Professional Documents
Culture Documents
UNIT
Answer (1)
Number of moles of 200 ml of 3 M AgNO3 = 200 3 103
= 0.6
Number of moles of 300 ml of 2M AgNO3 = 300 103 2
= 0.6
Answer (4)
1 ml H2O is equal to 1 g of H2O because density of water is 1 g/ml.
3.
Answer (4)
The change in oxidation number of Cr is +3 to +6. Total e lost are 6. Hence, equivalent weight of
M
.
Cr2(SO4)3 =
6
4.
Answer (3)
3% solution of H2O2 means
100 ml H2O2 solution 3g H2O2
1000 ml H2O2 solution 30g H2O2
2H2O 2 2H2O O 2
234
22.4 L
at NTP
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
2
5.
Physical Chemistry
Answer (3)
MgCO3 + 2 HCl MgCl2 + CO2 + H2O
MgCl2 + HCl no reaction
Now, 1 mole of MgCO3 1 mole of CO2
1 mole of CO2 1 mole of MgCO3
4
4
moles of CO2 =
moles of MgCO3
44
44
= 0.09
= 0.09 84 g of MgCO3
= 7.64 g
6.
Answer (3)
x
1000
mol. wt. of KMnO 4
56
60
N
5 .6
5
158
56
60
5
5
.6
x
1000
= 18.96 g
% purity of KMnO4 =
7.
18.96
100 63.2%
30
Answer (3)
100 g of solution contain 49 g of H2SO4
49
mol. weight of H2SO 4
M
100
weight of solution
density
100 NH2SO4 50 12
NH2SO4 6N
6N H2SO4 = 3 M H2SO4
49
98
3
1000
100
d
49
10 d
98
d = 0.6 g/ml
8.
Answer (1)
Number of moles of KClO4 formed =
0.395
138.5
= 2.85 103
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
Answer (2)
5 FeC2O4 + 3 MnO4 + 24 H+ 5 Fe3+ + 10 CO2 + 3 Mn2+ + 12 H2O
Molecular weight of FeC2O4 = 144 g
Number of moles in 1.44 g of FeC2O4 =
1
1.44 = 0.01 mole
144
y
50 0.2
2
2x + y = 10 2 = 20
x + y = 72 0.2
x + y = 14.4
x = 20 14.4
= 5.6
5.6 40
= 0.224 g
1000
WNaOH
0.224
0.48
WNa2CO3 0.4664
8.8 53
0.4664 g
1000
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
4
Fe2
Fe3
12. Answer (2)
4
1
4
u=
1
5
NA NA
4
4
18a.
x A 1000
xB
18
Answer (4)
(AIEEE 2011)
For 1 kg solvent
5.2
5.2
0.086
55.5 5.2 60.7
No. of moles of Cl
Total volume in litre
423 9
1.8
5
5
46
23
20a.
Answer (3)
(AIEEE 2012)
Physical Chemistry
3(number of atoms of A) + 6 NB = 2 NC
NA = 2
NB = 3
NC = 12
Hence A2(BC4)3
24. Answer (2)
100 ml of 1 M Ca(OH)2 = 100 ml of 2 N Ca(OH)2
10 ml of 20 N H2SO4 = 100 ml of 2 N H2SO4
Given V.D. of A =
= 2
1
VB
6
= 2 VB
=
1
6
x
6
12
100 37.5%
32
% of C in CO2 =
12
100 27.27%
44
% of C in CH3CH
CHCOOH =
% of C in COOHCOOH =
48
100 55.8%
86
24
26.6%
90
200
100 25%
800
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
100
14 g of compound
12
= 116.67 g
29. Answer (1)
( 58.5 )
1.25 25 = x 1250
x = 0.025 M
31. Answer (1)
100 0.5 + 200
x
1
2 N = 600 x
4
N
4
= 0.25
20 ml of 0.25 N solution (acidic) 25 ml of 0.2 N acidic solution
10 ml of 0.2 N NaOH will neutralize 10 ml of 0.2 N acidic solution
50
32
50 50
32 46
= 0.59
MgCO3
MgO CO 2
84 g
Weight of MgO =
40
40
42 20 g
84
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
B=N
81.6
2.2988
35.5
18.4
1.15
16
24
12.5 = 2.5 g of Mg
120
5.657
100 22.63%
25
NH2SO 4 0.5 N
Molarity of H2SO4 =
0 .5
0.25 M
2
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
: C
12
100 92%
13
% composition of CH2O
: C
12
2
100 40% H
100 6.7%
12 2 16
30
% composition of C3H6O
: C
36
100 62%
36 6 16
% composition of C3H4O2 : C
36
100 50%
36 4 32
65.38 g of Zn is present in
100
65.38
0.26
= 25146
= 2.5146 104 g
43. Answer (4)
The molecular mass of M(OH)2 = 171
x + 2(16 + 1) = 171
x = 171 34
= 137 g
137
68.5 g
2
12
15
= 0.8
MH2SO4 0.4 M
22.4
22.5 = 5.6 L
90
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
W
1000
152
= 0.456 g
% purity of sample =
0.456
38%
1 .2
0.384 g O2 is obtained by
2 122 .5
0.384
3 32
= 0.98 g KClO3
% of KClO3 decomposed =
0.98
100
9.8
= 10%
50. Answer (3)
Only Na2CO3 reacts with HCl.
M.e. of Na2CO3 = M.e. of HCl
W
1
1000 100
53
10
W = 0.53 g Na2CO3
So, weight of NaCl = 1 0.53 = 0.47 g
% of NaCl =
0.47
100 47%
1
SO 3 H2O H2SO 4
80 g
18 g
80
9 40
18
% of SO3 = 40%
4.5
112
5 .6
= 90 g
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
10
Physical Chemistry
0.5
12.25
1000
98
x
500
(x is the basicity)
x=2
2 HIO 3 10 NO 2 4 H2O
254 g = 630 g
Thus, HNO3 required for 5 g iodine
=
630
5 12.4 g
254
AsO34 AsO33 nf 2 ; I I2 nf 1
1.5 1022
1
mole electrons
6.02 1023 40
1
I2
2
1
mol
80
e
1
mol
40
wt. of iodine = w
1
80
254
3.2 g
2FeS2
x mol
11
O2 Fe2 O3 4 SO2
2
2x mol
11 x
mol
4
11x
1
11x
mol O2
13.1 x
4
0.21
4
%N2
16.6 x
100 81.97%
20.25 x
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
11
z2
n3
12
33
= 2.43 1014
t1
27
33
= 3 =
t2
64
4
61. Answer (2)
Cr(24) = 1s2 2s2 2p6 3s2 3p6 4s1 3d5
Number of unpaired electrons = 6.
62. Answer (2)
There are 3 complete waves in figure, means it produces 3 waves.
63. Answer (2)
2x 0
1 0
(KE)1
=
=
3 x 0
2 0
(KE)2
y
2x 0
=
4y
3 x 0
8x 40 = 3x 0
5x = 30
0 =
5x
3
2rn = n
2rn
2.n2a0
=
n
n
= 2na0 = 8a0
(... n = 4)
12
Physical Chemistry
x . p
n
2 n2
n (n 1)
K,
2
l (l 1)
h
=
2
2 (2 1)
h
=
2
h
2
3d
s = 6
1
6
=
=3
2
2
Spin multiplicity = 2s + 1 = 2 3 + 1 = 7
73. Answer (3)
Last electron is filled in 3d orbital.
74. Answer (3)
Energy of unfilled orbital is decided by (n+l) rule
75. Answer (3)
e is excited to 3rd shell.
76. Answer (4)
Work function of metal depend on ionisation energy.
77. Answer (3)
2 4mp 2 ev
2 mp .ev
2 2
1
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
13
sin4
2
e4 Z2
802h2n2
RHhC
R hC
= H
9
n2
n=3
3s
3p
3d
1
3
5
Total degeneracy = 1 + 3 + 5 = 9
86. Answer (3)
dxy orbital lies in xy plane.
87. Answer (1)
s orbital does not have angular nodes, only p and d orbitals have angular nodes.
88. Answer (3)
Number of nodal planes l
for 4d, n = 4, l = 2
Number of nodal planes = 2
89. Answer (3)
Spectrum depends on electronic environment of an atom.
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
14
Physical Chemistry
max =
1
1
1 1
R34
= RZ2 2
= 3R
2 = R (2)2 =
1 4
n
n
4
2
1
1
3R
Hence, =
h
m
2 =
h
m
h
m
v=
nh
2
nh
2mr
velocity
circumference
v
2 r
nh
2
mr
=
2r
=
nh
4 2mr 2
s1
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
15
1
.
2
1
2
[JEE (Main)-2014]
37 1s22s22p63s23p63d104s24p65s1
So last electron enters 5s orbital
Hence n = 5, l = 0, ml = 0, ms
1
2
h
4
x.m v
h
4
v.mv
h
4
(v)2 =
v =
h
4m
h
4m
p = mv = m
h
=
4m
mh
1 mh
=
4
2
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
16
Physical Chemistry
m1 m2
m2 m
m1 m2 2m 2
Rydberg's constant
RH
2
rn 0.53
n2
2.
3.
Physical Chemistry
17
Electronegativity
4.0
3.5
Cl
3.2
3.0
k(Z b)
where b is screening constant.
126. Answer (3)
Addition of e in N is an endothermic process.
127. Answer (1)
Fact
128. Answer (2)
129. Answer (2)
Gallium have smaller size than aluminium.
130. Answer (2)
For isoelectronic species, size
1
.
Atomic number
(AIEEE 2012)
[JEE (Main)-2015]
N3 > O2 > F
As per inequality only option (3) is correct
that is 1.71 , 1.40 and 1
131. Answer (3)
Energy have to be absorbed to increase the energy of the E.C. and decrease the stability.
132. Answer (2)
With respect to oxygen valency along period generally increase.
Al2O3, SiO2, P4O10, SO3, Cl2O7
133. Answer (4)
Polar bond is present between two atoms which have different electronegativity. If electronegativity is different,
then I.E. and E.A. should be different.
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
18
Physical Chemistry
(AIEEE 2012)
5
= 1.67,
3
1
= 0.33
3
1 .5
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
19
(AIEEE 2009)
O
PCl
Cl Cl
154. Answer (2)
H
5444'
H
H
H
155. Answer (3)
..
..
20
Physical Chemistry
F
163. Answer (2)
Due to pentagonal bipyramidal shape.
163a. Answer (1)
(AIEEE 2011)
Hybridisation of iodine is sp 3d 3
So, structure is pentagonal bipyramid.
164. Answer (1)
CH=CH2
Cl
167. Answer (2)
Fact.
168. Answer (4 )
Larger anion, easier polarisation.
169. Answer (3)
Smaller ionic radius, larger hydration radius.
170. Answer (1)
Larger ionic radius, more ionic mobility (drift velocity per unit electric field).
171. Answer (2)
ClF3 is T-shaped and other are pyramidal.
172. Answer (2)
Cl
F
P
Cl
Cl
>0
Cl
F
F
P
Cl
Cl
F
=0
Physical Chemistry
21
O
4- bonds O=PO
O
O
||
P
O
O
P=O
O
P
||
O
[JEE (Main)-2013]
O2 :
2
2
1s
*1s
2
2
2s
* 2s
22pz 22p
S2 :
2
2
1s
*1s
2
22s *2s
2
2p
2
z 2p
2
2p
*12p *12py
y
2
2p
*22p
2
*2p
y
2
2
2
*22pz 3s
*3s
3p
2 2 *13px *13py
z 3p x 3p y
Cl
B
Cl
Cl
181. Answer (1)
Due to more negative charge on F
181a. Answer (4)
[JEE (Main)-2015]
H-bond is one of the dipole-dipole interaction and dependent on inverse cube of distance between the
molecules.
182. Answer (1)
In Ar, London forces exist
183. Answer (1)
When Z 7, sp mixing take place
184. Answer (3)
PCl5 exist as PCl4 PCl6 [PCl4] [PCl6]
185. Answer (2)
BCl3 H2O H3BO3 3HCl
186. Answer (3)
In valence cell of S is 10e are present.
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
22
Physical Chemistry
Bond angle
102
104.5
109.25
120
(AIEEE 2012)
N
197. Answer (1)
Fact.
198. Answer (1)
LiH contains 76% (approx.) ionic character.
199. Answer (2)
In aqueous medium movement of ion becomes easier.
200. Answer (4)
Factual
201. Answer (1)
In NO2 , there are no l.p b.p repulsions and bond angle of O N O is 180.
202. Answer (3)
In (3) there is maximum charge separation.
203. Answer (3)
3
Physical Chemistry
23
(i)
H2
(ii)
1 2 = n2 R 300
n1
n2
n1 = n2
In vessel B, number of atoms will be 2 times that present in vessel A. Because H2 is diatomic while He is
monoatomic.
206. Answer (3)
At constant pressure (parallel to V axis)
V1 > V 2 > V 3
Since V T hence T1 > T2 > T3.
207. Answer (2)
V
= constant
T
Charles law.
208. Answer (1)
Molecular weight of C2H6 = 30 gm
Molecular weight of H2 = 2 gm
Since H2 is lighter hence it diffuses faster into balloon containing C2H6 hence balloon will be enlarged.
209. Answer (3)
PV =
W
RT
M
0.821
200
0 .5
0.0821 400
1000
M
M = 100
Molecular weight of C2F4 = 2 12 + 4 19 = 100.
210. Answer (3)
1
V
(3) is not correct representation.
Vrms
1 2 3 4
4
30
7 .5 .
4
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
24
Physical Chemistry
P a ( V b) RT
2
V
(AIEEE 2011)
2a
Rb
TB
a
Rb
TC
8a
27Rb
Ti
Ti
TB
TC
2
54
6.75
8
8
27
TC
8
0.296
TB 27
TB
3.375
TC
TC
Hence T is least.
B
Physical Chemistry
25
2
x
3
2
x 0.8 litre
3
x
0 .8
3
x
1 0 . 8 0 .2
3
x = 0.6 litre
Volume of ozone =
2
0.6 0.4 litre
3
v 100
10
t
10
(1)
x 100
2 .5
t
40
(2)
x 25
2 .5
t 10
(3)
x 100
10
t
10
(4)
x 5
2 .5
t 2
In option (3) rate of diffusion of O2 is same as that of rate of diffusion of H2 which is never possible because
H2 is lighter and O2 is heavier hence rate or diffusion of H2 will be faster and that of O2 will be slower.
222. Answer (3)
Collision frequency (pressure)2
Hence at 5 atm, collision frequency will be 25z.
223. Answer (2)
Tc
8a
27Rb
Vc = 3b and Pc
a
27b
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
26
Physical Chemistry
[JEE (Main)-2014]
PV
RT
a
)(V b) RT
V2
At low pressure
V b V
P 2 V RT
V
PV
a
RT
V
PV RT
a
V
PV
a
1
RT
VRT
So, Z 1
a
VRT
vA / t
vB / t
MA
MA
MA
MB
MB
MB
MA
MB
1
4
Physical Chemistry
27
RT
P
Vm will be maximum at higher temperature and lower pressure.
Vm =
2a
Rb
2a 2 27
Tc
8
33 9.8 K 263.2C
27
n
Pressure correction
v
(y = c + mx)
28
Physical Chemistry
P1V1
P V
2 2
T1
T2
242. Answer (1)
PV = constant
1
V
At sea level pressure is more hence volume less and density more.
d
3
KT
2
T = constant
hence KE = constant
245. Answer (3)
Postulate of kinetic theory of gases.
246. Answer (2)
Due to viscous force (frictional force) liquid comes to rest.
247. Answer (1)
At constant pressure the volume of a given sample of an ideal gas varies with temperature as follows
t
Vt V0 1
273
V = kT
log V = log T + log k
y = mx + c
m=1
c = log k
RT1 RT1
V
P1
2
RT2
2PT2
P P1 P1
or P1
T1 T1 2T2
2T2 T1
[ P = gh]
h1 = 70 m
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
29
2x + y = 50
15 mL O2 is in excess
C 2H2 +
x
1
O H2O
2 2
5
O 2CO2 + H2O
2 2
2x
CO
y
1
O2 CO2
2
y
H > E
9
O 2 2CO 2 3H2 O SO 2
2
( g)
(l)
( g)
( g)
At 298K, H2O will be in liquid state and CO2 and SO2 will be in gaseous state.
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
30
Physical Chemistry
( g)
( g)
( g)
1
1
ng = 1
=
2
2
H U = ng RT =
1
R 298 = 149R
2
H2O(l)
(AIEEE 2009)
H+(aq)
OH(aq);
H = 57.32 kJ
1
O (g) H2O(l); H = 286.20 kJ
2 2
Adding I & II we get,
II.
H2(g) +
1
O (g) H+(aq) + OH(aq)
2 2
H = 57.32 286.2
= 228.88 kJ
H2(g) +
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
31
Given
at 300K, G = H TS
= 25000 300 90 = 52000
G is ve (reversible).
272. Answer (1)
For expansion against vacuum work done PdV = 0.
For expansion of an ideal gas the change in internal energy E = 0 as there is no force of attraction amongst
gas molecules or no work has to be done to overcome the intermolecular force. Under adiabatic condition no
heat enters or leaves this further confirms E = 0.
H = E + PV
H = 0 + 0 = 0
H = 0
S =
H
276.5
=
= 414.5 K
S
0.667
275. Answer (1)
Teq =
3
O CO2 + 2H2O,
2 2
1
O CH3OH
2 2
H = x
H = y
H = ve
H = x y = ve
xy<0
y > x
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
32
Physical Chemistry
3 2.5
15 bar
0.5
W = Pext V = 15 (2.0) = 30 dm3 bar
289. Answer (2)
P2
228
76 kcal / mol1
PH bond energy =
3
H
H
P P
H
H
4(P H) + (P P) = 355
or 4 76 + (P P) = 355
(P P) .E = 51 kcal/mol1
290. Answer (1)
Cv
Cp Cv = R
R
1
dW n C dT 1 T T
v
nR
283
103
87
Physical Chemistry
33
[JEE (Main)-2015]
reaction
= G
formation
product
reactant
formation
RT ln K P = 2 G
NO 2
NO 2
NO 2
2 G
NO
2 G
NO
RT ln K P
286600 R 298 ln K P
2
3.6
(393.5) 103 J
12
= 1.18 105 J
=
[JEE (Main)-2014]
1 8.314 298
1000
1
= 1366.93 kJ mol
1364.47
0 = rG + 2.303RT log K
= rG + 2.303RT log 1
= rG + 0
K 1
kf
kb
34
Physical Chemistry
57.1 kJ
mc
(AIEEE 2011)
V2
V1
100
10
S = 38.3 J/mole/K
299. Answer (2)
H2O(l), 10C
H2O(l),0C
H2O(s),0C
S
S2
S = S1 + S2
= 2 2 2.303 log
273
1440
2
283
273
= 11.84 cal K1
300. Answer (3)
C2H6 (g) 2C(g) 6H(g)
(1)
rH = (99.8 6 + 83)
C(graph) C(g); 171kcal
(2)
H2 (g) 2H(g);
(3)
104 kcal
1
= 2416 cal
4.18
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
35
ln 2
35 s
K
E
S nF
2 96500 1.5 104 = 28.95 JK1 mol1
T P
306. Answer (2)
1st I.E. is for gaseous atoms only.
307. Answer (3)
In free expansion, W.D = 0.
308. Answer (1)
Fact.
309. Answer (3)
H2(g) +
1
S (g)
2 2
H2S(g)
H2(g) + Br2(g)
2HBr(g)
Br2(g) + H2S(g)
2HBr(g) +
1
S (g)
2 2
K1
...(I)
K2
...(II)
...(III)
(AIEEE 2012)
Hg(g) +
1
O (g)
2 2
2
P
3
PO2 =
KP = PHg PO2
KP =
2
3
3/2
1/ 2
1
P
3
2 1
= P P
3 3
1/ 2
P3/2
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
36
Physical Chemistry
N2O 4 (g)
1
2NO 2 ( g)
2
KP 2
at equilibrium
1
0.5 atm
1
2
=
0.5 atm
1
pN2O4 =
pNO2
KP =
2=
pN2 O
pN2O 4
4 2
(1 )2
2
(0.5)2 (1 )
=
1 2
(1 ) 0.5
1 2 = 2
22 = 1
2 =
1
2
= 0.707
= 71%
312. Answer (3)
COCl2
0.3
0.5
CO Cl2
0.1
0 .1
0.5
0.5
0.3
0.5
KC =
= 15
0.1 0.1
5
5
313. Answer (4)
More the value of equillibrium constant less is the stability of the oxide of nitrogen.
314. Answer (1)
KP = KC (RT ) ng
CO(g) + Cl2(g)
COCl2(g)
ng = np nr = 1 2 = 1
KP
1
= (RT)1 =
KC
RT
[JEE (Main)-2014]
1
O (g) SO3 (g)
2 2
KP = KC(RT)x
SO2 (g)
= 1 1 1
2
2 2
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
37
AgCl(s)
Ag+
...(i)
(NH3)2]+
+ 2NH3
[Ag
...(ii)
+
Due to removal of Ag through reaction (ii), equilibrium (i) shifts in forward direction.
316. Answer (1)
At 25C pKb for NH3 = 4.7 (in aqueous solution)
[NH4Cl] = 0.1 M
[NH3] = 0.01 M
for basic buffer
[conjugate acid B]
pOH = pKb + log
[ weak base BOH]
= 4.7 + log
0 .1
0.01
1.2 600
= 2.4 atm
300
1
108 which is greater than KSP.
8
321. Answer (4)
pH = 13
[H+] = 1013 mole ion/lit
1 mole ion have = 6 1023 ions
1 1013 mole ion have = 6 1023 1 1013
= 6 1010 ions per litre
Hence number of ions in 1 ml solution = 6 107.
IP =
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
38
Physical Chemistry
[Fe(OH)2]+2 + H+
2 Ag+ + CrO42
According to this equation the concentration of CrO42 ions will be half of concentration of Ag+ ions.
KSP = [Ag+]2 [ CrO42 ] = (1.5 104)2 (7.5 105)
= 1.6875 1012 = 16.875 1013
323a. Answer (1)
(AIEEE 2009)
[ CO32 ] = 104 M
Ksp [BaCO3] = [Ba2+] [ CO32 ]
[Ba2+] =
K sp
[CO32 ]
5.1 109
104
= 5.1 105 M
[Salt]
[ Acid]
pKa = 4.76
[Acid] = 10 ml of 1.0 M
[Salt] = 20 ml of 0.5 M
But total volume is made up 100 ml
[Acid] = 0.1 M
[Salt] = 0.1 M
[Acid] = [Salt]
pH = pKa
Hence pH of Buffer solution will be 4.76.
325. Answer (4)
Each reaction has a definite value of the rate constant at a particular temperature i.e. KP is constant at constant
temperature.
326. Answer (1)
Backward reaction is dissociation reaction and hence endothermic. The forward reaction will therefore be
exothermic. Further it is acccompanied by decrease in number of gaseous moles. Hence its equilibrium will
be affected by temperature and pressure.
327. Answer (3)
t0
O2
2SO 2
60
5
5 1 .5
at equilibrium 5
100
53
3 .5
0
2SO 3
3
2
Total = 2 + 3.5 + 3 = 8.5
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
39
t0
1 mole
1 mole
P4 (s) 6Cl2 (g)
at equilibrium 1 x
1 6x
1 x 1 6x
4PCl 3 ( g)
4x
4
2
[C]3
Q=
=
= 16
[ A ] [B]
1 2
2 2
Given KC = 20
here QC < KC
Thus to have Q = KC. The concentration of C must increase i.e. reaction should proceed from left to right.
331a. Answer (2)
[JEE (Main)-2015]
2A
B + C, G = 2494.2 J
1
1
Now A = , B = 2 and C =
2
2
Now QC =
CB
A 2
1
2
2
= 2 =4
1
2
10 2
M = 102 N
2
= 101 equivalent in 100 ml = 1 milliequivalent
Ca(OH)2 =
40
Physical Chemistry
0 .1
0.03
0
0
0
0
0.04
0.03
Now [ Ag(CN)2 ]
0.03 a
0.03
KC = 4 1019 =
(0.04)2 a
0.03
a = 7.5 1018
335. Answer (1)
Initial
0 .2
0 .6
N2
3H2
At equilibrium 0.2 a 0.6 3a
0
2NH3
2a
0.8 40
0.8 40 1
reacts to give
mole of NH3 or NH3 formed
100
100
2
is 0.16 mole
2a = 0.16
a = 0.08
Initial mole = 0.8
Final mole = (0.2 0.08) + (0.6 0.24) + 0.16
= 0.12 + 0.36 + 0.16 = 0.64
Ratio of final to initial mole =
0.64
4
= 0.8 =
0 .8
5
0
0
NH 3 + H2S
(g)
( g)
x
x
1
2
pH2S = pNH3 =
P
2
KP = pNH3 pH2S =
p2
= 64
4
p2 = 256
p = 16 atm.
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
41
CuS
Ag2S
HgS
[CH3COONa] =
0.01
M
2
pH = 7 +
pKa
log C
+
2
2
= 7 + 2.37 +
log 0.005
= 8.22
2
Salt
BA + H2O
A
B
+
+ H2O BOH + HA
C (1 h)
C (1 h)
Ch
Ch
mol / L
mol / L
mol / L mol / L
Kh =
1 10 14
5 10 7 5 10 7
1 10 7
5 10
h2
(1 h)
, Kh =
Kw
(1 h) 2
h2
(1 h)2
h
1 h
5h = 1 h
1
6
h = 0.166
h =
h = 16.6%
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
42
Physical Chemistry
H + A
C C
HA
C (1 )
pH = log10 [H+]
2 = log10 C
2 = log10 0.1
log10 0.1 = 2
0.1 = 102
=
10 2
10 1
= 101 = 0.1
(AIEEE 2012)
2HI
2HI
[HI] 2
K=
[H2 ] [I2 ]
At the initial number of moles of H2 and I2 were same therefore at equilibrium [H2] = [I2]
47.6 = K =
[HI] 2
[I2 ] 2
COCl2(g)
PCl3(g) + Cl2(g)
KP =
CO(g) + Cl2(g)
KP =
PPCl3 PCl2
PPCl5
PCO PCl2
PCOCl2
If CO is introduced, the dissociation of COCl2 will decrease and PCl2 will decrease. This will favour dissociation
of PCl5 because both reactions are attained in same vessel.
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
43
t0
1
N2 O 4
t eq 1 x
0
2 NO 2
2x
0.66 0.66
[NO2 ]2
0.66 0.66
=
=
1 0.33
[N2O 4 ]
0.66
KC = 0.66
347. Answer (3)
40 ml of 0.1 M ammonia solution = 40 0.1
= 4 milliequivalent ammonia solution
20 ml of 0.1 M HCl = 20 0.1
= 2 milliequivalent of HCl
4
2
0
NH4 OH HCl NH4 Cl H2O
42
0
2
2
[NH4 Cl]
2
pOH = PKb + log [NH OH] = 4.74 + log
= 4.74
2
4
pH = 14 4.74 = 9.26
348. Answer (4)
[Ag(H2O)2]+(aq) + NH3(aq)
K1 = 2.0
...(1)
[Ag(NH3)2]+(aq) + H2O(aq)
...(2)
103
103
[Ag(NH3)2]+(aq) + 2H2O(I) : K
44
Physical Chemistry
AgCl
KSP = S2
1.5 10 10
K SP =
0.02
ASC + H2O
0.02 x
0.02
HASC OH
x
[HASC][OH ]
Kn =
[ ASC ]
2 1010 =
x.x
x2
=
0.02 x
0.02
x2
0.02
x = 2 106
[OH] = 2 106
[H+]
1 10 14
2 10 6
= 5 109
10 2
4
1
2.5 103 = 1.25 103
2
2C + D + Heat
2 moles
3 moles
Reaction is exothermic.
Reaction involved increase in volume (number of moles). So it is most favoured at low temperature and low
pressure.
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
45
0
0
2NH3 CO 2
32 =
(1 ) 78 (2 17) 44
1 2
32 =
78 78 34 44
78
=
1 2
1 2
32 + 64 = 78
= 0.71875 = 0.72
355. Answer (1)
[Ag2O](s) = [Ag](s) = 1
KP = p O 2
356. Answer (4)
pH =
1
pKW (for pure H2O)
2
pH =
1
13.26 = 6.63
2
0.1435
103 mole
143.5
1000
2.45 gL1
20
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
46
Physical Chemistry
H2 O H2
1
n 1
2 1
2
; XH2
; XO2
2
2
2
XH2O
KP
PH2 PO1/22
PH2O
2
2
P
P2
3/2 P1/2
2
2
KP
2 1
1 2 1/2
P
2
361. Answer (1)
1
3
N H NH3 , n 1
2 2 2 2
k1k 2
H 2 S2
1021
H2S
0.12 S2
0.1
S2 10 20
2
and HCO3
H CO3
s2
K a2
s1
s2
10 4
4 10 10
103
2
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
47
11.45 103
Kc =
103 mole/L
8.314 298
= 4.6 103 M
371. Answer (3)
K p =
1
(K p )2
1
(4 103 )2
106
16
log K
H
S
2.303 RT
R
H
(+1)C = O
(0)
(1)
(1)
(1)
(1)
(1)
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
48
Physical Chemistry
OH
(+3)C = O
(0)
(1)
(1)
(1)
(1)
(1)
2 3
H
K 2 Cr 2 O 7 Fe C 2 O 4
Cr 3 Fe 3 C O 2
(nf 6 )
(nf 3 )
3
1
1
mole of K2Cr2O7
6
2
8 e
N2H4
(N2H4 ) 8 ( y )
2 x 4 8
x 2
Cu S
Cu + SO2
+2 e
6 e
M
4
N2 N H3
One mole of N2 loses 6 mole of electrons and one mole of NH3 gains 3 mole of electrons. Hence, equivalent
M1
M2
and
respectively. If an element is present in its lowest oxidation state
6
3
then it behaves as reducing agent only. So, NH3 acts as reducing agent only.
Physical Chemistry
49
O
+
K
O
Cr
O
OO K
O+
K
2
0 .5
4
M
36.5
73
0 .5
0.5
+3
Fe S 2
+4
Fe2O3 + SO2
1 e
2 5e
Total 11 mole of electrons are lost by 1 mole of FeS2. Hence, equivalent weight of FeS2 =
M
.
11
M
2
n-factor of Br2 =
M
10
M M 6M
2 10 10
10 5
6
3
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
50
Physical Chemistry
(+5) (0)
(0)
O
(+5)
O SSSSO
O
In which, two sulphur atoms have (+5) oxidation number and two sulphur atoms have zero oxidation number.
394. Answer (3)
Silver cant displace Cu from CuCl2 because Ag is placed below than Cu in electrochemical series.
395. Answer (3)
Electrolysis makes a non-spontaneous change spontaneous.
396. Answer (2)
Factual
397. Answer (1)
Factual
398. Answer (4)
Here energy evolved (G) is converted in electrical energy.
399. Answer (1)
Factual
400. Answer (4)
Electrochemical series is the arrangement of increasing order of standard reduction potentials.
401. Answer (1)
Oxidation potential of Li is highest and of H is zero.
402. Answer (3)
H2(g)
1 atm
Temperature = 298 K
Pt(s)
This is schematic diagram of S.H.E.
1 M HCl
Physical Chemistry
51
H
K 2 Cr2 O 7 Sn Cl 2
Cr 3 Sn Cl 4
( nf 6 )
(nf 2 )
H
K 2Cr2 O 7 3SnCl 2
Cr 3 SnCl 4
1
1 mole K Cr O
2
2 7
3
1
mole
3
+2 2+
Cu2 S
+4
Cu + SO2
+2 e
6 e
Total 8 e are lost by one molecule of Cu2S. So, equivalent weight of Cu2S =
M
.
8
CH3 CH CH2
412. Answer (3)
4
CH4
CO2 , n 4 4 8
1
1
4
8
2
Number of B atoms =
1
4 1
4
Number of C atoms =
1
2 1
2
Hence, formula of unit cell = A1/2BC and simplest formula of compound is AB2C2.
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
52
Physical Chemistry
NM
a3NA
2 452 1012 m / 3
ZA
V(in cm 3 ) N0
4 27
( 4 10
8 3
) 6.023 10
23
4 27
64 10
24
6.023 10 23
= 2.8 g/c.c
1
8 1
8
Number of B atoms =
1
6 3
2
Number of C atoms =
1
12 1 4
4
After passing tetrad axis, 2 face atoms and 1 body atom is removed. Now,
Number of A atoms =
1
8 1
8
Number of B atoms =
1
1
6 2 2
2
2
Number of C atoms = 4 1 = 3
Hence, formula of unit cell is AB2C3.
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
53
ZA
(AIEEE 2011)
8
8
5
2
So formula of compound is AB5/2
ZB
i.e., A2B5
427. Answer (3)
In Frenkel defect, ions occupy the interstial site like interstitial defect and create a vacancy in the lattice site
like vacancy defect. So, it is the combination of vacancy as well as interstitial defect.
428. Answer (2)
429. Answer (1)
In case of BCC structure,
3a
2
r r
3 3.5
2
r+ + r = 3.031
r r
Cl
[JEE (Main)-2014]
Cl
Cl
+
Cs
Cl
Cl
Cl
Cl
2rCl 2rCs 3 a
rCl rCs
3a
2
1
1
8 6 4
8
2
(12.5% T.V )
( 50% O.V.)
54
Physical Chemistry
a 80
40 pm
2
2
a
2 2
(AIEEE 2009)
361
2 2
127.6 pm
= 670.3 pm
2 (r+ + r) = 670.3 pm
670.3
pm 181 pm = 154 pm
2
436. Answer (3)
r+ =
Factual type.
437. Answer (2)
438. Answer (1)
For fcc,
ax 2
a
2
3
a
a3
2 2
2
439. Answer (2)
The length of body diagonal is a 3 . Two tetrahedral voids are present on each body diagonal at the distance
a 3
.
2
440. Answer (3)
The simplest unit of hcp structure is hexagon. Other statements are correct.
441. Answer (4)
For bcc,
a 3 5 3
2.165
4
4
r = 216.5 pm
r
(AIEEE 2012)
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
55
rNa 0.75 rK
Putting the value of rNa in
0.75 rK
rCl
rK
rCl
0.55
(i)
rNa
rCl
0.55
0.733
0.75
(Side for unit cell for KCl = 2(rK rCl ) , Side for unit cell for NaCl = 2(rNa rCl ))
1
1
1
Number of Cl ions = 4 2 4 2
8
2
2
56
Physical Chemistry
V1 = Vtetragonal = a2c
(because a = b c, = = = 90)
V2 = Vhexagonal = a2c
3
2
V1
2
V2
3
98 1000 1.6
32
49
100
1 kg =
9.1 10
1
9.1 10
31
31
1
6.023 10
23
1
9.1 10
31
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
57
n
Molarity = v
2
6
10
M=
0.5
M = 2 106 M.
460. Answer (4)
According to Raoults law for non-volatile solution.
PB P
PB
A solute
B solvent
xA
PB P
PB
Mass
1000 NVml
Eq mass
(i)
1000
g
5
w
Eq mass
g
1000 w 5
Eq mass
(ii)
w 5 = 0.5 100
w
(mass of solvent )
N 0.5 N
V 100 ml
= 10 g.
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
58
Physical Chemistry
a3Na
N
= 74.7 g mol1
467. Answer (1)
468. Answer (2)
469. Answer (3)
470. Answer (3)
471. Answer (1)
Osmotic pressure () =
i1n1RT
1 =
= 1 + 2
nRT
v
and 2 =
i2n 2RT
v
and v1 + v2 = v
i1n1 i2n 2
RT
=
T ini in2
v v
v
or
i1n1 i2n 2
= v v RT .
1
2
PB P
PB
in A
(i)
in A nB
A solute
B solvent
solution is concentrated
PB = 760 mm-Hg
nA =
5.85
= 0.1 mole
58.5
nB =
180
= 10 moles
18
P = 750 mm-Hg
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
59
AB A B
for
i=1+
760 750
0.1(1 )
760
(1 )0.1 10
1
0.1(1 )
76
10
1+=
(dilute solution)
100
76
= 0.315.
474. Answer (3)
Solution will be ideal and for ideal solution Hmix. = 0.
475. Answer (3)
Al 2 (SO 4 ) 4 2Al
1 mole
2 moles
3SO 4 2
3 moles
nsolute
1000
molality = w
solvent
3=
n
1000
250 1
n=
3
mole
4
d v
w 250 1
w 250 g
3
2 3
3
mole of Al2SO4 producing =
mole
4
1 4
2
3
23
23
6.023 10 9.03 10 ions.
2
2Cl
i1 = 1 + 2
i1 = 1 + 1
i1 = 2
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
60
Physical Chemistry
1
(CH3 COOH)2
2
2
i2 = 1 0.25
i2 = 0.75
i2 = 1
Total value of
i = i1 + i 2
i = 2 + 0.75
i = 2.75
i1 = 1 + 3
3Cl
( = 100%)
i1 = 4
NaCl Na Cl
1
i=1+
( = 100%)
i=2
1 = i1RT
2 = i2cRT
i
1
2 i2
1
4
2
1 : 2 = 2 : 1.
Physical Chemistry
61
1000 1000
55.56
18
1000
(i)
xA
xA
3 = x 55.55
B
xA
x = 0.054
xA
xB
xA + xB = 1
0.054
xA
0.054
x A 1
1
0.054
xA
A solute
B solvent
(i)
1
19.5
xA = 0.05
PB P = xA PB
PB P = 0.05 760 = 38.97 mm-Hg.
[JEE (Main)-2015]
PA PS nB
=
PS
nA
185 183 WB MA
183
MB WA
as we know
2
1.2 58
=
183 MB 100
MB =
1.2 58
183
2 100
= 63.68 g / mole
490. Answer (3)
491. Answer (1)
SO2 + NaOH NaHSO3
meq. of NaOH = meq of NaHSO3
NV
(NaOH)
g
1000(NaHSO 3 )
eq mass
g
1000
104
gNaHSO 1.04 g (mass of NaHSO )
3
3
0.1 1 100
PB P
PB
xA
A solute
B solvent
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
62
Physical Chemistry
1.04
104
36
PB
18
PB P 0.01
PB
3
PB P
(dilute solution)
0.01
1 (atm)
2
PB P
= 0.005 atm
(PB P) =
RT0 2
1000 Hv
2 (373)
9.72
3
1000
10
18
Kb = 0.52 mole/kg
Kb
Tb = Kb m
Tb = 0.52 0.1 = 0.052.
1
C H COOH
n 6 5
1
i = 1
100%
i = 1 1
n
i = 1 1
n
Tf (obserbed)
i=
(i)
Tf (calculated)
Tf
Kfm
(ii)
12.2 1000
122 100
m = 1 molal
m=
0.93
1.86 1
1
i=
2
Putting the value of i in equation (i)
i=
i 1 1
n
1
1
1 1
2
n
n = 2.
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
63
log Tb
log m
Tb = Kbm
(tan = 1, = 45)
m=1
nA
xA ~ n
B
(nA + nB ~ nB)
PB P in A
ix A .
PB
nB
CART = CBRT
CA = CB.
( vapour phase )
P A x A
P A x A PB x B
xA =
50 0.5
50 0.5 100 0.5
xA =
25
75
xA = 0.33.
R.H
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
64
Physical Chemistry
P XAPA0 XBPB0
505. Answer (3)
2A
A2
1
0
1
2
2
1
1 0.5
2
506. Answer (2)
i 1
Kb
3A
A3
1
3
2
3
2 1
1 0.33
3 3
i 1
RTb2 M1
8.314 383.7 92
Hv
1000Hv
1000 3.32 103
2
= 34 kJ mol1
507 Answer (2)
i = 5 for K4[Fe(CN)6) and i = 5 for Mohr salt.
507a. Answer (3)
(AIEEE 2010)
Tf = i Kfm
i for Na2SO4 is 3(100% ionisation)
Tf = 3 1.86
0.01
1
Tf = 0.0558 K
507b. Answer (1)
[JEE (Main)-2014]
i CRT
WC6 H6 0.8 78
m
0.2 1000
3.2
0.8 78
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
65
Fe
E0 = ?
3+
(1)
(AIEEE 2009)
Fe
2+
E0 = 0.439 V
(2)
Fe
E = 0.036 V
(3)
E0 + 2 0.439 = +3 0.036
E0 = +0.77 V
0.0591
1
log
1
2x
E=
Q=
PH2
[H ]2
518. Answer (4)
519. Answer (4)
Fact.
520. Answer (2)
Only H2O is electrolysed.
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
66
Physical Chemistry
22.4
= 3.73 L
6
...(i)
2H2O O2 + 4H+ + 4e
...(ii)
2x
units costing Rs.x
22.4
NO2
NO
nf 2
2e +
n=2
gram Eq = n mole = 2 0.5 = 1
1 Eq nitrogen benzene require 1F
Net charge =
1
= 1.25 F
0 .8
OH /Fe(OH)3 /Fe
E0
OH /Fe(OH)3 /Fe
E =
E0
Fe2 /Fe
0.0591
0.0591 (36.4)
log10 36.4
0.3
3
0.75V
Physical Chemistry
67
WAg
WMg
E Ag
EMg
K=
[JEE (Main)-2014]
C A C
Here A = B
C B C
0.0591
log [H+]2 = Eo + 0.0591 pH
2
0.250 35 60
F = 5.44 103 F
96500
5.44 10 3
1.36 10 2
0.4L
G
H
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
68
Physical Chemistry
(AIEEE 2009)
CH3OH(l) +
3
O (g) CO2(g) + 2H2O(l)
2 2
G
100
H
702.6
100
726
97%
1
538 Answer (2)
CHCOOH + H2O
CH3COO + H3O
c
48.15
0.1232
x (degree of ionisation) = =
390.7
0
Ka(ionisation constant) =
cx2
1.0283 10 3 (0.1232)2
=
= 1.78 105
(1 x)
(1 0.1232)
97.1 (ohmcm2equiv1) =
[JEE (Main)-2014]
1
1
cm
1.4 10 2
Now, R
l
a
l R
50 1.4 10 2
a
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
69
l
50 1.4 10 2
a
l
a
1 1 l
R a
1
1
50 1.4 10 2 =
70 10 2 = 2.5 103 S cm1
280
280
Now, m
1000
2.5 10 3 1000
=
= 5 S cm2 mol1 = 5 104 S m2 mol1
M
0.5
dE
S
=
dT
nF
540. Answer (3)
Order of deposition, Br > OH > N O3 > F
541. Answer (1)
E > 0, Q < 1.
541a. Answer (4)
(AIEEE 2011)
1
H2
H e
2
Apply Nernst equation
1
PH 2
0.059
E0
log 2
1
[H ]
E
0.059
21/2
log
1
1
Therefore E is negative.
542. Answer (4)
E = Z 96500
543. Answer (1)
Fact.
544. Answer (3)
Electrons released from Fe move towards impurity.
545. Answer (1)
546. Answer (2)
Cell is used for prepation of NaOH.
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
70
Physical Chemistry
1
O + 2e, H2O2 O2 + 2e
2 2
NaH
Na
( cathode)
1
H2 (g)
2
anode
[JEE (Main)-2014]
On electrolysis only in case of Ca2+ salt aqueous solution H2 gas discharge at Cathode.
Case of Cr
At cathode : Cr3+ + 2e Cr
So, Cr is deposited.
Case of Ag
At cathode : Ag+ + e Ag
So, Ag is deposited.
Case of Cu
At cathode : Cu2+ + 2e Cu
Case of Ca2+
At cathode : H2O + e
1
H + OH
2 2
E
it
96500
0.0591
[Cu 2 ]1
log
2
[Cu 2 ] 2
H2
H +e
2
K = [H+] = C1
E = E 0.0591 logC1
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
71
E decreases if C1 increases
1
Cl
Cl2 e
2
1
1
K
[Cl ] C2
E = E + 0.0591 logC2
E increases if C2 increases
+
Ag
Ag + e
K = C3
E = E 0.0591logC3
E decreases if C3 increases
556. Answer (2)
557. Answer (4)
For spontaneous cell reaction, E > 0.
557a. Answer (3)
(AIEEE 2012)
G3 = G1 + G2
n3E3 = n1E1 n2E2
+3E3 = 2 1.26 1 0.336
E3 = 0.728 V
559. Answer (2)
Cu does not react with dilute H2SO4.
560. Answer (2)
w=
E
it
96500
127
1
10 =
i 60 60
96500
i = 2.11 A
561. Answer (2)
It requires no gaseous reactant.
562. Answer (1)
Eo = +0.22 1.36 = 1.14 V
E Eo
0.059
log PCl2
1
72
Physical Chemistry
1
2 105
2 1.6 1019
1
1
moles
14
N0
1.6 10
1
1.6 6.023 1014 1023
= 1010
Normality =
Molarity =
1000 8 10 5
400
Normality
10 4 M
2
Ksp = S2 = 108 M2
565. Answer (3)
Cu /Cu
0.5208 V
+
Ag + e ; EAg/Ag+ = 0.80V
Ag
AgI+e
Ag + I ;
+
Ag + I
AgI
EI / AgI/Ag+ = 0.15V
ECell = 0.95V
0.0591
log k sp
1
0.95
log K sp
0.0591
D
0.059
log 0 at equilibrium
H
2
D
0.006 0.059log
H
D
D
0.102 log 100.102 1.2
H
H
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
73
a
2.303
log
t
a x
a
0.6932 2.303
log
t
( t / 2)
a x
a
0.6932
log
2 2.303
a x
a
0.15
log
a x
a
1.413
a x
a = 1.413a 1.413x
0.413a = 1.413x
x 0.413
a 1.413
0.413
100
1.413
= 29%
572. Answer (1)
t 1/ 2 &
1
a
n 1
2 t1/2 = 50
t1/2 = 25 mins
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
74
Physical Chemistry
ln 2
k
k=
(AIEEE 2009)
2.303 0.301
6.93
a
2.303
log
k
a 0.99a
Also, t =
1
2.303
t = 2.303 0.301 6.93 log 0.01 = 46.05 minutes
(i)
(ii)
(iii)
k[0.1] [0.4] = 4 10
k[0.2] [0.2] = 2 10
dividing equation (i) by (ii)
1 1
2 2
n=1
m=0
[JEE (Main)-2014]
2A B C D
Rate of Reaction =
1 d[A]
d[B]
d[C] d[D]
2 dt
dt
dt
dt
d[C]
k[A]x [B]y
dt
...(i)
...(ii)
...(iii)
1
1
2
y0
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
75
1
1
2 2
x 1
Hence
d[C]
dt
k[A]1[B]0 .
75
32 K
65
16 K
55
8K
45
4K
35
2K
25 K
Since the value of rate constant will be increased by 32 times therefore the rate will be increased by 32 times.
577. Answer (1)
t1/2 a
t1/2 = ka
log t1/2 = log k + log a
y = c + mx
m=1
= 45
x
10
for zero order reaction =
= 10
t
1
In second case k =
20
= 10
2
30
= 10
3
Since rate constant (k) is equal in each case therefore reaction follows the zero order mechanism.
In third case k =
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
76
Physical Chemistry
r2 = k[A]2
r3 = k[A]3
When the rate constant k is same for three reaction it is clear that
r1 = r2 = r3 when [A] = 1
r1 > r2 > r3 when [A] < 1
r1 < r2 < r3 when [A] > 1
582. Answer (3)
Energy
Ea
H
R
z
Reaction progress
Order of reaction is 2
Order of reaction = 2
Physical Chemistry
77
Ea
RT
y = c + mx
slope of graph =
Ea
R
2 B (g) C (g)
t 0 PA 90
t t 90 x
After time t
0
2x
0
x
90 + 2x = 180
x = 45
k=
2.303
90
log
10 60
90 45
0.6932
10 60
= 1.155 103 s1
591. Answer (1)
592. Answer (3)
Heat of the reaction H = Ea f Eab
H = x
2 .2
= 1.1 M
2
r1 = 2.4 M s1
r2 = 0.6 or
2 .4
4
(AIEEE 2012)
78
Physical Chemistry
d [I ] 0.5 0.46
0.004 M min 1
dt
10
d [I2 ]
0.002 M min 1
dt
tav =
N
N
e = 0 0 e e
N
N
t
N=
N0
e
2.303
a
2.303
log
2
=
k
a 0.99a
k
t=
2.303 2
k
1
t = 2.303 2 = 4.604 tav = 4.6
k
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
79
K 2Ea K 2Ea
K 2 K a
1.0 10 2 60 3.0 10 2 70
1.0 10 2 3.0 10 2
= 67.5 kJ mol1
(i)
R
= k[2A]x [2B]y
2
(ii)
R
= k[2A]x [B]y
4
(iii)
x = 2
t1/ 2
1
a
n 1
t1/2 an 1 = constant
n=2
t =
0.6932
k
2.303
100 2.303
log
log1000
k
0 .1
k
6.909
k
t = 10 t1/2
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
80
Physical Chemistry
ln 2
k
k =
(AIEEE 2009)
2.303 0.301
6.93
Also, t
a
2.303
log
k
a 0.99a
1
2.303
6.93 log
2.303 0.301
0.01
= 46.05 minutes
610. Answer (3)
k2
e(E1 E 2 ) / RT
k1
E1 E 2
2
2 .5
3
RT
2 10 400
k2
e 2 .5
k1
k 2 e 2 .5 k 1
611. Answer (1)
At very high conc. of NH3
1 + k2 [NH3 ]
rate =
k2 NH3
k 1[NH3 ]
constant
k 2 [NH3 ]
This follows the zero order kinetics therefore rate is independent of conc. of NH3 .
612. Answer (3)
A (g)
2 B (g) C (g)
initial pressure
P
0
After reaction P P
0
2P
0
P
2P = Pt P0
Pt P0
P =
2
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
81
P0
2.303
log
=
P0 P
t
2.303
P0
log
t
0 P P0
P t
2 P0
2.303
log
=
3 P0 P
t
t
A (g)
B (g)
Initial pressure
400
0
3
3
After t 40 mins 4001
400
4
4
C (g)
0
3
400
4
= 400 400
3
4
= 400 + 300
= 700 mm of Hg
614. Answer (1)
Let N0 and N be the number of atoms of the radioactive substance present at the start and after 5 minutes
respectively rate of disintegration at the start = N0 = 275 and the rate of disintegration after 5 minute = N
= 270 dividing both,
Or,
N0
1.76
N
We know that
N0 475
N
270
N
2.303
log10 0
t
N
2.303
log10 1.76 = 0.113 minute1
5
0.693 0.693
6.1 minute
0.113
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
82
Physical Chemistry
100
100
= 0.0315 g
Activity =
Activity =
0.693
Weight
t1/2
Atomic weight Avogadros number
0.693
1.3 109 365 24 60
0.0315
6.023 1023
40
k1
100
k1 k 2
2.5 10 3
2.5 10 3 1.25 10 2
100
2.5 10 3 10 2
1.50 10 2
25
1.50
= 16.66%
% z = 100 16.66 = 83.34%
617. Answer (2)
K1
Bicyclohexane
K2
Cyclohexene
Methyl cyclopentene
K1
Percentage of cyclohexene = K K 100
1
2
1.26 104
1.26 104 3.8 10 5
100
= 77%
% of methy cyclopentene = 23%
618. Answer (2)
kf = 4 104
kb = 2 104
keq =
kf
4 10 4
2 10 8
4
kb
2 10
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
83
(i)
(ii)
Ea
(E 20)
a
500 R
400 R
4 Ea = 5 Ea + 100
Ea = 100 kJ mol 1
620. Answer (4)
Rate = k[N2O5 ]
2.4 105 = 3 105 [N2O5 ]
[N2O5 ] =
2.4
0 .8
3
0.693 0.693
t1/2
22
222th
K1
2
K 2 98
t t1
2
N
ln N
. 0
ln 2
N0 24 N 48 g
0
0.693
4.5 109
t
2.303
4 1
log
t
4
84
Physical Chemistry
Ea
K1 K 2
102 3 102
= 67.5 kJ mol1
627. Answer (4)
Apply
x
ap
. At high P, 1 + bp bp.
m 1+ bp
Ea
RT
A
Ea
e RT
As Ea decreases, K increases
Hence rate of reaction increases.
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456
Physical Chemistry
85
(AIEEE 2009)
86
Physical Chemistry
4
D
Aakash Educational Services Pvt. Ltd. Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-75 Ph.011-47623456