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Heat (Q):
Is the transfer of energy between a system and its environment due to a
temperature difference between them.
Units of Heat
1- SI unit: Joule (J)
2- calorie (cal), where:
1 cal = 4.186 J
3- Calorie, with a capital C, used in describing the energy
content of foods, is actually a kilocalorie.
1 Cal = 1000 cal = 4186 J
SPECIFIC HEAT
If a quantity of energy Q is transferred to a substance of mass m, changing
its temperature by T = Tf - Ti , the specific heat c of the substance is
defined by:
(1)
SI unit: Joule per kilogram-degree Celsius ( J/kg . oC)
Dr. M. IBRAHIM
(2)
Example:
The energy required to raise the temperature of 0.5 kg of water by 3 C is:
Q=mcT
Q = (0.5 kg) (4186 J/ kg C) (3C) = 6.28 x 10 3 J.
Note:
When the temperature increases, then Tf > Ti , then T is positive, hence Q
is positive as well. This means that thermal energy (heat) transfers into the
system.
When the temperature decreases, then Tf < Ti , then T is negative, hence Q
is negative as well. This means that thermal energy (heat) transfers out of
the system.
The table below shows the specific heat for some substances.
Dr. M. IBRAHIM
CALORIMETRY
One technique for measuring the specific heat of an object (solid or liquid) of
known mass mx, is to raise its temperature to some known temperature T x,
placing it in a vessel containing water of known mass m w and temperature Tw
(Tw < Tx), and measuring the final temperature of the water after equilibrium
has been reached, Tf . This technique is called calorimetry, and devices in
which this energy transfer occurs are called calorimeters (calorimeter is an
insulated vessel, so that energy doesnt leave it).
If the system of the sample and the water is isolated, the principle of
conservation of energy requires that the amount of energy Q hot that leaves
the object (of unknown specific heat) equal the amount of energy Q cold that
enters the water. Then:
Qcold + Q hot = 0
Qcold is positive because energy is flowing into cooler objects, and Q hot is
negative because energy is leaving the hot object. Then
mwcw(Tf - Tw) = mxcx(Tf - Tx)
If cw is known, then cx can be determined.
Example:
A 125-g block of an unknown substance with a temperature of 90.0 oC is
placed in a Styrofoam cup containing 0.326 kg of water at 20.0 oC. The
system reaches an equilibrium temperature of 22.4 oC. What is the specific
heat, cx, of the unknown substance if the heat capacity of the cup is
neglected?
Dr. M. IBRAHIM
Solution:
Q = mL
(3)
where L, called the latent heat of the substance, depends on the nature of
the phase change as well as on the substance. This parameter is called latent
heat (literally, the hidden heat) because this added or removed energy
does not result in a temperature change.
SI unit: The unit of latent heat is the joule per kilogram ( J/kg).
The latent heat of fusion Lf is used when a phase change occurs during
melting or freezing.
The latent heat of vaporization Lv is used when a phase change occurs during
boiling or condensing.
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Dr. M. IBRAHIM
Then, when there is phase change, the temperature remains constant. The
heat supplied to the substance is needed for: (i) molecules to overcome
attractive forces from other molecules. (ii) separate molecules to greater
distances (increase the potential energy of molecules), (iii) breaking bonds.
The speed of molecules (and hence the average kinetic energy) doesnt
change since the temperature is constant.
Example:
Find the heat required to transfer a 1.00-g cube of ice at -30.0C into steam
(water vapor) at 120.0C.
Dr. M. IBRAHIM
The total amount of energy that must be added to change 1.00 g of ice at
-30.0C to steam at 120.0C is the sum of the results from all five parts of
the curve = 3.11 x 103 J.
ENERGY TRANSFER
Thermal energy (heat) flows spontaneously (by itself) from hotter to colder
bodies, never the other way round. Heat continues to transfer from the
hotter body to the colder body until both bodies have the same temperature.
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When this happens, the two bodies are said to be in thermal equilibrium.
Thermal energy is transferred by heat between a system and its
surroundings by three processes: thermal conduction, convection, and
radiation.
Thermal Conduction
Conduction is the flow of heat along matter without any flow of matter.
For heat to flow by conduction from one body to another, the two bodies
must be in contact.
Conduction is explained by means of the kinetic molecular theory. The fastmoving molecules in the hotter parts of matter collide with the slower-moving
molecules in the colder parts in contact with them, thus, passing on to them a
part of their kinetic energy. Therefore, kinetic energy travels across
molecule to molecule.
Metals are best conductors of heat because they have many free electrons
that are free to move throughout the body of the metal. If part of the
metallic object is hotter than another, free-moving fast electrons move
across the body of the metal, and thus carry thermal energy across the body,
much faster than it can be transferred from molecule to molecule by
molecular collision. Therefore metals are better conductors than non-metallic
solids.
Silver and copper are the best conductors of thermal energy. Water, glass,
air, plastic and wood are poor conductors of heat. Poor conductors of heat
are called insulators.
Consider a slab of material of thickness L and cross-sectional area A with its
opposite faces at different temperatures Tc and Th, where Th > Tc.
The slab allows energy to transfer from the region of higher temperature to
the region of lower temperature by thermal conduction.
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Dr. M. IBRAHIM
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Convection
In fluids (liquids and gases) heat transfers partly by conduction, but more
importantly by a natural stirring phenomenon called convection.
Convection is the flow of heat through a fluid from places of higher
temperature to places of lower temperature by the movement of the fluid
itself.
When a quantity of fluid is heated it expands i.e. its volume increases. Its
mass, however remains constant, hence its density (density = mass/volume)
decreases, hence it tends to float upward. Other denser parts of the fluid
sink, thus moving downward. The result is that upward, downward and lateral
currents of fluid movement are created. These currents are called convection
currents.
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Convection examples:
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Radiation
Radiation is the transfer of heat energy in the form of an infra-red
radiation (waves) that is a part of electromagnetic spectrum.
The radiation of heat occurs from any hot body. Heat radiation travels in all
directions from a hot source with the speed of light 3x108 m/s.
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Dark dull surfaces are good emitters and good absorbers of heat
radiation.
Bright shiny surfaces are poor emitters AND poor absorbers of heat
radiation.
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Example:
A steel railroad track has a length of 30.0 m when the temperature is 0 oC.
What is its length on a hot day when the temperature is 40.0 oC?
Solution:
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where M is the molar mass of the substance (the molar mass of the
substance is defined as the mass of one mole of that substance, usually
expressed in grams per mole).
Note:
It turns out that Avogadros number was chosen so that the mass in grams of
one Avogadros number of an element is numerically the same as the mass of
one atom of the element, expressed in atomic mass units (u).
This relationship is very convenient. Looking at the periodic table of the
elements, we find that carbon has an atomic mass of 12 u, so, the molar mass
of carbon M = 12 g and 12 g of carbon consists of exactly 6.02 x 10 23 atoms
of carbon. The atomic mass of oxygen is 16 u, so in 16 g of oxygen there are
again 6.02 x 1023 atoms of oxygen.
The pressure P (Pa), volume V (m3), temperature T (K), and amount n of an
ideal gas in a container are related to each other by an equation of state:
PV = nRT
Notes:
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1- T (K) = T ( C) + 273.
-3
2- V (in liters: L) = 10 m .
3- The pressure of a gas is explained by the particles colliding with the
sides of the container (constant volume), in doing so they exert a
force, and hence a pressure.
Example:
An ideal gas at 20.0 oC and a pressure of 1.50 x 10 5 Pa is in a container having
a volume of 1.00 L. (a) Determine the number of moles of gas in the container.
(b) The gas pushes against a piston, expanding to twice its original volume,
while the pressure falls to atmospheric pressure. Find the final temperature
of the gas.
Solution:
(a)
(b)
Then:
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This means that the temperature of a gas is a direct measure of the average
molecular kinetic energy of the gas. As the temperature of a gas increases,
the molecules move with higher average kinetic energy.
The total translational kinetic energy of N molecules of gas is simply N times
the average energy per molecule:
Since the mass of the gas m that has N molecules each of mass is: m = N,
then:
From this result, we see that the total translational kinetic energy of a
system of molecules is proportional to the absolute temperature of the
system.
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If the temperature of the gas in the container increases, then the particles
gain kinetic energy and will move faster and collide with the side more
frequently and hit the walls harder, therefore exert a greater pressure.
For a monatomic gas, translational kinetic energy is the only type of energy
the molecules can have, so the internal energy U for a monatomic gas:
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W = - F y = - PA y
W = - P V
Where P is the pressure throughout the gas and V (Vf Vi) is the change in
volume of the gas during the process.
If the gas is compressed, V is negative (Vf < Vi) and the work done on the
gas is positive. If the gas expands, V is positive (Vf > Vi) and the work done
on the gas is negative. If V doesnt change (Vf = Vi), the work is zero.
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The work done on the gas equals the negative of the area under the
graph in a PV diagram.
Example:
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Quick Quiz
By visual inspection, order the PV diagrams shown below from the most
negative work done on the system to the most positive work done on the
system.
(a)a,b,c,d (b) a,c,b,d (c) d,b,c,a (d) d,a,c,b
Notice that the graphs in the above figure all have the same starting and
endpoints, but the areas beneath the curves are different. The work done
on a system depends on the path taken in the PV diagram.
EXAMPLE
Find the work done on the gas in Figures a and b above.
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Isobaric Processes
In an isobaric process the pressure remains constant as the gas expands or is
compressed.
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Isobaric expansion
Isobaric compression
Adiabatic Processes
In an adiabatic process, no energy enters or leaves the system by heat. Such
a system is insulatedthermally isolated from its environment. In general,
however, the system isnt mechanically isolated, so it can still do work. A
sufficiently rapid process may be considered approximately adiabatic because
there isnt time for any significant transfer of energy by heat.
For adiabatic processes Q = 0, so the first law becomes:
Isovolumetric Processes
U = W
Isothermal Processes
During an isothermal process, the temperature of a system doesnt change. In
an ideal gas the internal energy U depends only on the temperature, so it
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Isobaric expansion
Isobaric compression
Cyclic Processes
During a cyclic process, the gas starts at some state and returns back to it.
Then Ui = Uf, so it follows that U = 0. In this case, the first law of
thermodynamics gives:
W=-Q
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The magnitude of the work done in a cyclic process equals the area enclosed
by the cycle.
Example:
Example:
A quantity of 4.00 moles of a monatomic
ideal gas expands from an initial volume of
0.100 m3 to a final volume of 0.300 m3 and
pressure of 2.5 x 105 Pa as shown. Compute
(a) the work done on the gas, (b) the
change in internal energy of the gas, and
(c) the thermal energy transferred to the
gas.
Solution
(a)
Find the work done on the gas by computing the area under the
curve:
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(c)
THE
SECOND
LAW
OF
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The thermal efficiency e of a heat engine is defined as the work done by the
engine, Weng, divided by the energy absorbed during one cycle, Qh:
Example:
During one cycle, an engine extracts 2.00 x 10 3 J of energy from a hot
reservoir and transfers 1.50 x 103 J to a cold reservoir. (a) Find the thermal
efficiency of the engine. (b) How much work does this engine do in one cycle?
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(c) How much power does the engine generate if it goes through four cycles
in 2.50 s?
Solution
(a)
(b)
(c)
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For a Carnot engine, the following relationship between the thermal energy
transfers and the absolute temperatures can be derived:
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Example:
A steam engine has a boiler that operates at 500 K. The energy from the
boiler changes water to steam, which drives the piston. The temperature of
the exhaust is that of the outside air, 300 K. (a) What is the maximum
possible engines efficiency? (b) If a 3.50 x 103 J of energy is supplied from
the boiler, find the work done by the engine on its environment.
Solution
(a)
(b)
ENTROPY
Studies showed that isolated systems tend toward disorder, and entropy S is
a measure of this disorder. For example, if you could view gas molecules, you
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would see that they move haphazardly in all directions, bumping into one
another, changing speed upon collision, some going fast and others going
slowly. This situation is highly disordered.
Let Q be the energy absorbed or expelled during a reversible, constant
temperature process between two equilibrium states. Then the change in
entropy during any constant temperature process connecting the two
equilibrium states is defined as:
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Past AP Papers
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2008
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