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POLYMER
TESTING
Polymer Testing 26 (2007) 927936
www.elsevier.com/locate/polytest
Test Method
Institute of Materials Science and Technology, Vienna University of Technology, FavoritenstraX e 9-11, A-1040 Vienna, Austria
b
Borealis GmbH, PO R&D, St.-Peter-StraX e, A-4021 Linz, Austria
Received 29 April 2007; accepted 15 June 2007
Abstract
A study on scratch deformation behavior of multiphase PP/EPR/PE materials with different polymer composition was
made by combining microscopic and macroscopic examination. The addition of PE to the PP/EPR blend leads to an
improvement of scratch resistance. No strong correlation was found between micro- and macro-scratch experiments on the
injection molded specimens, but when PE was added a reduction of the remaining deformation after scratching was found
at both scales. The visibility of the scratches, which should be the most important parameter in daily use, is affected by the
depth, the pile-up and the roughness of the scratch; the surface hardness does not play a role for the investigated polymers.
r 2007 Elsevier Ltd. All rights reserved.
Keywords: Polypropylene; Polyethylene; Ethylene/propylene copolymer; Blend; Scratch resistance; Micro-hardness
1. Introduction
Thermoplastic polyolens such as polypropylene
are being increasingly used as structural materials
due to the good strengthtoughness combination,
low cost and ease of fabrication. Low gloss,
aesthetical appeal and low susceptibility to mechanical damage (e.g., good scratch resistance (SR)) are
getting more and more relevant, especially in the
automotive industry.
The scratching phenomenon on the polymer
surface tends to be one of the key issues in this
respect. This topic has been the subject of numerous
research efforts in the past few years, both by
research institutions and manufacturing industries.
The different papers have established a series of
correlations between certain scratch parameters and
Corresponding author.
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Table 1
Used TPOs
Polymer blend
1
2
3
4
PP/EPR
PP/EPR/LDPE
PP/EPR/LLDPE
PP/EPR/HDPE
MFR (1901/
2.16 kg) (g/10 min)
Flex. Mod.
(MPa)
6.9
6.1
6.1
6.2
1088
972
965
1069
6.6
8.8
11.3
9.2
2
3.4
3
3.1
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Fig. 3. TEM micrographs in magnications of 26,000 and 52,000 (the black bar in the pictures represent on the upper pictures 500 nm and
underneath 200 nm) of PP/EPR/PE blends: (a) blend 1, (b) blend 2, (c) blend 3 and (d) blend 4.
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Fig. 4. (a) Skin layer (030 mm) and (b) subsurface layer
(100130 mm) of the polymer blend 1.
4F
.
pd 21
(1)
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Table 2
Parameters evaluated for the different PP/EPR/PE blends
Material
Blend
Blend
Blend
Blend
1
2
3
4
Macro-scratching
Micro-scratching
Visibility, DL
h1 (mm)
h2 (mm)
d (mm)
h1 (mm)
h2 (mm)
d (mm)
35
26
29
26
19
14
16
13
411
434
425
422
0.996
0.969
0.656
0.564
0.386
0.190
0.027
0.042
20
18
17
21
1.7
0.9
0.8
0.7
Fig. 5. Characteristic parameters of the scratches induced by macro-scratch experiments; load 10 mN, velocity 10 mm/s.
Typical AFM pictures of the remaining microscratches are shown in Fig. 7. Whereas the blends
1 and 2 show strong pile-up at the edges of the
scratch there was nearly no pile-up observed for
the blends 3 and 4. The strong difference between
the materials containing low-density polyethylene,
blends 2 and 3, are a little bit surprising because
their behavior was comparable in the macro-scratch
experiments. This could be due to a difference of
the morphology in the very outermost layer of these
specimens.
From the cross proles of the micro-scratches
(Fig. 8) a recovery parameter can be calculated in
h1;L h1;U
100%,
h1;L
(2)
where h1,L is the indentation depth during scratching and h1,U is the indentation depth after unloading.
The surfaces of the blends 1 and 2 show recovery
values of 78%, while for the blends 3 and 4 this
value reaches 83%. The difference in the recovery
behavior is relatively small, so we think that in these
materials the inuence of the recovery behavior on
the scratch geometry is not the dominating factor.
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Fig. 6. Scratch deformation by the macro-scratch experiments: blend 1 (a), blend 2 (b), blend 3 (c) and blend 4 (d).
Fig. 7. AFM pictures of the scratches in polymer blend 1 (a), polymer blend 2 (b), polymer blend 3 (c) and polymer blend 4 (d).
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Table 3
Ball indentation, Shore, micro- and scratch hardness of the studied blends
Material
Blend
Blend
Blend
Blend
1
2
3
4
BIH (MPa)
38
31
32
36
Shore D
59
57
58
59
Micro-hardness
HIT (MPa)
EIT (MPa)
H/E
49
41
40
43
904
647
654
755
0.054
0.063
0.061
0.057
Hs (MPa)
DL
75.4
67.6
70.5
71.5
1.73
0.93
0.83
0.73
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Fig. 9. Cross-sectional indentation hardness vs. distance to the surface for the different polymers.
60 60 2 mm3 specimen. The study of KargerKoscsis and Csikai [16] showed a few years ago
differences in the skin-core distribution of EPR
particles in injection molded specimens. We wanted
to check if we can also nd differences in the
distribution of micro-hardness over cross-section
between the studied blends. This would help further
to conclude on relevant issues about subsurface
hardness.
Fig. 9 presents the cross-sectional hardness values
of the materials. The black spots represent the
material hardness in the ow direction and the white
spots reect the across ow data. The rst position
is at a distance of 30 mm from the surface; this
relatively large distance is needed to meet the
requirements on a non-edge-inuenced indentation
and we could not reduce the indentation size for the
reasons given earlier. In the near-surface regions (up
to a distance of 60 mm) the behavior of polymers 2,
3, and 4 is comparable. The hardness values of
blend 1 are higher. In the middle region of the plates
(0.5 and 1 mm from the surface) the micro-hardness
values show the same relations between the materials as the ball indentation hardness values, irrespec-
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