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Produccin
Deduccin de ecuaciones a partir de
la ecuacin de compresibilidad
David Usia
c=
1
p
( )
c=
1 o
o p
( )
c=
1
p
1 V
a partir de c= V p
( )
( )
( )
( ) ( )
dVo
d o
(2)
m
o
(3)
( ) ( )x
T
( m )
o
d o
e) Derivando en funcin de
( V p ) =( p ) x ( m )
o
(4)
2
o
c=
o
1
x
Vo
p
o
o
x
m
p
( ) ( ) x (m )
2
o
( ) ( ) x ( m )
2
o
c=
1 o
o p
o
1
x
o
p
( )( )
( )
( )
( V p ) =( p ) x dd V
o
(2)
(3)
( ) ( )
d ( V sc x o )
d o
e) Derivando en funcin de
V o
o
=
p T
p
( ) ( ) x (V
T
sc
) (4)
c=
o
1
x
Vo
p
( ) ( ) x (V
T
sc
o
1
x
V sc x o
p
) ( ) x (V
T
sc
o
1
x
o
p
( )( )
1 V o
1 o
1
=
=
V o p T o p T
o
( ) ( ) ( )( p )
2.-Deducir
c=
1 o
o p
( )
c=
a partir de
1 V
V p
( )
( )
dV
x
(
)
( )
d
T
(2)
m
o
(3)
( V p ) =( p ) x
o
( m )
o
d o
e) Derivando en funcin de
V o
o
=
p T p
( ) ( ) x ( m )
f) Remplazando (4) en (1)
2
o
(4)
c=
o
1
x
Vo
p
o
o
x
m
p
( ) ( ) x (m )
2
o
( ) ( ) x ( m )
2
o
h) Simplificando tenemos
c=
o
1
x
o
p
( )( )
c dp=
pb
ob
c o dp=
p
ob
o o
ob
es mayor que
o
ob
( )
c o ( pb p )
o
ob
n) Despenando
c o ( pb p )
o= ob e
o= ob exp [ c o ( p b p ) ]
1 1 dZ
P Z dP
( )
3.-Deducir
a partir de
c=
1 V
V p
1 dv
(1)
v dP
ZnRT
(2)
P
dP
P dP
P2
dV
ZnRT 1 dZ
ZnRT 1
=
dP
P
Z dP
P
P
1 dV 1
=
V dP V
1 dZ
ZnRT 1
(
([ ZnRT
)
P
Z dP
P )P]
( )
1 dV
1 ZnRT
=
V dP ZnRT
P
P
)[( 1Z dZdP P1 )]
dP
P dP
P2
dV
ZnRT 1 dZ
ZnRT 1
=
dP
P
Z dP
P
P
1 dV 1
=
V dP V
1 dZ
ZnRT 1
(
([ ZnRT
)
P
Z dP
P )P]
1 dV
1 ZnRT
=
V dP ZnRT
P
P
)[( 1Z dZdP P1 )]
1 dV 1 1 dZ
=
V dP P Z dP
f) Remplazando de la ecuacin (1) la compresibilidad
1 1 dZ
c=
P Z dP
( )
1
P
dZ
=0
dP