2013

PrOX CO
*

*mingchuan@kaori.com.tw

100-EC-17-A-13-I1-0018

PrOX

PrOX

2013

(PEMFC)

()
(fuel reforming)

CO

CO 10 ppm

(fuel reformer)

2.1

CO 10ppm
:

CH 4 H 2O CO 3H 2

(1)

(1)

(SR, Steaming Reforming)

CO H 2 O CO 2 H 2

(2)

(2)
(WGS,
Water Gas Shift)
CO

1
O 2 CO 2
2

(3)

H2

1
O 2 H 2O
2

(4)

(3)(4)CO
CO2 CO

(3)(4)
(PrOX, Preferential Oxidation)
(1)~(4)
2-1
PrOX
CO

CO

CO

O2/C

PrOX

CO
2.2

2-1
SR

SR
SR

Fuel +
steam

H2 + CO2 + CO

Fuel +
air

CO2+H2O

2-1SRSR

2013

CO

Steam Reforming (SR)

CH4 + H2OCO+3H2

+206.2 kJ/mol

600~750

~10%

Water Gas Shift (WGS)

CO+H2OCO2+H2

-41.2 kJ/mol

300~400

< 1%

Preferential Oxidation
(PrOX)

CO+1/2O2CO2

-283.2 kJ/mol

H2+1/2O2H2O

-241 kJ/mol

250~350
120~200

10ppm

2-1
CO
PrOX

PrOX
2-2(a)

TC1TC2

TC3TC4TC5

SR WGS

PrOX 2-2(b)

O2/C PrOX

CO

(Air1)
(Air2)

2-3 PrOX

2-2 PrOX (a)(b)

2.3 PrOX
2-3 SRWGS
PrOX
kW SR WGS
PrOX

3.1 CO
CO

CO
CO CO
100%
CO

(5)

2013

H 2 H 2
100%
H 2

(6)

100oC~120oC
120oC CO
O2/C=1.5 CO
3.3 WGS

PEMFC CO
CO

3.2
3-1
PrOX

NDIR
PrOX
Air
H2,CO,CO2,
,N2,H2O

H2,CO,CO2,N2,
H2O,O2

Thermal
Couple 1

3.2
PrOX
SR/WGS
PrOX
PrOX CO
O2/C

WGS
CH4 3.5%CO 0.51%H2 75 %
3.4 PrOX

Air1=0.811.21.51.8 2Air2=0(
LPM) O2/C 1.2
1.51.82.32.7 3.1 O2 /C
CO
3-3 3-4

Thermal
Couple 2

3-1

3-3 O2 /C
CO

3-2 O2/C CO

3-2 O2 /C 1.01.522.5
O2/C 1
100oC~120oC CO
98%

3-4 O2 /C

2013

3-3 O2/C=1.5( Air1 1

LPM) PrOX CO
O2/C=1.8( Air1=1.2 LPM)
0.06% 0.56%
Air1 1 LPM

O2/C=1.5 (Air1=1 LPM) CO

3-4
P1 165.1
(100~120oC) CO
98.9% CO

3-5 CO

O2/C
O2/C 2
200oC CO

TC1 CO
WGS
TC1 TC2

TC2 TC2 TC3

TC3

TC2 TC2
130oC CO
CO TC3TC4TC5

TC3TC4TC5
TC2

3-6

3.4 PrOX

Air1=1Air2=00.20.50.81(LPM)
O2/C 1.51.82.3
2.8 3.1 O2/C CO

3-53-6 3-7

3-7
3-5 3-6
CO
O2 /C=2.3( Air1 =1 LPM, Air2=0.5
LPM) CO 99.69%
4.19%
O2/C=1.8( Air1 =1 LPM, Air2=0.2 LPM)
CO 99.59% 2.92%

2013

3-7
O2/C=1.8 2.3
TC1 160~170 oC
TC3
CO

120 CO

1. PrOX
O2/C=1.5
CO 98.94%
2.85%
O2/C=1.8 CO 99.59%
2.92%

CO
2. PrOX

CO

(100-EC-17-A-13-I1-0018)

[1]Gunther Kolb, Fuel Processing for Fuel Cell,

WILEY-VCH Verlag Gmbh&Co. KGaA.,2008
[2]H.SCOTT FOGLER, Elements of chemical
reaction engineering, Prentice hall PTR,1992
[3]Ryan P. O;HAYRE, Fuel Cell Fundamentals,
JOHN WIELY& SONS,INC,2006
[4] Diego G. Oliva, Javier A. Francesconi,
Miguel C. Mussati, Pio A. Aguirre, CO-PrOx
reactor design by model-based optimization,
Journal of Power Sources 182 (2008) 307316.
[5]P. Ferreira-Aparicio, M. J. Benito, J. L. Sanz,

New Trends in Reforming Technologies: from

Hydrogen Industrial Plants to Multifuel Microreformers, Catalysis Reviews, 47:491-588,
2005.
[6]Jung Yeon Won, Hee Kwon Jun, Min Ku
Jeon,Seong Ihl Woo,Performance of microchannel reactor combined with combustor for
methanol steam reforming, Catalysis Today
111 (2006) 158-163.
[7]G. Kolb, J. Schurer, D. Tiemann, M. Wichert,
R. Zapf, V. Hessel, H. Lowe, Fuel processing
in integrated micro-structured heat-exchanger
reactors, Journal of Power Sources 171 (2007)
198-204.
[8]Gunther Kolb, Christian Hofmann, Martin
OConnell, Jochen Schurer, Microstructured
reactors for diesel steam reforming, water-gas
shift and preferential oxidation in the kiloWatt
power range, Catalysis Today 147S (2009)
S176-S184.
[9]Shi-Tin Lin, Yih-Hang Chen, Cheng-Ching
Yu, Yen-Chun Liuc, Chiou-Hwang Lee,
Dynamic modeling and control structure design
of an experimental fuel processor, International
Journal of Hydrogen Energy 31 (2006) 413
426.
[10]Shi-Tin Lin, Yih-Hang Chen, Cheng-Ching
Yu,Yen Chun Liu, Chiou Hwang Lee, Modeling an experimental methane fuel processor,
Journal of Power Sources 148 (2005) 4353.
[11]Anca Faur Ghenciu, Review of fuel
processing catalysts for hydrogen production
in PEM fuel cell systems, Current Opinion in
Solid State and Materials Science 6 (2002)
389399.