Professional Documents
Culture Documents
DOI 10.1617/s11527-015-0603-9
ORIGINAL ARTICLE
B. J. Naden (&)
Chemistry & Biotechnology. Pera Technology Ltd, Pera
Business Park, Nottingham Road, Melton Mowbray,
Leicestershire LE13 0PB, UK
e-mail: b.naden@peratechnology.com
AE
AAS
UV
MPI
1 Introduction
Surfactant foaming agents are added to cement and
concrete formulations for the production of low
density materials, often used in applications that
require low strength void filling. Surfactants are
amphiphilic molecules that reduce the interfacial
tension between hydrophilic and hydrophobic phases
and increase contact surface area, enabling association
of these otherwise incompatible phases. The behaviour of a surfactant at the interface can be predicted
by the hydrophiliclipophilic balance (HLB), a semiempirical scale based on the relative molecular mass
of hydrophilic functionality compared to lipophilic
groups. A surfactant with a high HLB will have a large
hydrophilic group compared to the hydrophobic
component and this will influence its behaviour at an
oil (or hydrophobic solid particle)/water (or hydrophilic particle) phase boundary, although this
partitioning is independent of the overall size of the
molecule.
Surfactants promote the production of foams in
aqueous media by stabilizing the interface of the
hydrophobic gas phase and the hydrophilic aqueous
phase (Fig. 1). A surface tension gradient is established by the presence of the surfactant at the interface,
2 Experimental
2.1 Materials
The organoclay used in this study was a methylbenzyl
di-hydrogenated tallow ammonium chloride modified
montmorillonite (MB2HT-MMT) provided by Laviosa
Chimica Mineraria S.p.a. (Livorno, Italy). Powders
were dried at 70 C for a minimum of 24 h.
The following technical grade surfactants were
used for organoclay stabilisation in water:
Nonionic C10 fatty alcohol polyoxyethylene(6)
(AE)
from
Croda
Chemicals,
UK.
Non-adsorbed surfactant concentration was determined by loss of mass of the centrifuge supernatant
at 150 C. Approximately 510 g of sample was
placed in the pan of a thermal balance (MS-70
moisture analyzer, A&D Weighing) and reduction of
mass was monitored until rate of loss was less than
0.1 % per minute. The remaining weight was used to
determine equilibrium concentration and subsequently
adsorbed amount using mass balance calculations.
measured and was therefore used as being representative of the concentration of the surfactant sample.
3.2 Adsorption isotherms
Isotherms for the adsorption of AOS to MB2HTMMT, determined by RP-HPLC and by gravimetric
4 Conclusions
A-olefin sulphonate, a surfactant frequently used as a
foaming agent for cement and concrete, displays a
relatively high adsorption affinity for organically
modified nanoclay that is added to the cement
formulation for enhanced strength of the cured material. Although the maximum adsorbed amount of AOS
at the organoclay surface is considerably less than
those of the surfactants used as dispersing agents, this
References
1. van den Tempel M (1960) The function of stabilizers during
emulsification. 3rd Int Congr surf Act, Cologne 2:573
2. Ramamuthy K, Kunhanandan Nambiar EK, Indu Siva
Ranjani G (2009) A classification of studies on properties of
foam concrete. Cem Concr Compos 31:388396
3. Yakovlev G, Keriene J, Gailius A, Girniene I (2006) Cement based foam concrete reinforced by carbon nanotubes.
Medziagotyra 12:147151
4. Kuo W-YK, Huang J-S, Lin C-H (2006) Effects of organomodified montmorillonite on strengths and permeability of
cement mortars. Cem Concr Res 36:886895
5. Aly M, Hashmi MJ, Olabi AG, Messeiry M, Hussain AI
(2011) Effect of nano clay particles on mechanical, thermal
and physical behaviours of waste-glass cement mortars.
Mater Sci Eng A 528:79917998
6. Hakamy A, Shaikh FA, Low IM (2014) Characteristics of
hemp fabric reinforced nanoclaycement nanocomposites.
Cem Concr Compos 50:2735
7. Yeganeh JK, Sadegh M, Kourki H (2008) Recycled HIPS
and nanoclay in improvement of cement mortar properties.
Malays Polym J 3:3850
8. Tadros TF (2005) Adsorption of surfactants and polymeric
surfactants at the solid/liquid interface. In: Applied surfactants: principles and applications. Wiley-VCH, Weinheim,
pp 85114
9. Cohen Stuart MA, Scheutjens JH, Fleer GJ (1980) Polydispersity effects and the interpretation of polymer adsorption isotherms. J Polym Sci 18:559573
Villiams DA (eds) Foyes principles of medicinal chemistry, 7th edn. Wolters Kluwer, Philadelphia, pp 2960
12. Kronenberg B, Holmberg K, Lindman B (2014) Surface
chemistry of surfactants and polymers. Wiley, Chichester,
pp 147