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Enhancing the
performance of 1K PU
flooring & balcony
systems using
oxazolidine latent
hardeners
Enhancing the
performance of
1K PU flooring &
balcony systems
using oxazolidine
latent hardeners
case study
Introduction
Polyurethane coatings are highly versatile and have a
wide range of properties such as toughness and
impact resistance whilst still exhibiting good flexibility
and crack bridging characteristics.
Using aliphatic isocyanates as the curing mechanisms
for polyurethanes not only contributes to these
properties, but produces coatings with outstanding
appearance, durability and protection.
Polyurethane coatings based on aliphatic isocyanates
are well known for their non-yellowing properties
upon ageing thanks to;
1. The lack of a phenyl group this makes
polyurethane coatings prepared from aliphatic
isocyanates less prone to oxidation than those
prepared with an aromatic hardener.
2. The resistance of the urethane bond when
exposed to UV light.
In addition, incorporating the oxazolidine helps provide the applicators with systems that reduce the return-toservice time through the promotion of faster through cure.
This study investigated the impact on the cure and film properties of blending an oxazolidine latent hardener,
Incozol 4, with an aliphatic polycarbonate prepolymer, Incorez 705. The latent hardener (Incozol 4) was
combined with the control prepolymer (Incorez 705) at approximately 4% (w/w).
Dealing with moisture ingress
It is vitally important when handling PU prepolymer mixes with oxazolidine latent hardeners that moisture
ingress is minimised. Good practice recommends nitrogen purging of all mixing reactors and minimum
exposure to atmospheric moisture during handling.
Control
Inc 4
Time/Hours
20
15
15
10
Touch-Dry Time
Walk-On Time
Control
Shore D Hardness
90
Inc 4
80
70
60
50
40
30
20
10
0
Clear
12
Paint
Control
Inc 4
10
8
6
4
2
D. Chemical Resistance
Incorporating Incozol 4 into the system improves the resistance to many chemicals including dilute acids,
alkalis and hydrocarbon based reagents.
Chemical Resistance
Stain Resistance
HCI
5
Coffee
5
3
H2O
NaOH
Inc 4
Control
Shoe
Polish
Inc 4
Control
Ketchup
Acetone
IPA
Red
Wine
Mustard
EtOH
E. Stability
The change in viscosity was measured for unopened containers of PU prepolymer (Incorez 705) and with the
addition of Incozol 4 at approximately 4% (w/w).
Stability at elevated temp. (40C)
12000
Control
Inc 4
Viscosity (cps)
10000
8000
6000
4000
2000
0
10
20
30
40
50
60
Days
Control
Inc 4
Viscosity (cps)
10000
8000
6000
4000
2000
0
10
20
30
Days
40
50
60
Guide Formulations
Durable clear topcoat based on Incorez 705 prepolymer and Incozol 4 latent hardener
Materials
Supplier
Incorez 705
380.00
Incorez
Incozol 4
15.66
Incorez
Bannersolve C573
45.84
Samuel Banner
BAS 125
68.60
Samuel Banner
DBTDL
0.15
Akcros
Tinuvin 292
0.50
Ciba
Tinuvin 1130
0.50
Ciba
Total
500.19
Properties
% Solids
77.12
Application
Brush/Roller/Float
420
13
Specific Gravity
0.998
VOC (g/l)
222
Durable floor paint based on Incorez 705 prepolymer and Incozol 4 latent hardener
Materials
Supplier
Incorez 705
161.20
Incorez
Incozol 4
5.80
Incorez
Filler TiO2
62.49
Tioxide
Barytes B10
223.44
DBTDL
0.59
Akcros
BAS 125
40.05
Samuel Banner
Tinuvin 292
0.81
Ciba
Tinuvin 1130
0.81
Ciba
10.02
Clariant
Total
505.81
Properties
% Solids
84.18
Application
Brush/Roller/Float
4800
8.5
Specific Gravity
2.92
VOC (g/l)
158
4.0
6,000
Density (g/cm)
1.05
Colour (Gardner)
% Solids
80
14
Control
Inc 4
12
Time/Hours
10
8
6
4
2
0
Touch-Dry Time
Walk-On Time
120
Control
Inc 4
Shore D Hardness
100
80
60
40
20
0
The aliphatic prepolymer, Incorez 718 (control), was cured by moisture alone and with the addition of an
oxazolidine latent hardener, Incozol 4. Addition of the oxazolidine into the system significantly increased the
hardness.
D. Stability
The change in viscosity was measured for unopened containers of PU prepolymer (Incorez 718) and with the
addition of Incozol 4 at approximately 3.5% (w/w).
Control
Inc 4
700
Viscosity (cps)
600
500
400
300
200
100
0
10
20
30
40
50
60
Days
500
450
400
Viscosity (cps)
350
300
250
200
150
100
50
0
10
20
30
Days
10
40
50
60
Guide Formulation
Clear balcony coating based on Incorez 718 prepolymer and Incozol 4 latent hardener
Materials
Supplier
Incorez 718
379.86
Incorez
Incozol 4
15.95
Incorez
Bannersolve C573
45.82
Samuel Banner
BAS 125
68.57
Samuel Banner
DBTDL
0.75
Akcros
Tinuvin 292
2.50
Ciba
Tinuvin 1130
2.50
Ciba
Total
515.95
Properties
% Solids
77.12
Application
Brush/Roller/Float
280
Specific Gravity
0.981
VOC (g/l)
222
8.5
4500
Density (g/cm)
1.04
Colour (Gardner)
% Solids
70
Conclusion
The data generated from the study demonstrates the advantages of introducing oxazolidine latent hardeners
into 1K PU flooring & balcony systems.
Firstly, the ability of Incozol latent hardeners to act as moisture scavengers ensures that the reaction between
any moisture present and the isocyanate is prevented, thereby preventing the generation of carbon dioxide gas
which would result in coating defects.
Secondly, the addition of an oxazolidine latent hardener into the formulation will promote faster through cure
than that achieved by moisture alone. This is due to the ability of the latent hardener to hydrolyse quickly and
crosslink the PU prepolymer in preference to the water and isocyanate reaction.
Thirdly, introducing an oxazolidine latent hardener allows the formulator to use a prepolymer with reduced
isocyanate content. Typically, the isocyanate level can be reduced by as much as 10-15%.
Oxazolidine latent hardeners, such as Incozol 4, are therefore ideal for use in 1K PU flooring & balcony systems
where they help produce flexible, hard wearing coatings.
11
Oxazolidines
Polyurethane dispersions
Polyurethane prepolymers
Incorez Limited
Incorez Corporation
79 Bradley Street
Preston Lancashire
Middleton Connecticut
06457 USA
e: info@incorez.com
e: info@incorez.com
w: www.incorez.com
w: www.incorez.com
ISSUE 1 - 03/11