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3.1b Chemical word equations
==> means the direction of change from reactants == to ==> products
No symbols or numbers are used in word equations.
Always try to fit all the words neatly lined up from left to right, especially i
f its a long word equation.
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3.1c Balancing Symbol equations
Writing the correct symbol or formula for each equation component.
Numbers in a formula are written as subscripts after the number of atoms of
the element concerned
e.g. H2SO4 means 2 H's, 1 S and 4 O's
or the subscript number can double, treble etc. a part of the formula
e.g. Ca(OH)2 means 1 Ca and 2 OH's (or 2 O's and 2 H's in total)
Numbers before a formula double or treble it etc.
e.g. 2NaCl means 2 Na's and 2 Cl's in total
or 2H2SO4 means 2 x H2SO4 = 4 H's, 2 S's and 8 O's in total of 2 H2's and 2
SO4's
Its quite handy to think in different ways to balance an equation, but ultim
ately, and the most logically, its all about counting atoms correctly and making
sure you have the same number of atoms of each element on each side of the equa
tions BUT this only works if all the chemical formulae are correct in the equati
on!
If the number is 1 itself, by convention, no number is shown in a formula or
before a formula.
Using numbers if necessary to balance the equation, this is a matter of 'trial a
nd error'.
If you seem deficient on one side of the equation in terms of a particular a
tom (element), you may need to increase a balancing number on the other side of
the equation.
Also, you must use the smallest possible whole numbers (integers) to balance
an equation, its best to avoid half-numbers if you can. dealing in half-molecul
es may seem a bit strange!
If all is correct, then the sum of atoms for each element should be the same on
both side of the equation arrow .....
in other words: atoms of products = atoms of reactants
This is a chemical conservation law of atoms and later it may be describ
ed as the 'law of conservation of mass'.
the 7 equations are first presented in 'picture' style and then written
out fully with state symbols
The individual formulas involved and the word equations will be been pre
sented in the examples below.
NEVER alter a formula to balance an equation! BUT use the CORRECT FORMULA and on
ly put NUMBERS BEFORE THE FORMULA if needed to balance the number of atoms to ba
lance the equation.
PRACTICE QUESTIONS - on words and symbol equations (on other web pages)
Multiple choice quiz on balancing numbers
Balancing number/formula-fill exercises
Reactions of acids with metals, oxides, hydroxides, carbonates and ammonia.
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3.1d EXAMPLES of CONSTRUCTING WORD or SYMBOL EQUATIONS
Remember from the 'Law of Conservation of Mass' the mass of products = mass of o
riginal reactants, which means that the number of atoms of each element in the r
eactants must be equal to those in the products and that is the basis of writing
a correctly balanced symbol equation, BUT don't forget, you must write the corr
ect formula for each species in the equation, otherwise you may write a correctl
y balanced equation which is totally wrong! so beware!
Balancing equations example 3.1d(1)
A single symbol means an uncombined single atom of the element,(c) doc b or Fe 1
atom of iron,(c) doc b or S 1 atom of sulphur (2Fe would mean two atoms, 5S wou
ld mean five sulphur atoms etc.)
(c) doc b or the formula FeS means one atom of iron is chemically combined with
1 atom of sulphur to form the compound called iron sulphide
iron + sulphur ==> iron sulphide
(c) doc b
on average one atom of iron chemically combines with one atom of iron forming on
e molecule of iron sulphide
two elements chemically combining to form a new compound
Fe + S ==> FeS
Fe(s) + S(s) ==> FeS(s)
Atom balancing, sum left = sum right: 1Fe + 1S = (1Fe combined with 1S)
There is no need for any balancing numbers in this equation
For a balanced equation on both sides of the equation you should have 1 iron ato
m and 1 sulfur atom combined in their particular way in the reactants or product
s
All the reactants (what you start with) and all the products (what is formed) ar
e all solids in this case.
When first learning symbol equations you probably won't use state symbols like (
s) at first (see end note).
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Balancing equations example 3.1d(2)
(c) doc b or the formula NaOH means 1 atom of sodium is combined with 1 atom of
oxygen and 1 atom of hydrogen to form the compound called sodium hydroxide
(c) doc b or the formula HCl means 1 atom of hydrogen is combined with 1 atom of
chlorine to form 1 molecule of the compound called hydrochloric acid
(c) doc b or the formula NaCl means 1 atom of sodium are combined with 1 atom ch
lorine to form the compound called sodium chloride
(c) doc b or the formula H2O means 2 atoms of hydrogen are chemically combined w
ith 1 atom of oxygen to form the compound called water.
sodium hydroxide + hydrochloric acid ==> sodium chloride + water
(c) doc b
the reactants are one molecule of sodium hydroxide and one molecule of hydrochlo
ric acid
the products are one molecule of sodium chloride and one molecule of water
all chemicals involved are compounds
NaOH + HCl ==> NaCl + H2O
atom balancing, sum left = right: (1Na + 1O + 1H) + (1H + 1Cl) = (1Na + 1Cl) + (
2H + 1O)
For a balanced equation on both sides of the equation you should have 1 sodium a
tom, 1 oxygen atom, 1 chlorine atom and 2 hydrogen atoms combined in their parti
cular way in the reactants or products.
There is no need for any balancing numbers in this equation
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Balancing equations example 3.1d(3)
(c) doc b or the symbol Mg means 1 atom of the element called magnesium
(c) doc b(c) doc b(c) doc b or 2HCl means two separate molecules of the compound
called hydrochloric acid (see example 2)
(c) doc b or the formula MgCl2 means 1 formula of the compound called magnesium
chloride, made of one atom of magnesium and two atoms of chlorine.
(c) doc b or the formula H2 means 1 molecule of the element called hydrogen made
up of two joined hydrogen atoms
magnesium + hydrochloric acid ==> magnesium chloride + hydrogen
(c) doc b
one atom of magnesium reacts with two molecules of hydrochloric acid
the products are one molecule of magnesium chloride and one molecule of hydrogen
Mg and H-H are elements, H-Cl and Cl-Mg-Cl are compounds
Mg + 2HCl ==> MgCl2 + H2
Mg(s) + 2HCl(aq) ==> MgCl2(aq) + H2(g)
atom balancing, sum left = right: (1Mg) + 2 x (1H + 1Cl) = (1Mg + 2Cl) + (2H)
For a balanced equation on both sides of the equation you
m atom, 2 hydrogen atoms and 2 chlorine atoms combined in
n the reactants or products. You can only get the balance
front of the HCl formula because you need 2 Cl's to make
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Balancing equations example 3.1d(4)
(c) doc b or the formula CuCO3 means one formula of the compound called copper c
arbonate, made up of one atom of copper is combined with one atom of carbon and
three atoms of oxygen to form the compound copper carbonate
(c) doc b or the formula H2SO4 means one formula of the compound called sulphuri
c acid, which is made up of two atoms of hydrogen, one atom of sulphur and four
atoms of oxygen
(c) doc b or the formula CuSO4 means one formula of the compound called copper s
ulphate which is made up of one atom of copper, one atom of sulphur and four ato
ms of oxygen
H2O (example 2)
(c) doc b or the formula CO2 means one molecule of the compound called carbon di
oxide which is a chemical combination of one atom of carbon and two atoms of oxy
gen.
copper carbonate + sulphuric acid ==> copper sulphate + water + carbon dioxi
de
(c) doc b
the reactants are one formula of copper carbonate and one molecule of sulphuric
acid
the products are one formula of copper sulphate, one molecule of water and one m
olecule of carbon dioxide
all molecules are compounds in this reaction
CuCO3 + H2SO4 ==> CuSO4 + H2O + CO2
CuCO3(s) + H2SO4(aq) ==> CuSO4(aq) + H2O(l) + CO2(g) (with state symbols)
balancing sum left = sum right: (1Cu + 1C + 3O) + (2H + 1S + 4O) = (1Cu + 1S + 4
O) + (2H + 1O) + (1C + 2O)
For a balanced equation on both sides of the equation you should have 1 copper
atom, 1 carbon atom, 7 oxygen atoms, 2 hydrogen atoms, 1 sulphur atom combined i
n their particular way in the reactants or products
There is no need for any balancing numbers in this equation
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Balancing equations example 3.1d(5)
(c) doc b or the formula CH4 means one molecule of the compound called methane w
hich is made of one atom of carbon combined with four atoms of hydrogen
(c) doc b(c) doc b(c) doc b or 2O2 means two separate molecules of the element c
alled oxygen, and each oxygen molecule consists of two atoms of oxygen
CO2 (see also example 4)
(c) doc b(c) doc b(c) doc b or 2H2O means two separate molecules of the compound
called water (see also example 2)
methane + oxygen ==> carbon dioxide + water
(c) doc b
Using displayed formula the equation would look like this ...
... in which every individual atom is shown and how it is bonded ('connected') w
ith other atoms in the molecule. All the dashes represent the covalent bonds bet
ween the atoms in the molecules.
atom balancing, sum left = sum right: (1C + 4H) + 2 x (2O) = (1C + 2O) + 2 x (2H
+ 1O)
For a balanced equation on both sides of the equation you should have 1 carbon a
tom, 4 hydrogen atoms, 4 oxygen atoms combined in their particular way in the re
actants or products.
You can only get this to balance by having a 2 in front of the O2 and 2 in front
of the CO2, you need an O2 to make CO2 and another O2 to convert the H4 into 2H
2O
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Balancing equations example 3.1d(6)
(c) doc b or the formula Mg(OH)2 is the compound magnesium hydroxide made up of
one magnesium, two oxygen and two hydrogen atoms BUT the OH is a particular comb
ination called hydroxide within a compound, so it is best to think of this comp
ound as a combination of an Mg and two OH's, hence the use of the ( ). The subsc
ripted 2 doubles everything in the brackets.
(c) doc b(c) doc b(c) doc b or 2HNO3 means two separate molecules of the compoun
d nitric acid, each molecule is made up of one hydrogen atom, one nitrogen atom
and three oxygen atoms.
(c) doc b or the formula Mg(NO3)2 is the compound magnesium nitrate, it consists
of a magnesium (ion) and two 'nitrates' (ions), each nitrate consists of one ni
trogen and three oxygen atoms, again the nitrate is a particular combination of
atoms within a compound and hence the use of ( ) again.
(c) doc b(c) doc b(c) doc b or 2H2O meaning two molecules of the compound water
(see also examples 2 and 5)
magnesium hydroxide + nitric acid ==> magnesium nitrate + water
(c) doc b
one formula of magnesium hydroxide reacts with two molecules of nitric acid to f
orm one formula of magnesium nitrate and two molecules of water (all compounds)
Mg(OH)2 + 2HNO3 ==> Mg(NO3)2 + 2H2O
Mg(OH)2(aq) + 2HNO3(aq) ==> Mg(NO3)2(aq) + 2H2O(l) (with state symbols)
atom balancing, sum left = sum right: (1Mg + 2O + 2H) + 2 x (1H + 1N + 3O) = (1M
g + 2N + 6O) + 2 x (2H + 1O)
For a balanced equation on both sides of the equation you should have 1 magnesiu
m atom, 8 oxygen atoms, 4 hydrogen atoms, 2 nitrogen atoms combined in their par
ticular way in the reactants or products
to balance this equation you need a 2 in front of the HNO3 and a 2 in front of t
atom balancing, sum left = sum right: (2Al + 3O) + 3 x (2H + 1S + 4O) = (2Al + 3
S + 12O) + 3 x (2H + 1O)
For a balanced equation on both sides of the equation you should have 2 aluminiu
m atoms, 15 oxygen atoms, 6 hydrogen atoms, 3 sulfur atoms combined in their par
ticular way in the reactants or products
This is quite an awkward equation to balance, a bit of real trial and error, but
two 3s in the right place will do it.
The best clue here is that you need 3 x SO4 for the aluminium sulfate, so you ne
ed 3 of the H2SO4
GCSE-AS-A2-IB note: Aluminium sulfate is actually an ionic compound (Al3+)2(SO42
-)3
topExtra NOTE 1 Reversible Reactions
The (c) doc b sign means a reversible reaction, it can be made to go the 'other
way' if the conditions are changed. Example:
nitrogen + hydrogen (c) doc b ammonia
N2(g) + 3H2(g) (c) doc b 2NH3(g)
B
1 x 4 = 4 x 1 = CH4
1 x 3 = 3 x 1 = NCl3
1 x 4 = 2 x 2 = CO2
(c) doc b
The diagram on the left illustrates the three covalent examples above fo
r
methane CH4
nitrogen trichloride NCl3
carbon dioxide CO2
6 more examples of working out an ionic formula
numerically charge = valency of A or B to deduce the formula
valency or ionic charge = the combining power of the ion