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Revision: 12.01.2011
2 Hazards identification
Hazard description:
Xi Irritant
3 Composition/information on ingredients
Chemical characterization
Description: Mixture of substances listed below with nonhazardous additions.
(Contd. on page 2)
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Dangerous components:
CAS: 471-34-1
calcium carbonate
EI4ECS: 207-439-9
CAS: 111-46-6
2,2'-oxybisethanol
Xn; R 22
EI4ECS: 203-872-2
Danger:
3.1.O/3
CAS: 9004-62-0
Hydroxyethyl starch
EI4ECS: 217-576-6
T,
Xi; R 23/24/25-36/37/38
Danger:
3.1.O/2, 3.1.D/2, 3.1.I/2, 3.2/2, 3.3/2A, 3.8/3
CAS: 55965-84-9
mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and
2-methyl-2Hisothiazol-3-one [EC no. 220-239-6] (3:1) mixture of: 5chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-4isothiazolin-3-one [EC no. 220-239-6] (3:1)
T,
C,
4; R 23/24/25-34-43-50/53
Danger:
3.1.O/2, 3.1.D/2, 3.1.I/2, 3.4.S/1;
3.2/1B
Warning:
4.1.C/1
Additional information:
For the wording of the listed risk phrases refer to section 16.
CAS: 7732-18-5
water, distilled, conductivity or of similar purity
EI4ECS: 231-791-2
CAS: 13463-67-7
titanium dioxide
EI4ECS: 236-675-5
10-25%
2.5%
2.5%
2.5%
25-50%
10-25%
5 Fire-fighting measures
Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Protective equipment: 4o special measures required.
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Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
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Fluid
According to product specification
Characteristic
Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 100C
Flash point:
4ot applicable.
Self-igniting:
Danger of explosion:
23 hPa
Density:
95 -100 KU
Solvent content:
Organic solvents:
Water:
VOC (EC)
0.1 %
35.6 %
0.9 g/L
Solids content:
49.8 %
11 Toxicological information
Acute toxicity:
Primary irritant effect:
on the skin: Cause mild irritation
on the eye: 4o irritating effect.
Sensitization: Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version:
Irritant
Sensitisation May cause sensitisation by skin contact.
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12 Ecological information
General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
13 Disposal considerations
Product:
Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Uncleaned packaging:
Recommendation: Disposal must be made according to official regulations.
Recommended cleansing agents: Water, if necessary together with cleansing agents.
14 Transport information
Land transport ADR/RID (cross-border)
ADR/RID class: Maritime transport IMDG:
IMDG Class:
Marine pollutant: 4o
Air transport ICAO-TI and IATA-DGR:
ICAO/IATA Class: U- "Model Regulation": -
15 Regulatory information
Philippines Inventory of Chemicals and Chemical Substances
471-34-1 calcium carbonate
13463-67-7 titanium dioxide
111-46-6 2,2'-oxybisethanol
7631-86-9 silicon dioxide, chemically prepared
21645-51-2 aluminium hydroxide
9004-62-0 Hydroxyethyl starch
9036-19-5 Polyethylene glycol octylphenyl ether
330-54-1 diuron(ISO)
50-00-0 formaldehyde
10605-21-7 carbendazim (ISO)
26530-20-1 2-octyl-2H-isothiazol-3-one
1336-21-6 ammonia
25322-68-3 Polyethylene glycol
7631-99-4 sodium nitrate, containing in the dry statemore than 16,3 per cent by weight of nitrogen
10377-60-3 Magnesium nitrate 6-hydrate
Magnesium (II), hexahydrate
4itric acid, magnesium salt, hexahydrate
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Xi Irritant
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Relevant R-phrases
22
Harmful if swallowed.
23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
34
Causes burns.
36/37/38 Irritating to eyes, respiratory system and skin.
43
May cause sensitisation by skin contact.
50/53
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Department issuing MSDS:
Safety, Health and Environment Department
Gretchen A. Fontejon - g_fontejon@boysen.com.ph
Joanne C. Ysrael - joanneysrael@boysen.com.ph
Abbreviations and acronyms:
ADR: Accord europen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
RID: Rglement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
VOC: Volatile Organic Compounds (USA, EU)
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