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Mxico. *Corresponding author, Email: mgr@uaq.edu.mx
Abstract
The aim of this paper is to investigate key aspects related to the thermal conductivity of sandcement mortar mixed with polymethylmethacrylate (PMMA) microspheres. The assessment
was done with tests, following ASTM guidelines. Previously, cement particles were bond
permanently to the surface during PMMA microspheres synthesis. The embellishments of
PMMA microspheres increases the resistance of thermal conductivity of the mortar, shown by
this pioneering method substantially.
Keywords: Mortar, PMMA microspheres, saving energy.
1. Introduction
Currently, many people noticed the effect on climate change as a result of greenhouse gasses
emissions (Lashof & Ahuja, 1990). A sustainable development satisfies the requirements of
people without committing the capacity of future generations, conserving the environmental
resources using energy, water, and raw materials efficiently (Bruntland, 1987). As a priority,
the generation of new materials increases the productivity of resources and offer a more
efficient use of them (Velzquez-Castillo, Galvn-Ruiz and Rivera-Muoz 2010). Nowadays
is more noticeable the development of a sustainable technology committed to developing new
construction materials. The enhancement of thermal properties offers some advantages for the
common users, such as important savings on the cost of energy consumption. Wellbeing is
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essential in buildings and homes where people spend considerable time (Yeladaqui, 2010).
Comfort in construction depends on factors such as proper lighting, ventilation, and a pleasant
thermal environment. This last one depends primarily on construction materials and
intelligent systems being used (Galvn-Ruiz et al. 2009).
The appropriate use of thermal insulation in buildings contributes to reducing energy costs
(Al-Homoud, 2005). The magnitude of saving energy using thermal insulation varies
according to the type of building, climate conditions, building location and insulation
materials (Budaiwi & Abdou, 2013). In general, energy saving has a boundless impact on
environmental quality, use of resources, and human comfort. Hence, the thinking in the
building industry is no longer about should insulation be used or in what way and how much,
but to look ahead to new building material for energy saving (Galvn-Ruiz and Zaleta, 2013).
Research emphasizes thermal analysis to study various types of inorganic and organic
construction materials (Velzquez-Castillo et al. 2012), more extensively in the examination
of inorganic materials (Ramachandran, Paroli, Beaudoin, & Delgado, 2002).
Alternatively, mortars are broadly construction materials used by a huge number of cultures
disseminated worldwide. With the accelerated technological development, mortars have
evolved until obtaining a well-documented mix by their applicability and physical properties
(Galvan-Ruiz & Velzquez-Castillo, 2011). These spread over for building works as a lining
and final additions to walls (Ohama, 1995). Formerly, development of polymer-modified
mortars resulted in supplies currently used in the construction industry (Afridi, Ohama and
Iqbal 2003). Several studies on different materials were examined for improvement on walls
with compounds containing polymers (MacMullen et al. 2011; Bhutta, Ohama and Tsuruta
2011; Kong et al. 2013), as well for reducing water absorption and improving thermal
insulation saving energy (Saikia & de Brito, 2012). Several polymer additives modify the
properties of mortars (Lanzn and Garca-Ruiz, 2008; Gadea et al. 2010), or decrease the
density and modify the hydrophobic properties (Zhao et al., 2011; Afridi et al., 1995;
Frattolillo et al., 2005). This research then will be looking at the thermal efficiency by
studying the effect of polymer microspheres embedded in mortar for saving energy.
252
ASTM C 1437 Standard Test Method for Flow of Hydraulic Cement Mortar.
ASTM C191-08 Standard Test Methods for Time of Setting of Hydraulic Cement by
Vicat Needle
ASTM C266-08 Standard Test Method for Time of Setting of Hydraulic-Cement Paste
by Gillmore Needles.
ASTM C1403 Standard Test Method for Rate of Water Absorption in Masonry
Mortars.
ASTM C177-10 Standard Test Method for Steady-State Heat Flux Measurements and
Thermal Transmission Properties using the Guarded Hot Plate Apparatus.
Table 1. Percentages of Sand + Cement + PMMA according to the total addition of the
mixture.
Proportion (m3)
PMMA
PMM
microspheres Cement
Sand
A
volume (m3)
Cement
Sand
weight (kg)
PMMA
Cem
ent
Sand
PMM
A
0%
2.750
6.194
0.000
10%
2.475
5.575
0.028
20%
2.200
4.956
0.056
30%
1.925
4.337
0.084
40%
1.650
3.717
0.112
253
2.2 Characterization
2.2.1 Scanning Electron Microscopy (SEM)
The morphology and topology of samples were analyzed by scanning electron microscopy
using a JEOL JSM 5600, accelerating voltage 20 kV, and secondary electron images
recorded. A very fine layer of gold was placed on the sample surface, to prevent electrostatic
charge accumulation.
2.2.2 Compressive Strength Test
Standard Test Method for Compressive Strength of Hydraulic Cement Mortars ASTM C109
/C109M-08. This test method agrees with the measurement of the compressive strength of
hydraulic cement mortars using 50 mm cube specimens.
2.2.3 Water Absorption of Masonry Mortars
Standard Test Method for Rate of Water Absorption if Masonry Mortars ASTM C1403. This
test method provides a standardized laboratory procedure for determining the relative water
absorption by capillary uptake (wicking) characteristics of masonry mortars.
2.2.4 Flow of fresh mortar
Standard Test Method for Flow of Hydraulic Cement Mortar ASTM C 1437. This test method
determines the flow of hydraulic cement mortars, and of mortars containing cemented
materials other than hydraulic cement.
2.2.5 Time of setting by Vicat apparatus method
Standard Test Methods for Time of Setting of Hydraulic Cement by Vicat Needle ASTM
C191-08. The test method used in this research is the manually operated standard Vicat
apparatus.
2.2.6 Time of setting by Gillmore Needles method
Standard Test Method for Time of Setting of Hydraulic-Cement Paste by Gillmore Needles
ASTM C266-08. This test method covers the determination of the time of setting of hydraulic
cement paste using the Gillmore needles.
2.2.7 Thermal conductivity
Standard Test Method for Steady-State Heat Flux Measurements and Thermal Transmission
Properties using the Guarded Hot Plate Apparatus ASTM C177-10. This test method
contributes to the general design requirements necessary to construct and operate a suitable
254
Figure 1 shows the morphology and dimensions of the polymer microspheres. These spheres
have different diameter sizes from 15 to 140 m. It is also evident that the spheres are hollow.
Each microsphere is made of a thin PMMA shell with small air volume inside. This structure
makes this material extremely light and reduces the mortar density by the production of multiple
small air cells, which also increase the thermal conductivity resistance, making the material a
par to well-known traditional mixtures used as a thermal insulator. Several cement particles
added during the microsphere synthesis process improved the adhesiveness with the mortar
constituents. Figure 1 also demonstrated the key aspect of cement particles that hardly adhered
to microspheres surface, improving the physical response of the interphases of the admixture.
255
Figure 2 shows the mortar matrix appearance obtained after the compression test of the
samples; some microspheres looked broken and deflated and hence collapsed due to this test.
The spreading of the microspheres of various diameters is heterogeneous, contributing to a
more efficient development of the mixture. Dispersion of microspheres is significant
depending on the volume of the sand-cement mixture thus improving the mortar thermal
properties, including air inside.
256
257
Figure 3. Compression experiment on the test cubes according to guideline ASTM C109,
including PMMA microspheres from 0 to 40%, test age 7 and 28 days.
The results show an inversely proportional relation between the percentage of added
microspheres and the magnitude of the compression strength, for which the final effect will be
the maximum percentage of added PMMA that will allow an appropriate workability and, at
least, the minimum compression strength specified by ASTM directive. The optimal ratio
results at 40% content of PMMA microspheres and 8 Mpa compression strength, at 28 day's
test.
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decreasing due to the increment in the fluidity properties, originated by the water reduction
effect of growing of PMMA microspheres content.
259
20.620
10
22.250
20
24.550
30
23.050
40
22.250
50
19.920
60
18.025
260
269
10
251
20
244
30
239
40
233
50
228
60
215
140
260
10
130
255
20
130
250
30
125
240
40
125
220
50
120
215
60
120
215
261
10
20
30
40
4. Conclusions
The increase of PMMA microspheres transforms the mortar by decreasing its density while
modifying its mechanical properties, workability, and air content. The material is comparable
to lightweight mortars prepared with other traditional materials. The results obtained by
mixing cement with different ratio of aggregate and PMMA microspheres show noticeable
good thermal properties. On the other hand, decreasing compressive strength of the optimal
formulation proposed to agree with ASTM guidelines that unlock a valuable compatibility in
this research. The microspheres also provide a hydrophobic property to the mortar. The
linkage of cement particles to the surface during microspheres synthesis is a significant aspect
of adhesion to the mortar bulk. The microspheres decrease the density by the inclusion of micro-air
bubbles in the mortar bulk. Therefore, the air inclusion reduces significantly the thermal conductivity
increasing thermal insulation. The enhancement of thermal efficiency by the effect of PMMA
262
microspheres embedded in this innovative lightweight mortar maintain more stable room
temperatures and save energy.
Acknowledgements
The authors acknowledge to PROINSA for support this work and to Mr. Rene Plaza for
proofreading.
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