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Abstract
This article presents the transient modelling for a two-bed, activated carbon fiber (ACF)eethanol adsorption chiller. This
innovative adsorption chiller employs pitch based ACF of type A-20 as adsorbent which is a fibrous adsorbent having the
advantages of fast adsorption rate, high porosity and ease of handling when compared with granular adsorbents and powdered
adsorbents. Ethanol is used as refrigerant as it has no harm to environment, it is a non-toxic substance, moreover, ethanol has
comparatively higher vapor pressure even at low temperature. This innovative system utilizes effectively low-temperature waste
heat sources of temperature between 60 and 95 C along with a coolant at 30 C. We have found that, regardless of the initial
mass distribution, the ACFeethanol adsorption chiller is able to achieve the same cyclic-steady-state within three cycles or
1890 s.
2006 Elsevier Ltd and IIR. All rights reserved.
Keywords: Adsorption system; Carbon fibre; Ethanol; Chiller; Design; Modelling
1. Introduction
The severity of the ozone layer destruction problem due
to CFCs, HCFCs or HFCs has been calling for rapid
developments in environment friendly air conditioning technologies. Adsorption cooling and heat pump systems have
the advantages of being environmentally benign, having
zero ozone depletion potential (ODP) as well as zero global
warming potential (GWP) due to the use of natural refrigerants or alternative refrigerants of CFCs, HCFCs or HFCs.
The working pairs of adsorption cooling and heat pump
are mainly dominated by silica gelewater, zeoliteewater,
activated carboneammonia, activated carbonemethanol
87
Nomenclature
A
COP
Cp
D
Dso
Ea
h
ksav
M
m
m_
P
Ps
Q
R
Rp
T
tcycle
t
U
w
W
W0
DHst
area (m2)
coefficient of performance (e)
specific heat capacity (J kg1 K1)
exponential constant (K1)
pre-exponential constant (m2 s1)
activation energy (J kg1)
enthalpy (J kg1)
mass transfer coefficient (s1)
mass (kg)
mass (kg)
mass flow rate (kg s1)
pressure (Pa)
saturated pressure (Pa)
power (W)
gas constant (J kg1 K1)
fiber radius (m)
temperature (K)
cycle time (s)
time (s)
overall heat transfer coefficient (W m2 K1)
instantaneous uptake (kg kg1)
equilibrium uptake (kg kg1)
maximum uptake (kg kg1)
isosteric heat of adsorption (J kg1)
and activated carbon fiber (ACF)eammonia pairs. A considerable number of studies have been conducted on adsorption
cooling and heat pump systems using the above mentioned
adsorbenterefrigerant pairs. The followings are some representative examples [1e15], which are furnished in Table 1.
Among the systems shown in Table 1, the utilization of
water and methanol as refrigerant in adsorption systems
makes those possible to be powered by waste heat source
below 100 C. However, the water based adsorption cooling
system requires the development of very low vacuum system
and the uptake of water on porous adsorbent is limited usually
up to 40% of dry adsorbent mass [16]. Methanol has been
used before but reservations exist on its toxicity. On the other
hand, the utilization of ethanol as refrigerant in adsorption
cooling systems has couple of advantages, such as, ethanol
is environmental friendly, non-toxic and it has a relatively
high vapor pressure even at low temperature levels [17]. To
select suitable adsorbent for ethanol adsorption, the porous
characteristics of two silica gels and two pitch type activated
carbon fibers are presented in Table 2 [1]. As can be seen from
Table 2, the ACF of type A-20 has the biggest surface area and
pore volume which is followed by ACF of type A-15 in comparison with other adsorbents. The average pore diameters of
all four adsorbents are similar.
From the above perspective, the present study deals with
the performance investigation of a two-bed, non-regenerative
ACF (A-20)eethanol adsorption chiller. A cycle simulation
cond
dMref
=dt
evap
dMref
=dt
Subscripts
acf
activated carbon fiber
ads
adsorption
c
critical
chill
chilled water
eff
effective
f
liquid phase
g
gaseous phase
i
adsorption or desorption
in
inlet
j
cooling source or heating source
liq
liquid
o
outlet
v
vapor
w
water
Superscripts
ads
adsorber
bed
sorption heat exchanger
cond
condenser
des
desorption
evap
evaporator
88
Table 1
Developments in adsorption cooling and heat pump systems
Adsorbent/refrigerant pair
System type
Remarks
Source
Silica gelewater
Silica gelewater
Silica gelewater
Non-regenerative system
Non-regenerative system
Multi-stage system
Zeoliteewater
Cascaded cycles
Zeoliteewater
Activated carboneammonia
Activated carboneammonia
Combination of two
independent single
adsorption systems
Regenerative system
Regenerative system
Three-bed system
Multi-bed, dual-mode system
Can operate with regeneration
temperature of 40 C
Heating application; adsorption
heat is 3700 kJ kg1
Locomotive cooling application
Activated carboneammonia
Activated carbonemethanol
Regenerative system
Solid adsorption refrigerator
Activated carbonemethanol
Activated carbonemethanol
Four-bed system
Thermal wave system, required
regeneration temperature is very high
Convective thermal wave system
Solar powered system with
very low efficiency.
Solar refrigeration COP is
between 0.1 and 0.12
System COP is between
0.085 and 0.179
Refrigeration capacity is about
three folds higher than that
of the ACemethanol system.
Topping cycle regeneration
at 280 C and bottoming cycle
regeneration at 150 C
Solar COP is around 0.3
Average pore
)
diameter (A
N2
0.69 106
N2
0.74 106
N2
1.41 106
N2
1.93 106
(a)
Cooling
water in
Cooling
water out
V3
SE2
SE1
V2 Cooling
water out
Liquid
refrigerant
Hot
water out
Cooling
water in
Hot
water in
Table 3
Operation schedule of refrigerant valves and sorption elements
Cycle
(duration)
Mode A
(600 s)
Mode B
(30 s)
Mode C
(600 s)
Mode D
(30 s)
Valve
Valve
Valve
Valve
SE 1
Open
Closed
Open
Closed
Cooling
water
Hot water
Closed
Closed
Closed
Closed
Hot
water
Cooling
water
Closed
Open
Closed
Open
Hot
water
Cooling
water
Closed
Closed
Closed
Closed
Cooling
water
Hot
water
1
2
3
4
SE 1
V4
89
V1
Evaporator
[20]. It is found that the numerical values of F0 is 11, considering the cylindrical shape of ACF. The surface diffusion Ds
is calculated by using the Arrhenius equation and the numerical values of Dso and Ea are found to be 1.8 1012 m2 s1
and 306.7 103 J kg1, respectively.
Chilled
water in
Chilled
water out
Condenser
(b)
Cooling
water in
Cooling
water out
V2
V3
Cooling
water out
SE2
SE1
Hot
water out
Liquid
refrigerant
V4
V1
2b
where,
2c
Evaporator
Chilled
water out
2a
Ea
Ds Dso exp
RT
Hot
water in
Cooling
water in
vw
ks av W w
vt
Ds
ks av F0 2
Rp
Chilled
water in
Fig. 1. (a) Schematic diagram of the two-bed ACFeethanol adsorption cycle (Mode A). (b) Schematic diagram of the two-bed
ACFeethanol adsorption cycle (Mode C).
DHst hfg E lnW0 =W1=n aT=Tc b
2d
Table 4
Values adopted in the cycle simulation program
2
Ps
W W0 exp D T ln
P
Symbols
Dso
D
Ea
W0
Rp
Macf
mC
_ p j
_ p chill
mC
MCp bed
eff
MCp cond
eff
MCp evap
eff
bed
UAi
(UA)cond
(UA)evap
Value
Unit
12
1.8 10
1.716 106
306.7 103
0.797
6.5 106
60
6270
2926
86.7 103
(9341 5 cpl,ethanol(T))
(4825 80 cpl,ethanol(T))
2952
15,330
4870
m2 s1
K2
J kg1
kg kg1
m
kg
W K1
W K1
J K1
J K1
J K1
W K1
W K1
W K1
90
bed dTibed
dT bed
mCp i-phase i
eff
dt
dt
bed
dwi
fMacf
DHst mC
_ p j Tj;o Tj;in ;
dt
MCp
cond dT cond
dwbed
des
MCp eff
f hfg Macf
dt
dt
_ p w Tw;o Tw;in :
mC
Hence the left hand side of Eq. (5) represents the rate of
change of internal energy required by the metallic parts of
heat exchanger tubes due to the temperature variations in
the condenser. On the right hand side, the first term gives
the latent heat of vaporization due to the amount of refrigerant desorbed from the desorption bed and the amount of heat
that the liquid condensate carries away when it leaves the
condenser to the evaporator, and finally the last term represents the total amount of heat released to the cooling water.
In the current design, the condenser heat exchanging tubes
have been chosen to be corrugated, with the enhanced surface inevitably retaining a thin film of condensate on the surface, which ensures that the condenser and the desorber are
always maintained at the refrigerant (ethanol) saturated
vapor pressure. Using log mean temperature difference
approach, the outlet temperature of the condenser heat
exchanging tube is written as:
#
"
UAcond
bed
bed
Tw;o Tads Tw;in Tads exp
:
6
_ p w
mC
UAevap
:
_ p w
mC
Start
Data storage
Initial uptake
Pevap=f(Tevap)
Pcond=f(Tcond)
Wads =f (Tads,Pevap)
Wdes =f (Tads,Pevap)
Initial values of heat added
and rejected
Qads=0
Qdes=0
Qcond=0
Qevap=0
Initial Conditions at
(time=0)
No
If time = 0
Yes
Loop starting from
time = 0 to
time = the end of the
operation cycle time
Calculation of
adsorption kinetics
End
Data output
Ti -Ti-1<0.01
91
Calculation of
adsorption isotherms
Yes
Calculation of
ethanol properties;
(1) latent heat
(2) Saturated pressure
(3) Specific heat
Stop
No
A
bed
dMref
dwads dwbed
Macf
des
dt
dt
dt
92
Pre-heating
(Tpre-heating)initial=(Tads)final
Pre-cooling
(Tpre-cooling)initial = (Tdes)final
Calculation of
adsorption kinetics
Pre-heating
Solving a set of differential
equations using DIVPAG in IMSL
Calculation of
adsorption isotherms
Calculation of
ethanol properties;
(1) Latent heat
(2) Saturated pressure
(3) Specific heat
Pre-cooling
Solving a set of differential
equations using DIVPAG in IMSL
For adsorber/desorber heat
exchanger
Solving
(1) Energy balance equation
(2) Heat balance equation
For the overall system
Solving
(3) Mass balance equation
(4) Heat balance equation
End
Data output
Ti -Ti-1<0.01
Yes
Stop
No
C
Fig. 2. Continued.
93
For adsorber
Solving
(1) Energy balance equation
(2) Heat balance equation
For the overall system
Solving
(3) Mass balance equation
(4) Heat balance equation
Calculation of
adsorption kinetics
End
Calculation of
adsorption isotherms
Calculation of
Ethanol properties;
(1) Latent heat
(2) Saturated pressure
(3) Specific heat
Data output
No
Ti -Ti-1<0.01
Yes
End
Fig. 2. Continued.
94
100
60
40
Inlet cooling water Condenser
Adsorber
Inlet Chilled water
Evaporator
2000
1000
4000
3000
6000
5000
Temperature [C]
80
20
Concentration
0.7
0.6
0.5
0.4
0.3
0.2
2
0.1
0.05
1000
Desorber
100
10
20
30
40
50
60
70
80
atio
entr
c
Con
10
ratio
Satu
0.01
90
Temperature [C]
80
60
Condenser cooling water outlet
40
20
100
200
300
400
500
600
5. Conclusions
Table 5
Rated operating conditions
Hot water inlet
Temperature ( C)
Temperature ( C)
Temperature ( C)
85
1.5
30
(1.5 1.5)
14
0.7
1
Switching time: 30 s
References
[1] B.B. Saha, S. Koyama, J.B. Lee, K. Kuwahara, K.C.A. Alam,
Y. Hamamoto, A. Akisawa, T. Kashiwagi, Performance evaluation of a low-temperature waste heat driven multi-bed
adsorption chiller, International Journal of Multiphase Flow
29 (8) (2003) 1249e1263.
[2] B.B. Saha, I.I. El-Sharkawy, S. Koyama, J.B. Lee,
K. Kuwahara, Waste heat driven multi-bed adsorption
chiller: heat exchangers overall thermal conductance on chiller
performance, Heat Transfer Engineering 27 (5) (2006) 80e87.
[3] B.B. Saha, S. Koyama, T. Kashiwagi, A. Akisawa, K.C. Ng,
H.T. Chua, Waste heat driven dual-mode, multi-stage, multibed regenerative adsorption system, International Journal of
Refrigeration 26 (7) (2003) 749e757.
[4] B.B. Saha, T. Kashiwagi, Experimental investigation of an advanced adsorption refrigeration cycle, ASHRAE Transactions:
Research 103 (2) (1997) 50e58.
[5] N. Douss, F. Meunier, Experimental study of cascading adsorption
cycles, Chemical Engineering Science 44 (2) (1989) 225e235.
[6] D.C. Wang, Z.Z. Xia, J.Y. Wu, Design and performance
prediction of a novel zeoliteewater adsorption air conditioner,
Energy Conversion and Management 47 (5) (2006) 590e610.
[7] J.A. Jones, V. Christophilos, High-efficiency regenerative adsorption heat pump, ASHRAE Transactions 99 (1) (1993)
54e60.
[8] D.J. Miles, S.V. Shelton, Design and testing of a solid-sorption
heat-pump system, Applied Thermal Engineering 16 (5) (1996)
389e394.
[9] R.E. Critoph, Performance estimation of convective thermal
wave adsorption cycles, Applied Thermal Engineering 16 (5)
(1996) 429e437.
[10] E.E. Anyanwu, C.I. Ezekwe, Design, construction and test run
of a solid adsorption solar refrigerator using activated carbon/
methanol, as adsorbent/adsorbate pair, Energy Conversion
and Management 44 (18) (2003) 2879e2892.
[11] Z.F. Li, K. Sumathy, A solar-powered ice-maker with the
solid adsorption pair of activated carbon and methanol, International Journal of Energy Research 23 (6) (1999) 517e527.
[12] L.W. Wang, J.Y. Wu, R.Z. Wang, Y.X. Xu, S.G. Wang,
Experimental study of a solidified activated carbonemethanol
[13]
[14]
[15]
[16]
[17]
[18]
[19]
[20]
[21]
[22]
[23]
95