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2010 38 9

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Separation of Carbon D ioxide from Natural G as and U tilization

YAO X iao - long, WANG Yan - m ing, LI X in - q i
( Gas Design Institute of Shaanx i P rov in ce, Shaanx i X i. an 710043, China)
Abstract: Severa l econom ical m ethods of rem oval carbon d io x id e separated from natural gas w ere in troduced, w hich
in cluded m em brane separation, PSA absorpt ion, physical abso rpt io n and a lcoho l solution am in e chem ical absorption
( MDEA) . The latest prog ress of natural gas chem ical techno lo gy w as d iscussed.
K ey w ord s: carbon diox ide; natural gas purifica tio n; m em brane separation; PSA; physica l absorption; MDEA
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2008
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2010 38 9

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[ 1]

, , . [ J] . ,

[ 2]

2008 ( 9) : 1 - 3.
, . [ J].

[ 3]

, 2005, 27( 5) : 68- 71.

S. Sridhar, B. Sm itha, T. M. Am inabh av,i [ ] .
CO 2 ( ) [ J]. , 2008, 8 ( 4) : 11 - 16.

[ 4]

, , . [ J] .
, 2002, 21( 12 ) : 880 - 884.

[ 5]
[ 6]

. [ D ]. , 2004.
, , . [ P ]. CN
85 1 03557 A: 3- 4.
( 101 )

2010 38 9
1
T able 1 Cho ice o f cata lyst

95e ~ 100e

2. 4

catalyst

con tent /%

yield /%

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82. 78

99. 07

86. 09

92. 64

58. 09

2. 2

1. 2 , , 90e ~
100e , 2h3h4h
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4
T ab le 4 The ester ification of tim e
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con tent /%

yield /%

95. 78

81. 23

98. 83

86. 39

98. 92

86. 52

1. 2 , 0. 2mo
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0. 3m o
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2
2
T able 2 T he effec ts o f cata lyst reaction
catalyst u sage /mo l

conten t /%

yield /%

0. 2

90. 78

73. 65

0. 3

98. 18

85. 81

0. 4

98. 31

86. 23

2,
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T able 3 T he influence of the ester ification reaction temperature
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# 101#

conten t /%

yield /%

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86. 41

110

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72. 23

80e , ,
; 100e , ,
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[ 1]

. ( ) [ M ] . :

[ 2]

, 2000: 541- 542.

, . ( ) [ M ] . :
, 1994: 249- 250.

[ 3]

, . ( ) [ M ] . :
, 2007: 227.

[ 4]

. [ J ].
, 1990 ( 04) : 18 - 20.

( 55 )
[ 7]

CO 2 [ J] . 1994 ( 1) : 38 51.

[ 10] , . [ J] . ,
2005, 24( 11 ) : 54.

[ 8]

, , .

[ 11] . [ J] . , 2004, 32

[ 9]

[ J]. , 2003 ( 28) : 26 - 29.

, . [ J] .

( 5 ): 1- 6.
[ 12] . [ J] . ,

, 2002, 22 ( 6) : 92- 96.

2008, 26( 4) : 7 - 14.