Professional Documents
Culture Documents
Teachers Guide
CHAPTER 4: HEAT
4.1 : UNDERSTANDING THERMAL EQUILIBRIUM
By the end of this subtopic, you will be able to
Thermal equilibrium
:Keseimbangan terma
Hot
object
Equivalent to
Equivalent to
Cold
object
No net heat transfer
1. The net heat will flow from A to B until the temperature of A is the ( same, zero as the
temperature of B. In this situation, the two bodies are said to have reached thermal
equilibrium.
2. When thermal equilibrium is reached, the net rate of heat flow between the two bodies is
(zero, equal)
3. There is no net flow of heat between two objects that are in thermal equilibrium. Two objects
in thermal equilibrium have the same temperature.
4. The liquid used in glass thermometer should
(a) Be easily seen
(b) Expand and contract rapidly over a wide range of temperature
(c) Not stick to the glass wall of the capillary tube
5. List the characteristic of mercury
(a) Opaque liquid
(b) Does not stick to the glass
(c) Expands uniformly when heated
(d) Freezing point -390C
(e) Boiling point 3570C
JPN Pahang
Teachers Guide
6. ( Heat, Temperature ) is a form of energy. It flows from a hot body to a cold body.
7. The SI unit for ( heat , temperature) is Joule, J.
8. ( Heat , Temperature ) is the degree of hotness of a body
9. The SI unit for (heat , temperature) is Kelvin, K.
10. Lower fixed point (l 0 )/ ice point
11. Upper fixed point( l
100)
Temperature, =
l0
l100
l
l - l
x 1000C
l100 - l0
Exercise 4.1
Section A: Choose the best answer
1. The figure shows two metal blocks.
Which the following statement is false?
JPN Pahang
Teachers Guide
JPN Pahang
Teachers Guide
3. The distance between 00C and 1000C is 28.0 cm. When the thermometer is put into a beaker
of water, the length of mercury column is 24.5cm above the lower fixed point. What is the
temperature of the water?
Temperature, = l l0 x 1000C
l100 l0
= 24.5 x 1000C
28
= 87.50C
4. The distance between 00C and 1000C is 25 cm. When the thermometer is put into a beaker of
water, the length of mercury column is 16cm above the lower fixed point. What is the
temperature of the water? What is the length of mercury column from the bulb at
temperatures i) 300C
Temperature, = l l0 x 1000C
l100 l0
= 16 x 1000C
25
= 64.00C
Temperature, = l l0 (1000C)
l100 l0
300C = x (1000C)
25
x = 7.5cm
JPN Pahang
Teachers Guide
.
(b) He chooses two fixed points of Celsius scale to calibrate his thermometer. State them.
(2m)
Lower fixed point = freezing point of water.
Upper
fixed point = boiling point of water
(c) If the measurement length of the liquid inside the straw at the temperature of the lower
fixed point and the upper fixed point are 5cm and 16 cm respectively, find the length of
the liquid at 82.50C.
82.5 = l - 5 (100)
16 - 5
l = 14.08 cm
(e) What kind of action should he take if he wants to increase the sensitivity of his
thermometer?
Use a copper can instead of the aluminum can because it is a better thermal
conductor
5
JPN Pahang
Teachers Guide
Temperature
is a measure of degree of hotness of a body.
4.2
Heat capacity
Muatan haba
Specific heat capacity
Muatan haba tentu
1. The heat capacity of a body is the amount of heat that must be supplied to the body to
increase its temperature by 10C.
2. The heat capacity of an object depends on the
Temperature of the body
(a) .
Mass of the body
(b) .
Type of material
(c)
3. The specific heat capacity of a substance is the amount of heat that must be supplied to
increase the temperature by 1 0C for a mass of 1 kg of the substance. Unit Jkg-1 0C-1
Specific heat capacity , c =
Q__
m
JPN Pahang
Teachers Guide
5. High specific heat capacity absorb a large amount of heat with only a small temperature
increase such as plastics.
6. Conversion of energy
Heater
Electrical energy
Electrical
energy
Potential energy
Kinetic energy
Power = P
Heat energy
Pt = mc
Heat energy
mgh= mc
Heat energy
mv2= mc
Power = P
Slower increase
in temperature
Two object of
equal mass
Big value of c
Equal rate of
heat supplied
JPN Pahang
Teachers Guide
and the cool air from the sea flows towards the
land.
atmosphere.
2. The sea water has a higher c, and release more
heat.
3.
The air above the sea water to be hotter and
flows up and the cool air from the land flows
JPN Pahang
Teachers Guide
Exercise 4.2
SECTION A : Choose the best answer
1. The change in the temperature of an
object does not depend on
A. the mass of the object
B. the type of substance the object is
made of
C. the shape of the object
D. the quantity of heat received
JPN Pahang
Teachers Guide
= 36 160 J
2. Calculate the amount of heat required to raise the temperature of 0.8 kg of copper from 350C
to 600C. (Specific heat capacity of copper = 400 J kg-1 C-1).
Amount of heat required, Q = mc
= 0.8 x 400 x (60-35)
= 8 000J
3. Calculate the amount of heat required to raise the temperature of 2.5 kg of water from 32 0C
to 820C. (Specific heat capacity of water = 4200 J kg-1 C-1).
Amount of heat required, Q = mc
= 2.5 x 4200 x (82-32)
= 525, 000J
4. 750g block of a aluminium at 1200C is cooled until 450C. Find the amount of heat is
released. . (Specific heat capacity of aluminium = 900 J kg-1 C-1).
Amount of heat released, Q = mc
= 0.75 x 900 x (120-45)
= 50 625J
5. 0.2 kg of water at 700C is mixed with 0.6 kg of water at 300C. Assuming that no heat is lost,
find the final temperature of the mixture. (Specific heat capacity of water = 4200 J kg-1 C-1)
Amount of heat released, Q = Amount of heat required, Q
mc = mc
0.2 x 4200 x ( 70- ) = 0.6 x 4200 x ( - 30)
= 400C
SECTION C: Structured questions
10
JPN Pahang
Teachers Guide
1. In figure below, block A of mass 5kg at temperature 1000C is in contact with another block B
of mass 2.25kg at temperature 200C.
5kg
2.25kg
A
B
1000C
200C
11
JPN Pahang
Teachers Guide
4.3
State that transfer of heat during a change of phase does not cause a change in temperature
Determine the specific latent heat of fusion and specific latent heat of vaporisation
Solid
Condensation
Latent heat released
Solidification
Latent heat released
evaporation
Latent heat absorbed
Liquid
2. The heat absorbed or the heat released at constant temperature during a change of
phase is known as latent heat. Q= ml
3. Complete the diagrams below and summarized.
(a) Melting
12
JPN Pahang
Teachers Guide
change
even though heat is still being
absorbed.
substance.
3. The
heat absorbed is used for breaking up
increasing
the kinetic energy of the
molecules.
Temperature
Solid
liquid
P
Q
melting
[solid+liquid]
Time
(b) Boiling/evaporation
Temperature
Liquid
gas
R
S
boiling
[liquid+ gas]
Time
(c) Solidification
Temperature
Liquid
solid
R
S
solidification
[liquid+solid]
1. From
R to S the temperature does not
absorbed.
2. The
temperature is the boiling point of the
substance.
3. The
heat absorbed is used for breaking up
the bonds
of molecules. Its not used to
molecules.
4. At the
point R the liquid begins to boil and
.
all the liquid has boiled at point S.
released.
2. The temperature as same as the melting
(d) Condensation
Temperature
gas
R
liquid
S
condensation
[liquid+ gas]
13
Time
1. From
released.
2. The
to form a liquid.
4. At the point R the gas begins to condense and
JPN Pahang
Teachers Guide
water
ice
heat lost
( solidification/freezing)
The specific latent heat of vaporisation is the quantity of heat needed to change 1kg of liquid
temperature
into gas or vapour of its boiling point without any change in .. The S.I
unit is Jkg-1.
Latent heat absorbed
( boiling)
gas
water
heat lost
14
( condensation)
JPN Pahang
Teachers Guide
makes ice a suitable substance for use as a coolant to maintain other substance at a
low temperature. Beverage can be cooled by adding in several cubes of ice. When the
ice melts a large amount of heat (latent heat) is absorbed and this lowers the
them in contact with ice. With its large latent heat, ice is able to absorb a large
quantity of heat from the foodstuff as its melts. Thus food can be kept at a low
15
JPN Pahang
Teachers Guide
vapour releases a quantity of latent heat and heat capacity. This heat flows to the
EXERCISE 4.3
Section A:
1. The graph in figure below shows how
the temperature of some wax changes as
it cools from liquid to solid. Which
16
JPN Pahang
Teachers Guide
A.
B.
C.
D.
PQ
QR
RS
ST
17
JPN Pahang
Teachers Guide
2. Specific latent heat of vaporization of water = 2.26 X 10 6 J kg-1300g of ice at 00C melts. How
much energy is required for this
Q = ml
= 0.3 x 336 000 kJ kg-1
= 99 000kJ
3. An immersion heater rated at 500 W is fitted into a large block of ice at 00C. How long does
it take to melt 1.5kg of ice?
Q = ml
Pt = 1.5 x 3.36 xx 105
500 x t
t
= 501 000
= 1008s
4. 300 g of water at 400C is mixed with x g of water at 800C. The final temperature of the
mixture is 700C. Find the value of x
18
JPN Pahang
Teachers Guide
(0.3)(4200)(700-400) = x(4200)(800-700)
x = 0.9 kg
= 900 g
5. Calculate the amount of heat released when 2 kg of ice at 00C is changed into water at 00C.
Q = mLf
= (2)(336 000) = 672 000 J
6. Calculate the amount of heat needed to convert 3 kg of ice at 00C to water at 300C.
Q = mLf + mc
= (3) (336 000) + (3) (4200) (300)
= 1 386 000 J
7. Find the amount of heat needed to convert 0.5 kg of ice at -150C into steam at 1000C
Q = (mc)ice + (mLf)ice + (mc)water + (mLv)steam
= (0.5)(2100)(15) + (0.5)(336 000) + (0.5)(4200)(100) + (0.5)(2260 000)
= 1 523 750 J
8. Calculate the amount of heat needed to convert 100 g of ice at 00C into steam at 1000C.
Q = ( mLf)ice + (mc)water + (mLv)steam
= (0.1)(336 000) + (0.1)(4200)(1000) + (0.1)(2260 000)
= 301 600 J
9. The specific latent heat of vaporization of water is 2300 kJ kg -1. How much heat will be
absorbed when 3.2 kg of water is boiled off at its boiling point.
Q = mLv
= (3.2)(2 300 000)
= 7 360 000 J
4.4
JPN Pahang
Teachers Guide
Explain gas pressure, temperature and volume in terms of the behavior of gas molecules.
(ii)
(iii)
Solve problems involving pressure, temperature and volume of a fixed mass of gas
Temperature,T
K (Kelvin)
Pressure,P
Explanation
The molecules move freely in random motion and fill up the
Pa(Pascal)
temperature.
The molecules are in continuous random motion.
Boyles Law
P1
V
That is PV = constant
Or P V = P V
1
20
Relationship between pressure and volume
Small volume
molecules hit wall
more often, greater
pressure
JPN Pahang
Teachers Guide
1. Boyles law states that for a fixed mass of gas, the pressure of the gas is inversely
proportional to its volume when the temperature is kept constant.
2. Boyles law can be shown graphically as in Figure above
P
1/V
3. The volume of an air bubble at the base of a sea of 50 m deep is 250cm 3. If the atmospheric
pressure is 10m of water, find the volume of the air bubble when it reaches the surface of the
sea.
P2= 10m
PI=50m + 10m
4.4.2
P1V1 = P2V2
60m (250 x 10-6)m3 = 10m x V2
1.5 x 10-3 m3
= V2
Charless LawV1=250cm3
VT
that is V = constant
T
Relationship between
21
volume and temperature
Lower temperature
Higher temperature,
faster molecules,
larger volume to keep
the pressure constant
JPN Pahang
Teachers Guide
1. Charles law states that for a fixed mass of gas, the volume of the gas is directly proportional
to its absolute temperature when its pressure is kept constant.
2. The temperature -2730C is the lowest possible temperature and is known as the absolute zero
of temperature.
3. Fill the table below.
Temperature
Absolute zero
Ice point
Steam point
Unknown point
P/Pa
-273
4.4.3
Kelvin Scale(K)
0
273
373
( + 273 )
100
/0C
Pressures Law
PT
That is P = constant
T
22
Higher temperature
molecules move
faster, greater
pressure
JPN Pahang
Teachers Guide
1. The pressure law states that for a fixed mass of gas, the pressure of the gas is directly
proportional to its absolute temperature when its volume is kept constant.
EXERSICE 4.4Gas Law
1. A mixture of air and petrol vapour is injected into the cylinder of a car engine when the
cylinder volume is 100 cm3. Its pressure is then 1.0 atm. The valve closes and the mixture is
compressed to 20 cm3. Find the pressure now.
P1V1 = P2V2
(1.0)(100) = P2(20)
P2 = 5.0 atm
2. The volume of an air bubble at the base of a sea of 50 m in deep is 200 cm 3. If the
atmospheric pressure is 10 m of water, find the volume of the air bubble when it reaches the
surface of the sea.
P1V1 = P2V2
(50 +10)(200) = (10)V2
V2 = 1200 cm3
3. The volume of an air bubble is 5 mm3 when it is at a depth of h m below the water surface.
Given that its volume is 15 mm3 when it is at a depth of 2 m, find the value of h.
(Atmospheric pressure = 10 m of water)
P1V1 = P2V2
(h + 10)(5) = (2 + 10)(15)
5h + 50 = 180
h = 26 m
23
JPN Pahang
Teachers Guide
4. An air bubble has a volume of V cm3 when it is released at a depth of 45m from the water
surface. Find its volume (V) when it reaches the water surface. (Atmospheric pressure = 10
m of water)
P1V1 = P2V2
(45 + 10)(V) = (10)(V2)
V2 = 5.5 V cm3
5. A gas of volume 20m3 at 370C is heated until its temperature becomes 870C at constant
pressure. What is the increase in volume?
V1 = V2
T1
20
370 + 273
T2
V2
870 + 273
V2 = 23.23 m3
6. The air pressure in a container at 330C is 1.4 X 1O5 N m-2. The container is heated until the
temperature is 550C. What is the final air pressure if the volume of the container is fixed?
P1 = P2
T1
1.4 x 105
330 + 273
T2
P2
550 + 273
T2
150 + 273
3
T2
T2 =864K
T2 =2 + 273
24
JPN Pahang
Teachers Guide
2 = T2 273
= 864 - 273
2 = 591 0C
8. An enclosed container contains a fixed mass of gas at 250C and at the atmospheric pressure.
The container is heated and temperature of the gas increases to 980C. Find the new pressure
of the gas if the volume of the container is
rn2)
P1 = P2
T1
1.0 x 105
250 + 273
T2
P2
980 + 273
P2 = 1.24 x 105 N m2
9. The pressure of a gas decreases from 1.2 x 105 Pa to 9 x 105 Pa at 400C. If the volume of the
gas is constant, find the initial temperature of the gas.
P1 = P2
T1
T2
1.2 x 105
9 x 105
1 + 273
400 + 273
1 = -231.3 0C
= 41.7K
PART A: CHAPTER 4
1. A 5kg iron sphere of temperature 500C is
put in contact with a 1kg copper sphere
of temperature 273K and they are put
inside an insulated box. Which of the
25
JPN Pahang
Teachers Guide
26
JPN Pahang
Teachers Guide
PART B;
1. A research student wishes to carry out an investigation on the temperature change of the
substance in the temperature range -500C to 500C. The instrument used to measure the
temperature is a liquid in glass thermometer.
27
JPN Pahang
Teachers Guide
Thermometer
Liquid
Freezing point of liquid (0C)
Boiling point of liquid (0C)
Diameter of capillary tube
Cross section
A
Mercury
-39
360
Large
B
Mercury
-39
360
Small
C
Alcohol
-112
360
Large
D
Alcohol
-112
360
Small
Table 1
(a) (i) State the principle used in a liquid- in glass thermometer.(1m)
Principle of thermal equilibrium
........................................................................................................................................
(ii)
(b) Table 1 shows the characteristic of 4 types of thermometer: A,B C and D. On the basis
of the information given in Table 1, explain the characteristics of, and suggest a suitable
thermometer for the experiment.(5 m)
Alkohol freezing point is less than -50C, boiling point higher than 50C.Thus the
Capillary tube has small diameter will produce a large change in the length thus
28
JPN Pahang
Teachers Guide
..
(c) The length of the mercury column in uncalibrated thermometer is 6.0cm and 18.5 cm at
00C and 1000C. respectively. When the thermometer is placed in a liquid, the length of
the mercury column is 14.0cm
(i)
(ii)
State two thermometric properties which can be used to calibrate a thermometer. (6m)
2. A metal block P of mass 500 g is heated is boiling water at a temperature of 1000C. Block P
is then transferred into the water at a temperature of 300C in a polystyrene cup. The mass of
water in the polystyrene cup is 250 g. After 2 minutes, the water temperature rises to 420C.
Figure 2
Assuming that the heat absorbed by the polystyrene cup and heat loss to the
surroundings are negligible.{Specific heat capacity of water 4 200 j kg-1 C-1)
Calculate
(a) the quantity of heat gained by water the polystyrene cup
Q = mc
= 0.250 x 4200 x (42-30)
= 12 600J
29
JPN Pahang
Teachers Guide
= 12 600J
c
Figure 3.1
Figure 3.2
(a) State the energy change each time the tube is inverted.
Gravitational potential energy kinetic energy heat energy
..
..
(b) What is the average distance taken by the lead shot each time the tube is inverted?
45.0 cm
30
JPN Pahang
Teachers Guide
(c) Calculate the time taken by the lead shot to fall from the top to the bottom of the tube.
S = ut + at2
0.45 = 0 + (10)t2
t = 0.3s
(d) After inverting the tube 100 times, the temperature of the lead shot is found to have
increased by 30C.
i.
ii.
225
(0.500 x 3)
= 150 Jkg-1 C-1
iii.
...
No heat loss to the surroundings/All the gravitational potential energy is converted
Figure (a)
Figure (b)
31
JPN Pahang
Teachers Guide
[1 mark]
round-bottomed flask and any other apparatus that may he necessary. In your description,
state clearly the following:
i.
ii.
iii.
iv.
v.
vi.
vii. The way you would analyse the data. [10 marks]
32
JPN Pahang
Teachers Guide
Inference
Hypothesis
Aim
increases
To investigate the relationship between the air pressure and the
Variable
Arrangement of
apparatus
Procedure
33
JPN Pahang
Teachers Guide
Analysis of Data
34