Professional Documents
Culture Documents
Table of Contents 2
List of Tables & Charts 3
Study Overview 4
Sample Text, Table
& Chart 5
World Bioplastics
Industry Study with Forecasts for 2013 & 2018
Study #2548 | November 2009 | $5800 | 272 pages
www.freedoniagroup.com
Study #2548
November 2009
$5800
272 Pages
World Bioplastics
Industry Study with Forecasts for 2013 & 2018
Table of Contents
Executive Summary
Market EnvironmenT
General ....................................................... 4
World Economic Overview............................... 4
Recent Historical Trends............................. 5
World Economic Outlook............................. 7
World Population Outlook..............................11
World Manufacturing Outlook.........................12
World Agricultural Outlook.............................14
Maize.....................................................16
Sugar Crops.............................................18
World Plastics Overview.................................20
Plastics Demand.......................................21
Plastics Production...................................24
Pricing Trends..........................................25
World Converted Flexible Plastic
Packaging Outlook.....................................28
Regulatory & Environmental Considerations......31
Degradability Standards & Certification........31
Composting & Recycling............................34
Legislation..............................................36
Food Versus Industrial Crop Use..................37
WORLD BIOPLASTICS
OVERVIEW
General ......................................................39
Product Overview.........................................40
Biodegradable..........................................42
Starch-Based Resins..............................44
Polylactic Acid......................................47
Petroleum-Based Resins.........................50
PHAs...................................................53
Other..................................................56
Non-Biodegradable...................................58
Market Overview..........................................63
Packaging................................................65
Packaging Film.....................................67
Loose-Fill.............................................68
Containers & Other................................68
Nonpackaging..........................................69
Bags...................................................72
Foodservice Disposables.........................73
Automotive & Electronics.......................74
Agricultural Films..................................75
Other..................................................76
Regional Overview........................................77
Demand..................................................77
Production...............................................80
Trade Flows..............................................83
NORTH AMERICA
Company Profiles
General ......................................................85
Bioplastics Demand......................................86
United States..............................................89
Canada.......................................................96
Mexico..................................................... 101
Archer-Daniels-Midland............................... 227
Arkema SA................................................ 229
BASF SE.................................................... 231
BioMatera Incorporated.............................. 232
Braskem SA............................................... 233
Cardia Bioplastics....................................... 234
Cargill Incorporated................................... 236
Cereplast Incorporated................................ 239
Dow Chemical............................................ 241
DuPont (EI) de Nemours.............................. 242
Eastman Chemical...................................... 245
EBM Biodegradable Materials....................... 246
FKuR Kunststoff......................................... 246
Grace Biotech............................................ 247
Innovia Films............................................ 248
IRe Chemical............................................. 250
Merquinsa................................................. 251
Metabolix Incorporated............................... 252
Mitsubishi Chemical................................... 254
Ningbo Tianan Biologic Material................... 255
Novamont SpA........................................... 256
Perstorp AB............................................... 257
PHB Industrial........................................... 258
Plantic Technologies................................... 259
Rodenburg Biopolymers............................... 261
Showa Denko............................................. 262
Solvay SA................................................. 263
Sphere SA................................................. 265
Stanelco plc.............................................. 266
Synbra Holding.......................................... 267
Teijin Limited............................................ 268
Total SA................................................... 270
Zhejiang Hangzhou Xinfu Pharmaceutical....... 271
Zhejiang Hisun Biomaterials........................ 272
WESTERN EUROPE
General .................................................... 107
Bioplastics Demand.................................... 109
Germany................................................... 111
Italy........................................................ 116
United Kingdom......................................... 122
France...................................................... 127
Netherlands.............................................. 132
Other Western Europe................................. 137
Belgium................................................ 141
Norway................................................. 141
All Other............................................... 141
ASIA/PACIFIC
General .................................................... 144
Bioplastics Demand.................................... 146
Japan...................................................... 149
China....................................................... 156
South Korea.............................................. 162
Other Asia/Pacific...................................... 168
Taiwan.................................................. 173
Australia............................................... 173
All Other............................................... 174
OTHER REGIONS
Latin America: General................................ 177
Latin America: Bioplastics Demand............... 179
Brazil................................................... 181
Other Latin America................................ 187
Eastern Europe.......................................... 192
Africa/Mideast........................................... 198
List of Tables/Charts
INDUSTRY STRUCTURE
1 Summary Table....................................... 3
Executive Summary
Market EnvironmenT
1 World Gross Domestic Product by Region...10
2 World Population by Region....................12
3 World Manufacturing Value
Added by Region................................14
4 World Agricultural Value Added by Region 16
Cht World Maize Production by Region, 2008...18
Cht World Sugar Crop Production
by Region, 2008................................20
5 World Plastic Resin Demand by Region......23
(continued on next page)
Study #2548
November 2009
$5800
272 Pages
World Bioplastics
Industry Study with Forecasts for 2013 & 2018
List of Tables/Charts
(continued from previous page)
Cht World Plastic Resin Demand
by Region, 2008................................23
6 World Plastic Resin Production by Region.. 25
7 Plastic Resin Pricing..............................27
Cht Plastic Resin Pricing Trends, 1998-2018....28
8 World Converted Flexible Plastic
Packaging Demand by Region..............30
WORLD BIOPLASTICS
OVERVIEW
1 World Bioplastics Demand by Type...........41
2 World Biodegradable Plastics
Demand by Type................................43
Cht World Biodegradable Plastics
Demand by Type, 1998-2018................44
3 World Starch-Based Resin Demand
by Region & Market............................47
4 World Polylactic Acid Demand
by Region & Market............................50
5 World Petroleum-Based Bioplastic Demand
by Region & Market............................53
6 World PHA Resin Demand
by Region & Market............................55
7 World Other Biodegradable Plastic Resin
Demand by Region & Market................58
8 World Non-Biodegradable Bioplastics
Demand by Type, Region & Market........62
Cht World Non-Biodegradable Bioplastics
Demand by Type, 1998-2018................63
9 World Bioplastics Demand by Market........64
10 World Packaging Demand for Bioplastics
by Application & Region.....................66
Cht World Packaging Demand for Bioplastics
by Application, 2008..........................67
11 World Nonpackaging Demand for
Bioplastics by Application & Region......71
Cht World Nonpackaging Demand for
Bioplastics by Application, 2008..........72
12 World Bioplastics Demand by Region........79
Cht Bioplastics Demand by
Region, 1998-2018............................80
13 World Bioplastics Production by Region....82
Cht Bioplastics Production by
Region, 1998-2018............................83
14 World Bioplastics Net Exports by Region...84
NORTH AMERICA
1 North America -- Bioplastics
Supply & Demand...............................86
Cht North America Bioplastics
Demand by Country, 2008....................89
WESTERN EUROPE
1 Western Europe -- Bioplastics
Supply & Demand............................. 108
2 Western Europe -- Bioplastics
Demand by Type & Market................. 110
Cht Western Europe Bioplastics
Demand by Country, 2008.................. 111
3 Germany -- Bioplastics Supply & Demand 113
4 Germany -- Bioplastics Demand by Type.. 114
5 Germany -- Bioplastics
Demand by Market........................... 116
6 Italy -- Bioplastics Supply & Demand..... 118
7 Italy -- Bioplastics Demand by Type....... 120
8 Italy -- Bioplastics Demand by Market.... 121
9 United Kingdom -- Bioplastics
Supply & Demand............................. 123
10 United Kingdom -- Bioplastics
Demand by Type.............................. 125
11 United Kingdom -- Bioplastics
Demand by Market........................... 126
12 France -- Bioplastics Supply & Demand... 128
13 France -- Bioplastics Demand by Type..... 130
14 France -- Bioplastics Demand by Market.. 131
15 Netherlands -- Bioplastics
Supply & Demand............................. 133
16 Netherlands -- Bioplastics
Demand by Type.............................. 135
17 Netherlands -- Bioplastics
Demand by Market........................... 136
18 Other Western Europe -- Bioplastics
Supply & Demand............................. 138
19 Other Western Europe -- Bioplastics
Demand by Country & Type . ............. 140
20 Other Western Europe -- Bioplastics
Demand by Market........................... 143
ASIA/PACIFIC
1 Asia/Pacific -- Bioplastics
Supply & Demand............................. 146
2 Asia/Pacific -- Bioplastics
Demand by Type & Market................. 148
Cht Asia/Pacific Bioplastics Demand
by Country, 2008............................. 149
3 Japan -- Bioplastics Supply & Demand.... 151
4 Japan -- Bioplastics Demand by Type...... 153
5 Japan -- Bioplastics Demand by Market... 155
6 China -- Bioplastics Supply & Demand.... 158
7 China -- Bioplastics Demand by Type...... 160
8 China -- Bioplastics Demand by Market... 162
9 South Korea -- Bioplastics
Supply & Demand............................. 164
10 South Korea -- Bioplastics
Demand by Type.............................. 166
11 South Korea -- Bioplastics
Demand by Market........................... 167
12 Other Asia/Pacific -- Bioplastics
Supply & Demand............................. 170
13 Other Asia/Pacific -- Bioplastics
Demand by Country & Type................ 172
14 Other Asia/Pacific -- Bioplastics
Demand by Market........................... 176
OTHER REGIONS
1 Latin America -- Bioplastics
Supply & Demand............................. 179
2 Latin America -- Bioplastics
Demand by Type & Market................. 181
3 Brazil -- Bioplastics Supply & Demand.... 183
4 Brazil -- Bioplastics Demand by Type...... 185
5 Brazil -- Bioplastics Demand by Market... 187
6 Other Latin America -- Bioplastics
Supply & Demand............................. 190
7 Other Latin America -- Bioplastics
Demand by Type.............................. 191
8 Other Latin America -- Bioplastics
Demand by Market........................... 192
9 Eastern Europe -- Bioplastics
Supply & Demand............................. 194
10 Eastern Europe -- Bioplastics
Demand by Country & Type................ 196
11 Eastern Europe -- Bioplastics
Demand by Market........................... 197
12 Africa/Mideast -- Bioplastics
Supply & Demand............................. 200
13 Africa/Mideast -- Bioplastics
Demand by Type.............................. 201
14 Africa/Mideast -- Bioplastics
Demand by Market........................... 203
INDUSTRY STRUCTURE
1 Bioplastics Sales by Company, 2008....... 205
Cht World Bioplastics Market Share, 2008..... 206
2 Selected Acquisitions & Divestitures....... 211
3 Selected Cooperative Agreements........... 223
Study #2548
November 2009
$5800
272 Pages
World Bioplastics
Industry Study with Forecasts for 2013 & 2018
Growth factors include consumer demand for more environmentally-sustainable products, and
increasing restrictions on the use of nondegradable plastic products, particularly plastic bags.
Non-biodegradable types
to be fastest growing
Non-biodegradable plant-based plastics
will be the primary driver of bioplastics
demand, rising from just 23,000 metric
tons in 2008 to nearly 600,000 metric
tons in 2013. Biodegradable plastics,
such as starch-based resins, polylactic
acid (PLA) and degradable polyesters,
accounted for the vast majority (nearly
90 percent) of bioplastics demand in
2008. Double-digit gains are expected to
continue, fueled in part by the emergence on the commercial market of
polyhydroxy-alkanoates (PHAs). PLA will
also see strong advances in demand as
new production capacity comes online,
Western Europe
38%
North America
29%
Asia/Pacific
29%
photo: PolyOne
Other Regions 4%
Study #2548
November 2009
$5800
272 Pages
World Bioplastics
Industry Study with Forecasts for 2013 & 2018
Sample Text,
Table & Chart
TABLE VI-4
JAPAN -- BIOPLASTICS DEMAND BY TYPE
(thousand metric tons)
Item
sample
table
sample
text
The bioplastics market in Japan includes a diverse range of products, with starch-based resins, PLA, petroleum-based biodegradable
resins, and non-degradable bioplastics each accounting for around 20 to
25 percent of 2008 demand. Through 2013, the fastest gains among biodegradable plastics are expected for PLA, which will benefit from more
widespread availability as production in China begins to come online.
Additionally, Japanese compounders are making efforts to improve the
performance of PLA-based materials in order to penetrate durable goods
markets such as automotive and electronics uses.
CHART VIII-1
The most rapid growth among bioplastic products in Japan, however, will be for non-biodegradable resins such as bio-based polyethylene. WORLD BIOPLASTICS MARKET SHARE, 2008
($793 million)
While this is true in most countries, it is especially apparent in Japan,
due to the willingness of consumers to pay a premium for bio-based materials, as well as achieving the governments goal of bio-based plastic
152
O th e r s
38.2%
sample
chart
Market
L ead ers
61.8%
18.3%
N at u reW o rks
16.4%
Arkem a
15.8%
In n o v ia F ilm s
11.3%
N o v am o n t
Study #2548
November 2009
$5800
272 Pages
World Bioplastics
Industry Study with Forecasts for 2013 & 2018
Sample Profile,
Table & Forecast
TABLE VI-5
JAPAN -- BIOPLASTICS DEMAND BY MARKET
(thousand metric tons)
Item
sample
table
COMPANY PROFILES
Ningbo Tianan Biologic Material Company Limited
68 Dagang Road, Number 6
Beilun, Ningbo, Zhejiang
China
86-574-86895240
http://www.tianan-enmat.com
Annual Sales: $5 million (estimated)
Employment: 85 (estimated)
sample
profile
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Page 7
Other Studies
Extruded Plastics
This study analyzes the US extruded plastic industry.
It presents historical demand data for the years 1998,
2003 and 2008, and forecasts for 2013 and 2018 by
extruded plastic resin (e.g., polyvinyl chloride, low
density polyethylene, high density polyethylene, polystyrene, polypropylene, polyester) and market (e.g.,
construction, packaging, consumer goods). The study
also considers market environment factors, details
industry structure, evaluates company market share
and profiles industry players.
Foamed Plastics
US foamed plastics demand will reach 8.4 billion
pounds in 2013 as key construction and motor vehicle markets recover. Foamed urethane will remain the
largest segment while foamed LDPE grow the fastest.
Construction will provide the best opportunities
based on growth in insulation and carpet underlay
applications. This study analyzes the $22.5 billion US
foamed plastics industry, with forecasts for 2013 and
2018 by market and product. It also evaluates market
share and profiles industry players.
Natural Polymers
US demand for natural polymers will grow 7.1%
annually through 2012. Best opportunities are anticipated in packaging uses based on the increased
availability and cost competitiveness of novel polymers such as polylactic acid (PLA). Cellulose ether
will remain the largest segment while starch and
fermentation products jump at double-digit rates. This
study analyzes the $2.9 billion US natural polymer
industry, with forecasts for 2012 and 2017 by market
and product. It also evaluates company market share
and profiles industry players.
Biodegradable Plastic
US demand for biodegradable plastic will grow 15.5%
yearly through 2012. Gains will be driven by escalating costs for petroleum-based resins and growing
initiatives that favor renewable resources. Polyesterbased and polylactic acid resins will grow the fastest,
while starch-based types remain the largest segment.
This study analyzes the 350 million pound US biodegradable plastic industry, with forecasts for 2012 and
2017 by type and market. It also details market share
and profiles industry players.
Page 8
The Freedonia Group, Inc. 767 Beta Drive Cleveland, OH 44143-2326 USA Web site: www.freedoniagroup.com
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Bioplastics Industry
(2008 2012)
Innovation: as new things derived from the exploitation of knowledge and creativity,
leading to enhancement of social and economic value.
Design by
National Innovation Agency (NIA)
73/1 Rama VI Road, Rajdhevee, Bangkok 10400 Thailand
Tel. +662-2-644 6000 Fax. +66-2-644 8444
http://www.nia.or.th
Table of Contents
Page
Executive Summary
1.1 Introduction
13
13
18
23
25
27
30
Technology Cooperation
Strategy 3 Building Industry and Innovative Businesses
38
42
Abbreviations
55
Executive Summary
1. Rationale
Bioplastics, as the biodegradable plastics, are plastics which could be derived
from plant-based materials or other renewable resources through fermentation
process. This process requires low energy input and produces the plastics with the
ability to degrade when being composted, yielding carbon dioxide and water as end
products. In fact, bioplastics have become one of the most innovative materials which
answer to the ever-increasing demand for more environmentally friendly solutions.
Around the world, especially in the leading industrialized nations, there is a great
awareness in searching for new raw materials or polymers to improve the quality and
functionality of bioplastics so that they can replace the conventional plastics that
produced by petrochemical industries.
An awareness in using bioplastics can be witnessed in many developed
countries where a wide range of favorable initiatives are put into action, including
government policies, a research and development, and the industrial promotion. These
resulted in a rapid growth of bioplastics business in a clearly defined direction. The
United States, for example, has stepped forward to become the pioneer in bioplastics
industry as a result of the success in the industrial-scale bioplastics resin production.
NatureWork LLC (USA) has successfully produced lactic acids and polylactic acids
(PLAs) from corn feedstock; whereas, Metabolix Inc. has developed the technology to
produce PHAs (Polyhydroxyalkanoates) and is constructing its first production
facility in the USA.
This development has been encouraged by the state policies to increase the
production of biomass-based products from 5% in 2002 to 12% and 20% in 2010 and
2030 respectively. Furthermore, 11 states have declared the policies to promote the
environmentally friendly packaging market. Green Report I and II have also been
issued to serve as the guidelines for advertising eco-friendly products. With regard to
the plastic waste management, MARPOL convention prohibits the dumping of plastic
waste to the sea. These movements arose from the questioning of the conventional
plastics inability to degrade naturally and resulted in the initiation of 17 cent per
piece charged for each plastic bag.
On the other continent, the European Union also announced a mandate for
automobile industry that, from 1 January 2006 onward, more than 85% (by weight) of
the vehicle parts must be made of reusable or recoverable materials. Bioplastics,
consequently, stand out as one of most sought-after answers for those regulations. For
example, Germany has exempted the tax for the compostable packaging, while France
requires that by 2010 all trash bags must be compostable. In Florence, Italy, all food
packaging must be made from degradable materials. As another example, Denmark
bans the use of water containers which cannot be recovered. In Norway, the UK and
Ireland, there is a plan to program to lower the consumption of petrochemical-based
plastic shopping bags as these conventional bags must be bought by consumers
instead of be given freely.
Many more countries in Asia-Pacific also join in enforcing laws and measures
with an aim to reduce environmental loads from the growing demands for packaging.
In Japan, Green Procurement policies were imposed along with the Revised Recycling
Laws and the Pollutant Release and Transfer Register to counter this problem. In
Ladakh, India, it is announced that 1 May of every year is the Plastic Ban Day; while,
in Bombay and Himachal Pradesh, there is a strict regulation of plastic bags and
Styrofoam production. On the other hand, Bangladesh has issued a more strict
regulation of countrywide prohibition of plastic bags since 2002. In Taiwan, R.O.C.,
the conventional LDPE plastic bag control scheme called Plastic Shopping Bag Use
Restriction Policy bans all shops from distribute plastic bags and Styrofoam
containers to their customers without pay.
In some regions, bioplastics have been used as a tool for waste management.
Taking Australia for example, during the Sydney Olympics Games, bioplastics
containers and packaging were used and 75% of these bioplastics was gathered for
compost. This greatly eased the burden of having to separate conventional plastics
before compost and proved to be very effective in the management of plastic waste.
The growth of bioplastics market has been evident in many developed
countries, e.g. USA, European Union and Japan. In Germany, the advances in the
bioplastics compounding technology, the blending process of bioplastics resin and
other additives to attend the desired mechanical and physical properties, has resulted
in the rapid growth of small and medium enterprises (SMEs). Also, the governmental
agencies both at the national and local levels issue tax deterrent for non-degradable
plastics making their price higher and in turns helping the bioplastics to stay
competitive.
In Japan, the development of bioplastics product has been substantial and
rapid. Many large companies, e.g. Sony, Panasonic and Toshiba, have turned to
bioplastics for their product packaging, computer devices and compact discs.
Considering the business rationalization of bioplastics in the abovementioned
examples, it is apparent that the market share for bioplastics is on the rise and
bioplastics is rapidly replacing the conventional petroleum-based plastics. The
production capacity for bioplastics worldwide was 360,000 ton in 2005 or
approximately 1% of the total plastics production of 200 million ton per year. The
demand for bioplastics in the EU is estimated at 40,000-50,000 ton per year with the
projected growth of 20% each year; whereas the bioplastics consumption in Japan is
at 15,000 ton per year and this number is anticipated to double each year. On the other
hand, the demand for bioplastics in USA is estimated at 70,000 80,000 ton per year
with the projected growth of 16% each year. All these figures amount to the global
projected expansion for bioplastics demand of 30% per year.
At the same time, the private sector could develop some bioplastics products
from with the support from NIA through technology transfer and joint research with
universities and research institutes. This technology cooperation between private and
government sectors has resulted in the import of bioplastics compounds for products
processing and of bioplastic resin to blend with starch to produce cost-effective
compounds. These products, in fact, have made it to the international markets.
On the research and development collaboration, NRCT, NIA and TBIA have
initiated a targeted research to develop innovative bioplastics products. This has been
NRCT under the project, Research and Innovation Helix Program on Bioplastics.
Numerous universities and research institutions were the research counterparts in this
project; among these include Chulalongkorn University, King Mongkut's Institute of
Technology Ladkrabang, Suranaree University of Technology, Chiengmai University
and Kasetsart University.
Up to present, there are 3 strategic areas for bioplastics R&D in Thailand
namely: (1) Agricultural Raw Materials, (2) Biotechnology, and (3) Chemical and
Compounding Technology. Approximately 100 researchers have been actively
conducting studies on these 3 areas ranging from the improvement of plant breeding,
the enhancement of crop productivity for industry feedstock, selection of natural
strains of microbes, improvement of microbe strains, fermentation technology, starch
technology and polymerization technology.
In summary, the development of bioplastics industry in Thailand is still in the
early stage. Therefore, there is a need for a national roadmap in order to propel this
initiative into the streamlined manner to facilitate all stakeholders (both government
and private) to work together to induce a favorable environment for investment,
establishment of business partnership, establishment of supporting policy, market
development and development of technology and innovation. This roadmap can, in
turn, enable Thailand to secure a competitive edge to position herself on the global
bioplastics market.
7. Expected Outcomes
At the end of this 5-year Roadmap, the cooperation and initiative from both
governmental and private sectors under this action plan should create significant
impact on the following 4 areas:
7.1 Economic, Industrial and Agricultural Aspects
Thailand, through the new wave industries and innovative business on
bioplastics, can anchor herself on the international bioplastics market and manage to
take a considerable proportion of the global market share. Also, this can provide value
creation and value-added to the agricultural raw materials are anticipated to result in
the value totaling up to 4,500 million baht.
7.2 Technological Aspect
The development of new technology can lead to the creation of intellectual
properties, technology transfer and integration of technology from abroad resulting in
the growing number of research specialists on bioplastics. This consequently gears the
country toward the integrated and directed R&D process which could produce an
economic value of 500 million baht.
7.3 Environmental Aspect
Awareness in using bioplastics as a solution for environmental problems can
help lower the burden caused by the plastics waste. Thus, less money will be allocated
to the management of plastics waste and air pollution created from the burning of
these non-degradable plastics will be eliminated. This equates with an economic
impact of 500 million baht.
7.4 Policy Aspect
The execution of the National Bioplastics Roadmap can induce the
establishment of policy, framework and measure to promote and incentives favoring
the investment in the bioplastics industry including the establishment of various
testing and certification standards on bioplastics products.
Introduction
1.2
Corn starch
Cassava starch
Saccharification
by enzyme
Liquid glucose
Fermentation
by bacteria
PHAs
Lactic acid
Wheat flour
Succinic acid
Potato starch
1,3-Propanediol: PDO
Bioplastics products
Compounding
Molding
Polymerization
Biodegradable plastics such
as PLA, PBS
Sieving
Rasping
Separator
Liquid glucose
Liquid glucose can be produced from cassava starch and molasses. However,
the process is still under development to optimize the use of specific enzymes
necessary for the digestion process. Production of glucose from corn starch is possible
but different equipment must be used. Since there is only one corn starch factory in
Thailand and a 60% import tax is levied on, its use as a feedstock is not currently
cost-effective.
Location
Bangkhuntian, Bangkok
Ratburana, Bangkok
Muang, Samut Prakarn
Bangplee, Samut Prakarn
Bangplee, Samut Prakarn
Gaengkhoi, Saraburi
Nongyai, Chonburi
Banglamung, Chonburi
Bankai, Rayong
Pongnamron, Chantaburi
Panom, Sarakam, Chachoengsao
Muang, Nakhon Ratchasima
Muang, Nakhon Ratchasima
Sikeo, Nakhon Ratchasima
Tamoung, Kanchanaburi
Muang. Nakhon Phatom
Dontoom, Nakhon Phatom
Sampran, Nakhon Phatom
Sampran, Nakhon Phatom
Sources: http://www2.diw.go.th/cluster/Fac_EIA1.asp
Location
Phranakorn Sri-Ayutthaya
Product
Plastic bags for
plants
2. M.S.V.
Trading Ltd.,
Part
Bangkok
3. Bio Green
World Co.,
Ltd. (BGW)
Samut Prakarn
Food container
such as plate,
bowl, spoon and
fork
Food container
such as Plates,
bowls, spoons
and cups
4. BIOFOAM
Jazzy Creation
Co., Ltd.
Bangkok
5. Biodegradable
Packaging for
Environment
Co., Ltd.
(BPE)
6. KU-GREEN:
Biodegradable
Package
Bangkok
7. Thantawan
Industry
Public
Co., Ltd.
Bangkok
Bag, film
8. PURAC
Thailand
Rayong
Lactic acid
Bangkok
Heat-resistant
food packaging
(single-use)
such as
disposable
plates, bowls
and food trays
Single use food
packaging such
as disposable
plates, bowls
and spoons
Single use food
packaging such
as disposable
plates, bowls,
trays and
glasses
Technology
- produced from
corn starch
- import raw
plastic from
USA and
process in
Thailand
- produced from
PLA or PLA /
starch blend
- PLA pellets
imported from
Taiwan
- Produced from
cassava starch,
hot-molded into
finished
products
- Own proprietary
technology
- Produced from
bagasse
- Produced from
cassava starch,
hot-moulded
into finished
products
- Own proprietary
technology
- Import raw
plastic from
USA and
process in
Thailand
- Development
compounding
- Produced from
molasses or
cassava
1.3
1.3.1
Raw materials
Corn starch
Wheat flour
Cassava starch
Year
Figure 1.3 Prices of cassava starch, potato flour, corn starch
and wheat flour in the world market
In 2005, Thailand produced 16.94 million tons of fresh cassava roots, equal to
8% of world production and ranked No. 4 among fresh cassava producers, behind
Nigeria, Brazil and Indonesia. 73.5% of fresh cassava roots are exported as pellets,
chips or flour, as shown in Figure 1.4. As mentioned, Thailand is ranked as the
worlds top exporter of cassava products, with 4.6 million tons p.a., or 85.5% of
market share, valued at more than 30 billion baht. Its exports to China, Taiwan and
other emerging markets mean that cassava has now become one of Thailands most
important industrial crops. The non-exported production (26.5%) is mostly used as
fresh starch in various agro-industrial processes such as the monosodium glutamate
production, as well as the lysine, sweeteners, papers, and weaving industries.
However, the export demand for cassava remains the main market driver.
73.5 %
25 %
Flour
1.1 m tons
(4.12 m tons fresh
roots)
3.5%
Pellets
0.26 m tons
(0.6 m tons fresh roots)
838 million baht
World no.1
Ratio 85.5 %
34%
Flour
1.61 m tons
(5.9 m tons fresh roots)
20,150 million baht
Figure 1.4 Cassava utilization ratios between domestic industry and exportation (2005)
Source: adapted information from The Thai Tapioca Trade Association Book B.E. 2547 (the detail
based on the Ministry of Agriculture and Cooperatives and Customs Department) From draft report
Evaluation and Identification for Raw Intervention Ideas for Thailands Tapioca Subsector by
AgriSource Co. Ltd. Figure 3.3, page 28.
Notes:
Conversion ratio for fresh cassava roots:
1 kg cassava chip : 2.2-2.4 kg fresh cassava roots
1 kg pellets cassava : 2.5-3.0 kg fresh cassava roots
1 kg fresh starch : 3.5-4.0 kg fresh cassava roots
Cassava is cultivated over 6.5 million rai (1 rai: 1,600 square meters),
amounting to 14.22% of the total cultivated areas in Thailand. (Source: Ministry of
Agriculture and Cooperatives). Around 52% of the cassava production area is in the
northeastern provinces of Nakorn Ratchasima, Chaiyaphum, Kalasin, Khon Kaen,
Buriram, and Sa kaew, and 25% in the eastern provinces of Chacheongsao, Chonburi,
Chantaburi and Trat. The northern and central regions have 15% and 8%,
respectively. Table 1.3 to 4.6 show statistics on the cultivated area, annual
productivity, productivity per rai, farm gate prices of fresh roots, wholesale prices of
cassava product, and volumes and value of cassava exports.
Table 1.3 Primary information on commercial cassava cultivation
Average product
Production cost
Cost of product
3.5 tons/rai
2,100 baht/rai
4,000 baht/rai
Table 1.4 Cultivated area, product, product per rai, cassava selling price by farmers
B.E. 2539-2005
Cultivated Harvested
Production
Production
area
area
per rai
Year
1996
1997
1998
1999
2000
2001
2002
2003
2004
2005
(1,000 ton)
17,388
18,084
15,591
16,507
19,064
18,396
16,868
19,718
21,440
16,938
(kg)
2,265
2,352
2,388
2,479
2,697
2,805
2,731
3,087
3,244
2,749
Selling
price by
farmers
(baht/kg)
0.98
0.71
1.26
0.91
0.63
0.69
1.05
0.93
0.80
1.31
Cassava product
Wholesale price in Bangkok
FOB price (baht/ton)
(baht/kg)
Pellets
Chip
Flour
Pellets
Flour
2.36
2.03
5.16
3,700
5,740
2.62
2.40
5.70
3,860
6,070
2.57
2.40
5.59
3,850
5,893
2.16
1.94
4.31
2,736
5,056
2.43
2.22
4.31
2,736
6,184
3.10
3.08
8.48
3,495
8,869
2.96
2.70
6.47
3,160
7,343
2.21
2.05
6.46
2,479
7,566
3.20
3.01
10.64
3,301
11,306
2.65
2.43
5.85
2,865
6,826
2.00
1.81
5.27
2,210
6,308
2.22
2.27
7.29
2,574
7,648
2.22
2.69
7.62
2,807
7,898
2.57
2.56
6.39
2,911
7,052
2.72
2.85
7.60
3,097
7,473
3.20
3.99
9.28
3,207
9,495
Sources: Office of Agricultural Economics, Ministry of Agriculture and Cooperatives. From draft
report Evaluation and Identification for Raw Intervention - Ideas for Thailands Tapioca Subsector
by AgriSource Co. Ltd. Table 4.3
Amount
(ton)
2004
127
1,812,374
1,084,068
1,859,939
21,684
525,515
Cost
(million
baht)
4.2
5,352.9
7,439.6
5,096.0
251.9
8,780.0
Amount
(ton)
75
2,805,988
1,113,633
2,212,948
26,742
492,638
Cost
(million
baht)
1.8
8,640.7
8,196.5
6,391.6
315.5
7,500.7
5,091
61,594
5,370,392
161.2
138.7
27,224.7
10,231
194,267
6,856,522
289.5
479.2
31,815.5
Thailands cassava exports consist mostly of chips, pellets and starch, which
have low prices and depend on the foreign commodity market factors leading to
unstable prices and demanding conditions. Therefore, in order to increase its value,
cassava needs to be adopted as an industrial raw material. Cassava starch in particular
can be used for a number of industrial processes. As shown in Figure 1.5, when raw
cassava roots are transformed into secondary products such as pellets, chip or flour,
the value added will be only 50%, equal to 30 billion baht. But when further
transformed into its tertiary products such as bioplastics, modified starch, cellulose
products or liquid glucose, the added value will be 150% of its original, equal to 76
billion baht. For bioplastics alone, the added value would be 44 billion baht.
Cost
20,000 MB
Fresh roots
20 MT (1 B/kg)
20,000 MB
12 MT
50 %
30,000 MB
8 MT
Chips
2 MT
6,000 MB
Pellets
3 MT
9,000 MB
Exported
cassava starch
1.4 MT
Animal feed
150 %
76,000 MB
0.2 MT
Bioplastics
(PLA: 120-320 B/kg)
44,000 MB
Flour
2.3 MT (6.5 B/kg)
15,000 MB
Stalks
1 MT
1,000 MB
0.7 MT
Modified starch and
chemicals(14 B/kg)
20,000 MB
Cellulose
10,000 MB
Liquid
glucose
2,000 MB
1.3.2
Plastic granules/resin
Strengthening
Composites
SMC, BMC
Compounding
Blending
Additives
Molding
Mould and injector
production
Consumer market
Packaging
Sports equipment / toys
Parts / building materials
Downstream industries
Packaging
Electrical parts
Vehicle parts
Construction materials
Household appliance Sports equipment / toys
Synthetic fibres
Shoe parts, others
sources (natural gas from the Gulf of Thailand) than others such as the Middle Eastern
countries, Indonesia and Malaysia. Nevertheless, Mabtapud Petrochemical Industrial
Estate is ranked 8th in the world, and No.1 in the ASEAN region, as the producer of
plastic granules. Thailand produces a diverse range of high quality plastic granules,
including thermoplastics and thermoset. Both types are made in both basic and
engineering forms. Thailands plastic granule exports are destined mainly for Japan,
Singapore, USA, South Korea and Taiwan (See Figure 1.7).
Thailand
4.0%
USA
31.0%
Others
47.0%
Germany
10.5%
China Malaysia
6.0% 1.5%
Thailand
4,296
88
Bangkok and
surroundings
62
14,432
No.1 in ASEAN
Sources: Department of Industrial Works, Ministry of Industry and Department of Trade Negotiation,
Ministry of Foreign Affairs
There are 4,296 factories producing plastic products for molding registered
with Department of Industrial Works, Ministry of Industry (data from the DIW,
December 2002). However, it was estimated that the real number of factories could be
over 5,000, including 30 plastic granule factories. From 2002 data there are 4,229
registered factories categorized into packaging manufacturers (41.9%, the largest
market), followed by household products (16.9%) and finally, compounding plastic
granules (5.1%). Figure 1.8 below shows the breakdown of plastic product factories in
Thailand.
Vehicle parts
2%
Electrical parts
4%
Construction materials
4%
42 %
Toys, sport
equipment
5%
Others
16 %
Shoes
Fibre
4%
1%
Compounding plastic
granules
5%
Economic Importance
Although Thailand has always been considered primarily as an agricultural
country, over 75 percent of its exports are industrial products, including plastic
granules, which indeed form one of the countrys most important exports. Even
during the economic downturn in 1997, the export value of plastic granules is listed in
the top 10 in Thailand. Thailands export volume and value of plastic granules
between the years 1996 2003 are shown in Figure 1.9 below.
3.0
120,000
2.0
80,000
60,000
1.0
40,000
20,000
0.0
0
2539
2540
2541
2542
2543
2544
2545
2546
3.0
120,000
100,000
2.0
80,000
60,000
1.0
40,000
20,000
0.0
0
2539
2540
2541
2542
2543
2544
2545
2546
Figure 1.9 Export volumes and value of plastic granules (1996 2003)
Source: IT Centre for Economy and Trade, and the Customs Department
Value (m baht)
Volume (m tons)
Volume (m tons)
100,000
Woven sacks
2%
Pipes and tubes
2%
Boxes
and luggage2%
Clothing &
accessories
3%
Rainwear
0%
Fishing nets
4%
Tableware and
kitchenware
5%
Other
28%
Plastic Industry
Plastic product
Figure 1.11 Potential of Thai plastics industry (2003) by volume and value.
Figure 1.11 indicates the potential for Thailands plastic industry, from the
production of basic intermediates (plastic granules) from the petroleum industry at
Maptaphut to midstream technologies (compounding) and downstream (molding) and
the presence of strong market demand both within Thailand and overseas.
The potential and competitiveness of the petrochemical-based plastics industry
brings both advantages and possibilities for the production of bioplastics, especially
downstream technologies that employ similar production processes and machinery.
As shown in Table 1.8, Thailand has many advantages and strengths. With the
government policy supports in various areas such as an environment, trades and
investment as well as an encouragement to build technology, Thailand has the
potential to play a leading role in bioplastics industry development in the region.
Table 1.8 Strengths and potential of Thailands bioplastic industry
Industry
Polymer
Industry
Compounding
granule industry
Plastic products
industry
1.3.3
Constraints
Lack of
technology and
expertise
High price of
bioplastics
Possibility
Moderate
High
Highest
The government policy and support measures have a direct and major effect in
driving the bioplastics industry. Implementing existing policies and establishing new
ones to create an appropriate enabling regulatory framework to promote the
bioplastics sector will be crucial to achieve national objectives. Since there is
currently no law dealing specifically with bioplastics, laws concerning plastics and
foams packaging are currently applied. New Royal Decrees are needed to amend
existing legislation and ensure an effective enforcement in order to provide an
effective and enabling regulatory framework for a viable bioplastics industry sector in
Thailand. Some suggestions related to current legislation are offered below.
Table 2.1 Strategy and budget allocation for the Road Map for the Development of
Bioplastics Industry
Strategies
100
1,000
(100)
(900)
475
(445)
(30)
225
(55)
(50)
(120)
Total Budget
1,800
Action Plans
Strategy 1: Sufficient Supply of Biomass Feedstock (100 million baht)
- Ministry of Agriculture
and Cooperatives*
2012
Period/Budget
Sources of Budget Figures
2011
Responsible Agency
(* Key Agency)
2010
Functions (Budget)
2009
Key Indicators
- To have approximately 10,000 tons of cassava annually
- To increase the cassava productivity to more than 8 ton per rai #
#
1 Hectare = 6.25 Rai or 10,000 sq. m.
2008
Targets
1. To obtain sufficient cassava as raw materials for production feedstock
2011
2012
Period/Budget
Sources of Budget Figures
2010
3. Encourage improved
management of cultivated areas
(5 million baht)
Responsible Agency
(* Key Agency)
2009
Functions (Budget)
2008
0.8
0.8
0.4
2.6
2.6
2.6
2.6
2.6
- Ministry of Agriculture
and Cooperatives*
- Ministry of Agriculture
and Cooperatives*
- Ministry of Industry
[Working in a form of
committee consisting of
representatives from
Ministry of Education,
Ministry of Industry, Thai
Bioplastics Industry
Association, etc.]
- Ministry of Agriculture
and Cooperatives*
- Gather information and acting as
Thai Tapioca
source of information on the status
Development
Institute
of raw material supply
2012
- National Research
Council of Thailand*
2011
Period/Budget
Sources of Budget Figures
2010
Responsible Agency
(* Key Agency)
2009
Functions (Budget)
2008
22
20
0.6
0.6
0.6
0.6
0.6
33
31
17.6
9.2
9.2
- Ministry of Commerce*
Total Budget for STRATEGY 1: Sufficient Supply of Biomass Feedstock 100 million baht
Strategy 2: Accelerating Technology Development and Technology Cooperation (1,000 million baht)
2.1 Immediate adoption of available technologies (100 million baht)
- To have an access to at least 5 compounding formulae, with an emphasis on the formulae for use in
packaging applications, thermoforming film and injection
- National Innovation
Agency*
1.5
0.5
2012
Period/Budget
Sources of Budget Figures
2011
Responsible Agency
(* Key Agency)
2010
Functions (Budget)
- To have an access to 2 types of polymerization technologies such as PLA and PBS production
2009
Key Indicators
- To have an access to 2 types of technologies in transforming sugar into monomer and/or PHAs, such as
production of lactic acid, PDO, succinic acid and/or PHAs
2008
Targets
1. To gain an access to at least 1 modern technology for fermenting sugar
for monomer production and/or PHAs by 2012
2. To gain an access to at least 1 modern polymerization technology for
polylactic acids (PLAs) by 2012
3. To gain an access to modern compounding technologies for
the preparation of PLA resin for molding products at least 1 technology
by 2010
- National Innovation
Agency*
- Undertake activities to introduce
proven technologies to groups of
industry executives/entrepreneurs
(5 million baht)
- Allocate partial subsidy funds for
buying licenses of intellectual
property for groups of industry
entrepreneurs
(50 million baht)
- Issue investment incentives
2.5
2.5
1.5
1.5
1.5
0.5
20
20
10
2012
2011
Period/Budget
Sources of Budget Figures
2010
Responsible Agency
(* Key Agency)
2009
Functions (Budget)
2008
2011
2012
Period/Budget
Sources of Budget Figures
2010
Responsible Agency
(* Key Agency)
2009
Functions (Budget)
2008
2.5
2.5
5.5
- Board of Investment
(BOI)*
- National Innovation
Agency*
2.2 Further developing / generating indigenous new technologies (900 million baht)
Period/Budget
Sources of Budget Figures
2012
Responsible Agency
(* Key Agency)
2011
Functions (Budget)
2010
2009
Key Indicators
- To have at least 2 types of technologies for fermenting sugars for monomer production and PHAs,
e.g. production of lactic acids, PDO, succinic acids and/or PHAs
- To have at least 2 types of technologies in polymer production
- To have at least 5 compounding formulae per year for commercial use
- To have at least 20 research papers per year published in national academic journals and at least
5 papers per year in international academic journals
- To have at least 20 research papers presented in national academic conferences and at least 10
in international academic conferences
- To register at least 10 national patents per year and at least 1 international patent per year
(starting from 2011)
2008
Targets
(cont.)
- Allocate research funds for
research projects in the following
areas:
- Upstream research
(100 million baht)
- Midstream research
(90 million baht)
- Downstream research
(60 million baht)
- Support the instruments and
durable goods to research
institutes or research teams along
with research fund in order to
facilitate the development of
further research or improvement
of existing technology
(125 million baht)
- National Research
Council*
15
15
15
[Working in a form of
committee consisting of
representatives from
National Innovation
Agency, Bereau of the
Budget, Ministry of
Education, Ministry of
Industry, Thai
Bioplastics Industry
Association, etc.]
40
40
35
30
60
30
35
30
30
2012
2011
Period/Budget
Sources of Budget Figures
2010
Responsible Agency
(* Key Agency)
2009
Functions (Budget)
2008
2011
2012
- National Innovation
Agency*
Period/Budget
Sources of Budget Figures
2010
Responsible Agency
(* Key Agency)
2009
Functions (Budget)
2008
10
10
10
10
10
20
20
20
50
40
- National Research
Council*
[Working in a form of
committee consisting of
representatives from
National Innovation
Agency, Bureau of the
Budget, Ministry of
Education, Ministry of
Industry, Thai Bioplastics
Industry Association,
etc.]
50
25
25
[Working in a form of
committee consisting of
representatives from
National Innovation
Agency, Bureau of the
Budget, Ministry of
Education, Ministry of
Industry, Thai
Bioplastics Industry
Association, etc.]
15
20
20
10
10
10
10
10
10
2012
15
2011
20
- National Innovation
Agency*
- National Research
Council
- National Research
Council*
3. Encourage and support the
industrial engineering and
production process at model or
pilot level for building fullyequipped industrial factories
(150 million baht)
Period/Budget
Sources of Budget Figures
2010
Responsible Agency
(* Key Agency)
2009
Functions (Budget)
2008
2012
2011
- National Innovation
Agency*
Period/Budget
Sources of Budget Figures
2010
Responsible Agency
(* Key Agency)
2009
Functions (Budget)
2008
485
215
150
25
25
- Ministry of Commerce*
(Department of
Intellectual Properties)
- National Innovation
Agency*
Total Budget for STRATEGY 2.2: Further developing / generating indigenous new technologies
Strategy 3: Building industry and innovative businesses (total budget Baht 475 million)
3.1 Industry innovative business (445 million baht)
1. Encourage co-investment
between groups of
entrepreneurs and enterprises
which own foreign technologies
in order to build pilot industrial
factories for monomer and
polymer production
(350 million baht)
Functions (Budget)
Responsible Agency
(* Key Agency)
- Allocate zero-interest
contingency loans for building
factories (100 million baht)
- Establish co-investment with
groups of entrepreneurs
(250 million baht)
- Suggest, advise, facilitate and
coordinate relevant sectors for
building factories
- National Innovation
Agency*
- Board of Investment
(BOI)*
Period/Budget
Sources of Budget Figures
Zero-interest contingency loans worth 100
million baht
30
30
40
100
150
2012
2011
2010
2009
Key Indicators
- To have 2 starch, sugar or new factories to produce monomer (such as lactic acid, succinic acid, PDO)
from sugars, with capacity of at least 1,500 tons per year and approximate investment value of 1.0
billion baht
- To have 2 factories for monomer production (such as PLA and PHAs), with capacity of at least 1,000
tons per year and approximate investment value of 1.5 billion baht
- To have 5 compounding factories which expand their existing businesses to bioplastics, or set up new
factories, with capacity of at least 300 tons per year in productivity and approximate investment value
of 200 million baht
- To have 30 molding factories expanding their businesses lines to bioplastics, with capacity of at least
100 tons per year and with approximate investment value of 300 million baht
2008
Targets
- National Innovation
Agency*
- Issue support
incentives/measures
- Board of Investment
(BOI)*
- Ministry of Industry*
- National Innovation
Agency
- Ministry of Commerce
- Board of Investment
(BOI)
- National Innovation
Agency*
2. Encourage compounding
industry and product molding
by having manufacturers
expand their business lines to
include bioplastics, or building
new factory facilities to fully
support bioplastic production
(70 million baht)
2012
2011
Period/Budget
Sources of Budget Figures
2010
Responsible Agency
(* Key Agency)
2009
Functions (Budget)
2008
25
25
167
217
47
1. Encourage manufacturers to
participate in domestic product
exhibition shows
(10 million baht)
- National Innovation
Agency*
- Ministry of Commerce
2012
Period/Budget
Sources of Budget Figures
2011
- Subsidize participation in
exhibitions for manufacturers
(10 million baht)
Responsible Agency
(* Key Agency)
2010
Functions (Budget)
2009
Key Indicators
- To sell 4,500 tons per year of compounding granules, valued at 300 million baht per year
- To sell 800 million baht of bioplastic products per year
- To export 1,500 ton per year of compound granules and bioplastic products worth 400 million baht per
year.
2008
Targets
1. Establish a domestic business on bioplastics compounding and
bioplastics products
2. Establish overseas markets for bioplastics compounding and
bioplastics products
- National Innovation
Agency*
- Ministry of Commerce
2012
2011
2. Encourage manufacturers to
participate in product
exhibitions and major trade
events abroad
(20 million baht)
Period/Budget
Sources of Budget Figures
2010
- Subsidize participation of
manufacturers at exhibitions and
trade shows
(20 million baht)
Responsible Agency
(* Key Agency)
2009
Functions (Budget)
2008
- National Innovation
Agency*
- German Technical
Cooperation (GTZ)
Total Budget for STRATEGY 3.2: Building domestic and overseas markets
30 million baht
Responsible Agency
(* Key Agency)
- National Innovation
Agency*
- Ministry of Industry*
(Thai Industrial
Standards Institute)
- Ministry of Industry*
(Thai Industrial
Standards Institute)
- National Innovation
Agency
Period/Budget
Sources of Budget Figures
0.5
0.5
- Standards establishment
4 million baht.
2012
Functions (Budget)
2011
2010
2009
Key Indicators
- To set up certification standards for biodegradation for domestic products, including assurance logo
for certification
- To establish at least 2 functioning centers
2008
Targets
Total Budget for STRATEGY 4.1: Building industry standards for biodegradability and testing
2012
- Personnel development
(10 million baht)
- Provide information on testing
techniques and equipment.
- Participate in development of the
Testing Center
- Support information and advise
on the model of Testing Center
2011
2. Establish a Degradability
Testing Center for bioplastics
(50 million baht)
Period/Budget
Sources of Budget Figures
2010
Responsible Agency
(* Key Agency)
2009
Functions (Budget)
2008
2.5
40
10
4.2 Environnent
4.2.1 Environnemental conservation (50 million baht)
- National Innovation
Agency*
- Ministry of Natural
Resource and
Environment*
(Department of
Pollution Control)
- Ministry of Science and
Technology
2012
Period/Budget
Sources of Budget Figures
2011
Functions (Budget)
2010
Responsible Agency
(* Key Agency)
2009
Indicators
- To establish at least 2 government measures/policies to encourage manufacturing and use of
bioplastics
- To launch at least 2 projects/campaigns such as the Green Airline and Compost Bag for Organic
Waste
- To reduce waste in Bangkok by at least 12 percent (equivalent to 1,000 tons per day)
2008
Target
1. Implement government measures or policies to encourage and
facilitate the production and utilization of bioplastics
2. Establish pilot bioplastic project for environmental protection
5. Establish an efficient
biodegradable waste
management model
(20 million baht)
- Ministry of Natural
Resource and
Environment* (Department
of Pollution Control)
- Ministry of Interior*
(District Administration)
- Ministry of Public Health*
(Department of Health)
- Ministry of Natural
Resource and
Environment*
(Department of
Environmental Quality
Promotion)
- Ministry of Commerce*
- Ministry of Natural
Resource and
Environment* (Department
of Pollution Control)
2012
2011
Period/Budget
Sources of Budget Figures
2010
Responsible Agency
(* Key Agency)
2009
Functions (Budget)
2008
- Ministry of Interior*
(District Administration)
- National Innovation
Agency*
- Ministry of Transport*
- Ministry of Interior*
(District Administration)
2012
2011
- Ministry of Natural
Resource and
Environment*
(Department of Pollution
Control)
Period/Budget
Sources of Budget Figures
2010
Responsible Agency
(* Key Agency)
2009
Functions (Budget)
2008
16
16
- Thailand Environmental
Institute (TEI)*
50 million baht
- National Innovation
Agency*
- Ministry of Education*
(Schools, colleges and
universities)
- Produce or purchase
documentaries
(30 million baht)
- Distribute documentary to
education institutes
- Determine conditions and
award prizes
(5 million baht)
- Produce advertising media to
create positive attitudes towards
bioplastics
(30 million baht)
2012
2011
Period/Budget
Sources of Budget Figures
2010
Functions (Budget)
2009
Responsible Agency
(* Key Agency)
2008
Target
1. Arrange campaigns to introduce bioplastics to consumers
2. Create positive attitudes towards using bioplastics, including social
and environmental consciousness
- National Innovation
Agency*
- National Innovation
Agency*
Total Budget for STRATEGY 4.2.2: Public relations and building awareness
2012
2011
- National Innovation
Agency*
Period/Budget
Sources of Budget Figures
2010
Responsible Agency
(* Key Agency)
2009
6. Convene an international
exhibition in Thailand
(50 million baht)
Functions (Budget)
2008
10
10
10
10
10
24
24
24
24
24
Key Indicators
- Technology policies created and implemented
- Ministry of Finance*
(Thai Customs Department,
Revenue Department)
- National Innovation
Agency*
- National Research Council
- Ministry of Education
(education institutes,
Commission on Higher
Education, Institute for the
Promotion of Teaching
Science and Technology)
- Thailand Research Fund
2012
2011
Period/Budget
Sources of Budget Figures
2010
Responsible Agency
(* Key Agency)
2009
Functions (Budget)
2008
- Ministry of Industry*
(Dept. of Industrial
Promotion, Board of
Investment, Office of
Industrial Economics,
Office of SME Promotion,
Industrial Estate Authority)
- Ministry of Finance
- Ministry of Natural
Resource and
Environment*
- Ministry of Industry
(Board of Investment)
- National Innovation
Agency
- Ministry of Finance*
(Thai Customs Department,
Revenue Department)
- Ministry of Commerce
(Dept. of Foreign Trade,
Dept. of Interior Trade,
Dept. of Trade Promotion,
Dept. of Export Promotion)
- National Innovation
Agency
- Ministry of Industry*
(Office of SME Promotion,
Industrial Standards
Institute)
- National Innovation
Agency
2012
2011
Period/Budget
Sources of Budget
2010
Responsible Agency
(* Key Agency)
2009
Functions (Budget)
2008
Total
2008
2009
2010
2011
2012
11.0
11.0
9.6
9.2
9.2
50.0
2. Ministry of Industry
5.0
5.0
10.0
496.0
224.0
147.0
14.0
14.0
895.0
36.0
11.0
6.0
6.0
6.0
65.0
25.0
25.0
238.0
288.0
98.5
45.5
45.0
715.0
7. Ministry of Commerce
4.0
4.0
4.0
4.0
4.0
20.0
4.0
4.0
4.0
4.0
4.0
20.0
819.0
547.0
269.1
82.7
82.2
1,800.0
Total
Total
2008
2009
2010
2011
2012
11.0
11.0
9.6
9.2
9.2
50.0
22.0
20.0
8.0
50.0
7. Ministry of Commerce
8. Ministry of Interior
33.0
31.0
17.6
9.2
9.2
100.0
Total
Total
2008
2009
2010
2011
2012
2. Ministry of Industry
474.0
204.0
139.0
14.0
14.0
845.0
42.5
42.5
25.5
12.5
12.0
135.0
7. Ministry of Commerce
4.0
4.0
4.0
4.0
4.0
20.0
520.5
250.5
168.5
30.5
30.0
1,000.0
8. Ministry of Interior
Total
Total
2008
2009
2010
2011
2012
5.0
5.0
10.0
168.0
218.0
53.0
13.0
13.0
465.0
7. Ministry of Commerce
8. Ministry of Interior
173.0
223.0
53.0
13.0
13.0
475.0
Total
Total
2008
2009
2010
2011
2012
2. Ministry of Industry
36.0
11.0
6.0
6.0
6.0
65.0
25.0
25.0
27.5
27.5
20.0
20.0
20.0
115.0
4.0
4.0
4.0
4.0
4.0
20.0
92.5
42.5
30.0
30.0
30.0
225.0
7. Ministry of Commerce
8. Ministry of Interior
Total
Abbreviations
Organization
ASEAN
MTEC
NIA
NRCT
PPC
R&D
SME
TBIA
Chemical reagents
AAC
BDO
BOD
COD
DMT
DOA
DOP
HDPE
HDT
LDPE
PBA
PBAT
PBS
PBSA
PBT
PCL
PDLA
PDO
PE
PEG
PES
PET
PGA
PGLA
PHAs
PHB
PHBV
PLA
PLLA
aliphatic-aromatic polyester
1,4-butane diol
biological oxygen demand
chemical oxygen demand
dimethyl terephthalate
dioctyl adipate
dioctyl phthalate
high density polyethylene
heat distortion temperature
low density polyethylene
poly(butylene adipate)
poly(butylene adipate terephthalate)
poly(butylene succinate)
poly(butylenes succinate adipate)
poly(butylene terephthalate)
poly(carprolactone)
poly(d-lactic acid) or poly(d-lactide)
1,3-propane diol
polyethylene
poly(ethylene glycol)
poly(ethylene succinate)
poly(ethylene terephthalate)
poly(glycolic acid)
poly(glycolic-co-lactic acid)
poly(hydroxyalkanoate)s
poly(hydroxybutyrate)
poly(hydroxybutyrate-hydroxyvalerate)
poly(lactic acid) or polylactide
poly(l-lactic acid) or poly(l-lactide)
PP
PS
PTT
PVA
PVAc
PVC
Tg
Tm
TPA
TPS
polypropylene
polystyrene
poly(trimethylene terephthalate)
poly(vinyl alcohol)
poly(vinyl acetate)
poly(vinyl chloride)
glass transition temperature
melting temperature
terephthalic acid
thermoplastic starch
Cassava roots are first transformed into cassava starch, which is then put
through a scarification process using enzymes to produce liquid glucose.
In Thailand, the worlds largest lactic acid producer, PURAC, (The Netherlands-based company)
opened a state of the art lactic acid production facility in Rayong on Jan 2008
Raw Materials
The Plastics Industry and Market Growth in Thailand
Government Policy and Support Measures
( : !"#$%& )
Technology
Economics
Policy
Market
Should indicate
how much carbon
dioxide is able to
reduce by
using respective
bioplastics
product.
Renewable feed
stocks in Thailand
such as
sugar and tapioca.
- Drive bioplastic
business
through
Biodegradable
plastic
national road
map,
which approved by
Thai
cabinet on July
2008
- Board of
InvestmentBOI (Thailand) has
planned to put
investment
incentives and
explore
opportunities of
bioplastics
business in
Thailand
- Price sensitive
- Uncompetitive
prices.
No local raw
material
available.
- Lack of serious
environmental
law enforcement
Technology
Economics
Policy
Market
Researcher
Researchers are
working on PLA
polymerization
and mechanical
property
improvement.
Price sensitive
Manufacturing
Plastic converter
industry
in Thailand is
hand on
experience
and existing
machinery
equipments are
suitable or only
small
adjustment
needed to
apply with
biodegradable
plastics
Price uncompetitive.
Limited PLA
producer
and no local
producer
available.
High cost of end
product,
when compare
with conventional
plastics
Environment Policy
Investment Policy
Environment Policy
Investment Policy
Objectives
Research Methodology
Study, interview, collect and analyze the
related data.
Conclusion of the important issues of the
present situation
Meeting to consult with
the GTZ and the NIA
Organization of brainstorming workshops
(SWOT Analysis)
Meeting to consult with
the GTZ and the NIA
Compilation of the results of the
workshops and the revision of the drafted
policies
Domestic Data
1)
Since Thailand has not yet possessed the policies or the measures that are
directly connected with the promotion and the production and usage of bioplastic,
the study team will therefore collect and analyze the following data:
Environmental policies and related regulations, such as policies on the
management of plastic and foam packages.
Relates laws, such as the Act on Revenue Tax and the Consumers
Protection Act.
2) Organizations
Organizations that are related to the promotion of the protection and usage
of bioplastic and the environmental-friendly materials.
The potentiality of the various organizations to become partners in the push
for the production and usage of bioplastic products and the environmentalfriendly materials under the national roadmap for the development of
bioplastic industries.
Others
Qualitative Surveys
Team Project
DISPOSABLE BIOPLASTICS
CONSUMER DISPOSABLES
AGRICULTURAL FILMS
A Market Opportunity Study
April 2008
By: Phil Sarnacke & Stephen Wildes
OMNITECHINTERNATIONAL,LTD
2715 Ashman Street Midland, Michigan 48640
Phone: (989)631-3377
Fax: (989)631-0812
TABLE OF CONTENTS
Executive Summary
TABLES
Table
Table
Table
Table
Table
Table
Table
Table
Table
Table
Table
Table
A
B
C
D
E
F
G
H
I
J
K
L
CHARTS
Chart
Chart
Chart
Chart
Chart
A
B
C
D
E
EXECUTIVE SUMMARY
PART 1 - CONSUMER DISPOSABLE PLASTICS
The demand for bioplastics, both biodegradable and non-biodegradable,
makes it one of the fastest growing thermoplastic product types globally.
Global demand is expected to reach over one billion pounds by 2012.
Currently, the biodegradable segment of bioplastics is the largest segment of
the bioplastics category, but it is projected to be displaced by the nonbiodegradable bioplastics group of products, which may or may not be 100%
derived from biomass. Packaging, disposable food service and fiber
applications are major use areas.
In the United States, the growth of bioplastics is estimated to be 19% per
annum through 2011, reaching a projected consumption in the U.S. of over
600 million pounds. The growth is driven by several factors: 1) large
retailers, such as Wal-Mart and Target, requesting that their suppliers adopt
bioplastics for packaging products they stock, 2) the public concern over the
depletion of petroleum based raw materials, 3) the desire of manufacturing
companies to develop more sustainable raw material sources, 4) the
improvement in properties of bioplastics, 5) state and federal government
support for biobased products, and 6) the more cost competitive relationship
that bioplastics have achieved versus petroleum based plastics.
Polylactic acid polymer (PLA) demand is growing rapidly in both packaging
and fiber applications. Demand for starch based polymers, in a modified form
or blended with another polymer such as PLA for biodegradability or with a
polyolefin such as polypropylene, will continue to grow. Omni Tech estimates
that the growth in demand for starch based plastics will be equal to the
growth in PLA at about 19% per year through 2011, reaching,
conservatively, 180 million pounds.
Among the bioplastic applications, four uses have standout growth
opportunities in the immediate future: 1) biodegradable bags/films, 2)
biodegradable plastic foam cushioning blocks, 3) bioplastic fibers, degradable
and non-degradable, and 4) bioplastic molded products, degradable and nondegradable.
Significant research and development work at several universities on
developing biodegradable bioplastics made from soy protein products (meal,
flour, concentrate, and isolate) in combination with PLA and other
biodegradable plastics is being funded by USB New Uses, and should
continue to be supported. This work is building on past R&D efforts that have
laid the technical ground work for these new projects.
Although past research and development work to develop a bioplastic using
soy protein as a component has not as yet been commercially successful,
DISPOSABLE BIOPLASTICS
PART 1
CONSUMER DISPOSABLE PLASTICS
Phil Sarnacke
INTRODUCTION
The last Omni Tech report on opportunities in the thermoplastic market was in 2001.
At that time agricultural films and polyvinyl chloride (PVC) plasticizer segments were
the focus of the study. Since that time not only have the customers and soy
opportunities changed, but the market prices of many competing petrochemical based
plastics have increased dramatically, making soy based plastic more economically
competitive.
The study will identify the current market size, market growth, competitive products
and opportunities for soy based plastics in the disposable plastics market. This market
segment includes biodegradable/compostable plastics and non degradable plastics
derived from renewable biomass. Opportunities for soy based plastics exist in both
sub classification segments.
Disposable plastics products are those plastic products that are not
designed to last in use for a long period of time. In many cases, mostly
packaging, food service and agricultural applications, they represent a onetime
only use, followed by disposal. Most applications for disposable plastic products
are found in the following market segment categories:
Consumer and Institutional Products; Disposable food service ware including
cups, dinnerware, tableware, kitchenware, drinking straws; luggage, buttons,
hardhats, handbags, apparel; picnic jugs, ice chests, flower boxes, plant pots;
healthcare, medical products and personal care items including combs, brushes,
medical tubing, blood packs, syringes, IV bags; toys and sporting goods (not vehicles)
including liners, fishing line; laboratory supplies; footwear; signs, displays, credit
cards, placemats, ashtrays, mats.
Packaging: Bottles, jars, vials; drums, pails, cans, barrels, buckets; caps, closures,
food containers excluding disposable cups; coating for all types of packaging; flexible
packaging including bags, household and institutional refuse bags and film; boxes and
baskets; personal care packaging products; pallets, crates, spools, reels, bobbins,
tape, strapping, twine
Adhesives - Inks - Coatings: Adhesives and sealants; paper coating and glazing;
printing ink; paints, varnishes, enamels; core binder, foundry facing.
Other (Industrial/Construction) : Agricultural mulch, blasting media.
Current Outlook
In spite of the reasons mentioned in the preceding paragraph, the current demand
outlook for the use of degradable plastics based on renewable (biomass) raw
materials is more promising due to a number of market, societal and technological
developments that favorably impact demand for biodegradable plastic:
In spite of these favorable factors, the amount of biopolymers being used today in
total is small relative to the total market for thermoplastics. One estimate from
Chemical Market Associates, reported in Plastic News, places the total consumed in
packaging, the largest market for degradable bioplastics, at 90 million pounds
worldwide and 35 million pounds in North America.
According to several industry participants (Frederic Sheer, President of Cereplast, Inc,
and William Riesbeck, Vice President of Sales and Marketing for Ex-Tech Plastics,
Inc.), bioplastics must meet the cost performance requirements of the
petroleum based plastics. Hurdles to overcome include:
Government Action
The following ordinance went into effect in San Francisco, California:
Food Service Waste Reduction Ordinance
Effective June 1, 2007, the Food Service Waste Reduction Ordinance requires
that San Francisco restaurants and food vendors serving food prepared in San
Francisco no longer use any polystyrene foam, otherwise known as Styrofoam,
as disposable food ware. The ordinance also requires that any disposable food
service ware or to-go containers be compostable or recyclable for food prepared
and served in San Francisco, unless there is no suitable product that is within
15% of the cost of non-compostable or non-recyclable alternatives
Global Market Size
In spite of the cost performance hurdles mentioned in the preceding list, a recent
report by the European Bioplastics association places global production capacity for
bioplastics, including both biodegradable and non-biodegradable plastics) at 576
million lbs. in 2007 growing to 3,300 million lbs. in 2011. This growth will occur as a
shift occurs among the following three categories (excluding synthetic/nonbiodegradable plastics) of plastic materials:
Synthetic/biodegradable
Bio-based/biodegradable
Bio-based/non-biodegradable
2006
2007
2012
CAGR %
Compost Bags
Loose-fill Packaging
Other Packaging (1)
Miscellaneous (2)
173
152
51
33
242
161
59
54
587
214
48
171
19.4
5.7
23.4
25.0
TOTAL
409
516
1,200
17.3
The rapid predicted change in demand growth of biomaterials is due to the increasing
concern over of the earths hydrocarbon reserves, thus the main driving force behind
sustainable plastics in the 21st century is use of annually renewable resources.
Biodegradability is an advantage in those countries that have an industrial composting
infrastructure in place. However, no biopolymer can sustain a position in the market
place without a competitive cost performance profile and for many applications the
biodegradability attribute has no added value.
Additionally development work continues in the development of durable plastic
products which are usually produced by injection molding and thermoforming
processes.
2003
2007
2011
07-11
CAGR %
45
150
300
19
<1
110
49.5
50
0
NA
95
100
10
NA
260
180
50
NA
640
16
49%
NA
25%
The demand for the most common bioplastics is estimated based on public
announcements by the companies producing the products, usually in conjunction with
an announcement of increased bioplastic production capacity. The high growth rate
projection of 25% assumes that the capacity brought on stream this year and next is
essentially sold out by 2011.
Polylactic Acid - NatureWorks, the major producer of polylactic acid (PLA) polymers
in the U.S., has publicly stated that they will be starting up their second production
train in the 2nd half of 2008 which should give them the full production capacity
previously announced of 300 million lbs. of PLA produced on two production trains.
Polyhydroxyalkonates - The commercial production of Mirel polyhydroxyalkonates
(PHA) is scheduled to start late in 2008. Telles, a joint venture between Metabolix and
Archer Daniels Midland, announced the production capacity to be 110 million lbs.
Another potential producer of PHA, Meredian Inc. will begin production in a pilot plant
facility in 2009. Capacity is expected to be 30 million lbs. Additional plant capacity of
600 million lbs. of PHA is being planned by Meredian.
Starch Polymers - Starch based polymers will continue to be a large bioplastic
product used by itself in a modified form or blended with another polymer such as PLA
for biodegradability or with a polyolefin, such as polypropylene. Omni Tech estimates
that the growth in demand for starch based plastics will be equal to the growth in PLA
at about 19% per year through 2011.
Bio-Polyester - The demand for hybrid bioplastic polyesters (products with both a
petrochemical component and a biomass component) in the polymer backbone will
also grow. BASF a producer of EcoFlex, a biodegradable polyester, and Ecovio, a
blend of PLA and EcoFlex, expects the market for bioplastics to grow at 20%
annually for the next 5 years. DuPont has developed a family of non-biodegradable
polyesters based on 1,3 propane diol derived from corn syrup.
Cellulosic Plastic This product category has a long history of use in the plastics
market. The products include cellulose esters, cellophane and rayon. They are derived
mostly from wood pulp which is reacted with caustic followed by a variety of
petrochemical monomers to produce the final products.
Since cellophane is biodegradable, demand for it is again growing in the packaging
film market.
Consumer and Institutional Products Market Demand by End Use
TABLE C
MARKET DEMAND FOR BIO-BASED PLASTICS
Films /Bags
Ring Carriers1
Loose fill/Foam
Food service
Molded
Fiber
Total
20052
20073
20113
117
40
16
7
28
5
213
200
42
17
17
46
11
333
359
51
20
31
123
50
634
07-11
CAGR3
15.8
4
4
16
28
46
17.5
Demand for bioplastics is accelerating as more supply of all bioplastic types come into
production. This will be especially true in the molded products and film/bags markets.
Plastic ring carriers are used for soft drink bottles, cans and for a variety of individual
serving containers sold as one unit. We assume that the penetration of ring carries is
at saturation and may in fact be losing market share to other unit packaging designs
so that growth will be modest until a biodegradable bioplastic is available at a
competitive price to the photodegradable polyethylene currently used.
Molded products will show the fastest growth driven by the use of PLA blends, the PHA
products and the starch plastic blends with polyolefins.
According to reports in the trade press, PLA fibers are also experiencing rapid growth
in clothing and there is even a small amount of soy protein based fiber being imported
from China also for use in high end clothing.
Packaging
10
natural gas). According to Innovia Films marketing manager, a major issue facing the
introduction of bio-based films in place of petrochemical based films is their current
cost. Additionally, he points out that one of the packaging industries greatest hurdles
for adoption of compostable materials is the lack of curb-side collection and municipal
compositing facilities (a sentiment echoed by Business Development Director of
Heritage Bag, a major producer of biodegradable trash bags).
However, in spite of the hurdles of cost and lack of composting facilities, the growth
experienced by the biodegradable packaging suppliers has been very high.
Within packaging applications the following food packaging areas are receiving
considerable attention:
Fresh-food packaging
Dried snacks and candy
Bakery goods
Water and juice bottles
Meat trays
Coatings for beverage cups
Films and card stock
A recent study from Pira Ltd. estimates that in 2006 biodegradable packaging of fresh
food was the largest end-use food packaging category at 39.6 million lbs. in the US.
The U.S. is the largest single market for biodegradable packaging, where the growth
will continue and is estimated to reach 96.9 million lbs. in 2011.
Large potential new applications for bioplastics and especially degradable bio plastics
include diaper backing, adult incontinence products and landfill covers.
Another bioplastic film application that is showing considerable growth, despite a cost
premium, is the biodegradable plastic bags applications for yard and garden waste
and industrial refuse. One supplier of the industrial biodegradable plastic bags told us
that their production volumes had been doubling each year for the last 3 years, and
was set to double again in 2008. The total bag market, which includes:
11
Protective packaging is also making use of starch based bioplastics that are
biodegradable. The products are formed as foam sheets or loose-fill peanuts. The
major uses are for general impact protection of valuable items such as electronic
equipment components, glass items and generally fragile consumer products. Because
of their ability to dissipate static charge, they are especially useful in packaging
microchips and electronic product susceptible to damage from static electricity. The
bioplastics are made mostly from modified starch. Since they will degrade in water as
well as compost sites, and are cost competitive with expanded polyethylene foams,
the demand for them in growing. The biggest disposal negative comes from the fact
that they are considered a contaminate in the petroleum based plastic recycle streams
and thus, if not disposed of by composting or dissolution in water will end up in a
standard land fill. Waste disposal of loose fill has become an issue for Wal-mart and
its supplier base according to one starch packaging company that attended a recent
meeting at Wal-mart headquarters. The goal is to eliminate all loose fill including
starch based peanuts in favor of green protective packaging and space fillers.
Because of the largest retailer in the U.S. is urging its supplier base to drop loose fill
we see the demand for these products to be growing at rates of 4-5% annually driven
in large part by purchases over the internet and overseas legislation requiring
packaging to be compostable or biodegradable. Offsetting these drivers are
competition from starch based board stock or planks and inflatable bags.
Food Service
This market segment describes those product used to serve food in a fast-food or
causal dinning setting. It includes cutlery, plates, dishes, cups and bowls. Also
included are paper products that have a water roof coating made from a renewable
plastic such as PLA.
At EXPO 2005 Aichi, Japan more than 10 million eating utensils were used at the
food and beverage facilities in the food courts at the EXPO site. This represented
the first time biodegradable plastics have been used for such a large number of
eating utensils at a single event. The disposable utensils were collected by waste
disposal companies which composted the waste and utensils.
Industry contacts by Omni Tech indicated that food service consumed about 17 million
pounds. This end use is expected to have U.S. growth rate of 16% CAGR through
2011. At that growth rate, the volume of bioplastics consumed in 2011 would be
approximately 31 million lbs. The products used in this application include blends of
starch and polylactic acid (PLA), baggase from sugarcane and PLA,
polyhydroxyalkonates, and PLA alone. As an example, a Hong Kong company named
Roots Biopac, has introduced trays made from sugarcane fibers.
Fibers
Fibers made from the new bioplastics are gaining strength, mostly because they are
based on renewable biomass. NatureWorks, the major PLA manufacturer in the U.S.,
has introduced their fiber grade product call Ingeo which is being used in clothing.
Mazda has introduced a biofabric made of 100% PLA for use in automotive interiors.
DuPonts Bio- PDO, 1,3 propane diol from corn syrup, is being incorporated into the
polymer backbone of a polyester resin named Sorona, which is being promoted by
OMNI TECH INTERNATIONAL, LTD.
12
DuPont into textile and carpet fiber applications. Even though it is only partially a
biobased plastic, it is being accepted as a bioplastic by end users looking for a green
product. This is another example of the biobased but not biodegradable type of
bioplastic that will be reaching the market in large quantities in the future; thus, we
see a fast growth rate (46% CAGR) for this category over the immediate future as
production of these biopolymers increases.
13
TABLE D
PRICING of Selected Thermoplastic and Bioplastic Polymers
April, 2008
Polymer Type
Polyethylene
Polypropylene
Polystyrene
Polyester
Polylactic acid
Starch foam
1
Price1
(Cents/lb.)
86-104
92-98
85-95
80-85
95-110
65-75
Comments
(>20 million lbs)
HD LD grades volumes.
Homopolymer
General purpose
PET bottle grade
Very volume dependent
The pricing of starch based plastic foams and polylactic acid are competitive with
estimated pricing of various polyolefin products. Polyhydroxyalkonates are being
quoted at $2.50/pound or higher, which would place them in the engineering plastics
category with polycarbonate and other high performance plastics. Blends of starch
with modified polypropylene have been reported to be cost competitive to
polypropylene homopolymer.
CONCLUSIONS and RECOMMENDATIONS
The bioplastics markets, both bioplastic biodegradable and bioplastic nonbiodegradable, are the fastest growing product type categories of plastics
globally with an expected demand in 2012 of over a billion pounds.
14
Biodegradable bags/films,
Biodegradable plastic foam cushioning blocks,
Bioplastic fibers, degradable and non-degradable
Bioplastic molded products, degradable and non-degradable
Several large retailers such as Wal-Mart and Target are actively requesting
that their product suppliers use as much biobased packaging as possible
while still protecting the products during shipping.
RECOMMENDATIONS
Additional projects using soy protein products combined with nonbiodegradable biomass plastics and petroleum based plastics and targeted
at specific large volume applications in fibers, molded products and films
should be supported.
15
APPENDIX
CHART A
POLYMERS FROM RENEWABLE RESOURCES
Polymers
from renewable
resources
from
plants
from
microorganisms
starch,
starch
derivatives
polylactic acid
(PLA)
cellulose,
cellulose
derivatives
polyhydroxyalkanoates
(PHB, PHA)
from
animals
chitin,
chitosan
proteins, e.g.
casein, gelatin
Thermoplastic Processing
lignin
16
CHART B
BIO-BASED FEEDSTOCKS
BIO-BASED FEEDSTOCKS
Annually Renewable Bio FeedStocks
Cellulosics &
Lignocellulosics
Products:
Cellulose
(Cellophane)
Cellulose
Derivatives
(CA, CAB)
Engineered
Wood Products
Starches
Examples:
Corn
Potato
Sugar cane
Products:
Thermoplastic
Starch
Starch Foams
Starch Graft
Copolymers &
Reactive
Other
Polysaccharides
Examples:
Pectin
Chitin
Levan
Pullulan
Examples:
Soybean
Lesquerella
Rapeseed
Products:
Biodiesel
Lubricants
Polyols Urethanes
Plasticizers/Process
Aids
Solvents
Unsaturated
Polyester Resins
17
Proteins
Examples:
Zein
Soy Protein
Biodegradable Thermoplastics
Trade Name
Rilsan nylon 11
EcoFlex
Cereplast
Hybrid Resins
DaniMer Scientific
DuPont
Seluma
BIOMAX,(35%)
/SORONA EP
Innovia Films
Cerenol polyol
Selar VP (40%)
Hytrel RS (2550%)
NatureFlex
Polymer Family
Biodegrade
na
co-polyester polybutylene
succinate/ terephthalate
modified Starch+ PLA, starchmodified polyolefins
polyester
polyesters (polytrimethylene
terephthalate )/1,3
propanediol(PDO)
yes
cellophane
yes
na
yes
yes
Meredian
GS Pla
ECO-Foam
NatureWorks
PLA / Ingeo
MATER-BI,
Eastar Bio Ultra
Nodax H
poly(3-hydroxybutrate-co-3hydroxyhexanoate (PHBH))
SoyPlus
soy protein
Mirel
polyhydroxyalkonate (PHA)
films, bottles,
rigid
packaging
licenses other
producers
yes
Mitsubishi Chemical
National Starch
NatureWorks(Cargill)
Novamont
yes
18
Applications for injection molded Mater-Bi include cutlery, pencil sharpeners, rulers,
cartridges, toys, plant pots and toys for pets, using a starch-based material obtained
from cellulose. Combs made of Mater-Bi have the additional advantage of being
anti-static, eliminating accumulation of electrical charge on conventional combs.
Mater-Bi loose fillers are predominantly made of starch, and are expanded using
water. It is recommended for packaging pharmaceutical products, laboratory
equipment, consumer goods and mail order goods.
They are purported to be completely biodegradable and water-soluble, resilient and
anti-static, and have excellent shock-absorbing, elastic properties.
Wave by Mater-Bi is starch-based, and is expanded using water, extruded into
sheets and then assembled into blocks that can be cut into any shape. Wave by
Mater-Bi has a robust and resilient closed-cell structure; sheets and blocks are
available in different sizes, with densities from 30 to 400 kg/m3.
TABLE F
UNIT OF
MEASURE
MATER-BI
PP
PS
ASTM 1238
ASTM D638
g/10 min
MPa
6-30
15-35
0.9-9
25-37
19-24
31-40
ASTM D638
20-150
ASTM D638
ASTM D955
MPa
%
600-5000
0.08-1
40-400
10001600
1.2-1.6
29003200
0.1-0.6
ASTM D1238
ASTM D822
ASTM D822
ASTM D638
g/10 min
MPa
%
MPa
8-10
18
130
1400
ASTM D1238
ASTM D882
ASTM D882
ASTM D638
ASTM D1938
2-4
20-50
200-600
100-600
20-120
20-120
LDPE
0,1-6
20-30
150-600
150-300
70
70
ASTM E96
g/10 min
MPa
%
MPa
N/mm
N/mm
gr 30mm/m2
24H
250-1000
15
TEST
MATER-BI for INJECTION MOLDING
MFI
Breaking load (tensile strength at break)
Breaking extension
(% elongation at break)
19
PROPERTIES
Physical properties
Melt flow rate (g/10 min)
Density (g/cm3)
Haze
Amorphous grades
Yellowness index
Water absorption
Mechanical properties
Tensile strength at yield
(MPa)
Elongation at yield (%)
Flexural Modulus (MPa)
Youngs Modulus (MPa)
Notch Izod (KJ/M2)
NatureWorks
PLA
1.24
2.2
transparent
20-60
Polystyrene
General Purpose
1.04
Polyethylene
terephthalate
1.3-1.4
transparent
0.16
53
36-52
55-75
10-100
350-450
1.0-2.2
3,150-3,240
2800-3100
50-15-
Thermal Properties
HDT (C)
Melt Temperature Tm
Glass Transition
Temperature Tg
Heat Transfer Coefficient
(W/mK)
44-55, 135
(crystalline)
140-152 C
56.7-57.9 C
87-97C
260 C
75 C
0.24
In addition to being biodegradable, PLA has other properties such as high optical
clarity, good mechanical properties, gas and water barrier properties.
Technical hurdles for PLA include a low glass transition temperature of 60 C which
might be improved if PLA were composed of both D- and L- lactic acid. This
compositional change would probably increase the heat resistance as high as 175 C.
Additionally, PLA needs better impact strength, and improved gas barrier properties.
Currently, PLA is in short supply, It is estimated by PURAC Biochem that with
improvements in PLA supply and quality that the market can grow to over several
hundred thousand tons in 10 years.
20
POLYHYDROXY ALKANOATES
Polyhydroxy alkanoates is the generic term for a family of polyester polymers. Specific
members include: poly 3-hydroxybutyrate co-4- hydroxybutyrate, polydroxy
butyrate- co-3- hydroxyvalerate. Metabolix is the major developer of technology for
producing polyhydroxyalkonates from bacteria and corn sugar. They have formed a JV
with Archer Daniels Midland to produce the biodegradable plastics called Mirel.
Together they are building a production plant in Iowa that will be on stream in late
2008.
Metabolixs Mirel family of plastics range in properties from rigid to tough and highly
elastomeric to soft and tacky. They can be made as resins or aqueous dispersions with
excellent film forming characteristics. Robust in use yet biodegradable, they offer a
renewable and environmentally friendly alternative in many applications now served
by synthetic plastics, including fiber, film, molded goods, extruded products,
adhesives and coatings.
Applications to date include holiday gift cards sold by Target. According to Metabolix,
potential applications include single use (disposable) items such as coffee cups,
dinnerware, containers for cosmetics, food and detergent. Agricultural applications
include degradable plant pots, stakes, erosion control netting and mulch film. The
companies are expecting to charge a premium for the plastic. Receiving a premium for
low value items such as disposable dinnerware or horticultural applications would be
very unusual except in those political geographies that are banning non-degradable
plastic items.
POLYESTERS
TABLE H
ECOFLEX BIODEGRADABLE PLASTIC WITH HIGH FUNCTIONALITY vs LDPE
UNIT
TEST METHOD
ECOFLEX F
LDPE
Density
g/cm3
ISO 1183
1.25-1.27
0.922-0.925
ISO 1183
2.5-4.5
0.8-1.2
Melt viscosity
MVR 190 C, 2.16
kg
ml/10min
Melt point
DSC
110-120
111
Shore D hardness
ISO 868
32
48
ISO 806
80
96
21
UNIT
TEST METHOD
ECOFLEX F
LDPE
Transparency
ASTM D 1003
82
89
N/mm2
N/mm2
%
ISO 527
ISO 527
ISO 527
35/44
36/45
560/710
26/20
300/600
J/mm
DIN 53373
24
5.5
ml/(m2d bar)
g/(m2d)
DIN 53380
DIN 53122
1400
170
2900
1.7
Tensile strength
Tensile stress at
break
Tensile strain at
break
Fracture energy
(Dynatest)
Transmission
rates:
Oxygen
Water vapor
Film thickness um
WVT g/m2 d 23
C,
85% r.h 100 um
20
15
32
12
85
35
83
48
Ecoflex F
Ecoflex F + wax
Ecoflex F + talc
Ecoflex F + talc,
1:4
Tensile strain at
break in
extrusion direction
N/mm2
41
39
25
70
22
Cellulose Polymers
Cellulosic polymers are produced by chemical modification of natural cellulose. The
main representatives are cellophane, cellulose acetate and regenerated cellulose for
fibers, e.g. Viscose rayon. Both cellulose and starch have glucose as their basic
monomer unit but the polymers differ in the linkage between the glucose units and in
the configuration of their polymer chains. Celluloses configuration provides an
opportunity to form stronger hydrogen bonds as well as a close interaction with other
polymeric structures such as lignin, pectin, hemicelluloses and proteins. Because of
this mixed polymer morphology, cellulose is more resistant to hydrolysis than is
starch.
NatureFlex Cellophane
NatureFlex films are based on renewable resources (wood-pulp from managed
plantations) and use novel heat-seal resins on each side. The films are static free
and offer a super wide heat-seal range for outstanding machine performance. The
films offer good gas barrier properties and the coatings can be tailored to provide
varying degrees of moisture barrier, depending on the needs of the wrapped product.
Soy Protein Thermoplastics
Although no bioplastics currently contain soy protein, several projects supported by
the United Soybean Board have as their objective the development of a soy protein
containing bioplastic or water soluble polymer. The projects are:
TABLE I
CURRENT USB SOY PROTEIN PROJECTS
USB Project
Number
7426
Organization
Univ. of Wisconsin Madison
8425
8476
Washington State
University
Battelle Memorial Inst.
8437
8457
8459
Description
Development of Soy Protein blended
with modified starch to form a
biodegradable plastic
Soy Meal as reactive filler in
elastomeric matrices
Development of Soy Protein
biodegradable Plastics
Soy protein polymer as super
absorbent water soluble polymer
Soy Protein fiber development
Soy Protein fiber spinning
23
PART 2
AGRICULTURAL FILMS
STEPHEN G. WILDES
24
LDPE
LL/LDPE Blends
HDPE
2000
40%
10%
50%
2007
0%
60%
40%
5. Film disposal Still an unresolved issue Recovery cost escalation, reduce landfill
availability, very little recycling
6. Biodegradable mulch films
Market need higher than ever
None commercially available in U.S.
Two new films being introduced
o Novamont, Novara, Italy Mater Bi based on polymerized corn
starch
o Telles (ADM/Metabolix JV), Lowell, MA Mirel based on corn
fructose
25
26
Food security
- Populations are growing and individual calorie intake rising
Arable farm land in cultivation is static
Improved yields are essential
- In 1950 one hectare fed 2 people
- In 1995 one hectare fed 4 people
- In 2025 one hectare will feed 5 people
Water scarcity
Move to reduce trade subsidies
27
CHART C
Japan
1%
Latin America
5%
NAFTA
5%
Europe
20%
Rest of World
8%
Total demand 7.8 billion pounds
CHART D
Silage (1.5)
19%
Mulch (3.2)
41%
Greenhouse (3.1)
40%
Total demand 7.8 billion pounds
28
CHART E
NAFTA (160)
5%
Latin America (160)
5%
TABLE J
WORLD MULCH FILM MARKET
Million Pounds
AREA
1999
North America
U.S.
Mexico
Latin America
Europe
Spain
Italy
Germany
France
Others
E. Europe
China
Rest of World
TOTALS
150
2007
160
90
60
90
410
60
100
160
640
70
60
50
50
100
310
850
200
1,220
1,950
290
3,200
29
LD/LLDPE Blends:
Gauge 0.9 - 1.0 mils
Width 64
Roll 4,000 ft, 102 lbs/roll
Pricing - $1.25 - $1.30/lb, $127/roll
HDPE:
Gauge 0.6 - 0.7 mils
Width 64
Roll 7,000 ft, 107 lbs/roll
Pricing - $1.50 - $1.70/lb, $180/roll
Specialty Films:
Embossed, barrier, metalized and coextruded versions of above films at premium
prices. Film colors black, white, clear, silver, red, blue, green, yellow
30
GAUGE (mils)
2000
1.0
0.7
1.25
2007
0.9-1.0
0.6-0.7
PRICE/LB
2000
$0.75
$1.00
$0.55
2007
$1.25-1.30
$1.50-1.80
MARKET
SHARE
2000
2007
10%
60%
50%
40%
40%
0%
$1.60-2.10
$1.60-2.85
$1.25-1.80
The use of LD/LLDPE blend mulch film is growing and becoming dominant. The use of
LLDPE imparts additional stretch and strength to the film. HDPE film is stronger than
LDPE and can be downgauged further but it does not stretch. Mulch film is typically
stretched when applied in the field. Too weak a film will tear under the tension necessary
for its application.
HDPE
2007
LD/LLDPE BLENDS
Pliant Corp. Chicago, IL
Olefinas Guatemala
Ginegar Israel
TRM Los Angeles, CA
EPA Mexico
Climagro Montreal, Canada
OMNI TECH INTERNATIONAL, LTD.
HDPE
Hilex Poly Co. Hartsville, SC
(purchased Sunoco products)
31
This is a new European voluntary industrial quality standard that includes plastic films for
agricultural use. It covers product specifications for mulching and silage films and includes
ISO 9002 standards.
ECONOMICS
The cost of row crop farming has increased significantly since 2000. Price escalation of ag
films, pesticides and fertilizers has occurred due to petrochemical feedstock price inflation
crude oil and natural gas. Prices of mulch films have risen 70% since 2000. Typical
mulching costs have increased from $130 per acre to $200 per acre since 2000.
Mulch film disposal costs for field collection (labor), trucking and disposal (landfill tipping
fees) have, concurrently, increased from $50 to $100 per acre on an average depending
on location.
Film disposal remains an unresolved and costly problem. Landfilling waste film is a
declining alternative as landfill space becomes less available. Film recycling has been
attempted but it was not cost-effective. In Florida, the largest mulch film user state, film is
typically burned in the field. This practice will not be allowed much longer.
32
The obvious unmet market need is for an effective biodegradable mulch film that will meet
standard performance requirements at a price not to exceed film disposal costs. To date,
no commercial biodegradable mulch film is available in the U.S. However, two companies
have been developing these films and one of them is being marketed in Italy and eastern
Canada. These films will be described later in this study in the State of the Art section.
MARKET OUTLOOK
The use of plastic mulch films will continue to grow globally, especially in the intensive
cultivation of high value row crops such as tomatoes, strawberries and tobacco. External
conditions will continue to challenge the farmer and accelerate the use of mulch films.
FARMER CHALLENGES
Demand for cost-effective biodegradable mulch films would be strong across most world
row crop markets. Farmers would probably be willing to pay a significant price premium
for biodegradable films to eliminate the film disposal problem. Biodegradable films could
reinvigorate the U.S. market and help make the American farmer more competitive.
A successful biodegradable mulch film could also create additional market opportunities
beyond fruits, vegetables and tobacco.
33
Telles, Lowell, MA
Metabolix, Inc. & ADM Joint Venture
Mirel
Clinton, Iowa resin plant 110 million pounds start up scheduled for late 2008
Pricing Expected to be 2.5 to 3 times LL/LDPE blend films - $3.00 - $3.50 per pound
34
MARKET OPPORTUNITY
U.S. market is 60 million pounds, 5% of a global market of 3.2 billion pounds. This market
has stabilized after declining due to film downgauging and the loss of some crop farming to
Mexico. The U.S. market is poised to resume growth with the availability of higher
performance mulch films. World market demand, meanwhile, continues to increase
significantly. While some countries could not afford premium priced films, Europe
definitely could.
BIODEGRADABLE MULCH FILMS
Two new biodegradable mulch films Novamonts MaterBi and Telles Mirel have
been developed and are in early market introduction. They are based on corn starch and
corn fructose respectively as described in the State of the Art section of this report.
Mention has been made by these companies that each film resins contains vegetable
oils. This will be investigated further to determine if soybean oil and derivatives are and
can be utilized.
Development of soy protein-based films will require considerable cost and time. Earlier
research at Iowa State University demonstrated that such films are feasible. An invitation
for development was presented to the American Society for Plasticulture at their recent
Congress on March 9, 2008.
RECOMMENDATIONS
Omni Tech International, Ltd. recommends that the USB New Uses Committee consider
funding support for future projects involving the development of soy-based biodegradable
agricultural mulch films. USB funding support was not recommended in the 2000 market
study update. However, demand for biodegradable mulch films has increased
considerably since then and the market will now support premium priced biodegradable
films if they perform well and eliminate the need for mulch film collection and disposal. An
RFP (Request for Proposal) focused on soy protein-based biodegradable mulch films sent
to key universities and mulch film manufacturers could stimulate R&D efforts.
35
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(Plastic)
(Bioplastic) (Biodegradable plastic)
(biodegradable)
cellulose collagen casein polyester (starch)
(monomer) (lactic acid)
polymerization (polymer)
5
1. (Photodegradation)
(UV) (Ketone group)
(Free radical)
2. (Mechanical Degradation)
3. (Oxidative Degradation) )
(hydroperoxide, ROOH)
(stabilizing additive) ROOH RO OH)
(Hydroperoxpide,
ROOH) (Free radical)
4. (Hydrolytic Degradation)
2 (Catalytic hydrolysis) (Non-Catalytic Hydrolysis)
2 (External Catalytic
Degradation) (Internal catalytic degradation)
2 (Enzyme) Depolymerase lipase esterase glycohydrolase
(Non-enzyme) (alkaline metal) (base)
(acid)
(Carboxyl Group)
5. (Biodegradation) 2
endo-enzyme
exo-enzyme
2
(ultimate biodegradation) (Mineralization)
(biomass)
++++++++++++++++++++++++++++++++++++++
2
1. Polylactic acid (PLA)
2. Polyhydroxybutyrate (PHB)
PLA
PLA
NEC FOMA(R)N70iECO
CD/DVD
Polyhydroxybutyrate (PHB)
PHB Maurice Lemoigne Alcaligenes eutrophus
acetyle CoA
PHB
PHB Alcaligenes eutrophus 3
3-ketothiolase Acetyl CoA Acetoacetyl-CoA
acetoacetyl-CoA reductase acetoacetyl-CoA R(-)-3-hydroxybutynl-CoA
PHA synthase polymerizes R(-)-3-hydroxybutynl-CoA PHB
PHB
: http://en.wikipedia.org/wiki/Polyhydroxybutyrate
http://web.mst.edu/~microbio/BIO221_2005/A_eutrophus.html
http://www.rsc.org/education/teachers/learnnet/inspirational/resources/3.1.11.pdf
http://www2.mtec.or.th/th/special/biodegradable_plastic/type_de_plas.html
http://opac.tistr.or.th/Multimedia/STJN/4901/4901-1.pdf
http://dspace.library.drexel.edu/bitstream/1860/2878/1/Singh_Vishesh.pdf
http://en.wikipedia.org/wiki/Bioplastic
Bioplastics
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4: describe, preparation, base, cleavage, cleaved end, coupling, double bond, fatty acid chain, intermediate for polymers, natural oil
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5: production, biomass, process, bioplastics, bacterial, gasify, hydrogen, organic material, recycle, suit 11
6: field, extract, ex, medicine, high, invention, example, min, dwg, place 11
7: encode, produce, gene, select, group, consist, coding sequence, construct, genetic construct, genome 10
8: plasma, use, apparatus, embodiment, produce, useful, manufacturing, assess, biological response modifier, concentration 10
9: combination, additive, comprise, contain, make, increase, biopolymer, coat, extrusion, inorganic particle 9
10: similar, form, include, composition, cured silane-modified oil, degree of unsaturation, disclosure, facilitate, fat, free radical
initiator 6
(Unclustered Publications) 24
(Patent Assignees X IPC)
Bioplastics
(IPC) A61K 8/72 A61L 27/00
Cross Correlation Map (Inventors) (IPC-R)
2 1 6 2 3 Bioplastics /
0.25-0.75 1
90
1 450
1 100 / .. 2550 . 85,000
/ 21 1,800 /
1.78 / 650 /
1
Ref : , ,
Polylactic Acid PLA Polyhydroxyalcanoates PHAs
2
poly (butylene adipate-co-terephthalate) polymer
BASF 2
""
""
(PLA :
Polylacticacid) (Terramac)
PLA
(polymerization)
(PET) (PE)
(NatureWorks LLC)
PLA
""
120 200
PET
(NEC) 701 (Forma N701
iECO)
(Vaio)
(PS) 3 (MP3)
10
1% (Hiroyuki Mori)
2000-2002 (minidisc)
2002-2003 90 %
(AIBO)
2004-2006
(Dummy card) (IC card)
(.)
10 2551 (TOP TEN
INNOVATIVE BUSINESS 2008)
(bioplastics hub)
10
.
1. (Biotechnology)
(health biotechnology)
2. (agri-biotechnology) (Natural Products)
(nutraceutical
& functional food) (pharmaceutical & cosmeceutical)
(novel food)
""
(polymer) poly
mer polymer
polymer monomer monomeric
unit polymer
polymer
(
Dacron )
1.
2.
3.
plasticizers ( )
hydrophobic
(reuse) (recycle) (reduce)
1.
2.
(feed monomer)
(final plastic
finished product )
1.
2.
3.
cellulose collagen casein polyesters
monomer lactic
polymerization lactic polymer
polylactic acid (PLA)
polylactic acid (PLA)
polylactic acid
Sony
NEC polylactic acid 20
2 NEC
14
1
2005