Professional Documents
Culture Documents
K. Arulanandan
SOIL STRUCTURE:
In Situ Properties and Behavior
K. Arulanandan
Department of Civil and Environmental Engineering
University of California, Davis
July 2003
Foreword
The sadness of realizing Arul has left us was my predominant feeling as I started
writing this foreword. But as I kept writing, trying to bring back the most memorable
moments of my acquaintance with him, a smile comes over and my feelings change to
happiness to have met him.
Kandiah Arulanandan, or Arul as he was known to us, was my friend despite the
age difference. Arul had the ability to adjust his age towards the younger side. My first
impression of him when I came to UC Davis as a young Assistant Professor was that he
never knocks on the door before he enters. Later I understood that this was part of his
infusing personality. He literally forced me to deal with soil mechanics, for which I am
grateful to this day. I still remember him storming into my office during the first years of
our acquaintance waving a bunch of papers on soil fabric studies and experiments he
wanted me to work on. And I happily did, until days later I was finding a paper missing
which Arul had it but of course he forgot to give it to me at first place, costing both of us
many lost hours. He was not very well organized; the few times his office was neat and
orderly was when he had just moved into a new office when the Civil Engineering
department was changing buildings, and the faculty offices. Yet, within the mess of
papers in his office, Arul was the only one to know where a paper was hiding. The order
he had was of a different kind than most of us know, rooted in his head with the visionary
ideas he lived by. In his personal life with his students and friends, Arul was very
generous and the main images that come to my mind are those of laughing heartily
together on the social occasions we so often had. Arul may have appeared to do things
spontaneously, and this may have been true in many cases, but he also had plans of great
depth for his field, his students and his colleagues. The outgrowth of this book is perhaps
the greatest of his personal plans; pity he is not around to see it materializing, unless he
is.
Arul was a person with a vision for modern methods of numerical analysis in
geomechanics, an even more remarkable trait realizing that he was a traditionally trained
geotechnical engineer with no immediate grasp of advanced numerical techniques,
although he was very adept in soil mechanics theories of the Cambridge school of
thought. The VELACS project realized at UC Davis under the directorship of Arul was
perhaps the largest gathering of renowned researchers in geomechanics with the goal of
validating constitutive and numerical soil modeling by true predictions of centrifuge
experiments considered as boundary value problems. The late Cliff Astill of NSF who
funded VELACS has said that upon this accomplishment Arul had moved on to being a
statesman.
The true technical strength of Arul, though, was on soil characterization by
electrical methods, which constitutes the core aspect of this book and is a testimony of
Aruls contribution that will stay with us and future generations of geotechnical
engineers, as long as these issues are relevant to the profession. It was not only the
theoretical aspects that lead to the refinement of existing theories and development of
new ones that Arul with his students and colleagues worked on, but also the practical
application of such findings that Arul was so keen to pursue by working on a probe and
applying it in the field.
iii
But before I close this brief foreword for my friend, I shall refer to the other big
testimony of Aruls contribution: the excellent students he had supported and guided
throughout his years as a Professor and advisor. He had an innate ability to choose the
best of them. In the Civil Engineering Department of UC Davis there is no other faculty
member, past or present, with so many of his PhD advisees becoming Professors at USA
Universities. I was personally benefited by being able to also teach these students upon
the request of Arul, and eventually learn from them. All of them are now my friends. And
I am sure that I express their feelings when I say: Arul, we miss you.
Yannis F. Dafalias
Davis, January 2008.
iv
Preface
Soil Structure: In Situ Properties and Behavior is designed as a text for
undergraduate and graduate students in Soil Mechanics. An intensive effort was made to
correlate soil structure to soil properties. We have then used these relations to help
redirect soil properties using nondestructive in situ methods. Examples and problems are
included to illustrate the application of these methods. This text has been successfully
used in ECI 174 and ECI 283 classes at the University of California, Davis. Soil
Structure: In Situ Properties And Behavior has been principally written for students;
however, geotechnical engineers, technical geologists, environmental engineers, and
instrumentation specialists should also find it valuable in improving their nondestructive
in situ soil testing capabilities.
The focus of this text is on the quantification of soil structure, the establishment
of property-structure relationships, the mechanisms causing the behavior of soils, and the
properties that must be determined to analyze the influence of local site characteristics
and environmental factors on soil behavior. The book is divided into seven chapters.
Chapter 1 describes the need for nondestructive soil and site characterization, and it
briefly compares conventional methods and electrical methods. Chapter 2 describes the
need for a method to assess the factors that determine soil structure: mineralogy, pore
fluid composition, stress history, particle orientation, cementation, water content, and
density. Chapter 3 is devoted to quantifying soil structures and clay properties. This
chapter derives equations characterizing the electrical response of aggregate systems by
extending the MaxwellWagner and Fricke equations. Here, microscopic approach
predicts electrical dispersion characteristics of soil containing clay minerals. A
macroscopic approach, known as the Three-Element Model, is also presented. Chapter 4
explores the relationship between the electrical dispersion characteristics of soil and
various engineering properties. Chapter 5 gives an overview of the equipment used to
nondestructively determine electrical dispersion data in situ. Chapter 6 discusses
characterization of non-clay minerals. The chapter presents theoretical development of
the formation factor tensor and anisotropy index along with an example evaluating the
formation factor and anisotropy index of Monterey 0 sand using theoretical equations.
Chapter 7 describes the successful use of electrical methods to predict two complex soil
behaviors. Erosion potential was predicted using a combination of dielectric dispersion
behavior and Sodium Absorption Ratio (SAR), while frost heave potential was evaluated
using the dielectric constant and c parameter (from the ThreeElement Model.) Appendix
A presents example applications using the formation factor method of nondestructive soil
characterization and SUMDES program for site response analysis. Derivations for double
layer equations and the three element model are given in Appendix B. Sample laboratory
experiments for understanding the methods presented are given in Appendix C.
The book is an outgrowth of an accidental observation I made in 1960 when I was
the senior materials engineer for the Gold Coast government. During this period, several
Russian geologists visited the Gold Coast to explore for oil. One method used to detect
hydrocarbons is to determine the electrical conductivity of a soil. During the
measurements a change in the frequency of measurement showed a change in the
vi
CONTENTS
2. SOIL STRUCTURE
9
10
12
2.1 Introduction
12
2.2 Mineralogy
13
17
18
2.5 Fabric
22
2.6 Conclusions
26
2.7 Problems
27
28
3.1 Introduction
28
29
34
37
42
45
46
3.8 Summary
56
vii
3.9 Problems
57
61
4.1 Introduction
61
61
65
66
67
68
69
72
74
76
4.11 Summary
80
4.12 Problems
80
88
88
109
113
6.1 Introduction
113
114
125
136
140
6.6 Problems
143
viii
147
7.1 Erosion
147
163
7.3 Problems
167
170
171
APPENDIX B DERIVATIONS
B.1 Double-Layer Theory
197
229
229
232
232
234
236
C.4 Erosion
237
ix
Chapter 1
Need for Soil and Site Characterization
1.1 IMPORTANCE OF SOIL AND SITE CHARACTERIZATION
Over the past eight thousand years, we humans have built structures on the earth ranging
in size and complexity from simple mud huts to towering skyscrapers. Except for airplanes in
flight and ships in the ocean, virtually all our infrastructure systems are built on or in soil. So the
question must be asked, how can we reliably predict soil behaviors due to natural hazards, such
as earthquakes, erosion, frost heave, swelling, and liquefaction, and man-made hazards, such as
contaminant migration. To understand soil behavior, proper soil characterization is critical.
1.2 HISTORICAL DEVELOPMENT OF SOIL CLASSIFICATION
Up until the 19th century, every problem in soil mechanics was referred to a geologist.
The suitability of a site for constructing a large structure was determined by an extensive
geological survey. The geologist or soil engineer would classify the soil at the site into broad
categories. Each soil type was assigned a particular range of strength values based on the bearing
capacity of the soil. When a structure designed on the basis of this classification failed, the
failure was attributed to an inaccurate geological survey.
In 1910, an engineer named Karl Terzaghi started investigating the causes of such
failures. For two years of hard labor, he collected data pertaining to a number of case histories
of foundation failures. The geological surveys carried out at sites where failure had occurred
were found to be correct and adequate. Terzaghi concluded that it was the nature of the surveys
themselves that led to the failure of foundations which were thought to be safe. The methods
used to determine soil stability were somehow lacking. Thus, the actual causes of the failures
were unknown.
In 1916, Terzaghi realized that the cause of the failures was improper soil classification.
According to Terzaghi (1957):
After I arrived in Istanbul, late in the fall of 1916, the first topic of my
contemplation was the dismal failure of my attempt to get useful information out
of my collection of case records. Going over my data once more, I realized, quite
suddenly and surprisingly, the classification of the materials whose performance
was observed was, from an engineering point of view, inadequate, although for
geological purposes it was quite satisfactory.
The subsurface materials
encountered at the sites of construction operations were divided into categories
such as coarse and fine sand, or soft and stiff clay, each of which included
minerals of widely different engineering properties. Hence, I concluded, this time
correctly, that engineering geology cannot possibly become a reliable tool in the
hands of earth works engineers unless and until we acquire the capacity to assign
to each material of the earth numerical values which make it impossible to
mistake it for another with significantly differing engineering properties.
1
Figure 1.1
Activity vs. Clay Content
(After Lambe and Martin, 1953-1957)
For these reasons, Atterberg Limits are often not reliable for properly estimating soil
properties. Furthermore, for two soil samples with the same gradation, both containing a small
percentage of fines (e.g., 5%), it would not be possible to determine Atterberg Limits for either
sample because there are not enough fines to test. However, if the fines in one sample contained
clay minerals, and the fines in the other contained non-clay minerals such as silica flour, the
mechanical properties of the two soils would be different. Lambe and Martin (1953-1957) found
that Atterberg Limits could not always be used to accurately predict compressibility. For soils
indigenous to St. Louis and elsewhere, they found that "very large changes in volume can occur
with changes in load or changes in moisture conditions, and that these changes are partially
reversible. The Atterberg Limits of the St. Louis soil (Sample 19, [L.L.] = 58, [P.L.] = 22) do
not suggest such unusual compressibility characteristics" (Lambe and Martin, 1953-1957).
Figure 1.2
Relation Between Clay Content and Clay Size
for Several Soils (After Lambe and Martin, 1953-1957, and
Basu and Arulanandan, 1973)
The parameters used to identify swell potential, activity, and percent finer than 2 m, are
not adequate to evaluate percent swell for some natural soils. Seed, et al., (1962) used activity
and percent finer than 2 m to evaluate the swell potential of a soil. Their results were valid for
the artificial soils they tested. A study of both natural and artificial soils evaluated the ability of
the activity index and the percent clay size to predict swell potential (Basu and Arulanandan,
1973). Table 1.1 tabulates the composition, percent clay size, activity, and percent swell for
each sample. Figure 1.3 plots the percent swell for the samples on the chart developed by Seed,
et al., (1962). The percentage of total swell predicted for samples 1PB, 3SC, and Marysville Red
(MR) is significantly lower than the measured value. Thus, while the predicted values are
reasonable for artificial soils, the predictions are inconsistent for some natural soils.
Table 1.1
Composition and Swell Properties of Natural and Artificial
Soils (After Basu and Arulanandan, 1973)
Figure 1.3
Classification Chart for Swelling Potential
(after Seed, et al., 1962)
The soil samples from Table 1.1 are also plotted in Skempton's (1953) activity chart,
Figure 1.4. The three solid lines represent the three clay minerals, montmorillonite, illite, and
kaolinite, from highest to lowest activity. These lines were developed by mixing quartz sand
with varying percentages of the three clay minerals. Comparison of the samples to the solid
lines shows that activity does not consistently follow mineralogy. For example, Soil 15 with
15% montmorillonite is expected to plot near the solid line representing montmorillonite with an
activity of 7.2. Soil 15 actually plots below the line representing kaolinite (activity = 0.38),
suggesting an entirely different mineralogy. Note that samples 1PB, 3SC, 11, 9, 3, and 8 show
similar deviations. Thus, activity cannot be used to predict soil mineralogy.
Figure 1.4
Clay Fraction and Plasticity Index of Some Natural Soils in
Relation to the Activity Chart of Skempton (1953)
In the construction of a section of road in Marysville, California, the subgrade consisted
of a silty soil with the following properties: LL = 46, PI = 11, % < 2 m = 20, % < 1 m = 14,
% Sand Size = 10, % Silt Size = 70, and % Clay Size = 20 (Arulanandan, 1974). Three different
methods were used to predict the swell potential: Skempton's Activity (1953), Holtz and Gibbs
percent of free swell (1956), and a chart developed by Seed, et al. (1962). All of these methods
predicted that the soil would have a low swell potential. However, during construction, the
desired density could not be obtained regardless of the compactive effort, due to the expansive
nature of the soil. To determine the actual swell potential of the soil, free swell tests were
conducted in the laboratory. Numerous samples of the soil were compacted. They were then
subjected to swell at various water contents and dry densities, in -inch-deep by 4-inchdiameter, Teflon-lined rings with porous plugs. The free swell of the samples varied up to 30%.
This swelling suggested that the soil had a high swell potential (Arulanandan, 1974).
From the previous examples, several points can be made about some of the standard
methods used in conventional geotechnical analysis: (1) gradation analysis alone is insufficient
to characterize soils unless the mineralogy of the fine particles is taken into consideration;
(2) Atterberg Limits alone are insufficient for predicting the volume change characteristics of all
natural soils (Lambe and Martin, 1953-1957); and (3) the percent of particles less than 2 m in
size and the activity criteria are insufficient for predicting swell potential of all natural soils.
It has also been shown that numerous dams designed to withstand erosion based on the
Unified Soil Classification System have failed (Arulanandan and Perry, 1983). Exxon developed
methods for evaluating frost heave at a cost of 75 million dollars during Alaskan pipeline
construction. These methods, which used particle size criteria and properties such as gradation
and plasticity characteristics, have been shown to be inapplicable to soils in Canadas Mackenzie
Valley (Arulanandan and Shinde, 1981). For sands placed at the same porosity by different
methods, it reportedly takes significantly different stress ratios to cause a loss of bearing strength
due to high pore water pressure (liquefaction). This difference is a function of soil particle
arrangement (the soil fabric) (Arulanandan and Muraleetharan, 1988). It is well known that
hydrogeologic properties such as permeability depend on the in situ structure of soils. Therefore,
a non-destructive method of quantifying soil structure is necessary.
In spite of the significant observations reported by Lambe and Martin and others,
engineers have continued to use Atterberg Limits and particle size as the principal parameters to
classify soils and predict soil behavior. Swell, erosion, frost heave, and liquefaction potentials
have been evaluated using particle size, relative density, Atterberg Limits, and activity, with
serious consequences (Lambe and Martin, 1953-1957; Arulanandan, 1974; Basu and
Arulanandan, 1973; Muraleetharan and Arulanandan, 1986; Arulanandan and Perry, 1983;
Arulanandan and Shinde, 1981; Arulanandan, et al., 1986). Why do procedures based on grain
size or the properties of remolded materials fail? The answer may be they do not take into
consideration the characteristics of intact materials (soil structure) as found in nature.
1.3 DEVELOPMENT OF IN SITU METHODS
The methods thus far described exhibit severe limitation in soil classification. Other
laboratory procedures for determining soil composition, including x-ray diffraction and
differential thermal analysis, are destructive and cannot be used in situ to assess the intact state
of the soil. Additionally, while these methods may be used qualitatively to describe soil
composition, they cannot be used quantitatively to evaluate the potential behaviors of soils.
Since the 1930s, engineers have been using the Standard Penetration Test (SPT) and
Cone Penetration Test (CPT) as the primary methods of characterizing soils in situ. The SPT is
used because it permits rapid, economic evaluation of gross ground conditions in boreholes. The
CPT is used to obtain quantitative data on the thickness and consistency of soft layers and to
estimate the bearing capacity of piles in deep sand layers. Unfortunately, CPTs and SPTs cannot
identify the type of clay within a broad group called "clay." Standard field methods cannot
evaluate the soil mineralogy, pore fluid composition, particle orientation, mineral-solution
interface characteristics, total porosity, and inter- and intracluster void ratios in clays. Thus,
there is a need for in situ field tests that can be used to evaluate these characteristics to
accurately and rapidly determine soil properties and behavior at a reasonable cost.
Without disturbing the soil, current methods of site characterization cannot evaluate in
situ any of the following engineering soil properties and behavior: mineralogy (i.e., clay type and
amount), permeability, porosity, compressibility, strength, swell, erosion, frost heave, and
liquefaction potential.
Figure 1.5 shows the relationship between cyclic stress ratio and number of cycles
needed to cause initial liquefaction for samples of Monterey 0 sand prepared by different
methods at the same relative density. In Figure 1.5, dc is the amplitude of deviatoric cyclic stress
and o' is the initial confining pressure. Also given in Figure 1.5 are the measured electrical
anisotropy index (A) values. The figure shows that, for the same cyclic stress ratio, samples with
a higher value of A need fewer cycles to cause initial liquefaction. This implies that, for a given
number of cycles and given cyclic stress ratio, higher anisotropy produces a larger increase in
pore-water pressure. This effect cannot be quantified using traditional approaches.
Figure 1.5
Cyclic Stress Ratio versus Number of Cycles to cause initial
Liquefaction for Monterey 0 Sand Samples Prepared by Different Methods
(after Mulilis, et al., 1977)
1.4 NEW DEVELOPMENTS IN NON-DESTRUCTIVE METHODS OF IN SITU SOIL
AND SITE CHARACTERIZATION
During the last thirty years, methods have been developed to quantify of soil composition
and fabric by non-destructively measuring the electrical properties of a soil in its intact state.
These methods, namely the Dielectric Dispersion Method and the Formation Factor Method, are
described and detailed in Chapters 3, 4, 5, and 6 and used throughout this book to quantify soil
structure and to evaluate soil properties and behavior. By using the dielectric dispersion
behavior of clay minerals, the engineer can characterize the intact state of the soil nondestructively, thus evaluating, in situ, the engineering properties and soil behavior.
Measurement of electrical properties is a non-destructive process. This process can be carried
out in either field or laboratory on "undisturbed" samples, thereby preserving the intact structure
of the soil. Electrical soil characterization allows for in situ soil classification. This approach
can be used to evaluate and remediate a number of natural and manmade hazards, such as swell,
erosion, frost heave, and liquefaction.
1.5 PROBLEMS
1. Discuss the traditional approaches available for studying the relationship between soil
composition and engineering properties.
2. Why is it difficult to use the knowledge of soil composition to quantitatively predict
engineering properties?
REFERENCES
Arulanandan, K., (1974). Properties and Behavior of Marysville Soil, University of California
at Davis Report, Davis, CA.
Arulanandan, K., and Muraleetharan, K. K. (1988). "Level Ground Soil-Liquefaction Analysis
Using In Situ Properties: I," Journal of Geotechnical Engineering, ASCE, Vol. 114, No. 7, July.
Arulanandan, K., and Perry, E. B. (1983). Erosion in Relation to Filter Design Criteria in Earth
Dams Journal of Geotechnical Engineering, ASCE, Vol. 109, No. 5, pp. 682-697.
Arulanandan, K., and Shinde, S. B. (1981). Frost Heave Susceptibility Criteria for Soils,
University of California at Davis Report.
Arulanandan, K., Yogachandran, C., and Meegoda, N. J., (1986). Comparison of the SPT,
CPT, SV and Electrical Methods of Evaluating Earthquake Induced Liquefaction Susceptibility
in Ying Kou City During the Haicheng Earthquake, Proceedings of In Situ 86, ASCE,
Blacksburg, VA, pp. 389-415.
Atterberg, A. (1908). Studien auf dem Gebiet der Bodenkunde (Studies in the field of soil
science), Landw. Versuchsanstait, 69.
Basu, R., and Arulanandan, K. (1973). A New Approach for the Identification of Swell
Potential of Soils, Proceedings of the Third International Conference on Expansive Soils, Haifa,
Israel, Vol. 1, pp. 1-11.
Casagrande, A (1948). Classification and Identification of Soils, Transactions, ASCE, Vol.
113, pp. 901-991.
Holtz, W. G., and Gibbs, H. J. (1956).
Transactions, ASCE, Vol. 121, pp. 641-677.
10
Seed, H. B., Woodward, R. J., and Lundgren, R. (1962). Prediction of Swelling Potential for
Compacted Clays, Journal of Soil Mechanics and Foundations Division, ASCE, Vol. 88, No.
SM3, pp. 53-87.
Skempton, A. W., (1953). The Colloidal Activity of Clays, Proceedings of the Third
International Conference on Soil Mechanics and Foundation Engineering, Zurich, Vol. 1, pp. 5761.
Terzaghi, K., (1957). Opening Session Address, Proceedings of the Fourth International
Conference on Soil Mechanics and Foundation Engineering, London, 3, 55-58.
U. S. Bureau of Reclamation, (1963). Earth Manual, 1st ed., revised, Washington, DC.
11
Chapter 2
Soil Structure
2.1 INTRODUCTION
Soil structure encompasses soil mineralogy, particle-solution interface characteristics,
and fabric or arrangement of particles. Many of the factors that make up the soil structure are
interdependent. The structure of a soil is also influenced by environmental factors such as
temperature and confining stress. Together, soil structure and environmental factors determine
the engineering properties and behavior of soils.
To characterize a soil adequately by any method, it is necessary to get a handle on the
seven factors that determine soil structure. These factors are mineralogy, pore fluid composition,
stress history, particle orientation, cementation, water content, and density. The importance of
each factor is briefly described below.
2.1.1 Mineralogy
Mineralogy refers to the composition of the individual particles in an element of soil.
The nature and arrangement of the atoms in a soil particle significantly affect its physicalchemical properties (Mitchell, 1993).
2.1.2 Pore Fluid Composition
The spaces, or pores, between soil particles are filled with pore fluid, composed of air
and/or water. This portion of the soil plays a vital role in site characterization. The composition
of the pore fluid strongly influences the nature of the mineral-solution interface. It follows that it
will also affect the interaction of particles with one another. Pore fluid composition is an
important factor when evaluating such concepts as swell potential, erosion potential, frost heave
potential, and contaminant migration.
2.1.3 Stress History
The history of a site will obviously play a role in site characterization. An
overconsolidated soil will exhibit different characteristics than a normally consolidated soil. In
most cases, soil deposits have been in place for many years. During this period they develop a
stress history that can influence the overall behavior. It is important to retain this history if a
proper evaluation is to be performed. Removing a sample from the ground significantly changes
the effects of the different levels of stress exerted on the soil over time. It is unlikely that a
laboratory experiment will be able to reconstitute or exactly simulate field conditions. Thus,
proper site characterization requires completely undisturbed soil samples or non-destructive, in
situ methods of characterization.
12
13
relation to the long-term physical and chemical properties controlling soil behavior under altered
and extreme environmental conditions.
2.2.1 Types of Minerals in Soils
Silicates are, by far, the most common minerals in soils. Indeed, silicates make up over
90% of the Earths crust. Other minerals found in soils include carbonates, sulfates, and native
metals.
For the purposes of soil mechanics, the types of minerals found can be divided into two
broad groups: clays and non-clays. All clays are silicates, as are the vast bulk of non-clays.
What differentiates them is that non-clay minerals are only very weakly cohesive and are
considered granular soils. Their properties and behavior depend primarily on particle size,
particle shape, surface texture, size distribution, and fabric. The behavior of a soil consisting of a
substantial quantity of clay, however, depends largely on the type and amount of clay minerals
present, as well as mineral-solution interface characteristics and fabric.
Because of their crystal structure and composition, clay minerals exhibit a negative
surface charge. This property of clay minerals dominates their behavior when pore fluid is
present. Non-clay minerals lack this surface charge, and so their behavior can be explained in
terms of particle size, shape, and packing arrangement.
2.2.2 Clay Minerals
The clay minerals in soils belong to the mineral family called phyllosilicates. Clays have
small particle sizes, and their unit cells ordinarily have a residual negative charge that is
balanced by adsorbing cations from solution. The net negative charge is the result of
isomorphous substitution in the unit cells and has an important effect on soil properties such as
swelling and erosion.
Clay structures are made up of combinations of two simple structural units: the silicon
tetrahedron and the aluminum or magnesium octahedron, as shown in Figure 2.1. These
structural units may repeat in number to form silica sheets, alumina sheets (also called gibbsite
sheets), or magnesium sheets (also called brucite sheets). Different clay mineral groups are
characterized by the different stacking arrangements of these sheets, as illustrated in Figure 2.2.
Not only may the stacking arrangements vary between the clay minerals, but also the type of
chemical bonding between the clay sheets. As shown in Figure 2.2, illite minerals have
potassium ions complexed between the silica sheets, whereas in montmorillonite minerals, the
silica sheets are separated by thin layers of water molecules. Mitchell (1993) provides detailed
descriptions of the structure of many clay minerals.
Grouping the clay minerals according to crystal structure and stacking sequence of the
layers is convenient, because members of the same group have generally similar engineering
properties. Two-sheet minerals such as kaolinite consist of a silica sheet and an octahedral sheet
(e.g., gibbsite or brucite). Three-sheet minerals such as illite and montmorillonite consist of
either two or three octahedral sheets between two silica sheets.
14
Figure 2.1
Arrangement of the Basic Structural Units of Clay Minerals
Figure 2.2
Arrangement of Unit Layers to Form Different Clay Minerals
15
The combination of an octahedral sheet with one silica sheet (for two-sheet minerals) or
of an octahedral sheet with two silica sheets (in the case of three-sheet minerals) are called unit
layers. Most clay minerals consist of many unit layers stacked upon each other in a parallel
fashion as shown in Figure 2.2.
As mentioned earlier, isomorphous substitution is an important factor in the structure and
properties of clay minerals. In an ideal gibbsite sheet, only 2/3 of the octahedral positions are
filled, and all cations are Al3+. In an ideal brucite sheet, all octahedral positions are filled with
Mg2+, and in an ideal silica sheet, all cations are Si4+. However, due to a similarity of ion size,
some octahedral and some tetrahedral positions can be occupied by other cations. When this
substitution occurs without changing the crystal structure, it is known as isomorphous
substitution. Isomorphous substitution causes a net negative charge on clay minerals because of
the lower valence cations replacing those of higher valence. Common examples of isomorphous
substitution include aluminum in place of silicon, magnesium in place of aluminum, and ferrous
iron in place of magnesium.
Isomorphous substitution in all of the clay minerals (with the possible exception of
kaolinites) gives clay particles a net negative charge. To preserve electrical neutrality,
surrounding cations (from the pore fluid for example) are attracted and held between the unit
layers (as shown in Figure 2.2 for illite) and on the surface edges of the clay particles. Many of
these cations are exchangeable because they may be replaced by different cations. The quantity
of exchangeable cations is termed the cation exchange capacity of a particular clay mineral, and
is usually expressed as milliequivalents per 100 grams of dry clay.
The types of bonding between unit layers of three-sheet minerals (bonding between the
silica sheets) influence clay properties such as swelling and erosion. For example, the water
layers between the unit layers of montmorillonite lead to weak bonding. This influences
engineering properties such as strength, swelling, and erosion.
2.2.3 Non-Clay Minerals
Non-clay soils are virtually cohesionless and have special characteristics determined
primarily by particle size, shape, surface texture, size distribution, and packing. The mineral
composition determines hardness, cleavage, and resistance to physical and chemical breakdown.
While some carbonates and sulfate minerals are soluble within a project's time frame, in most
cases the non-clay minerals can be considered relatively inert.
Bulky, non-clay particles constitute gravel, sand, and most of the silt fraction in a soil.
Most soils results from the weathering or breakdown of preexisting rocks and soils. Thus, the
predominant mineral constituents in any soil are those abundant in the source material and either
are highly resistant to weathering, abrasion, and impact or are the weathering products of
minerals such as feldspar and olivine. The non-clay fraction of soil is mostly rock fragments or
grains of common rock-forming minerals.
Quartz is the most abundant mineral in most soils, with small amounts of feldspar and
mica present. Quartz belongs to the group of silicates called tectosilicates. The structure of
tectosilicates consists of silica tetrahedra arranged in three-dimensional frameworks with all four
oxygens in each tetrahedron shared with neighboring tetrahedra. This tetrahedral structure is
very stable and strongly bonded. The result is that quartz has no cleavage planes, no weakly
bonded ions in the structure, and a high hardness (resistance to scratching). These factors
explain the persistence of quartz in soil.
16
4r2
4
r3
3
6
=
r D
(1)
The SSA for bulky particles is on the order of 1 m2/g. Platy particles are long, thin boxes of
length L, width b, and height h as illustrated in Figure 2.3.
Figure 2.3
Schematic Representation of a Platy Particle
17
SSA =
(2)
The SSA for platy particles can be up to 600 m2/g. Size and SSA are usually inversely related as
shown in Figure 2.4.
Figure 2.4
General Relationship Between Specific Surface Area (SSA) and Particle Size
Although clay size is defined in soil mechanics as smaller than 2 m, true clay properties result
from the high SSA of their plate-shaped particles. For example, quartz can be ground to a
powder of less than 0.002 mm size. Despite the fact that the quartz flour is of clay size, it has no
cohesion or plastic properties. The particles, though small, are still roughly spherical and bulky
and do not behave as clay particles. Atterberg Limits and gradation cannot be used to define soil
adequately because behavior depends on mineral composition, particle shape, and mineralsolution interface characteristics. Because of their large SSA, surface forces dominate in clays,
while gravity forces dominate in non-clays.
2.4 PARTICLE-SOLUTION INTERFACE CHARACTERISTICS
The termination of a solid particle at a surface or phase boundary produces unsatisfied
bonds. This is because of the absence of atoms that would normally be bonded to the atoms at
the surface. The unsatisfied bonding forces may be balanced in one of several ways (Mitchell,
1993):
1) attraction and adsorption of ions or molecules from the adjacent phase
2) cohesion to the surface of another particle of the same substance
18
19
Figure 2.5
The Diffuse Double Layer
In developing an equation for the double layer thickness, which is the region occupied by
the diffuse layer, the following idealizing assumptions were made:
1) One clay particle suspended in an electrolyte solution is considered.
2) The particle surface is a plate that is large relative to the thickness of the
double layer (no edge effects).
3) Charge on the particle surface is distributed uniformly.
4) The electrolyte solution has a uniform dielectric constant.
5) The negative charge on the clay plate is neutralized by excess ions of opposite sign.
6) All ions are taken as point charges and there are no interactions between them.
The thickness of the double layer for dilute suspension of particles can then be expressed as:
1 = o DkT
(3)
K
2no e 2 2
where:
1/K = double layer thickness, Angstrom
k = Boltzman's constant, 1.38 X 10-23 JK-1
T = absolute temperature, K
0 = permittivity of a vacuum, 8.85 X 10-12 C2/Jm
D = dielectric constant of the medium
v = valence of the cation
20
K=
(8.85X10
(2)(5.0X10
12
22
C 2 J 1 m 1 )(80)(4.0X1021 J)
ions/ m )(1.602X10
3
19
C ) (1)
2
= 3.33X10 m = 333A
The equation for the double layer thickness quantitatively indicates the influence of
compositional factors. Increasing the dielectric constant increases the double layer thickness.
Increasing the temperature should have the same effect, but the higher temperature reduces the
dielectric constant, so the net effect is a reduction in double layer thickness. A decrease in the
salt concentration increases the double layer thickness, while an increase in the bulk
concentration decreases in the double layer thickness. Cation exchange from a higher valence
ion to a lower valence ion increases the double layer thickness, because a weaker attraction to
the mineral surface means more ions are needed to neutralize the charge on the clay plate.
The composition and type of pore fluid present in the soil greatly affects the surface
forces acting on the soil particles. Therefore, it is necessary to quantify electrolyte to evaluate
soil behavior. The bulk concentration of electrolyte in the pore fluid can be obtained by
extracting some pore fluid from the soil and measuring the electrical conductivity. The following
equation may be used to estimate the concentration of salts in the fluid:
c 10
(4)
where is the conductivity in /cm, and c is the concentration of pore fluid in normality (N).
Using special electrodes, we can determine the concentrations of the major cations in soil pore
fluid, Na+, Ca2+, and Mg2+. From these concentrations, we can obtain the sodium adsorption
ratio (SAR):
21
SAR =
Na +
Ca 2 + + Mg2 +
2
(5)
Here Na+, Ca2+ and Mg2+ are the concentrations of the respective cations in the solution
expressed in milliequivalents per liter. The SAR measures the amount of Na+ in the solution
phase. Because sodium is of lower valence than either calcium or magnesium, a lower SAR
value corresponds to a thinner double layer (i.e., fewer low-valence cations compared to highvalence cations). SAR and conductivity are good indications of the composition and type of
pore fluid.
2.4.3 Density of Surface Charge
The density of charge on the surface of clay particles can be derived from the exchange
capacity per gram and the SSA.
2.5 FABRIC
The term fabric refers to the arrangement of particles, groups of particles, and pore
spaces in a soil. Figure 2.6 illustrates the two major types of clay soil fabrics.
Figure 2.6
Dispersed (a) and Flocculated (b) Soil Structure
There are two extremes: dispersed (or deflocculated) and flocculated. In dispersed soil, the clay
particles are oriented nearly parallel to each other, as shown in Figure 2.6a. In flocculated soil,
the platy clay particles are oriented in all different directions, as shown in Figure 2.6b. Two
particles may have edge to face or edge to edge associations. Sometimes a few soil particles
may have face to face associations. These small groups are called aggregates.
Many researchers have proposed the concept of soil particles existing in clusters (Olsen,
1962; Yong and Sheeran, 1973). Clusters are groups of particles or aggregates forming larger
fabric units. Soil particles, especially clays, form clusters. These clusters can contain millions of
particles. Dispersed structure results in only a few dozen particles in a floc (cluster), while
22
flocculated structure can result in hundreds of particles making up each floc. Pictures of the two
types of clusters are shown in Figure 2.7.
Figure 2.7
Dispersed and Flocculated (Clay) Clusters
If the overlapping double layers between two clay particles are thick, then the repulsion between
the two similarly charged layers may be sufficient to prevent the particles from getting close
enough for van der Waals' forces to operate. This means that the clay particles cannot form
clusters, and they remain in a completely dispersed or deflocculated state.
Electron microscope studies have shown that soils in which clay particles form clusters
exhibit the two kinds of void ratio shown in Figure 2.8: intracluster and intercluster. Intracluster
void ratio (ec) characterizes voids between particles inside clay flocs. Intercluster void ratio (ep)
describes the voids between the clusters. The clustering of particles in a floc controls several
properties. Permeability is highly dependent on intercluster void ratio, as flow rate is
proportional to the fourth power of the radius of the pore. Because intracluster pores are very
small compared to intercluster pores, the bulk of the flow moves between clusters. A dispersed
system has a low intercluster void ratio, so permeability is lower by one or two orders of
magnitude. Flocculated systems tend to have a higher intercluster void ratio and thus a higher
permeability.
23
Figure 2.8
Intracluster (eC) and Intercluster (eP) Void Ratios
Figure 2.9
Sodium Adsorption Ratio (SAR), Total Cation Concentration, and the Demarcation
between Deflocculated and Flocculated Soil Structures (after Rowell, 1963, and Aitchison
and Wook, 1965)
24
The effect of SAR on soil fabric can be seen by considering the following. A soil with a
constant total salt concentration will have different permeabilities when the SAR is changed. As
SAR increases, permeability will be roughly the same for a while. It will then drop off sharply
by about three orders of magnitude (10% to 15%) at a certain SAR. If SAR is varied for soils
with other total salt concentrations, still locating the sharp change in permeability, a curve can be
determined. The curve connecting the SAR values when the large change in permeability occurs
forms the demarcation line between flocculated and dispersed fabric. Figure 2.9 shows this
demarcation line for montmorillonite.
The change in fabric type is due to the SAR's effect on the double layer thickness. At
high SARs, the double layer is thick, and repulsive forces dominate between clay particles. This
results in a dispersed fabric and minimal cluster formation. At low SARs, repulsion between
particles is reduced, resulting in a flocculated fabric and the grouping of particles into clusters.
Figure 2.10
Compression of Dual Porosity Soils
Olsen's cluster model went beyond merely theorizing the existence of dual porosity in
clays. He hypothetically assumed that when soils with large water contents are compressed, the
void ratio of the clusters (intracluster void ratio) does not change very much, as shown by the flat
portion of Figure 2.10. Initial compression is the result of decreasing the intercluster void ratio
causing the clusters to become more tightly packed. When the intercluster pore space becomes
comparable to that of a system of closely packed spheres, the clusters themselves start to
25
compress. At this point, the intracluster void ratio starts to decrease along with the intercluster
void ratio, although the intercluster void ratio now decreases less rapidly than before. When the
soil is unloaded, the increase in total void ratio is mainly due to swelling of the clusters. Thus,
the slope of the swell line , as shown in Figure 2.11, relates to the intracluster void ratio, ec.
Figure 2.11
Typical Consolidation Curve
High ec means large swelling, and low ec means low swelling. The swelling line is
elastic, so the recompression will follow the same slope as the rebound. However, the virgin
compression line with slope represents plastic deformation, resulting in a change in void ratio
that cannot be entirely recouped when the soil is unloaded along the swelling line of slope
(<). Thus, the decrease in the intracluster void ratio occurring along the line is not wholly
recoverable when the soil is unloaded. The elastic rebound and recompression line characterize
ec, and the normal plastic compression line characterizes ep.
In summary, flocculated soils, characterized by low SAR and extensive cluster formation,
have low swell potential but are highly permeable. Conversely, dispersed or deflocculated soils,
characterized by high SAR and minimal cluster formation, have high swell and erosion potential
with low permeability.
2.6 CONCLUSIONS
Heterogeneous media, such as the three-phase soil-mass system, have a geometrical
structure that is not always regular. Interpreting the properties of such media is of fundamental
practical importance in understanding their behavior. Thus, it is worthwhile to characterize such
media by non-destructive methods. Examples of such media are clay-water-electrolyte systems,
granular soils, certain porous water- or oil-bearing rocks, ion-exchange columns with interstitial
pore space filled with aqueous electrolyte solutions, and even certain molecular filter
membranes. One approach to nondestructive characterization is to use electrical response
characteristics to quantify soil structure. This approach is based on evaluating the electrical
response characteristics of soil placed in an alternating electrical field. Chapter 3 presents the
background of the electrical methods.
26
2.7 PROBLEMS
1. Describe the electrical double layer that forms around clay particles. Why do the balancing
cations diffuse away from the particle surfaces in an aqueous environment?
2. Illustrate the effects of changes in each of the following on the thickness of the double layer.
Give reasons for the effects shown. (a) ionic concentration; (b) valence; (c) temperature; (d)
dielectric constant; (e) ionic size; (f) pH; (g) anion adsorption.
3. Discuss the effects of changes in each of the variables given in Question 2 on the swell and
swelling pressure of given clay.
4. Define Specific Surface Area (SSA) and calculate the SSA of a sphere, a flat plate, and a
circular plate (disk).
REFERENCES
Aitchison, G. D., and Wook, C. C. (1965). "Some Interactions of Compaction, Permeability, and
Post-Construction Deflocculation Affecting the Probability of Piping Failure in Small Earth
Dams," The Sixth International Conference on Soil Mechanics and Foundation Engineering,
Montreal, Canada, Vol. 2, p. 442.
Chapman, D. L., (1913). A Contribution to the Theory of Electrocapillarity, Philosophical
Magazine, Vol. 25, No. 6, pp. 475-481.
Gouy, G. (1910). Sur la Constitution de la Charge Electrique a la Surface d'un Electrolyte,
Anniue Physique, Paris, Serie 4, Vol. 9, pp. 457-468.
Mitchell, J. K., (1993). Fundamentals of Soil Behavior, John Wiley and Sons. New York.
Olsen, H. W., (1962). Hydraulic Flow through Saturated Clay, Proceedings of the Ninth
National Conference on Clays and Clay Minerals, pp. 131-161.
Rowell, D. L. (1963). Effect of Electrolyte Concentration on the Swelling of Oriented
Aggregates of Montmorillonite, Soil Science, Vol. 96, p. 368.
Yong, R. N., and Sheeran D. E., (1973). Fabric Unit Interaction and Soil Behavior,
Proceedings of the International Symposium on Soil Structure, Gothenburg, Sweden, pp. 176183.
27
Chapter 3
Electrical Dispersion and
Soil Structure
3.1 INTRODUCTION
The engineering properties of soil depend to a large extent on the following factors,
which influence soil structure:
1.
2.
3.
4.
5.
Mineralogy
Pore fluid composition
Fabric
Porosity
Stress history.
This is shown by the works of Lambe (1958, 1960), Lambe and Martin (1953-1957), Rosenquist
(1955, 1958), Bolt (1956), Mitchell (1956), Seed and Chan (1959), Martin (1960), Olsen (1961),
and many others. Different testing methods have demonstrated the fundamental dependence of
engineering properties on the above factors. However, no single method can quantitatively
evaluate all the factors making up the total structure of a soil. Most current methods for
determining mineralogy and soil fabric involve sample destruction. The search for a method to
evaluate these soil characteristics without destroying the sample has led to investigations into the
usefulness of soil electrical properties for characterization.
The extension of the Maxwell, Wagner, and Fricke work on the conductivity of aggregate
systems incorporates the conductivity of the soil particles associated with surface charges and the
multi-directional orientation of particles (Arulanandan and Yogachandran, 2000). In the
resulting equations, a microscopic approach predicts electrical dispersion characteristics of soils
containing clay minerals.
Numerous studies have evaluated the applicability of the radio-frequency dielectric
behavior and conductivity dispersion behavior of clay minerals to soil characterization.
Specifically, the studies have explained the extent to which a single set of these electrical
measurements can characterize the mineralogy, mineral-solution interface characteristics, fabric,
inter- and intracluster void ratios, and total void ratio of an intact sample for the purpose of
predicting engineering properties and explaining soil behavior (Arulanandan and Mitra, 1970;
Arulanandan and Smith, 1973; Smith and Arulanandan, 1981; Arulanandan et al., 1973; Basu
and Arulanandan, 1973; Alizadeh, 1975; Arulanandan, 1987; Arulanandan, K. and Arulanandan,
S., 1985; Arulanandan, 1991; Arulanandan and Yogachandran, 2000; and Arulanandan et al.,
1994). These studies showed that the structural parameters that control soil behavior also control
electrical dispersion.
A macroscopic approach will also be presented. This approach utilizes an electrical soil
model in which circuits of resistors and capacitors represent the different possible current paths
through a saturated soil-water-electrolyte system. This model is known as the Three-Element
28
Electrical Model. This chapter shows how a three-element electrical model can be used to
quantify soil structure.
3.2 ELECTRICAL RESPONSE CHARACTERISTICS OF CLAY MINERALS
Applying an electrical field to a material produces a response. This response can be
evaluated quantitatively in terms of resistance, R, and capacitance, C, irrespective of whether the
system represents a series or parallel combination of resistance and capacitance. The choice of
circuitry representation is arbitrary and not indicative of any mechanism. The material can be
solid, liquid, or a solid-liquid mixture (soils).
The values of capacitance and resistance can be converted into dielectric constant, ',
and conductivity, . The dielectric constant is defined as C/Co where Co is the capacitance of a
unit capacitor with a vacuum between the plates. The dielectric constant and conductivity can be
obtained by employing the following equations for a cylindrical specimen with two electrodes
placed on the ends, as shown in Figure 3.1.
Figure 3.1
Parallel Plate Electrodes on Opposite Ends of a Soil Sample
' = Cd/A a
= d/RA
(1a)
(1b)
where,
d = length of the specimen (cm)
A = cross sectional area of electrodes (cm2)
a = dielectric constant of vacuum (= 8.85 x 10 -14 farad/cm)
29
30
Figure 3.2
Decay of Polarization Voltage
The sudden removal of an electric field in equilibrium with a dielectric material produces
dielectric relaxation, or the exponential decay, with time, of the magnitude of induced
polarization. The relaxation time is defined as the time in which the polarization reduces to 1/e
(about 0.37) times its original value, where e is the natural logarithmic base. The relaxation
mechanism depends on the process causing polarization. Different relaxation mechanisms
display different relaxation times.
When measuring over a range of frequencies, the dielectric constant, ', can
vary, as shown in Figure 3.3. The fall of dielectric constant with increasing frequency is called
anomalous dispersion. The dielectric constant falls off with rising frequency because the
polarization can no longer change fast enough to reach equilibrium with the electric field (Hill,
1969). This lag in attaining equilibrium is again referred to as relaxation. For a particular
dielectric material, several regions of anomalous dispersion may be observed over the frequency
range from zero to the microwave range (1011 Hz). At the lower end of the frequency spectrum,
there may be sufficient time between electric field alternations for many relaxation mechanisms
to contribute to the dielectric constant. However, as the frequency increases and the time
between alternation decreases, it may become impossible for certain relaxation mechanisms to
operate. As polarization mechanisms cease to function, the dielectric constant decreases.
As shown in Figures 3.3 and 3.4, there are three regions of electrical dispersion with
respect to frequency.
31
Figure 3.3
Dielectric Behavior of Clay-Water and Ion Exchange Resin Systems
(Arulanandan & Mitra, 1970)
Figure 3.4
Multiple Anomalous Dispersions in a Dielectric Material
These three dispersions occur in the electrical frequency range, the radio frequency range,
and the microwave range. Each dispersion is indicative of the different mechanisms involved in
the process. Electrical dispersion in the low frequency range (electrical frequency range) is due
to particle size and is a diffusion-controlled relaxation process (Schwarz et al,., 1962;
Arulanandan and Mitchell, 1968; Mitchell and Arulanandan, 1968). The electrical dispersion in
32
the microwave range is due to the Debye molecular rotation (Debye, 1929). The electrical
dispersion in the radio frequency range is due to the polarization of interfaces between mineral
particles and the solution (i.e., polarization of the double layer) (Okonski, 1960).
The Maxwell-Wagner, Maxwell-Wagner-Fricke, and extension of the Maxwell-WagnerFricke microscopic theoretical models (Arulanandan, et al., 1994) deal with this polarization of
interfaces between mineral particles and pore fluid. Measurements of electrical dispersion due to
the Maxwell-Wagner relaxation mechanism may potentially be used to gain information on the
structure of a soil without destroying the sample. For this reason, a number of studies have been
conducted on the radio frequency response characteristics of soils (Arulanandan and Mitra, 1970;
Arulanandan, et al., 1973; Arulanandan and Smith, 1973; and Arulanandan et al., 1974).
3.2.3 Mechanism of Radio Frequency Electrical Dispersion of Soils
When the conductivity and dielectric constant of a liquid such as water or of an
electrolyte solution are measured as a function of frequency in the radio frequency range, it is
found that 'and do not vary (see Figure 3.5).
Figure 3.5
Variation of Dielectric Constant and Conductivity with Change in Frequency
For 0.01 N NaCl Solution
The electrical properties do not change with frequency because substances such as water
and electrolyte solutions are considered homogeneous systems. In a homogeneous system the
current density, which is proportional to the ratio of conductivity to dielectric constant, does not
vary from point to point. However, when a heterogeneous system is considered, such as a
saturated clay-water-electrolyte system, current density varies from point to point, as the ratio of
conductivity to dielectric constant is different for each component. Such a system exhibits a
dispersion in the radio frequency range due to a Maxwell-Wagner relaxation mechanism.
Charges accumulate at the interface between the clay particle and the surrounding solution.
Because this buildup of charges takes time, as the frequency is increased there is less time for the
33
charges to accumulate at the interface. This decreases the ability of the system to store electrical
potential energy and thus decreases the dielectric constant. When the frequency reaches a certain
value, there is not enough time for any charges to accumulate at the interface. At this point, the
dielectric constant becomes independent of frequency.
3.3 MICROSCOPIC MODEL OF THE ELECTRICAL DISPERSION
CHARACTERISTICS OF SOILS
The electrical conductance of a soil particle depends on the mineralogy and the adsorbed
pore fluid. The electrical conductivity of the particle may be defined as the sum of two
conductivities. The first conductivity is due to the charged carriers in the soil particle, and the
second conductivity is due to the existence of the double layer in the interface between the clay
particle and the surrounding pore fluid (surface conductance). For dry particles, the double layer
is not present, and the conductivity of the particle is due to the charges in the particle. For
saturated systems, the double layer is formed, and the particle conductance is due to the double
layer and the charges on the particle surface. Weiler and Chaussidon (1968) investigated the
surface conductivity of spherical and ellipsoid particles based on Okonskis (1960) theoretical
approach. For the ellipsoidal particle, Weiler and Chaussidon indicated that the effective
conductivity of the charged particle consists of two components, one arising from the surface
conductance, and the other from the conductivity of the ellipsoid, which depends on the axis
under consideration (Weiler and Chaussidon, 1968). In highly hydrated systems, such as
saturated clay minerals, it is reasonable to consider the ellipsoid conductivity negligible when
compared to the particles surface conductivity.
As was shown in Chapter 2, clay minerals have thin, plate-shaped particles. Oblate
spheroids with R>>1 would appropriately model these particles. Extremely oblate spheroids may
be considered as discs or plates. Weiler and Chaussidon (1968) give the surface conductance, S
(in mhos), of such an oblate spheroid (R>>1) as:
S =
a S
4
(2)
where s is the surface conductivity of the oblate spheroid in mho/cm. For a circular disc (an
extreme case of an oblate spheroid) the specific surface area, SSA, can be obtained as:
SSA=
2b2 + 2ba
b2aS
(3)
where s is the density of the particle, b is the radius of the disc, and a is the thickness of the
disc. Equation (3) can be rewritten as:
SSA =
2
1
1+
Sa
R
(4)
34
where R = b/a. Using equations (2) and (3) and eliminating a from both equations, an expression
for S is obtained as (Arulanandan and Yogachandran, 2000):
S =
1 + S
2(SSA) S
R
(5)
The surface conductance of the clay mineral can be obtained using Equation (5). Because the
conductivity due to the charges within the particle can be neglected, the conductivity of the
particle, 2 , will be approximately equal to s.
The conductivity of the particle, 2, approximately equal to S , may be determined by
fitting electrical dispersion data using the three element model (as described in Section 3.8).
Figures 3.6, 3.7, and 3.8 show this fitting procedure for different montmorillonite/sand mixtures.
Once 2 is determined, S may be calculated by using Equation 5. Table 3.1 shows values of S
calculated for the montmorillonite/sand mixtures. These values of s agree with values of
surface conductance obtained by other researchers (Cremers, et al., 1966; Weiler and
Chaussidon, 1968; Schwan, et al., 1962). For example, Weiler and Chaussidon (1968) calculated
values of
s on the order of 10-9 mho, which agree with the values given in Table 3.1.
Dielectric and Conductivity Dispersion Curve
200
0.005
dielectric constant
180
dielectric constant
160
0.0045
conductivity
0.004
140
120
0.0035
100
0.003
80
0.0025
60
40
1
10
conductivity, mho/cm
0.002
100
freqency, MHz
Figure 3.6
Optimization and Experimental Dielectric Dispersions of a 40% Montmorillonite, 60%
Sand Mixture
35
0.0028
three element model optimization
0.0026
dielectric constant
0.0024
conductivity
0.0022
0.002
0.0018
0.0016
0.0014
conductivity, mho/cm
dielectric constant
0.0012
1
10
0.001
100
freqency, MHz
Figure 3.7
Optimization and Experimental Dielectric Dispersions of a 30%
Montmorillonite, 70% Sand Mixture
0.0028
three element model optimization
dielectric constant
conductivity
0.0026
0.0024
0.0022
0.002
0.0018
0.0016
0.0014
conductivity, mho/cm
dielectric constant
0.0012
1
10
0.001
100
freqency, MHz
Figure 3.8
Optimization and Experimental Dielectric Dispersions of a 20% Montmorillonite, 80%
Sand Mixture
36
Table 3.1
Observed and Optimized Electrical Parameters for Given Conditions of Particle Shape,
Orientation, Porosity, and Specific Surface Area Used for Calculation of Surface
Conductance
Soil Type
Conductivity
Conductivity
Axial
Specific
Surface
of Pore Fluid
of particle
Ratio
Porosity
Surface
1 (mho/cm)
2 (mho/cm)
(optimized)
(optimized)
(assumed)
(measured)
Area
2
SSA (m /g)
Conductance
s (mho)
(Calculated)
0.00050
0.00490
40
0.746
241
1.21E-09
0.00039
0.00300
30
0.709
181
9.96E-10
0.00041
0.00285
20
0.629
121
1.37E-09
37
300
0.0035
0.003
250
illite
200
kaolinite
0.0025
0.002
3 element
optimization
150
0.0015
100
0.001
50
Conductivity, mho/cm
Dielectric Constant
montmorillonite
0.0005
0
1
10
0
100
Frequency, MHz
Figure 3.9
Effect of Mineral Type on Electrical Dispersion
(Arulanandan and Mitra, 1970)
Figure 3.10
Effect of Clay Percentage on Electrical Dispersion of Illite-Grundite
(Arulanandan and Smith, 1973)
3.4.3 Water Content
Three samples of illite-grundite were made homoionic to sodium and consolidated to
water contents of 78%, 52%, and 48.6%. Figure 3.11 shows the electrical dispersion
characteristics obtained. Increasing consolidation pressure reduces the water content. Thus the
38
relative transport of electric current through the solution path becomes less. At the same time the
particles are brought closer together, thus increasing the tortuosity of the current path. The
reduction in the pore water phase (i.e., the phase with larger dielectric constant) and a change in
the tortuosity shift the electrical dispersion characteristics downward.
Figure 3.11
Dielectric and Conductivity Dispersions for Illite Consolidated to
Different Water Contents (Arulanandan and Smith, 1973)
3.4.4 Particle Orientation
Electrical response characteristics were obtained on a sample of kaolinite hydrite UF that
was prepared by consolidating from a slurry under 1 kg/cm3. Cylindrical specimens were cut
with their longitudinal axes both in the direction of consolidation and at right angles to the
direction of consolidation. The resulting electrical dispersions, shown in Figure 3.12, are
significantly different. When the current flows along the long axis of the oriented particles, i.e.,
parallel to the 1 plane, obstruction in the current path is less than with the perpendicular flow.
This suggests that dispersion characteristics will change with the direction of the current path
through the soil since compositional and geometrical parameters are known to vary in the 1 and
3 directions, it is likely that they contribute to the variation in dispersion characteristics in the
same way. Later, we will quantify these parameters by applying the Three-Element Model to the
experimental results.
3.4.5 Flocculated and Dispersed Soils
Figure 3.13 shows the dispersion curves for two illite-solution aggregates. In preparing
of the flocculated soil, the clay was initially treated with 0.1 N NaCl. This relatively high
concentration of NaCl causes flocculation of the solid particles. After consolidation to 1 kg/cm2
the sample was leached with 0.01 N NaCl solution. The second illite sample was treated with
0.01 N sodium oxalate and then consolidated at 1 kg/cm2 to produce a sample with dispersed
structure.
The electrical dispersion curves are distinctly different, with the flocculated sample
showing smaller dispersion. This suggests that less water is associated with solid in the
flocculated than in the dispersed illite. It also suggests that the particles have a higher
39
tendency toward parallel orientation in the dispersed sample, increasing in the tortuosity of the
path (parallel to the loading direction) of the electric current through the solution.
Figure 3.12
Effect of Soil Fabric (Particle Orientation) on the Electrical Dispersion of a Kaolinite
Sample as Shown by Measurement in Different Directions (Arulanandan and Smith, 1973)
Figure 3.13
Effect of Flocculated and Dispersed Structure on the Electrical Dispersion of an Illite Soil
(Arulanandan and Smith, 1973)
40
Figure 3.14
Effect of Electrolyte (Pore Fluid) Concentration on the Electrical Dispersion of an IlliteSand Mixture (Arulanandan and Smith, 1973)
Figure 3.15
Effect of Pore Fluid Cation Size on the Electrical Dispersion of an Illite-Sand Mixture
(Arulanandan and Smith, 1973)
41
k 2 k 2
2 2
a
r s + s r + 2 2 r s + r s
1 d
d (1 d )S 1 d
d
d
+ b + c
r
s
th =
k k 2 k 2k
2k
2k
a
r s + r s + 2 2 s r + r s
1 d
d(1 d)S 1 d
d
d
(6a)
+ bk + ck (6b)
r
s
42
where
2
k
k
S s + r + 2 2 s + r
1 d d
1 d d
(6c)
and in which is the capacitance of a unit capacitor in a vacuum (i.e., 8.85 x 10-14 F/cm), and
= 2 f is the angular frequency.
Figure 3.16
Model of Heterogeneous Porous Plug (after Sachs and Spiegler, 1964)
These theoretical equations can be fitted to experimental electrical dispersion data for
saturated fine-grained soils by computer optimization of the geometrical (a, b, c, d) and
compositional ( r, s, kr, ks) parameters. By systematically varying the structure-determining
factors, Arulanandan and Smith (1973) have evaluated the ability of the parameters to
characterize the composition and heterogeneity of the soil system. The c parameter was found to
measure the size and distribution (tortuosity) of the intercluster pores and the intercluster void
43
ratio. The c parameter is very sensitive to intercluster void ratio and intercluster pores and is
independent of compositional variations. Model parameter b measures the contact area between
the clusters. This parameter is always small for untreated fine-grained soils. The term r is
mainly an average measure of the type of clay mineral present in the soil and the intracluster
void ratio. The distinctive r values obtained for different wet minerals relate to each minerals
characteristic water retention. The r parameter is thus referred to as the dielectric constant of
the wet soil cluster.
We have formulated theoretical dispersion curves in terms of model parameters (i.e.,
Equations 6a, b, c). Next, a method must be found to extract the values of the model parameters
from experimental data. In other words, a combination of compositional ( r, s, kr, ks) and
geometrical (a, b, c, d) parameter values must be obtained for optimal fit to experimental
dispersion curves. If dielectric constant and conductivity are measured at n frequencies, then 2n
equations must be solved to get a best-fitting combination of the unknowns. A digital computer
optimization program has been developed to solve such a system of equations (Arulanandan and
Mitra, 1970; Muat, 1968). The optimization program is used to determine the values of the
geometrical and compositional parameters of the model, such that the electrical dispersion curves
calculated from the theoretical equations (6) fit the empirical results within acceptable error
limits. By setting s equal to 80, the dielectric constant of water, and noting that a = 1-(b+c),
the number of unknowns in equations (6) is reduced to six.
At this point, it is reasonable to question whether choosing six parameters to fit
dispersion curves can produce physically meaningful results. It is true that six varying unknowns
can describe just about any set of curves; however, closer scrutiny reveals that only three
independent geometrical parameters are genuine unknowns. The conductivities kr and ks of the
solid and interstitial solution, respectively, and the dielectric constant of the solid particles or
clusters, r, must have values that are reasonable from the point of view of physical science. The
conductivity of the interstitial solution should be of the same order as the conductivity of the soil
pore fluid extract. The conductivity of the solid should be of the same order as the
isoconductivity value. The dielectric constant of the cluster of particles should be between 4.5
(the dielectric constant of a dry silicate material) and 80 (the dielectric constant of pure water),
depending on the water content. Although the latter limitations were not written into the
computer program, the model results are consistent with these requirements.
Example of the Use of the Three-Element Model for Quantifying Clay Mineral Structures
The electrical dispersion data for illite soil was obtained using a Boonton Rx meter as
described in Chapter 5. Figure 3.17 shows the dispersion data. A simplex optimization program
was used to obtain the geometrical and compositional data as shown in Table 3.2.
44
80
0.0028
75
0.0026
70
65
optimized results
0.0025
Dielectric Constant
0.0024
Conductivity
0.0023
60
0.0022
conductivity, mho/cm
dielectric constant
0.0027
0.0021
55
0.002
50
1
10
0.0019
1000
100
freqency, MHz
Figure 3.17
Dielectric and Conductivity Dispersion Characteristics of Saturated Illite-Grundite
Table 3.2
Optimized Three-Element Model Parameters of Illite-Grundite, Figure 3.10
Geometrical parameter
Geometrical parameter
Geometrical parameter
Geometrical parameter
Dielectric constant of the cluster
Conductivity of the cluster (mhos/cm)
Conductivity of the pore fluid (mhos/cm)
Dielectric constant of the pore fluid
Water content of the sample
a
b
c
d
er
kr
ks
es
78.00%
0.59
0.02
0.39
0.91
31
0.0036
0.00106
78
The compositional parameter, r, defining the dielectric constant of the cluster is used to
evaluate inter- and intracluster void ratios of the soil as described below.
3.6 INTERCLUSTER VOID RATIO AS A FUNCTION OF THREE-ELEMENT MODEL
PARAMETERS
(7)
45
where nc is the intracluster porosity, defined as the ratio of the intracluster void to the volume of
the cluster. Assuming s = 80, p = particle 4.5 (dielectric constant of dry silicate mineral),
equation (7) becomes
r = 74.5n c + 4.5
(8)
nc
1 nc
(9)
can be calculated. The total void ratio of the soil, e, can be used to estimate the intercluster void
ratio, eP, because the total void ratio is the sum of the inter- and intracluster void ratios as
follows:
e = e P + eC
(10)
Thus, the three-element electrical model can be used to quantify the inter- and intracluster
void ratios. These ratios are necessary to evaluate hydraulic conductivity using the KozenyCarman equation and the swell index of clays due to unloading (as explained Section 3.10).
The inter- and intracluster void ratios for the illite soil sample shown in Figure 3.10 are as
follows:
Intercluster void ratio, e p = 1.74
Intracluster void ratio, ec = 0.41
Total void ratio, e = 2.15
3.7 THREE-ELEMENT MODEL OPTIMIZATION
46
a = 1 b c
The b Parameter
Unless soils are cemented, the b parameter is almost always approximately zero. This is
because current does not generally move all the way through a sample without moving through
intercluster pore fluid. Thus, under most conditions, the a parameter is very generally
approximated by:
a = 1 c
The S Parameter
S is the dielectric constant of the pore fluid. In all natural cases without contamination,
the pore fluid will be water and S will be approximately 80, the dielectric constant of water.
When the pore fluid is contaminated, it is necessary to adjust S by calculating or measuring the
dielectric constant of the pore fluid solution or mixture.
The r Parameter
r is the dielectric constant of the soil clusters or, more accurately, the average cluster
dielectric constant. As shown in Olsens cluster model (1962), the clusters contain pore fluid
(the intracluster porosity) and soil particles. Therefore, r is usually somewhere between the
dielectric constant of the soil particles, approximated by 4.5, and the dielectric constant of water,
80. r may be approximated using the intracluster porosity, nc and a simple mixing rule proposed
by Arulanandan (1980):
r = n c 80 + (1 n c ) 4.5
The obvious question arises, how does one obtain nc? Refer to the relationship between and
0 shown in next Chapter (Figure 4.7). Given the electrical dispersion experimental data,
0 may be approximated, and thus may be determined. Typically the slope of the rebound
line is 1/10 to 1/5 . A decent first approximation of for starting an optimization is
therefore = 1/8 . Also refer to the relationship between and the intracluster void ratio
shown in Chapter 4 (Figure 4.14). Once is estimated, using its relationship with ec/eT (the
intracluster void ratio divided by the total void ratio), the ec/eT ratio may be approximated. The
total void ratio may be determined by water content, w, and specific gravity of the soil, Gs
( 2.7 for non-organic clays):
eT = wGs
or by using the vs. porosity, n, relationship shown in next chapter (Figure 4.7). Knowing the
total void ratio eT, the porosity of the sample may be calculated:
e
n= T
1 + eT
47
Given eC/eT and eT, eC is easily calculated. Finally, the intracluster porosity, nC, may be obtained
by:
e
nC = C
1 + eC
The kS Parameter
The conductivity of the pore fluid, kS, should be roughly the same order of magnitude as
the conductivity of the pore fluid extract. However, the optimized value for kS is typically
different from that of the pore fluid extract. It is usually lower than the conductivity of the
extracted pore fluid.
The kr Parameter
The conductivity of the soil clusters, kr, may be directly measured by determining a soils
isoconductance value. This may be determined by measuring the conductivity of the saturated
sample and plotting sample conductivity vs. pore fluid conductivity, as shown in Figures 3.18
and 3.19. The isoconductance value, which approximates kr, is where sample conductivity
equals pore fluid conductivity. A Three-Element Model optimization will determine kr if it is not
known in advance.
Figure 3.18
Laboratory Determination of the Isoconductance Value
48
Figure 3.19
Determination of Isoconductance Value of an Illite Soil (Arulanandan and Mitra, 1970)
Figure 3.20 shows the direct relationship between kr and specific surface area, SSA.
Specific surface area may be estimated using 0 by the following correlation (Meegoda, 1985).
Figure 3.20
Magnitude of Dielectric Dispersion vs. Specific Surface Area
49
The d Parameter
The d parameter has a very critical influence on the electrical dispersion calculated by the
Three-Element Model. An initial guess for d is made by trial and error after c and r are first
approximated, as seen in the example problem that follows.
The c Parameter
The c parameter represents the pure-water electrical path. This is the primary pathway
responsible for the hydraulic conductivity of soils, as discussed earlier in this chapter. Smith and
Arulanandan (1981) have shown a clear relationship between the c parameter and the hydraulic
conductivity of several soils. c may be approximated initially by the following relationship
between c and eP/eT (Arulanandan, 1997).
Figure 3.21
Non-Dimensional Void Ratio, eP/eT vs. the Three-Element Model c Parameter
3.7.2 Fine Tuning Initial Guesses
Once the initial guesses for the parameters are made, it helps to plot the dielectric
constant and conductivity data vs. frequency. These are plotted over another set of curves
representing the Three-Element Model dielectric constant and conductivity curves obtained using
the initial guess parameters. Use a spreadsheet so changes made in the initial guess parameters
are reflected as they are made. Slightly change the initial guesses by trial and error to provide a
closer fit to the experimental data. Start by manipulating only the parameters kr, ks, and d. Keep
the a parameter a function of c and b, and try to keep changes to r and c to a minimum. Keep the
b parameter approximately zero for uncemented soils.
Once the parameters have been more closely fitted to the experimental data, a computer
program may be used to optimize the parameters.
50
The computer optimization program is included on the disks enclosed with this book.
The program runs in DOS mode for PCs. Keep all files under the same directory (optimize on
the disk). The computer program optimizes based on ranges specified for each Three-Element
Model parameter. The ranges are based on initial guesses for each parameter. Use a minimum of
11 frequency-dielectric constant and frequency-conductivity conductivity data points to define
the dispersion curves. If the dispersions are not smooth, it is very helpful to smooth over the
points and create new curves to enter into the program. If there are not enough points to use in
the program, interpolate to create an adequate number of points.
3.7.4 Running the Program
The optimization program works in two steps: 1) the input step, and 2) the optimization
step.
The Input Step
1) To run the input step, input under the program directory (optimize on the disk).
2) The prompt will ask for a file name. Keep the name to less than 8 digits as usual for DOS
applications. Do not type a file extension.
3) The prompt will ask for comments. Make any relevant comments to help identify the soil or
input file.
4) The prompt will ask for the S. Enter 80, which is the appropriate dielectric constant of water.
5) The prompt will ask for the number of data points. Type in the number of points to be
optimized. (This number should be at least 11.)
6) The program will begin prompting for frequencies and relevant dielectric constants
and conductivities one by one. Conductivities units are in mho/cm x 10-3. For
example, 0.0005 mho/cm is entered as 0.5.
7) The program will prompt for a number of generations. Use 500.
8) The program will prompt for a number of individuals. Use the number of data points.
9) The program will prompt for a lower limit for b, and then for an upper limit. Use low
values such as 0.0001 and 0.01 for uncemented soils.
10) The program will prompt for a lower limit for c, and then for an upper limit. Use a
range with the approximated initial guess as the median.
11) The program will prompt for a lower limit for d, and then for an upper limit. Give
51
the d parameter plenty of range for the computer program to work with. The initial
guess based on trial and error will indicate whether d is on the low (0.5) or on the
high (0.999) end.
12) The program will prompt for a lower limit for r, and then for an upper limit.
Typically it is useful to start with limits of 0.1 above and below the initial guess.
13) The program will prompt for a lower limit for kr, and then for an upper limit. The
limits should be expressed as mho/cm. kr is usually larger than ks for clay systems.
Give the optimization program a fair amount of range to work with for kr.
14) The program will prompt for a lower limit for ks, and then for an upper limit. The
limits should be expressed as mho/cm. A decent upper limit for ks is slightly above
the measured pore fluid conductivity.
The Optimization Step
1) If any of the optimized parameters are at the very edge of the initially prescribed ranges, edit
the input file to slightly change the ranges for the parameter and then reoptimize. Repeat if
necessary until the error is minimized and none of the optimized parameters occur at the ends
of the chosen ranges.
2) To change the input file, under the appropriate directory prompt (optimize) type edit
filename.in, where filename is the name of the input file. Use the curser to change the
parameters. The parameter ranges are listed from top to bottom in the following order: b, c,
d, r, kr, kS.
3) Lastly, plot the Three-Element Model optimized results over the experimental data to check
the optimization. Slightly manipulate the parameters by hand to achieve an even better fit if
needed.
52
This section describes the optimization procedure and results for the Marysville soil
electrical dispersion shown in Figure 4.3. Table 3.3 contains electrical dispersion data extracted
from Figure 4.3.
Table 3.3
Electrical Dispersion Data for Marysville Soil
(Extracted from Figure 4.3)
frequency
MHz
3
4
6
8
10
15*
20
25*
30
35*
40
76
74.5
69.6
63.6
59.5
55.2
50.9
49.4
47.9
47.1
46.4
mho/cm
0.000380
0.000410
0.000420
0.000440
0.000460
0.000495
0.000530
0.000565
0.000600
0.000625
0.000650
* interpolated values
53
90
0.0007
dielectric constant,
0.0006
70
0.00055
60
0.0005
50
0.00045
40
0.0004
30
0.00035
0.0003
10
0.00025
0
1
10
conductivity, mho/cm
0.00065
80
0.0002
1000
100
freqency, MHz
79
0.0000
0.120
0.800
42.0
kr
kS
(mho/cm) (mho/cm)
0.000580 0.000200
a
0.880
Figure 3.22
First-Guess Approximations of Three-Element Model Parameters
Therefore, the following ranges are specified for the parameters in this example.
b
c
d
r
0.00001
0.07
0.75
30
to
to
to
to
0.01
0.22
0.999
50
kr
0.0004
to
0.0007
mho/cm
kS
0.0001
to
0.0003
mho/cm
The input program is run using the data and the parameter ranges, and the data is optimized using
the opt command.
The results using iseed = 0 produce few iterations and high error (over 0.4). Therefore,
the opt command is reissued, and 100 is used for iseed. The following results are obtained:
54
b
c
d
r
0.00001
0.07
0.75
34.06
kr
0.000588
kS
error
0.000188
0.3051
This error is still high. Notice that c and d are on the borders of their parameter. On the
command line, enter edit mary.in where mary is the specified filename, and change the c and
d ranges to:
c
d
0.05
0.6
to
to
0.2
0.85
0.00001
0.05
0.6
30.41
kr
0.000553
kS
error
0.000252
0.19
Notice the error is reduced, but c and d still fall on the borders of the specified ranges, and r is
now bordering on the earlier specified minimum of 30. Change the ranges in the input file to:
c
d
r
0.04
0.5
25
to
to
to
0.19
0.8
45
Save the new input file and rerun the opt command, again using iseed = 100. The new results
are:
b
c
d
r
0.000322
0.05157
0.5961
29.08
kr
0.000588
kS
error
0.00026
0.2
55
Note that the results are now all within the specified ranges, and the error is no longer reduced by
optimization. These Three-Element Model data are now plotted against the electrical dispersion
data in Figure 3.23.
Dielectric and Conductivity Dispersion Curve
90
0.0006
70
0.00055
60
0.0005
50
0.00045
40
0.0004
30
0.00035
20
0.0003
10
0.00025
0
1
10
conductivity, mho/cm
0.00065
80
dielectric constant,
0.0007
0.0002
1000
100
freqency, MHz
79
0.0003
0.052
0.596
29.1
kr
kS
(mho/cm) (mho/cm)
0.000588 0.000260
a
0.948
Figure 3.23
Electrical Dispersion Data and Three-Element Model Optimization
of Marysville Soil
Because the optimization fits the experimental data reasonably well, the results can be accepted.
Minor hand modifications of the results are justified if necessary.
3.8 SUMMARY
We can use nondestructive technology to accurately classify clay and non-clay soils. The
composition and structure of intact soil, determined by the non-destructive radio frequency
electrical dispersion technique, provides a method to classify intact soils either as clay minerals
or non-clay minerals based on the magnitude of dielectric dispersion. The magnitude of
dielectric dispersion depends on mineralogy, with montmorillonite showing the largest
magnitude of dielectric dispersion (around 250-300), and kaolinite showing a magnitude of
dielectric dispersion of around 10-15. Sand exhibits no dielectric dispersion; i.e., zero magnitude
of dielectric dispersion. Mixtures of non-clay and clay minerals exhibit magnitudes of dielectric
dispersions between 0 and 300.
56
3.9 PROBLEMS
Alizadeh, A. (1975) Amount and Type of Clay and Pore Fluid Influences on the Critical Shear
Stress and Swelling of Cohesive Soils, Thesis submitted in partial satisfaction of the
requirements for the degree of Doctor of Philosophy in Engineering, University of California,
Davis.
Arulanandan, K. (1980). ECI 283 class notes, Department of Civil and Environmental
Engineering, University of California, Davis.
Arulanandan, K. (1987). Non-Destructive Characterization of Particulate Systems for Soil
Classification and In Situ Prediction of Soil Properties and Soil Performance. Keynote Lecture,
Proceedings of the International Conference in Geotechnical Engineering, Calgary, Canada; A.A.
Balkema, Rotterdam.
Arulanandan, K. (1991). Dielectric Method for the Prediction of Porosity of Saturated Soils,
Journal of Geotechnical Engineering, ASCE, Vol. 117, No. 2, February, pp. 319-330.
Arulanandan, K. (1997). ECI 174 class notes, Department of Civil and Environmental
Engineering, University of California, Davis.
Arulanandan, K., and Arulanandan, S. (1985). Dielectric Methods and Apparatus for In Situ
Prediction of Porosity, Specific Surface Area (i.e., Soil Type), and for Detection of Hydrocarbon,
Hazardous Waste Materials, and the Degree of Melting Ice and to Predict In Situ Stress-Strain
Behavior. Patent Serial No. 709,592. Regents of the University of California.
Arulanandan, K., Basu, R., and Scharlin, R. J. (1973). Significance of the Magnitude of
Dielectric Dispersion in Soil Technology, Highway Research Board, Highway Research
Record, No. 426, pp. 23-32.
Arulanandan, K., and Mitchell, J. K. (1968). Low Frequency Dielectric Dispersion of ClayWater-Electrolyte Systems, 4th Annual Meeting of the Clay Mineral Society, Denver,
Colorado.
57
Arulanandan, K., and Mitra, S. K. (1970). Soil Characterization by Use of Electrical Network,
Proceedings of the Fourth Asilomar Conference on Circuits and Systems, November 1970, pp.
480-485.
Arulanandan, K., and Smith, S. S. (1973). Electrical Dispersion in Relation to Soil Structure,
Journal of the Soil Mechanics and Foundations Division, ASCE, Vol. 99, No. SM12, December,
pp. 1113-1131.
Arulanandan, K., Smith, S. S., and Spiegler, K. S. (1974). Radiofrequency Properties of
Polyelectrolyte Systems, Polyelectrolytes, D. Reidel Publishing Company, Dordrecht, Holland,
pp. 301-321.
Arulanandan, K., Yogachandran, C., and Rashidi, H. (1994). Dielectric Conductivity Methods
of Soil Characterization, Geophysical Characterization of Sites, Volume Prepared by ISSMFE
Technical Committee #10 for the XIII International Conference on Soil Mechanics and
Foundation Engineering, New Delhi, India, pp. 81-90.
Arulanandan, K., and Yogachandran, C. (2000). Dielectric Method for Non-Destructive
Characterization of Soil Composition, GeoDenver 2000, ASCE Geo-Institute, ASCE Special
Publication.
Basu, R., and Arulanandan, K. (1973). A New Approach for the Identification of Swell
Potential of Soils, Proceedings of the Third International Conference on Expansive Soils, Haifa,
Israel, Vol. 1, pp. 1-11.
Bolt, G. H. (1956). Physico-Chemical Analysis of the Compressibility of Pure Clays,
Geotechnique, London, England, Vol. 6, pp. 86-93.
Cremers, A., Van Loon, J., and Laudelout, H. (1966). "Geometry Effects for Specific Electrical
Conductance in Clays and Soil." Fourteenth National Conference on Clays and Clay Minerals,
pp. 149-162.
Debye, P. (1929). Polar Molecules, New York, reprinted by Dover Publications, Inc., New
York.
Hill, N. E. (1969). Dielectric Properties and Molecule Behavior, Van Nostrand Reinhold,
London.
Lambe, T. W., and Martin, R. T. (1953-1957). Composition and Engineering Properties of
Soil, Proceedings of the Highway Research Board, I-1953, II-1954, III-1955, IV-1956, and V1957.
Lambe, T. W. (1958). The Structure of Compacted Clay, Journal of Soil Mechanics and
Foundations Division, ASCE, Vol. 84, No. SM2, Proceeding Paper 1654, May, pp. 1654-4-165434.
58
59
60
Chapter 4
Electrical Dispersion and Engineering
Properties
4.1 INTRODUCTION
The previous chapter demonstrates how the factors controlling the structure of soils
influence electrical dispersion behavior. Because the electrical dispersion and structure of soils
are influenced by the same factors, it follows that electrical dispersion can be used to quantify
soil structure. This chapter shows how the electrical dispersion method can be used to quantify
soil structure to evaluate engineering properties. Thus, the magnitude of dielectric dispersion can
be correlated with
The cation exchange capacity, CEC
Specific surface area, SSA
61
Figure 4.1
Experimental and Theoretical Dielectric Dispersions of Clay
(Montmorillonite, Illite, and Kaolinite) and Non-Clay (Silica Flour) Samples (Arulanandan
and Yogachandran, 2000)
The dielectric constant of clay minerals varies with frequency, while the dielectric
constant of non-clay minerals is independent of frequency. Thus, the magnitude of dielectric
dispersion can be used to determine whether a soil contains clay minerals.
The magnitude of dielectric dispersion, 0 , for a natural soil consisting of clay and nonclay minerals is the difference in the dielectric constants measured at about 2 MHz and 50 MHz.
These magnitudes are shown in Figure 4.2 for a hypothetical clay and in Figure 4.3 for a
Marysville soil.
As seen in Figure 4.3, the magnitude of dielectric dispersion, 0 , of the Marysville soil
is roughly 0 = 83-42 = 41. As seen in Figure 4.1 different soils may exhibit different
magnitudes of dielectric dispersion. The magnitude of dielectric dispersion depends on the
mineralogy. Montmorillonite shows the largest magnitude of dielectric dispersion, followed by
illite and kaolinite.
The magnitude of dielectric dispersion, 0 , is a parameter that can be used to generally
characterize intact soils. Because the dielectric constant of non-clay minerals is independent of
frequency, the dispersion can be used to determine whether a soil contains clay minerals. 0
can thus be used to measure the type and amount of clay minerals. Figure 4.4 illustrates the
effect of clay type and amount on the magnitude of dielectric dispersion.
62
ff
2 MHZ
50 MHz
Figure 4.2
The Magnitude of Dielectric Dispersion, 0
Figure 4.3
Electrical Dispersion and the Magnitude of Dielectric Dispersion, 0 ,
of a Marysville Soil (Arulanandan and Yogachandran, 2000)
In preparing the samples used in Figure 4.4, montmorillonite, illite and kaolinite were
mixed with different percentages of sand. Sand, by itself, demonstrates no electrical dispersion
due to lack of surface charge. The addition of sand lowers the magnitude of dielectric dispersion
of clay soils.
As described earlier, we know pore fluid concentration affects electrical dispersion
(Figure 3.14.) Figure 4.5 shows the influence of clay type and amount and pore fluid
composition on the magnitude of dielectric dispersion.
63
Figure 4.4
The Magnitude of Dielectric Dispersion vs. Clay Type and Percent.
(Alizadeh, 1975)
Figure 4.5
The Magnitude of Dielectric Dispersion vs. Clay Type, Clay Amount, and Pore Fluid
Concentration (Arulanandan, et. al., 1994)
64
Figure 4.6 shows a correlation between the total percentage of swell and the magnitude of
dielectric dispersion, 0 , measured on samples at the end of the swell test.
65
Figure 4.6
Magnitude of Dielectric Dispersion vs. Total Swell Percent for Natural and Prepared Soil
Samples (Muraleetharan and Arulanandan, 1986)
A good correlation between the percentage of swell and 0 exists for artificial and
natural soils. This relationship can be used to evaluate the swell potential of soils once the
magnitudes of dielectric dispersion of saturated samples are known.
4.4 THE MAGNITUDE OF DIELECTRIC DISPERSION, 0 , AND
COMPRESSION INDEX
It has been shown that the type and amount of clay mineral significantly influences 0 .
The values of 0 have been shown to increase in the sequence kaolinite < illite <
montmorillonite. The compression indices of these soils also increase in this sequence. As shown
in Figures 3.10, 4.4, and 4.5, both the magnitude of dielectric dispersion and the compression
index increase with an increase in the percentage of clay in sand-clay mixtures (Arulanandan, et
al.,, 1973; Alizadeh, 1975; Arulanandan and Smith, 1973). Olson and Mesri (1970) have shown
that the compression index of kaolinite decreases when the electrolyte concentration is increased
from 0.0001 N Sodium to 1.0 N Sodium. Results presented in Figures 3.14 and 4.5 (Arulanandan
and Smith, 1973) show that 0 also decreases with increasing electrolyte concentration.
Since the clay mineral type and amount and pore fluid composition influence the
compression index and the magnitude of dielectric dispersion ( 0 ), a correlation between 0
and (slope of the consolidation line in e -ln p space) is expected. Figure 4.7 shows the
relationship between 0 and . This relationship was established mainly for clay minerals.
66
Figure 4.7
Slope of the Virgin Consolidation Line, , vs. Magnitude of Dielectric Dispersion, 0
(Arulanandan, et al., 1983)
Mitchell (1960) and Olson and Mitronovas (1962) investigated the influence of particle
size on compressibility characteristics. Their results show that particle size influences the
compressibility of sand-clay mixtures. The influence of particle size on was investigated
using three soils consisting of 3.3%, 5%, and 10% montmorillonite mixed with 96.7%, 95% and
90% Monterey 10/30' sand of particle size 0.3 mm. Figure 4.7 plots the measured values of
and 0 for these soils. The relationship obtained for the montmorillonite-sand mixtures is
lower than that obtained for clay minerals, probably because of the mechanical interaction
between the larger particles. The values of increase with an increased amount of clay mineral.
This is possibly due to the reduction in mechanical interaction between particles. The values of
and 0 were also measured for silt size silica flour (particle size = 0.01 mm) mixed with
3.3% and 5% montmorillonite, respectively. Figure 4.7 shows that the measured values of and
0 for these mixtures follow the relationship established for clay minerals. Thus, the
relationship established for clay minerals is valid for mixtures of clay and non-clay minerals in
which the non-clay minerals have particle sizes less than 0.01 mm. For soils with particle sizes
greater than 0.01 mm, different relationships similar to those developed for the Monterey sand
and montmorillonite mixtures shown in Figure 4.7 must be established.
4.5 CRITICAL STATE FRICTION ANGLE
Triaxial tests were conducted on samples to determine the slope of the critical state line
in p'-q space, M. Electrical dispersion tests were conducted on the same samples. The following
results show the correlation between M and the magnitude of dielectric dispersion.
67
Slope of the , M
1.3
1.2
1.1
1
0.9
0.8
0.7
0
20
40
60
80
Figure 4.8
Slope of the Critical State Line in p'-q Space, M, vs. the Magnitude of Dielectric Dispersion
Figure 4.8 shows the relationship for clays with 0 varying between 10 and 60. To calculate
the critical state friction angle, , the following formula can be used:
6 sin
M=
(1)
3 sin
4.6 THE MAGNITUDE OF DIELECTRIC DISPERSION, 0 ,
AND CATION EXCHANGE CAPACITY
The cation exchange capacity (CEC) of soils is important for use in both agriculture and
engineering. In agriculture, CEC is important when considering saline and alkali soil
reclamation, selection of soil fertility practices, and prediction of drainage water. In engineering,
CEC is important when considering electro-osmotic dewatering efficiency and erodability. CEC
is also used in soil classification.
This section details the evaluation of soil CEC using the magnitude of dielectric
dispersion in both field and laboratory. Conventional methods for determining soil CEC are time
consuming. Furthermore, conventional analytical procedures do not necessarily reflect field
conditions: They may alter the pH and ionic strength of the pore fluid, which directly influence
the CEC.
Recalling Figure 4.4, 0 varies with both clay type and clay percent. Montmorillonite
clay minerals produce the largest magnitude of dielectric dispersion, followed by illite and then
kaolinite. As shown in Figure 3.9, the percentage of clay mineral also influences the magnitude
of dielectric dispersion, 0 .
68
The CEC of montmorillonite, illite, and kaolinite were determined to be 95, 29.9, and 7.5
meq/100g, respectively, at a pH of 7. CECs of the various sand-clay mixtures shown in Figure
4.4 are calculated based on the relative mixture percentages, assuming sand has zero CEC. This
data shows a trend relating CEC to 0 as illustrated in Figure 4.9. However, the slope of the
correlation line is different when natural soils are considered.
Figure 4.9
Magnitude of Dielectric Dispersion vs. Cation Exchange Capacity
for Natural and Artificial Soils (Fernando, et al., 1977)
The reason for this discrepancy between artificial and natural soils is potentially due to
field conditions, such as the presence of organic matter, iron oxides, carbonates, or silica, which
act as cements or relatively inelastic bridges between charged colloidal particles. These variables
do not occur in the artificial soil samples produced in the lab. Ultimately CEC may then be
obtained for field- or laboratory-prepared samples based on 0 .
4.7 AND POROSITY
Figure 4.10 depicts another important dielectric index, , the dielectric constant at which
the dielectric dispersion levels off.
69
Figure 4.10
and 0
is usually defined at high frequencies above 50 MHz. However, most soils exhibit a leveling
off of dielectric dispersion around 50 MHz. Therefore, this frequency is often used for the
determination.
The formation factor, under very high frequencies, i.e., as , reduces to the
following when measurements are made in the direction of loading (Arulanandan, 1991):
P
1 P
1 n
(FV ) = 1 +
+
( 2 1 ) A 1 + ( 2 1 ) A
n
1+
a
b
1
1
(2)
and reduces to the following when measurements are made at right angles to the direction of
loading:
1 P
1 + P
1 n
(FH ) = 1 +
+
( )
2n ( 2 1 )
Aa 1 + 2 1 Ab
1+
1
1
(3)
where:
n = porosity
1 = dielectric constant of the solution
2 = dielectric constant of the particle
P = an orientation parameter
Aa, Ab = shape factors
70
Aa + 2Ab = 1
(4)
For spherical particles, Aa = Ab = 1/3. By assuming the particles are spherical, and using the
relationship developed for the average formation factor,
F + 2FH
F= V
3
(5)
21
1
1 n
F = 1 +
+
(
(
2 1 )
2 1 )
3n
1 +
1 +
3
3
(6)
1 n 31
n 21 + 2
(7)
Arulanandan (1991) also showed that at high frequencies (such as approximately 50 MHz):
(FV ) =
1 2
( V ) 2
(8)
(FH ) =
1 2
( H ) 2
(9)
where V and H are measured dielectric constants of the soil-particle/pore-fluid mixture in the
vertical and horizontal directions, respectively. Assuming an isotropic condition, the following
equation is obtained for the average formation factor at high frequencies:
(F ) =
1 2
2
(10)
where = (V ) = ( H )
By setting this equation for (F ) equal to 1 +
1 n 31
as derived earlier, we obtain:
n 21 + 2
71
1+
1 n 31
=
n 21 + 2
1 2
2
(11)
and through further algebraic reductions we can eventually solve for porosity alone, obtaining:
n=
1
1 2 2
+ 1
+
3
3
2
1
(12)
By plotting porosity vs. , using 1 = 80 for water and 2= 4.5 for the soil particles. we obtain
the relationships shown in Figure 4.11.
Figure 4.11
Note that in Figure 4.11, the theoretical plot shows calculations using axial ratios, R, of
1.0 (spherical particles), 0.1, and 0.001. The vs. porosity relationship shown in Figure 4.11
illustrates that axial ratio plays a relatively minor role in porosity prediction using .
4.8 SPECIFIC SURFACE AREA
s =
1 + s
2(SSA ) s R
where S = the surface conductance,
(13)
72
The conductivity of the soil particle, s, can be replaced by kr, one of the Three-Element Model
parameters. As shown in Section 3.3, because the conductivity due to charges within the particle
can be neglected, the conductivity of the particle, k2, is approximately equal to s. The surface
conductance becomes equivalent to:
s =
(14)
1 + k r
2(SSA ) s R
where SSA = the specific surface area, area/mass.
The axial ratios, R, of pure montmorillonite and kaolinite are about 100 and 10,
respectively (Lambe and Whitman, 1969). Therefore the 1/R term may usually be neglected for
clay minerals. As discussed in this chapter, the surface conductance of clay minerals obtained by
many researchers is on the order of 1 x 10-9 mho (Cremers, et al., 1966; Weiler and Chaussidan,
1968; Schwan, et al., 1962; Fricke and Curtis, 1937). The specific surface area can therefore be
evaluated by rearranging the above equation, neglecting the 1/R term:
SSA =
kr
(15)
2 s s
Figure 4.12 illustrates the relationship between kr and SSA for several soils.
kr vs. Specific Surface Area
35
30% montmorillonite, 70% Snow Cal
25
20
experimental
marysville red
kr (x10 ) mho/cm
30
15
5% montmorillonite
95% snow cal
illite
ssa calculated based on
measured hydraulic
conductivity
yolo loam
10
kaolinite
5
0
0
20
40
60
80
100
120
140
160
180
Figure 4.12
Kr vs. Specific Surface Area, SSA
*calculated SSA evaluated using measured hydraulic conductivity and the modified Kozeny-Carman
equation as detailed in Section 4.10
73
Many researchers have investigated the swelling characteristics of saturated clays due to the
removal of external load. Mechanical models, such as the one used by Terzaghi (1929), have
assumed that swelling results from elastic rebound of bent particles. Physico-chemical models,
such as the one used by Bolt (1956), have assumed that osmotic repulsive forces cause swelling.
Although it was possible to explain the mechanisms controlling swelling using the above
concepts, the models were not very successful owing to the complicated structural arrangements
of particles in clays.
Olsen (1961) used the concept of clusters in fine-grained soils, discussed by Michaels and
Lin (1954), and Quirk (1959), in his study of hydraulic flow through saturated clays. Olsen
concluded that discrepancies between the measured and calculated permeabilities are mainly due
to unequal pore sizes due to grouping of clay particles in clusters. Many have observed the
existence of primary particle aggregation using electron microscopes (Quigley and Thompson,
1966). Figure 4.13 shows the variation of intra- (ec) and intercluster (eP) void ratios obtained
using the Three-Element Model, with total void ratio using electrical dispersion data for snow cal
(95%) + montmorillonite (5%). The results, corresponding to vertical and horizontal
measurements, are identical and are very similar to the ones predicted by Olsen (1961), Meegoda
(1983), and Abdullah (1983).
Figure 4.13
Variation of Intracluster (ec) and Intercluster (eP) Void Ratio with Total Void Ratio (e) for
95% Snow Cal + 5% Montmorillonite (after Meegoda, 1983)
It has been shown that the swelling of fine-grained soils is caused by swelling of clusters (Smith
and Arulanandan, 1981), and the decrease in intercluster pores during compression is irreversible
(Meegoda, 1983). If the ratio of intracluster to total void ratio is large for a given soil, the elastic
compression due to an increase in external load would be high. Consequently, swelling would
also be high when the load was removed. Assuming this mechanism of swelling, the ratio of ec/e
is correlated with , the slope of the swelling line, as shown in Figure 4.14.
74
Figure 4.14
Slope of the Swelling Line, , vs. Intracluster/Total Void Ratios, ec/e
(Arulanandan, 1987)
In order to use this relationship for , we must be able to quantify ec/e. Recalling from Equation
(7):
r = n C S + (1 n C ) P
(16)
we may obtain nC, the intracluster porosity, if r is known. The value of r is obtained through
optimizing the Three-Element Model to fit electrical dispersion data of a given soil sample. The
optimization procedure was described in Chapter 3. Recall that S is 80 for pore water, and P
is typically about 4.5 for dry soil particles. ec is obtained by using the following volumetric
relationship:
n
(17)
ec = c
1 n c
The total void ratio may be calculated using the known water content of the sample:
e = wG s
(18)
where w is the water content in decimal form and Gs is the specific gravity of the soil, typically
about 2.7. An alternative method for determining the void ratio using the electrical parameter
was detailed in Section 4.7. Knowing ec and e, one can use the relationship in Figure 4.14 to
determine the slope of the swelling line, , for a given soil.
75
The following equations describe hydraulic flow rate through liquid-saturated porous media.
These incorporate Darcys law and the Kozeny-Carman equation (Kozeny, 1927; Carman, 1956).
q=
p dh
k
dl
1
k=
k0T 2
(19)
e3 1
2
1 + e S0
(20)
where:
q = Darcy velocity of the permeant,
= viscosity,
p = unit weight of the permeant,
k0 = pore shape factor 2.5 for uniform pore sizes,
T = tortuosity 2 for sands,
S0 = specific surface area (particle surface area per volume),
e = void ratio,
dh/dl = hydraulic pressure gradient (ft/ft), and
k = permeability
The inadequacy of the above equation in evaluating the permeability, k, of clays has long been
recognized. The equation fails to predict the magnitude and the porosity dependencies of the
hydraulic flow rate. The equation does not account for the chemical composition of clays, the
chemical composition of the permeant, or the stress history of the soil (Michaels and Lin, 1954).
Olsen (1961) analyzed the possible causes for the inadequacy of the Kozeny-Carman equation to
predict the hydraulic conductivity of clays and concluded that the deviation of predictions could
only be due to unequal pore sizes. Olsen proposed the cluster concept to explain the deviation.
To evaluate the hydraulic conductivity of clays, it is therefore necessary to quantify the
inter and intracluster void ratios, the total void ratio, the specific surface area, pore shape, and
tortuosity parameters. Then, the modified Kozeny-Carman equation can be used:
kh =
ep3
k o T 2S0 2 1 + e T
(21)
where:
ep = the intercluster void ratio
eT = the total void ratio
kh = the hydraulic conductivity (velocity units)
p = the unit weight of the permeant (pore fluid)
= the viscosity of the pore fluid
ko = the pore shape factor
T = the tortuosity
S0 = the volumetric specific surface area of the soil (surface area/volume)
76
The term p/ is a constant of about 9.74 x 105 for water. Although the viscosity of
water is temperature dependent, temperature has only a minor effect. The term 1/koT2 is a
structural parameter denoting the shape and arrangement of particles. The volumetric specific
surface area, S0, may be rewritten as S0 = SSA x s , where SSA is the specific surface area in
units of area/mass and s is density of soil particles (mass/volume)
. The resulting equation becomes:
3
ep
1
1
cm
5
10 8
k h = 9.74 10
*
(22)
2
2
2
k oT 1 + eT SSA s
s
using units of m2/g for SSA, and g/cm3 for s .
The above equation is valid for clays. The original Kozeny-Carman equation presented at the
beginning of this chapter is not valid for clay minerals. The existence of unequal pore sizes
(Olsen, 1961) has been shown to be the reason for the inapplicability of the Kozeny-Carman
equation for the prediction of hydraulic conductivity of clays. Flow rate is based on the fourth
power of the radius of the pore. Pores between clusters have a much larger radius than pores in
the clusters, so more flow can travel through the intercluster pore space. Thus, we need to
quantify the intercluster void ratio in a clay to determine hydraulic conductivity. Section 3.7
showed an approximate method of quantifying the intracluster porosity based on the following
expression:
r = n c (80) + (1 n c )4.5
(23)
where
r = a Three-Element Model parameter representing the dielectric constant of the clay cluster,
nc = the cluster porosity,
80 = the dielectric constant of water, and
4.5 = the dielectric constant of soil particles.
Section 3.7 describes the Three-Element Model. Optimizing the Three-Element Model to
electrical dispersion data requires determining the dielectric and conductivity dispersion
characterization of a clay soil over the radiofrequency range, 2 50 MHz, as detailed earlier in
this chapter.
The only parameter left to be determined is 1/koT2. The c parameter in the Three-Element
Model is a function of tortuosity and porosity. It is approximately equal to k0. If c (a ThreeElement Model parameter) is approximated as 1/F, where F is the formation factor (described in
detail in Chapter 5), then k0T2 can be approximated by:
koT2 = np = cT2
(24)
where np is the intercluster porosity. The final Modified Kozeny-Carman equation then becomes:
1
k h = 9.74 10
np
5
e 3
p
1+ e
T
10 8 (cm / s )
SSA 2 G 2
s
(25)
This equation can be used to evaluate hydraulic conductivity as shown in the example problem
that follows.
77
Given the following electrical dispersion curves (dielectric constant and conductivity) for
illite (Figure 4.15) and the given optimized Three-Element Model parameters Table 4.2,
calculate the hydraulic conductivity of the soil.
75
0.0017
0.0016
70
Dielectric Constant
0.0014
0.0013
dielectric constant
0.0012
conductivity
55
0.0011
0.001
50
Conductivity, mho/cm
0.0015
65
0.0009
45
0.0008
40
1
0.0007
100
10
Frequency, MHz
Figure 4.15
Electrical Dispersion of Na+ Illite, and Optimized Three-Element Model Parameters
(After Smith, 1971)
Table 4.2
Optimized Three-Element Model Parameters
s
79
0.002
0.36
0.65
21
kr
ks
mho/cm mho/cm
1.500E-03 8.00E-04
a
0.638
78
np =
ep
1 + eT
1.3944
= 0.5215
1 + 1.674
m2
m2
0.0015(mho / cm)
= 87.27
SSA =
kr =
2 s s
g
2 1 10 9 (mho) 2.7 (g / cm 3 )
10000 cm 2
10 8 (cm / s )
SSA 2 G 2
s
1.3944 3
1
1
10 8 (cm / s )
k h = 9.74 10 5
2
2
k h = 9.74 10 5
1
np
e 3
p
1+ e
T
1.00E-05
1.00E-06
yolo loam
60% snow cal + 40% illite
Marrysville red, CA
1.00E-07
yolo loam
illite example
illite
Encapco material, Kleinfelder
1.00E-08
1.00E-08
1.00E-07
1.00E-06
1.00E-05
Figure 4.16
Calculated (Theoretical) and Measured Hydraulic Conductivity of Various Soils
79
4.11 SUMMARY
The magnitude of dielectric dispersion has been correlated with swell potential as shown
in Figure 4.6, compression index as shown in Figure 4.7, critical state friction angle as shown in
Figure 4.8, and cation exchange capacity as shown in Figure 4.9. Dielectric constant and
conductivity vary with frequency in the radio frequency range. This variation has been used to
quantify the soil structure using a Three-Element electrical network Model described by
Arulanandan and Mitra (1970), Arulanandan and Smith (1973), and Smith and Arulanandan
(1981). The parameter r, representing the dielectric constant of the soil cluster, has been used
to evaluate intercluster and intracluster porosities. The dielectric constant at about 50 MHz
relates to total porosity (Arulanandan, 1991). The Three-Element Model parameter kr,
representing the conductivity of the soil cluster, relates to the specific surface area of the cluster
as shown in Figure 4.12. The ratio of the intracluster void ratio to the total void ratio relates to
the swell index due to unloading, , as shown in Figure 4.14.
Thus, one can approach the characterization and classification of intact soils and obtain
the following properties based on electrical dispersion characteristics:
The cation exchange capacity, CEC
Specific surface area, SSA
4.12 PROBLEMS
1. a) Plot the dielectric constant and conductivity variation in the frequency using the Rx meter
results of the two soils shown in the following tables.
b) Determine o for each soil.
c) Obtain appropriate values for the geometrical parameters (a, b, c, d) and compositional
parameters (r, s, ks, kr). Use the optimization program to determine and o.
d) Estimate the porosity, specific surface area, hydraulic conductivity, compression index,
and total swell potential for both soils.
80
L1
1.382
1.382
1.382
1.382
1.382
1.382
L2
0.75
0.75
0.75
0.75
0.75
0.75
l
1.855
1.855
1.855
1.855
1.855
1.855
Cp
12.5
9.42
7.6
6.41
5.5
5.25
C p'
19.74
14.08
10.80
8.57
6.61
6.04
Rp
290
284
279
270
254
245
R p'
Cp0
164
12.6 2.35
161
25.1 2.35
157
50.3 2.35
153 100.5 2.35
141 201.1 2.35
135 251.3 2.35
C0
0.0900
0.0900
0.0900
0.0900
0.0900
0.0900
Ct
2.200
2.200
2.200
2.200
2.200
2.200
Rs
Cs
Ct
2.320
2.320
2.320
2.320
2.320
2.320
Rs
3.54E+02
3.63E+02
3.89E+02
6.40E+02
-2.58E+02
-6.43E+01
L1
1.382
1.382
1.382
1.382
1.382
1.382
L2
0.66
0.66
0.66
0.66
0.66
0.66
l
2.084
2.084
2.084
2.084
2.084
2.084
Cp
C p'
11.3 20.1
8.9 14.38
7.25 10.98
6.3 8.55
5.45
6.6
5.15 5.91
Rp
336
329
325
310
292
286
R p'
Cp0
155
12.6 2.35
153
25.1 2.35
150
50.3 2.35
144 100.5 2.35
135 201.1 2.35
129 251.3 2.35
C0
0.0900
0.0900
0.0900
0.0900
0.0900
0.0900
Cs
2.
A
2d
3. Given the electrical dispersion characteristics of a soil in Figure 4.17 below, and the optimized
parameters of a Three-Element Model used to characterize the soil, evaluate the following
properties:
a) Total porosity, intra-and intercluster void ratios
b) Soil SSA, compression index, and swell index
c) Swell potential
d) The hydraulic conductivity of the soil, given a specific gravity for the soil of 2.75
81
63.48308
63.12631
61.77649
60.83841
54.83918
48.95364
44.45255
41.27760
39.06803
37.51096
36.39006
35.56424
34.94210
34.46373
34.08906
33.79074
33.54971
33.35240
33.18898
33.05219
32.93661
32.83110
32.75351
mho/cm
0.0009084
0.0009116
0.0009237
0.0009322
0.0009861
0.0010390
0.0010794
0.0011079
0.0011278
0.0011418
0.0011519
0.0011593
0.0011646
0.0011692
0.0011725
0.0011752
0.0011774
0.0011792
0.0011806
0.0011819
0.0011829
0.0011838
0.0011845
0.0014
60
0.0012
50
0.0010
40
0.0008
30
0.0006
20
0.0004
10
0.0002
0
1
10
0.0000
100
Frequency, MHz
Figure 4.17
Optimized Parameters
78
b
c
d
0
0.197
0.843
18.21
kr
ks
1.25E-03
4.99E-04
82
Conductivity
Dielectric Constant
Frequency
MHz
1
2
4
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
SSA(m2/g)
500
160
20
1
Figure 4.18 shows the relationship between the percentage of clay minerals and the magnitude of
dielectric dispersion, 0 .
Figure 4.18
Effect of Clay Type and Amount on Magnitude of Dielectric Dispersion
Develop a relationship between the magnitude of dielectric dispersion, 0 and Specific Surface
Area, SSA. Give the results in graphical form.
5. Determine the hydraulic conductivity of the soil with the following electrical dispersion data
(Figure 4.19). What are some possible causes for discrepancies between the actual permeability
behavior of clays and that predicted by the Kozeny-Carman equation? What is the most likely
cause?
83
Figure 4.19
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Stress Strain Behavior In Situ. Dissertation presented to the University of California, Davis, in
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Davis.
Arulanandan, K. (1987). Non-Destructive Characterization of Particulate Systems for Soil
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Fernando, M. J., Burau, R. G., and Arulanandan, K. (1977). A New Approach to Determination
of Cation Exchange Capacity, Soil Science Society of America Journal, Vol. 41, No. 4, JulyAugust, pp. 818-820.
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Dielectric Dispersive Systems. Physical Review, Vol. 24, pp. 575-587.
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Soil Mechanics and Foundations Division, ASCE, Vol. 95, No. SM1, pp. 209-225.
85
Kozeny, J. (1927). Ueber Kapillare Leitung des Wassers im Boden, Wien, Akad. Wiss., Vol.
136, Part 2a, p. 271.
Lambe, T.W. and Whitman (1969). Soil Mechanics Wiley, New York.
Meegoda (1983) Prediction of In Situ Stress State using Electrical Method Thesis submitted to
the University of California, Davis, in partial fulfillment of the requirements for the degree of
Master of Science in Engineering.
Michaels, A. S. and Lin, C. S. (1954) The Permeability of Kaolinite, Industrial and
Engineering Chemistry, Vol. 46, pp. 1239-1246.
Mitchell, J.K. (1960). "The Application of Colloidal Theory to the Compressibility of Clays."
Proceedings: Seminar on Interparticle Forces in Clay-Water-Electrolyte Systems,
Commonwealth Scientific and Industrial Research Organization, pp. 292-297
Muraleetharan, K. K., and Arulanandan, K. (1986). Site Characterization in Foundation
Engineering with Reference to Compressibility and Swell, Asian Regional Symposium on
Geotechnical Problems and Practices in Foundation Engineering, Colombo, Sri Lanka, February
25-27.
Olsen, H. W. (1961). Hydraulic Flow Through Saturated Clays, Thesis presented to
Massachusetts Institute of Technology at Cambridge, Mass., in partial fulfillment of the
requirements for the degree of Doctor of Science.
Olson, R. E. and Mesri, G. (1970). Mechanisms Controlling Compressibility of Clays, Journal
of the Soil Mechanics and Foundations Division, ASCE, SM6, pp. 1863-1878.
Olson, R.E., and Mitronovas, F. (1962). "Shear Strength and Consolidation Characteristics of
Calcium and Magnesium Illite." Proceedings of the 9th National Conference on Clays and Clay
Minerals, pp. 185-209.
Quigley, R. M., and Thompson, C. D. (1966). The Fabric of Anisotropically Consolidated
Sensitive Marine Clay, Canadian Geotechnical Journal, Vol. 3, No. 2, pp. 61-73.
Schwan, H. P., Schwarz, G., Maczuk, J., and Pauly, H. (1962). On the Low Frequency
Dielectric Dispersion of Colloidal Particles in Electrolyte Solutions, Vol. 60, pp. 2626-2642.
Seed, H. B., Woodward, R. J. and Lundgren, R. (1962). Prediction of Swelling Potential for
Compacted Clays, Journal of the Soil Mechanics and Foundations Division, ASCE, Vol. 80,
No. SM3, pp. 53-87.
Smith, S. S. (1971). Soil Characterization by Radio Frequency Electrical Dispersion,
Dissertation presented to the University of California, Davis, in partial fulfillment of the
requirements for the degree of Doctor of Philosophy in Engineering.
86
87
Chapter 5
Equipment for Measuring Electrical
Dispersion of Soil
5.1 LABORATORY EQUIPMENT
5.1.1 Boonton Rx Meter
Many electrical dispersion studies of soil have been made using an Rx Meter such
as a Type 250 Boonton Rx meter (Boonton Radio Corporation, Division of HewlettPackard). This meter employs a novel cell design and method of connecting the cell to
the electrical bridge which eliminates the impedance effects in the circuit that arise at
radio frequencies (Sachs and Spiegler, 1964). This procedure eliminates the influence of
the transmission line, the electrodes themselves, and the surroundings of the cell in
general. Note that this product is no longer in production (see Figure 5.1).
Figure 5.1
Boonton RX meter
The main features of the cell and its connections are: (1) the length of the
transmission line is the same in both positions; and (2) the geometry of the line is similar
88
at two different sample heights, as shown in Figure 5.2. Measuring sample resistance and
capacitance at two different sample heights lets us essentially subtract out the
impedances of the transmission line and cell surroundings. The length of sample, for the
purpose of calculating conductivity and dielectric constant, is the length of soil removed
(or the difference in sample heights). Figures 5.2 and 5.3 show the cell and the principle
of measuring at two different electrode lengths.
Figure 5.2
Radio Bridge Transmission Line at Two Different Heights
Figure 5.3
The Radio Bridge Sample Cell
Sachs and Spiegler (1964) evaluated the measured impedances by means of the
equivalent circuits shown in Figure 5.4.
89
Figure 5.4
The Circuits Representing the Sample at Two Different Sample Heights
(a and b - longer length sample; c and d - shorter length sample)
From the circuits in Figure 5.4, we may derive the following equations for the true
resistance, R, and capacitance, C, of the sample.
R=
R p 2 Cp Ct
R 'p C'p C t
2
1 + R 2 2 C C 2
p
t
p
1 + R 'p 2 C'p C t 2
1 + R 22 C C 2 1 + R ' 22 C ' C 2 l2
p
p
t
p
t
p
)]
)]
2
2
2 2
' 2 2 '
'
R p 1 + R p C p C t R p 1 + R p C p C t (l 1)
)]
2
2 2
2
' 2 2 '
'
R p 1 + R p C p C t R p 1 + R p C p C t l
+
2
2
2 2
2
'
2 '
1 + R p C p C t 1 + R p C p C t (l 1)
)]
(1)
)]
2
2
2
1 + R p 2 2 C p C t 2 1 + R 'p 2 C'p C t (l 1)
1
C=
2 2
2
2
R2 R p 1 + R 'p 2 C 'p C t R 'p 1 + R p 2 2 C p C t 2 l R
)]
(2)
Convert the frequencies to hertz by multiplying by 106, and then calculate the angular
frequencies using = 2f :
(rad/s)
125663706
157079633
219911486
251327412
314159265
408407045
L1 and L2 are the distances between the electrodes at two different sample heights: L1 =
5.00 cm and L2 = 2.90 cm.
L1
l=
= 1.724
L2
Measure the stray capacitance, Ct , of the cell with no sample included (air only between
the electrodes).
RP (ohm) CP (picofarad)
560
15.98
490
14.09
393
11.91
358
11.13
306
9.72
240
8.4
Measure the resistance RP' and the capacitance CP' of the sample at electrode distance L2
at all the chosen frequencies. Convert CP' to farad units for subsequent calculations.
Mhz
20
25
35
40
50
65
Use Equations 1 and 2 to calculate the resistance R (ohm) and capacitance (farad) of the
sample:
91
Mhz
20
25
35
40
50
65
R (ohm)
541.7
503.0
417.4
391.1
368.7
303.6
C (picofarad)
11.46
10.59
8.44
7.70
6.25
5.49
farad
cm
Aa
= 5.5578 1014 farad
L1
The dielectric constants are calculated based on the cell constant as follows.
equation for conductivity is also shown below:
C
=
Co
=
Mhz
20
25
35
40
50
65
206.1
190.4
151.9
138.4
112.4
98.7
The
L1
RA
(mho/cm)
0.00294
0.00317
0.00382
0.00407
0.00432
0.00497
To account for fringe field effects, use a correction factor, . is calculated by placing
water in the cell at a known conductivity. Deviation of dielectric constant from 80 and
deviation of conductivity from the true conductivity is used to calibrate . Typically the
same may be used as approximate for both dielectric constant and conductivity
corrections. corrections are taken into account as follows:
corrected =
corrected =
92
0.980
0.984
0.989
1.007
1.017
1.072
dielectric constant,
0.00400
150.0
0.00300
100.0
0.00200
50.0
0.00100
0.0
conductivity,
0.00500
200.0
(mho/cm)
0.00600
250.0
0.00000
100
10
Frequency, MHz
Figure 5.5
Dielectric Constant and Conductivity Dispersion Curves
For Ion Exhange Resin Example
93
dielectric constant, e
0.006
500
0.005
400
0.004
three element model
300
0.003
200
0.002
100
0.001
0
1
conductivity, s (mho/cm)
600
0
100
10
Freqency, MHz
er
es
0.65
0.02
0.33
0.9
38
78
kr
ks
(mho/cm) (mho/cm)
0.0075 0.000001
Figure 5.6
Three-Element Model Optimization for the Ion Exhange Resin Example
5.1.3 Hewlett Packard Impedance Analyzer
The HP4191A and the subsequent, newer models of Hewlett Packard and Agilent
Technologies impedance analyzers are useful for determining dielectric constants and
conductivities of soil samples at many radio frequencies. The HP4191A has been used
for studying the electrical dispersion of soils by Anandarajah (1982), Meegoda (1983,
1985), Broughton (2001), and others.
To successfully use impedance analyzers (or other radio frequency bridges) for
measuring the dielectric constants and conductivities of soil samples, it is critical to
compensate for, or eliminate, the electrical effects of the lead lines and the soil cell. One
way to eliminate these effects is to measure resistance and capacitance using two separate
electrode distances but with a constant lead length. This method was described in the
section regarding the use of the Boonton RX meter. Under circumstances where the soil
cell design makes varying the sample height difficult, one must electrically compensate
for cell and transmission line losses. The following section demonstrates the procedures
for making transmission line and cell corrections when using an impedance analyzer for
electrical dispersion measurements (Broughton, 2001). In this example, the cell is a
self-built, non-commercial, parallel electrode device of constant lead length.
For use and calibration, the testing setup includes: 1) the Hewlett Packard
HP4191A RF Impedance Analyzer, 2) a binding post fixture 16093A with a coaxial cable
attached to the posts and a BNC connection at the free end of the cable, and 3) a parallel
94
electrode soil cell, with a BNC connection to attach to the transmission line. On the cell
end of the BNC connection, the line should be split. The inner line should attach to one
electrode, and the outer line to the other. The soil cell should have a porous stone and
drainage system at the bottom for consolidating the sample and collecting pore fluid for
conductivity measurement.
All impedance readings should be made in R-X mode. The DC bias switch on the
front of the fixture table should be turned off, and the electrical length of the fixture
should be entered as 0.34 cm for the 16093A test fixture.
5.1.4 Autocalibration of the HP4191A RF Impedance Analyzer
Calibration of the soil cell entails measuring the open electrodes, the shorted
electrodes, and various water samples with different conductivities. An example
calibration follows this discussion to demonstrate the procedure. The R, X mode of
95
the impedance analyzer is used when taking all measurements. This mode outputs real
and imaginary resistances (impedance). Checks should be made after the calibration
using samples with known conductivities and dielectrics other than water. To short the
electrodes, use the outer shielding mesh of a coaxial cable to keep resistance to a
minimum.
An equivalent circuit for the test fixture, transmission line (coaxial cable), soil
cell, and soil sample is shown in Figure 5.7.
Figure 5.7
Equivalent Circuit for Test Fixture, Transmission Line (Coaxial Cable), Soil Cell,
and Soil Sample
Figure 5.8
Equivalent Circuit for Calibration and Measurement Calculations
5.1.6 Choosing the Calibrating Frequencies
The first step is to choose the frequencies. An input matrix mhz contains the
chosen frequencies in MHz. These frequencies are not truly variables once the calibration
is finished, since only these frequencies may be used in subsequent measurements. The
chosen frequencies must be within the frequency limits set during autocalibration of the
HP4191A. All calibration variables are 1-dimensional arrays with as many entries as
96
chosen frequencies, thus, if there are 12 chosen frequencies in the mhz matrix, the Z
matrix shown in Figure 5.8 will also have 12 entries, one for each frequency.
5.1.7 Calibrating the Test Fixture
Z1 and Z2 are the impedances of the fixture as seen in Figure 5.8. These
impedances are calculated as described for the test fixture in the HP4191A Operations
and Service Manual. Using the 10693A binding post text fixture, we obtain the following
equations for Z1 and Z2.
Z 1 = R + (2 (mhz )10 6 x1.8 x10 9 )i
1
Z2 =
(2 (mhz )10 6 x1.8 x10 12 )i
(3)
(4)
The resistance value R in Z1 varies with frequency and must be accounted for as
the R matrix. R values of the test fixture are given for different frequencies in the
Operations and Service Manual.
5.1.8 Calibration of the Transmission Line
All readings should be corrected for the impedances of the transmission line. The
next step is to calculate the transmission line impedances. The transmission line may be
calibrated by obtaining impedance readings when the transmission line is open and closed
(shorted) at the BNC connector end. The matrices transo and transs are the
impedance analyzer readings for the open and closed transmission line for the
corresponding calibration frequencies.
The transmission line measurements transo and transs must be corrected for the
text fixture impedances, given Z1 and Z2. The quantities transoa and transsa are the test
fixture-adjusted values of transo and transs given by the following equations.
transo.Z 2 Z 1 .Z 2
Z 2 + Z 1 transo
transs.Z 2 Z 1 .Z 2
transsa =
Z 2 + Z 1 transs
transoa =
(5)
(6)
97
ccc = x +
y ( z + wire )
y + z + wire
(7)
The cell should be shorted with a short length of coaxial cable shielding across the
electrodes. The quantity wire is the impedance of the cable and should be measured
directly across the fixture at the binding posts. The wire impedances are measured
directly at all the desired frequencies and entered as the variable wire. The ccc reading
impedances should be measured for all frequencies. ccc will be corrected for fixture and
transmission line effects later. wire will be corrected for fixture effects only.
Figure 5.9
Equivalent Circuit for Closed Cell Reading
Assuming an open circuit across the electrodes of the cell (Figure 5.10), we obtain the
following equation for cco (open cell reading). cco should be measured for all
frequencies.
cco = x + y
(8)
Figure 5.10
Equivalent Circuit for Open Cell Reading
There are now two equations involving the three unknowns x, y, and z. A third equation
is needed to solve the system of equations. Using a substance of known impedance in the
sample cell can solve this problem. We therefore use water of known conductivity in the
cell. The impedance analyzer registered impedance for the desired frequencies are
entered as the read matrix. Later, the read matrix will be used for the soil samples.
When using water, we obtain the circuit shown in Figure 5.11. The quantity s given in the
following equation is the true impedance of the water.
z( y + s )
(9)
read = x +
y+z+s
98
Figure 5.11
Equivalent Circuit for Sample Cell Reading
Equations (7), (8), and (9) may be manipulated to solve for x, y and z; however, this
system is difficult to solve because the variables are complex numbers. Subtracting x
from both sides of all the equations, the equations become:
y ( z + wire )
y + z + wire
cco x = y
z( y + s )
read x =
y+z+s
ccc x =
(10)
(11)
(12)
Now new variables are introduced. Variables cccx, ccox, and readx are used to represent
ccc, cco and read, each with x subtracted. Variable x will be solved by trial and error
later. In the meantime, the x matrix is initially set at all zeros for all frequencies. The
equations are then easily solved for s, y and z.
y = ccox
(cccx. y + cccx.wire) y.wire
z=
y cccx
readx.( y + z ) y.z
s=
y readx
(13)
(14)
(15)
The readings ccc, cco, and read must be adjusted for the test fixture and the transmission
line, which have been neglected briefly while explaining the previous solution for y and z.
Text fixture corrections using Z1 and Z2 are made for ccc, cco, and read. The corrected
values are ccca, ccoa, and reada. The adjustments are made in the same fashion as the
transmission line readings transs and transo are corrected to yield transsa and transoa in
Equations (5) and (6)..
wire.Z 2 Z 1 .Z 2
Z 2 + Z 1 wire
ccc.Z 2 Z 1 .Z 2
ccca =
Z 2 + Z 1 ccc
wirea =
(16)
(17)
99
cco.Z 2 Z 1 .Z 2
Z 2 + Z 1 cco
read .Z 2 Z 1 .Z 2
reada =
Z 2 + Z 1 read
ccoa =
(18)
(19)
Transmission line corrections must now be made for ccca, ccoa, and reada.
These corrections are made as directed in the impedance analyzer Operation and Service
Manual (Appendix II, Pages 3-B and 3-C). The new transmission-line-corrected values
are calculated and named cccat, ccoat, and readat and are given by the following
equations. The transmission line corrections are made using two key variables zo and
tanh gl, also given below.
zo = transoa transsa
transsa
transoa
zo. tanh gl ccca
cccat = zo.
ccca. tanh gl zo
zo. tanh gl ccoa
ccoat = zo.
ccoa. tanh gl zo
zo. tanh gl reada
readat = zo.
reada. tanh gl zo
tanh gl =
(20)
(21)
(22)
(23)
(24)
To accurately solve for y and z, use the adjusted cell impedances cccat, ccoat, and
readat should be used in place of ccc, cco, and read, respectively. Variables y and z are
then solved in terms of cccatx, ccoatx, and readatx, which are the x-subtracted values of
cccat, ccoat, and readat.
Once all circuit variables are known, we can solve for s, the impedance of the
sample. Variable s is a complex number representing a resistor and capacitor in parallel.
The equivalent circuit is then:
1 1
(25)
= + jC
s r
where r is the resistance of the sample, C is the capacitance of the sample, j = 1 , and
= 2 (mhz ) . Once r and C are known, the sample conductivity and dielectric constant
may be calculated using proper inputs, including length between electrodes and electrode
area. The conductivity and dielectric constant are calculated as follows:
L
RA
(26)
CL
A a
(27)
100
Step 1: Calibrating the Impedance Analyzer, the Test Fixture, the Transmission Line,
and the Test Cell
Use the HP4191A automatic calibration
Select desired frequency and range (mhz values).
Initially set x equal to zero for all frequencies.
Use the data for transo, transs, wire, cco, and ccc. Note the X values are imaginary
reactive terms of the impedance readings. The zero frequency readings (the first row in
each array) are placeholder remnants of the MATHCAD program from which the data
was taken, and are basically ignored.
101
mhz
R (ohm)
0
1.4
2
3
5
7
10
15
21
30
41
55
71
80
100
0
0.0005
0.001
0.002
0.003
0.004
0.005
0.007
0.008
0.012
0.013
0.015
0.017
0.018
0.02
R (ohm)
0
-150
-70
-20
-9
-3.5
-3
0
-0.1
0.2
0.25
0.3
0.35
0.36
0.4
wire
mhz
0
1.4
2
3
5
7
10
15
21
30
41
55
71
80
100
transo
R (ohm)
0
0.023
0.023
0.03
0.035
0.041
0.045
0.053
0.063
0.075
0.088
0.102
0.116
0.127
0.15
transs
X (ohm)
0
-7300
-5160
-3450
-2077
-1484
-1037
-691
-490.8
-339.9
-244
-175.79
-128.96
-110.06
-78.51
R (ohm)
0
0.063
0.075
0.095
0.123
0.147
0.175
0.216
0.261
0.319
0.387
0.4775
0.585
0.66
0.85
ccc
X (ohm)
0
0.179
0.237
0.331
0.543
0.761
1.073
1.595
2.224
3.165
4.312
5.778
7.452
8.339
10.51
R (ohm)
0
0.076
0.094
0.123
0.165
0.201
0.245
0.315
0.397
0.54
0.78
1.31
3
7
480
X (ohm)
0
0.765
1.062
1.549
2.539
3.529
5.007
7.466
10.424
14.895
20.45
27.75
36.53
41.74
54.31
cco
X (ohm)
0
1.879
2.646
3.917
6.479
9.047
12.93
19.525
27.79
41.31
60.96
95.74
170.91
267.4
-1940
R (ohm)
0
-50
0
10
5
4
3
3.2
1.35
1
0.96
0.8
0.72
0.77
0.87
X (ohm)
0
-5300
-3750
-2520
-1519
-1086
-759
-505.1
-359
-247
-175.54
-123.95
-87.95
-73.08
-47.76
Use tap water (conductivity = 0.518 mmho/cm) for initial calibration. Measure the tap
water impedance (R ohms and X ohms) for each frequency, and enter into the read
variable as shown below.
102
read
MHz
0
1.4
2
3
5
7
10
15
21
30
41
55
71
80
100
r
0
428.6
412.3
377.6
298.5
228
152.4
85.9
50.17
28
17.52
12.33
10.724
11.15
18.78
x
0
-84.1
-114.8
-156.5
-204.3
-215.4
-201.5
-161.1
-121.3
-80.3
-47.53
-17.73
11.35
28.56
83.06
Now use Equations (3) and (4) to obtain Z1 and Z2. Next make the text fixture corrections
for the measured variables transo, transs, wire, ccc, cco, and read using Equations (5),
(6), and (16)-(19). Next calculate the transmission line corrected values for ccca, ccoa,
and reada for all frequencies using Equations (20)-(24). Next calculate the x-subtracted
values for cccat, ccoat, and readat using the following equations. Note at this point,, for
x, resistive R and reactive X terms are set equal to zero for all frequencies. Also note that
s is the actual impedance of the sample in the test cell.
y (z + wirea )
y + z + wirea
ccoatx = ccoat x = y
z( y + s )
readatx = readat x =
y+z+s
cccatx = cccat x =
(28)
(29)
(30)
(31)
(32)
(33)
Knowing s, we can calculate the dielectric constants and conductivities of our water
sample at each of the measured frequencies using Equations (25)-(27). The calculated
values are given below. In these calculations a value of 9.2625 cm2 was used for the area
of the electrodes (A) as and the dielectric constant of the vacuum was set at 8.85 x 10-14
farad/cm.
103
NA
127.3
127.1
126.9
126.8
126.4
126.5
126.3
126.4
127.5
129.7
134.1
142.3
149.2
176.5
mhz
0
1.4
2
3
5
7
10
15
21
30
41
55
71
80
100
(mmho/cm)
NA
0.854
0.854
0.854
0.855
0.858
0.860
0.866
0.872
0.884
0.908
0.949
1.033
1.111
1.527
Note that the dielectric constant and conductivity, respectively, are not equal to the
expected values of 80 and 0.518 mmho/cm. We must still solve for x to complete the
calibration. Alter the real (R) and imaginary (X) terms of x until the resulting dielectric
constants and conductivities are 80 and 0.517 mmho/cm for all frequencies. This can be
done by trial and error, but after a few frequencies are completed, plotting R and X versus
frequency can aid in determining R and X values for subsequent frequencies. The
resulting x and sample readings are given below.
mhz
0
1.4
2
3
5
7
10
15
21
30
41
55
71
80
100
R (ohm)
X (ohm)
NA
-77.63
-105.80
-42.71
-2.70
16.45
13.81
14.93
13.90
7.54
3.70
1.67
0.91
0.50
1.05
NA
5479.3
3885.2
2647.5
1596.0
1143.4
793.7
525.4
374.8
260.3
193.3
149.0
123.1
114.3
106.0
water sample
(mmho/cm)
NA
NA
79.1
0.518
79.1
0.518
79.1
0.518
79.1
0.518
79.0
0.517
79.0
0.518
79.0
0.516
78.8
0.515
78.9
0.516
78.8
0.516
78.7
0.514
78.5
0.511
78.3
0.509
77.9
0.503
104
r
0
-100.981
-122.353
-64.3907
-22.8181
-5.03689
-0.04354
6.248193
11.55807
7.487272
3.936412
2.043891
1.284339
0.922129
1.954983
x
0
5427.745
3850
2623
1593
1143.592
801.9285
536.3008
384.7344
266.5719
196.8831
150.8854
124.1292
115.1041
106.3844
2.10
(mmho/cm)
r
0
-122.081
-155.378
-85.327
-40.6249
-21.4822
-14.2653
-7.56388
1.850995
0.316321
-0.40596
-0.33262
0.688203
1.143266
4.581347
x
0
5841.939
4143.508
2827.552
1715.24
1231.729
865.2386
579.9084
419.6082
292.0062
214.4
160.4149
131.2158
120.6966
109.9255
3.02
(mmho/cm)
r
0
-140.136
-166.529
-93.1435
-45.432
-26.0896
-17.9498
-11.4037
-1.96793
-4.39382
-4.07537
-2.40844
-0.21745
1.444852
6.38364
x
0
5952.003
4223.887
2883.89
1748.461
1255.615
882.4597
591.5876
429.2124
299.139
219.9355
166.1044
133.8379
122.3232
110.2987
4.07
(mmho/cm)
r
0
-149.666
-176.251
-97.4894
-49.9551
-29.534
-20.5029
-15.2276
-5.22832
-9.08661
-8.70252
-5.62203
-2.17945
-0.23126
6.344455
x
0
6061.132
4302.076
2936.177
1781.464
1279.022
898.6246
602.8984
437.509
305.2653
224.5197
169.602
136.4989
124.8382
111.1607
Using Yolo Loam soil in the sample cell, the following values for R and X are
determined:
MHz
0
1.4
2
3
5
7
10
15
21
30
41
55
71
80
100
r
0
352.4
341.5
323.2
284.9
247.9
199.8
142.8
102.25
69.23
49.72
38.12
32.95
32.27
35.96
x
0
-56.6
-72
-93.9
-124.8
-141.9
-151
-143.3
-125.2
-98.07
-71.94
-47.19
-25.24
-14.43
7.76
Using x data from the 0.518 mmho/cm conductivity (water), we obtain the following
values for the dielectric constant and conductivity of the sample over the frequency
range:
105
mhz
0
1.4
2
3
5
7
10
15
21
30
41
55
71
80
100
NA
81.9
73.6
66.3
59.0
55.5
51.8
48.3
45.0
41.8
39.2
36.8
35.0
34.2
32.5
(mmho/cm)
NA
0.638
0.645
0.655
0.672
0.686
0.709
0.744
0.785
0.845
0.909
0.980
1.050
1.083
1.126
mhz
0
1.4
2
3
5
7
10
15
21
30
41
55
71
80
100
NA
80.6
72.7
65.1
57.7
54.0
50.6
47.3
44.3
41.3
38.9
36.7
34.9
34.1
32.5
(mmho/cm)
NA
0.640
0.648
0.658
0.674
0.688
0.708
0.740
0.777
0.836
0.901
0.973
1.043
1.076
1.114
106
Using 0.638 as the chosen value of conductivity between 0.518 and 1.023 and
interpolating between the two sets of dielectric constant and conductivity data, we obtain
the final dielectric constant and conductivity values for the Yolo Loam sample. Note that
in this case, the interpolation using the two x values makes little difference in the final
values of the dielectric constant and conductivity.
90
0.0012
80
0.0011
70
0.001
60
0.0009
50
0.0008
40
0.0007
30
20
0.0006
10
0.0005
0
1
10
(mho/cm)
dielectric constant,
(mmho/cm)
NA
0.638
0.646
0.656
0.673
0.687
0.709
0.743
0.783
0.843
0.907
0.978
1.048
1.082
1.123
conductivity,
NA
81.6
73.4
66.1
58.7
55.1
51.5
48.1
44.8
41.7
39.1
36.8
35.0
34.2
32.5
mhz
0
1.4
2
3
5
7
10
15
21
30
41
55
71
80
100
0.0004
100
frequency, MHz
Figure 5.12
Final Electrical Dispersion Curves, Yolo Loam Example
.
5.1.11 Laboratory Dielectric Probe
107
Figure 5.13
Geoelectronics Laboratory Dielectric Probe
The soil cell, shown on the right side of Figure 5.13, contains two horizontally placed
electrodes. These electrodes are used to measure dielectric properties across the diameter
of the sample. The concave electrodes serve to contain the electrical field and
concentrate the field in the middle of the sample. This eliminates the sample disturbance
effect on the measurements. The laboratory dielectric probe is automatically operated,
and the dielectric constants are reported on the screen shown on the left.
5.1.12 Example Application of the Laboratory Dielectric Probe
Selected soil samples obtained in a borehole at the Rough and Ready Island site in
Stockton, California were tested at the University of California, Davis laboratory to
obtain the magnitude of dielectric dispersion, 0 . Identical samples were tested at the
Kleinfelder laboratory in Stockton, California to obtain the coefficient of permeability.
108
0
k (cm/sec) k (cm/sec)
7 59.4 0.47
60
33
27
9
34 0.56
57
36
21
3.71E-07 1.80E-07
14 57.2 0.59
69
43
26
2.93E-07 3.80E-07
22 110 0.38
77
27
50
29 50.6 0.41
52
29
23
34 87.3 0.31
61
22
39
Before 1916 it was common engineering practice to classify soils as simply clays,
silts, and sands. In 1916 Terzaghi pointed out the need for distinguishing between the
different types of clays and silts. Terzaghis idea led to the development of soil
mechanics. Mechanical methods such as the CPT are used today to characterize soils in
situ. However, since these methods do not determine the type of silt or clay present, the
resulting site characterization must revert to pre-1916 practice.
Thus, a more fundamental approach to site characterization is required. A
fundamental approach for characterizing soils requires quantifying mineralogy, mineralsolution interface characteristics, and soil fabric in situ, and relating these microstructural characteristics to macro soil properties and behavior.
5.2.3 In-Situ Dielectric Cone Probe
109
Figure 5.14
Geoelectronics Ge 400 Dielectric Cone Probe
The dielectric cone probe was used to determine the critical state friction angle of
the soils at a location on Rough and Ready Island in Stockton, California. The dielectric
cone probe measurements and the parameters derived from these measurements are
shown in Table 5.2.
110
Table 5.2
Results of Dielectric Constant Measurements Using the Geoelectronics
Dielectric Cone Probe, and Calculated Specific Surface Area, Slope of the Critical
State Line in p'-q space, M, and Critical State Friction Angle,
Stockton, California Samples
Depth
ft
6
10
12
14
16
18
22
Vr
-4.64
-4.89
-4.81
-4.89
-5.11
-5.05
-4.98
Vc
2MHz
1.6
2.12
1.45
1.83
2.83
2.76
2.29
SSA
M2/g
22
66
46.2
11
17.6
0
17.6
Vr
44
54
62
60
42
39
51
-2.94
-3.62
-2.76
-2.54
-3.42
-3.35
-2.85
M
1.17
1.03
1.11
1.19
1.17
1.21
1.11
Vc
32MHz
5.69
5.37
5.48
5.08
4.76
4.76
4.87
34
24
41
55
34
39
43
10
30
21
5
8
0
8
Deg
29
26
28
30
29
30
28
REFERENCES
111
112
Chapter 6
Formation Factor, Soil Structure,
Engineering Properties and Behavior
6.1 INTRODUCTION
The formation factor, F, is the ratio of the conductivity of the fluid that saturates a sand
aggregate to the conductivity of the mixture. The formation factor has been shown to be
dependent on a particles shape, long axis of orientation, contact orientation, void ratio,
cementation, and degree of saturation (Dafalias and Arulanandan, 1979). Thus, it is a function of
the grain (particle shape) and aggregate (porosity and fabric anisotropy) characteristics, which
together define the soil structure.
The formation factor method is an electrical method that can be used to characterize soils
and to index their structure by taking into account the porosity, anisotropy and particle shape.
The electrical measurements required for this method can be carried out in situ, thus overcoming
the difficulty of retrieving undisturbed samples. The formation factor method is especially useful
in determining liquefaction potential of granular soils because both depend on grain and
aggregate characteristics. The mechanical properties relevant to analyzing soil liquefaction have
been correlated with appropriate electrical indices, as discussed in this chapter.
This chapter demonstrates that the average formation factor, F , for a given sand
is only a function of porosity and is independent of the orientation of particles for non-cemented
soils. The average formation factor is related to porosity and to the average shape factor, f , by
the expression F = n f . This chapter will also show that F and f are independent of particle
orientation. Arulanandan and Kutter (1978) have proposed an electrical index, A (the anisotropy
index), quantifying the anisotropy of particles.
The grain and aggregate characteristics of particles and stress conditions govern the
derived properties of non-clay minerals. It has been shown that F is a unique function of
porosity. The anisotropy index, A, quantifies particle orientation, and f indicates particle shape.
Thus F and A may be used to quantify the aggregate property, which is sensitive to sample
disturbance and needs to be measured in situ. Meanwhile, grain property (shape), which is
insensitive to sampling disturbances, can be determined on disturbed samples. Empirical
correlation of these parameters ( F , A, and f ) could be extremely useful in evaluating the
performance of sites with sand deposits during earthquakes. This chapter presents laboratory
correlations between electrical parameters and the following variables: cyclic stress ratio
required to cause liquefaction as a function of number of cycles of loading, shear wave velocity,
shear modulus, compression index, hydraulic conductivity, coefficient of earth pressure at rest,
critical state friction angle, and in situ porosity.
113
(1)
k1 k 2
1 n
fV
= 1+
n
kV k2
(2)
114
FH =
k1 k 2
1 n
fH
= 1+
n
kH k2
(3)
where:
fV =
1 P
P
+
k k1
k k1
1+ 2
Aa 1+ 2
Ab
k1
k1
1 P
1 + P
1
fH =
+
k 2 k1
2 k 2 k1
Aa 1 +
A b
1 + k
k1
1
(4)
(5)
Equations (3), (4), and (5) were originally developed for dilute suspensions and were
later shown to also apply to higher volume concentrations of particles (Dafalias and
Arulanandan, 1979; Arulanandan, 1991). In the above expressions, k1 and k2 are the complex
electrical conductivities of the solution and the particle, respectively. Variables kV and kH are the
complex electrical conductivities of the composite medium in the vertical and horizontal
directions. Complex conductivity is defined as:
k = + ja
(6)
where is the conductivity, is the apparent dielectric constant, a is the dielectric constant of
air, is the angular frequency and j is equal to 1 . is related to the frequency, f, by the
expression:
= 2f
(7)
1 1 R 2
2
R
ln
Ab =
2 1 R 2 2 1 R 2 1 + 1 R 2
+ 1 for 0 R < 1
(8a)
and:
R2
Ab =
tan 1 ( R 2 1) 1 for R > 1
2 R 2 1 R 2 1
1
(8b)
and Aa = 1-2Ab, where the axial ratio, R = b/a. Some values of shape indices for spherical cases
are given: for spherical particles, R = 1 and Ab = 1/3. For laminae shaped particles, R and
115
Ab 0; for infinite cylinders, R = 0 and Ab = 1/2. The orientation factor, P , in equations (4)
and (5) represents multi-directional particle orientations and is defined as:
/2
P = p() cos 2 d
(9)
Here, the probability density function, p( ), characterizes the distribution of the orientation of
semi axis a with respect to the vertical direction for 0 2 (Dafalias and Arulanandan,
1979), such that:
/2
p()d = 1
(10)
kV = k1 + (k 2 k 1 )
(1 n)fV
n + (1 n)fV
(11a)
kH = k1 + (k 2 k 1 )
(1 n)fH
n + (1 n)fH
(11b)
Equations (11a) and (11b) are expressions for complex electrical conductivities kV and kH, in
terms of the complex conductivities of the solution, k1; the particles, k2; porosity, n; the particle
orientation, P ; and the axial ratio, R. When the complex conductivities in equation (11a) are
replaced by the conductivities and dielectric constants in equation (6), the real part of equation
(11a) yields an expression for the variation of vertical conductivity, V, as a function of 1, 1,
2, 2, P , f, R, and the porosity, n. In this expression, 1 and 2 are the solution and the
particle conductivity; 1, and 2 are the dielectric constants of the solution and the particle; and
f is the frequency. The imaginary part of equation (11a) is an expression for the vertical
dielectric constant, V, as a function of 1, 1, 2, 2, P , R, f, and n. Similarly, expressions
for the horizontal conductivity, H, and the horizontal dielectric constant, H, can be obtained
using equations (11b) and (6). The dielectric constant of the solution, 1, is approximately equal
to 80 for water. The dielectric constant of dry clay particles, 2, is about 6.5.
6.2.2 Formation and Shape Factors
The formation factor is defined as the ratio of the conductivity of the electrolyte that
saturates a particulate media to the conductivity of the electrolyte/particulate mixture. The
formation factor is thus a non-dimensional parameter. Experimental studies conducted by
Archie (1942), Arulanandan and Kutter (1978), Arulmoli (1980, 1982), Jackson (1975), and
Wyllie and Gregory (1953), showed the formation factor to depend on particle shape, long axis
116
Fv = sol
v
(12a)
(12b)
1n
f
n v
(13)
FH = 1 +
1n
fH
n
(14)
fv =
2S P (3S 1)
4S(1 S)
S + 1 + P (3S 1)
4S(1 S)
p()cos2 d
(15)
(16)
(17)
where p( ) is the probability density function that characterizes the distribution of long axes
orientation of the particles with respect to the vertical axis for 0 /2, such that:
p( ) d = 1
(18)
and is the inclination of the particles long axis with the vertical.
117
If a, b, and c represent the semiaxes of an ellipsoid, then for a prolate spheroid (a > b = c)
the factor S, which depends only on the axial ratio (R = b/a) of the particles, is given by:
R2
1 1 R2
S=
ln
+ 1 ,
2
2
2
21 R 2 1 R
1+ 1 R
0R1
(19)
R1
(20)
R2
tan 1 R 2 1 1 ,
2 1 R 2 R 2 1
Equations (13) and (14) assume no electric field interaction between particles and are
valid for very dilute suspensions. For a dense suspension, the interaction between particles can
be taken into consideration indirectly by using Bruggemans (1935) integration technique, which
yields the following equations:
Fv = n f v
FH = n fH
(21)
(22)
E i = ijJ j
(23)
where Ei is the electric field intensity in the direction i; Ji is the electric current density in the
direction j; and ij is the resistivity in the direction i due to a current density in direction j.
In matrix form, equation (23) becomes:
E1 11 12 13 J1
(24)
E 2 = 21 22 23 J2
3 31 32 33 J3
If 1, 2, and 3 represent principal directions of resistivities, the resistivity matrix becomes
a diagonal matrix. In addition, if transverse isotropy is assumed (such as with respect to a
horizontal bedding plane), the principal directions are vertical and horizontal, and the resistivity
matrix becomes:
v 0
0
ij = 0 H 0
(25)
0 0
H
Substituting the following relations in equation (25):
1
v =
v
(26)
118
1
H
and multiplying equation (25) by the conductivity of the solution, sol (a scalar), gives:
0
0
sol v
sol ij = 0
sol H
0
0
sol H
0
H =
(27)
(28)
(29)
sol ij = 0 FH 0 = Fij
0
0 FH
The first invariant of the formation factor tensor (Fij), which does not depend on the
orientation of the axes, is given by:
Fii = Fv + 2FH
(30)
Defining an average formation factor, F , as:
F
F = ii
(31)
3
it follows that F is also then independent of the orientation of the axes. Finally, from equations
(13), (14), and (31), it follows that:
1n
F =1+
(f + 2fH )
(32)
3n v
If an average shape factor, f , is defined as:
f + 2fH
f = v
(33)
3
then it follows that:
1n
F =1+
f
(34)
n
and, from equations (5), (6), and (23):
3S + 1
f =
(35)
6S(1 S)
Equation (35) shows that f is only a function of the shape of the particles. However, the
experimental results show that f is also a function of cementation (Wyllie and Gregory, 1953).
From equations (34) and (35), it is evident that f and F are independent of particle
orientations. This is an expected result, since F is shown to be an invariant of the formation
factor tensor. Extending equation (34) for dense suspensions gives:
F = n f
(36)
Hence, the average formation factor, F , is only a function of the porosity and shape of the
particles for uncemented soils.
119
Consider a Cartesian coordinate system in which x and y represent the horizontal axes
and z represents the vertical axis. Assuming transverse isotropy, with the vertical axis as the axis
of rotational symmetry, and x, y, and z as the principal directions of conductivity, Ohms law can
be written as follows:
(37)
J = H
i+
j v
k
y
z
x
where J is the electrical current density; is the electric potential; and i, j, and k represent the
unit vectors in the directions x, y, and z, respectively.
For the case of constant conductivities, continuity of charges leads to the following
expression:
2 2
2
J = 0 = H
+
+ v
(38)
x 2 2 y
z 2
When H = v, i.e., in the isotropic case, equation (38) becomes Laplaces equation.
Introducing the coordinates u = x, v = y, and w = z, where = ( H/ v)1/2, and noting that:
2
z 2
= 2
2
w 2
(39)
(40)
That is, in (u, v, w) space, the potential in the anisotropic case satisfies Laplaces equation just as
it does in the (x, y, z) space for the isotropic case. Alternatively, as approaches 1, the
anisotropic case approaches the isotropic case in the limit. Hence, is the measure of anisotropy
for the electrical conduction through a suspended medium (Mousseau and Trump, 1967).
Arulanandan and Kutter (1978) proposed an electrical index, A, quantifying the
anisotropy of particles. It is defined in the following manner:
Fv
(41a)
A=
FH
sol
A=
sol
v
H
H
=
v
Also from equations (15), (16), (21), (22), and (41a):
or
(41b)
A=
A = n
(41c)
(41d)
120
where
(3S 1)(3P 1)
8S(1 S)
(41e)
With the introduction of key electrical indices complete, attention is now turned to predicting
values for these, as well as for related indices.
6.2.5 Predicting Formation Factors and Anisotropy Index
Using thin section studies (Mitchell, et al., 1976), Dafalias and Arulanandan (1979) have
predicted the vertical and horizontal formation factors and the anisotropy index for Monterey 0
Sand. Two pieces of information are necessary for the prediction: the shape factor, S, and the
orientation factor, p . Figure 6.1 shows typical results of these thin section studies, as well as
the predicted p values using equation (7) with known probability density p( ). The p( ) is
given in a discrete form as the percent frequency p of the long axis orientation with respect to
the vertical. This value was obtained using the histograms of Figures 6.1 and 6.2, where the sum
of p from = 0o to = 180o is equal to one.
Figure 6.1
Histograms of Particle Long Axis Orientations for Samples of Monterey 0 Sand Prepared
to 50% Relative Density by Different Methods (after Mitchell, et al., 1976)
121
Figure 6.2
Histograms of Particle Long Axis Orientations for Samples of Monterey 0 Sand Prepared
to 80% Relative Density by Different Methods (after Mitchell, et al., 1976)
Noting that cos2 = cos2( - ), equation (27) can be written in a discrete form as:
P =
= 85 O
2
(p + p ) cos
O
=5
(52)
where summation is carried out for nine 10o angular intervals from 0o to 90o, taking at the
middle of each interval, i.e. = 5o, 15o, ..... , 85o. Table 6.1 tabulates the values of
p +p from the histograms, the computed values of p from equation (32), and the average
azimuthal angles = cos 1 P .
122
Table 6.1
Tabulation of the Percent Frequency of Long Axes Orientation from Histograms of
Figures 6.1 and 6.2 and Calculation of the Orientation Factor and Average
Azimuthal Angle
Based on these thin section studies, Monterey 0 Sand particles were modeled as prolate
spheroids with R = 0.65. For R = 0.65, equation (29) yields S = 0.386. In Tables 6.2 through
6.4, the predicted vertical and horizontal formation factors, and the anisotropy index values
obtained using equations (11), (12), and (31d), respectively, are compared with the values
measured in the laboratory. For the moist tamped sample at n = 0.397, no corresponding
histogram was available, thus p was obtained by interpolating between the p at n = 0.38 and n
= 0.419. Close agreement between measured and predicted values confirms the validity of the
theoretical equations derived earlier.
123
Table 6.2
Prediction of Vertical Formation Factor Using Orientation Factor (P) Calculated from
Thin Section Studies and Comparison with Measured Values
Monterey 0
preparation
method
Dry
Pluviated
Moist tamped
Moist vibrated
Porosity
n
0.380
0.419
0.380
0.397
0.419
0.419
Orientation
factor
P
0.340
0.414
0.438
0.429
0.420
0.434
Vertical
shape
factor
fv
1.515
1.491
1.483
1.486
1.488
1.484
Vertical
formation
factor
Fv = n-fv
4.33
3.66
4.20
3.94
3.64
3.63
Vertical
formation
factor
measured
4.32
3.74
4.22
3.92
3.60
3.47
Percent
error
(%)
0.23
-2.14
-0.47
0.51
-1.11
4.60
Table 6.3
Prediction of Horizontal Formation Factor Using Orientation Factor (P) Calculated from
Thin Section Studies and Comparison with Measured Values
Monterey 0
preparation
method
Pluviated
Moist tamped
Moist vibrated
Porosity
n
0.380
0.397
0.419
Orientation
factor
P
0.340
0.429
0.434
Horizontal
shape
factor
FH
1.518
1.533
1.534
Horizontal
formation
factor
FH = n-fH
4.34
4.12
3.80
Horizontal
formation
factor
measured
4.18
3.97
3.60
Percent
error
(%)
3.83
3.78
5.56
Table 6.4
Prediction of Electrical Anisotropy Index Using Orientation Factor (P) Calculated from
Thin Section Studies and Comparison with Measured Values
Monterey 0
preparation
method
Pluviated
Moist tamped
Moist vibrated
Porosity
n
0.380
0.397
0.419
Orientation
factor
P
0.340
0.429
0.434
0.0017
0.0239
0.0252
Electrical
anisotropy
index
A = n
0.998
0.978
0.978
Electrical
anisotropy
index A
measured
1.016
0.994
0.982
Percent
error
(%)
-1.77
-1.60
-0.41
The agreement is much better for Fv than for Fh. This can be attributed to two factors.
First, the p is computed directly from the vertical, thin-section histograms. Its use to predict Fh
assumes ideal transversely isotropic symmetries that may not be satisfied. Second, the values of
Fh were measured initially in cubical samples. They were then corrected by a geometrical factor
124
This section describes the use of the formation factor, shape factor, and anisotropy index
for evaluating maximum shear modulus, slope of the virgin compression and swelling lines,
coefficient of earth pressure at rest, K0, hydraulic conductivity, porosity, critical state friction
angle, location of the critical state line, and state parameter.
6.3.1 Porosity
Section 6.2 showed porosity to be theoretically related to the average formation factor,
F . To illustrate this, horizontal and vertical formation factor measurements were made in the
laboratory on lucite balls and Monterey 0/30 sand samples prepared by three different methods.
Two 6-inch cubical cells, one with two 6-inch-square, platinum-coated, copper electrodes fixed
on two opposing vertical faces, and the other with electrodes on top and bottom faces, were used
for making horizontal and vertical electrical resistance measurements, respectively (Arulmoli, et
al., 1985). As Figures 6.3 and 6.4 show, the F vs. porosity relationships obtained for all three
methods of sample preparation were shown to be a function of porosity.
Figure 6.3
Vertical, Horizontal and Average Formation Factor versus Porosity
Relationships for Lucite Balls Prepared by Three Different Methods
125
Figure 6.4
Vertical, Horizontal and Average Formation Factor versus Porosity Relationships
for Monterey 0/30 Sand Prepared by Three Different Methods
Note that the samples were prepared in two separate cubical boxes and vibrated to different
porosities. Electrodes were placed in the horizontal direction for FV measurements in one box,
and in the vertical direction for FH measurements in the other box. As a result, the FV and FH
values plotted in Figures 6.3 and 6.4 are at different porosities. A unique relationship between
F and n was found to exist for five more uniform sands and a silty sand obtained from the
Revelstoke Dam site as shown in Figure 6.5.
Figure 6.5
Average Formation Factor versus Porosity Relationships Using Cubic Cells in the
Laboratory
126
The unique relationship between F and n can be used to evaluate the in situ porosity of
uncemented sands using an in situ method (see Figure 6.17) for measuring the formation factors.
6.3.2 In Situ Determination of Stress Ratio Required to Cause Liquefaction as a Function
of Number of Cycles of Loading and an Electrical Structure Index, A3 / F f
To correlate the cyclic stress ratio required to cause liquefaction in 10 cycles, c10 , with
an electrical parameter, laboratory electrical measurements were made on reconstituted samples
whose liquefaction characteristics have been extensively studied and reported by various
investigators. It has been observed that c10 increases with increasing F and f , and decreases
with increasing A, and further, that the combination of F , f , and A that best correlates with
stress ratio to cause liquefaction is A3 / F f . Table 6.5 summarizes the results, and Figure 6.6
shows the correlation curve between c10 and the electrical parameter, A3 / F f .
Table 6.5
Electrical Measurements and Cyclic Stress Ratios to Cause Initial Liquefaction for Sands
Tested
Sand type
Monterey 0
Method of
preparation
Dry pluviation
Wet pluviation
Moist tamping
Porosity
n
A3
0.416
0.395
0.416
0.416
3.72
3.94
3.72
3.72
0.401
0.406
0.380
0.366
0.433
0.401
3.87
3.44
3.74
3.90
3.20
3.48
A
1.029
1.026
1
F fm
0.196
0.185
0.194
0.174
0.225
0.306
0.250
0328
0.167
0.217
0.200
0.192
0.234
0.215
0.370
0.180
0.232
0.270
0.110
0.180
0.202
0.197
0.183
0.225
0.286
0.348
0.202
0.195
0.191
0.183
0.225
0.270
0.325
0.285
0.172
0.435
10
Investigator
Mulilis,
et al.
0.989
Ottawa C-109
Dry pluviation
1.01
Harder Jr.
Finn, et al.
1.01
Sierra
Diamond
Lawson's
Landing site
Moist tamping
Reid Bedford
site
Moist tamping
Wet pluviation
0.383
0.375
0.463
3.71
3.80
3.33
0.429
0.419
0.412
0.424
3.62
3.74
3.82
3.52
0.404
3.74
0.982
1.032
0.985
Arulmoli
Arulmoli
Townsend,
et al.
127
Figure 6.6
Laboratory Correlation Between Cyclic Stress Ratio Required to Cause Initial
Liquefaction in 10 Cycles and Electrical Parameter, A 3 / (F f )
Similar correlations have been established for the cyclic stress ratios that cause
liquefaction in 5, 10, 15, 30 and 50 cycles (Arulmoli, 1982). These are shown in Figure 6.7.
Figure 6.7
Laboratory Correlations Between Cyclic Stress Ratio to Cause Initial Liquefaction
and Electrical Parameter, A3 / F f
128
Using these correlations, the cyclic stress ratios were plotted against the number of
cycles, N, for various values of the electrical parameter A3 /( F f ) , as shown in Figure 6.8.
Figure 6.8
Correlation Between Cyclic Stress Ratio Required to Cause Initial Liquefaction and
Number of Cycles for Different Values of Electrical Index, A3 / F f
If A3 /( F f ) can be obtained for a sand deposit, then the relationship between the cyclic
stress ratio that causes liquefaction and number of cycles can be established using the results
shown in Figure 6.8.
Figure 6.9 shows the relationship between cyclic stress ratio and number of cycles that
cause initial liquefaction for the Monterey 0 sand prepared by different methods at the same
porosity. In Figure 6.9, dc is the amplitude of deviatoric cyclic stress and '0 is the initial
effective confining pressure. Also given in Figure 6.9 are the measured electrical anisotropy
index (A) values. It shows that for the same cyclic stress ratio, samples with a higher value of A
need fewer cycles to cause initial liquefaction. This implies that, for a given number of cycles
and given cyclic stress ratio, higher anisotropy produces a larger increase in pore-water pressure.
Since the same sand with the same relative density was considered, F and f were constants for
all three cases shown in Figure 6.9. Hence, an increase in A implies an increase in A3 /( F f )
and an increase in pore water pressure.
A decrease in porosity, on the other hand, reduces the amount of settlement occurring for
a given number of cycles and hence reduces the pore-water pressure generated in a given number
of cycles. Also, a decrease in porosity increases F and hence decreases the index A3 /( F f ) .
Concerning the shape of particles, rounded particles are known to be more susceptible to
pore pressure generation due to dynamic loadings than platy ones. Also, rounded particles have
a smaller f than platy particles and hence a larger value of A3 /( F f ) . These observations
qualitatively justify correlating the parameter A3 /( F f ) to properties associated with dynamic
129
responses. The power 3 in the index shows the increased influence of anisotropy on dynamic
properties.
Figure 6.9
Cyclic Stress Ratio versus Number of Cycles to Cause Initial Liquefaction for
Monterey 0 Sand Samples Prepared by Different Methods (after Mulilis, et al., 1977);
Measured Electrical Anisotropy Index Values are after Arulanandan and Kutter (1978)
Figure 6.10
Comparison of Relationship Between Cyclic Stress Ratio to Cause Initial Liquefaction and
Number of Cycles Obtained from Conventional Cyclic Tests and that Predicted from
Electrical Measurements on Undisturbed Sand Samples from the Niigata Earthquake Area
Correlations were performed to examine the validity of the electrical method to predict,
in situ, the relationship between the cyclic stress ratio needed to cause initial liquefaction and the
number of cycles for soils. These correlations compared laboratory cyclic tests on undisturbed
samples of sand from the Niigata earthquake area with predictions using electrical measurements
on the same sample. Undisturbed samples were obtained by freezing the soil. Figure 6.10
compares the results. The close agreement between the predicted and measured values justifies
130
using this methodology to predict, in situ, the relationship between cyclic stress ratio required to
cause initial liquefaction and the number of cycles of loading.
6.3.3 Residual Friction Angle
By measuring the formation factors (vertical and horizontal) and porosity of a sand in the
laboratory, one may obtain the average shape factor.
fV =
log FV
log n
(42)
fH =
log FH
log n
(43)
f + 2f H
f = V
3
(44)
Knowing f , the following correlation provides the slope of the critical state line (M) in
q - p space (Arulanandan, et al., 1994):
Figure 6.11
Relationship Between the Average Shape Factor and the Slope of the Critical State
Line (M) in q p Space
Moreover, from:
M=
(6 sin )
(3 sin )
(45)
One may, therefore, obtain the critical state friction angle, , using Equation (45).
131
Specific surface area of sands can be obtained from grain size distribution curves as those
shown in Figure 6.12 (Arulanandan and Muraleetharan, 1988).
Figure 6.12
Particle-Size Distribution Curves for Sierra Diamond and Monterey 0/30 Sands
The specific surface area, given as surface area per unit volume of soil particles, may be
calculated as follows.
W W W1
100 Wn 1
+ ......... +
6 1 + 2
d
d
d
1
2
n
SSA =
100
(46)
where W1, W2, . . . , etc., are the percentages passing; and di is the average diameter between Wi
and Wi-1.
Once we know the porosity (obtained electrically via the formation factor method) and
the specific surface area as defined above for sands, we may use the Kozeny-Carman equation
to calculate hydraulic conductivity. By solving for hydraulic conductivity and substituting in
known electrical parameters for porosity, we obtain the following electrical index, which is
directly proportional to hydraulic conductivity:
F3 / f
1 F
1 / f
(SSA )
(47)
Figure 6.13 shows the linear relationship between hydraulic conductivity and the electrical index
given in Equation (47) (Arulanandan and Muraleetharan, 1988).
132
Figure 6.13
Correlation between Vertical Hydraulic Conductivity of Sands and Silty Sands and an
Electrical Index
6.3.5 Shear Modulus
One way of predicting maximum shear modulus, Gmax, is by measuring the in situ shear
wave velocity, VS, and using:
G max = VS 2
(47)
in which is the mass density of the deposit at the depth of measurement. Investigations have
shown that the maximum shear modulus values for sands are strongly influenced by the
confining pressure and the void ratio (Hardin and Drenevich, 1970; Seed and Idriss, 1970). Seed
and Idriss (1970) gave a relationship between shear modulus, G, in pounds per square foot and
mean effective confining pressure, ' m , in pounds per square foot, as:
G = 1000 K 2 max (' m )1 2
(49)
In the above equation, K 2max depends largely on the void ratio, the age of the deposit and
in situ stresses (Seed and Idriss, 1970). A correlation between K 2max and an electrical parameter,
F /( A f )1 / 2 , was developed using measurements made in both the laboratory and the field
(Arulanandan, et al., 1982). Field shear-wave velocities were measured using crosshole seismic
methods; the electrical measurements in the field were made using an electrical probe, which is
described below. Figure 6.14 shows the correlation.
133
Figure 6.14
Correlation between K2 max and Electrical Parameter, F /( A f )1 / 2
6.3.6 Compression Index, CC, and Swelling Index, CS
Figure 6.15 correlates the compression index, CC, of sands (i.e., non-clay minerals) and
the electrical index, Af / F , which is a polynomial of degree 2 (Harvey, 1981).
Figure 6.15
Correlation Between Compression Index and Electrical Index Af / F for Sands
(after Harvey, 1981)
134
Since the initial void ratio influences the compression index of a sand, it follows that the average
formation factor ( F ) calculated using the initial porosity should be included in the correlation.
This correlation is valid up to a vertical effective stress of 5,500 lbs/sq ft. An approximate
estimate of the swelling index (CS) may be possible by assuming CS = (1 / 4)CC .
Electrical parameters can only be used to evaluate porosity, cyclic stress ratio required to
cause liquefaction, and shear wave velocity if in situ measurement of F and A is possible. Since
f can be obtained from the F - n relationship, independent of aggregate properties and thus
sample disturbance, it can be measured from laboratory tests of disturbed samples. F and A
depend on aggregate properties and should be measured in situ. Section 6.3.8 describes an
electrical formation factor probe used for measuring electrical parameters in situ.
6.3.7 The Coefficient of Lateral Earth Pressure at Rest, K0
Anisotropic constitutive models (Anandarajah, et al., 1984; Pietruszczak and Mroz, 1983)
show that the coefficient of lateral earth pressure at rest, K0, is a function of fabric anisotropy and
fabric friction. Since clay structure is viewed using the cluster concept, it is appropriate to use the
term fabric friction. It is impossible for frictionless material to develop any fabric anisotropy.
On the other hand, if there is no fabric anisotropy, (i.e., the fabric is isotropic), any isotropic
constitutive model should show that K0 is a function of the angle of internal friction, ' , which is
a measure of fabric friction. The anisotropy index, A, is an indirect measure of fabric anisotropy.
Anandarajah, et al., 1982, and Arulanandan, et al., 1982, quantified fabric friction in terms of
electrical parameters. Since K0 is a function of fabric anisotropy and fabric friction, it is possible
to develop a correlation between K0 and electrical parameters as shown in Figure 6.16.
Figure 6.16
The Relationship Between the Coefficient of Lateral Earth Pressure at Rest and the
Electrical Index, A4 f (Meegoda and Arulanandan, 1986)
Figure 6.16 is derived for clay soils. Figure 6.16 has been used successfully for sands
when obtaining K0 for predicting earthquake simulation of liquefaction-induced deformation.
135
However, further work is needed to show the correlation between K0 and the electrical
parameters for sands.
In developing Figure 6.16, when there is no friction or anisotropy, K0 is assumed as 1,
and the lower limit of K0 for fine-grained soils is assumed as 0.38. The higher power of A in the
electrical index A4 f demonstrates the heavy dependence of fabric anisotropy on K0.
6.3.8 Critical Void Ratio versus Mean Normal Stress
Relationships between critical void ratio, eC, and effective mean normal stress, p', for
Sacramento and Nevada sands were established based on triaxial test data and the average shape
factor, f , obtained using formation factor tests. Figure 6.21 shows the interpolated eC versus p'
relationships based on f variation for Niigata and Toyoura sands (Arulanandan, 1995).
Figure 6.21
Critical Void Ratio, ec, vs, Effective Mean Normal Stress, p', for Different Average Shape
Factors, f
6.4 IN SITU FORMATION FACTOR PROBE
The electrical formation factor probe shown in Figure 6.17 can be used to make electrical
measurements of soils in situ (Arulanandan, 1977).
136
Figure 6.17
Geoelectronics Electrical Formation Factor Probe with Control Unit and Cable
The probe is capable of making measurements at any depth below the water table. The
probe consists of three main parts.
1) The Main Body
A 12- to 18-inch-long replaceable steel tube (3 inch outside diameter and 1/16 inch thick)
is screw fitted to the above. The probe tip carries the electrodes for horizontal and vertical
measurements. Figure 6.18 shows a schematic view of the electrodes.
137
Figure 6.18
Schematic Views of In Situ Formation Factor Electrodes
The probe tip also carries a porous stone on its outside, about 4 inches from the end,
which is attached to one end of a thin metal tube. The other end of this tube is connected to the
water sampler through the pump.
3) Control Unit
A microprocessor control unit for transmitting the electrical signal and receiving the
measured electrical properties is connected to the electronics in the main body through a stiff
cable.
6.4.1 Operation
The probe tip is connected to the main body, and the assembly is dropped into a
previously bored hole to the desired depth. The tip is pushed about 8 to 9 inches into the soil
below the end of the borehole so that measurements can be made in the undisturbed region of
soil. The area ratio is 8.9%, well below the minimum Hvorslev (1949) recommends to achieve
good results. The setup is operated with a 12 V DC power source. The solution is pumped from
the saturated soil into the water sampler. The microprocessor varies the bridge impedance in
steps. The horizontal, vertical, and solution resistances are obtained to an accuracy of about 1%.
These results are used together with calibration curves for the vertical and horizontal electrodes
and the water sampler, obtained from laboratory measurements. Vertical measurements are
made at an angle. By constructing a Mohrs circle of formation factors (similar to a Mohrs circle
of stresses), the true vertical formation factor is obtained. The applicability of the electrical
probe was checked in the laboratory and in the field and is reviewed below in detail.
6.4.2 Verification of the Electrical Probe Using Chamber Test
To check the validity of the electrical probe in predicting the void and stress ratios
required to cause liquefaction, controlled laboratory tests were performed on samples with and
without confining pressure (Arulmoli et al., 1985).
138
Monterey 0/30 sand was pluviated through water into a cylindrical bucket, and
formation factor measurements were made with the probe.
Figure 6.19
Verification of Formation Factor Test in Chamber under Confining Pressure
The sample was then densified by vibration, and measurements were repeated. Average
formation factor values were obtained from these measurements using the following equation:
F=
(FV + 2FH )
3
These values were compared with the F - n relationship already obtained in the
laboratory. Figure 6.20 shows the results. The probe measurements appear to be within
acceptable accuracy range for sands. While measuring with the probe, due to the electrode
configuration, most of the electric potential drop occurs in the central portion of the sample,
where the disturbance due to pushing the probe is expected to be low. This may explain why the
predictions do not show a substantial variation in porosities.
139
Figure 6.20
Comparison of Laboratory Average Formation Factor Measurements Made in Cubic Cells
with Those Made with the Formation Factor Probe in Laboratory Chamber Tests
6.5 STATE-PARAMETER-DEPENDENT SAND MODELS
6.5.1 Introduction
Attempts have been made in recent years to take into account the state dependent
response of sand. Manzari and Dafalias (1997) introduced a sand model that defines a linear
dependence of phase transformation stress ratio on (Figure 6.22), such that when = 0 , the
phase transformation stress ratio becomes identical to the critical stress ratio. The model
guarantees satisfaction of the basic premises of critical state soil mechanics, and allows modeling
of both loose and dense sand behavior with a unique set of parameters. Li (1997) investigated
the response of sand at the ultimate stress ratio. He pointed out that the dilatancy is related not
only to the stress ratio, but also to the plastic volumetric strain. To model dilative hardening
correctly, care was taken to distinguish the ultimate stress ratio from the ultimate material state
(critical state), at which the dilatancy is equal to zero. The dependence of dilatancy on density
(proposed by Li for the ultimate stress ratio), is generalized to all stress ratios by using the
technique proposed by Manzari and Dafalias (Li, et al., 1999).
The loose and dense states of sand are distinguished in reference to the critical or steady
state. In this state, the effective mean normal stress p', the deviatoric q, and the volumetric strain
v , are all constants, while the deviatoric strain q continuously develops. Been and Jefferies
(1985) introduced a parameter, , called the state parameter, which measures the difference
between the current and critical void ratios at the same confining pressure. Figure 6.22 illustrates
the definition of the state parameter. When is positive, the material is in a loose state (looser
than the critical state). When is negative, the material is in a dense state (denser than the
critical state). When the critical state is reached, = 0 . Li and Dafalias (2000) identified
140
dilatancy, d, as the key variable that uniquely relates the contractive and dilative responses to
stress and material state: d = d vp d qp , where d vp and d qp are the increments of the plastic
volumetric and deviatoric strain, respectively.
Figure 6.22
Critical State Line and State Parameter,
6.5.2 In-Situ Determination of the Critical State Line and the State Parameter
To determine the state parameter, , we need to define a critical state line in the e- p
plane. It has been shown experimentally (e.g., Verdugo and Ishihara, 1996) that a straight line in
the e- p space can approximate the critical state for sand if a wide range of pressure is
considered. To describe this line, Li (1997) adapted the following relationship, which was
originally proposed by Wang, et al. (1990) for the virgin compression line of sand:
p
e C = e c c
pa
where ec and p c are the critical void ratio and associated critical mean normal stress,
respectively. p a is a reference pressure usually set to equal the atmospheric pressure (101 kPa)
for convenience; and c , and e are dimensionless material constants. Locating the critical
state line in e-p' space is critical for determining the state parameter, . It has been shown that
we can closely approximate the critical state line in the e-p' space by considering the relationship
between the average shape factor, f , and the position of the critical state line of sands based on
laboratory triaxial test data as shown in Figure 6.21. The plot shown in Figure 6.23 defines the
slope of the critical void ratio versus c for Sacramento sand:
141
Figure 6.23
Relationship between Critical Void Ratio and Mean Normal Stress for Sacramento Sand
Figure 6.24
In-Situ Critical Void Ratio Variation with Mean Normal Pressure for Sands at the
Instrumented Site, Port Island, Kobe
Figure 6.24 shows the in situ critical void ratio variation with the mean normal pressure
for sands at an instrumented site, Port Island, Kobe, Japan (Arulanandan, 1995). To determine
142
the model parameters c , , and e one has to transfer the critical state line to a line on
p
e c plane as shown in Figure 6.22.
pa
6.6 PROBLEMS
1. Describe in detail the non-destructive electrical method to determine the in situ porosity of
saturated non-clay minerals (sand) and clay minerals.
2. a) Given the average formation factor = 3.0, average shape factor = 1.3, and anisotropic
index = 1.1 of a saturated sand layer, determine whether the sand will boil.
b) Derive any equations used in solving part (a).
3. For a dilute suspension containing non-clay minerals, show that the following equation is
true for the formation factor, F:
1 n
F = 1 +
f ,
n
where n is the porosity and f is related to the shape factor S.
(3S 1)
4. Show that for concentrated suspensions F = n-f , where f =
.
6S (1 S )
5. Describe in detail how you can independently predict the formation factor using thin section
studies by considering orientation and shape parameters.
6. Discuss using the formation factor, shape factor, and anisotropy index in non-destructively
quantifying the structure of non-clay minerals to determine in situ properties.
7. Describe briefly the mechanism causing each of the following soil behaviors: (a) Swelling;
(b) Liquefaction. Discuss how to evaluate them using non-destructive soil characteristics.
REFERENCES
Anandarajah, A., Dafalias, Y. F., and Herrmann, L. R. (1984). Bounding Surface Plasticity
Model for Anisotropic Clays, Proceedings of the 5th ASCE-EMD Conference, University of
Wyoming, Laramie.
Anandarajah, A., Arulanandan, K., Dafalias, Y. F., and Herrmann, L. R. (1982). In-Situ
Determination of Stress-Strain Relationships of Clays,
International Symposium on
Constitutive Laws for Engineering Materials: Theory and Applications, Tucson, Arizona, Jan.
10-14.
Archie, G. E. (1942). The Electric Resistivity Log as an Aid in Determining Some Reservoir
Characteristics, Transcripts of the American Institute of Mining, Metallurgical and Petroleum
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143
Arulanandan, K. (1977). Method and Apparatus for Measuring In-Situ Density and Fabric of
Soils, Patent, Regents of the University of California.
Arulanandan, K. (1980). ECI 283 class notes, Department of Civil and Environmental
Engineering, University of California, Davis.
Arulanandan, K. (1987). Non-Destructive Characterization of Particulate Systems for Soil
Classification and In Situ Prediction of Soil Properties and Soil Performance. Keynote Lecture,
Proceedings of the International Conference in Geotechnical Engineering, Calgary, Canada; A.A.
Balkema, Rotterdam.
Arulanandan, K. (1991). Dielectric Method for the Prediction of Porosity of Saturated Soils,
Journal of Geotechnical Engineering, ASCE, Vol. 117, No. 2, February, pp. 319-330.
Arulanandan, K. (1995). UC Davis Report, Lecture, Kyoto University, Japan.
Arulanandan, K. (1997). ECI 174 class notes, Department of Civil and Environmental
Engineering, University of California, Davis.
Arulanandan, K., and Yogachandran, C. (2000). Dielectric Method for Non-Destructive
Characterization of Soil Composition, GeoDenver 2000, ASCE Geo-Institute, ASCE Special
Publication No. 110.
Arulanandan, K., and Kutter, B. (1978). A Directional Structure Index Related to Sand
Liquefaction, Proceedings of the Specialty Conference on Earthquake Engineering and Soil
Dynamics, ASCE, Pasadena, California, pp. 213-230.
Arulanandan, K., and Muraleetharan, K. K. (1988). Level Ground Soil Liquefaction Analysis
using In-Situ Properties: I and II, Journal of Geotechnical Engineering, ASCE, Vol. 114, No. 7.
Arulanandan, K., Arulmoli, K., Dafalias, Y. F., and Herrmann, L. R. (1982). In Situ
Characterization of Saturated Sands and Silts for the Prediction of Dynamic Shear Modulus and
Shear Wave Velocity, Department of Civil Engineering, University of California, Davis,
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Arulanandan, K., Yogachandran, C., and Rashidi, H. (1994). Dielectric Conductivity Methods
of Soil Characterization, Geophysical Characterization of Sites, Volume Prepared by ISSMFE
Technical Committee #10 for the XIII International Conference on Soil Mechanics and
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Arulmoli, K. (1980). Sand structure characterization for in situ testing. Thesis submitted in
partial satisfaction of the requirements for the degree of Master of Science in Engineering,
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144
145
Manzari, M.T., and Dafalias, Y.F. (1997). A critical state two-surface plasticity model of
sands. Geotechnique, 47(2), 255-272.
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Oxford.
Meegoda, N. J. (1983). Prediction of In Situ Stress State Using Electrical Method, Thesis
submitted in partial satisfaction of the requirements for the degree of Master of Science in
Engineering, University of California, Davis.
Meegoda, N. J., and Arulanandan, K. (1986). Electrical Method of Predicting In Situ Stress
State of Normally Consolidated Clays, Proceedings of the In Situ 86, GT Division, ASCE,
Blacksburg, Virginia, June 23-25, pp. 794-808.
Mitchell, J. K., Chatoian, J. M., and Carpenter, G. C. (1976). The influence of fabric on the
liquefaction behavior of sand, Report, U.S. Army Corps of Engineering, Waterways Experiment
Station, Vicksburg, Mississippi.
Mousseau, R.J., and Trump, R.P. (1967). Measurement of electrical anisotropy of clay like
materials, Journal of Applied Physics, 38(11), 4375-4379.
Mulilis, J. P., et al. (1977). Effects of Sample Preparation on Sand Liquefaction, Journal of
the Geotechnical Engineering Division, ASCE, Vol. 103, No. 2, pp. 91-108.
Pietruszczak, St., and Mroz, Z. (1983) On Hardening Anisotropy of K0 Consolidated Clays,
International Journal for Numerical and Analytical Methods in Geomechanics, Vol. 7, pp. 1938.
Seed, H. B., and Idriss, I. M. (1970). Soil Moduli and Damping Factors for Dynamic Response
Analysis, Report No. EERC 70-10, University of California, Berkeley, California, December.
Verdugo, R., and Ishihara, K. (1996). The Steady State of Sandy Soils, Soils and Foundations,
Vol. 36, No. 2, pp. 81-91.
Wagner, K. W. (1914). Archives of Electrotechnology, Vol. 2, p. 371.
Wang, Z. L., Dafalias, Y. F., and Shen, C. K. (1990). Bounding Surface Hypoplasticity Model
for Sand, Journal of Engineering Mechanics, ASCE, Vol. 116, No. 5, May, pp. 983-1001.
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146
Chapter 7
Soil Behavior:
Erosion in Relation to Earth Dam Failure
and Frost Heave
7.1 EROSION
7.1.1 Introduction
One of the major concerns regarding the safety of embankment dams is the
problem of internal soil stability, especially when particles are subjected to drag forces
resulting from reservoir seepage. This problem is particularly important when transverse
cracking of the core occurs. There are various reasons why cracking occurs, such as
differential settlement or hydraulic fracture, all of which can cause serious internal
erosion resulting in catastrophic dam failure. Numerous cases of near failure and total
failure of dams, resulting from internal erosion, have been investigated and reported in
detail (Sherard, 1972a, b; Vargas and Hsu, 1970; Vaughan, 1976).
7.1.2 Classification of Impervious Core Materials with Respect to Dispersion and
Erodibility
Serious internal erosion of dams appears to have occurred with increasing
frequency during the past 40 years, based on the number of cases summarized by Ripley
(1978). These incidents have resulted in extensive studies to identify core materials that
have dispersive fines.
Investigators have used a variety of empirical tests to identify and classify soils
with respect to their dispersion characteristics. These include the crumb test (Emerson,
1954), the SCS dispersion ratio test (Decker and Dunnigan, 1976), and the pinhole test
(Sherard, et al., 1976). These three tests are used mainly to identify dispersive clays, and
even then are not suitable for all cases. Perry (1976) summarizes the reasons why these
tests are not able to identify erosion characteristics of some soils.
Figure 7.1 shows the classification chart for erosion proposed by the Bureau of
Reclamation (1962). The misuse of Figure 7.1 in deciding on the erodibility of a core
without site-specific testing could lead to problems. Plotted on this chart are the
plasticity characteristics of nondispersive core materials used in various dams
(Washington Co., Dam, Hills Creek Dam, Balderhead Dam, and Stockton Creek Dam)
that have shown piping failure through the core. Also plotted are the plasticity
characteristics of nondispersive core materials used in two dams (Cedar Springs Dam and
Yosemite Dam) that have shown stable performance with respect to internal erosion.
These results show that the classification system used is not able to predict piping
performance. The reason for this is that the system does not take into account important
147
erosion factors such as the chemistry of the soil and the composition of pore and eroding
fluid.
Figure 7.1
Soil Erodibility Based on Plasticity Chart versus Performance of Dams Constructed
of Nondispersive Cohesive Soils (PI > 6, % Clay < 12)
7.1.3 New Approach to Quantifying the Erodibility Characteristics of Soils
Any classification system used to identify the erodibility of soil should be based,
ideally, on some measure of the ease with which a soil can be eroded. The phenomenon
of surface erosion occurs when fluid flow induces strong shear stresses in the surfaces of
a cracked zone of core material, removing aggregates or flocs of particles. One of the
accepted approaches for evaluating the initiation and sustaining of particle motion or
aggregation involves calculating the shear stress caused by hydraulic flow. Any critical
shear designation should denote either: (1) a stress at which erosion begins, or (2) a stress
that would cause a particular erosion rate. Shields (1963) defined the critical shear stress,
C , as a measure of erosion resistance. Specifically, C is the value of the stress for zerosediment discharge obtained by extrapolating a graph of observed erosion rate vs. shear
stress as shown in Figure 7.2.
Values of critical shear stress have been measured directly on remolded and
undisturbed samples of soils using a rotating cylinder (Arulanandan et al., 1976b).
Figures 7.3, 7.4 and 7.5 show a photograph and schematics of a rotating cylinder
apparatus.
148
Figure 7.2
Definition of Critical Shear Stress, Rate of Change of Erosion Rate, and Rate of
Erosion
Figure 7.3
Photograph of a Rotating Cylinder Apparatus (Arulanandan and Krone, 1974)
149
Figure 7.4
Schematic of a Rotating Cylinder Apparatus and Soil Sample
(Arulanandan, Loganathan, and Krone, 1974)
Figure 7.5
Rotating Cylinder Apparatus Shear Stress Measurement
(Arulanandan et al., 1976b)
The literature reports numerous results showing the influence of clay type and
amount, pore and eroding fluid compositions, pH, temperature, and organic matter on C
(Arulanandan, et al., 1976b; Arulanandan and Heinzen, 1977; Karpoff, 1955;
Arulanandan, et al., 1973). The mechanism of soil erosion is a complex phenomenon
involving soil structure and the nature of the interaction between the pore and eroding
150
fluid at the surface. Because the critical shear stress, C , depends on these factors, it can
be used as a fundamental parameter to classify erodibility characteristics.
In cases where the rotating cylinder or flume apparatus is not available, we can
indirectly measure C from knowledge of the soil structure and the composition of the
pore and eroding fluid. A composite index that can characterize the soil type is the
magnitude of dielectric dispersion, 0 (Arulanandan and Heinzen, 1977). This index,
obtained from the measurement of electrical properties, has been used to propose a new
soil classification system as shown in Figure 7.6.
Figure 7.6
Effect of Clay Type and Amount on Magnitude of Dielectric Dispersion
(Alizadeh, 1975)
In conjunction with values of pore fluid concentration and the Sodium Adsorption
Ratio (SAR), with distilled water as the eroding fluid, 0 can be used to indirectly
measure C . This measurement is based on correlations established from extensive tests
on a wide variety of clay soils (Alizadeh, 1975; Arulanandan and Heinzen, 1977), as
shown in Figures 7.7 through 7.10.
151
Figure 7.7
Relationship between Critical Shear Stress, Sodium Adsorption Ratio, and
Dielectric Dispersion for Saturated Remolded Soil with Distilled Water as Eroding
Fluid and Soil Pore Fluid Concentration of 5 Milliequivalents/Liter
(Arulanandan and Perry, 1983)
Figure 7.8
Relationship between Critical Shear Stress, Sodium Adsorption Ratio, and
Dielectric Dispersion for Saturated Remolded Soil with Distilled Water as Eroding
Fluid and Soil Pore Fluid Concentration of 50 Milliequivalents/Liter
(Arulanandan and Perry, 1983)
152
Figure 7.9
Relationship between Critical Shear Stress, Sodium Adsorption Ratio, and
Dielectric Dispersion for Saturated Remolded Soil with Distilled Water as Eroding
Fluid and Soil Pore Fluid Concentration of 125 Milliequivalents/Liter
(Arulanandan and Perry, 1983)
Figure 7.10
Relationship between Critical Shear Stress, Sodium Adsorption Ratio, and
Dielectric Dispersion for Saturated Remolded Soil with Distilled Water as Eroding
Fluid and Soil Pore Fluid Concentration of 250 Milliequivalents/Liter
(Arulanandan and Perry, 1983)
153
Figure 7.11
Relationship between Magnitude of Dielectric Dispersion and Cation Exchange
Capacity for Artificial and Natural Soils
(Fernando et al., 1977)
We can now estimate the value of C for each dam from Figures 7.7 through
7.10, which apply to remolded saturated soil containing 40% clay. Tables 7.1 through
7.3 summarize the results.
154
Table 7.1
Properties of the Fines in Dispersive-Cohesive (PI > 6, % Clay > 12) Embankment
or Core Materials and their Erodibility Characteristics
(Arulanandan and Perry, 1983)
155
Table 7.2
Properties of the Fines in Nondispersive-Cohesive (PI > 6, % Clay > 12)
Embankment or Core Materials and their Erodibility Characteristics
(Arulanandan and Perry, 1983)
Table 7.1 shows 19 dispersive-cohesive soils from dams that all experienced
piping failure. In each case the estimated critical shear stress is 4 dynes/cm2. Table 2
shows six nondispersive-cohesive soils from both stable and unstable dams. For the four
dams that experienced piping failure, the estimated critical shear stress is 4 dynes/cm2.
156
For the two stable dams, it is 9 dynes/cm2 and 13 dynes/cm2. Table 3 shows four
noncohesive soils from both stable and unstable dams. For the three dams that
experienced piping failure, the critical shear stress is 4 dynes/cm2. For the stable dam
it is 14 dynes/cm2.
Table 7.3
Properties of the Fines in Noncohesive (PI 6, % Clay 12) Embankment or Core
Materials and their Erodibility Characteristics
(Arulanandan and Perry, 1983)
One of the main points these data demonstrate is that core materials other than
dispersive clays can show low erosion resistance similar to dispersive clays. A good
example of this is the core material from the Balderhead Dam, a glacial till that,
according to Figure 7.1, has been considered to have high erosion resistance. It actually
has low erosion resistance, as suggested by the low value of critical shear stress (4
dynes/cm2). The core materials from the Stockton Creek, Washington County, and Hills
Creek Dams would also have been expected to have high erosion resistance according to
Figure 7.1. Again the low values of C ( 4 dynes/cm2) suggest a low resistance to
erosion. In the case of the Teton, Hyttejuret, Matahina, and Mill Site Dams, the core
materials are all suspected of being highly erodible due to their low plasticity. For the
first three this is confirmed by the low critical shear stress ( 4 dynes/cm2). The high
value (14 dynes/cm2) of C for the Mill Site Dam suggests high erosion resistance.
Based on this limited data, certain categories are proposed for the classification of
core materials with respect to their erosion resistance. These categories, defined in terms
of critical shear stress, are as follows:
157
158
dollars in property damage (Independent Panel to Review Cause of Teton Dam Failure,
1976).
Figure 7.13
Results of Rotating Cylinder Test on a Teton Dam Core Sample
(Arulanandan, et al., 1976a)
159
Figure 7.14
Results of Rotating Cylinder Test on a Teton Dam Core Sample
(Arulanandan, et al., 1976a)
Subsequent analysis of the failure and core soil revealed that the core material had
a low critical shear stress. Figures 7.13 and 7.14 show the results of rotating cylinder tests
on core samples of the Teton Dam (Arulanandan, et al., 1976a). The three tests show
critical shear stresses below 1 dyne/cm2
7.1.7 Modified Rotating Cylinder Apparatus
Moore and Marsh (1962) developed an original rotating cylinder test at the
University of Texas at Austin. Baker (Baker, 1996) modified the rotating cylinder device
to reduce friction in the system and to enable direct measurement of the shear stress
induced on the sample.
In essence, the modified rotating cylinder device consists of a stationary soil
sample with a rotating outer cylinder surrounding, but not touching, the soil sample. The
space between the cylinder and soil sample is filled with the chosen eroding fluid. As the
cylinder rotates, the eroding fluid produces shear stress around the sample. The rotational
speed of the cylinder controls the amount of shear. The shear stress may be measured
directly with the modified rotating cylinder device as follows. A floating air puck is
connected on top of the sample. If the soil sample were allowed to turn freely as the
shear stress was induced, friction would be minimal due to the air bearing. However, an
external force resists rotation, which aids in measuring the shear stress. A thin aluminum
beam is attached to the top center of the air puck. A stationary post is placed near the far
end of the beam to resist movement. By this mechanism, the sample is not allowed to
rotate with the eroding fluid and the outer cylinder. As the force is applied, the aluminum
160
beam bends. The amount of deflection is measured by a strain gauge and directly
correlated to shear stress induced on the sample via a gauge factor. Figure 7.15 shows a
schematic of the modified rotating cylinder device.
Figure 7.15
Schematic of the Modified Rotating Cylinder Device (Baker, 1996)
7.1.8 Calculating the Gauge Factor
A strain indicator can be modified via the gauge factor to display shear stress
directly. The gauge factor may be calculated as follows given the dimensions of the
aluminum beam and the placement of the strain gauge:
Figure 7.16
Strain Gauge Placement for Calculation of the Gauge factor (Baker, 1996)
Measure the radius of the sample and the length from the center of the sample to
the strain gauge represented by l 2 in Figure 7.16. Measure the length from the strain
gauge to the point where the stationary post touches the rod and force Fa is applied as
represented by l1 in Figure 7.16. Based on a free body diagram, the equation for shear
stress is:
161
2
2
lb / in
12r l1
(1)
(2)
where:
E = Youngs Modulus of the aluminum beam = 9.6 x 106 psi
b = the thickness of the aluminum beam
h = the height of the aluminum beam
r = the radius of the sample
strain constant = 2.065
The gauge factor may be calculated as:
2.065(12l1 r 2 )
lb / in 2
gage factor =
(3)
When the gauge factor is entered into the strain indicator, the output can be
directly read as shear stress in dyne/cm2.
7.1.9 Measuring the Erosion Rate:
The erosion rate of a sample during a rotating cylinder test is measured as
follows:
e& =
M
At
(4)
where:
e& = the erosion rate
M = the change in sample mass due to a period of testing
t = the time elapsed during a period of testing
A = the surface area of the sample exposed to the eroding fluid
As shown in Figure 7.17 a rotating cylinder test consists of several trial periods
with different shear stresses. Each trial period results in a different erosion rate, which is
plotted versus shear stress. The critical shear stress, C , is determined as the shear stress
at which erosion begins or where the experimental erosion rate/shear stress line crosses
the shear stress axis as Figure 7.2 demonstrates. Below the critical shear stress, the
erosion rate is zero, and the soil will not erode. As seen in Figure 7.17, the critical shear
stress for the Yolo Loam sample is approximately between 0 and 1 dyne/cm2. This
162
indicates a very erodible soil, in combination with this particular pore fluid concentration,
pore fluid Sodium Adsorption Ratio, and eroding fluid (deionized water).
0.25
0.2
0.15
0.1
0.05
0
0
10
20
30
40
Figure 7.17
Rotating Cylinder Test on Yolo Loam with a Pore Fluid Concentration of 50 meq/L
and an SAR of 45 with Deionized Water as the Eroding Fluid (Baker, 1996)
The shear stress may be controlled during a rotating cylinder test by varying the
speed of cylinder rotation. Faster rotation causes greater eroding fluid velocity around
the sample, producing larger shear stresses. The shear stress should be kept constant
during a test time period. Baker (1996) used one-minute test periods. The sample should
be weighed before and after the test period to determine the change in mass. The sample
surface area may be assumed constant during the testing.
7.1.10 Conclusion
The erodibility of consolidated soils depends on the swell potential of a soil, i.e.,
the soil mineralogy, pore fluid composition (SAR and concentration), and concentration
of the eroding fluid. The magnitude of dielectric dispersion depends on mineralogy (and
swell potential), and thus is a useful parameter for determining soil erodibility. The
critical shear stress, C , is a useful parameter defining soil erodibility. C may be
determined via a rotating cylinder test, or by combining the magnitude of dielectric
dispersion with knowledge of the SAR and pore fluid concentration.
7.2 FROST HEAVE
7.2.1 Introduction
When a soil freezes, ice layers or lenses form in the soil, as shown in Figure 7.18.
They range from a millimeter to several centimeters in thickness. The lenses are pure ice
163
and are free from large numbers of entrapped soil particles. As the soil freezes, the
ground surface may heave by as much as several centimeters, and the overall volume
increase can be many times greater than the 9% increase due to the increase in the
volume of water upon freezing.
Due to high heaving pressures, freezing soils under foundations and pavements
can lead to major problems. Uneven uplift can occur during freezing, and there can be a
loss of support when ice lenses melt, leaving water-filled voids in the soil. Clearly,
freezing soils can cause large amounts of damage to structures and roadways.
Figure 7.18
Ice Lenses and Frost Heave (Mitchell, 1993)
There are three necessary conditions for ice lens formation and frost heave:
1. A frost-susceptible soil
2. Freezing temperatures
3. A supply of water
Frost heave is therefore common in areas where winter temperatures are below freezing
and in soils where the water table or a pocket of water is close to the freezing front.
Almost any soil could be made to heave if the water supply and the freezing rate
were properly controlled. However, only certain soils in nature have freezing rates that
make them frost susceptible. Sands, gravels, and fat intact clays generally do not heave.
Soils with more than 3% of their particles smaller than 0.002 mm are potentially frost
susceptible.
7.2.2 Mechanisms of Frost Heave
164
The process of freezing and ice lens formation is complicated. For example, if a
homogeneous soil at a uniform water content and temperature, T0, above freezing is
subjected to a surface temperature, Tn, below freezing, temperatures will vary with depth
at some time t, as shown in Figure 7.19.
Figure 7.19
Variation of Temperature with Depth in a Freezing Soil (after Mitchell, 1993)
The rate of heat flow at any point is given by k(dT/dz). If (dT/dz) at a point A is
greater than at a point B, then the temperature of the element will drop. When the water
changes to ice, it gives up its latent heat, thus slowing the rate the freezing front moves
through the soil.
Heave results from the formation of an ice lens at point A in Figure 7.19. The
energy needed to lift the overlying material is available because ice forms under a
condition of supercooling. One degree Celsius of supercooling is enough to lift 12.5 kg a
distance of 1 cm. As long as water can flow to a growing ice lens fast enough, the
volumetric heat and latent heat can produce a temporary steady-state condition so that
heaving will occur. For example, a silty clay can supply water at a rate adequate for a
heave rate of 1 mm/hr. In a sand, the volume of water in the pores is large, and the latent
heat raises the freezing temperature to the normal freezing point. Therefore, there is no
supercooling and no heave. In a clay, the hydraulic conductivity is so low that water
cannot be supplied fast enough for ice lens growth. Heave can only develop in clays if the
freezing rate is slowed beyond that found in nature. Silts and silty soils have the optimum
combinations of pore size, hydraulic conductivity, and freezing point depression so that
natural rates of freezing in the field can result in large heave.
7.2.3 Segregation Potential Method for Predicting Frost Heave Potential
165
The segregation potential method uses a laboratory freezing test to measure the
property of segregation potential. Segregation potential is defined as the ratio of the rate
of water migration to the overall temperature gradient in the frozen fringe (the zone
between the frost front and the segregation front where ice lenses grow). Water migration
and temperature gradient depend on soil structure and physico-chemical properties.
Therefore, using such an approach to quantify the frost susceptibility of soils will result
in accurate predictions of frost heave.
Although the segregation potential approach is relatively accurate, the freezing
test requires a long time to conduct. Also, unless factors such as cooling rate are kept
constant, the results will vary from laboratory to laboratory. To overcome the long
testing time and discrepancies between laboratories, Arulanandan and Shinde (1989)
developed a relationship between the segregation potential, the c parameter from the
Three-Element Model, and the specific surface area. Figure 7.20 shows this relationship.
Specific surface area can be used to quantify the mineralogy and the shape of the
particles, and the c parameter quantifies pore size distribution. By considering the rate of
water migration, temperature gradient, pore size distribution, mineralogy, and particle
shape, we can accurately predict frost heave potential.
Figure 7.20
Correlation between Specific Surface Area, the c Parameter of the Three-Element
Model, and Segregation Potential
In preparing the results shown in Figure 7.20, specific surface area of the soils
was predicted from the magnitude of dielectric dispersion using the relationship shown in
166
Figure 3.20. The c parameters were determined via Three-Element Model optimizations.
The soil mixtures used by Rieke, et al. (1983) during their segregation potential studies
were duplicated in the laboratory at the University of California, Davis, for electrical
dispersion tests. Rieke then performed segregation potential measurements on the soils
newly mixed at UC Davis (Rieke, 1972; Arulanandan and Shinde, 1989). The pressure
and the rate of cooling affect segregation potential. In this newer study, both the pressure
and the rate of cooling were kept constant to concentrate on pore size and specific surface
area effects (Arulanandan and Shinde, 1989).
7.3 PROBLEMS
1. How can the erodibility characteristics of clays be evaluated? Assuming that you have
no erosion test apparatus at your disposal, describe how you will evaluate the erosion
potential of soil. Discuss the mechanism of clay erosion. Explain the factors that
influence the erodibility characteristics.
2. Describe the mechanism causing frost heave, and how you would evaluate frost heave
potential.
REFERENCES
Alizadeh, A. (1975). Amount and Type of Clay and Pore Fluid Influences on Critical
Shear Stress and Swelling of Cohesive Soils, Dissertation, presented to the University of
California at Davis, CA, in partial fulfillment of the requirements for the degree of
Doctor of Philosophy.
Arulanandan, K., Gillogley, E., Rabbon, P., and Heinzen R. (1976a). Evaluation of
Erodibility Characteristics of Teton Dam Soils, Report to the Independent Panel to
Review Cause of the Teton Dam Failure, October.
Arulanandan, K., and Heinzen, R. T. (1977). Erosion and Solid Matter Transport in
Inland Waters Symposium, Proceedings: Symposium-United Nations Educational,
Scientific and Cultural Organization and IAHS, pp. 75-81.
Arulanandan, K., Loganathan, P., and Krone, R. B. (1975) Pore and Eroding Fluid
Influences on Surface Erosion of Soil, Journal of the Geotechnical Engineering
Division, Proceedings of the American Society of Civil Engineers, Vol. 101, No. GT1,
Jan., pp. 51-66.
Arulanandan, K., Loganathan, P., and Krone, R. B. (1976b) Closure to Pore and
Eroding Influence on the Surface Erosion of a Soil, Journal of Geotechnical
Engineering Division, ASCE, Vol. 102, No. GT8, Proceedings Paper 11078, Aug., pp.
883-884.
167
Arulanandan, K., and Perry, E. B. (1983). Erosion in Relation to Filter Design Criteria
in Earth Dams, Journal of Geotechnical Engineering, ASCE, Vol. 109, No. 5, May, pp.
682-698.
Arulanandan, K., Sargunam, A., Loganathan, P., Krone, R. B. (1973). Application of
Chemical and Electrical Parameters to Prediction of Erodibility, (Special Report 135 on
Soil Erosion), Proceedings: Conference Workshop on Soil Erosion, Highway Research
Board, Jan. 26, pp. 42-51.
Arulanandan, K., and Shinde, S. B. (1989). Frost Heave Susceptibility Criteria For
Soils, Report: Research Department, Esso Resources Canada, ERCL.RS.88.03.
Baker, C. T. (1996). In-Situ Evaluation of Critical Shear Stress and Porosity of Soils,
Thesis submitted in partial satisfaction of the requirements for the degree of Master of
Science, Department of Civil Engineering, University of California at Davis.
Decker, R. S., and Dunnigan, L. P. (1976). Development and Use of the SCS Dispersion
Test, American Society for Testing and Materials Symposium on Dispersive Clays,
Chicago, IL.
Emerson, W. W. (1954). The Determination of the Stability of Soil Crumbs, Journal of
Soil Saturation, Vol. 5, pp. 233-250.
Fernando, M. J., Burau, R. G., and Arulanandan, K. (1977). A New Approach to
Determination of Cation Exchange Capacity, Proceedings: Soil Science Society of
America.
Gibbs, H. J. (1962). A Study of Erosion and Tractive Force Characteristics in Relation
to Soil Mechanics Properties, Soils Engineering Report No. EM-643, U.S. Department
of the Interior, Bureau of Reclamation, Denver, CO.
Independent Panel to Review Cause of the Teton Dam Failure (1976). Report to U.S.
Department of the Interior and the State of Idaho on Failure of the Teton Dam.
Karpoff, K. P. (1955). The Use of Laboratory Tests to Develop Design Criteria for
Protective Filters, Proceedings: American Society of Testing and Materials, Vol. 55, pp.
1183-1193.
Mitchell, J. K., (1993). Fundamentals of Soil Behavior, John Wiley and Sons, New
York.
Moore, W.L., and Masch, F.D. (1962). Experiments on the Scour Resistance of
Cohesive Sediments, Journal of Geophysical Research, 67(4), 1437-1449.
168
Perry, E. B. (1976). Dispersion Characteristics of Soil From Teton Dam, Idaho, Report
to the Independent Panel to Review Cause of Teton Dam Failure.
Rieke, R. D. (1972). The Role of Specific Surface Area and Related Index Properties in
the Frost Susceptibility of Soils, Thesis submitted in partial satisfaction of the
requirements for the degree of Master of Science, Oregon State University, Corvallis.
Rieke, R. D., Vinson, and T. S., Mageau, D. W. (1983). The Role of Specific Surface
Area and Related Index Properties in the Frost Heave Susceptibility of Soils, Fourth
International Conference on Permafrost, National Research Council, Washington, D.C.
Ripley, C. F. (1978). Filter Zones for Earth Dams, Internal Communication-Water
Rights Branch, Ministry of the Environment, Victoria, British Columbia, Canada.
Sherard, J. L. (1972a). Embankment Dam Cracking, Embankment-Dam Engineering,
John Wiley and Sons, Inc., New York, NY, pp. 271-354.
Sherard, J. L. (1972b). Study of Piping Failure and Erosion Damage from Rain in Clay
Dams in Oklahoma and Mississippi, Soil Conservation Service, Washington D.C.,
March.
Sherard, J. L., Dunnigan, L. P., Decker, R. S., and Steel, E. F. (1976) Pinhole Test for
Identifying Dispersive Soils, Journal of Geotechnical Engineering Division, ASCE,
Vol. 102, No. GT1, Jan., pp. 69-85.
Shields, A. (1963). Anwendung der Aen lickei Kemechanik und der Tur bulentz
Porschung auf die Geschiebebewegung, (Berlin, 1936), translated by W. P. Off and
J. C. Van Uchelen, California Institute of Technology, Pasadena, CA.
Vargas, M., and Hsu, S. J. C. (1970). The Use of Vertical Core Drains in Brazilian
Dams, Proceedings, 10th ICOLD, Vol. 1, A36, R36, Montreal, Canada.
Vaughan, P. R.. (1976). Cracking of Embankment Cores and Design of Filters for their
Protection, Soueded Espanola de Mechanica del Suelo y Cimentaciones, No. 23, Sept.Oct., pp. 23-24.
169
Appendix A
Example Applications of the Formation
Factor Method
170
A.1.1 Abstract
The observed dynamic response of the instrumented Wildlife site, California,
during the 1987 Superstition Hills earthquake was utilized to demonstrate the feasibility
of computer simulation of earthquake-induced site response and liquefaction-induced
deformations of a level ground site. A non-destructive in-situ electrical method was used
to obtain the initial state parameters and constitutive model constants representative of
the site. The measured shear wave velocity measurements were compared with the shear
wave velocity values evaluated using the electrical method. The dynamic response
analysis used the effective stress-based, nonlinear, fully coupled, finite element program
SUMDES with a reduced order bounding surface hypo-plasticity model to simulate the
stress-strain behavior of cohesive soils and modified reduced order bounding surface
hypo-plasticity model to simulate the stress-strain behavior of non-cohesive soils. The
results of the dynamic analysis showed that the acceleration, excess pore water pressure
response histories, and liquefaction-induced deformations agreed reasonably well with
the observed behavior during the Superstition Hills earthquake. The results of this study
show that computer simulation of earthquake effects of a level ground site is possible
using non-destructive in-situ testing to obtain the initial state and constitutive model
parameters representative of the site and a verified numerical procedure.
A.1.2. Introduction
Before-the-event evaluation of the response of our infrastructure systems
subjected to earthquakes is a desirable objective for the adoption of appropriate, safe and
economical retrofit measures of existing facilities and the safe and economical design of
new infrastructure facilities. Once a verified numerical procedure and in-situ properties
representative of the site are available, computer simulation of earthquake effects of any
site can be carried out, as demonstrated in a recent paper, Numerical Simulation of
Liquefaction-Induced Deformations (Arulanandan et al., 2000). The first objective of
this paper is to provide an additional example: an evaluation of the earthquake response
of the instrumented site (Wildlife site, California) where the pore pressure and
acceleration time responses and liquefaction-induced deformation were recorded during
the Superstition Hills earthquake of 1987. Wildlife site, California is the only
instrumented site where acceleration time responses, pore pressure time responses,
vertical and lateral deformations have been recorded (Holzer et al., 1989a). The second
objective of this paper is to demonstrate how the initial state parameters and constitutive
1
2
Professor, Dept. of Civ. and Envir. Engrg., Univ. of California, Davis, CA 95616.
Graduate Student, Dept. of Civ. and Envir. Engrg., Univ. of California, Davis, CA 95616.
171
model constants representative of the site were obtained using shear wave velocity and
in-situ formation factor measurements (ERTEC WESTERN, INC., 1982). In the earlier
paper Numerical Simulation of Liquefaction-Induced Deformations (Arulanandan et
al., 2000), the initial state parameters and constitutive model constants were obtained
using laboratory formation factor measurements on remolded samples and shear wave
velocity measurements.
A.1.3 Earthquake and Soil Characteristics at Instrumented Site
On November 24, 1987, at 05:15 PST (Pacific Standard Time) the Superstition
Hills, California earthquake struck the instrumented Wildlife site, adjacent to the Alamo
river in the Imperial valley, caused liquefaction, and developed lateral displacements
toward the river ranging from 0 to 230 mm. Extensive ground cracking indicative of
lateral spreading accompanied liquefaction at the array. The site is 23 km east of the
epicenter of the Elmore ranch earthquake and 31 km east-northeast of the epicenter of the
Superstition Hills earthquake. A location map of the liquefaction array and earthquake
epicenters, a stratigraphic cross-section of the array, and a schematic of instrument
deployment are shown in Figures A1a and A1b. A representative soil profile of the
Wildlife site is shown in Figures A2a and A2b.
172
173
The site had been instrumented with both accelerometers and electrical
piezometers and, for the first time, excess pore water pressure ratios of 100% were
measured in the field in a saturated silty sand site during an earthquake (Youd and
Bartlett, 1988; Holzer et al., 1989 a, b). Six pore water pressure transducers and two three
component force-balance accelerometers, one at the surface and one downhole, were
installed at the array. Instrumentation was installed in 1982. Shallow deposits at the array
consist of saturated, flood plain sediments that fill an old incised channel of the Alamo
River. The uppermost unit at the array is a 2.5 m thick flat lying silt bed that overlies the
unit that liquefied a 4.5 m thick silty sand. Beneath these floodplain deposits is a 5.0 m
thick silty clay unit, the uppermost unit of a dense and regionally extensive sedimentary
deposit. The Alamo River, a perennial stream because of drainage from irrigation,
currently occupies a 3.7 m deep channel 23 m east of the center of the array and controls
the water table depth at about 1.2 m. The soil properties of the site had been thoroughly
measured prior to the earthquake. Therefore, the 1987 Superstition Hills, California
earthquake records provide researchers with a unique opportunity to improve the
understanding of the mechanics of seismic pore pressure build up and liquefaction, as
well as the understanding the complex relation between pore pressure, water flow,
cracking and permanent displacements during lateral spreads.
A.1.4 Field Investigations
Seismic shear wave velocity tests and in-situ resistivity measurements were
performed at the Wildlife site on February 9, 10, 11 and 12, 1982. The field resistivity
measurements were obtained using a Geoelectronics Electrical Soil Probe Model GE-100
shown in Figures A3a and A3b. The electrical soil probe consists of a 3-inch diameter, 5
foot long tube with one foot hollow section at the end. The one foot hollow section is
similar to a conventional thin wall sampler, except that it contains three oriented
electrodes located on the surface of the inside wall. Aggregate soil resistivity is measured
in two directions between the three electrodes. In the probes solid section, an electric
pump draws fluid from the soil into an electrode cavity where water resistivity
measurements are automatically taken.
A drill rig is used to bore the hole to push the probe 9 inches into the undisturbed
soil at the borehole bottom. The operator then balances the down-hole resistivity bridge
from the surface control box. The bridge impedance is incrementally stepped by digital
electronic messages sent from the microprocessor housed in the instrument case or, if
necessary, the bridge is balanced manually. Separate readings from the horizontal
electrode set, the vertical electrode set, and the water cavity electrode set are then taken.
Crosshole shear wave velocity surveys were conducted at the field site. The
surveys were performed to determine the compressional (Pwave) and the shear wave
(Swave) velocities of the subsurface materials. During a crosshole survey, the seismic
waves were generated at a specific depth in a boring. The waves were detected by
geophones which were positioned at the same depth in adjacent borings. The result of a
crosshole survey is a profile of horizontally measured seismic velocities varying with
depth. Seismic waves were generated by striking the top of the drill rod in the source
boring with a sledge hammer while the drill bit was in contact with the formation. This
procedure generated relatively large amplitude, vertically oriented, S waves and much
174
lower level P waves in the horizontal travel path. Crosshole shear wave velocity
measurements are compared with the shear wave velocities evaluated using the electrical
method in Figure A3c.
175
177
178
179
180
laboratory tests to avoid disturbance of the sample to calibrate constitutive models seem
to be a major obstacle in advancing the use of fully coupled, effective stress-based,
nonlinear, numerical procedures using elastoplastic constitutive models. The in-situ nondestructive site characterization is necessary to get the initial state parameters and
constitutive model constants representative of the site for the computer simulation of the
site to earthquakes.
It has been shown experimentally by numerous studies conducted by Archie
(1942), Arulanandan and Kutter (1978) and Wyllie and Gregory (1957) that a nondimensional electrical parameter, called the formation factor, is dependent upon the
particle shape, long axis orientation, contact orientation and size distribution, and also
cementation, degree of saturation, void ratio and anisotropy. The formation factor is thus
a function of the fabric of the soil and varies with stress to the extent that the fabric is
altered by the stress. An index, the formation factor F, is experimentally obtained as the
ratio of the conductivity of the pore fluid and the conductivity of the soil sample. Thus,
the formation factor is a non-dimensional parameter. It depends on sand structure,
especially on its elements associated with particle arrangement, particle shape, and
porosity. The dependence of the formation factor on void ratio, particle shape and long
axis orientation has been shown theoretically by Arulanandan and Dafalias (1979), and
Dafalias and Arulanandan (1979). The formation factor F has been shown to be a
valuable directional index parameter when the sand structure is anisotropic. Due to the
above facts, in-situ measurements of formation factor (F) provides a means to
characterize the structure of sands in the field and to obtain empirical correlations
between shape and the anisotropic state of sand characterized in terms of F and the
engineering behavior such as liquefaction characteristics of sands.
The formation factor can be used to quantify and predict the porosity, shape and
anisotropy of sand deposits. An average formation factor F , is given by
F=
( Fv + 2 Fh )
3
(A1)
where, Fv is the vertical formation factor and Fh is the horizontal formation factor.
It has been shown that F is independent of anisotropy caused by the orientation
of preferred particles and is a direct measure of porosity (n), for a given sand. For
practical purposes, an integration technique proposed by Bruggeman (1935) was used by
Dafalias and Arulanandan (1979) to derive an expression for the average formation
factor, F , as a function of porosity (n), and average shape factor ( f ), as
-f
F =n
(A2)
It has been shown both theoretically and experimentally that the shape factor is
directional and depends on porosity, gradation, the particles shape and orientation of the
particles (Dafalias and Arulanandan, 1979; Arulanandan and Kutter, 1978). An
anisotropy index (A), was introduced by Arulanandan and Kutter (1978) as
F
A = v
Fh
0.5
(A3)
181
The anisotropy of sand structure is due to the orientation of individual particles and the
contact orientation.
A.1.10 Method of Analysis
Samples were taken from the silty sand layer at the instrumented site at wildlife
site, California, and a correlation between the formation factor and porosity was
established (see Figure A7).
182
From the non-destructive electrical measurements, the average shape factor and
anisotropy index were calculated. The average formation factor was calculated using insitu non-destructive resistivity measurements in two different directions. Porosity was
obtained from the pre-established relationship (see Figure A7) between formation factor
and porosity using the calculated average formation factor. All the constitutive model
constants and initial state parameters were calculated using the average formation factor,
average shape factor and anisotropy index as detailed in Chapter 6 (also see Arulanandan
et al. 2000).
A.1.11 Comparison of Shear Wave Velocity Measurements
A correlation between K2max and the electrical parameter F /( A f ) 0.5 is given by
Arulanandan et al. (1983) and is used to obtain K2max. K2max depends on void ratio, strain
amplitude, geological age of the sand mass and in situ stresses. The mean effective
confining pressure, p, can be calculated using site configuration and unit weight of the
soil mass. The maximum shear modulus can be obtained using
Gmax = 1000 K 2 max ( p )
0.5
(A4)
where p and Gmax are given in pounds per square foot. Using known maximum shear
modulus and density of soil mass, one can obtain the shear wave velocity
Vs =
G max
(A5)
The comparison of the shear wave velocity values calculated using above
procedure with the measured crosshole shear wave velocity values as shown in Figure
A3c demonstrate a reasonable agreement.
A.1.12 Analysis Results
183
accelerations at the ground surface are compared in Figure A10. Note that recorded and
SUMDES results compare favorably.
184
Recorded and evaluated excess pore water pressures at different depths are shown
in Figures A11a and A11b, respectively. Field pore water pressure measurements were
reported for comparison with the evaluated pore water pressure during the earthquake
shaking at four different depths. The maximum pore water pressure ratio variation with
depth is shown in Figure A12. It shows that the zone of high pore water pressure ratio in
excess of 90% extended in the first 6.8m below water table. Pore pressure time histories,
in terms of pore-pressure ratio, recorded and evaluated are shown in Figures A13a and
A13b, respectively. Vertical settlement variation with time at the ground surface is shown
185
in Figure A14a. Reported average vertical settlement at the ground surface is about 5 cm.
Evaluated lateral displacement variation with depth is shown in Figure A14b. Reported
maximum lateral displacement 230 mm occurred at the waterfront (Dobry et al. 1989).
The observed lateral displacements were generally large near the waterfront and
decreased with distance inland. These results provide validation to the computational
analysis.
186
187
188
189
190
A14a
191
A14b
A.1.13 Conclusions
The authors are indebted to Dr. X. S. Li and Prof. Y.F. Dafalias for reviewing the
manuscript and providing valuable comments.
192
A.1.15 References
193
194
195
Fh
Fv
f
Gmax
Go
hp
hr
Ko
K2max
k
kr
m
n
n
q
Rp/Rf
ec
p
= anisotropy index
= parameter affecting the shape of the stress paths of the virgin shear
loading
= parameter which characterizes the rate of the effective mean normal stress
change caused by shear unloading
= average formation factor
= horizontal formation factor
= vertical formation factor
= average shape factor
= maximum shear modulus
= constant related to shear modulus
= parameter controlling the amount of shear strain increment due to the
change of the maximum effective mean normal stress in the loading
history
= parameter which characterizes the relationship between shear modulus
and shear strain magnitude
= coefficient of earth pressure at rest
= modulus related to maximum shear modulus
= coefficient of hydraulic conductivity
= parameter which characterizes the amount of the effective mean normal
stress change caused by shear loading
= model constant
= model constant
= porosity
= deviatoric stress
= ratio of stress ratio at phase transformation state and stress ratio at failure
state
= friction angle
= slope of the rebound line in e-ln(p) space
= constant
= state parameter
= critical void ratio
= pressure
196
197
Figure A15
Major Causative Faults in Treasure Island (TI) Vicinity (modified from Housner
and Penzien, 1991), Probability of Magnitude 7+ Earthquake (Working Group on
California Earthquake Probabilities, 1990). Rectangle T1 Indicates Instrumented
Area
198
The first 13.6 m at the fire station site is composed of tan and grey sands. The
groundwater level was measured at approximately 1.4 m below the surface of this
material in August 1991. Beginning at the surface (see Figure A16), a thin layer of
dumped fill overlies 7.7 m of tan and grey hydraulic fills. Below these fills is a thin layer
of naturally deposited shoal material. This is underlain by a thin layer of sandy clay to
clayey sand, which transitions to a dark grey silty clay layer. The dark grey clay layer
shown between 13.6 m and 29.2 m in Figure A16 contains several shelly layers and is
part of the Young Bay Mud formation. The fine to coarse sand layer underlying the
Young Bay Mud is made up of four sublayers belonging to the San Antonio formation.
Small, uniformly sized shell particles in sublayer A at the fire station site suggest an
association with the aeolian parts of the Merritt sands. Sublayer B does not fit
descriptions of units found in the Posey sands, which often underlies the Merritt sands,
but is somewhat similar to a silty and clayey unit belonging to the Merritt sands. The
large shell fragments and many rounded pebbles in sublayer C mark a clear distinction
from the upper two layers (A and B). Sublayer C fits well into what Trask and Rolston
term the D-2 unit of the San Antonio formation. Trask and Rolston's San Antonio forms
the lowest portion of the larger San Antonio formation, suggesting an association with
sublayer D. The grey-green clay layer between 42.4 m and 75.6 m is part of the Old Bay
Clay. Between the Old Bay Clay and bedrock is 5.5 m of gravelly sand, followed by 10 m
of clay. These are parts of the Alameda formation.
199
Figure A16
Schematic Soil Profile with Correlations of Layers to Geological Formations.
A.2.4 Analysis
1. Initial and constitutive model constants were evaluated using the electrical parameters
F, f , and A . Using the values of porosity n, coefficient of earth pressure at rest Ko,
and shear modulus Gmax, and the relationships between the electrical parameters
F, f , and A and the above properties, electrical parameters F, f , and A were
evaluated.
2. Verified numerical code SUMDES was used to predict, before-the-event the site's
response to earthquake loading. Vertical heterogeneity observed at the lower sand
layer (29.2 m to 42.4 m) was analyzed; the influence of the heterogeneity on the
lateral deformation was demonstrated. The influence of earthquake magnitude on pore
200
pressures, lateral deformation, and settlement were shown using the Kern County and
Foster City Earthquakes (see No. 3).
3. Kern County CA 1952 07 21 0453 PDT Earthquake of Magnitude 7.5 was scaled for
the distance from the causative fault using scaling laws, and used in the analysis.
Similarly, the Foster City Earthquake of Magnitude 7.0 was used in the analysis.
A.2.5 Soil Properties
The following tables and figures (from Pass, 1994) were used to obtain the values
of porosity n, coefficient of earth pressure at rest Ko, and shear modulus Gmax for major
layers.
201
202
203
204
Figure A17
Profiles of G0 Calculated Using Crosshole Shear Wave Velocities
205
Figure A18
Profiles of Lateral Stress Coefficient (K0) from Self-Boring Pressuremeter Testing
and Dilatometer Testing
206
Model Parameters
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
Friction Angle
n Porosity
K0 Earth pressure coefficient at rest
k Coefficient of hydraulic conductivity
G0 Initial elastic shear modulus
The slope of the virgin compression line
The slope of the rebound line
hr The parameter that characterizes the relationship between shear modulus and
shear strain magnitude.
b A parameter affecting the shape of the stress path of the virgin shear loading
Rp/ Rf The ratio of the slope of the phase transformation line to the slope of the
failure line.
d characterizes the rate of the effective mean normal stress change caused by shear
unloading.
kr characterizes the amount of the effective mean normal stress change caused by
shear loading.
207
Figure A19
Influences of d, Kr, b, and Rp/Rf
a. For a sandy soil with known A 3 / F f , select two or more shear stress amplitudes
first, with a specified mean normal confining pressure.
b. Assume a pair of parameters (kr and d).
c. Run utility program TESTMODL for the two or more stress levels. Count the number
of cycles required to cause liquefaction for each of the shear stress amplitudes.
d. Check the results obtained from (c) against the given relationship of stress ratio versus
number of cycles to liquefaction. Adjust the two parameters (kr and d) if needed.
e. Repeat steps (c) and (d) until satisfactory results are obtained.
Parameter Descriptions
- Friction angles
Using electrical measurements one can obtain f . With f , the slope of the
critical state line (M) in the q -p' space can be obtained as shown in the paper by
Arulanandan et al. 1994 (see Figure A20).
Moreover, from;
208
M =
(6 sin )
(3 sin )
Figure A20
Relationship Between the Average Shape Factor and the Slope of the Critical
State Line (M) in q p Space
n -Porosity
Using electrical measurements one can obtain porosity using an established
relationship between formation factor and porosity for a particular soil as shown in
Arulmoli et al.1985 (see Figure A21).
209
Figure A21
Vertical, Horizontal and Average Formation Factor versus Porosity
Relationships for Monterey 0/30 Sand Prepared by Three Different Methods
210
Figure A22
The Relationship Between the Coefficient of Lateral Earth Pressure at Rest
and the Electrical Index, A4 f (Meegoda and Arulanandan, 1986)
+ ......... +
6 1 + 2
d
d
d
2
n
1
SSA =
100
where W1, W2, ..etc, are the percentages passing; and di is the average diameter
between Wi and Wi-1.
Arulanandan and Muraleetharan, 1988, have shown the linear relationship
between hydraulic conductivity and an electrical index above as shown in Figure A23.
211
Figure A23
Correlation between Vertical Hydraulic Conductivity of Sands and Silty
Sands and an Electrical Index
Go
This parameter is the modulus coefficient defining the initial (maximum) elastic
shear modulus Gmax using the following equation (Li, et al., 1992):
K2max depends on void ratio, strain amplitude geological age of the sand mass and in situ
stresses. P is the mean effective confining pressure, in pounds per square foot and Gmax is
given in pound per square foot. A correlation between K2max and the electrical parameter
F /( A f )0.5 is given by Arulanandan, et al. (1983) and is used to obtain K2max.
212
Figure A24
Correlation between K2 max and Electrical Parameter, F /( A f )1 / 2
Figure A25
Correlation Between Compression Index and Electrical Index Af / F for
Sands (after Harvey, 1981)
213
The slope of the rebound line in e -In(p') space is defined by (Li, et al., 1992)
hr
The parameter, hr , characterizes the relationship between shear modulus and shear
strain magnitude. The value of hr can be determined based on the standard modulus
reduction curve (Li, et al., 1992) or the secant shear modulus measured at a control shear
strain. The parameter hr, so calibrated, is in general a function of density (Li, et al., 1999).
b
This is a parameter affecting the shape of the stress paths of the virgin shear
loading. A typical value of b is 2.0.
kr
The parameter, kr characterizes the amount of the effective mean normal stress
change caused by shear loading. kr value also affects the liquefaction resistance. Since do
is a constant kr is not an independent parameter (Li, et al., 1999). kr must satisfy the
calibrated value of do.
d
The parameter, d, characterizes the rate of the effective mean normal stress
change caused by shear unloading. This parameter is the major one controlling the
liquefaction resistance of a material.
Stress Ratio Required to Cause Liquefaction
214
Figure A26
Correlation Between Cyclic Stress Ratio Required to Cause Initial
Liquefaction and Number of Cycles for Different Values of Electrical Index,
A3 / (F f )
(A6)
215
K2max = 24.2
(A7)
Using,
F = n f
F = 0.4 f
(A8)
(1 F ) (SSA)
1 / f
=5
216
kr = 0.5
d = 0.72
Similar calculations were done for other layers. The following table summarize the state
and model parameters.
Table A5 State and Model Parameters
217
Horizontal Direction 1
Horizontal Direction 2
Vertical
Figure A27
Kern County Earthquake Input Motions
218
Displacement (m)
Depth (m)
-0.50
0
0.00
-20
-40
-60
-80
0.50
1.00
With vertical
Hetrogeniety
Without Vertical
Hetrogeniety
Figure A28
Evaluated Lateral Displacement with Depth
Simulated Kern County Earthquake
219
1.2
1
5 m Depth
0.8
10 m Depth
0.6
26.5 m Depth
0.4
36.5 m Depth
62 m Depth
0.2
0
0
20
40
60
Time (Sec)
Figure A29
Variation of Pore Water Pressure with Depth
Simulated Kern County Earthquake
Predicted Vertical Settlement
0.000
Settlement (m)
-0.005 0
10
20
30
40
50
-0.010
-0.015
-0.020
-0.025
-0.030
-0.035
-0.040
Time (Sec)
Figure A30
Predicted Vertical Settlement
Simulated Kern County Earthquake
220
Stress (Pa)
60000
40000
20000
0
-0.05 -200000.00
-40000
-60000
0.05
0.10
0.15
Strain (%)
Figure A31
Stress-Strain Plot at 40 m Depth (Liquefied
Element)
Simulated Kern County Earthquake
Acceleration at the Surface N00E Component
Acc (m/s )
1.0
0.0
0
10
20
30
40
50
60
50
60
50
60
-1.0
Time (Sec)
Acc (m/s2)
2.0
1.0
0.0
-1.0 0
10
20
30
40
Time (Sec)
Acc (m/s )
1.0
-4.0
10
20
30
40
Time (Sec)
Figure A32
Evaluated Surface Accelerations
Simulated Kern County Earthquake
221
Acc (m/s )
1.00
10.00
Period (Sec)
Acc (m/s
2)
6
4
2
0
0.10
1.00
10.00
Period (Sec)
Acc (m/s )
1.00
10.00
Period (Sec)
Figure A33
Evaluated Surface Response Spectra
Simulated Kern County Earthquake
222
Horizontal Direction 1
Horizontal Direction 2
Vertical
Figure A34
Foster City Earthquake Input Motions
223
90
80
70
60
50
40
30
20
10
0
0
100
200
300
400
500
600
Time (Sec)
Figure A35
Excess Pore Water Pressure at a Depth of 5m
Simulated Foster City Earthquake
Excess Porewater
Pressure Ratio
1.5
1.0
0.5
0.0
0
20
40
60
Time (Sec)
1.5
1.0
0.5
0.0
0
20
40
60
Time (Sec)
Figure A36
Excess Pore Water Pressure Ratios at Different Depths
Simulated Foster City Earthquake
224
Excess Porewater
Pressure Ratio
1.5
1.0
0.5
0.0
0
20
40
60
Time (Sec)
Excess Porewater
Pressure Ratio
1.5
1.0
0.5
0.0
0
20
40
60
Time (Sec)
225
Depth (m)
-0.85
0
-10
-20
-30
-40
-50
-60
-70
-80
0.15
1.15
2.15
With Vertical
Hetrogeniety
Witout Vertical
Hetrogeniety
Displacement (m)
Figure A37
Predicted Lateral Displacements
Simulated Foster City Earthquake
Settlement (m)
0.000
-0.001
10
20
30
40
50
60
-0.002
-0.003
-0.004
-0.005
-0.006
-0.007
Time (Sec)
Figure A38
Predicted Vertical Settlement
Simulated Foster City Earthquake
226
Stress (KPa)
100
50
0
0.00
-0.10
0.10
0.20
0.30
0.40
-50
-100
Strain (%)
Figure A39
Stress-Strain Plot for a Liquefied Element at 40 m Depth
Simulated Foster City Earthquake
A.2.9 Summary
Using the values of porosity n, Coefficient of earth pressure at rest Ko, and Shear
Modulus Gmax and the relationships between the electrical parameters F , f , and A and
the above properties, the electrical parameters F , f , and A were evaluated. Initial and
Constitutive model constants were evaluated using the calculated electrical parameters.
Verified numerical code SUMDES was used to predict before the event evaluation of the
response of the site to earthquake loading.
A.2.10 References
227
228
APPENDIX B
DERIVATIONS
B.1 DOUBLE-LAYER THEORY
B.1.1 Double Layer Equations
The concentration of ions (ions/m3) of type i, ni, in a force field at equilibrium is
given by the Boltzmann equation
E Ei
ni = ni 0 exp i 0
kT
(B1)
where the subscript 0 represents the reference state, taken to be at a large distance from
the surface, E is the potential energy, T is temperature (0K), and k is the Boltzmann
constant (1.38 x 10-23 J0K-1).
For ions in an electric field, the potential energy is
E = vi e
(B2)
where vi is the ionic valence, e is the electronic charge (1.602 x 10-19 coulomb), and is
the electrical potential at the point. Potential varies with distance from a charged surface
in the manner shown by Figure B1. In clays, is negative because of the negative
surface charge. The potential at the surface is designated as 0. As Ei0 = 0, because = 0
at a large distance from the surface,
Ei0 Ei = - vi e and the Boltzmann equation becomes
vi e
ni = ni 0 exp
kT
(B3)
The Poisson equation relates potential, charge, and distance. For one-dimensional case
d 2
=
2
dx
(B4)
where x is distance from the surface (m), is charge density (C/m3), and is the static
permittivity of the medium (C2J-1m-1). The charge density in the diffuse layer is
contributed by the ions so that
= e vini
(B5)
229
kT
= e vi ni 0 exp
(B6)
dx
kT
(B7)
Equation (B7) is the differential equation for electric double layer adjacent to a planer
surface. Its solution provides a basis for computation of electrical potential and ion
concentrations as a function of distance from the surface.
For the case of a single cation and anion species of equal valence, that is, i = 2 and
v+ = v - = v, n0+ = n0- = n0, equation (B7) simplifies to the Poisson-Boltzmann equation
d 2 2n0 ve
v e
=
sinh i
dx
kT
(B8)
Figure B1
Variation of Electrical Potential with distance from a Charged Surface
B.1.2 Single Diffuse Double Layer
230
kT
ve 0
z=
kT
and
Potential functions
(B9)
= Kx Distance function
where
K2 =
2 n0 e 2 v 2
kT
(B10)
(B11)
dy
= 0 . Thus,
d
(B12)
e z / 2 + 1 + (e z / 2 1)e
e z / 2 + 1 (e z / 2 1)e
(B13)
Equation (B13) describes a roughly exponential decay of potential with distance from the
surface.
If the surface potential is small (less than about 25 mV), ve/kT << 1, and
equation (B8) may approximated by
d 2
= K 2
dx 2
(B14)
= 0 e Kx
(B15)
where
and the potential decreases purely exponentially with distance. In this case, the center of
gravity of the diffuse charge is located at a distance x = 1/K from the surface.
Consequently, the quantity (1/K) is a measure of the thickness of the double layer.
From equation (B10),
1 = o DkT
(B16)
K
2no e 2 2
231
APPENDIX C
LABORATORY EXERCISES
C.1 DIELECTRIC DISPERSION
C.1.1 Objective
Use laboratory equipment to determine radio frequency alternating current (AC) response
characteristics for different soil samples. These electrical properties are then correlated to
standard geotechnical engineering properties.
C.1.2 Equipment and Materials
Soil samples
Test cell with opposing semi-circular electrodes
Impedance analyzer for use at frequencies of 2 MHz and 32 MHz
Moisture content cups and spatula for obtaining moisture content sample
Microwave oven and analytical scale for moisture content determination
C.1.3 Background
Traditional soil behavior analysis involves index testing of remolded laboratory samples,
mechanical testing of undisturbed field samples in the laboratory, or in-situ field testing,
typically using empirical correlations with standard penetration test (SPT) or cone penetration
test (CPT) results.
This laboratory exercise demonstrates the use of relatively simple radio frequency
measurements on soil samples from the field. Other equipment that have been developed for
direct AC response in the field include the Dielectric Conductivity Cone Probe and the
Formation Factor Probe. As described previously, various correlations have been developed to
obtain soil physical properties from the soil-radio frequency AC response (Arulanandan and
Smith, 1973; Arulanandan et al., 1994; and Basu and Arulanandan, 1973).
C.1.4 Procedure
Soil samples are prepared for testing as follows:
A quantity of sand is pluviated into the test cell.
A clay sample in a field sampling tube may be extruded into the test cell, or a clay
sample may be consolidated inside the test cell.
Using the dielectric laboratory probe (shown in Chapter 5, Section 5.1.11) or an
impedance analyzer, each sample is tested at AC frequencies of 2 MHz and 32 MHz. Specific
assumptions for the tests include:
All samples are saturated.
232
The last assumption may not be valid for some soils. For example, heavy clays such as
illite and montmorillonite require a frequency of at least 55 MHz. Note that with an impedance
analyzer, higher frequencies may be used, but 32MHz will be used in this text to concur with the
laboratory dielectric probe frequency readings. With each soil in the test cell, testing involves
balancing electrical circuitry to obtain constant voltage readings, VC and VR. These values are
used with the calibration charts to obtain the apparent dielectric constant, . Porosity is
determined as described in this textbook. After each sample is tested, it is extruded from the test
cell, and a sample is obtained for moisture content determination. Based on routine soil
mechanics correlations, porosity is calculated and compared to that obtained by electrical testing.
C.1.5 Report
1. Sketch the test apparatus.
2. Report dielectric constant at different frequencies for each soil sample.
3. Determine porosity based on Figure 4.11, and determine the theoretical porosity based on
traditional soil mechanics.
4. Compare and discuss results.
C.1.6 Lab References
Arulanandan, K., and Smith, S. S. (1973). Electrical Dispersion in Relation to Soil Structure,
Journal of the Soil Mechanics and Foundations Division, ASCE, 99 (SM12), 1113-1133.
Arulanandan, K., Yogachandran, C., and Rashidi, H. (1994). Dielectric and Conductivity
Methods of Soil Characterization, Geophysical Characterization of Sites, XIII ICSMFE, New
Delhi, India, 81-90.
Basu, R., and Arulanandan, K., (1973). A New Approach to the Identification of Swell
Potential in Soils, Proceedings of Third International Conference on Expansive Soils, Haifa,
Israel, Vol. 1, 1-11.
233
Clay sample
Boonton RX Meter, Model 250
Moisture content cups and spatula for obtaining moisture content sample
Microwave oven and analytical scale for moisture content determination
Optimization software program
C.2.3 Background
What follows first is a brief discussion of the Three-Element Model. The Three-Element
Model addresses the mineral-solution interface characteristics of a soil-water-electrolyte system
by describing the electrical behavior of soil in terms of an electrical network model. The
geometrical parameters in the model are:
a = area of the cluster-solution path
b = area of the cluster contact path
c = area of the solution path
d = length of path in the solids solution phase
The area of b is very small and may be taken as about 0.0006 to 0.006. Since this is
negligible, we have a = 1 c. Further, d is a function of water content, so depending on water
content and type of clay (or dielectric dispersion), d will vary between 0.7 and 1.0. Arulanandan
and Smith (1973) note that the parameter, c, should depend on such factors as porosity, particle
shape, orientation, and cementation. As can be seen, this parameter becomes very important in
optimizing the Three-Element Model. The c parameter varies from about 0.03 to 0.2.
The compositional parameters in the model are:
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C.3.3 Background
Traditional soil behavior analysis involves index testing of remolded laboratory samples,
mechanical testing of undisturbed field samples in the laboratory, or in-situ field testing,
typically using empirical correlations with standard penetration test (SPT) or cone penetration
test (CPT) results. This laboratory exercise demonstrates the use of relatively simple radio
frequency apparatus on soil samples from the field. Other equipment that have been developed
for direct AC response in the field include the Dielectric Laboratory Probe and the Formation
Factor Probe. Various correlations have been developed to obtain soil physical properties from
the soil radio frequency AC response (Arulanandan and Smith, 1973; Arulanandan, et al., 1994;
and Basu and Arulanandan, 1973).
C.3.4 Procedure
Soil samples are prepared for testing as follows:
Sand is pluviated into a large container
A saturated clay sample is prepared in a similar container
Calibration charts for the dielectric probe are needed beforehand. Each sample is tested at AC
frequencies of 2 MHz and 32 MHz. Specific assumptions for the tests include:
This textbook notes that the last assumption may not be valid for some soils. For
example, heavy clays such as illite and montmorillonite need a frequency of at least 55 MHz.
With each soil in the test cell, testing involves balancing electrical circuitry to obtain constant
236
voltage readings, VC and VR. These values are used with the calibration charts to obtain the
apparent dielectric constant, . Porosity is determined based on the relationship developed in this
textbook.
After each soil is tested with the Dielectric Cone Probe, the probe is removed from the
test container and a representative soil sample is obtained for moisture content determination.
Based on routine soil mechanics correlations, porosity is calculated and compared to that
obtained by electrical testing.
C.3.5 Report
1. Sketch the test arrangement, including soil sample, probe and connections to control unit.
2. Report dielectric constant at different frequencies for each soil sample.
3. Determine the porosity of both samples based on , and determine the theoretical
porosity based on traditional soil mechanics.
4. Compare and discuss results.
5. Discuss applications in the field.
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C.4.3 Background
The subject of cohesive soil erodibility has been of concern in soil science and dam core
design for some time, as has the general erodibility of clayey soils. Various methods have been
developed in an attempt to evaluate the potential erodibility of a cohesive soil. The Rotating
Cylinder Test was originally proposed by Arulanandan, et al. (1975). The test method is
described below under Procedure. Some benefits of this test over the previous dispersion tests
are:
Quantitative test results are available.
The test can be used on any combination of clay soil and eroding water.
A critical shear stress can be identified below which surface erosion is absent or very
slow.
Because of the geometry of the test apparatus and the nature of clay soil erodibility, a
linear relationship has been demonstrated between applied shear stress (above critical
stress) and erosion rate.
The critical shear stress, c, is an important result from this test, and is defined as the
shear stress at which erosion begins. Arulanandan and Perry (1983) showed that this value could
be obtained by extrapolating a graph of observed erosion rate vs. shear stress as shown in Figure
7.17.
This value can then be used to quantify erodibility. In fact, Arulanandan and Perry
(1983) proposed some preliminary categories based on limited data for erodibility in terms of
critical shear stress, as follows:
Erodible soils, c 4 dynes/cm2
Moderately erodible soils, 4 dynes/cm2 c < 9 dynes/cm2
Erosion resistant, c 9 dynes/cm2
C.4.4 Procedure
1. Prior to mounting in the test apparatus, weigh the soil sample (a cylinder of cohesive soil,
approximately 3 inches in diameter and 3 inches high).
2. Measure the conductivity of the eroding fluid, and fill the transparent rotating cylinder half
full with the eroding fluid. Deionized water is a good eroding fluid to use for testing, as it
reasonably represents rainwater as well as natural waters found in freshwater impoundments.
3. Mount the soil sample concentrically inside the larger cylinder such that a -inch annular
space remains between sample and cylinder.
4. Rotate the cylinder at a specified speed (shear stress). After rotation for 2 minutes, remove
the eroding fluid (distilled water) and soil sample.
5. Replace the eroding fluid with clean fluid, if needed, and weigh the soil sample.
6. Repeat Steps 4 and 5 as necessary, calculating the erosion rate after each 2-minute run. The
erosion rate, e& is defined as:
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e& =
M
At
Where, M is the change in mass (grams), A is the surface area of the sample exposed to the
eroding fluid, and t is the time of rotation.
Note: As the outer cylinder is rotated with the inner cylinder (soil sample) held stationary,
rotation is imparted to the fluid. This movement of the fluid, in turn, transmits a shear to the
surface of the inner cylinder (soil). Since the annular spacing between the soil sample and the
outer cylinder is constant, and since there are no abrupt changes in roughness on the eroding
surface, the stresses are believed to be nearly uniform at all points on the surface of the soil. The
soil sample is stationary, but is mounted on a compressed air bearing. Thus, the shear stress
transmitted to the surface results in a slight rotation of the supporting mandrel against a
mechanical load. The rotation is measured by a strain gauge and pressure transducer. A
schematic of the rotating cylinder test apparatus is shown in the text.
C.4.5 Report
1.
2.
3.
4.
5.
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ISBN 978-0-615-18983-3