Professional Documents
Culture Documents
Acids-Base titration
Arrhenius theory
a)
Lewis theory
b)
d)
e)
f)
g)
h)
i)
c)
a)
b)
c)
Bronsted-Lowry theory
a)
j)
k)
l)
ii)
iii)
3. Solubility equilibria
a)
i)
Define
i)
solubility
ii)
molar solubility
iii)
b)
Calculate Ksp
c)
d)
e)
IONIC EQUILIBRIUM
7.1 Theory of Acids and Bases
BASES
Feel slippery
WHAT IS ACID ?
WHAT IS BASE ?
Acidbase definition:
Arrhenius
Svante August Arrhenius (1859-1927). Swedish chemist.
BrnstedLowry
Johannes Nicolaus Brnsted (1879-1947). Danish chemist.
Thomas Martin Lowry (1874-1936), English chemist.
Lewis theories
Gilbert Newton Lewis (1875-1946). American chemist.
+
+
H2O(l)
H2O(l)
H3O+(aq)
CH3COO(aq)
NO3(aq)
+
H3O+(aq)
Na+(aq)
OH(aq)
BRNSTEDLOWRY ACIDBASE
DEFINITION
Acid: Any species that donates H+ (proton donor)
EXAMPLE:
CH3COOH(aq)
acid
H2O(l)
base
CH3COO(aq)
conjugate
base
+ H3O+(aq)
conjugate
acid
H2O(l)
acid
NH4+(aq) + OH(aq)
conjugate
conjugate
acid
base
CH3COOH(aq) + CN(aq)
acid
base
CH3COO(aq) + HCN(aq)
conjugate
conjugate
base
acid
A +
acid
:B
AB
base
new covalent bond
acid
H
N
B
F
H
H
N
H
base
Lewis base
EXAMPLE
Identify the conjugate acidbase pairs:
a) HCOOH(aq) + H2O(l)
b) H2O(l) + F(aq)
c) H2PO4(aq) + CO32(aq)
d) H2O(l) + SO32(aq)
HCOO(aq) + H3O+(aq)
OH(aq)
HF(aq)
HCO3(aq) + HPO42(aq)
OH(aq) +
HSO3(aq)
Ans: EXAMPLE
A = acid
B = base
cA = conjugate acid
cB = conjugate base
a) HCOOH(aq) + H2O(l)
b) H2O(l) + F(aq)
HCOO(aq) + H3O+(aq)
OH(aq)
HF(aq)
Ans: EXAMPLE
A = acid
B = base
cA = conjugate acid
cB = conjugate base
c) H2PO4(aq) + CO32(aq)
d) H2O(l) + SO32(aq)
HCO3(aq) + HPO42(aq)
OH(aq) +
HSO3(aq)
STRONG ACID
Dissociate completely (100 %, = 1.0) into ions
in water
HA(l) + H2O(l) H3O+(aq) + A(aq)
Ka extremely large
EXAMPLE:
HNO3(aq)
H2O(l)
H3O+(aq)
NO3(aq)
WEAK ACID
Dissociate very slightly ( < 1.0) into ions in water
HA(aq) + H2O(l)
H3O+(aq) + A(aq)
Ka very small
EXAMPLE:
HCN(aq) + H2O(l)
H3O+(aq) + CN(aq)
Hydrohalic acids: HF
Oxoacids: HClO, HNO2 and H3PO4
Organic acids: CH3COOH and C6H5COOH
Other: HCN and H2S
STRONG BASE
Dissociate completely (100 %) into ions in water
Kb extremely large
M2O or MOH:
M: Group (1) metal (Li, Na, K, Rb, Cs)
MO or M(OH)2:
M: Group (2) metal (Ca, Sr, Ba)
NaOH(aq)
Na+(aq)
OH(aq)
WEAK BASE
Dissociate very slightly into ions in water
Kb very small
EXAMPLE:
..
NH4+(aq) + OH(aq)
EXAMPLE
Classify each of the following compounds as
a strong acid, weak acid, strong base, or
weak base, or species with negligible acidity.
a)
b)
c)
d)
e)
f)
g)
h)
(CH3)2CHCOOH
KOH
(CH3)2CHNH2
HNO2
H2SO4
HPO42
CH4
CH3NH3+
Ans: EXAMPLE
a)
(CH3)2CHCOOH
b)
KOH
c)
(CH3)2CHNH2
d)
HNO2
e)
H2SO4
f)
HPO42
g)
CH4
h)
CH3NH3+
pH = - log [H+]
If [H+] , pH .
pOH is defined as the negative logarithm (log) of
the hydroxide ion.
concentration of OH- is measured using pOH.
pH SCALE
pH = log [H3O+]
pOH = log [OH]
The higher [H3O+], the lower pH
The higher the [OH], the lower pOH
pH MEASUREMENT
Acidbase indicator
pH paper (& color chart)
pH meter
pH of a neutral solution = 7.0
pH of an acidic solution < 7.0
pH of an basic solution > 7.0
AUTOIONIZATION OF WATER
Water dissociates into ions very slightly
H2O(l) + H2O(l)
H3O+(aq) + OH(aq)
KW = [ H3O+ ] [ OH ]
= 1.0 x 1014 (at 25oC)
KW : ion product constant for water
In pure water at 25oC;
[H3O+] = [OH] = 1.0 x 107 M
lower [OH]
Higher [OH]
lower [H3O+]
[H+] [OH-] = Kw
Both ions are present in all aqueous systems
In acidic solution,
In basic solution,
KW = [ H3O+ ] [ OH ]
[ H3 O + ] =
KW
[ OH]
[ OH ] =
KW
[H3O+ ]
H2O(l)
0.020 M
0
after:
(100% dissociated)
pH = log [H3O+]
= log [0.020]
= 1.70
H3O+(aq)
0
0.020 M
Cl(aq)
0
0.020 M
Ba2+(aq)
0
0.00035 M
0
2OH(aq)
0
0.00035 M
0.00070 M
(100% dissociated)
[ H3O+ ] =
KW
[OH ]
1.0 x 1014
0.00070
= 1.43 x 1011 M
pH = log [H3O+]
= log (1.43 x 1011) = 10.85
EXAMPLE
a)
b)
Ans: EXAMPLE
Ans:
Ans:EXAMPLE
EXAMPLE
Ans: EXAMPLE
Ans: EXAMPLE
H3O+(aq) + A(aq)
[ H3 O + ] [ A ]
[ HA ]
EXAMPLE:
HCN(aq) + H2O(l)
Ka =
H3O+(aq) + CN(aq)
[ H3O+ ] [ CN ]
[ HCN ]
H+(aq) = H3O+(aq)
EXAMPLE:
HCN(aq) + H2O(l)
Ka =
H3O+(aq) + CN(aq)
[ H3O+ ] [ CN ]
[ HCN ]
or
HCN(aq)
H+(aq) + CN(aq)
Ka =
[ H+ ] [ CN ]
[ HCN ]
stronger acid
higher [H3O+]
larger Ka
smaller Ka
lower % HA dissociated
weaker acid
EXAMPLE
Nitrous acid, HNO2, is a weak acid that formed in the
stomach when nitrite food preservatives encounter
stomach acid. There has been some concern that
this acid may for carcinogenic products by reaction
with proteins.
Write the chemical equation for the equilibrium
ionization of HNO2 in water and the appropriate
Ka expression.
Ans: EXAMPLE
BH+(aq) + OH(aq)
[ BH+ ] [ OH ]
Kb =
[ B]
EXAMPLE:
NH3(aq) + H2O(l)
Kb =
NH4+(aq) + OH(aq)
[ NH4+ ] [ OH ]
[ NH3 ]
N2H4(aq) + H2O(l)
(CH3)2NH(aq) + H2O(l)
NH4+(aq) + OH(aq)
N2H5+(aq) + OH(aq)
0(CH3)2NH2+(aq)
+ OH(aq)
EXAMPLE
Hydrazine is a weak base. It is a poisonous substance
thats sometimes formed when chlorine bleach is
added to an aqueous solution of ammonia.
Write the equation for the reaction of hydrazine
(N2H4) with water and write the expression for
its Kb.
Ans: EXAMPLE
HA(aq) + H2O(l)
H3O+(aq)
At equilibrium,
[ H 3O + ] [ A ]
[ HA]
A-(aq)
cx ~ c
Ka =
x2
c
x2 = Ka.c
x
= (Ka . C)
= [H3O+]
HA(aq) + H2O(l)
At equilibrium,
HA(aq)
A-(aq)
H3O+(aq)
-c
+c
+c
c - c
= c( 1- )
Ka = [A-] [H3O+]
[ HA ]
[ H 3O + ] [ A ]
Ka =
[ HA]
(c ) (c )
c(1 )
c 2
(1 )
Ka <<< 1, therefore: 1 - 1
Ka = c 2
= (Ka
/ c) 1/2
HB+(aq) + OH-(aq)
HB+(aq)
OH-(aq)
Change (M)
-x
+x
+x
Equilibrium conc.(M)
c- x
At equilibrium,
Kb = [BH+] [OH]
[B]
At equilibrium,
= ( x ) ( x)
( c-x )
Kb =
cx ~ c
x2
c
x2 = Kb.c
= Kb . c
= [OH-]
HB+(aq) + OH-(aq)
B(aq)
HB+(aq)
OH-(aq)
-c
+c
+c
c( 1- )
Kb = [HB+] [OH]
[B]
(c ) (c )
c(1 )
c 2
(1 )
Kb = c 2
= (Kb
/ c) 1/2
Assumptions:
[H3O+] from autoionization of H2O is
negligible
A weak acid has a small Ka, So:
[HA]initial [HA]dissoc [HA]initial
Approximation
method or quadratic
method??
Apply the
approximation
method if Ka or
Kb 10-5
HOW??
Example if Ka or Kb is
1.8 x 10-5 M then use
approximation method if
6.8 x 10-4 M use quadratic
HOW??
B.Weak Base
Example 1 :
Kb
use approximation
method because
Ka is 1.8 x 10-5
CHECK!
=
Ka or Kb x 100
c
= 1.8 x 10-5 x 100
0.15
= 1.09 % less than 5%
(use approximation method )
Exercise :
1. Calculate the percentage of HF molecules ionized in
(a) a 0.10 M HF solution the Ka of HF is 6.8 x 10 -4
use quadratic
because Ka of HF is
6.8 x 10 -4 greater
than 10-5
(7.9 %)
CHECK!
Ka or Kb x 100
c
= 6.8 x 10 -4 x 100
0.10
= 8.24% more than 5%
(use quadratic)
EXAMPLE 1
What is the pH of a 0.5 M HF solution (at 25oC)?
Ka of HF = 7.1 x 104
Ans: EXAMPLE 1
Ans: EXAMPLE 1
EXAMPLE 2
Calculate:
a) The basedissociation constant, Kb,
for the fluoride ion (F)
Ka of HF = 6.8 x 104
b) The aciddissociation constant, Ka,
for the ammonium ion (NH4+)
Kb of NH3 = 1.8 x 105
Ans: EXAMPLE 2
Ans: EXAMPLE 2
Kb =
NH4+(aq)
+ OH(aq)
Conjugate acid
[ NH4+ ][ OH ]
[ NH3]
NH3(aq)
[ NH3 ] [ H3O+ ]
[ NH4+]
+ H3O+(aq)
NH4+(aq)
+ OH(aq)
NH4+(aq) + H2O(l)
NH3(aq)
+ H3O+(aq)
base
Conjugate acid
acid
Conjugate base
2H2O(l)
Kb x Ka =
[ NH4+ ] [OH-]
[ NH3]
H3O+(aq) + OH(aq)
x
[ NH3 ] [H3O+ ]
[ NH4+]
Ka x Kb = Kw
pKa + pKb = pKw
= [ H3O+ ][OH]
Ka AND pKa
pKa = log Ka
Kb AND pKb
pKb = log Kb
Kb
pKb
4.74
8.77
9.42
14.82
base-dissociation
constant (Kb)
The value of Ka or Kb can be used to distinguish the
relative acidity strength of weak acid and weak base.
Ka (pKa ) = [H+] , thus pH (more acidic)
Kb (pKb ) = [OH-] , thus pH (more basic)
Example :
Acid
pKa
Base
pKb
CH3COOH
4.74
C6H5NH2
9.37
HCOOH
3.76
NH3
4.74
Relative acidity,
HCOOH > CH3COOH
Relative basicity,
NH3 > C6H5NH2
EXERCISE 1
a) Lactic acid, HC3H5O2, is responsible for the
taste of sour milk. At 25oC it Ka = 1.4 x 104.
What is the Kb of its conjugate base, the
lactate ion, C3H5O2?
b) Methylamine, CH3NH2, resembles ammonia in
odor and basicity. Its Kb = 4.4 x 104.
Calculate the Ka of its conjugate acid
ANS:
a) 7.1 x 1011
b) 2.3 x 1011
EXERCISE
EXERCISE224
Propanoic acid (C2H5COOH)(monoprotic)
is an organic acid whose salts are used to
retard mold growth in foods.
What is the [H3O+] of 0.10 M C2H5COOH ?
Note: Ka = 1.3 x 10-5.
ANS:
[H3O+] = 1.1 x 10-3 M
7.1
EXAMPLE
20
EXERCISE
3
7.1
ANS:
a) [H+] = 4.0 x 108 M
b) [OH] = 6.0 x 107 M
EXERCISE 4
1. A 0.20 M solution of weak acid HX is 9.4% dissociated.
Using this information, calculate H3O+ , X- and HX
concentrations at equilibrium. Determine also pH and
Ka for HX acid.
(1.88 x 10-2 M, 0.1812 M, 1.73, 1.76 x 10-3)
SALT HYDROLYSIS
Salt hydrolysis: reaction of an anion or cation of a
salt (or both) with water.
General equation of neutralization :
HX
+ MOH
(acid)
(base)
MX
+ H 2O
(salt)
(water)
M+
X-
MOH(aq) + H+(aq)
HX(aq) + OH-(aq)
EXAMPLE:
CH3COONa(s)
H2O
Na+(aq) + CH3COO(aq)
Species exist:
Na+ and CH3COO
H3O+ and OH from autoionization of H2O
(negligible)
Salt hydrolysis:
Na+ + H2O What happen ?
CH3COO + H2O What happen?
What is the effect to the acidity of the solution?
H2O
Na+(aq) + Cl(aq)
H2O
Na+(aq) + CH3COO(aq)
CH3COOH(aq) + OH(aq)
H2O
NH4+(aq) + Cl(aq)
H2O
Na+(aq) + Cl(aq)
or
NaCl(aq)
Na+(aq) + Cl(aq)
EXAMPLE
Write the hydrolysis salt equation:
a)
b)
c)
d)
e)
f)
g)
h)
i)
NH4I
CaCl2
KCN
LiClO4
CH3NH3+ NO3
NaOCl
KCl
NH4NO3
NaNO2
Ans: EXAMPLE
EXAMPLE
Ans: EXAMPLE
35
7.1
EXAMPLE
Ans: EXAMPLE
35
7.1
BUFFER SOLUTION
How does blood maintain a constant
pH in contact with countless cellular
acidbase reaction ?
The normal of pH of blood is 7.4
Severe illness or death can results
from sustained variation just a few
tenths of a pH unit
from this
normal value
BUFFER SOLUTION
is a solution which has the ability to maintain its pH
when a small amount of strong acid or strong base
is added to the solution.
It must contains:
Acidic component
can react with added [OH]
Basic component
can react with added [H3O+]
Most common buffer components:
base - Conjugate acid pair (of weak base) OR
acid - Conjugate base pair (of weak acid)
Addition of 1 M HCl
Addition of 1 M HCl
Solution of mixture of
1 M CH3COOH and
1 M CH COONa
Addition of 1 M NaOH
Addition of 1 M NaOH
EXAMPLE
Which of the following are buffer systems?
(a) KF / HF
(b) KBr / HBr
(c) Na2CO3 / NaHCO3
Ans: EXAMPLE
BUFFER SOLUTION
Two types of buffer solutions :
i. Acidic buffer solution (pH<7)
ii. Basic buffer solution (pH>7)
EXAMPLE:
CH3COOH
CH3COO
acid (H+)
H+(added) + CH3COO-
CH3COOH
OH-(added) + CH3COOH
CH3COOCH3COOH
CH3COO- + H2O
CH3COOCH COOH
CH3COO- 3
Addition of H3O+ :
H3O+(aq) + CH3COO(aq)
CH3COOH(aq) + H2O(l)
CH3COO- (aq) + H+
CH3COOH (aq)
CH3COOCH3COOH
CH3COOH
CH3COO-
Addition of OH :
OH(aq) + CH3COOH(aq)
CH3COO(aq) + H2O(l)
CH3COO- (aq)
CH3COOCH3COOH
CH3COOH
CH3COO-
EXAMPLE 1 38
EXERCISE
7.1
Ans: EXAMPLE 1
HENDERSONHASSELBALCH EQUATION
For weak acid:
HA(aq) +
Ka =
A(aq) + H3O+(aq)
H2O(l)
[A] [ H3O+]
rearrange
[HA]
[ H3O+] = Ka x [ HA]
[A]
pH
pKa
log
[ HA]
[A]
[ Conjugate base]
[weak acid]
HENDERSONHASSELBALCH EQUATION
For weak base:
NH3(aq) +
Kb =
H2O(l)
rearrange
[NH4+][OH-]
[NH3]
log [OH-]
pOH
NH4+(aq) + OH-(aq)
[OH-] = Kb x [ NH3]
[NH4+]
= log Kb log
pKb
+ log
[NH3]
[NH4+]
[ Conjugate acid]
[weak base]
EXAMPLE241
EXAMPLE
7.1
a)
b)
Ans:
EXAMPLE
EXAMPLE
41 2
7.1
EXAMPLE
41 2
Ans:
EXAMPLE
7.1
EXAMPLE
41 2
Ans:
EXAMPLE
7.1
EXAMPLE349
EXAMPLE
7.1
Ans:
EXAMPLE
EXAMPLE
49 3
7.1
Ans:
EXAMPLE
EXAMPLE
49 3
7.1
Example :
EXERCISE 1
Ans: EXERCISE 1
Ans: EXERCISE 1
Ans: EXERCISE 1
Ans: EXERCISE 1
7.2 :
ACID-BASE
TITRATION
KEYWORDS
titration
end point
equivalence point
titration curve
indicators
ACIDBASE TITRATION
A solution of accurately known concentration
is added gradually to another solution of
unknown concentration until the chemical
reaction (neutralization) between the two solution
is complete.
ACIDBASE TITRATION
Burette:
Concentration of solution inside:
known (EXAMPLE: NaOH(aq))
Indicator:
(EXAMPLE:
phenolphthalein)
Before titration
begin
After titration
(at the end point)
Conical flask:
Concentration of solution inside:
unknown (EXAMPLE: CH3COOH(aq))
INDICATOR
A weak organic acid that has different color
than it conjugate base
Color changes occurring over a specific and
relatively narrow pH range
pH RANGE
Range over which the indicator changes from
the acid color to the base color
EXAMPLE:
pH range
Phenolphthalein
8.3 ~ 10.0
Methyl orange
3.1 ~ 4.4
Methyl red
4.2 ~ 6.3
acidic
in
between
basic
TITRATION CURVE
3 types of acid-base titration :
Strong Acid Strong Base
Weak Acid Strong Base
Strong Acid Weak Base
pH range
Phenolphthalein 8.3 ~ 10.0
Methyl red
4.2 ~ 6.3
Volume of NaOH
added (mL)
pH range
Phenolphthalein 8.3 ~ 10.0
pH
Methyl red
4.2 ~ 6.3
pH range
pH
4.2 ~ 6.3
EXAMPLE
Sketch titration curves for the following
acidbase titrations:
a) HCl versus NaOH
b) HCl versus CH3NH2
c) CH3COOH versus NaOH
In each case, the base is added to the acid
in a conical flask. Your graph should show
pH on the yaxis and volume of base added
on the xaxis.
Ans: EXAMPLE
a) Titration curve: HCl versus NaOH
pH
7.00
equivalence
point
Volume of
NaOH added
Ans: EXAMPLE
b) Titration curve: HCl versus CH3NH2
pH
buffer region
< 7.00
equivalence
point
Volume of
NaOH added
Ans: EXAMPLE
Titration curve: CH3COOH versus NaOH
pH
equivalence
point
> 7.00
buffer region
Volume of
NaOH added
EXERCISE
EXERCISE130
7.1
pH range
Phenolphthalein
8.2 10.0
Methyl orange
3.2 4.2
Bromothymol
blue
6.0 7.6
phenol red
6.8 8.4
colour change
KEYWORDS
solubility
molar solubility
solubility product (Ksp)
precipitation
Q
Sugar (solute)
In max. amount
SOLUBILITY OF SLIGHTLY
SOLUBLE IONIC COMPOUNDS
Assumption: The small amount of a slightly
soluble ionic compound that dissolves in water
also dissociates completely into ions
EXAMPLE:
Slightly soluble PbCl2(aq)
100% dissociates into ions
Pb2+
(aq)
PbCl2(s)
2Cl
(aq)
PbCl2(s)
Pb2+(aq) + 2Cl(aq)
Pb2+(aq) + 2Cl(aq)
Ag2S(s)
2Ag+(aq) + S2(aq)
Ag+(aq) + Cl(aq)
Ksp =
[Ag+] [Cl]
EXAMPLE
Write the ionproduct (Ksp) expression for each
of the following:
a)
b)
c)
d)
e)
f)
Silver carbonate
Barium fluoride
Copper(II) sulfide
Iron(III) hydroxide
Barium phosphate
Tin(II) sulfide
Ans: EXAMPLE
Ans: EXAMPLE
Ans: EXAMPLE
Solubility
EXAMPLE:
MgCO3(s)
Mg2+(aq) + CO32(aq)
PbSO4(s)
Pb2+(aq) + SO42(aq)
EXAMPLE 1
Silver bromide, AgBr, is the lightsensitive
compound used in nearly all photographic film.
The molar solubility of AgBr is 7.1 x 107 M.
at 25oC. Calculate Ksp for AgBr at this
temperature.
ANS:
5.0 x 1013
Ans: EXAMPLE 1
EXAMPLE 2
The solubility of silver carbonate is
0.032 mol L1 at 20oC. Calculate the Ksp
of silver carbonate.
ANS:
1.3 x 104
Ans: EXAMPLE 2
EXAMPLE 3
The solubility of calcium sulfate is found
experimentally to be 0.67 g/L.
Calculate the value of Ksp for calcium sulfate.
(Molar mass of CaSO4 = 136.2 g/mol)
ANS:
2.4 x 105
Ans: EXAMPLE 3
Ans: EXAMPLE 3
EXAMPLE 1
What is the molar solubility of AgCl in
pure water at 25oC?
Ksp of AgCl = 1.8 x 1010
ANS:
1.3 x 105 mol L1
Ans: EXAMPLE 1
EXAMPLE 2
Calculate the molar solubility of PbCl2.
Ksp = 1.6 x 105
ANS:
1.6 x 102 M
Ans: EXAMPLE 2
EXERCISE
EXERCISE130
7.1
EXAMPLE 1
Will a precipitate of CaSO4 form in a solution
if the Ca2+ concentration is 0.0025 M and the
SO42 concentration is 0.030 M ?
(Ksp of CaSO4 = 2.4 x 105)
ANS:
Precipitate will form until Qsp = Ksp
Ans: EXAMPLE 1
EXAMPLE 2
What possible precipitate might form by
mixing 50.0 mL of 1.0 x 104 M NaCl with
50.0 mL of 1.0 x 106 M AgNO3? Will it form?
(Ksp of AgCl = 1.8 x 1010)
ANS:
Qsp = 2.5 x 1011
AgCl precipitate will not form
Ans: EXAMPLE 2
Ans: EXAMPLE 2
Ans: EXAMPLE 2
Ans: EXAMPLE 2
Add CrO42
Pb2+(aq) + CrO42(aq)
Pb2+(aq) + CrO42(aq)
= 2.3 x 10-13
Add CrO42
PbCrO4
Pb2+
CrO42
PbCrO4
Pb2+
CrO42
PbCrO4
EXAMPLE 1
What is the molar solubility of AgBr in
(a) pure water
(b) 0.0010 M NaBr ?.
Ksp of AgBr = 7.7 x 1013
ANS:
a) 8.8 x 107 M
b) 7.7 x 1010 M
Ans: EXAMPLE 1
Ans: EXAMPLE 1
EXAMPLE 2
Calculate the solubility of silver chloride
(in g/L) in
a)
b)
pure water
a 6.5 x 103 M silver nitrate solution
Ksp of AgCl = 1.6 x 1010
ANS:
a) 1.8 x 103 g/L
b) 3.6 x 106 g/L
Ans: EXAMPLE 2
Ans: EXAMPLE 2
Ans: EXAMPLE 2
Ans: EXAMPLE 2
EXAMPLE130
EXERCISE
EXERCISE
7.1
Kidney Stone
Ca2+(aq) + C2O42(aq)