
32,
in
They
the
first
(or
The
boiling water.
~ 18 = .4105
By
each
to 8.4853, or subtracting
it
from
it,
the rest of
The
ON TEMPERATURE.
numbers
in the
1?
obtained by
all
The
unequal
differences in the
down by
inconve-
being carried
its
The
The
by the theory.
4th column
the difference of
common method
is
40%
is
found to be
at
175.
to
make
it
conform to the
of numbering on Fahrenheit's
scale.
The
5th column
is
The appa-
is
shewn by
be shewn hereafter.
De
But
has been
it
less in the
;
this
must
of expansion.
By
what
is
dictated
calculating from
mercury
in the
by the law
De
Luc's
middle of the
3"^
higher
ON TEMPERATURE.
18
however
it
Not
to over-rate
it
column
in
is
corrected accordingly.
The numbers
this
beyond the
for
By
viewing
this
1st,
the
common
scale
natural series,
1, 2, 3, &c.,
Thus,
ture.
if
a quantity represented
by 289,
temperature, then at 52
it
expanded
1,
at
will
at
the boiling
be found to have
Water
in the
as
absolute
expansion
of bodies.
The apparent
but about 42
The
ON TEMPERATURE.
19
in
sion of
air,
taken
is
Gay
The volume
or elastic fluids.
at 32
Lussac's and
my own
experiments.
As for
mid-way of
at
my
Mem. Vol. 5,
temperature may be esti-
Part
2,
mated
at
119i
nity of having
experiments I
will
total
but
air
at
By more
32.
am convinced
or 118 of
to 212.
Table
it
common
According
scale, as
if
that to 117^
from the
term
last
above
Now
recent
its
expansion.
total
do otherwise
The
it
the
It
num-
It is
ON TEMPERATURE.
20
that might
from
much
actual experience, so
difference
to,
differ
as 2 in
any part
The
which
is
mer Essay on
to correct
for-
am enabled
by trusting
my
Since writing
ed
to the
accuracy of the
of temperature as
nearly 100.
namely,
from
all
*'
liquids
is
But
now
find that 30 of
more than 30
common
in the higher
temperature
scale
is
much
and other
The
truth
is,
geometrical
ON TEMPERATURE.
progression to the temperature
21
but the ratio
is
Ether as manufac-
homogeneous
liquid.
have purchased
it
in
when thrown up
the mercury
its
into a
vapour
namely, such as
68"*.
for
those
ment
as far as
from
to 212
an
artificial
were found
Essays
cold mixture
in
the
manner
my
former
it,
in
more ether
and
in
it
maximum
effect
it
is
ON EXPANSION.
22
The
This
vapour of water.
spirit of
in the
is
this case is a
as the
and homogeneous.
wine, de-
same way
is
not pure
vapour.
SECTION
2.
EXPANSION BY HEAT.
One
is
The
many
the expansion
fluids
instances
been determined
most of
have
in
but partly
little
The
experiments.
force
necessary to
counteract the expansion has not been ascertained, except in the case of elastic fluids
is
no doubt
it is
all
but there
The
quantity and
permanent
elastic fluids
very great.
law of expansion of
ON EXPANSION.
have already been given
it
23
it is
1st.
mark
in the
stem
and that
it
was known
then
it
same mark.
2nd. Suppose as before, except that both bodies
then
it
liquid
tity
would appear
sion of the
two bodies.
expands
liquid
the
ON EXPANSION.
24
in
this case if
and afterwards
stationary,
For,
expands
is
which the
uniformly accelerative,
all
in
to
some
stationary
must
degrees, from
moment be
it
moment, the
previously to
liquid
that
must appear
time
the liquid
third proposition,
moment
denoted by
1,
of equal velocities be
time must be 2
by an uniformly accelerating
time.
sunk
1,
force, is such as to
Again,
let an-
4,
li-
ON EXPANSION.
25
also
and therefore
2nd
to
it
the
first,
by the
portion.
it
will
make
2, that
in like
manner 5
But the
ag-
Hence
well known.
is
real,
only starting
is,
either heat
expansion will
the real.
For,
point of the
it
still
ascends to
if
or
is
in
the circumstance of
ON EXPANSION.
26
be
5,
by another
The
by another portion
will
it
7? &c., as before.
may be
Let
by equal increments of
temperature, then
25
p,
p, 4
mon
p, 5
by
p, 7
p,
series of square
But
is 2.
it
is
com-
demon-
progression,
is
metical series
3p,
1,
difference of
in
form an arithmetical
common
we have
Hence,
as
Now
p, &c.,
arithmetical
2= twice
difference of which
strated
4 p,
namely 3
form a series
^ p, 16
&c., will
2p, 9
common
differ-
is 1
common range
quantity
is
of temperature
so small
ON EXPANSION.
27
many
cases.
to the
Cor.
in the other,
time or temperature,
expansion
?;
= velocity,
that
and
.v
and
is, if ^
= space or
then,
f^ or ti\ or if are as s.
Cor.
is
as
s IS
SiS
t f
s is as
t,
2.
maximum
The
real
temperature,
is
of water
expansion
number
of degrees of
from
any vessel
For instance,
and appears
from thence
to
to
212
expand
-aV
then
it
of
common
its first
may be
volume
inferred
ON EXPANSION.
28
density by 170
-^ of
is
its
volume
is
so that the
determinable this
its
is
vessel containing
it.
then
may
as-
of
all solid
Cor.
4. If
maximum
a
its
velocity
any
solid
body be found
to
must be
And
if
max. density
then
its
Because
By
in
water v
is
as
t,
he.
sels, filling
to dif-
every 10 of the
henceforward
common
call it)
in
glass
ON EXPANSION.
EXPANSION OF WATER.
OLD SCALE.
29
ON EXPANSION.
30
for 1804,
traction of water
by heat
in
low temperatures.
In this
facts
and
There appear
32
be
to
it
its
maximum
density;
essay, I
Dr, Hope
argued from
own experiments
his
to the subject,
I
found them
favour of
in
all
to
facts,
way between
two
In
13 and
14, I
endeavoured
to
and no
other.
I shall
shew
this
now shew
that
Dr.
conclusion
that
my own
The
results of
my
ON EXPANSION.
31
Vol. 10.
It
may be
and act
so as to resemble
The
meter.
as
observations follow:
Water
stationary.
Corresponding points
of expansion.
Brown
ware,
&
44*
32
&
48
&
&
&
&
&
&
&
52i
at 32
at 38
earthen ware
40
3 Flint glass
42
32
4 Iron
32
5 Copper
42+
45+
6 Brass
45i
32
7 Pewter
46
32
8 Zinc,
48
32
9 Lead
49
32
As
32
53
59
60
60i
64 +
67
first
is,
that the
all
to find
that
we
point must be
below 38.
According
to
32
ON EXPANSION.
expands
-^
in bulk.
is
water at 42
the former
through
this
is
must therefore be yV of
last
of
5,
new
not be accurate
scale
at
The
38.
which
4 of old scale,
it is
absolutely of
below
is
-Ys
^ of 90
way)
temperature must be
inaccuracy arises, I
have no
under-rated by Smeaton
are seldom
if
ever properly
in a state of violent
rods,
and
it
might be expected
expand more
its
still,
because
being less
brittle
From
the
above
experiments
it
ON EXPANSION.
33
to glass, such as
very
is
little
temperature
this is
hence 90
sion of water
from 42 +
6 of
leaves
-r-
12
7^ of true mean
36''
to iron as
is
of
Copper
180''
by
in length
is
of greatest density.
2 in expansion
there-
must be
hence 45
""
36, for
the
temperature as before.
Brass expands about sV more than copper ;
shall have 45l
9i = 36, for the
temperature as above.
hence we
Fine pewter
is
to iron as 11
according to Smeaton
6 in expansion,
pewter
much
as
Smeaton
much
scale
= 35%
it
is
as
if
we may
whence 48
13| =
not
to be relied upon.
11
for the
so
hence 46
It
expan-
34
ON EXPANSION.
is
over-rated
was found to
it
The
more.
it
made
vessel was
Hodson and
malleable zinc of
contains a portion of
tin,
of the patent
Perhaps
Sylvester.
which
will
account for
the deviation.
Lead expands
tt^ of
its
^=
gives 90 -h
scale
161 of
whence 49
new
13 =
scale
water
much
this
13 of old
36, as before.
is
near
at or
new
stone ware
is |,
same.
The
in a ther-
which
is
at
.0037
Con-
sV'
authors
is
equal to the
De Luc
makes
make
less
it
it
sum
of these
.02
all
un-
Hence we
35
ON EXPANSION.
nearly, which expresses the effect of the expansion of glass on the mercurial
is,
thermometer
that
at the
had no expansion.
De
if
the glass
.00083 in
This
is soft.
Liquids
constitution
Thus,
if
is
Solutions
;
salt crystallizes,
and
whereas water and mercury, when partially congealed, leave the remaining liquid of the same
quality as before.
Most
Alcohol as we
commonly have
it, is
Ether
is
and probably
liquids,
and
except
volatile,
ON EXPANSION.
36
we
use
it is
it.
Few
and mercury.
authors have
experi-
My
own
in
inves-
tigations
mercury
my
made
of
water
in
but
it
may be proper
from
given by
35 parts
The
to 172.
my
as to fire
The
to
I find
an indefinite
this is
judge
it
is
common
.86, I find
1072 at 170'
mercurial
at 1039, or half a
test.
gravity
division
to 212;
and 45 parts
gunpowder but
very weak.
from 32
From my experiments
at the
De Luc
cond 90.
relative expansions of
According
his.
its
1000 parts
is
When
the sp.
at 50
become
1035 + whence
,
ON EXPANSION.
3?
much
not so
in this case as
and 1029^
170,
at
at
gravity
is
to 37.
29^
hence the
to 32^.
45
and 1017^
which
is
at 110,
the same as
It is true
hol.
ratio of
When
the
become 1040
at
giving a ratio of 35 to
De Luc
is
the
When
110
35
but
As
it.
wide
The
was used
I
in
Particular
posed temperature.
ON EXPANSION.
38
As
it is
fair to infer
apparent degree
differ
in
when we consider
no
But
glass,
as 1,
5^ and 22 respectively,
must be obvious
has
little
influence on alcohol,
presumed
that a spirit
equable in
its
by reason of
Hence
comparative insignificance.
mercury,
it
its
may be
This
it
ought to
or congelation of alcohol,
is
below that of
mercury.
at 36,
and alcohol
it
was
to
at a
be ex-
thus
we
in the
mixtures as
ON EXPANSION.
1000 parts at 32
122
at
39
expands
salt
become 1050
at
as
212
it is
This
of mercury.
is
congeal
at
7,
This solution
De Luc's
is
said to
as
differs
oils
by 180 of temperature
pansion of olive
with
in
regard
expansion by temperature.
to its
me
it is
oil
more
De Luc
cent,
salt.
180
it
in the
it
higher than
ought to do,
somewhere about 3
have
not
it
know how
below 212,
to 5.
The
Several authors
but
it
do
boils
It accords with
Sulphuric acid,
mercury
as
the scale.
sp.
gravity
ON EXPANSION.
40
whence
it
mercury.
is
at
36
at 45,
and
congealed
or below
law as water
which remains
it
continues liquid.
same rate
the expansion
as that of
is
near-
mercury, the
dis-
The
sp.
it is
more
dispro-
The
ratio
nearly 6 to 7.
this liquid
with that of
In this interval
it
accords so nearly with mercury that I could perceive no sensible difference in their rates.
said to freeze at
From what
It is
46.
it
may be
seen
yet
it
in reality
ON EXPANSION.
41
Alcohol and
expand
which appear to
density, and
much, do
we
estimate
cumstances.
at
if
so
It is
in like cir-
Water,
if it
much
the
in the
first,
reckoning from
does in
it
36.
EXPANSION OF SOLIDS.
No
to
but as
be subject to
we may
As
it
may be presumed
that solids
undergo no
may
be,
it
it
is
will
may be
is
but
it
may be observed
It is
how low
not
this
ON EXPANSION.
42
nomenon
indicates
lower than
it
may
it
to
commonly apprehended.
is
Perhaps
absolute cold.
ther
it
fluids,
is
is
progres-
but whe-
of the temperature,
absolute cold,
it
if it
still
must appear
power
be estimated from
to
be nearly uniform,
as that
lowing calculation
let us
43
ON EXPANSION.
Now
they are in
14 to 15 nearly.
supposed
mean
is
to
scale, the
therefore
be
right, the
and something
Experience
higher part.
present
at
For
purposes we
may adopt
the notion of
Only
glass has
been found to expand increasingly with the temperature, and this arises probably from
constitution, as has
its
peculiar
Various pyrometers, or instruments for measuring the expansion of solids, have been invented, of
losophy.
is
to ascertain the
expan-
The
longi-
may be
derived from
much. Thus,
if
it,
and
will
be three times as
by a
same
will
ON EXPANSION.
44
The
180^ of temperature
that
Fahrenheit.
at 32 are denoted by
from 32
is,
to
212 of
1.
EXPANSION.
In bulk.
SOLIDS.
Brown earthen
ware....
Stoneware
Glass
In length.
0012=^
.0025=^
.0025=^
.0037=^
Platinum
.0034=^
.0038=^
.0042=^
.0042=^
Steel
Iron
Gold
Bismuth
Copper
240
12
8
10
115
8 8 2
1
T9~0
1
TTT
TTT
1
1
.0051
100
5 8 8
1
33
Silver
.0056=,,,
.0060=1^0
Fine Pewter.
.0068=-ri^
440
Brass
'0074=^
.0086=^
0093=^
Tin
Lead
Zinc
LIQUIDS.
Mercury
Water
Water sat. with
.0200=3^
.0466= 2iy
salt.
Sulphuric acid
Muriatic acid
Oil of turpentine
Ether
Fixed oils
Alcohol
.0500=^
.0600=^
.0600=:iV
.0700=-iV
.0700=^
.0800=yi^
Nitric acid
.1100= i
.1100= ^
ELASTIC FLUIDS.
Gases of all kinds
.376
Smealon,
Elhcott.
4
t
Boida.
1
1
Too"
3 2 2
on expansion.
45
Wedgwood's thermometer.
The
spirit
thermometer serves
we
to
measure the
new
250 by the
mercury
very
An
is
the best
clay,
and
This
is
tempera-
very desirable
we have yet
improvement.
for
or about
ture.
tures
boils.
scale,
composed
but there
is still
is
great room
in the
When
used, one of
them
is
exposed
in a crucible
to the heat
cooling,
it is
after
the quantity of
of this thermometer
is
is
The
lowest, or 0,
is
common
scale continued
According
to the
new views
of temperature in the
ON EXPANSION.
46
The
is
large.
more
remarkable temperatures in the whole range, according to the present state of our knowledge.
Wedg.
240
Pig
150
and
iron, cobalt
nickel, melt
from 130 to
125
124
Gold melts
32
29
Silver melts
28
Copper melts
27
Brass melts
21
Diamond burns
Red heat visible
14
in day-light
Fahrenheit,
old scale.
to
1000
Antimony melts
809
Zinc
700
Lead
612
Mercury boils
600
Linseed
600
oil boils
590
Bismuth
476
Tin
442
303
240
Water and
212
ON SPECIFIC HEAT.
4?
Fahrenheit.
Bismuth 5
parts, tin 3
and lead
2,
210
melt
Alcohol boils
174
142
Ether boils
98
Blood heat 96 to
98
Summer
Sulphuric acid
(^1.78)
80
to melt..
45
32
Milk freezes
30
Vinegar freezes
28
20
Snow
3 parts, salt 2
at
10
Kendal, 1791
Mercury
freezes
Greatest
artificial
23
39
90
cold observed
SECTION
3.
ON THE
SPECIFIC
HEAT OF
BODIES.
measure of
noted by
.5
nearly
hence the
by
and
be de-
specific heats of
will
1,
may be
signi-
.5 respectively.
ON SPECIFIC HEAT.
48
.5
by
That bodies
is
differ
much
1.
be
far
below the
mean temperature.
If a measure of
2.
mercury of 32 be mixed
be
far
3.
If two equal
and
like vessels
be
the
filled,
4.
mixture
will
higher.
These
ous
facts clearly
vari-
it
in like circumstances
in
its
new
ON SPECIFIC HEAT.
affinity,
This no doubt
new arrangement
or disposition of
arises from a
its
by which
ultimate particles,
on becoming
heat,
49
Thus
even though
liquid, as
their atmospheres
its
bulk
is
diminished
and a
capacity for
by
ly
we may
this
conceive, sole-
its
body
same
in the
capacity
state
is,
by change of temperature.
Does
water,
heat, as at 212,
degrees
and through
all
the intermediate
after
As
may be
admitted
an out-
but
it
is
whether the
by temperature,
and
also,
it
is
uniform or otherwise.
it is
of
little
is
settled,
ON SPECIFIC HEAT.
50
mean tempera-
ist.
is
condensation
at
two measures.
less than
of volume
is
certain
Now
mark of
effect of
When
2nd.
capacity
of form,
it
always from a
is
and vapour.
its
3rd.
the same
by a change
less to a greater, as
liquids
he
tried,
were found
crease of temperature.
it fol-
ON SPECIFIC HEAT.
degree.
mean
I place the
With respect
at 110.
to
uniformly or otherwise in
varies
am
51
its
capacity, I
will
to the increase
in bulk,
and consequently
will
be four times as
much
at
may
212 of the
and 23.
new
scale,
may be denoted by
22,
22|
much nearer
equality,
city of water at 32
The
gave
it
as
was to that
my
at 212, as 5 to 6, nearly.
served, that a small mercurial thermometer at the temperature 32 being plunged into boiling water, rose to 202 in
15"
was 18"
in descending to 42
On more
difference
capacities, as
212
is
mature consideration
occasioned, not so
is
more
by the
fluid
too,
find, that
gave the
am
much by
ratio of 5
persuaded
this
the difference of
Water of
ment
it
facility.
mercury cools
By
a subsequent experi-
thermometer twice as
52
ON SPECIFIC HEAT.
Dr. Crawford, when investigating the accuracy
of the
aware, that
if
its
this
He
accuracy.
was not an
allows that
al-
infallible
if
water
may be formed
some degree
to
capacity of water,
This
so as to deceive us
;
and he appears
it.
by no means
is
is
sufficient
to
the
sum
oz. of
water
60 ounces
of water.
in
and melted
the tem-
60
oz.
water of 212
60
oz.
water of
60
oz.
water of
fast
as
water, though
it
is
its
ON SPECIFIC HEAT.
From
the
first
53
1681
the
difference
345
1681
176|,
made
150,
water of 32.
Similar
calculations being
we
and
follows that as
it
much heat
5, 6,
is
and
7.
Hence
necessary to raise
it
7 in the higher,
and
6 in the
middle.*
The most
specific
and any proposed body of two known tempera* Perhaps the above results
may account
so called) in water.
(Inquiry, page
ON SPECIFIC HEAT.
54
tures,
and
to
Thus,
ture.
if
pound of water of
32,
and a
common
7i
degrees;
be
heat of water
way
Black,
or,
specific heat of
Irvine,
/i
in-
specific
mercury.
In this
Such bodies
as
have an
may be
confined in a vessel of
known
ed into water so as
be heated or cooled, as
to
capacity,
and plungin
The
results
sume the
their
1st.
that
is,
the specific
thermometer
is
But
it
is
warrantable.
The
it
was calculated
in-
to
shew
body heated
to a
ON SPECIFIC HEAT.
given temperature could melt.
It
55
was therefore
Unfor-
answered well
in practice.
Meyer attempted to
These
cities
(An-
de Chemie Tom.
nal.
recommended
a similar
mode
From my own
this
method
Leslie
30).
for
trials
experience I
am
on
has
since
and
liquids,
five of
them.
inclined to adopt
The
appear to be ascertainable
mon
this
ferent, a
The
results
mixture
is
of
little
dif-
consequence.
by
thermometric
scale.
The
phenomena of
conceived
ON SPECIFIC HEAT.
'^6
unequal bases.
(See plate
Fig. 1).
1.
Suppos-
a:,
will
.r.
Those
Let
and JV
hot bodies
and
grees
and n
m =
ture, (supposing
then
we
warmer
after mix-
1.
2.
m =-w c^W C
-\-
n=
d,
WCd
Wn
action);
ON SPECIFIC HEAT.
57
W Cn
4,
If
(7=
c,
If
J^=
w;,
wm
Wd
m=
then, 5.
j^^w
'
m
c
To
then, 6.
C=
and
C=
Let
the less,
the
number
m=
in equal weights,
n=
the num-
s =
the
To
then,
7.
CX
8.
find
a:
= On =
Cn
cm
C-c
~ C-c
771.
C^
x,
be as before
mixture, and
let
Let
iv,
Wy
M = capacity of the
58
ON SPECIFIC HEAT.
produced
then
=
(w+ W)
bodies will be
a:
the
w+C W)
(c
(w-\-
W)
n.
Mn
(cw+CW)^
(w+ W)
9.
and x
It is to
has been
be regretted that so
made
W)
(w +
little
improvement
Some
department of science.
still
reflec-
a view to enlarge,
It
of the particulars.
may be proper
For
liquids I
some
to relate
used an egg-
to this
file,
when
When
and heated a
little
above 92
it
was then
sus-
ON SPECIFIC HEAT.
pended
in
accurately noted
92,
meter
at the
it
was
82, another
at
thermo-
The
The mean
as follow
59
oz. of water.
were
AIR IN THE
KOOM
52.
Minutes.
to 82, in
29
Milk (1.026)
29
Ammoniacal
Common
ammonia
28i
28i
(1.035)
solution (.948)
28i
vinegar (1.02)
Solution of
common
salt,
27i
88
W. +32
W+4
S. (1.197)
27
26^
S. (1.17)
26^
25i
25
21
21
19i
Alcohol (.85)
19i
Ditto
Hi
(.817)
15^
Spermaceti
14
oil (.87)
accurately
the
ON SPECIFIC HEAT.
60
But
into consideration.
proved
to
to f of an
be equal
to f of
was
an ounce of water, or
ounce measure of
oil, it
evident
is
we
On
oil.
this
in the last
may be proper
articles
preceding ones.
sults
will
trial
above re-
of the several
indeed, in
below
I
room was,
52, the
in
any
case, a little
If the
above or
by the time of
its
cooling in
other
solids
after
the
ON SPECIFIC HEAT.
Crawford
glass
61
found
its
it,
vv^ater, to-
was raised
to 212,
The
solid.
solid
Some
used on the
copper, lead,
iron,
zinc,
tin,
The results
antimony, nickel,
differed little
from
numbers
their
till
In
ence
will not
the
first
a few instances
except from
it
may, perhaps, be
remark.
so,
but in
or 2 wrong;
specific heats
I shall
further
ON SPECIFIC HEAT.
62
21.40*
Hydrogen
Oxygen
Common
equal
eq.
weights, biks.
air...
SOLIDS.
002 Ice
4.73*
006
1.79*
002
Dried woods,
and
other vegetable
substances, from
.45 to
Quicklime
Carbonic acid.
vapour....
LIQUIDS.
Water
Arterial blood
Milk (1.026)
Carbonat. of ammon. (1.035)
Carbonat. of potash (1.30).
Solut. of ammonia (.948)....
Common vinegar (1.02)
Venous blood
Solut. of common salt (1.197)
Solut. of sugar (1.17)
Nitric acid (1.20)
Nitric acid (1.30)
Nitric acid (1.36)
Nitrate of lime (1.40)
Sulph. acid and water, equal b
Muriatic acid (1.153)
Acetic acid (1.056)
Sulphuric acid (1.844)
Alcohol(.85)
Ditto
(.817)
Sulphuric ether (.76)
Spermaceti oil (.87)
Mercury
Charcoal
001 Chalk
Hydrat. lime
1.55* 001 Flint glass (2.87)
Muriate of soda
Sulphur
.79*
Azotic.
Aqueous
1.05*
Iron
1.00 1.00 Brass
1.03*
Copper
l.OO Nickel
.98
.98 Zinc
.95
.98 Silver
.75
.98 Tin
1.03
.94 Antimony
.92
.89*
Gold
.78
.77
.76
.68
.63
.62
.52
.60
.66
.35
.76
.70
.66
.52
.04
.93 Lead
.90 Bismuth
.96
.88 Oxides of the metals
.85 surpass the
metals
.87 themselves,
accord.80 ing to Crawford.
JO
.70
.65
.65
.57
.50
.45
.55
eq.
63
ON SPECIFIC HEAT.
The
articles
dis-
depends
it
or 2 tenths of a degree
Great merit
process.
The
is
difference
between
arterial
is
remarkable,
From
hydrogen
gravity,
which
Oxygen,
as
hydrogen, or water and ammonia, we must conclude that the superiority of the two last articles
is
chiefly
ON SPECIFIC HEAT.
64
them
into
compounds,
Water appears
for heat of
as
oil,
may be
it
indeed
The
great
which both
its
Hence
it is
in
volume of water*
increase the
for, salts
and hav-
to possess a
exceed water
the characters of
woods,
all fall
it
If
it
could be
would probably
in this particular.
The compounds
high specific
oil,
last
mentioned
it
the
ap-
J. D.,
1841.
ON SPECIFIC HEAT,
65
ment of a low
The
in
only one
who
be ,66
some other of
cent,
and should
as the
compound
63 per
in
it
it
This
the
It is
water, and
is
this with
is
Lavoisier
is
he finds the
an ele-
specific heat.
acid
is
is still
its
heat on com-
more observable
whence
not only the heat of the acid gas, but part of that
in the water
is
this
ac-
The
make
.43,
it
.34, Lavoisier
.33
been
Crawford
finds
it
Common
it
diff*er
ON SPECIFIC HEAT.
66
version.
The
acetic
Quicklime
Crawford
it
much
be .22
with
oil.
plunged
fixed at .28
(that
1 part, or
by Gadolin
it
The
have underrated
subject will
much
when
in water,
Hydrat of lime
'
heat.
I think they
to
is
com-
33
or
is,
or
more
inclosed in a
when mixed
quicklime 3
was .25 by
I
my
is
first
<
have underratedit.
SECTION
4.
SPECIFIC HEAT OF
ELASTIC FLUIDS.
THEORY OF THE
ments
It is
yet
off*,
to conceive
The
be relied upon
Crawford.
phenomena
67
because the
fluids,
results
The
all of
reiterated
elastic fluids,
it
2. 4
(page 263) at a
The comparative
to
heat of atmospheric
credit.
air
and
far
in
heats communicated
the
by equal bulks of
common
air,
very uncertain.
He
The
tenor of
equal
weights
of
it
it
will
necessarily led
him
to
carbonic
;;
68
it
was then
called,
its
being
Indeed
air,
air.
13,
for
he makes
ofas
it
differ-
He
has in
all
probability
much underrated
it
may
When we
consider that
all
and
ral
it
There are
merit discussion.
1.
the
Equal weights of
elastic fluids
may have
stances of temperature
The
several facts
is
disproved by
their
much
69
heat,
elements composing
unite
acid
it.
is
heat
is
with
it
oxygen
much
rived from
contain
Carbonic
the
oxygen
heat,
little
if
inferior in heat to
far
gas.
Equal
2.
may have
the
temperature.
of volume
hydrogen
is
when
a mixture of
sioned by a proportionate
absolute heat
the same
the diminu-
oxygen and
may be
diminution
may be
occa-
of
the
said of a mix-
The minute
observed by Crawford, may have been
inaccuracies occasioned
experiments.
But
which render
bable,
if
by the complexity of
this supposition
they
his
extremely impro-
its
own bulk
of
it.
oxygen
70
its
be exactly equal
to
on
this supposition
but
by the combustion of one pound of charseems, at least, equal to the heat by the com-
the heat
coal
to,
sufficient to
because steam
is
elastic
it
produced
is
it
only about ^ of
it.
Were
this
supposition
weights would be inversely as their specific graIf that of steam or aqueous vapour
vities.
represented by
1,
8.4, azote
supposition
The
3.
.72,
is
oxygen would be
.64,
.46.
were
hydrogen
But
the
untenable.
ulti-
evident the
number
of ultimate particles
gas
is
for, if
equal
71
measures
same weight
as the
two original
No
two
the same
elastic
fluids,
number of particles,
either in the
same
Suppose, then, a
fluid to
be constituted
medium
force,
such as
air
;
was
query
can be given, as
particles
will
it
The
appears to me,
is
this.
The
will
is
Hence
may now be
demonstrated.
72
Corel.
The
1.
weights
fluids,
Those
is
spent in accu-
When
affinity to
heat
is
two
elastic
form one
elastic atom,
When
disengaged.
when
union become
general,
heat retained as
One
particles
n
will
specific attraction of
eff'ect
in
by chemical
m
it
And
disengaged, &c.
is
elastic
;
is
to the
to n.
is
per to obviate
same
be
said,
it
may be pro-
an increase in the
nal pressure.
Now
this last is
known
to express
sion
must be admitted
and
it
This conclu-
tends to establish
The heat
<4
amounts
my
to
mer experiments
elastic
much
as
it
seems
one
be shewn
as will
hereafter,
for-
aifect
be merely the
to
cules of
air,
to them,
because
it is
to
belong
equally found in a
vacuum
is
we must
first
ascer-
Assuming
at present
be
1,
that of
what
will
be proved here-
oxygen
will
be
7,
azote
5,
nitrous
moniacal gas
gas
6,
carburetted hydrogen
7, olefiant
vapour
16;
we
8,
shall
have the
to
In order
shall fur-
steam as 6
to 7, or as 1 to
L166.
74
9-333
Olefiant gas
Azote
1.866
Nitric acid
491
Oxygen
1.333
Carbonic oxide
.777
1.759
Sulph. hydrogen
583
Atmos.
air
1.555
424
Nitrous gas
777
Muriatic acid
Nitrous oxide
549
Aqueous vapour
Carbonic acid
491
Ether, vapour
848
1.555
Alcohol, vapour
586
1.333
Water
Ammon.
gas
Carb. hydrogen
common
heat of
Crawford found
excels
is
air
it
1.000
by experiment
also,
all
1.166
but oxygen
The
azote higher.
as
hydrogen
principles
all
change.
we
compound
compound
of
Upon
fact
in regard to the
whether
elastic
is
specific
or liquid, that
heats of bodies,
is
repugnant to
ON HEAT BY COMBUSTION.
the above table as far as I
know
75
and
it
is
to
be
to solid
and
SECTION
5.
ON THE
certain bodies
and
is
is
unite
chemically with
denominated combustion,
of the products.
voisier
and Laplace
The
fine
attempt of La-
Perhaps
this
it
Much
are not
its
obtained on this subject by the use of a very simple apparatus, as will appear from what follows
ON HEAT BY COMBUSTION.
76
I
when
tended with
water
air,
was
this
was equal
filled
30,000 grains of
to
to
it
a tinned
vessel,
ex-
much water
of
its
w^as
put into
as to
it
make
grains of water.
The
point of the small flame was applied to the concavity of the bottom of the tinned vessel,
till
the
the increase of
noted
whence the
effect of the
combustion of a
common
and temperature,
temperature of an
in raising the
pressure
very small
this
loss
of heat
method must be
by
radiation, &c.,
liable to,
which
The mean
when
the experiments
same species of
gas.
is
scarcely
The
ON HEAT BY COMBUSTION.
Hydrogen, combustion of
it
77
an equal volume of
raises
4.5
water
10
Olefiant gas
14.
Carbonic oxide
4.5
Oil, alcohol,
&c.,
and the
Oil, spermaceti,
effect
observed as under
combustion of 10
grs. raised
in a lamp,
30,000 grs.
5.
water
Oil of turpentine
Alcohol (.817)
2.9
Ether, sulphuric
3.1
5.2
Phosphor.
Charcoal
Sulphur
Campli or
3 .5
Caoutchouc
2.1
The
water
much
as possible
never amounted
generally approached
upon the
to 2
it
for ten
nearly.
it
was
the re-
grains, but
ON HEAT BY COMBUSTION.
78
clearly,
to a
well be expressed
ice
which
it
it
granted that
for
is
equal to
The
results
maybe
new
table.
lb.
hydrogen takes
^"^
'"''
carbur. hydrogen
71bs.
^
_
_
5 & acid 85
_ 4.5
88
1.58
acid
25
4.5 w. and
104
_ _
60
_ _
58
4
62
\v.
car.
carb.
car. ac.
3.8
w. &
60
carb. acid
40
sulph. acid
car. ac.
20
70
ice,
ON HEAT BY COMBUSTION.
tus.
By
appear as follows
lb.
79
ON HEAT BY COMBUSTION.
80
experiments on the heat produced by the respiration of animals, support this supposition.
Wax
and Oil.
Crawford's
Lavoisier's cer-
be supported.
He
seems not
to
given out by
its
much
combustion
he
&c.,
must contain
of combination
when
separate, agree-
on
in a state
combination.
In
fact,
both
Crawford and
by
by combustion.
This
is
the
more remarkable of
much
heat
ON HEAT BY COMBUSTION.
as the
81
Azote an-
oxygen.
would be
far
Oil,
wax,
in
class.
Upon
guage of Crawford,
contain
which
the
we cannot adopt
little
is
air,
*'
the lan-
that inflammable
produced by combustion
bodies
**
derived from
is
applied
universally to
combustible bodies.
it
is
almost unnecessary
light also,
body
know
aught we
for
similar observa-
by the
Before we
conclude
this
is
evolved.
section
it
may be
82
were no
fuel,
by the combustion of
loss) to raise
lib.
is suffi-
45 or 50lbs.
perature
or
it is
sufficient to
heat
lost,
more than
If
is
convert 7 or 8lbs.
this
weight of
a proportionate quantity of
which ought,
if
possible, to
SECTION
be avoided.
6.
ON THE
we suppose
body
at the ordinary
tempera-
by
portions, the
the
fluid.
it
is
body would
It is
finally
be exhausted of
determine,
how many
means of
effecting this
by
83
direct experiment
but
The
to
difficult investigation.
the
is
it is
According
common temperature
others,
results hitherto
according to
whilst,
The most
and water
to
be found.
is
that of ice
known
of 32, or to melt
it.
it
much
heat
into water
Consequently, according to
the 8th formula, page 57, water of 32 must contain ten times as
the
zero
much
heat, or 1500.
must be placed
at
That
is,
84
mined with
its
been deterbecause of
common
scale.
gation are,
water
1st,
mixture or combination of
and
in this investi-
4th, combustion of
charcoal.
Upon
nitric
3rd,
these
will
it
be necessary to
enlarge.
to the
weight,
determines
the
zero
at
by
7292 below
by Fahrenheit.
But
same
at 2630.
He
first
essay
85
it for granted to
be 1400 below the freezing point on the sup-
given us data
calcu-
His results
but as he has
each experiment,
it
will
from
far
Taking the
finds,
by
water at
specific heat of
1,
Gadolin
concentrated
sulphuric
acid
to
;
be
.339
(See
of the mixtures.
Whence we have
by formula
9?
page 58.
In
86
The mean
of these
is
2300, which
is
far be-
As
three
articles
is
so considerable,
and as
on
these
liquids.
The
strongest
;;
87
this
me
it
is,
falls,
or
becomes
slaked,
quicklime than
verize
it,
is
when mixed
is
produced
in
due
the lime
no more water
sufficient to slake
it,
is
put
or pul-
If
more water
is
may be
When hydrat
is
evolved
88
the
For
lime.
it
this
becomes necessary
to
of dry hydrat
of
heat
specific
the
be slaked with an excess of water
till
the
heat
expelled
by
then
be
must
excess
is
to
hydrat
is
of this powder
or any other
perature, and
By
ingly.
A given weight
its specific
of another tem-
a variety of experiments
made
in this
nearly
.30.
Lime
page 62.
Crawford
itself I
undervalues
find to
be
lime,
by
because
I
lime.
it
if
The
If 1 oz. of lime
specific heat
may be found
be put into 4
as
oz. of water,
100
in this case
1^
oz.
it
hydrat
is
formed, and
89
therefore the
sufficient to raise 8
times the
Whence
is
we
is
in
page 58,
temperature.
According
to the
of 9j parts of said acid, and one of lime, is .619But supposing there was no change of capacity
upon combination,
this
in
fact,
the
inexplicable
be established,
it
Were
would exhibit an
phenomenon, unless
to those
who
existing in the
more properly, of
same body, or
caloric
combined so
to
speak
as to retain
90
characteristic properties,
all its
and
com-
caloric
One
out, in
.30,
we
If
and ap-
we shall find it
common temperature,
to
as
trials, its
spe-
ed to cool
20,
added, and
it
when
it
was
suffer-
left
be
out,
and
left.
were dissolved,
sp. gravity.
to
dis-
.69.
we
The
temperature.
freezing
91
was
experiment
still
is still
underrated.
COMBUSTION OF HYDROGEN.
Lavoisier finds the combustion of lib. of hy-
my
ice.
The
results of
we may
truth.
take 400lbs.
as
approximating
combustion of
lib.
to.
the
thing, the
of water 7500.
By
adopting Crawford's
from the
common
we
find the
temperature.
But
zero 1290
if
we adopt
fluids,
page 72, we
the formation of steam, one
in
out
will
corol.
its
elements
is
given
92
of ice
now
if
hy-
lib. of
will
melt
lbs.
of
ice,
which the
heat in 8lbs. of water, at the ordinary temperature, is sufficient to melt, or the heat in lib.
is
COMBUSTION OF PHOSPHORUS.
One pound
is
it
From
whole heat
to
in
nearly half as
each
specific
The
ice.
lb.
of
as
it
oxygen
is
sufficient to
articles,
previous to combustion,
melt 75
+ 18 =
93lbs. of ice.
oil,
much
is
both
in
sufficient to
From which
de-
ought to melt.
in 2.5lbs.
of phosphoric acid
specific heat
all
impro-
The
bable.
93
combustion of phos-
result of the
COMBUSTION OF CHARCOAL.
Crawford's data are, specific heat of charcoal
.26,
10350\
doubt, that
oxygen
It
to convert
the zero
by
now
beyond
established
lib.
these data,
is
it
4400.
From
we deduce
If
we adopt
the theory
it,
com-
we
shall
this equa-
tion,
(1+2.6) X .491 X h
i
X .26
2.6 X 1.333
3.6
x .461
6000^
From
lib. of charcoal
would
this,
is
found
6650'.
But
this
heat
94
would
raise
3265.
or
it
of water
3.61bs.
Or it would raise
6650 x .491
11750
lib. of water,
Lavoisier finds
ice.
it
69.
is
not
the effect
and Crawford
961bs.,
finds
is
COMBUSTION OF
We
concerned.
OIL,
voisier, as well as
am
my
own,
of hydrogen
by
zero
is
ice,
By
is
sufficient to
applying Cor.
of
1, at
oxygenous gas
oil,
melt 461bs.
melt 53lbs.
and
it
Let
19 parts of carbonic
The
page 72, we
heat in lib.
60.5lbs.,
23lbs.,
oxygen
1.31b. of water,
and
of ice
and 3.5 of
oil
of combustion are
gether containing as
131.2lbs.
would be
ice, whicli
melted by
95
much
this
by
oil,
ment.
The
is
water.
By
instituting a
ought to be
671bs. of ice
be attributed to the
loss unavoidable in
it
may
was
well
my method
of observation.
I
page 78, as
far as
in
the
96
question
From
of olefiant gas
body
in the
we may
gaseous
state,
in a liquid state
their constitution
the result
do not
differ
for, oil
much
in
oil,
seem
but
it
should
an elastic
fluid,
is
of
my
into
to
Fahrenheit.
From
water
6400
4150
1.6
6000
lime
4260
7 nitric acid
From
and
lime
11000
5400
phosphorus
5400
charcoal
6000
oil,
ether
6900
6000
97
We
are au-
The mean
of
thorised then,
to
all
till
these
6150.
is
freezing water,
The
Fahrenheit's scale.
lieve
it
wiir
the
divisions
be impossible
of
I be-
to reconcile these
two
it is
This deserves
farther enquiry.
The
fric-
of volume,
body
condensation of
known
air
manner
produces heat.
It is a well
same time
as the
and
if
in
volume
a diminution of capacity
it
is
because
it is
small,
sufficient ac-
actually takes
curacy.
98
when it is considered,
once hammered in this way,
been heated
in
fire
efi*ect, till it
and cooled
has
gradually.
Count Rumford has furnished us with some important facts on the production of heat by friction.
He
and that
it
suf-
On
off",
was given
66360 of temperature
But
ed.
this is manifestly
the subject
at the
an incorrect view of
loss of scales ?
The
fact
less
is,
same time
make
when
he found their
is
more or
in boring,
temperature of 70 or 100
is
too
its
ca-
and a
rise of
lib.
The phenomena
99
sufficiently
shew
that
small a distance
common
as
some philosophers.
SECTION
7.
ON THE
As from
bodies
is
liable to
perpetual fluctuation,
it
becomes
in its
passage
its
inces-
solid bar
posed to the
the
air,
being heated
air,
the heat
at
is
partly dissipated in
varies
greatly, according
to
the nature
of the
100
subject:
in
When
general, metals,
a fluid
is
heated at
its
and
fluids
seem
to
have a
diff'er-
of solids.
is
fluid,
temperature
and
still
is
in their ascent to
retaining a supe-
is first
till
ebullition in liquids, at
temperature
specific gravity,
ment of
is
fluid,
is
the case
riority of
applied to the
uniform.
the
commence-
one
is
the
same
fluid,
is
thus
diffused
with great
The
celerity.
effectual
led,
latter source
much more
so
is
lOl
though without
sufficient reason, to
doubt the
Nothing appears, then, but that the communication of heat from particle to particle,
in the
same way
dity of
diffusion in fluids,
its
is
by which heat
and through
is
and by
fluids,
another method
By
this
this,
the rapi-
elastic
particular notice.
of the sun
be ascribed to
to
is
performed
is
in fluids as in solids
It is called
fire.
light
to consider the
But
light
heat
is
it
is
and
refraction,
something appears
102
to the contrary.
An
ordinary
fire,
coal, or
which
the
is
light
seem
to
be not of
sufficient
but
energy
it
should
to penetrate
glass, or
Several
been ascertained by
on Heat."
Enquiry
Having invented an ingenious and
delicate air
*'
been done.
and circum-
Some
it
will
be proper to
mention.
1.
it,
depends
the vessel.
if
from
it
if
paint, paper,
times as
glass,
much heat
&c.,
it
will
then radiate 8
in like circumstances.
with
thermometer be covered
2.
103
tinfoil,
is
3.
fire,
found to
from
its
This
Here then
is
last is
anterior surface,
most essential
much
is
the
and heat.
From
these facts
it
consequently to radiate
it
it
and
stances.
4.
tinfoil, &c.,
being
were proved
completely
to
by
their radiation.
thermometer was
The
heat radiating
104
5.
air
in its
provided
effect,
it
sub-
The
all
distances
whereas, in
light,
it is
it is
This
seems
to
hollow globe of
meter, being
filled
tin,
the same
81 minutes.
8.
air,
When
The
a heated
air of the
body
is
room was
15.
is
directly pro-
hollow glass
globe
In
filled
The
tinfoil, is
not constant at
disproportion
in
Mr. Leslie
is
high.
all
greater in
Thus,
in
ratio to
tin,
105
ture in degrees.
No
when h
is
very
is
but
little.
ing in water.
and
intricate,
but ingenious
investigation,
of the air
namely,
in
fluid
By
abduction, that
power of
By
air,
the 524th.
recession, that
rent of air
is,
excited
Ax 21715th.
By pulsation,
is,
or radiation, the
2533rd part
which
is
is
(It
Leslie contends
106
11.
body
cools
more slowly
common
in rarefied air,
density
and the
dif-
Common
gerating powers.
air
and hydrogenous
According
1.7857.
surface
causes
.57
air
to
.5
.57
is
:
common
ratio is
by
radiation,
loss
He
finds
be very
the
little
diminished by rarefaction
but
of the
effects
and
Leslie's
to
Mr.
facts
and
work
but as
occurred to
my
some of the
experience to be ques-
now proceed
me on
reason to withhold
to state
what has
have no
these subjects.
my
first
but the
last
107
satisfac-
tory.
will
of the
in
new thermometric
in the table,
it
one
page 14.
Old
scale.
108
442
new
scale,
and suffered
to cool in a hori-
The
below the
The
scale.
to 92,
conds each.
se-
the times
in the suc-
ways observed
more
in the
From
to
be rather
al-
and
this
experiment
it
appears,
that
the
thermometer was raised 400 above the temperature of the air, or to 600 of the old scale
it
;
lost
first
and 50
interval of
in the third.
nounced
at
page 12,
that,
according to the
new
increments of time.
EXPERIMENT
According
to
Mr.
2.
Leslie, the
same law of
me
always appeared to
this
109
satisfy
fact.
With
with a bulb of
.7
scale attached to
it.
This
tinfoil,
the
pasted upon
it,
and the
sur-
made as smooth as well could be the thermometer was then heated, and the times of cooling
face
The
of the differences
rounding
air,
The temperature
is,
most convenient
of the
air
to
air,
and
it
is
obviously
considered as zero
in
which case 19
110
Thermom.
By
it
Ill
w^ith tinfoil
in cooling
from 175^ to
whole times
Whence
it
to
24
It
must
not,
quite correct
however, be understood
is
is
if
the sur-
makes
it
cool
The
how
far the
progression in cooling
periment.
It
is
law of geometrical
112
the times of
by
EXPERIMENT
As Mr.
the law.
3.
more
mode-
especially, I
for
10 degrees,
this
was
were
as
under
Thermom.
experiment
smaller,
it
ed
bulb
the
being
in surface
by the
tinfoil,
in small slips,
many
because
113
in
places.
of their
refrigeration,
accuracy of Mr.
Leslie's
experiments, I was
more
own way,
above,
my method
EXPERIMENT
I took two
monly used
new
4.
tin canisters,
The
lid,
of water.
surface of one of
oz.
it
both,
new graduation
above the
affixed
pended by small
strings
when
filled
to be sus-
with water,
114
and
to
They were
centres.
its
successively
bulb in their
filled
with
40,
noticed as below.
Water
From 205
cooled.
to
195
115
it
be unnecessary to
will
new
It will
upon
be understood
or 25 below
insist
being 40,
when immersed
of cooling
seem then
in
water
it
should
that
the
heat
is
Taking
this
for
granted,
we
can
by
easily
radiation,
find
and
For, let
same time
then 8
:v
will
116
and from
we shall have,
l+.r: 1+8^; whence 2 + 16^= 3 + 3^',
and
::
.t'=r3
this gives
l^,
for the
whole heat
dis-
part
radiated.
That
is,
part
The
.4
air
.6.
Mr.
is
and
it
in the
lower
The
is
required to be
Whenever
heat
is
by
body with
as
containing vessel,
much
if
vegetable matter
given out
will
11?
or
charcoal,
;
in
some animal
surface.
REFRIGERATION OF BODIES
VARIOUS KINDS OF
IN
ELASTIC FLUIDS.
Bodies cool in very different times
the
elastic fluids.
who
lieve,
in
some of
first, I
be-
common
air
and
also
may be proper
to give.
My
apparatus was a
20 cubic
or
to
it,
so as to be air
file
on the
filled
The
bottle
it
was
had
air,
118
to the
The
as under.
under
surround-
Thermometer immersed
/ 112
sulphuretted hydrogen,
cooled in
seconds.
nitrous 1
com.
and oxygen gas 100
nitrous gas
90
carburet, hyd. or gas
70
hydrogen
40
azotic
air,
coal
The
remarkable
I cooled the
is
truly
thermometer 10 times
at
each
in, till
by
this,
mon
air
was admitted
larly increased
as
half
follows
air.
46, 48,
;
Equal mea-
common
to cool
and the
from mark
Condensed
air
were then
air
119
of common
pidly,
air cools
density
and rarefied
own experience
Density of the
for
common
The
air
results of
were
as follows
Therm, cools
air.
my
:
in
85 seconds.
2
1
100
116
128
140
^
W
160
iVo
70 seconds
eff*ects
when
rarefied 7
From Mr.
Leslie,
we
120
[between atmospheric
proves
its
entirely, in
The
same
hydrogenous gas as
in
we may
infer
of gas
and therefore
it is
air
is
the
same
is
in
atmospheric
air,
performed independently
carried on the
same
in
vacuo
in air.
that
in
upon rarefaction
is
effects
consequent
scarcely be conceived
if air
radiation.
The
effect of radiation
and
will
may be
investigated,
In
100
density being
air,
the
100
:: t
.004
t=
+ by
is,
by
radiation
by hypothesis,
as
.066
121
+ .006 tx/d=
1,
and
^=
3_
.004
+ 006 v/^/
.
common
we
air of
the several
densities as under
Density of the
air.
Times of cooling.
86.5 seconds.
100
114
129
143
T^
157
iV
170
182
193
250
iSflSit^
In
the
by
substituting
.0007 for .004, and .0093 for .006 in the preceding formula.
The
if
122
100": .4
40": .16
::
by radiation
whence .84 = the
40 seconds
that gas in
in
per second
common
but in
second by abduction
only .006
is
air
;
from
this
it
genous gas
is
common
air.
It
the cause
why
different
same quantity of
heat
differ
the
To
this
we may answer,
number of atoms
in
in a
the
all
in
Now
both
number
that
is,
to
if
re-
two
given volume,
it is
weight
and
if
its
least
number
moved,
will
in a
given volume
be as the number of
in like circumstances.
number
Of
of
123
particles in the
are,
hydrogen, ear-
page 73).
Of those
the latter
SECTION
8.
been
phere
in
remarkable
fact,
I believe,
and seasons
is
found to decrease
Sometimes
have observed
it
so
but
frost, I
ON THE TEMPERATURE
124
effect
What
duration.
then
is
minution of temperature
this question
at
is
ascending
in
can be solved,
may be proper
common solution.
it
it is
the sun
to
said, is
it
Before
as a transparent
calorific
effect,
The
more remote,
re-
ture, similar to
iron
when one
The
its
ends
is
heated.
first
correct
Air,
to heat
it
it
should seem,
is
is
probably
singular in regard
radiant state
through
of
air
if
so,
must be
the
propagation
effected
by
its
rity,
it is
is
in a
of heat
conducting
Now we know
of water
it
column
by the
From
these observations
it
OF THE ATMOSPHERE.
125
one
in v^hich the
namely,
Whether
must
I think
this
it
fact
tion.
conceive
that
it
to
principle of heat
with,
and which
such.
I shall
is
endeavour
in
what follows
to
make
The
principle
is this
of heat in
air in the same perpendicular column is possessed
of the same quantity of heat ; and consequently,
the natural equilibrium
is
when
of heat in an atmosphere
ascending.
That
denied,
this
is
a just consequence
when we consider
of heat
is
cannot be
when
its
the quan-
ON THE TEMPERATURE
126
It is
ob-
is
temperature
seems
if it
the
new
principle
announced above,
But
be examined,
it
together, that
distinction
we
making any
scarcely think of
No
is
found
to
when each particle of the body becomes in possession of the same quantity of heat.
Now the law thus expressed is what I apprehend
be restored
to
an
equality
It is
an
of tempera-
presents
perpendicular column of
air,
we
striking
see in a
all
but
OF THE ATMOSPHERE.
If
it
12?
temperature
know
it
of temperature
upon
but
the atmosphere.
me any
why
reason
the
corroborated by
powerfully
are
facts
sure,
By the
establish,
following
J that
the
behalf of
at the surface, is
where
its
weight
is
and from
my
experi-
ments (Manch.
Mem.
appears that
to
air
vol.
5,
measure
525,)
it
Whence we may
produces 50 of cold.
infer, that a
page
its
original temperature,
and suffered
reduced
to
rounding
air
the
;
same temperature
or vice versa,
if
as
the sur-
two measures of
ON THE TEMPERATURE
128
air at the
and temperature,
earth's
volume of
summit
air
of the
in density
volume of
In like manner we
surface.
that if a
to the
as the like
air at the
may
infer,
it
and temperature
around
as the air
it,
without
in
favour of the
serial
atmosphere were to be
were substituted
in its place
the
Sup-
surface
weight equal to
and suppose
further,
atmosphere
at the
its
at
it
minish more
diminution
for
It
could not
of temperature of 25
di-
that a
reduces the
OF THE ATMOSPHERE.
force of vapour one half;
if
129
therefore a greater
perpetually from
But
regions.
if
thus
condensations
we suppose on
be
in
disturbed
the
upper
that the
these intervals
regions
would
equilibrium
general
could
condensation
is
admit of
but
it
at
the
The
specific gravity of
air,
and
30 inches of mercury,
its
temperature
at the
12 miles,
162;
at
In
18 miles, 137;
at
24
density, not
maximum,
isting temperature
nor
evaporation
in
any region.
ON THE TEMPERATURE
130
2.
degree.
at
now
diminish-
not being sufficient to support the weight, a condensation must take place
is
would be perpetual
at
30
strife
Thus
inches.
there
of rain descending.
position
much
less likely
3.
but
else
so that
slowly
in this case
would be a maximum
where
before,
if
no
it
would evaporate
in the 1st
OF THE ATMOSPHERE.
131
case,
owe
to
which
elastic fluids,
present section
first
me some
he suggested to
maximum
if it
pace with
maximum density
is,
if
it is
sion
there
it
would con-
its elasticity.
In
when
it
32, of
in
it
as
in the
which
no change
is
is
the expulsion
is
same whether
that approximation
Indeed,
if
we
estimate
1,
by
it
would
volume
is
to
out.
But
it
132
atmospheres
other
necessarily most
with
which however
intimately mixed,
capable of demonstration.
and
to enforce
the
illustrate
have endeavoured
I
it
in several
Essays
in
and
in
Society,
is
it
think
is
fluid,
Now
whether of the
but
it
one we have of
ture
Something of an
air.
tions,
though
it
may
at
effect simi-
by the
occupied by
it
and
its
atmosphere.
At
the
first
towards
atom or
solid
whole space
compression,
space
greater,
but at the
last,
the reduction
would be much
by theory.
Since writing the above, Mr. Ewart informs
idea respecting steam, which I had from him,
Mr. Watt's.
thor, speaking of
steam
is
at least as
It is
is
that the
originally
diminished."
1,
me
much
we
at
low
is
little
noticed.
ON CONGELATION.
what
lar to
is
133
namely, a
condensation of vapour
is
going on below.
own
moment
evaporation
observation
our mixed
in
This
all
is
actually
know from
a cloudy stratum of
that
their
air
fre-
is
comparatively dry.
SECTION
9.
so
different from
mechanical
all
the appearances.
This attempt
It will
is
the
be expedient
The
is
ON CONGELATION.
134
2.
When water is
jar to cool in
still
20 or
30,
but
if
it
may be
any tremu-
in the water.
of ice at the
commencement, and
in the
early
150 of the
again
quantity
may be ^
of 32 contains.
to the
of the temperature.
6.
If water be
tation,
it
exposed
to the air,
and
;
to agi-
the appli-
and the
still,
135
ON CONGELATION.
not severe,
it
may be
if
the water be
difficult
water
the
cool
without
as 7 or 8,
but
it is
much below
freezing.
its
that temperature
have obtained
it
it
it
as low
again without
being frozen.
8.
equally difficult to
any part of
very
it
it is
may be caWed/orced
is still
observed as
given above.
When
9.
bulb,
but
it
water
retains the
if it
cooled to 15 or below in a
is
like snow,
is
moment
is
pro-
When
water
is
it
be
let
all
globular,
each
particle
touches
1,
Plate
3,
so that
ON CONGELATION.
136
horizontal plane.
particles placed
squares, but
upon these
so that
each globule
falls
first
stratum, and
perpendi-
exhibited in
is
Fig. 3.
that of water
To
into the
at the
of
order
like
in
number of globules
which
is
given
in
let
cubic
n =
the
and because a
line
n -^ sine
number of
=71-^
Whence the
J\/2.
particles in the cubic vessel = ri' -r ^\/2= 7i^V2.
of 45
Now
let
instantly
2)
it
drawn
of the
same number of
pile
is
rhombus (Fig.
still
consist
in
now
ON CONGELATION.
137
particle being
But
to counter-
are
increased in
height.
number
greater
disposition
last case,
will
hold a
It
is
then arises
question
in the
is
therefore elevated
sented in Fig. 4.
The
as 1
v/f,
^/f, but
that
is,
.750
as .707 to
nearly, or as
the
first
The
last or
rhomboidal arrangement
is
suppos-
upon congelation.
The
But
to 100.
is
bulk of atmospheric
liberated
air
and
ice in
is
such sort
ON CONGELATION.
138
ing
its
weight
this
makes
it
Hence
is
explained.
The
angle of a rhombus
ment 120
if
60,
is
and
its
supple-
we ought
to
nomena.
Whenever
any remarkable
internal constitution
of any
change in the
body takes
place,
existing in
it
pheres
of
heat must
though
it
tity,
some modification
may be
evidently
difficult to
in the atmos-
be
required;
produced,
as
the
in
present
case.
So
far,
4th phenomenon.
it
ponent particles
fluids,
by heat. Is
by the enlarge-
are expanded
This
is
solids,
ON CONGELATION.
with liquids.
How is
it
139
upon the
perature, and
like
The
and abstraction of
heat. It
is
to
by the addition
be supposed then
the particles
commence
form
to,
but
if
or taken from
is
or
below
that
point.
If heat be taken
expansion
is
38, then
form
the mass
is
way
whilst
occasioned by friction
ON CONGELATION.
140
affinities,
new form
the
formed
heat
is
subsequent formation,
This
gealed.
But
tion.
if
is
till
at last the
whole
is
con-
is
kept in
farther
carried
much
is
sufficient
to
counteract the
new forma-
till
similar
operation
to
is
table,
the proxi-
is
much
as-
of the table.
Hence
phenomena
CHAPTER
II,
ON THE
CONSTITUTION OF BODIES.
There
more
especially
instance
A very familiar
and solids.
is
assuming
all
is
capable
In steam
we
of
recog-
and
in ice a
complete
solid.
These obser-
all
bodies of sensolid,
are con-
is
it
endea-
very properly
142
it
of cohesion ; but
them from a dispersed state (as from
collects
names
more
or,
it
may go
same power.
called, attraction
it is
simply,
by, they
It is
not
affinity.
and the
signify one
still
my
of aggreWhatever
design to
call in
ques-
made no use
of
the
it,
thrown upon
The
is
new
daily
growing more so
lights
attempted to be
it.
opinions I
more
of Chemical
there
Laws
and that in
exist insensible
all
propor-
is
chemical unions
gradations
in
the
pro-
The
in-
I think,
fail
to strike
nomena.
Whether
is,
of the
same
some importance.
weight, &c.,
is
From what
is
a question of
figure,
to appre-
exist in water,
it
must equally
143
does
if it
Now,
oxygen.
how
it is
If
if
must be supposed
it
Similar
observations
therefore,
particles
is
In other words,
^c.
like
'perfectly
is
like
every
derable bodies,
we
all
is
like-
matter which
This
is
now
atmosphere of
this
An
them
144
This
by abstracting some of
its
it
should seem
we cannot
avoid inferring,
Be
this as
it
may,
We
now
are
to consider
antagonist powers
how
of attraction and
repulsion
of elastic fluids^
states
We
fluids
tic
and
solids,
shall
namely,
liquids,
first,
on
fluids
third,
on the constitution of
liquids,
145
SECTION
1.
particles of
which are
tinguishable.
is
one,
all alike,
the constituent
way
or in no
dis-
azotic
These
gas,* and
fluids are
very diffuse
or
two thousand
by such an atmosphere
as all the globules in
it
or figure
when surrounded
must be globular
but
and
will therefore
be arranged
all
in hori-
volume of
146
fluid
elastic
pressure
is
taken
is
off*.
The
of an elastic
ing,
fluid,
we have no means
little
of estimat-
great
but the
diminution be ascertained in
many
may be
cases.
Thus
of water;
that of a
watery sur-
particles of a
is
equivalent to
therefore
steam
is
ticles of water,
feet
And
whose height
is
34x144 = 4896
With
re-
is
entirely counteracted
move
the particles
is
is
by
that
efficacious
if
the attraction be as
as
is
fluid, so far
its particles, it
them
It
2.
147
to separate
in their situation, or to
ration.
A vessel full
The globules
shot.
are
all
one
full
of small
but
small
central
atom
of
solid matter,
which
is
known from
Whence
is
versely as
is
its
power of each
diameter.
repulsive power,
if
That
we may
particle
is,
so speak
is
is in-
the apparent
;
not known, as
When we
its
elastic
fluid,
any material
148
change
it
follows
must
a measure of air
were expanded
Thus, suppose
into 8
measures
dis-
and the
elastic
whence we see
that
Some
resist
them.
same
ratio as the
elastic fluids, as
mass of elastic
fluid.
force of heat
is
it is
more than
to
To what
say
a
still
we cannot
superiority,
elastic fluid
other elastic
fluids, as
when
the
solid.
In
and
fall
down.
From
149
1,
it
was owing
The
ing of one.
The
fact.
however
last
to
cwh-
I believe is the
which the
ened.
latter
As
overruled,
is
the
it
should seem, in a
the approximation
degree,
when an
powers takes
result.
That
has
still
affinity in-
greater ratio,
a
attained
certain
place,
and the
we may
wherein
it is
shewn
condensation of steam,
is
in all probability
fluid,
could
like
it
by the
off
no
by any perma-
be mechanically con-
volume, and
is
moreover a
combination.
cerned
in
this
As
far
is
con-
150
The
as water,
constitution of a liquid,
must
particles,
manner
an equal degree.
Of
this
SECTION
more
in the sequel.
2.
two or more
elastic fluids,
whose
parti-
they
difi'used
main
so,
The
fact admits
whatever
may be
of no doubt
but explanations
them completely
satisfactory.
As
the subject
is
more
we must
enter somewhat
earliest to notice
naturally struck
it
two
elastic
fluids,
him with
having apparently no
selves
according to their
liquids
do in like circumstances.
specific
this
surprise,
affinity for
found
151
gravities, as
Though he
as probable, that if
exposed
fluids
could be
to
specifically heavier
He
tion.
two of such
would retain
much
does not so
its
lower situa-
as hint at such
With regard
to his suggestion of
affinity.
made
From
series.
these
it
1.
new
but
it
if exposed
ever so
of
communication
is
small.
This
time
freedom of communication.
When
or
152
know
propagated, I do not
affinity
but
it
was
first
seems proba-
led
air,
being dissolved in
air.
dis-
that of air
to
Philosophers
appeared or evaporated
its elasticity
to
ance of the
air,
was necessary
resist-
In the
fluids
and increased
air,
was known
permanently
in
indeed,
much wanted,
agency
this
as they are
been
satisfied
nay,
for
air,
it
was
of water in
solution
natural to suppose,
In
water,
different
Saus-
hydrogen
gas,
be expected that
powers of carbonic
and common
at least the
air.
It
might
its
solvent pow-
153
some proportion
again
we
density
to the
are disappointed
faction, if
extreme moisture, as
These
ception
how any
between
air
extreme
common
in air of
difficulty in
fiicts
are
the con-
It is
thousand
in the
dissolves water
and
a torricellian
in this instance
is,
the
what makes
vapour
it
in such
given
vacuum
air in a
we
air at all
to
air of
extreme moisture.
154
seemed to be exactly
phenomena of vapour
it
gave
rise to a great
and published
memoirs,
1802.
The
new theory
own
kind.
upon the
if
vessel, with
its
proper
elasticity, just as
between the
fluids
themselves
is
observed.
This
because
to
it
and
more nor
support
neither
it
was perfectly
less
So
far
own weight
obvious why
its
in a
air
of
The
firm the
only thing
all
now wanting
155
The
temperatures.
to completely establish
atmosphere,
liquids
to
to
to
advantage
if it
existed,
vapour
The
at ordinary temperatures.
on
its
existence
occasional
its
of water
atmosphere
how does
subject
The
it
to the
rise
from a sur-
pressure
consideration of this
if
From
it
made
being
of the
would,
be accomplished.
were
both
were soon
circulated,
The new
facts
and
156
verted
and
misunderstood,
consequently
reprobated.
at least
from
my
in its
exposition.
who
publicly animadverted
gentleman, so well
known
know,
this
as far as I
first,
but
that,
for
granting
still
arrange them-
was adapted so
permanent
it
it
as to obtain the
diffusion of gases
But
was quite of a
but
was as a vacuum
it
was urged,
to another, a
to a
measure of
Finding that
my
November, 1802.
voured
mixed gases
more
my
at large, according to
particularly
touched
feature of
that of
it,
upon
more
or
were interposed
affecting the
particles
of
casually to
A.
Or,
come
stated law,
action of the
any
if
it,
this
said
particle of
in contact with
two
were
one of A, and
and
discriminating
the
by the known
reciprocal
press against
hypothesis
15?
all
in
the surrounding
contact with B.
is
resembling
as
As
more
or less,
it
will
it is
made by
expedient
be proper to point
First, I
new theory
own views
on the subject
and then
and
reflection
The
158
given a chapter on the constitution of the atmosphere, in which he has entered largely into a
new
discussion of the
chemist,
ments made by
sier,
Watt,
De
&c.,
This celebrated
theory.
results of experi-
together
with
that vapours
elasticity of
much
those
assent to the
full
of every
alike,
and just as
so,
vapour in
and vapour
air
Gay
of
vacuo
1.
in
Sect.
vacuo
4.)
is
in all cases
Consequently he
which
have
laid
down
can dissolve,
air
namely,
P
where p represents the pressure upon a given
volume (1) of dry air, expressed in inches of
mercury, /= the force of the vapour in vacuo
at
So
he objects
far therefore
we
to the theory
J9,
after satura-
perfectly agree
by which
but
attempt to
159
of his own.
The
first
is
one that
he
opposes
interstices
of
vacancies, there
of volume
they were
when aqueous
combined with
occupied the
though
as
the air
nevertheless there
is
one
air,
as has
is
whereas
it
renders
it
specifically lighter,
This
urged
if I
it
gentleman
is
9?
page 162)
profoundly skilled in
Let
dry
air
tall cylin-
be inverted
by a syphon,
till
an equilibrium of pressure
is
but what
is
the obvious
160
consequence
Why,
new
raised vapour,
and
without,
of air
is
and by the
air,
an
restore
unavoidable, in order to
equilibrium.
there
is
air
the
suppose
one
= 23 inches of mercury,
= 6 inches. The air
The vapour
by the
first
formed
that below,
must, in the
and
as constantly resisted
first
(for,
upward
elasticity of the
quence of which
its
is dilitation.)
force to the
pressure, the
alleviates their
air,
in part
necessary conse-
At
last
when
all
admit
of,
equilibrium
original
In this case
the others
return to
is
true, there
was combined with the air humidity would increase the weight of the congregated atmospheres,
;
I6l
pressure.
solution of the
this
thought that
any one
try.
division of the
**
enquires,
Is
such a
Can
be conceived that an
it
which adds
exists,
volume
its
to that of another,
it,
Certainly
is,
act
and
Two
reduced
to
air
atoms
may
act
as inelastic bodies
So two
all,
unless
if
when
inelastically,
and therefore
reciprocal
combinations
same
elastically,
in contact.
but
they were
particles of the
not only
kind of
its
this
we can
by
it
on
act
allowed to be in point.
other, that
substance
elastic
also
action
produce
which
azotic
nitric acid
decides
the
162
commencing
at the precise
it
ducing
effect,
its
moment
at
which
it is
manifested,
becomes preponderant."
It is
till
it
When
comparatively
ter
I
is
it
to manifest
any sign of
to
deny an energetic
affinity
hydrogen,
mixed
state
is
&c., in a
but that
affinity
it is
not
the
Is
it
with oxygen
itself
necessary to
like
have recourse
to a sup-
possible this
may appear an
objection to a person
who does
163
who
such as atmospheric
air,
it
never
If a mixture of gas,
does.
to
just the
change
my hypothesis,
press
same
as
a similar
by heat and
And
cold.
We
shall presently
examine
Another objection
is
it.
were as a vacuum
for another,
certainly plausible
we
why
?
is
if
one gas
the equili-
This objection
shall consider
it
more
at large hereafter.
without
it
persed, and that nothing would limit their separation, unless their
collect
them
164
to
form an atmosphere."
This, I
may remark,
is
surely the
we now
possess
of mercury,
at the
from
rising, unless
temperature.
there were an
increase
of
that
vacuum
at
What need
then
serial
may in
165
be much
fact
may be much
greater
cannot see
how
conclusions.
The experiments
air,
air
doubt
without resistance.
This
its
way
true no
is
in such cir-
its
form as
fast as
trating
in
the
if
cool,
and
sides,
it is
external
atmosphere
the vapour
fall
to
its
remote
extremity.
We
come now
to
phenomena
ing to his
affinity.
of gaseous mixtures.
there
theory,
The one
is
are
strong,
Accord-
two degrees of
makes the
particles
and
may be
166
gas
is
when oxygen
The
had previously.
other
is
its effect
for
atmospheric
in
air, in
upon
tic fluid in
this
elas-
observations.
That
following quotations.
no change
is
is
observed
temperature, or in
may be
hence
it
elasticity, or
."
"Although both
which only
differs in its
maybe
established be-
very material
is
167
the combination
and gives
new
rise to
properties
"The mu-
between them an
effect
which
is
which belongs
is
(Page 218.)
inferior
to each mole-
not changed by
is
that
produce
is
preserves
retained
by an
first,
each of
affinity so
weak,
its
cohesion, as
undergo
an
not happen
equal
distribution,
which
could
chemical attraction
that which
constitutes the
168
force of cohesion."
of chemical
The
has,
the translator
English idiom.
Here
affinity,
force of cohesion
terogeneous
but
this
He
particles.
mean
homogeneous
elastic fluids
the
phenomena
the
of their
centres
diminishes
in
This deduction
distances.
the
are.
Laws
What
of elastic fluids
reason,
a pity
is
it
will stand as
long as
who attempt
or to theorise respecting
to
the constitu-
make themselves
tion of
thoroughly acquainted with this immutable Law,
elastic fluids,
should not
it
in their
!
When we
contemplate a
consist of such
and he ought
very
first
l69
oxygen
unity,
same, then
we must conclude
mutual
that the
oxygen
is
the same as
retains
Law
above
But
by chemical agency.
solution
be sup-
if it
elastic
number of
particles of
fluid
Law
Newtonian
may
in this
when
the
in
3, &c.
Now
take place
something like
when
as 1 to 2, 1 to
this
a real combination
and
nitric acid
does actually
is
formed, as
formed of a
have new
the
new
fluids
differ
Here we
is
given
170
It
is,
in so small a
It certainly requires
One
or
this,
from the
arises
How
of water.
too great
is
it
said,
is
there must
But when
we
is
is
subject to
between the
is
a sensible affinity
affinity
object of which
menon.
upon
is
Further,
why
how
It is to
me
a particle of water to
assigned
it,
an inferior one of
its
property,
when each
particle
If a portion of
com-
l7l
mon
salt
acid added,
muriatic
little
is
combined
ously had
water,
Or,
if
is
be said in the
will
it
affection
all
the atoms in
it is
it
not the
that of a
is
the uni-
reciprocal,
on the
is
it
But
like action
its
constantly giving
have a
previ-
is
oxygen
it
air,
as all
its
weight, which
is
contradicted
by experience.
When
the whole
is
fired
by the
electric
if
number
as in
is
the same
one of oxygen.
172
of oxygen,
According
how
is
to the principle
be found
like this is
at the
and ought
latter,
nothing
Much more
might be advanced
to
it
to explain
was
likely to give
in
its
it
behalf
Dr. Thomson,
of Chemistry,
the subject of
in the
3rd Edition of
his
System
mixed gases
he seems to compre-
my
notions on
He does
my hypo-
mon an
air,"
There
objection.
173
is
my
At page
hypothesis.
448,
Vol.
he
3.
Nor can
sure.
whole pres-
I perceive
this
well founded."
Upon
equili-
brium
is
particle of gas
particles
is
of
is
its
pressed as
own kind
if
by the surrounding
It is in the re-
only.
The
the weight of
oxygen
all
in the
the particles of
low-
atmosphere sustains
oxygen above
It
it,
was therefore a
of gas
is
equally pressed in every direction, but the pressure arises from the particles of
its
own kind
come
of azote, at the
in contact, the
moment
is
only.
put to a
full
force
174
same
its
at last
till
The
volume.
just
becomes the
.26
cube
it
nearly.
that
is,
as ^\/2
1,
be 1.26
it
only to be
is
exactly
all
the rest
he takes
notice of
vacuum
and conceives
this
to another.
He
fact
is
as
a particle of
unite with
it,
and form a
oxygen coming
into
of hydrogen, ought to
particle of water
but,
state
is,
;
upon the
when one
that
is
175
facility of certain
of the ingredients
is
in a
ob-
combinations,
nascent form,
he observes,
this,
*'
seems incompatible
Upon
elastic."
Thomson
it
inclines
have the
and admits,
may appear
at first
doubt
if
have no
this
absurd
it
This occurred to
speculations
ought to do on
me
in a
the entrance
my
hypothesis
my
of reasoning
but
it
it
The
to the
resistance which
till it
was called
176
of that body,
greater,
all
and
is
is
made
but
tance
it
did before
Hence
diameter.
it
medium,
it is
is
maximum.
consider particles
their
own
moving
in
any
gravity,
We
maximum when
the
by
Here we
must he conceived
may be
shall find
to he infi-
The
shall
lately
at present.
edited a system
of
and of other
He
phenomena
177
of the atmosphere,
mixtures of elastic
similar
fluids.
thinks
is
phenomena
well, but
He
which he adopts.
my
does
hypothesis in
my
principal feature in
of the application of
evaporation.
The
it
from mine,
to recount the
clusion, because
It is
unnecessary
arguments on behalf of
it
Murray announces
will
attrac-
this con-
are merely
z
when they
dis-
178
union,
their
may
still
separation
be so
far exerted, as to
they
or,
by the
may be
prevent
retained in
many
them
bodies, retains
He
by various
in
supports
observations,
whose doctrine on
is
this subject, as
may be
farther,
and
to adopt as a
first
it
little
fluid,
to,
in the
distinction
relative,
for
Mur-
case of
are
attrac-
This, Mr.
to combine.
a permanent
is
this
merely
the state
Is
it,
is
no traces of
number
What
is this
oxygen
then
notwithstanding
it
is
is
so far ex-
No
they
attraction,
of particles of
gaseous form.
179
when
do,
like
in the
the conclusion
It
and
in every situation^
is
then the
differ-
From the
are consistent
being so
far
but
:"
So
far I think
when we hear
they
of this affinity
propriety
it
Suppose
this
affinity
of 212
to the
weight of a
feet high.
(See page
146.)
It
is
somewhat remarkable
that
those gases
180
known
to
faci-
for,
hydrogen
is
20
One
more
to
But
it
is
who adopt
the the-
1 of
hydrogen,
it
is
medium
Now
is
this
those
connected by
would be well
tain
the
if
doctrine
of chemical
solution
would
be
to
it,
who
would
are dis-
precision.
it
learn, to obtain
181
more
central distance
to illustrate
information,
my
any pre-
it is
sideration
that the
mixture of
fluids
to
affinity is
preserves
can this
weak
repulsive
power of
its
affinity do,
so
weak
that the
What
dimensions.
when opposed by a
infinite superiority ?
quantity of vapour
is
it
more abounds.
touchstone
theories
of
and
the
I
that the
fact,
to ascertain in
This
mechanical
is
which
certainly the
and
chemical
mechanical theory.
182
it is,
it is
Berthollet
inimical
condemning
in
it,
as
extravagant the
Upon which
at
presents
little
exists
more
in
it.
In 1802, Dr.
them more
Henry announced
at large.
a very curious
the
in
Philosophical
Transactions
water
is
to the
atmosphere
it
to
me
that
air,
by
of time ought to
compensate
for
weakness of
183
its
to
be surprised
at
water ab-
this
till
Immedi-
it
is
perfectly pure or
maximum
effect for
otherwise
to
be correct
became expedient
in
consideration of
all
became convinced,
elastic fluids
consequence
to repeat
some of
telligible
the
produced.
of which,
unmixed
Upon due
was no system of
in-
if
the
184
Nicholson's Journal,
may be
Henry
preference.
is
has clearly
my
theory a
a letter from
Mr.
Henry.
In the 8th, 9th, and 10th Volumes of Nicholson's Journal,
chester
and
in the first
Memoirs (new
series)
Vol. of the
may be
seen some
my
doctrine of
mixed
gases, with
some of
Man-
his
own
opinions on
the
air
shewing that
air
it
the one
supported be
it
was
Franklin,
was
first
changed
into vapour,
and was
in that
dissolved by the
185
This amphibious
air.
any converts
to
though
it,
it
in-
received
air,
its
all
in the Philoso-
These gentlemen
demonstrated, that
De Luc's
is
All the
present.
is
to
becomes the
it
same.
The
me
to raise
any
to
Gough
media,
it is
chiefly
difficulty,
sound
be heard double
that
is,
same sound
as
was brought
it
By calculation
I find that if
sound move
per second
to
move
at the rate of
A a
If
the
in
of two distinct
by one
has pre-
1000
it
feet
ought
namely,
186
Feet.
Sound moves
in azotic
gas
oxygen gas
930
carb. acid
804
aqueous vap.
According
to
this
1175
table, if a strong
be a weak impression of
it
off,
the
and loud
would
first
in
59 seconds
brought by
all,
would be much
inferior
to
the
the
the second,
it
comes
that of the
as near
more simple
it,
perhaps, as
it
does to
Derham,
who has perhaps made the greatest number of
accurate observations on distant sounds, remarked
that the report of a
cannon
was repeated 5 or 6
it
"
The two
first
cracks
but the
last
cracks
rest."
18?
Cavallo, in
much
houses, or other
hills,
But
we cannot
is
or 20 miles,
when
near.
may be compared
musical sound
ous,
it
begins
may be observed
it is
in
a grave
to a determinate
Nearly the
are likewise
by the distance."
now proceed
greatest loudness,
same
Whereas
In the latter
sound, which
dif-
is
(Vol.
2.
altered in
page 331.)
my present views
on the subject of mixed gases, which are somewhat different from what they were when the
I shall
to give
lights
diffused.
In prosecuting
nature of elastic
fluids, I
my
soon perceived
it
wa>
188
necessary,
if possible,
whether the
to ascertain
By
it
signifies the
fused idea, as
many
surrounding
its
At
the time I
had a con-
same
size
that a given
in this
mean
the size
many
volume of hydrogenous
all
of the
volume of oxygenous
particles as the
same
But from a
train
same
as a
trary
size
maxim,
:
to the con-
namely,
pai'ticles^
189
to
ascribe re-
acts
For,
another.
if
effect
on
why
a particle of
oxygen
one of
its
were both of a
size.
deration, I see
no
the
common
and
heat
may
still
own
consi-
sufficient
I think the
be accounted
for,
by
repulsion, without
When we
we perceive
it
strata,
forming a square
particle rests
of
its
in
upon four
contact with
all
On
this
account
190
the pressure
is
in
any
is
vessel,
presented to a
we have then
in contact with
another
from 40
from
to 90
all
the
way
this inequality,
and the
particles of
one kind
The
elastic sur-
that
tion
till
the
particles
is
stability,
at length is acquired
when
till
so far as to be restrained
that
is,
It is
till
by
their
own weight
sustain
IQl
principle of diffusion
for, particles
of fluids are
least.
is
Thus, in a mixture of
common
being denoted by
1,
noted by
the
Vi=
its
density, will
when
be de-
.794.
plausibility.
The
1st.
is
effected
to the
diffusion of gases
homogenous
which
is
particles
or to that principle
2nd.
When
ac-
if it
were withdrawn.
all
the
192
the former
why mixed
against
known on
certain oc-
why any
more disposed
to
more
and
It
it
is
has
will also
so powerful
trance of another.
One
difficulty still
removes
in the
at-
it
rise
how does
inch
30 inches of mercury
This
difficulty applies
theories
of the
it
to
of mercury, detach
has
oppose
nearly the
solution
weight of
the
of water
its
ascent?
same
in
to
air,
all
and
193
affinity
always described as
sufficient to
is
it
is
overcome the
ject are.
It
have endeavoured
(Manch. Memoirs,
in another place
series^
my own
to
shew
vol. 1.
new
it is
not
till
the
becomes uniform
cles
in
the
subject to but
Bb
little
pressure.
in
reality
ON LIQUIDS.
194
SECTION
3.
ON THE
CONSTITUTION OF LIQUIDS,
AND THE MECHANICAL RELATIONS BETWIXT
LIQUIDS AND ELASTIC FLUIDS.
A liquid
may be
or inelastic fluid
defined to
another.
This definition
may
for the
suffice
is
no substance
cause of elasticity,
the
word
elastic to
inelastic
if
heat be the
bodies containing
all
necessarily be elastic
Strictly speaking,
but
such
it
must
we commonly apply
fluids
Water
is
compressed by a great
the pressure
is
removed.
its
force,
original
We
it
but
yields a
bulk when
are indebted to
ON LIQUIDS.
Mr. Canton
195
is
demon-
about
aTrroth
Water, he found,
strated.
part of
its
by which
lost
phere.
When we
steam,
we have no reason
pressibility,
and that
would be wonderful
The
in a
if
to
times
it
is
We
reduced
to
know
still
What
compressing force
The
com-
at its
must
wonder
truth
retain the
a powerful
make
is,
against a
water, and
must be considered
by
as bo-
is
is
repulsion, be-
an equilibrium.
applied
it
If
any
yields, indeed,
tion of liquid
is
is
different
ON LIQUIDS.
196
that
being balanced
heat, a
moderate force
capable of producing
we
the' separation.
the attractive
is
force
to prevail,
perceive
It
being a
there
Whence
when two
but
if
as to separate the
case,
why do
to
overcome.
they at
first,
If this
upon
or
With regard
ment of particles
and arrange-
to the collocation
in
It
is
same
as in
nomena
law of
expansion
fine liquids to
is
by
unaccountable
heat.
The
we
con-
if
if that
were the
for,
case,
197
way
When
an elastic
fluid is
confined by a vessel
it
is
external
till
is
air,
to
no doubt but
this is
There
fluids.
Other
most completely.
porous
air.
I believe
no
sort of
such a one
in practical chemistry.
is
a desideratum
each other.
Do
they
gases,
in
How
resemble
regard
to
glass,
their
or
earthenware,
or
power of confining
198
elastic fluids
Do
they confine
do
they treat
some,
gases alike, or
all
and
transmit
others.
examine the
facts.
down
lay
a rule,
if
it
will
possible,
be necessary to
by which
to
dis-
of
I think the
When an
elastic fluid is
lime
falls
upon standing a
time,
the
which
Laws
it
of specific gravity.
portion of lime
is
Why ?
dissolved
to the
Because that
by the water.
If a
upon standing
a sufficient time,
parent
199
trans-
it
portion of
air,
Why?
gravity.
Laws
contrary to the
air is dissolved
of specific
by the water.
So
two
far the
But
we
if
place the two portions of water under the receiver of an air pump, and exhaust the incumbent
air,
is
If
now
water
is
an
upon
none on that
for lime
its
is
The water
in.
it
why
on the surface
elastic force
which holds
as
have some
solution
of the
in
still
But, perhaps,
of the water
may
for air,
and
affinity
Let the
air
be drawn
off
pressure.
changed
The
lime
water
The
more
remains un-
difficult
much
by
this fact to
seemed
to
in
be
be
the
200
yet in
all
it
appears as
three,
it is
From
these
facts,
namely,
One
it,
whatever
which
air.
decide hastily.
*'
and
water
red hot,
there
air
in
if
when
aerial
is
form
it
recovers, after
it
it
has been
the
retort."
till it
But
travagant an opinion.
From
with those of
my
its
201
202
same degree
is
condensed or rarefied
One remarkable
at
another in water
like as in a
fact,
no one gas
that
is,
it
is
capable of retaining
like as car-
it.
just
stated,
it
appears
of the
It
first class is
not at
From
is
the
all
affected
by the water.
the water
is
present or absent.
with water
abide by the
we must
Law
mutual action
therefore, I conceive, if
we
pronounce the
to
be mechanical.
takes place
three gases
when
is
a portion of
3^0
203
the
if
a small portion of
common
air is
it
film
airs
of water
come
into
ascend
with great
water runs up
speed,
below,
finally bursts.
is
till it
common
it is
air.
density within the water should be such as to require the distance of the particles to be just 2, 3,
or 4 times what
it is
without.
is
is
and
in
is
3 times as
This
gation
whether the
tion to
but at present
it
affected
is
if
water takes Vt
204
of
its
exerts -^ of the
absorbed
gas so
the
it
gas
same
thus, if water
gases
is
of
its
if this
certain
after
Dr.
is
aV
it
It
seems
a mechanical one.*
bo-th
written
combined
in a greater or less
this
affinity is
degree towards
all
supposed to be of the
which holds
all
gases in a state
The
the
first
series,
Vol.
Dr. Henry,
1.)
nature, wTote
two essays
son's Journal, in
clearly, and,
which
think,
in the
tlie
his
own
experience,
was of a mechanical
unanswerably stated.
do not intend
'205
time
it
its
whole force
in
in a short
to enter
that
the
gentlemen adopt.
repulsion
between the
absorbed,
particles
He
just
then proceeds
such
is
and of
is
azote, ^, &c.
Now
if a particle
it
two
if so,
and
if
it
into
is
Hence,
should
infer,
from
and consequently
lib.
of water would
Mr. Murray
make
for instance,
known
conceives
some
to be absorbed
affinity
therefore
and
206
gas
the
Finally,
the
gas within the water then presses on the containing vessel only, and reacts upon the incumbent
The water
gas.
In olefiant gas
sure, in
CVC,
4.
When
any gas
is
conceive nothing
is
;
be allowed to
agent
wherever
it
Whoever undertakes
agent.
to
to point out
is
it is
it is
fou7id
to
a chemical
a mechanical
maintain the
chemical
Henry
"
absorbed by water,
gas,
and since
it is
perfectly safe to
by water,
There
is
is
re-
no occasion,
when
appearances."
;;
in the
207
medium
air is filtering
its
becomes
Water
tort
it
an earthenware re-
same time.
It
is
should be so permeable to
and not
The
densities
|,
^^^
^V)
a reference to a
wi^
No
if
Upon
the whole
earthenware,
is
meable
in
mechanical
the densities of
by
this
law
agree in some
all
earthenware
others.
why
the
in
but
why water
one respect
but
it
the last
is
differs
is
from
alike per-
much more
208
permeable
to
liquids
Other
to others.
sufficiently
examined
in
this respect.
The mutual
number
will
be best
and
alkalis.
SECTION
4.
ON THE
CONSTITUTION OF SOLIDS.
solid
body
is
attraction
that
in
heat resists
resists
it.
it
The
is
if
in their distances
If an approximation
ing planes of attraction and repulsion seems unnecessary, except that upon forcibly breaking the
in its
atmosphere
209
The
solids,
between
essential distinction
perhaps consists in
liquids
and
heat changes
this, that
is
whereas
in the lat-
size,
particles.
of
moving the
particles
one
The
ductility
only to be mentioned.
ticles glide
if assisted
It
without
being at
The
cohesion.
all
end of a mag-
weakened
by experiment,
It
is
an enquiry
of an inch in diameter,
Dd
their
in
were
heat.
net,
by
210
Lead
29i
Tin
49i
Copper
299J
360
Brass
370
450
500
Silver
Iron
Gold
Pound
yard long,
will just
One would be
Iron
is
about 10 times as
same dimensions.
but this
is
Glass
much
is
harder
the stronger of
the two.
Crystallization exhibits to us the effects of the
various
compound bodies
but
we
are scarcely
and analysis
process.
to
the proper
position
of 4, 6,
8,
arise
from
or 9 globular
ON CHEMICAL SYNTHESIS.
particles, the
10
particles, the
211
Perhaps,
to ascertain the
number and order of elementary particles, constituting any given compound element, and from
that determine the figure which
crystallization,
mature
to
it
will prefer
but
it
on
seems pre-
this subject,
till
we
have discovered from other principles the number and order of the primary elements which
combine
to
which we
shall
the
endeavour
to
CHAPTER
III.
method
for
ensuing chapter.
ON CHEMICAL SYNTHESIS.
When
any body
exists
in the
state;
much
each particle
occupies
the
centre
of a
ON CHEMICAL SYNTHESIS.
212
all
its
a respectful distance.
ceive the
number
dig-
When we
it,
at
attempt to con-
of particles in an atmosphere,
it
so minute, the
finite;
num-
infinite.
to
the
separation of particles
or destruction of matter
We
chemical agency.
introduce a
GO annihilate
new
is
one from
No new
creation
to
we can produce,
all
chemical investigations,
it
has justly
213
ON CHEMICAL SYNTHESIS.
tute a
compound.
and weight
compounds would
other
in various
and to correct
investigations,
it is
importance
Now
relative weights
simple
their results.
this
of the ultimate
and compound
particles^ both
bodies, the
of
number of sim-
compound particle, and the number of less compound particles which enter into the formation
of one more compound particle.
If there are
two bodies,
2
1
the order
is
A
atom of A
atoms of A
atom of A
atoms of A
atom of
+ atom of B =
+ 2 atoms of B =
1
atom of
-{-
3 atoms of
-f-
atom of
B
B
B
=
=
==
viz.
atom of C, binary.
atom of D, ternary.
atom of E, ternary.
atom of
atom of G, quaternary.
F, quaternary,
&c. &c.
The
may be adopted
ON CHEMICAL SYNTHESIS.
214
guides in
as
our
all
investigations
respecting
chemical synthesis.
1st.
When
can be obtained,
binary one,
must be presumed
to
be a
the
it
contrary.
When
2nd.
When
3rd.
to be a binary^
two ternary.
4th.
we
When
four combinations
observed,
are
binary
specifically
two ingredients.
6th.
which would,
simple,
it
combined,
if
and a
constitute
&c.
apply,
The above
when two
D and
7th.
From
chemical
the application
facts
such
bodies,
already
as
of these rules,
well
and D,
to
ascertained,
the
we
ON CHEMICAL SYNTHESIS.
deduce the following conclusions
water
215
1st.
That
oxygen,
gas
.
is
a binary
is
a binary or ternary
compound
azote,
nitrous acid
is
a binary
a binary
; 4th.
compound,
charcoal,
nearly 12
that
nitric acid
compound of
weighing 26
binary
weighing 17
compound of
consisting
of
one atom of
&c. &c.
In
denoted by unity.
ON CHEMICAL SYNTHESIS.
216
which these
conclusions
detailed
as
derived,
are
inferred the
will
constitution
be
and
acids,
metallic oxides
neutral
salts,
the
earths,
and
train of
com-
good
analysis.
From
deemed
expedient to give plates, exhibiting the mode of
combination in some of the more simple cases.
it
The elements
is
by a small
circle,
more of these
when
it is
to
in the juxta-position
three or
more
combined together
FIRST.
217
author's
1,
the subject of the capacities of bodies for heatThere are three cylindrical vessels placed one
See page 3.
within another, having no communication but over their
margins the innermost is connected with a lateral and
ideas on
ensue,
when
coincide, as do 20
PLATE
TL
and
70, &c.
2E
Fig.
1,
218
steam
is
Now if
the side of the vessel, and to be cemented into it.
we may suppose the piston to move without friction, and
the vessel to be taken up into the atmosphere, the piston
will gradually ascend, and suffer the air within to dilate, so
as to correspond every where with the exterior air in density.
This dilitation tends to diminish the temperature of the air
within (provided no heat is acquired from the vessel). Such
an instrument would show what the theory requires, namely,
that the temperature of the air w ithin would every where in
the same vertical column agree with that without, though
the former would not receive or part with any heat absolutely, or in any manner communicate with the external air.
III.
See page 135. The balls in Fig. 1 and 2,
represent particles of water : in the former, the square form
denotes the arrangement in water, the rhomboidal form in
the latter, denotes the arrangement in ice.
The angle is
always 60 or 120.
PLATE
two arrangements.
219
commencement of
PLATE
ultimate particles.
Fig.
Fig.
11
Strontites
Barytes
4 Oxygen
5 Phosphorus
6 Sulphur
7 Magnesia
12
13
14
15
16
17
18
19
8 Lime
9 Soda
10 Potash
21
22
An
9
13
20
23
28
42
Iron
Zinc
Copper
Lead
Silver
Platina
Gold
20 Mercury
46
68
38
56
56
95
100
100
140
167
220
33
34
An atom
An atom
35
36
37
An atom
16
31
gas
ammonia
26
1
water
of sugar,
alcohol
-\-
carbonic acid
...
33
35
2.
ST.,
MANCHESTER.
r2L0
oKr
Scale
A'^apoTxr
SoaEe
-7000
-200
ASateL-
190
100 --
500
I80
400
3oo
300
-B
Zee
'F
20
30
-40
Steam
t/,, Ya/.
ria.te ^
.
O0O0
10
VI
il
14
\A
15
'.fj
so
iH
17
-'O
I^/
JBifffiry
23
2^
21
O 0 O O
26
28
21
25
24.
I
29
o#o
30
O^
33
32
31
CTO
D
35
34-
O^DO
Se/Jtrjiffrjr
36
37
%
f\
iM