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Compression
Overview
In this section, you will learn about the specific variables that force gases to behave in
a predictable fashion. These variables include:
Pressure.
Temperature.
Volume.
Density and specific gravity.
Pressure
All gases are made of tiny particles
called molecules. Because
molecules move in all directions,
gas pressure is exerted in all
directions. As the molecules
move, gas molecules exert a force
on everything they touch. This
force is called pressure.
Pressure is the amount of force
exerted on 1 unit of area. It is
usually measured in pounds per
square inch, or PSI. Pressure is
also measured in thousands of
pascals (kPa). A pascal (Pa) is the
amount of pressure equal to the
force of one newton (N) acting
uniformly over an area of one
square meter.
At 1 PSI (7 kPa), gas acting on a 3 square inch (0.002 square meter) surface exerts a
total force of 3, or 1 x 3 pounds. In newtons, this would be 14 newtons, or 7 x 0.002 x
1,000. The total force of compressed gas is the PSI times the number of square inches
the gas is acting on, or:
PSI is the most common measure of pressure in the United States. Your facility may
use kPa or other units of measurement.
Gas pressure is caused by the _______ of gas
molecules.
Heat.
Size.
Motion.
Answer
Atmospheric Pressure
Atmospheric pressure is the pressure
exerted by the air around us.
The weight of a 1-square-inch column of air
that extends to the top of the atmosphere is
about 14.7 pounds at sea level. Likewise, a
1-square-centimeter similar column of air
weighs about 100 grams. Atmospheric
pressure is equal to about 101 kilopascals
(kPa).
Answer
Answer
Gauge Pressure
Most pressure gauges show pressures either above or below atmospheric
pressure. This is known as gauge pressure. Gauge pressure is measured in pounds
per square inch gauge (PSIG) or kilopascal gauge (kPag).
Pressures that are less than atmospheric pressure are measured with a vacuum gauge
or with a mercury manometer. A vacuum gauge is calibrated to read from 0 to 14.7
PSI (101 kPa) vacuum, or from 0 to 29.9 inHg (760 mmHg) vacuum, or both. On a
pressure gauge, 0 indicates normal atmospheric pressure.
Answer
Absolute Pressure
Absolute pressure is gauge pressure plus atmospheric pressure. It is measured in PSIA
(kPaa), or pounds per square inch absolute (kilopascal absolute). If a pressure gauge
at sea level reads 100 PSIG (689 kPag), the absolute pressure is 100 PSI plus 14.7 PSI
(689 kPa plus 101 kPa), or 114.7 PSIA (790 kPaa). At sea level:
Answer
Answer
Answer
Answer
Answer
Temperature
measure the same amount of temperature increase, but the temperature in Rankine is
always 460 more than the temperature in Fahrenheit. Conversions between F and
R can be made using addition and subtraction.
Compare the Celsius and Kelvin temperatures. Celsius is abbreviated C, and Kelvin is
abbreviated K. Absolute zero in Kelvin (0 K), is -273 C. Both Celsius and Kelvin
measure the same amount of temperature increase, but the temperature in Kelvin is
always 273 more than the temperature in Celsius. Conversions between C and K
can be also be made using addition and subtraction.
To convert F to R, add _______ to the
Fahrenheit reading.
Answer
To convert R to F,
subtract 460 from the
Rankine
reading. Temperatures
given in Fahrenheit are
always 460 higher when
they are converted to
Rankine.
Answer
To convert K to C,
subtract 273 from
the Kelvin
reading. Temperatures
given in Celsius are always
273 higher when they are
converted to Kelvin.
Volume
The volume of a substance is the space it occupies.
The volume of this cube is 1 cubic foot (cubic meter). It
is filled with gas, and the gas occupies all the space in the
cube. So, the volume of gas in the cube is 1 cubic foot
(cubic meter).
Cylinder A.
Cylinder B.
Answer
Answer
Answer
Standard conditions for the measurement of gas volume is 14.7 PSIA (101 kPaa) and
60 F (15.6 C). SCF means standard cubic feet, and SCF is the volume a gas will
occupy if it is measured at a standard pressure of 14.7 PSIA and 60 F. Likewise, SCM
means standard cubic meters, and SCM is the volume a gas will occupy if it is
measured at a standard pressure of 101 kPaa and 15.6 C.
At atmospheric pressure, a cubic foot (cubic meter)
of gas contains less than one SCF (SCM) if the
temperature is _______ than 60 F (15.6 C).
More.
Less.
10
Answer
Units of Measurement
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cubic meters.
Answer
Answer
Answer
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Answer
Overview
The main variables that influence gas behavior include pressure, volume, and
temperature. The gas laws describe gas behavior in predictable terms involving these
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variables.
To
To
To
To
convert
convert
convert
convert
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Boyle's Law
A basic law of gas behavior is based on the
reasoning of Robert Boyle. He discovered
that gas pressure is due entirely to the
heat motion of molecules. Boyle reasoned
that gas pressure is not caused by
gas density or weight, but by a
relationship between pressure and
volume.
Boyles Law states that a change
in absolute pressure of gas is inversely
proportional to a change in volume.
Answer
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Answer
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Answer
Answer
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Charles' Law
When the temperature of a gas
increases, the molecules move faster. If
this happens in a constant volume
container, the pressure of the gas
increases.
Charles Law states that if temperature
increases while pressure remains the
same, the volume of gas increases
in direct proportion to the increase in
absolute temperature. For example, if
absolute temperature doubles, the
volume doubles, if pressure remains the
same.
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Answer
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Answer
70 F is 530 R and 80 F is
540 R. Likewise, 21 C is
294 K and 27 C is 300 K.
Answer
Answer
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The General Gas Law expresses the relationship between pressure (P), volume (V), and
temperature (T), by this equation:
If you multiply the original pressure and volume of a gas and divide by its temperature,
you have a constant number. Then, any new changes in pressure, volume, or
temperature, when multiplied and divided in the equation PV/T, must result in the same
constant number. Because the product or total value of this fraction must always be
the same for a given gas, you can find the exact amount of change in one of these
variables, if you know the other two variables.
The value of the constant number PV/T is sometimes called the gas constant R. It is
different for different gases. The value of R is a property of gases, so you must always
compare the same gas or mixture of gases to calculate the PV/T changes. The gas laws
state that for any gas or mixture of gases, the value of PV/T will always be the same.
If pressure falls without a change in volume, then:
The temperature has also fallen.
The temperature has increased.
Answer
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Answer
Review
In this section, you learned about the gas laws that predict gas behavior. You learned
that these laws only apply when conditions are ideal. Under some conditions, gases
may behave in a slightly different manner than predicted by the gas laws.
The three laws include:
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Overview
In this section, you will learn about factors that influence compressor
operations. These factors include:
Ratio of compression.
Heat of compression.
Intercooling.
Ratio of Compression
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A compressor is a machine that works to increase gas pressure. The compressor takes
in gas at one pressure (suction pressure), and then discharges it at a higher pressure
(discharge pressure). The difference between the suction pressure and the discharge
pressure represents the work done by the compressor.
The ratio of compression (R) is the ratio of the absolute discharge pressure to the
absolute suction pressure. If the compressor doubles absolute gas pressure, R is 2. If
the compressor triples absolute gas pressure, R is 3.
R is calculated by dividing the absolute discharge pressure by the absolute suction
pressure:
/20 (345/138).
20
/50 (138/345).
Answer
Answer
kPaa = kPag + 101
= 310 + 101
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45
/14.7 (411/101).
/14.7 (310/101).
59.7
/14.7 = 4.06
59.7
/45 (411/310).
In metric terms:
14.7
/59.7 (101/411).
411
/101 = 4.06
Answer
If a compressor takes in gas at 13 PSIA, or 1.7 PSI vacuum (90 kPaa, or 11 kPa
vacuum) and discharges the gas at 14.7 PSIA (101 kPaa), the R is 14.7/13 or
approximately 1.13 (101/90 or approximately 1.12).
Multiplying the absolute suction pressure times R gives the absolute discharge pressure
of the gas being compressed.
If suction pressure is 14.7 PSIA (101 kPaa) and R is
2.5, absolute discharge pressure is approximately:
5.88 PSIA (40.4 kPaa).
36.75 PSIA (252.5 kPaa).
Answer
2.5 = D/14.7
Discharge = 36.75. This is
equivalent to approximately
22.05 PSIG.
In metric terms:
2.5 = D/101
Discharge = 252.5
kPaa. This is equivalent to
approximately 151.5 kPag.
R=
Answer
45
/15
In metric terms:
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R=
310/103.
Answer
For example, suppose two compressors with the same suction are suctioning
methane. Each compressor operates at an R of 3, but with different pressures.
The amount of temperature increase caused by these
two compressors is:
The same.
Different.
Answer
For the same gas at the same suction temperature, the amount of temperature
increase in compression depends only on the ratio (R). Compared with heavy gases,
light gases have a greater temperature increase for the same ratio of
compression. Light hydrocarbon gases (and hydrogen) tend to show more heat of
compression than heavier ones.
For example, methane is lighter than ethane, so methane experiences a greater rise in
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Suction temperature.
Ratio (R).
The type of gas.
Answer
N Factor Chart
Gases may have different
specific gravities ("n"). The
N Factor Chart shows the
series of curves for various
average compressor
temperatures.
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Answer
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Decreasing R.
Cooling the gas before it enters the compressor.
Cooling the compressor.
Answer
Answer
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Intercooling
This diagram represents a
multi-stage compression unit.
The gas is being compressed in
two stages. The discharge from
the first compressor is passed
through a cooler before it
reaches the second stage
compressor. Intercooling is
used to reduce the temperature
of the gas before it goes
through the second stage
compressor.
Suction pressure.
Discharge pressure.
Answer
In some cases where R is less than 3.0, compressors are multi-staged without
intercooling to reduce the load on each compressor. Without intercooling, multi-staging
does not reduce final discharge temperature. If the gas is allowed to enter each stage
at its existing temperature, the overall total temperature rise is the same as singlestage compression. When R is 3.0 or more, it is necessary to use two or more stages
with intercooling.
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Increases volume.
Answer
Section 4:
Overview
In this section of the program, you will learn about factors affecting
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Suction cooling.
Capacity and rate.
Horsepower.
Suction Cooling
When temperature is lowered and pressure remains
the same, the volume of gas decreases.
For example, if a balloon is filled with gas at
atmospheric pressure, then cooled, it will
shrink. When gas is cooled, it becomes denser.
More standard cubic feet (cubic meters) are
compressed for the same actual cubic feet (cubic
meters) when the gas is cooled. One reason
for intercooling is to reduce the final temperature of
the gas. But, a more important reason is to shrink
the volume of the gas before it reaches
the compressor's second stage.
About 1% of horsepower is saved for every 5 F
(2.8 C) absorbed at the intercooler. Multi-staging
with intercooling reduces the _______ required for a
given compression.
Temperature.
Horsepower.
Volume.
All of the above.
Answer
Suction cooling decreases the final temperature of the gas and permits more gas to be
processed for the same power input.
Suction cooling can be used to _______ the power
required to maintain a constant flow rate in SCF
(SCM) per hour or day.
Decrease.
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Increase.
amount of horsepower
needed for compression.
Answer
Answer
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Answer
Rate can also be expressed in cubic feet (cubic meters) per minute, or CF/min
(CM/min). For example, a rate of 65 cubic feet (cubic meters) per minute is
abbreviated 65 CF/min (65 CM/min).
A capacity of 100 SCF/min (100 SCM/min) means
the compressor is taking in and discharging _______
SCF (SCM) of gas every minute.
Answer
Answer
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Answer
Horsepower
The basic unit of measuring work in compressor systems is the foot-pound. One footpound is the work done in lifting 1 pound of weight the distance of 1 foot. Work can
also be measured in joules (J). One joule is equal to one newton-meter (Nm), which is
force in newtons times distance in meters. To lift a 10-pound weight (44.5 newtons) a
distance of 1 foot (0.3 meters) requires 10 foot-pounds (13.4 Nm, or 13.4 joules) of
work.
Work is force times distance. Lifting a 60-pound
(267 newton) weight 3 feet (0.9 meters) off the floor
requires _______ of work.
20 foot-pounds (296.7 joules).
180 foot-pounds (240.3 joules).
60 x 3 = 180 foot-pounds
of work. In metric, 267 x
0.9 = 240.3 joules.
Answer
Answer
99,000 33,000 = 3. In
metric, 134,280 44,760 =
3.
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Exercise: Horsepower
HP can be determined by knowing
the foot-pounds (joules) of work
done and the time taken to do
it. As the amount of foot-pounds
(joules) per unit of time
increases, the HP required
increases. When more time is
consumed in doing work, the HP
required
decreases. This table lists other
units of energy and power.
746 watts
1 Horsepower
1 Horsepower
1 Horsepower
1 BTU
778 foot-pounds
1 BTU
1 BTU
1,000 watts
1 Kilowatt
1,055 joules
1 Kilowatt
1.34 horsepower
1 Kilowatt
1 Kilowatt
1 kilowatt
Answer
Answer
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Answer
Answer
The work done by a compressor depends on the rate of flow through the compressor,
and on the ratio (R) of compression, the suction temperature, and the kind of gas being
compressed. On a constant-speed unit, HP loading can be adjusted by changing R.
Intercooling reduces the actual volume of the gas as
it enters the second stage of the compressor and
permits handling the gas with _______ HP.
More.
Less.
Answer
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Glossary
Absolute Pressure
Total pressure, equal to gauge pressure plus atmospheric pressure; measured in Pounds per
Square Inch, Absolute (PSIA) or Kilopascals Absolute (kPaa). To convert gauge pressure to
absolute pressure, add atmospheric pressure (approximately 14.7 PSI or 101.3 kPa at sea level) to
the gauge pressure reading.
Absolute Zero
The lowest possible temperature; the point where all molecular motion ceases and there is no
heat; or at which an ideal gas, kept at a constant volume, would exert no pressure.
Air-In-Stream Analyzer
Type of analyzer that is used to detect light hydrocarbon gases in the air.
Asphyxiation
Suffocation.
Atmospheric Pressure
Pressure caused by the weight of the atmosphere. Normally 14.7 PSIA (101.3 kPaa) at sea level.
Atmospheric pressure decreases as altitude increases (above sea level), and increases as altitude
decreases (below sea level). Also known as barometric pressure.
Atom
The smallest particle of an element that retains all the properties of the element.
Barometer
Instrument used to measure atmospheric pressure.
Barometric Pressure
Atmospheric pressure expressed on a barometer.
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Boiling Point
The temperature at which a substance boils, or when the liquid is converted into vapor. The boiling
point of a substance increases if pressure is raised and decreases if pressure is lowered. The
corresponding term for mixtures that exhibit a boiling range is "bubble point."
Boiling Range
The range of temperature where a given product or process stream boils, from initial to final boiling
temperature. Usually determined at atmospheric pressure and by a standardized distillation test,
over which boiling or distillation of a liquid proceeds. Only a pure substance has one definite boiling
temperature at a given pressure. Mixtures of pure substances, such as petroleum products, exhibit a
boiling range.
Boyles Law
Principle based on the idea that a change in absolute pressure of a gas is inversely proportional to a
change in volume when kept at a constant temperature:
Butane
A hydrocarbon fraction; at ordinary atmospheric conditions butane is a gas which is easily liquefied.
Calibration
The act of checking or adjusting (by comparison with a standard) the accuracy of a measuring
instrument; the determination of the true value of the spaces in any graduated instrument.
Capacity of Compression
Refers to the speed of compression.
Celsius Scale
Temperature scale on which the freezing point of water registers 0 and the boiling point registers
100. Temperatures are expressed in C.
Charles Law
Principle based on the idea that the volume of a gas at a constant pressure varies directly with the
absolute temperature.
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Combustion
Chemical reaction between a fuel and oxygen that releases energy; a process that converts
chemical energy to thermal energy.
Compression
The process of reducing volume by pushing together, increasing density and pressure.
Compression Ratio (R)
An index of the work done by a compressor; the ratio of the absolute discharge pressure to the
absolute suction pressure.
Compressor
Rotating equipment used to increase gas pressure and move a process gas. The compressor takes
in gas at one pressure (suction pressure), and discharges it at a higher pressure (discharge
pressure). Compressor types include centrifugal or reciprocating.
Condensate
Liquid formed as a result of cooling or compressing a vapor. Also refers to the light hydrocarbon
liquid formed when hydrocarbon vapor is cooled. Condensed steam is also referred to as
condensate.
Condensation
The process by which gas or vapor changes to a liquid.
Contraction
Decreasing in size or volume.
Density
Mass of a substance per unit of volume, or the heaviness of a substance.
Dewpoint
The temperature where a vapor begins to condense. A drop in temperature below the dewpoint will
cause the vapor to condense into droplets or fog. The dewpoint temperature of a vapor decreases if
the pressure is lowered, and increases if the pressure is raised.
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Direct Relationship
The relationship between two variables; when one variable changes in one direction, the other
variable changes in the same direction.
Energy
The capacity to do work or cause heat to flow.
Evaporation
The process of molecules leaving a liquid in vapor form. Also called vaporization.
Expansion
Increasing in size or volume.
Explosive Limits
Calculated values of the range considered dangerous for the percentage of hydrocarbon vapors in
air. Hydrocarbon/air samples falling within that range indicate an explosive mixture.
Explosive Mixture
A combination of a hydrocarbon vapor with air which will explode if ignited.
Fahrenheit Scale
Temperature scale where the boiling point of water registers 212 and the freezing point registers
32. Temperatures are expressed in F.
Flammable Range
A range of fuel concentration that must be present for a fuel to burn. Below the lower limit, there is
not enough fuel to burn; above the upper limit, the fuel has displaced too much oxygen to burn.
Flash Point
Temperature that will produce just enough vapor to cause a momentary flash when ignited but will
not sustain a continuous burn.
Flow
Fluid movement from one place to another caused by pressure differences.
Fluid
Any substance that flows and has no definite shape.
Foot-Pound
The basic unit of horsepower; a unit of work equal to the work done by lifting a mass of one pound a
vertical distance of one foot.
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Force
Energy applied in any direction, measured in pounds or newtons. Force tends to produce or prevent
motion.
Freezing Point
Temperature where a substance will solidify if energy is withdrawn, or melt if energy is added.
Friction
The force that resists motion between bodies in contact with one another.
Fuel
Any combustible matter that is burned to generate thermal energy.
Gas
State of matter where molecules are in random and chaotic motion. Gases always assume the
shape of their containers and are compressible. In contrast with a vapor, the term gas is used for
substances that are in the gaseous state at ambient conditions.
Gasoline
Light petroleum fraction with an approximate boiling range between 100 F - 400 F (38 - 204 C),
obtained by distillation, cracking, polymerization, and other processes.
Gauge Pressure
The pressure above atmospheric pressure; the difference between the total or absolute pressure at
the point of measurement and atmospheric pressure. Most pressure gauges read gauge pressure,
not absolute pressure. Measured in Pounds per Square Inch, Gauge (PSIG) or Kilopascals Gauge
(kPag). To convert gauge pressure to absolute pressure, add 14.7 to the PSI measurement or 101.3
to the kPa measurement.
General Gas Law
Law which states that gas volume changes in direct ratio to changes in absolute temperature, and
that gas volume changes in an inverse ratio to changes in absolute pressure.
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Heat
Form of energy. Measure of the kinetic energy of the molecules of a substance.
Heat of Compression
Temperature increase resulting from compressor operation.
Horsepower
The time rate of doing work, or a measure of foot-pounds (kilogram-force per meter) of work done
per unit of time. 1 horsepower (HP) is 33,000 foot-pounds (75 kilograms-force per meter) of work
done in 1 minute.
Hydrocarbon
Compound containing only hydrogen and carbon. The simplest hydrocarbons are gases at ordinary
temperatures; but with increasing molecular weight, they change to a liquid form and, finally, to the
solid state. They form the principal constituents of petroleum:
Paraffin: A type of hydrocarbon with single bonds (saturated) that are usually waxy and
can have high pour points.
Olefin: An open chain, unsaturated hydrocarbon, with at least one carbon-carbon double
bond.
Naphthene: A saturated hydrocarbon with a cyclic molecular structure, such as cyclopropane, cyclo-butane, cyclo-pentane.
Aromatic: The benzene series of hydrocarbons; they are cyclic, with alternating single and
double bonds.
Hydrogen
The lightest of all elements and one of the basic components (along with carbon) of hydrocarbon
compounds.
Hydrogen Sulfide
Compound of hydrogen and sulfur (H2S); a colorless, flammable, poisonous gas. It has a distinct
odor of rotten eggs, however it can quickly deaden the sense of smell. Also called sulfurated
hydrogen.
Ideal Gas
A gas whose behavior does not deviate from calculations derived from the general gas laws.
Inches of Mercury (inHg)
A unit of pressure, using the pressure required to support a column of mercury one inch high as a
standard. Metric equivalent is millimeters of mercury (mmHg), the pressure required to support a
column of mercury one millimeter high.
Intercooling
The process of cooling a gas before it goes through another compression stage.
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Inverse Relationship
Describes the relationship between two variables; when one variable changes in one direction, the
other variable changes in the opposite direction.
Joule (J)
A unit of work or energy, equal to the force of one newton moving an object a distance of one meter.
One joule per second equals one watt. As a unit of energy, it is the amount of energy required to
raise the temperature of one kilogram of water 1 C.
Kelvin Scale
Temperature scale used for absolute measurements. Temperatures are expressed using "K" and
have the same degree increments as the Celsius scale.
Light Fractions
The hydrocarbon components of crude oil with small molecules, low boiling points, and high vapor
pressures.
Liquid
State of matter which assumes the shape of its container. Liquids have no definite shape and are
not compressible.
M
Abbreviation for 1,000.
Manometer
An instrument used to measure pressure in liquids and gases; a pressure gauge or vacuum gauge.
Mass
The amount of matter contained in an object.
Matter
Any substance that occupies space. Composed of single elements or combinations of elements.
Melting Point
Temperature where a substance will freeze if energy is withdrawn, or melt if energy is added.
Methane
Gas, consisting of carbon and hydrogen (CH4). The major component of natural gas. One of the
alkane or paraffin series of gases.
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MM
2
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Real Gas
Actual gas found in nature. Deviates from theoretical values of an ideal gas when changes in
temperature, volume and pressure are introduced.
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Refinery
A process facility for manufacturing finished or semi-finished products from crude oil.
Solid
Substances that have a definite shape and do not flow freely.
Specific Gravity
Ratio of a substance's density compared to the density of a standard substance. For liquids and
solids, the standard is water. For gases, the standard is air or hydrogen.
Standard Conditions
60 F (15.6 C) at atmospheric pressure, 14.7 PSIA (101.3 kPaa).
Stream
Fluid entering or leaving a process unit.
Suction
The upstream or feed side of a pump or compressor. Also, the act of drawing a fluid into a pump or
compressor.
Suction Cooling
Decreasing the final gas temperature, to permit more gas to be processed for the same power input.
Telescoping Gas Holder
Gas-holding tank with telescoping sides that raise and lower to adjust volume. Usually done to
maintain constant pressure in response to temperature changes.
Temperature
An indication of the average thermal/internal energy in a substance. Temperature is often reported
in degrees Fahrenheit ( F) or degrees Celsius ( C).
Terminal Velocity
The maximum acceleration that is reached when the air resistance exactly balances an object's
weight, and velocity is no longer increasing.
Thermal Expansion
The tendency of molecules to move farther apart when they are heated.
Thermometer
An instrument used to measure temperature.
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Turbine
An engine that produces energy from a fast-moving stream of steam, water, gas, or air.
Vacuum
Pressure below atmospheric pressure; negative pressure.
Vapor
The gaseous state of a substance that is liquid or solid under ordinary conditions.
Vapor Pressure
The pressure exerted by a liquids vapor when the liquid and vapor are at equilibrium. A measure of
a liquid's tendency to vaporize at a given temperature. The vapor pressure of a substance
increases with temperature.
Vaporize
To convert into vapor by applying heat.
Vent
An opening for a gas or liquid to escape, or for pressure relief.
Vessel
Closed container for holding gas and liquid under pressure or vacuum. It may be used for storage
(for example, butane drum, reflux drum). Process vessels will permit volume fluctuations, settling of
mixed stocks, release of vapors, or reactions (such as treaters or reactors).
Volatile Material
Any material which tends to vaporize at ambient temperatures.
Volatility
A measure of how easy it is for a substance to vaporize. Factor affecting flammability.
Volume
The amount of 3-dimensional space occupied by a substance.
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