Professional Documents
Culture Documents
Triumph Chemistry
Based on Maharashtra Board Syllabus
Salient Features
Exhaustive subtopic wise coverage of MCQs
Quick review and/or important formulae provided for all the chapters
Hints included for relevant questions
Various competitive exams questions updated till the latest year
Includes solved MCQs from JEE (Main), AIPMT, MH CET 2015
Evaluation test provided at the end of each chapter
TEID : 915
Preface
Std. XII: Sci. Triumph Chemistry is a complete and thorough guide to prepare students for competitive
level examinations. This book not only assists students with MCQs of Std. XII but also helps them to prepare for JEE,
AIPMT, AIIMS, AFMC, CET and various other competitive examinations.
The content of this book is based on the Maharashtra State Board Syllabus. Quick Review which summarizes
the important concepts of the entire chapter is provided for all the chapters. Formulae that form a vital part of MCQ
solving are provided for relevant chapters. Shortcuts provide easy and less tedious solving methods.
MCQs in each chapter are divided into three sections:
Classical Thinking: consists of straight forward questions including knowledge based questions.
Critical Thinking: consists of questions that require understanding of the concept and the applications of the same.
Competitive Thinking: consists of questions from various competitive examinations like JEE, AIPMT, AIIMS,
AFMC, CET, CPMT, etc.
Hints (i.e., complete solutions broken down to the simplest form possible) have been provided to the MCQs.
An Evaluation Test has been provided at the end of each chapter to assess the level of preparation of the
student on a competitive level.
In order to understand how chemistry plays an important role in our day to day life, we have made an attempt to
illustrate the same in the form of images/visuals in the related chapters.
The journey to create a complete book is strewn with triumphs, failures and near misses. If you think weve
nearly missed something or want to applaud us for our triumphs, wed love to hear from you.
Please write to us on : mail@targetpublications.org
Sr. No.
Topic Name
Page No.
1
2
3
4
5
Solid State
Solutions and Colligative Properties
Chemical Thermodynamics and Energetics
Electrochemistry
Chemical Kinetics
General Principles and Processes of Isolation of
Elements
pBlock Elements
d and fBlock Elements
Coordination Compounds
Halogen Derivatives of Alkanes and Arenes
Alcohols, Phenols and Ethers
Aldehydes, Ketones and Carboxylic Acids
Compounds Containing Nitrogen
Biomolecules
Polymers
Chemistry in Everyday Life
1
28
71
112
160
6
7
8
9
10
11
12
13
14
15
16
193
217
250
277
314
361
417
464
490
513
540
01 SolidState
Syllabus
1.0
Introduction
1.1
Classification of solids
1.2
1.3
1.4
Packing in solids
1.5
1.6
1.7
1.8
Electrical properties
1.9
Magnetic properties
Quick Review
Classification of solids on the basis of the presence or absence of orderly arrangement of the
constituent particles:
Solids
Crystalline
A homogeneous solid in which the constituent
particles are arranged in a definite geometric
pattern.
Isomorphous Form
Two or more substance having same
crystal structure.
eg. i. NaF and MgO
ii. K2SO4 and K2SeO4
iii. NaNO3 and CaCO3
iv. Cr2O3 and Fe2O3
Amorphous
Substances that appear like solids but do not have well
developed perfectly ordered crystalline structure.
eg. Tar, glass, plastic, rubber, butter, etc.
Molecular solids
Constituent particles are
molecules of the same
compound.
Ionic solids
Constituent particles
are ionic molecules.
eg. NaCl, ZnS, CuCl
Metallic solids
Formed by atoms
of the same metallic
elements.
eg. Copper, gold
Covalent solids
Formed by chemical
(covalent) bonds between the
neighbouring constituent
atoms of non-metallic solids.
eg. diamond, graphite and
fullerene
Simple
Lattice points at eight corners
of unit cell.
(1 particle per unit cell)
(52.4% occupied space)
eg. Polonium
2
Body centered
Lattice points at eight corners and
one at body center of unit cell.
(2 particles per unit cell)
(68% occupied space)
eg. Fe, Na
Face centered
Lattice points at eight corners
and six face centers of unit cell.
(4 particles per unit cell)
(74 % occupied space)
eg. Cu, Al
Magnetic
alignment
Characteristics
Diamagnetic
materials
Paramagnetic
materials
Ferromagnetic
materials
Example
Application
Benzene,
Insulators
NaCl, TiO2
O2, CuO, TiO Electronic
devices
Fe, Ni,
Co,
CrO2
CrO2 is used in
audio,video
tapes.
Formulae
1.
z.M
a 3 .N0
2.
Packing efficiency =
3.
4.
5.
r
:
r
Radius Ratio
The critical radius ratio of the void (cation) and sphere (anion), is calculated by solid geometry.
r
Cation radius
Radius ratio = =
Anion radius
r
ii.
Coordination Number (CN) :
The number of spheres (atoms, molecules or ions) directly surrounding a single sphere in a crystal, is
called coordination number.
Crystal structures of some elements and their coordination numbers (CN):
Crystal structure
Example
Coordination No.
bcc
Li, Na, K, Rb, Cs, Ba
8
fcc or ccp
Al, Ni, Cu, Ag, Au, Pt
12
Relation between radius ratio, coordination number and geometry :
r
r
Radius ratio
0.155 to 0.225
0.225 to 0.414
0.414 to 0.732
0.732 to 1.0
Coordination
number
Geometry
Examples
3
4
6
8
Planar triangular
Tetrahedral
Octahedral
Cubic
B2O3
ZnS
NaCl
CsCl
3
Classical Thinking
1.0
1.
2.
3.
Introduction
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
Classification of solids
18.
19.
20.
26.
27.
28.
29.
30.
25.
21.
22.
23.
31.
1.4
32.
33.
24.
Packing in solids
1.5
35.
36.
37.
38.
43.
1.7
44.
45.
46.
NaCl
lattice,
the
radius
ratio
Cation
Anion
is
Na +
(A)
(B)
(C)
(D)
= _______.
Cl
(A)
(C)
0.225
0.5248
(B)
(D)
0.115
0.471
39.
40.
41.
42.
Schottky defect
Frenkel defect
Metal excess defect
Metal deficiency defect
47.
48.
Electrical properties
49.
50.
Silicon is a _______.
(A) conductor
(C) non-conductor
(B)
(D)
semiconductor
metal complex
52.
53.
Magnetic properties
59.
60.
Miscellaneous
54.
55.
56.
57.
58.
2.
Classification of solids
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
Introduction
1.
3.
1.2
14.
15.
16.
17.
18.
19.
20.
metallic
molecular
26.
27.
28.
29.
21.
30.
22.
31.
32.
33.
23.
24.
25.
substances, the
in a regular
Benzene
Carbon black
1.4
Packing in solids
34.
35.
36.
37.
(A)
(B)
2
4
8
(C)
2
(D)
6
6
38.
39.
41.
42.
43.
44.
45.
40.
(A)
(C)
tetrahedral
octahedral
(B)
(D)
1.5
(C)
10
a3 M
g cm3
z N0
(D)
M N0
g cm3
3
a z
200 pm
(B)
(C)
142.2 pm
(D)
3
2
pm
2 pm
46.
47.
cubic
triangular
(A)
48.
49.
50.
51.
52.
53.
54.
55.
56.
57.
58.
59.
60.
61.
368pm
276pm
62.
63.
65.
66.
72.
73.
(A)
(C)
1.122
1.414
Cl
Na
(B)
(D)
1.224
0.732
74.
75.
67.
68.
76.
77.
78.
79.
69.
70.
71.
81.
82.
84.
86.
87.
Electrical properties
88.
89.
90.
91.
92.
93.
83.
85.
1.9
94.
Magnetic properties
95.
96.
97.
Which
of
the
ferromagnetism?
(A)
(C)
following
(B)
(D)
represents
98.
99.
r+
, the
r
_______.
(A) forces of attraction are larger than the
forces of repulsion
(B) forces of attraction are smaller than the
forces of repulsion
(C) forces of attraction and repulsion are
just equal
(D) forces are not equal
107. At low temperature and high pressure, SO2
freezes to form crystalline solid. Which term
best describes the solid?
(A) Ionic crystal
(B) Covalent crystal
(C) Metallic crystal
(D) Molecular crystal
Competitive Thinking
1.0
1.
2.
Classification of solids
3.
4.
1.2
Introduction
5.
6.
7.
14.
8.
15.
16.
17.
18.
19.
20.
21.
9.
10.
11.
12.
13.
30.
23.
31.
24.
22.
25.
26.
27.
The ratio
of close-packed
atoms to
tetrahedral holes in cubic close packing is
[Pb. PMT 1998]
_______.
(A) 1 : 1
(B) 1 : 2
(C) 1 : 3
(D) 2 : 1
28.
29.
2r
(D)
3
r
2
32.
33.
34.
Packing in solids
(D)
35.
1a :
3a:
2a
1
3
1
a:
a:
a
2
4
2 2
1
1
a: 3a:
a
2
2
36.
43.
37.
44.
38.
45.
46.
39.
40.
41.
42.
18
1.6
47.
Cl
48.
49.
51.
52.
53.
54.
55.
56.
57.
58.
59.
Na Cl Na Cl Na Cl
Cl Na+
Na+
Cl
+
+
Na Cl
Cl Na Cl
Cl Na Cl Na+
Na+
(A) Frenkel defect
(B) Schottky defect
(C) Interstitial defect
(D) Frenkel and Schottky defects
60.
61.
62.
63.
65.
67.
(C)
Electrical properties
64.
66.
(D)
71.
72.
73.
74.
75.
76.
77.
68.
69.
70.
Answer Key
Classical Thinking
1.
11.
21.
31.
41.
51.
(D)
(A)
(A)
(D)
(B)
(A)
2.
12.
22.
32.
42.
52.
(C)
(C)
(A)
(A)
(A)
(C)
3.
13.
23.
33.
43.
53.
(A)
(C)
(B)
(B)
(D)
(C)
4.
14.
24.
34.
44.
54.
(A)
(A)
(C)
(A)
(D)
(B)
5.
15.
25.
35.
45.
55.
(D)
(C)
(C)
(B)
(D)
(D)
6.
16.
26.
36.
46.
56.
(C)
(B)
(D)
(D)
(A)
(B)
(A)
(B)
(A)
(B)
(C)
(C)
(B)
(A)
(C)
(B)
(A)
(B)
4.
14.
24.
34.
44.
54.
64.
74.
84.
94.
104.
114.
(D)
(C)
(C)
(A)
(C)
(B)
(D)
(B)
(D)
(C)
(A)
(B)
5. (D)
15. (D)
25. (C)
35. (C)
45. (A)
55. (C)
65. (B)
75. (B)
85. (C)
95. (A)
105. (C)
6. (B)
16. (A)
26. (A)
36. (A)
46. (A)
56. (B)
66. (C)
76. (B)
86. (A)
96. (A)
106. (C)
4.
14.
24.
34.
44.
54.
64.
74.
(A)
(B)
(A)
(C)
(B)
(B)
(D)
(D)
5.
15.
25.
35.
45.
55.
65.
75.
6.
16.
26.
36.
46.
56.
66.
76.
7.
17.
27.
37.
47.
57.
(A)
(D)
(B)
(A)
(B)
(C)
8.
18.
28.
38.
48.
58.
(A)
(C)
(C)
(C)
(B)
(B)
9.
19.
29.
39.
49.
59.
(D)
(D)
(D)
(C)
(B)
(B)
10.
20.
30.
40.
50.
60.
(A)
(B)
(D)
(D)
(B)
(C)
7. (C)
17. (D)
27. (B)
37. (D)
47. (A)
57. (B)
67. (B)
77. (B)
87. (C)
97. (A)
107. (D)
8.
18.
28.
38.
48.
58.
68.
78.
88.
98.
108.
(B)
(D)
(C)
(B)
(D)
(A)
(A)
(B)
(B)
(D)
(A)
9. (D)
19. (A)
29. (A)
39. (C)
49. (C)
59. (C)
69. (B)
79. (A)
89. (C)
99. (A)
109. (B)
10. (C)
20. (B)
30. (B)
40. (B)
50. (D)
60. (B)
70. (B)
80. (C)
90. (A)
100. (D)
110. (B)
7.
17.
27.
37.
47.
57.
67.
77.
8.
18.
28.
38.
48.
58.
68.
(C)
(D)
(A)
(B)
(C)
(A)
(B)
9.
19.
29.
39.
49.
59.
69.
10.
20.
30.
40.
50.
60.
70.
Critical Thinking
1.
11.
21.
31.
41.
51.
61.
71.
81.
91.
101.
111.
(D)
(D)
(D)
(B)
(A)
(B)
(C)
(C)
(A)
(C)
(B)
(D)
2. (C)
12. (C)
22. (A)
32. (C)
42. (A)
52. (B)
62. (B)
72. (C)
82. (C)
92. (A)
102. (A)
112. (B)
3.
13.
23.
33.
43.
53.
63.
73.
83.
93.
103.
113.
Competitive Thinking
1.
11.
21.
31.
41.
51.
61.
71.
(B)
(D)
(B)
(B)
(A)
(C)
(C)
(C)
2.
12.
22.
32.
42.
52.
62.
72.
(A)
(B)
(B)
(A)
(C)
(D)
(C)
(A)
3.
13.
23.
33.
43.
53.
63.
73.
(A)
(B)
(B)
(C)
(A)
(D)
(C)
(C)
(B)
(A)
(C)
(A)
(C)
(A)
(D)
(A)
(D)
(B)
(D)
(A)
(C)
(A)
(B)
(C)
(C)
(C)
(B)
(B)
(B)
(D)
(A)
(B)
(D)
(D)
(C)
(C)
(B)
(B)
(B)
Hints
Classical Thinking
34.
23.
33.
8
3
64r 3
3 3
r3
38.
Na +
= 0.95
8
3
3 3
64r 3
100 = 68.04 %.
Radius ratio =
Cl-
Na
Cl
0.95
1.81
= 1.81
= 0.5248
21
(C)
(D)
(D)
(A)
(D)
(B)
(C)
55.
Critical Thinking
40.
41.
42.
43.
g cm 3
d N0 a 3
z=
M
2.75 6.022 1023 (6.54 108 )3
=
119
2.75 6.022 27.97 463.197
=
= 3.89 4
=
119
119
For fcc lattice,
4r = 2 a
a = 620 pm;
2 620 1.414 620
r=
=
= 219.17 219.20 pm
4
4
1 108
zM
N0 =
=
3
da
8 (3 108 )3
=
46.
Ag = 12 (edges)
108 10
216
24
Au = 1
61.
62.
r++ r =
63.
64.
68.
= 0.51024 = 51023
69.
4 98.99
6.022 1023 3.4
395.96 1023
a3 =
a3 = 19.34 1023
20.47
a = 3 1.934 10 22 = 5.783 108 cm
= 5.783 1010 m = 5.783
47.
2r+ + 2r = 520
520
r+ + r =
= 260; r = 260 80 = 180 pm.
2
There is one octahedral hole per oxide ion and
71.
670.284
= 335.142
2
46 1024
6.022 76.22 1023
= 0.1002 101 = 1.002 g cm3
48.
54.
Number of atom of B =
1
8+1=2
8
The formula of solid is AB2.
2
only of these holes are occupied.
3
2
the ratio should be
:1=2:3
3
2r + + 2r = 3 a
3 387
1.732 387
=
r++r=
2
2
=8
22
400
= 200 pm
2
r = 200 75 = 125 pm
95
r
= 0.52
radius ratio = =
181
r
Since the radius ratio is in between 0.414 to
0.732, the coordination number of cation is 6.
rd
=3
4
Cu4Ag3Au
552
= 276
2r + + 2r = 552; r + + r =
2
r = 276 95 = 181 pm.
a3 =
Cu = ccp = 4
72.
compound is AuCu3.
An atom at the corner of a cube is shared
among 8 unit cells. As there are 8 corners in a
cube, number of corner atom [A] per unit cell
1
=8 =1
8
A face- centered atom in a cube is shared by
two unit cells. As there are 6 faces in a cube,
number of face- centered atoms [B] per unit
1
cell = 6 = 3
2
Na
= 0.55,
Cl
Cl
Na
+ 1 = 0.55 + 1
Competitive Thinking
+ 1 = 0.74 + 1
Cl
Na
Cl
Cl
= 1.74
Cl
Cl
Cl
Na
78.
Cl
Na
Cl
6.
Ionic
crystals
exhibit
properties of the bond.
10.
14.
19.
= 1.55
Cl
77.
Cl
1.74
1.55
= 1.122
Cl
r
1.46
=
= 0.67
2.16
r
Since the limiting value is in between 0.414 to
0.732, the probable structure is NaCl type.
radius ratio =
r+ / r =
25.
30.
=
32.
3
3
r r
a
267 = 231.2 pm
2
2
1 3
=
8 4
non-directional
24.
180
= 0.962 which lies in the range of
187
0.732 1.000.
Hence, coordination number = 8 i.e., the
structure is CsCl type.
3
:3=1:4
4
Composition of alloy = AB4
A:B=
Cl
1
=3
2
= 0.74
Number of atoms of B = 6
2r 2
100 = 78.5 %
(2 2r ) 2
In fcc, 4r = 2 a,
Where r = radius of the sphere
a = edge length of the unit cell = 620 pm
2a
2 620
= 219.20 pm
r=
4
4
23
35.
r=a/2
a 3
Body centered unit cell, r =
4
a
Face centered unit cell, r =
2 2
36.
N0 =
37.
d=
39.
40.
4 3
r .
3
34.
38.
41.
z=
42.
58.5 4
6.023 1023
Number of unit cells in 1 g NaCl
1
6.023 1023
=
58.5 4
Mass of one unit cell
=
44.
45.
Edge length = 2r + + 2r
508
= r++r;
2
254 = 110 + r
r = 254 110 = 144 pm.
Metal has fcc lattice,
z=4
zM
d= 3
a N0
3079.2 101
= 42.7 101 = 4.27 4
72
4 100
zM
=
= 4 1025
3
da
10 (108 )3
zM
a N 0 1030
2 100
=
= 5.188 g / cm3
3
(400) (6.02 1023 ) 1030
24
z =
46.
2.72 =
4 M
4.04 10
8 3
6.02 1023
M=
47.
49.
= 27 g mol1
1
=3
2
72.
52.
53.
54.
55.
65.
70.
73.
7.014 1023 cm 3
= 4.12108 cm=4.121010 m
= 4.12 4
So, the smallest Cs to Cs internuclear distance
is nearly 4 .
74.
75.
76.
Packing
Examples
efficiency
Simple cubic lattice
52.4%
Polonium
Body centred cubic lattice 68%
Iron,
Tungsten
Face centred cubic lattice 74%
Aluminium
Type of unit cell
Substance
Dioxygen
Chromium (IV) oxide
Benzene
Dihydrogen monoxide
Magnetic property
Paramagnetic
Ferromagnetic
Diamagnetic
Diamagnetic
25
Evaluation Test
1.
2.
3.
the
5.
8.
9.
10.
11.
12.
most
4.
6.
7.
13.
14.
(D)
(A)
(B)
(C)
2.
6.
10.
14.
(C)
(C)
(D)
(A)
3. (B)
7. (A)
11. (B)
4. (B)
8. (A)
12. (C)
27