Roll No.

xE

SS41Chem.

No. of Questions 30
No. of Printed Pages 15

=SS vE {I, 2014

SENIOR SECONDARY EXAMINATION, 2014

x Yx
CHEMISTRY

1
4

Ph]

{hE : 56
x] : Eh E +E i i ii { JB*
{Il E B x xn :
GENERAL INSTRUCTIONS TO THE EXAMINEES :
1.

{Il |l +{x |x {j { xE +xi: J*

Candidate must write first his / her Roll No. on the question paper
compulsorily.

2.

|x Ex +x *
All the questions are compulsory.

3.

|iE |x E =k n M< =k-{iE J*

Write the answer to each question in the given answer-book only.

4.

Vx |x +xiE Jhb , =x E =k BE l J*
For questions having more than one part the answers to those parts
are to be written together in continuity.

5.

|x {j E xn +OV {xi E |E E j] / +xi / v x

{ xn E |x E x*
If there is any error / difference / contradiction in Hindi & English
versions of the question paper, the question of Hindi version should
be treated valid.

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6.

7.

|x J

+E |iE |x

1-13

14-24

25-27

28-30

Q. Nos.

Marks per question

1-13

14-24

25-27

28-30

|x GE 21, 27, 28, 29 30 +xiE E{ *

Question Nos. 21, 27, 28, 29 and 30 have internal choices.

1.

E< vi +{x =SSi +CEh +l E +C<b +l }+<b

C |ni Ei ?
Why is the highest oxidation state of a metal exhibited in its oxide or

fluoride only ?
2.

+{ BE {n b B]] E lx {ii E EM ?
How will you convert sodium acetate to methane in one step ?

3.

+{ x E xVx {ii E EM ?
How will you convert phenol to benzene ?

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4.

V Blx E G xp

H2SO4

E l

413 K

{ E< Vi , i J

=i{n C ?
What is the major product when ethanol is treated with conc. H2SO4 at

413 K ?
5.

xVx b<BVx C<b E x E l Mx +G JB*

Write the coupling reaction of benzene diazonium chloride with

phenol.
6.

(i)

B]E B (ii) B]E |lE Bx E x<] + +GB JB*

Write the reactions of (i) aliphatic and (ii) aromatic primary amines

with nitrous acid.

7.

i{ og E C ?
What are thermosetting polymers ?

8.

PHBV

E E BEE E x JB*

Write the names of the monomers of PHBV polymer.

9.

x<x 6,6 E |E |{i E Vi ? +G nVB*

How is Nylon 6,6 obtained ? Give reaction.

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10.

xE +G JB V ME Ex E ={li E {]
i *
Write that chemical reaction which confirm the presence of carbonyl

group in glucose.
11.

]x A, B, C + D E V il i E +v { MEi E =xE
ix EVB*
Classify Vitamins A, B, C and D depending upon their solubility in
water and fat and compare them.

12.

xE<b C i ?
1

What are monosaccharides ?

13.

x <b +G JB*
Write Hofmann's bromamide reaction.

14.

C i V 1 B 2 {lE BE E xV G ]<+C<b
u +CEh E Vi ? xE Eh JB*

( Cr O3 )

What happens when the 1 and 2 alcohols are oxidised by anhydrous

chromium trioxide ( Cr O3 ) ? Write chemical equations.

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15.

xx +G+ E E] i<B :
(+) Ej xE I
() =SS n { M +x E i{i Pt i { Vx
() Blx E <bVxx
(n)

N2O5 E

+{P]x*

Give the order of the following reactions :

(a)

Artificial radioactive decay

(b)

Decomposition of gaseous ammonia on a hot Pt-surface at high

pressure

16.

(c)

Hydrogenation of ethene

(d)

Decomposition of N2O5.

(+) {h E +l {h i d-EIE

(4d10)

BE Gh ii * E ?
() BC]xb +ESx Z<B*

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(a)

Silver atom has completely filled d-orbitals (4d10) in its ground

state, even then it is a transition element. How ?

(b)
17.

Explain actinoid contraction.

1+1

xxJi +G+ |{i =i{n E +xx M<B :

(+)

CH3

CH2

Br + AgCN

(V BE)

()

CH3

CH2

Br + KNO2

(V BE)
Cl
+ Na

()

(n)

CH3

E <l

E <l

I + Mg

Predict the products of the following reactions :

(a)

CH3

(b)

CH3

CH2

CH2

Br + AgCN
( aq. alcohol )

Br + KNO2

( aq. alcohol )

Cl

(c)

(d)

+ Na

CH3

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dry ether

I + Mg

dry ether

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18.

(+)

vi+ E rEh Ij ={Vx ME E +x|M BE =nh E

l Z<B*

()
(a)

={Vx ME [Ag(NH3)2][Ag(CN)2] E IUPAC x JB*

Explain the applications of coordination compounds in the field
of metal purification giving an example.

(b)

Write the IUPAC name of [Ag(NH3)2][Ag(CN)2] coordination

compound.

19.

1+1

u-h il E +xi Zi B |iE E BE-BE =nh nVB*

Explain the difference between a double-salt and a complex, giving an
example in each case.

20.

u-+hE xEM |il{x +G

(SN2)

il BEhE xEM

|il{x (SN1) +G E Gv E< n +xi i<B*

Describe

any

two

differences

in

substitution

nucleophilic

bimolecular (SN2) and substitution nucleophilic unimolecular (SN1)

reaction mechanisms.

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21.

Bx E xEh E ti +{P]x E xEi Sj x<B B <

x {h +G JB*
+l
b {Eh |G E xEi Sj x<B* v J { E
={M ?
Draw labelled diagram of electrolytic cell for the extraction of
aluminium and the overall reaction taking place in it.

OR
Draw labelled diagram of Zone refining process. In which this process
is useful ?

22.

E +G E +v C ? |l E] +G E M Eh
{] EVB E < +G E +v +GE E |E xpi+ { x
x i*
What is half-life period of reaction ? Justify from the rate equation for
first order reactions that the half-life period for such reaction is
independent of the initial concentrations of the reactants.

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23.

(+)

CuSO4

E x E E {j hbh E Ei ?

Z<B*

24.

()

E> E x JB B BE +x|M i<B*

(a)

Can we store CuSO4 solution in an iron vessel ? Explain.

(b)

Write Kohlrausch law and give one application of it.

(+)

E VM Mx E {h xE +G JB*

()

bx E {h +G nVB B < E B xx] Eh

1+1

E Mhi { JB*
(a)

Write the complete chemical reaction of rusting of iron.

(b)

Give overall reaction of Daniel cell and write mathematical

expression of Nernst equation for it.

25.

(+)

1+1

xi B E {h BE n E {E , Px vi E G]
Ex Ii E Mhx EVB*

()

+xE ` E |Ei E +v { E n B ]E n E ix
EVB*

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(a)

Assuming that atoms are touching each other, calculate the

efficiency of packing in case of a crystal for simple cubic metal.

(b)

On the basis of nature of ionic solids compare Frenkel defect

with Schottky defect.

26.

(+)

2+1

(i)

V { n E C M n BE SS Sx = b n V ?

(ii)

nh+ E px Yi Ex E Ex- +hJ Mhv

={H ?

()

C ClxE E =zx x M n
01

()

01

b C<b

Sx E 1 ] V E VB ? Z<B*

C l-Cl h E ME E |V +x u {lE E
Ei ? Z<B*

(a)

(i)

What happens to vapour pressure of water if a tablespoon

of sugar is added to it ?

(ii)

Which colligative property is preferred for the molar mass

determination of macromolecules ?

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(b)

Will the elevation in boiling point be same if 01 mole of sodium

chloride or 01 mole of sugar is dissolved in 1 L of water ?

(c)

Can we separate the compounds of azeotropic mixture by

fractional distillation ? Explain.

27.

(2)+1+1

xx E Z<B :

(+)

{iv

()

Ej vE

()

|i-+*

+l

xx E Z<B :

(+)

()

Jt {IE

()

|iE*

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Explain the following :
(a)

Antiseptics

(b)

Artificial sweetening

(c)

Antacids.
OR

Explain the following :

28.

(a)

Disinfectants

(b)

Food preservatives

(c)

Tranquilizers.

(+)

x E E<b xx E v E Sj i hx EVB*

()

B V C +xi ?

()

Enx E Ei ? Z<B*

1+1+1

+l
(+)

ti +{P] E +iH j E +r E<b x E

rEh E v E Sj i hx EVB*

()

B B C +xi ?

()

{{]x E Ei ? Z<B*

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(a)

Describe the method for the preparation of gold colloidal sol

with diagram.

(b)

What is the difference between a sol and a gel ?

(c)

What is coagulation ? Explain.

OR

(a)

Describe the method for the purification of colloidal sol

containing excess amount of electrolytes with diagram.

29.

(b)

What is the difference between aerosol and foam ?

(c)

What is peptization ? Explain.

(+)

Cx E S +C + E xE j JB*

()

=iE] M E x <C]x x JB* SE +xxn

2+1+1

|i (MRI) < E Ex- ii ={M ?

()

C2H5OH

PCl3

PCl5

E l {lE {lE xE +GB

JB*
+l
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(+)

E S +C + E xE j JB*

()

EEVx E x <C]x x JB* B{ h E

xE j JB*

()

+x BE < IE E i Ei * Z<B*

(a)

Write the chemical formulae of four oxy acids of chlorine.

(b)

Write the general electronic configuration of noble gas group.

Which element of this group is useful in magnetic resonance
imaging (MRI) ?

(c)

Write the chemical reactions of C2H5OH with PCl3 and PCl5

separately.
OR

(a)

Write the chemical formulae of four oxy acids of sulphur.

(b)

Write the general electronic configuration of chalcogen group.

Write the chemical formula of epsom salt.

(c)

Ammonia act as a Lewis base. Explain.

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30.

=Si =nh E l xx E Z<B :

(+)

Vxb +{Sx

()

M]x-EJ +G*
+l

=Si =nh E l xx E Z<B :

(+)

Cxx +{Sx

()

]x +G*

Explain the following with suitable example :

(a)

Rosenmund reduction

(b)

Gatterman-Koch reaction.
OR

Explain the following with suitable example :

(a)

Clemmensen reduction

(b)

Stephen reaction.

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