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Ilmu Kimia
Kuat putus menunjukkan kekuatan akhir bahan polimer yang dihitung dari beban pada saat putus
dibagi luas penampang awal spesimen polimer, atau dapat diungkapkan dalam bentuk persamaan
berikut:
=F/A
dimana
F
A
=
=
=
kuat
beban
luas
putus
pada
penampang
bahan
saat
bahan
polimer
putus
polimer
(kgf/mm 2)
(kgf)
(mm 2)
Perpanjangan saat putus (%) didapat dari selisih antara panjang pada saat putus dengan panjang
mula-mula dan dibagi dengan panjang mula-mula atau dapat diungkapkan dalam bentuk
persamaan:
% = [L / Lo] x 100
Bila kecepatan tarik diperkecil, maka perpanjangan bahan akan bertambah, yang mengakibatkan
kurva teganganregangan menjadi landai sehingga modulus elastiknya menjadi kecil dan batas
lumernya tidak jelas. Kecenderungan ini sangat terlihat pada bahan yang fleksibel pada suhu kamar.
Makin tinggi kecepatan tarik maka kuat putus dan modulus elastiknya makin besar, sedangkan
perpanjangan menjadi kecil. Dengan demikian kecepatan tarik memberikan pengaruh besar pada
sifat mekanik bahan polimer. Oleh karena itu, persyaratan yang ketat harus diperhatikan untuk
setiap
pengujian
suatu
bahan
polimer.
Pengaruh temperatur terhadap kekuatan tarik polimer termoplastik adalah sangat besar. Jika
temperatur dinaikkan maka kekuatan tarik bahan polimer akan turun. Pada batas temperatur
tertentu (temperatur lunak, temperatur transisi gelas), deformasi karena tarikan akan meningkat
dengan cepat, sedangkan kuat putus dan modulus elastiknya akan menurun.
Sebaliknya di bawah temperatur tersebut kuat putus dan modulus elastik akan meningkat dan
perpanjangan pada saat putus akan menurun. Jadi, dalam penentuan sifat mekanik bahan polimer
perlu diperhatikan temperatur transisi tersebut (temperatur lunak, temperatur transisi gelas) agar
dapat
diketahui
sifat
mekanik
bahan
polimer
yang
sesungguhnya.
Pada umumnya pengaruh kelembaban terhadap kekuatan tarik serupa dengan pengaruh
temperatur. Meningkatnya kadar air yang terabsorpsi cenderung menghasilkan kurva teganganregangan
yang
serupa
dengan
pengaruh
temperatur.
Dengan meningkatnya air yang terabsorpsi maka kuat putus dan modulus elastik bahan akan
menurun, sedangkan perpanjangan saat putus akan meningkat. Polimer temoset dan termoplastik
umumnya tidak bersifat higroskopis, sehingga pengaruh kelembaban tidak dapat diamati. Akan
tetapi, seringkali diamati bahwa adanya air dalam jumlah sedikit dapat menyebabkan terjadinya
pengurangan modulus elastik.
Strength
Elongation
Modulus
Toughness
Mechanical Properties of Real Polymers
Pool Your Strengths
The slope isn't constant as stress increases. The slope, that is the
modulus, is changing with stress. In a case like this we usually that the
initial slope as the modulus, as you can see in the stress-strain curve
above.
In general, fibers have the highest tensile moduli, and elastomers have
the lowest, and plastics have tensile moduli somewhere in between
fibers and elastomers.
Modulus is measured by calculating stress and dividing by elongation,
and would be measured in units of stress divided by units of elongation.
The blue plot is the stress-strain curve for a sample that is strong, but
not tough. As you can see, it takes a lot of force to break this sample,
but not much energy, as there isn't much area underneath the curve.
Likewise, this sample can't stretch very far before it breaks. A material
like this which is strong, but can't deform very much before it breaks is
called brittle.
On the other hand, the red plot is a stress-strain curve for a sample that
is both strong and tough. This material is not as strong as the sample in
the blue plot, but the area underneath its curve is a lot larger than the
area under the blue sample's curve. So it can absorb a lot more energy
than the blue sample can.
So why can the red sample absorb so much more energy than the blue
plot? Take a look at the two. The red sample elongates a lot more before
breaking than the blue sample does. You see, deformation allows a
sample to dissipate energy. If a sample can't deform, the energy won't be
dissipated, and will cause the sample to break.
In real life, we usually want materials to be tough and strong. Ideally, it
would be nice to have a material that wouldn't bend or break, but this is
the real world. You have to make trade-offs. Take a look at the plots
again. The blue sample has a much higher modulus than the red sample.
While it's good for materials in a lot of applications to have high moduli
and resist deformation, in the real world it's a lot better for a material to
Fibers like KevlarTM , carbon fiber and nylon tend to have stress-strain curves
like the aqua-colored plot in the graph above. Like the rigid plastics,
they are more strong than tough, and don't deform very much under
tensile stress. But when strength is what you need, fibers have plenty of
it. They are much stronger than plastics, even the rigid ones, and some
polymeric fibers, like KevlarTM, carbon fiber and ultra-high molecular weight
polyethylene have better tensile strength than steel.
Elastomers like polyisoprene, polybutadiene and polyisobutylene have
Tensile Strength
The tensile strength is the stress
needed to break a sample45. It is
expressed in Pascals or psi (pounds
per square inch).
1 MPa =
145 psi
The tensile strength is an important
property for polymers that are going
to be stretched. Fibers, for instance,
must have good tensile strength46.
Return to Top
% Elongation to Break
The elongation-to-break is the strain on
a sample when it breaks. This usually
is expressed as a percent.
The elongation-to-break sometimes is
called the ultimate elongation46.
Fibers have a low elongation-to-break
and elastomers have a high elongationto-break47.
Return to Top
Young's Modulus
Young's modulus is the ratio of stress to
strain. It also is called the modulus of
elasticity or the tensile modulus48.
Young's modulus is the slope of a
stress-strain curve. Stress-strain curves
often are not straight-line plots,
indicating that the modulus is changing
with the amount of strain. In this case
the initial slope usually is used as the
modulus, as is illustrated in the diagram
at the right.
Rigid materials, such as metals, have a
high Young's modulus. In general, fibers
have high Young's modulus values,
elastomers have low values, and plastics
lie somewhere in between46.
Return to Top
Toughness
The toughness of a material is
the area under a stress-strain
curve. The stress is proportional to
the tensile force on the material and
the strain is proportional to its
length. The area under the curve then
is proportional to the integral of the
force over the distance the polymer
stretches before breaking.
Return to Top
% Elongation-to-
Young's Modulus
Break
(GPa)
Stainless Steel
Balls50
2,000
Very small
200
Cellophane
Film51
50 - 120
10 - 50
Nitrile Rubber
Sheet51
20 - 30
250 - 500
Very low
Fiberglass Yarn52
1400 - 2000
3-4
72
50
150
Nylon
53