AIiTS 5 (XII) - SET D

INDIA(Advance)
iNTERNAL TEST SERIES

FIITJEE ALL
- JEE
CHEMISTRY, MATHEMATICS & PHYSICS
SET D
APT - 5
CODE: 080089.4
Time Allotted: 3 Hours
AI2TS - 5
Maximum Marks: 207
Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet
before attempting the paper. Wrong CODE or no CODE will give wrong results.
CLASS - XII
A.
General Instructions
B.
Filling of OMR Sheet
C.
Attempt ALL the questions. Answers have to be marked on the OMR sheets.
This question paper contains Three Sections.
Section-1 is Chemistry, Section-2 is Mathematics and Section-3 is Physics.
Each section has two parts: Part-A & Part-C
Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
OMR sheet contains alphabets, numerals & special characters for marking answers.
Marking Scheme For All Parts.
Part-A (01 07) contains 7 Multiple Choice Questions which have only one correct answer. Each
question carries +3 marks for correct answer and 1 mark for wrong answer.
Part-A (08 11) contains 2 Paragraphs. Based upon paragraph, 2 Multiple Choice Questions have
to be answered. Each question has only one correct answer and carries +4 marks for correct answer.
There is no negative marking.
Part-A (12 15) contains 4 Multiple Choice Questions which have one or more than one correct
answer. Each question carries +3 marks for correct answer. There is no negative marking.
Part-C (01 05) contains 5 Numerical Based questions with single digit integer as answer, ranging
from 0 to 9 and each question carries +4 marks for correct answer and 1 mark for wrong answer.
Name of the Candidate : ____________________________________________

Batch : ___________________ Date of Examination : ____________________
Enrolment Number : _______________________________________________
FIITJEE
Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
Website: www.fiitjee.com, Mail : aiits@fiitjee.com
2
AI2TS-5-(APT-5)-SET-D-CMP-XII
ALL INDIA iNTERNAL TEST SERIES
SECTION 1 (Chemistry)
PART A
(Single Correct Choice Type)
This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONLY ONE is correct.
1.
Which statement is incorrect for the molecule PCl5?

(A)
(B)
(C)
(D)
2.
What is the sum of the number of electrons with = 0 and = 2 present in Cu ion?
(A)
3.
It has trigonal bipyramidal geometry

It contains two different sets of PCl bonds in terms of bond length
3
Phosphorus undergoes dsp hybridization
+
In solid state it exists as [PCl4] and [PCl6] ions.
18
(B)
16
(C)
15
(D)
17
X(g)
Y(g) + Z(g)
The concentrations of X, Y and Z gases in the above reaction are same at equilibrium which is
established at 6 atm and 40C. The equilibrium constant Kp is :
(A)
4.
0.5 atm
(B)
2 atm
(C)
3 atm
(D)
1.5 atm
Graph is given for the following reaction, X(g)

Y(g) + Z(g).
Choose correct statement regarding the reaction.
-1
(A) The unit of rate constant is time
t1/2
(in sec)
(B)
It is a second order reaction
(C)
The rate of reaction does not depend on concentration of reactant

The rate of reaction decreases with time i.e., with progress of
reaction.
(D)
[A0](in M)
Space for rough work
FIITJEE
3
5.
X(g)
Products
If the initial concentration of X in the above reaction is reduced to half-of its initial value, the half-life
is reduced to
(A)
6.
1 th
of its initial value, what is the order of the reaction?
8
(B)
-1
(C)
-2
The greatest angle observed in the following molecule is :

(A)
(B)
(D)
Cl
7.
(D)
c
(C)
C
d
a
H
The electron of hydrogen atom was excited from ground state to a higher orbit. During de-excitation
of the electron, photons of six different wavelengths were emitted. If each photon forms a spectral
line, how many spectral line will be visible to naked eye?
(A)
(B)
(C)
(D)
FIITJEE
4
(Comprehension Type)
This section contains 2 paragraphs. Based upon each paragraph 2 multiple choice questions have to be
answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
Paragraph for Questions 08 to 09
Read the paragraph carefully and answer the following questions:
2X(g) 3Y(g)
X2 Y3 (g)
Data for the above reaction is given below :
Expt. No.
[X0] in mol L1
1
0.1
2
0.2
3
0.2
8.
Rate in mol L1s1

4 108
16 108
32 108
What is the rate constant of the reaction?

(A)
(C)
9.
[Y0] in mol L1
0.1
0.1
0.2
4 106 mol2L s1
2
4 105 mol2L s1
2
(B)
(D)
4 108 mol2L s1
2
4 104 mol2L s1
2
Which statement is correct for the half life of X?

(A)
(B)
(C)
(D)
It is directly proportional to concentration of X

It is inversely proportional to the concentration of X
It is directly proportional to the square of concentration of X
It is inversely proportional to the square of concentration of X
Gaseous reactions generally takes place in closed vessels. The reactions proceed towards both direction
at equilibrium whatever may be the difference of number of gaseous moles of products and reactants.
A 10 litre vessel contains one mole each of SO3 , CO, SO2 and CO2 at 400 K.
SO3 (g) CO(g)

SO2 (g) CO2 (g)
The above reaction attains equilibrium in the closed 10 L vessel at 400 K. 50%(mole) of reactants
undergo reaction at equilibrium.
Answer the following questions on the basis of above write up :
10.
If 1, 2, 3, and 4 moles of SO3 ,CO,SO2 and CO2 respectively are taken in a 10 litre vessel and the
above reaction takes place in it, then the reaction will proceed towards.
(A)
(C)
11.
forward direction
both direction
(B)
(D)
backward direction
Unpredictable
(C)
13.136 atm
What is the equilibrium pressure of the system?

(A)
11.336 atm
(B)
1.316 atm
(D)
11.846 atm
FIITJEE
5
(Multi Correct Choice Type)

ONE OR MORE may be correct.
12.
2KClO3 s
2KCl s 3O2 g ; H ve
The product yield of above reaction can be increased by
(A)
(C)
13.
increasing temperature
removing KCl
(B)
(D)
decreasing pressure
adding KClO3
Which of the following statement(s) is/are correct for PF2Cl3?
F
F
P
Cl
Cl
Cl
(A)
(B)
(C)
(D)
14.
The order of a reaction can be changed by

(A)
(B)
(C)
(D)
15.
Fluorine occupy the axial positions of the tbp geometry which triangular plane contains chlorine
atoms at vertices and phosphorus at centre
Its dipole moment is zero
The orbitals used by phosphorus for hybridization are 3s,3p x,3py which comprises the triangular
2
2
plane with sp hybridization, and 3pz and 3dz which are perpendicular to the plane
The structure of the molecule is
changing concentration
using catalyst
increasing temperature
increasing partial pressure in case of gaseous reactants
The electronic configuration of an atom is :

2
10
1s 2s 2p 3s 3p 3d 4s 4p
Which of the following statement(s) is/are correct for the atom.

(A)
(B)
The spin multiplicity of the atom is 4

It contains eight electrons with l = 0
(C)
Its spin magnetic moment is 2 2B.M

Its tripositive ion contains the electron configuration of an inert gas
(D)
FIITJEE
6
PART C
(Integer Answer Type)
This section contains 05 multiple choice questions. The answer to each question is a single digit integer, ranging
from 0 to 9 (both inclusive).
1.
What is the sum of the number of unpaired electrons present in the given species? N, N2, O, O2
2.
The time and concentration graph of the reactant(X) and

product(Y) of the following first order reaction is given above.
3X g
Y g
If the half-life of the reaction is 4 sec, then the value of t in sec.

unit is:
Concentration
in M
t
Time in min
3.
What is the azimuthal quantum number of the unpaired electron of chlorine?
4.
How many maximum number of electrons of an atom have the following set of quantum numbers?
n = 4, = 0, 1, 2, m = 0, +1, s = -
5.
NH4Cl s
NH3 g HCl g
2
The equilibrium constant Kp of the above reversible reaction is 16 atm at 400 K. What is the
equilibrium pressure in atm unit?
FIITJEE
7
SECTION 2 (Mathematics)
PART A
1.
The function f x x2 3x 2 cos x is not differentiable at

(A)
2.
(B)
(D)
4x 3
4x 3
2 cos
is
2
6
3 2
(B)
(C)
(D)
If f x 9x 3 x 1 x , 1 , then the range of f x is ([.] denotes the greatest integer

function)
(A)
4.
The period of the function f x 4 sin4
(A)
3.
(C)
0,1,2,3,4,5,6
(B)
0,1,2,3,4,5,6,7
(C)
1,2,3,4,5,6
(D)
1,2,3,4,5,6,7
1
x
If 2 x2 3 , then the number of positive roots of x 2 , (where {x} denotes the
fractional
part of x) is
(A)
5.
(C)
1/ x 1
, 0 1,
(B)
(D)
(D)
None of these
0 , then S is equal to
(C)
, 0 1,
100x 99 sin x
, where [.] denotes the greatest integer function, is

sin x x
The value of lim

x0
(A)
7.
(B)
If S is the set of all real x for which 1 e

(A)
6.
197
(B)
198
(C)
199
The relation R on the set of complex numbers defined by z1Rz2 if and only if
(A)
(C)
reflexive but not symmetric

symmetric but not transitive
(B)
(D)
(D)
does not exist
z1 z 2
z1 z 2
is real, is
reflexive but not transitive

an equivalence relation
FIITJEE
8
A circular arc of radius 1 subtends an angle of x radians, 0 x
, as shown in the figure. The point R

2
is the intersection of the two tangent lines at P and Q. Let T (x) be the area of triangle PQR and let S(x)
be the area of the shaded region.
R
P
Q
x
1
O
On the basis of above information, answer the following questions:

8.

x0 S x
The value of lim
(A)
9.
T x
1/2
is
(B)
2/3
(C)
(D)
3/2
(B)
1/3
(C)
1/2
(D)
2/3
The value of S ' is

(A)
FIITJEE
9

f x min x x , x x , 2 x 2; g x 2 x 2 , 2 x 2
Let
and
sin x
(D)
None of these
h x
, 2 x 2 ,
sin x
x0
(where [x] denotes the greatest integer function).

On the basis of above information, answer the following questions:
The sum of all the roots of the equation g x h x 0 is
10. 1/2
(A)
11.
Positive
(B)
Negative
Zero
(C)
The set of values of a such that the equation f x a 0 has exactly eight real and distinct roots
is
(A)
a 0,
(B)
1
2
a 0,
(C)
a 0, 1
(D)
a 0, 1
FIITJEE
10

12.
x 1 1 t dt,x 2
If f x 0
(A)
(B)
(C)
(D)
13.
5x 1, x 2
, then
f(x) is not continuous at x = 2

f (x) is continuous but not differentiable at x = 2
f (x) is differentiable everywhere
the right derivative of f x at x = 2 does not exist
If f x 2x sinx and g x 3 x, then

(A)
(C)
range of gof is R
both f and g are one one
(B)
(D)
gof is one one

both f and g are onto
14. Which of the following functions are periodic?
(A)
f x sin x sin x
g x
(B)
1 sinx 1 sec x
1 cos x 1 cos ec x
p x x x
(C)
15.
h x max sinx,cos x
lim x
x
(A)
lim
x0
x 1 x
2
x
3x 10 ,
3
3
where [.] denotes the greatest integer

function.
equals
ln 1 x x
2
(D)
(B)
lim
x0
1 cos x
x
(C)
lim
x0
1 x 1
x
(D)
lim
x0
x
2
x x 2x
FIITJEE
11
PART C
x
2
1.
The number of solutions of sin 2x x 2 2 1 is
2.
1 sin3 x
,
x
2
2
3 cos x
1/3
b
If f x a,
is continuous at x , then the value of is
x
2
2
a
b
1
sin
x
2x 2 , x 2
3.
If f x f y f
4.
If f x
3f 3
f x
xy
for
all
,
and
,
then
the
value
of
is
x,y
R
xy
1
lim
x0 x
f ' 2
1 xy
sin
1 x .cos1 1 x , then the value of

2 x.1 x
18 2
lim f x is (where {x} denotes the

x0
fractional part of x)
5.
x
x
x
cos tan
is . The value of
4
12
3
The fundamental period of the function f x sin
is (where [.] denotes the greatest integer function)
FIITJEE
12
SECTION 3 (Physics)
PART A
1.
A person walking at the rate of 3km/hour, the rain appears to fall vertically when he increase his to
0
speed 6 km/hr it appears to meet him at angle of 45 with vertical. The speed of rain is
(A)
2.
3 2 km / hr
(B)
km / hr
(C)
(D)
6 2 km / hr
2 3 km / hr
Force acting on a particle moving in a straight line varies with the velocity of the particle as
F=
. Here, K is a constant. The work done by the this force in time t is:
(A)
K
v
3.
(B)
.t
(C)
Kt
(D)
2Kt
v
Acceleration time graph of a particle is shown. Work done by all the forces
acting on the particle on the particle of mass m in time interval from t 1 to t2
while a1 is the acceleration at time t1, is given by :
(A)
ma12 3
3
(t 2 t1 )
4t1
(C)
ma1 4
4
(t 2 t1 )
2
4t1
(B)
4.
2Kt
(D)
ma1 4
4
(t 2 t1 )
2
8t1
ma1
2t1
2
2
(t 2 t1 )
If vectors P, Q and R have magnitude 5, 12 and 13 units and P Q R , the angle between Q and
R is
(A)
cos
5
12
(B)
cos
(C)
cos
13
1 12
13
(D)
cos
7
13
FIITJEE
13
5.
A spring has a length l1 when tension in it is n1(in N). It has a length l2 when tension is n2 (in N). Find
its spring constant :
(A)
6.
(n2l2 n11
l )
(l1 l2 )
(B)
(n1 n2 )
(l1 l2 )
(C)
(n2 n1)
(l1 l2 )
(D)
(n11
l n2l2 )
(l1 l2 )
A particle is projected from ground At a height of 0.4 m from the ground, the velocity of a projectile in
vector form is v (6i 2j) m/s (the x-axis is horizontal and y-axis is vertically upwards). The angle of
2
projection is (g = 10 m/s ) :
(A)
7.
45
(B)
60
(C)
30
(D)
tan (3/4)
A block of mass 2 kg rests on a rough inclined plane making an angle of 30 with the horizontal. The
coefficient of static friction between the block and the plane is 0.7. The frictional force on the block is
(A)
9.8 N
(B)
0.79.8 3N
(C)
9.8 3 N
(D)
0.7 9.8 N
FIITJEE
14
A block of mass 6 kg is kept on a rough horizontal surface and is pulled by time varying force F = Kt
1
where K = 5Ns , acting at an angle 37 with horizontal. It is observed that motion of block has started at t
2
2
= 4 sec. and just after that acceleration of block is 2/3 m/s (g = 10 m/s ).
8.
Co-efficient of static friction between block & surface is

(A)
9.
2/3
(B)
1/3
(C)
4/5
(D)
(D)
233
m/s
2
Velocity of block when it breaks off the surface is equal to

(A)
218 m/s
(B)
128 m/s
(C)
112 m/s

Taking y axis along line of greatest slope of the given

inclined plane and x axis perpendicular to it as shown in
figure. A body is projected along the inclined plane with
0
speed 10 m/s at an angle 53 with x axis from origin O ( g =
2
10 m/s )
10 m/s
53
O
37
10.
Time after which body is moving perpendicular to initial direction is (approx)

(A)
11.
2.1 sec
(B)
1.8 sec
(C)
3 sec
(D)
3.6 sec
(D)
2 13 m / s
Speed of body after t = 2 sec is

(A)
2 10 m / s
(B)
42 m / s
(C)
13 m / s
FIITJEE
15

12.
The potential energy of a particle moving along x-axis is given by U = 20 + 5sin(4x) where U is in J
and x is in metre under the action of conservative force :
(A)
(C)
13.
(B)
(D)
at x = 7/8 m, particle is not at equilibrium.

x = 3/8 m, particle is not at equilibrium.
S1, S2 and S3 are the different sizes of windows 1, 2 and 3 respectively, placed in a
vertical plane. A particle is thrown up in that vertical plane. Find the correct options :
(A)
(B)
(C)
(D)
14.
at x = 7/8m, particle is at equilibrium.

x = 3/8m, particle is at equilibrium.
average speed of the particle passing the windows may be equal if S1 < S2 < S3
average speed of the particle passing the windows may be equal if S1 > S2 > S3
if S1 = S2 = S3, the change in speed of the particle while crossing the windows will satisfy V1 <
V2 < V3
if S1 = S2 = S3 , the time taken by particle to cross the windows will satisfy t 1 < t2 < t3
A bead is sliding down a smooth, massless rod PQ attached on the circumference

of a vertical circle of radius R. The bead starts from rest from P :
(A)
Time taken by bead to go from P to Q is 2
R cos
g
15.
(B)
Time taken by bead to go from P to Q is
(C)
The velocity of bead when it reaches centre of circle is 2g R cos
(D)
The velocity of bead when it reaches centre of circle is 2 gR cos
g cos
A ball of mass m is attached to the lower end of light vertical spring of force constant k. The
upper end of the spring is fixed. The ball is released form rest with the spring at its normal (unstretched) length, and comes to rest again after descending through a distance x. Then,
(A)
(B)
(C)
(D)
x = mg/k
x = 2mg/k
The ball will have no acceleration at the position where it has descended through x/2.
The ball will have an upward acceleration equal to g at its lowermost position
FIITJEE
16
PART C
1.
Potential energy of a particle moving along x-axis is given by U =
x3 9x 2
20x . Find out

3
2
position of stable equilibrium state.

2.
Power supplied to a particle of mass 2 kg varies with time as P
3t
W. Here t in second. If velocity
of particle at t = 0 is v=0. Find the velocity (in m/sec) of the particle at time t = 2Sec.
3.
In the figure, find the minimum value of mass m (in kg) of the rod so
that the block of mass M =12 kg remains stationary on the inclined
2
plane (take g = 10 m/s ) assume there is no friction between rod and
block
rod
m
= 0.5
37
4.
3
kg is placed horizontally. The length of rod
2
In a hemispherical shell of radius R, a rod of mass
is R. Find the normal reaction at any end of the rod (in N).
5.
Two blocks of masses 6 kg and 4 kg connected by a

rope of mass 4 kg are resting on frictionless floor as
shown. If a constant force of 21 Newton is applied to
6 kg block, tension (In N) in the rope at point B is
(CB BA = 1 : 1)
4 kg
Q
6 kg
C
21N
FIITJEE

AIiTS 5 (XII) - SET D

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INDIA(Advance)

iNTERNAL TEST SERIES

Time Allotted: 3 Hours

Filling of OMR Sheet

Marking Scheme For All Parts.

Name of the Candidate : ____________________________________________

ALL INDIA iNTERNAL TEST SERIES

Which statement is incorrect for the molecule PCl5?

It has trigonal bipyramidal geometry

Graph is given for the following reaction, X(g)

It is a second order reaction

The rate of reaction does not depend on concentration of reactant

Space for rough work

ALL INDIA iNTERNAL TEST SERIES

The greatest angle observed in the following molecule is :

Space for rough work

ALL INDIA iNTERNAL TEST SERIES

Rate in mol L1s1

What is the rate constant of the reaction?

Which statement is correct for the half life of X?

It is directly proportional to concentration of X

Read the paragraph carefully and answer the following questions:

SO3 (g) CO(g)

What is the equilibrium pressure of the system?

Space for rough work

ALL INDIA iNTERNAL TEST SERIES

(Multi Correct Choice Type)

Which of the following statement(s) is/are correct for PF2Cl3?

The order of a reaction can be changed by

The electronic configuration of an atom is :

Which of the following statement(s) is/are correct for the atom.

The spin multiplicity of the atom is 4

Its spin magnetic moment is 2 2B.M

Space for rough work

ALL INDIA iNTERNAL TEST SERIES

The time and concentration graph of the reactant(X) and

If the half-life of the reaction is 4 sec, then the value of t in sec.

What is the azimuthal quantum number of the unpaired electron of chlorine?

Space for rough work

ALL INDIA iNTERNAL TEST SERIES

The function f x x2 3x 2 cos x is not differentiable at

If f x 9x 3 x 1 x , 1 , then the range of f x is ([.] denotes the greatest integer

The period of the function f x 4 sin4

If 2 x2 3 , then the number of positive roots of x 2 , (where {x} denotes the

, where [.] denotes the greatest integer function, is

The value of lim

If S is the set of all real x for which 1 e

reflexive but not symmetric

does not exist

reflexive but not transitive

Space for rough work

ALL INDIA iNTERNAL TEST SERIES

A circular arc of radius 1 subtends an angle of x radians, 0 x

, as shown in the figure. The point R

On the basis of above information, answer the following questions:

The value of lim

The value of S ' is

Space for rough work

ALL INDIA iNTERNAL TEST SERIES

Paragraph for Questions 10 to 11

(where [x] denotes the greatest integer function).

Space for rough work

ALL INDIA iNTERNAL TEST SERIES