Professional Documents
Culture Documents
INORGANIC SALT
I. PRELIMINARY TEST
OBSERVATION
1.
INFERENCE
EXPERIMENT
Colour and
appearance :
2. Solubility:
a. soluble
a. S.S. prepared in
water
b. insoluble
b. S.S prepared in
dil.HCl
EXPERIMENT
Salt + dil. H2SO4
Pass the gas through
lime water.
INFERENCE
Brisk effervescence ,
a colorless gas is
evolved.
-
a. vigorous reaction ,a
colorless gas which
gives dense white
fumes with a glass rod
dipped NH4OH shown
near the mouth of the
T.T
b. reddish brown
vapours are evolved
5.
c. Iodide ion is
present.
, Br- , I-
S.S + dil.HNO3 +
AgNO3
confirmed
b. Br-
confirmed
a. Cl
c. I-
confirmed
Salt+ potassium
dichromate solid +
Conc. H2SO4 + heat
Pass the gas that is
evolved through
NaOH solution.
The solution is
acidified with acetic
acid and add lead
acetate solution .
8.
Cl-
confirmed
Yellow ppt
confirmed
OBSERVATION
9.
EXPERIMENT
Test for Sulphate:
S.S + BaCl2 solution.
INFERENCE
SO4
-2
present
White ppt
SO4 2confirmed
INFERENCE
EXPERIMENT
11
.
A pungent smelling
gas which gives dense
white fumes glass rod
NH4
ion is present
Nesslers reagent
test:
S.S + Nesslers
reagent
NH4
ion is confirmed
Group-I GroupII
S.S +
dil.HCl
No ppt
Pb+2
absent
S.S +
dil.HCl+
H2S(g)
No ppt
Cu+2
absent
Group-III
S.S +
NH4Cl(s)+
NH4OH (Ex)
S.S +
NH4Cl(s)+
NH4OH (Ex)
+ H2S(g)
S.S +
NH4Cl(s)+
NH4OH
(Ex) +
(NH4)2CO3
No
common
group
reagent
Gelatinous
white ppt
Al+3 present
Greyish
white ppt
Zn+2 present
Buff ppt
Mn+2 present
Black ppt
White ppt
Mg+2 may
be
present
Ba+2 / Sr+2/
Ca+2
present
Ni+2 / Co+2
No ppt
Al+3 absent
present
No ppt
+2
No ppt
+2
Zn / Mn /
Ni+2 / Co+2
Ba+2 / Sr+2/
Ca+2
absent
absent
EXPERIMENT
S.S + NH4OH solution
drop by drop to
excess.
INFERENCE
Al+3 present
a. Zn+2 present
b. Mn+2 present
S.S+ potassium
Pale green ppt
ferrocyanide solution.
Zn+2 confirmed
Supernatant solution
turns pink in colour
Mn+2 confirmed
S.S+ NH4OH
solution+ acetic acid
Yellow ppt
Co+2 confirmed
solution + crystals of
potassium nitrite.
warm.
Ni+2 confirmed
EXPERIMENT
S.S+ acetic acid+
potassium chromate
solution.
Yellow ppt.
INFERENCE
Ba+2 present.
22
.
Salt + Conc.HCl
.make a paste with
glass rod and then
introduced it into the
flame.
S.S + ammonium
Sulphate solution.
white ppt
Ba+2 confirmed.
Sr+2 present
24
.
Salt + Conc.HCl
.make a paste with
glass rod and then
introduced it into the
flame
S.S+ NH4OH
solution+ ammonium
oxalate solution.
Sr+2 confirmed
White ppt
Ca+2 present
Salt + Conc.HCl
.make a paste with
Ca+2 confirmed
S.S + NH4Cl(s)+
NH4OH (Ex)
+ammonium
phosphate (scratch
the inner side of the
test tube with a glass
rod)
Result:
-2
SCO3