Professional Documents
Culture Documents
and
CombustionTechnology
CompletedModules
1 PropertiesofFuels
2 PetroleumScience
3 RefineryProcesses
4 MajorRefineryProducts
5 SolidFuels WoodAndPeat
6 SolidFuels Coal
7 NuclearEnergy NuclearFissionAndNuclearFusion
8
NuclearEnergy NuclearReactors
Lubrication Types,Functions,Tribology
9 Lubrication Regimes,Additives,Properties,ProductionProcess
LetsRevise
1 PropertiesofFuels
2 PetroleumScience
3 RefineryProcesses
4 MajorRefineryProducts
5
SolidFuels WoodAnd
Peat
6 SolidFuels Coal
7
FlashPoint,Vapor Pressure,Octane#,
Cetane #,Density
HowtoClassifyCrude Oils?
HowCrude Oil&NaturalGasisFormed?
Whatisdone inaRefinery?
HowaRefineryisconfigured?
What arethey?
Where&howtheyareemployed?
WhatisCoalGasification &Liquefaction?
ClassesofCoal?
8 NuclearEnergy Plants
How areNuclearPlantsconfigured?
9 Lubrication
Function/sofLubs andtheirTypes?
HowaretheyProduced?
nC+(n+1)H2 CnH2n+2
CoalGasification
BindingEnergyCurve
CanYouFind?
Howmuchenergywouldbereleasedif1gramofU235 weretoundergofission?
FunctionsofaLubricant
Cooling
Lub oilcirculatingthroughtheenginewillcarryawayexcess
heat
Sealing
Lub oilprovidesanairtightbarrierbetweenthepistonrings
andcylinderwall.Maintainingthissealwillreduceenginewear
andincreasepoweroutput.
Lubrication
Flushing
Maintainingafilmofoilbetweenmovingpartswill:
Reducewearonparts
Reduceheatgenerationduetofriction
Circulatingengineoilwillremoveanycontaminants(Fuel
deposits,Metalfilings)fromtheengineblock.
OtherInformation
Regimes
Additives
Characterization
Hydrodynamic
PourPointDepressants
CarbonResidue
Boundary
ViscosityIndexImprovers
Viscosity
Mixed
Defoamants
Density &Gravity
OxidationInhibitors
FlashandFirePoints
RustandCorrosionInhibitors
NeutralizationNumber
DetergentsandDispersants
TotalAcid/BaseNos.
AntiwearAdditives
PourPoint
ExtremePressureAdditives
Color
ViscosityIndex
Important!
However,thequalityortheperformancefeaturesofa
lubricantcannotbeadequatelydescribedonthebasis
ofphysicalandchemicaltestsalone.
Thus,majorpurchasersoflubricatingoils,suchasthe
military,equipmentbuilders,andmanycommercial
consumers,includeperformancetests aswellas
physicalandchemicaltestsintheirpurchase
specifications.
E.g.OxidationTests,ThermalStability,RustProtection
Tests,FoamTests,EPandAntiwearTests,Emulsion
andDemulsibility Tests
TypesofLubricants
Physical
Applicationwise
Liquid Mineraloilorsyntheticoils
Engineoils
Solid Graphite,MoS2
GearOils
Semisolid Greases
TurbineOils
Gases Atomized2strokeoils
HydraulicOils
Metalworkingoils Cuttingoils,
FormingOils
Rustpreventives
LubeProcessingScheme
TypicalLubricantApplications
10
ChemicalFormulae
Compositions
CalorificValues
Prof.
SASP
11
CombustionEquations
CombustionCharacteristicsofFuels
Prof.
SASP
12
SelectionandApplicationofFuelBasedonEconomics&
Quality
TAD
13
CombustionCharacteristicsandotherConsiderations
EnvironmentalPollution
AlternativeOptionsforpetroleumfuels
TAD
14
CalculationofEnergyProductionbycombustionoffuels
DesignofBurnersandFurnaces
TAD
SelectionandApplicationofFuel
BasedonEconomics&Quality
Case1a:
Youhaveafixedamountofcapitaltobuyamotorcar.
Assumingthatyouhaveafixedincomeatthemoment
whatconsiderationsyouwouldgiveinbuying?
Case1b:
Suddenlyyoureceiveagoodjobopportunity,which
involvesconsiderableamountoftravelling,wherethey
provideyouwithavehicleofyourchoiceandyouhaveto
manageonlyfuelonyourown.Nowwhatwillbeyour
concerns?
SelectionandApplicationofFuel
BasedonEconomics&Quality
Case2:
Assumethatyouareintheplanningstageof
Utilitiesforalargeindustrialcomplexclosetoa
residentialarea.
Whatareyourconsiderationsinselectingpower
plantforthefacility?
SelectionandApplicationofFuel
BasedonEconomics&Quality
Case3:
Aprocessplantuseshighpressuresteamtodriveitsturbinesand
mediumpressuresteamforprocessheating.Lowpressuresteamis
alsoemployedinstrippingcolumns.
AllsteamrequirementsarefulfilledviaSuperheatedHPSteamBoilers.
Mediumpressuresteamtakenfromsteamturbinewhilelowpressure
steamistakenbythrottlingMPsteam.
Powerisproducedviasteamturbines,DieselGeneratorwhichuses
lowSulphurdieselandalsofromNationalgrid.
Howtowedeterminethebestmixofheatandpowersources?
SelectionandApplicationofFuel
BasedonEconomics&Quality
Inalmosteverycase,thecostswhichoccur
overthelifeofacapitalinvestmentcanbe
classifiedintooneofthefollowingcategories:
InitialCost,
AnnualExpensesandRevenues,
PeriodicReplacementandMaintenance,or
SalvageValue
Thefuelcostwillbeapartofregularexpense
SelectionandApplicationofFuel
BasedonEconomics&Quality
TheamountofPowerGeneratedbydifferentfuelsarealmost
sameperunitmassinmanycases.
Buttheapparentcostofafuelwillbeasumofmanycost
componentsimposedbygovernmentsdependingontheir
fiscalpolicies.
Themaintenancecostswitheachtypeofengines,technology,
availabilityofspares,availabilityofvenderserviceswillthen
determinethecomparingparametersofoptions.
Cashflowdiagramsisagoodtoolinanalyzingselectionoffuel
/technology
DieselVs Gasoline
Categoriesofcostsforpower
generatingtechnologies
Exhibit 1
CIFPrice
LandedCost
TaxedCost
WholesaleCost
RetailCost
RetailPricebeforeVAT
RetailPriceAfterVAT
MaximumConsumer
Price
FOBPrice
CompetitorDiscount/Premium
Freight
Insurance
LossesDuringFreight
Jetty/PipelinePrices
PortDevelopmentTaxes
BankCharges
LCCharges
CustomsDuty
ExciseDuty
SocialResponsibilityLevy
CostofWorkingCapital
StorageTerminalCharges
ProfitMargin
Marketing&DistributionCosts
ProvincialCouncilTaxonImportedFuel
ProvincialCouncilTurnoverTax
VAT
DealerDiscount
CIFprice
Portcharges
Taxes
DistributionCharges
ImporterCosts
ImporterMargin
Dealermargin
Exhibit 1
FuelBasedCharacteristicPerformance
ParametersofanEngine
Air/fuelratios(MassBasis)
ThenormaloperatingrangeforaconventionalSIengine
usinggasolinefuelis12 A/F18whileforCIengines
withdieselfuel,itis18 A/F70
VolumetricEfficiency
Volumetricefficiencyisonlyusedwithfourstrokecycle
engineswhichhaveadistinctinductionprocess.
Itisdefinedasthevolumeflowrateofairintotheintake
systemdividedbytherateatwhichvolumeisdisplacedby
thepiston:
SpecificFuelConsumption
Fuelflowrateperunitpoweroutput
ImportantFeaturesofInternal
CombustionEngines
Vc ClearanceVolume
Vd Displacedvolume
Vt=Vc+ Vd
Tc Top(Dead)Center
Bc Bottom(Dead)Center
FuelInjectorinaDieselEngine
Q.
Ahydrocarbonfuelofcomposition84.1
percentbymassCand15.9percentbymassH
hasamolecularweightof114.15.
Determinethenumberofmolesofair
requiredforstoichiometriccombustionand
thenumberofmolesofproductsproduced
permoleoffuel.
CalculateA/Fratioandthemolecular
weightsofthereactantsandtheproducts.
C=12.011/H=1.008
Themolecularweightrelationgives
114.15=12.011a+1.008b
Thegravimetricanalysisofthefuelgives
.
.
.
.
Thusa=8b=18
C8H18 +12.5(02 +3.773N2)=8C02 +9H20+47.16N2
Inmoles:1+12.5(1+3.773)=8+9+47.16
InMass:
114.15+59.66x28.96=8x44.01+9x18.02+47.16x28.16
1:15.6
&
Sincethecompositionofthecombustionproductsis
significantlydifferentforfuelleanandfuelrich
mixtures,andbecausethestoichiometricfuel/air
ratiodependsonfuelcomposition,theratioofthe
actualfuel/airratiotothestoichiometricratio(orits
inverse)isamoreinformativeparameterfordefining
mixturecomposition: hence
fuel/airequivalenceratio=(A/F)Actual/(A/F)Stoichiometric=
Andtheinverseisknownas