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Study Topic 1
Introduction to materials and family of materials
Chapter 1 (Callister Pg 2-15 1, Pg 1-16 2)
Study theme outcomes: After studying this chapter, the student should be
able to:
- Appreciate the development and increase in diversity of materials
- Know and define materials properties and to understand and
apply the use thereof in specifying materials
- Know the six families of materials and their distinguishing
properties
- Understand the classification system for a material
- Classify a given material with known properties
- Know the three families of processing of a material
- Understand the classification system for a process
- Understand the process-property interaction and quote
examples
- Specify a material and/or process for the manufacturing of a
given component/s
- Solve problems in which knowledge gained in this chapter
must be applied
1
2
Ninth edition
Eight edition
1-1
Mechanical properties
Thermal properties
Electrical, magnetic and magnetic properties
Chemical properties
1-2
Uses of materials with high and low thermal conductivity and heat
capacity:--------------------------------------------.
4) Thermal diffusivity : Its a measure of rate of heat transfer in non-steady
state conditions. a =/*Cp
1-3
1-4
1-5
Study Topic 2
The Structure of Crystalline Solids
(Callister p 47-51 p 75-93 ,p100-103 1: p 45-72 2)
Study theme outcomes: At the end of this chapter a student will be able to:
- formulate the definitions and the terms listed at the end of the chapter
- sketch BCC, FCC, BCT and HCP unit cells and indicate the location of
the atoms
- define the shape and size of the above unit cells in terms of their axial
lengths and inter-axial angles
- determine the coordination number and the number of atoms per unit cell
of the BCC, FCC, BCT and HCP unit cells
- calculate the lattice constants (a, c) of the BCC, FCC and HCP unit cells
if the size of the atoms or ions involved is given, and vice versa
- calculate the atomic packing factor (APF) of the BCC, FCC and HCP
crystals
- distinguish between close-packed and non-close-packed directions and
planes within unit cells
- sketch various planes within unit cells and show to scale the atomic or
ionic arrangement of the atoms or ions within these planes
- explain the difference in stacking sequence of close-packed planes in
FCC and HCP crystal types
- calculate the density of a material if the atomic mass , atomic radius and
crystal type are given
- solve the problems referred to in on clickUp or in the Class Notes.
1
2
Ninth edition
Eight Edition
2-1
Each point in
surroundings.
the
space
lattice
has
identical
Space Lattice
Unit Cell
Example:
If the cube size of the unit cell of iron is 0,287 nanometers (nm),
how many unit cells can be fitted into a length of 1 mm?
2-2
9 th ed.
2-3
FCC:
but a = 22/R
APF = 0,74
CN = 8
9 th ed.
2-4
= atomic radius
= lattice constant (cube side)
Example 2.1: Iron is BCC and has an atomic radius of 0,124 nm.
Calculate its lattice constant.
=
=
APF =
The HCP crystal structure also has a APF of 0,74 but the mode of
packing of the atoms is different from that of FCC. (See 4.3)
2)
6
(central
plane)
3
+
3
=
(plane
(plane
below)
above)
3)
4)
Geometrical relationships:
12
2-6
a = 2R
and
Answers:
Ninth edition
2-7
Examples:
(1)
-iron
912C
(BCC)
(2)
1394C
-iron
(FCC)
-iron
(BCC)
graphite
(hexagonal flakes)
high p
diamond
(diamond-cubic)
Table with allotropic form for some metals (Ref. Smith table 3.5)
Metal
Ca
Co
Hf
Li
Na
Tl
Ti
Y
Zr
Structure
below temp.
FCC
HCP
HCP
HCP
HCP
HCP
HCP
HCP
HCP
Transformation
temp. oC
447
427
1742
-193
-233
234
883
1481
872
Structure
above temp.
BCC
FCC
BCC
BCC
BCC
BCC
BCC
BCC
BCC
2-8
Ninth ed.
Ninth ed
8
Eight ed.
7
2-9
Assignment: Sketch the BCC unit cell and indicate the position
of the atoms.
a) Sketch one diagonal plane within the BCC unit cell.
b) Make a separate sketch of the plane to show the
atomic arrangement within this plane. (Use circles to
represent the atoms.)
c) Sketch the BCC unit cell and draw two possible intersecting
diagonal planes within this unit cell.
2-10
9th ed.
2-11
Study Topic 3
Solidification and Crystalline Imperfections in Solids
Study theme outcomes: At the end of this chapter a student should be able to:
- formulate the definitions and concepts addressed in this chapter
- explain the purpose of and the operation of the Chzokralski process
- give some examples of engineering applications of single crystals
- predict the relative degree of solid solubility of a given element in the
crystal lattice of a given parent metal, by application of the HumeRothery rules
- specification of composition
- calculate the size of the interstitial void within a given crystal lattice
- know crystal defects and sketch schematic representations of the various
point and line defects within crystals
- calculate the concentration of vacancies in a crystal
- show that the presence of solid solution atoms, point defects and edge
dislocations have an effect on the properties of a material
- determine the ASTM grain size number of a polycrystalline material
1
2
9th ed.
8th ed.
3-1
Fig. 3.1;
(2)
3-2
mechanical
ductility
electrical and heat conductivity
atomic diffusion
corrosion resistance
Micro defects
1) Point defects. There are basically 5 types:
3-3
9th ed.
9th ed.
3-4
Hardness
[Cu]
% Ni
[Ni]
The fraction (%) of the alloying element (solute) which can be dissolved
in the crystal lattice of the parent metal (solvent) can vary from almost
none to as much as 100%.
0,036 nm
0,025 mass%
0,053 nm
2,08 mass%
In both cases the voids are smaller than the carbon atoms. Therefore,
lattice distortion occurs during solution of carbon atoms. This lattice
distortion results in an increase of the hardness of the steel.
(Class problem)
3-6
# Schottky defect
# Frenkel defect
Schottky and Frenkel defects are found in ceramic materials
(ionic bonds). Electrical neutrality is maintained.
3) Surface defects:
Only Grain and twin boundaries will be considered in more detail.
(Callister p 162-165 ; p102-104)
#
Grain
boundaries
are
two-dimensional
imperfections
in
3-8
3-9
Macro defects
1) Cracks could form during shrinkage of solidifying material or
mechanical deformation.
2)
Pores or blow holes form e.g as a result of the decrease in gas
solubility in the liquid at the interface with the solid during solidification
3)
Inclusions are foreign matter in the material introduced during
fabrication
3-10
N = 2 n 1
N = number of grains per square inch at a magnification of
100X
n = ASTM grain size number
(n 1/grain size)
If Magnification is not 100X and area is not one inch squared then we
have
(N/A)(M/100)2 = 2n-1
3-11
STUDY TOPIC 4
Mechanical Properties of Metals
This chapter contains material from Chapters 6 and 8 in Callister (for 8th edition)
This chapter contains material from Chapters 8 and 10 in Callister (for 9th edition)
4.1
of fracture, surface energy, elastic and plastic deformation energy, tensile and brittle material
(in the context of fracture mechanics), modes of fracture and fracture toughness and their
interrelationship
- apply equations in solving problems
4.1 Introduction
The mechanical properties of a material are those properties
associated with the elastic and the non-elastic (plastic) reactions
of the material, when an external force is applied.
- Toughness
- Fatigue strength
- Creep resistance
- Stiffness
4.2
Engineering stress
F/Ao
or Pa ]
Engineering strain
Engineering strain is a measure of the elastic and /or the plastic
deformation resulting from the application of a uniaxial tensile
force.
(See Callister Fig. 8.2 1)
= (li - lo) / lo
= l / lo
(mm/mm)
= l x 100 / lo
9th ed.
4.3
= % elongation
(See: Callister Ex. Problem 8.1 2)
= S/A
Shear strain
= a/h = tan
Further
(MPa)
9th ed
4.4
Test data
The test data from the chart are converted to engineering stress
and engineering strain, from which an engineering stress vs.
strain diagram is constructed.
4.5
Examples:
= E
[ N/m2 or Pa]
(Hookes law)
(See: Callister Table 8.1 & 8.2 and Example problem 8.1.) 3
Yield Strength
The yield point is the stress at which elastic deformation ends and
plastic deformation begins. Due to the gradual transformation
from elastic to plastic behaviour observed for most ductile
materials, the 0,2%-offset yield strength (p 0,2) is often chosen as
the yield point (the stress at which 0,2% plastic strain has
occurred) (p = 0,002).
In some materials, e.g. mild steel, the yield point is very sharp.
This stress is defined as the yield strength (y).
9th ed.
4.7
Ductility
% Elongation (A) = ( lf - l0) x 100
l0
with
4.8
F / Ao
True stress
F / Ai
[ MPa ]
[ MPa ]
4.9
t = ln li / lo
4.10
Hardness tests:
# Brinell Hardness (BHN) (steel ball indentor)
BHN = Load / Area of indentation
[ kg/mm2 ]
[ kg/mm2 ]
[ No units ]
depth of indentation
diamond conical indentor (150 kg load)
(for hard metals like steel)
steel ball indentor (100 kg load)
(alloys like brass)
steel ball indentor (60 kg load)
(soft alloys like Al-alloys)
4.12
4.13
Stress concentration
A defect in a material specimen under load causes a local
increase in stress.
local = ( 1 + yc/2r )
with local = the stress at a distance r from the crack tip [m]
= applied tensile (uniform) stress [MPa]
c = crack length associated with a crack tip [m]
= length of surface crack
= length of an internal crack
y = constant ( y = 1 if c << width of material. If not, a
value must be experimentally determined)
local = yc/2r
When r is very small or close to crack tip.
4.15
[MPa.m]
Fracture toughness
A material fracture under stress when cracks propagate. When a
sample of cross sectional area A m2 fracture, 2A m2 surfaces are
created. A surface has specific surface energy [J/m2]. The
amount of energy required to fracture the surface is therefore:
4.16
2 A
This energy is obtained from the elastic deformation energy
released (resilience) when the crack propagates. The elastic
energy stored in a sample is:
Uv = = 2/ E
It could be shown that the critical stress c required to propagate
a crack and therefore fracture a brittle material is given by:
c = 2E / c
cc = 2E
But for y = 1:
K1 = c
Thus:
K1c = cc
= 2E
or
K1c = ycc = y 2E
[MPa.m]
With K1c = fracture toughness which relates the critical stress for
propagation of a crack with length c. K1c is a materials property.
Its value is experimentally determined and it is independent of
sample size or geometry.
The fracture toughness of ductile material is higher than brittle
material. It is explained as follows:
4.17
Class examples:
1. Assume the fracture toughness of (K1c) a steel is equal 40
MPam. Calculate:
a) The stress intensity K1 at the tip of a 3 mm long surface crack
when a stress of 200 MPa is applied. Let Y = 1,3 (25,24)
b) Will the sample fracture or not. Give a brief motivation.
2. A material has a fracture toughness of 55 MPam, yield
strength of 355 MPa and critical surface crack size of 5 mm.
Will a component made from the same material but with an
internal crack with a length of 15 mm fracture when a stress of
300 MPa is applied to it. Y 1.
4.18
r = max - min
4.19
4.20
Class examples.
4.22
4.23
4.24
4.25
The relationship:
ss =Bn
4.26
4.28
# Creep fracture
After a certain period of time of tertiary creep, depending on the
temperature, the applied stress and the type of material, the
component will eventually fail by rupture. Grain boundaries slide
relative to each other. Micro voids or internal cracks also form in
the material at grain boundaries during creep. These voids grow
and coalesce to reduce the load carrying surface and the stress
increases resulting in fracture.
An empirical equation for the time to fracture tf in creep is:
ss.tf = C
..13.7
4.29
4.30
Study Topic 5
Plastic Deformation, Strengthening and
Recrystallization of Metals (Callister Chapter 9)1
Study outcomes:
At the end of this study a student must be able to:
Define and explain the meaning of terms, concepts and properties
such as: formability, mechanism of slip, slip systems, hot working,
cold working, % cold work (% reduction), work hardening, solid
solution strengthening, recovery, recrystallization, grain growth,
toughness, ductile fracture and brittle fracture
Explain why (1) plastic deformation (slip) is assisted and facilitated
by the presence of dislocations and (2) plastic deformation (slip) is
favoured along close-packed planes and directions.
Determine and indicate the number of and the nature of the slip
systems present in FCC, BCC and HCP explain by means of the
mechanism of slip why HCP metals tend to be less ductile than FCC
metals
Explain by means of the mechanism of slip why the yield strength of a
metal or alloy is improved by each of the following means: (1) grain
refinement (2) cold work (3) solid solutions
Quantify the effects of grain refining, cold work and solid solutions
on the strength and ductility properties of metals and materials.
Explain the changes which occur in the internal structure of metals
during annealing heat treatment (recovery , recrystallisation and grain
growth) of previously cold-worked metals; as well as the practical
purpose of this heat treatment.
Explain the various factors which affect the recrystallisation process
Calculate parameters such as time and temperature of
recrystallization, by means of an Arrhenius-type equation
9th Ed.
5-1
5-2
Slip planes:
HCP:
FCC:
BCC:
basal plane
there are various intersecting octahedral planes)
diagonal planes - not close-packed, but they are the
most densely packed or closest planes in BCC
5-3
For each slip plane, slip occurs along the most densely or closed
packed direction within that plane.
Example:
directions.
y = 0 + k d 1/2
y
0
d
k
yield strength
grain size independent material constant
mean grain diameter
constant
Class example:
By use of Callister Fig. 9.19 (b) & (c), compare the yield strength
which can be obtained in the following materials:
(1)
(2)
Which of the above two materials (1) or (2) has the best strength :
ductility ratio?
106 cm/cm3
1012 cm/cm3
% Reduction =
to = original thickness
tf = final thickness after cold working
For rods and wire:
% Reduction
recovery
recrystallization
grain growth
5-8
(1) Recovery
It occurs at a temperature range just below the temperature range
for the recrystallization step. It also occurs at a short heating time
at high temperature.
During this stage, point defects are reduced, (+) and (-)
dislocations eliminate each other and the remaining dislocations
rearrange to form a sub-grain structure with low-angle grain
boundaries known as polygonization. Internal stresses are
relieved, due to the above. The driving force for this step is the
reduction in internal energy.
Polygonization
From: Dieter, G.E. 1961. Mechanical Metallurgy. McGraw-Hill: New York.
Fig. 5-5. p126
(2) Recrystallization.
During this stage, completely new gains are nucleated within the
cold worked structure. These grains will grow at the expense of
the cold worked metal, which eventually results in a completely
new recrystallized grain structure.
The driving force for recrystallization is the decrease in lattice
energy.
The recrystallization step is considered to be completed when all
cold worked material has transformed to non-cold worked
material.
5-9
process
on
the
(2)
(3)
(4)
(5)
The larger the original grain size, the greater the amount of
cold work required to produce an equivalent recrystallization
temperature.
(6)
t x%
tx%
Q
T
= C e( + Q /RT)
[J / g.mol K]
Class example
It takes 9 x 103 minutes to 50% RC a piece of cold worked Cu at
88 oC and 200 min at 135 oC. Calculate the activation energy for
the RC process of Cu.
STUDY TOPIC 6
Diffusion in Solids
(Callister p 180-194 1 ; p 122-143)
Study Theme outcomes: After studying this chapter the students
should be able to
- describe the diffusion mechanism
- distinguish between steady and unsteady state
diffusion process
- Understand the difference between ficks first law and second
law.
- Application of diffusion in industry.
- Factors that influence the diffusion coefficient
-Solve problems based on knowledge gained in this chapter
regarding diffusion
Ninth ed
6-1
Ni
100
%Cu
t > t2 > t1
50
at t : homogenous solid
solution of Cu and Ni
6-2
Interstitial diffusion
Small atoms (eg. carbon) can diffuse by moving from one
interstitial position to another, without permanently displacing
the atoms in the matrix (parent) crystal lattice.
Interstitial diffusion requires less activation energy and is
therefore more rapid than substitutional diffusion. Interstitial
spaces need not be created as vacancies are.
Ninth ed.
6-3
(1)
6-4
(2)
Cs Cx
Cs C0
erf
Cs
C0
Cx
=
=
=
=
x
= erf
2 Dt
x
D
=
=
9th ed
6-6
D = D0 e Q/RT
with D0 = temp. independent constant (m2/s)
Q = activation energy (J/mol) (Callister Table 7.2)
See: Callister ex. Problem 7.4 & 7.5
2)
3)
Impurity diffusion into silicon wafers for integrated microelectronic circuits ("doping").
6-8
7.1
7.2
Consider for example the Ni Cu phase diagram in Fig 7. 2. The properties of the atoms and their
crystal structures are such that there is complete solubility between Cu & Ni. The element which is
in the majority is the parent metal or solvent and that which is in the minority the alloying element
or solute. Such a system is referred to as a binary isomorphous system.
7.3
7.4
7.5 The iron-iron carbide (Fe-Fe3C) or iron-carbon (Fe-C) phase diagram. (p363-373; p319322)
The equilibrium Fe-C or Fe-Fe3C phase diagram, as shown in Fig. 7.4, is an important tool in
predicting the response of steel to heat treatment.
7.5
4. - iron. It is Fe with a BCC crystal structure. This phase occurs at temperatures above
that where steel is normally heat treated and will not be considered further in this
chapter.
5. Fe3C or cementite. It is an iron carbon intermediate compound with a fixed ratio of Fe to
C namely 6,7 wt % C.
6. In between the single phase areas are dual phase areas of which the following are of
relevance:
+ , + L, + Fe3C (ledeburite) and + Fe3C (pearlite)
Fe containing more than 6,7 % C is too brittle to use in engineering applications. Fe3C therefore
forms the right hand compound on the composition scale.
Phase transformations or reactions in the iron-iron carbide phase diagram
The Fe-Fe3C phase diagram contains three horizontal lines that indicate isothermal invariant
reactions (phase transformations that take pace at a single temperature and composition):
Peritectic reaction: This is a reaction that occur at 1493 oC where:
(0,1 %C)+ L (0,5 %C) (0,18 %C)
Temperatures in the vicinity of the peritectic temperature is above the normal heat treating
temperatures of steel and will not be further considered in this course.
Eutectic reaction: At the eutectic reaction point, liquid of 4,3 %C forms or austenite of 2,14 %C
and the intermetallic compound Fe3C or cementite with 6,7 %C. This reaction which occurs at
1147 oC, can be written as:
L (4,3 %C) (2,14 %C) + Fe3C (6,7 %C)
The eutectic mixture of + Fe3C in the Fe-Fe3C system is called ledeburite.
Eutectoid reaction: At the eutectoid reaction point, solid austenite of 0,76 %C produces a fine
eutectoid mixture of -ferrite with 0,022 %C and Fe3C (cementite) with 6,7 %C. This reaction
which occurs at 727 oC , can be written as:
(0,76 %C) ( 0,022 %C) + Fe3C (6,7 %C)
The eutectoid reaction product + Fe3C is called pearlite. The eutectoid reaction which takes
place in the solid state is important in the heat treatment of steel.
7.6 Equilibrium cooling of steel (p 363-373 : 319-322)
The equilibrium cooling of eutectoid plain carbon steel (0,76 %C).
If a sample of a 0,76%C steel is heated to above 727oC in the austenite phase area (austenitising.)
for a sufficient period of time, the microstructure will become homogeneous austenite. On slow
cooling to just above 727oC, the structure will be 100 % with a composition of 0,76 %C. When
cooled to just below the eutectoid temperature of 727 oC, it will transform to ( 0,022 %C) + Fe3C
(6,7 %C) or pearlite. The relative amounts of or ferrite and Fe3C or cementite can be calculated
by applying the lever rule.
w% = ( 6,7 0,76)x100 / (6,7 0,022) = %
w% Fe3C = 100
=
%
7.6
which formed above 727 oC. The % Fe3C and % total can be calculated by applying the lever
rule just below 727 oC. The % eutectoid can be calculated by subtracting the % primary from
the total
Fig 7.6 :
(a) coarse pearlite
(b) Fine pearlite
The equilibrium cooling of hyper-eutectoid ( more than 0,76 %C) plain carbon steel.
Austenitise a sample with say 1,3 %C. On slow cooling, primary or pro-eutectoid Fe3C nuclei will
form on the grain boundaries. These nuclei will grow with further cooling, to form a layer of Fe3C
on the grain boundaries. On further cooling, the or austenite composition, gradually moves
towards the eutectoid composition or 0,76 %C just above 727 oC. The Fe3C composition, remains
constant at 6,7 %C.. The relative amounts of the phases present can be calculated by applying the
lever rule. The % Fe3C increase while the % decrease as the temperature is decreased. When the
alloy is cooled to just below 727 oC, the (with 0,76 %C) which remained just above 727 oC will
now transform or react to form pearlite. The Fe3C which forms in this eutectoid reaction (below 727
o
C) is called secondary or eutectoid Fe3C to distinguish it from the pro-eutectoid Fe3C which
formed above 727 oC.
The % total Fe3C and % total can be calculated by applying the lever rule just below 727 oC. The
% eutectoid Fe3C can be calculated by subtracting the % primary Fe3C from the total.
the long axis of the needles that make up the matrix. Lower bainite forms at temperatures between
250 oC and 350 oC and consist of very fine Fe3C plates usually oriented at an angle of 60 o to the
long axis of the needles. Fig .8 shows the difference between upper and lower bainite.
7.9
Fig 9.9 martensitic microstructure. Needle shaped grains are the martensite phase and white
regions are austenite that failed to transform during rapid quench
Figure 7.9.
Since no atomic diffusion takes place during martensite formation, the reaction is not time
dependent and occurs very rapidly. The amount of to martensite transformation is temperature
dependent. The transformation start at Ms and is completed at Mf .
7.8 Some heat treatments of plain carbon steel. (p591-593;p 404-418; p422-425; p375-376)
Annealing is a heat treatment process by which the steel is heated up to the austenite phase area
and then allowed to cool very slowly. It is very often allowed to cool with or in the furnace.
Equilibrium phases as discussed in para. 9.6 are obtained. The microstructures render soft ductile
material with large grain sizes and course pearlite.
Normalising is a heat treatment whereby the plain carbon steel is heated up to the austenite phase
area for hypo-eutectoid and eutectoid steels and then allowed to cool at an intermediate cooling rate
like being cooled in air. The equilibrium phase diagram can therefore not be used to determine the
amount of phases present. Normalising renders a finer pearlite and lower % pro-eutectoid
component than annealing. It is thus harder and less ductile than the annealed steel
Hyper-eutectoid steels are normalised at temperatures just above 727 oC This limits the amount of
pro-eutectoid Fe3C at the grain boundaries. Fe3C is hard and brittle and will cause embrittlement of
the steel if excessive amounts form on the grain boundaries. The decrease of the relative amount of
Fe3C will also improve machine-ability of the steel.
Hardening is the heat treatment process whereby the steel is austenitised and then very rapidly
cooled (quenched) to form martensite..
Tempering
7.10
Martensite is hard and brittle and has high residual stresses. Tempering is a heat treatment whereby
the physical properties of the martensite is altered to comply to certain requirements. The steel is
heated to a temperature range below the eutectoid temperature , kept at the temperature for a certain
period of time and then cooled to room temperature. Residual stresses are relieved and hardness
and ductility improved during tempering. Ductility increase but hardness and strength decrease.
The mechanism of tempering:
Martensite is a metastable phase, and as thermal energy is supplied during tempering, carbon will
tend to precipitate as rod-shaped carbide (Fe3C) and the iron, now depleted of carbon, will assume a
BCC ferrite structure. The process is diffusion controlled. The amount of diffusion is dependent on
temp. and time at temp.
Extended tempering at relatively high tempering temp. will result in the rod-like Fe3C particles
coalescing to from spherical Fe3C particles within the ferrite. This is known as spheroidising. The
corresponding microstructure is shown in fig 9.10. ( Spherodized cementite at 1000X
magnification)
ductile and softer and less strong than the phases from which it originated. It also has good
machine-ability.
The driving force for spheroidising is the minimisation of the inter-phase energy. The interface
between two phases has a surface energy (J/ m2). The microstructure with the lowest internal energy
is therefore a structure where the surface area between phases is a minimum. The geometry or shape
which has the lowest surface to volume ratio is a sphere.
7.9 Some mechanical properties of heat treated steel
See Callister for graphs. (fig 12.30 and 12.32 in callister)
7.12
9th Ed
8.1
10.1 Introduction
Some uses of magnets
[T]
8.2
B=H
Thus
Where
(B > Bo )
Diamagnetism
8.3
The atomic magnetic dipole moments which are created when the
material is placed in a magnetic field opposes the applied magnetic
field. r is then smaller than 1
(See Callister Fig. 21.5 (a) )
Paramagnetism
The randomly oriented atomic dipole moments align themselves in the
direction of the applied magnetic field. When the external magnetic
field is removed, the material looses its magnetism. r is just larger
than 1.
(See Callister Fig. 21.5 (b))
Ferromagnetism
Some metallic elements i.e.Fe, Co, and Ni can be permanently
magnetized. The magnetic dipole moments maintain there orientation
in the same direction even after the external magnetic field was
removed.
Explanation
Figure showing electronic structure of the 3d orbital for transition metals
Atomic number
Element
23
24
Cr
25
Mn
26
Fe
27
Co
28
Ni
29
Cu
The 4s valence electrons participate in metallic bonding and are not shown..
Antiferromagnetism
Ferrimagnetism
8.5
Tc
Fe (paramagnetic)
Tc = 770 oC
Tc = 1123 oC
Tc = 358 oC
Magnetic domains
The crystal structures of ferro- (and ferri-) magnetic materials contain
small regions called magnetic domains, in which the atomic diploe
moments are aligned parallel. If the magnetic domains are randomly
orientated, there will be no net magnetization in a bulk sample. By
magnetization in a solenoid, they become orientated in one direction
and the material is macroscopically magnetized.
(See: Callister Fig. 21.11)
8.6
Magnetization
When an external magnetic field is applied to a demagnetized
ferromagnetic or ferimagnetic material, it will become magnetized
again, due to the following structural changes:
(a) Magnetic domains whose moments are initially parallel to
the applied field (H), grow at the expense of the less favourably
orientated domains.
(b) If the applied field (H) is high (strong) enough, less favourably
orientated domains are also re-orientated by rotation of the dipole
moments thus moving the domain wall. See Callister Fig 20.12
Demagnitization
8.7
Hysteresis loop
The hysteresis loop of a ferro- or ferrimagnetic material is developed
by subjecting the material to a number of magnetization and
demagnetization cycles
The shape of the loop is a function of the type of ferromagnetic metal
or alloy. The internal area is a measure of the energy lost by the
magnetizing and the demagnetizing cycles.
magnetic induction (B) increases along Q-A, until the saturation level
is reached. (Bs = saturation induction)
(2) The applied field is now decreased to zero. The magnetic induction
(B) will decrease from A to C. Br is termed the remanent induction,
which is due to the magnetization of the material.
(3) The magnetic induction is now decreased along C-D by application
of a reverse (negative) applied field of the amount
Hc ( coercive force)
(4) If the negative applied field is increased still more, saturation is
reached at E.
(5) The reverse field is now decreased to zero, and the magnetic
induction (B) will now return to the remanent induction (Br) at F
(6) Upon final application of a positive field, the B-H curve will follow
F-G-A to complete the hysteresis loop.
8.9
8.10
STUDY TOPIC 9
Electrical Properties of Materials
(Callister Chap. 19 p 681 687, 693-701, 723 ;p721-732,p733742;p766-768)
Study outcomes:
-
formulate the relevant definitions of the terms and know and understand the terms
used in this chapter
relate examples of typical practical applications of conductors, semiconductors
and insulators
explain why electrical resistance (R) is not a materials property, whilst resistivity
and conductivity are considered as materials properties
explain and indicate the similarity between the microscopic and microscopic form of
Ohm's law
calculate the resistivity and conductivity of a material at a specific temperature if its
temperature resistivity coefficient is given
predict the effect of impurities and alloying elements on the resistivity and the
conductivity of a conductor, by applying graphs with data
explain why the resistivity of a conductor like copper is increased by: (1) an
increase in the temperature, (2) the addition of alloying elements and (3) cold
working, of the material
apply the energy-band model to explain why some elements are good
conductors and why others are poor conductors of electricity
give examples of the use of dielectric materials
explain the mechanism by which electrical conduction occurs in intrinsic
semiconductors like silicon and germanium
derive an expression for the conductivity of an intrinsic semiconductor
calculate the resistivity and the conductivity of intrinsic semiconductors.
explain why the conductivity of semiconductors is increased by an increase of the
temperature, whilst the conductivity of good conductors is decreased by an
increase of the temperature.
explain by using a typical example of each, the difference in the mechanism of
electrical conduction between n-type extrinsic semiconductors and p-type
extrinsic semiconductors.
derive expressions for the conductivity of n-type and p-type extrinsic
semiconductors.
explain the mechanism by which an piezo-electric crystal works
calculate the resistivity and the conductivity of extrinsic semiconductors
solve the problems on clickUP
9-1
9-2
V = IR
(.m)-1
Table with conductivities of some materials: (Taken from Callister Table 18.1)
Metal
Non-metal
(m)-1
(m)-1
Silver
6.8 x 107
Graphite
ca 105
Copper
6.0 x 107
Porcelein
ca 10 11
Gold
4.3 x 107
Al2O3
< 10 13
Aluminium
3.8 x 107
Polystyrene
< 10 14
Polyethylene
10 16
Nylon
ca <10 13
electrical conductor.
Ohm's law can also be expressed in its microscopic form, which is
independent of the shape of the conductor:
J = E/
J
E
=
=
=
=
or
J = E
current density [A / m2 ]
electrical field [V / m ]
electrical resistivity [.m]
electrical conductivity [.m] -1
Tot. =
Thus
t + i + d
T +
i + d
Temperature
Thus, the free path of electrons are decreased and resistivity is increased.
(See: Callister Fig. 19.8 )
Resistivity at 0 oC and temperature resistivity coefficient for some metals.
METAL
Aluminium
Copper
Gold
Iron
Lead
Magnesium
Nickel
Silver
Tungsten
Zinc
RESISTIVITY AT 0 0C,
(.nm)
27
16
23
90
190
42
69
15
50
53
TEMP. RESISITIVITY
COEFF. T, OC-1
0.0039
0.0039
0.0034
0.0045
0.0039
0.004
0.006
0.0038
0.0045
0.0037
(Ref. Van Vlack. L.H. 1980. Elements of Matl. Sc & Eng. Addison-Wesley:
London. p 154)
= 0C ( 1 + T T) [.m]
0C = electrical resistivity at 0C
T = temperature coefficient of resistivity
(T is a function of the type of metal)
T
= temperature of conductor (C)
Class example:
a) Calculate the resistivity for pure Al at 90 oC
b) What is the conductivity of pure Al at 90 oC
(2)
Alloying Elements
(3)
Crystal Defects
The fig. shows the sequence how orbitals are filled by electrons.
9-6
Na: 3S1
Mg: 3S2
Al: 3S23p1
Energy bands: Callister Fig. 18.5 ; Smith. W,F. 1996 Fig. 5.13(a)
This same argument can be followed for all good conductors like9-7
occurs because some of the valence electrons are exited from their
bonding positions by thermal activation. The electrons jump from
the valance band across the energy gap Eg to conduction band.
(See: Callister Fig. 19.6)
When a valence electron is exited by an electric field from its
bonding position as shown below, a positively charged "hole" is left
behind and the electron becomes a free conducting electron.
Conduction will occur under the applied electric field due to the
movements of the positive "holes" to the negative pole and the
negative electrons to positive hole.
=
=
=
n =
p =
But
p
ni
Thus:
ni
intrinsic carriers / m3
niq (n + p )
(m)-1
Si
1.11
4 x 10-4
0.14
0.05
1.5 x 1016
2300
Ge
0.67
2.2
0.38
0.18
2.4 x 1019
0.46
(Data taken from Smith (1996) Table 5.4 and Callister Table 18.3)
= o e-Eg/2kT
with o = temp. independent constant
k = Boltzman constant = 8.620x10-5 (eV/K)
Eg = Energy gap (eV)
(See: Callister Fig. 19.16)
(See: Callister Ex. Problem 19.2)
9-10
Group 4A
(parent lattice)
(valence = 4+)
Si
Ge
Group 5A
(dopant)
(valence = 5+)
P
As
Sb
n - type
p- type
= nqn
The p-type extrinsic semiconductor
If an atom from Group 3A e.g. boron (valence 3+) replaces a silicon
atom (valence 4+), there will be one missing valence electron.
Therefore a positive hole is created at one of the four covalent
bonds surrounding this boron atom in the silicon lattice.
If an external electric field is applied to the silicon crystal, one of the
valence electrons from a neighbouring silicon atom can be exited to
move to the hole, and thereby the hole is transferred to another
position.
Hereby conduction will occur, due to the motion of holes in the
direction of the negative terminal of the applied electric field.
See: Callister Fig. 19.14
The energy associated with the movement of the hole in the case of
B in Si is 0,045 eV. This is small in relation to the 1,1 eV required
for the conduction of electrons in Si.
Therefore due to their valence of 3+, impurities from Group 3A like
B, Al or Ga provide easily excitable holes for conduction, when
added to Si and Ge.
In terms of the energy-band diagram, these elements provide an
9-12
pqp
=
=
ni
ni
-- - - - - - - - - - - - - - - - (2)
nn pn = ni
- - - - - - - - - - - - - - - - (3)
Nd
- - - - - - - - - - - - - - - - - (4)
pn
ni
= n
n
Conductivity (n-type):
Because
ni
N
d
- - - - - - - - - - (5)
nn q n
nn q n - - - - - - - (6)
pn q p
nn >> pn
9-14
Resistivity
#
- - - - - - - - (7)
np pp = ni
- - - - - - - - - - - - - - - (8)
Na
-- - - - - - - - - - - - - - - - (9)
np
ni
= p
p
ni
N
a
- - - - - - - - - - - - - -(10)
Conductivity: (p-type) = np q n + pp q p
pp q p
- - - - - - - - - (11)
Because pp >> np
Resistivity
- - - - - - - - (12)
ni
n
p
=
=
=
9-15
9.5
9-16
p 767)
9-17